#------------------------------------------------------------------------------
#$Date: 2016-02-13 20:28:24 +0100 (Sat 13 de Feb de 2016) $
#$Revision: 176429 $
#$URL: svn://www.crystallography.net/cod/cif/1/53/23/1532353.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1532353
loop_
_publ_author_name
'Uma, S.'
'Bliesner, R.'
'Sleight, A.W.'
_publ_section_title
;
 Oxygen ion conductivity in new oxygen deficient phases with scheelite
 related structures
;
_journal_name_full               'Solid State Sciences'
_journal_page_first              329
_journal_page_last               333
_journal_volume                  4
_journal_year                    2002
_chemical_formula_sum            'Bi0.7225 Ca0.2775 O3.92 V'
_chemical_name_systematic        'Bi0.71 Ca0.29 V O3.855'
_space_group_IT_number           81
_symmetry_space_group_name_Hall  'P -4'
_symmetry_space_group_name_H-M   'P -4'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   5.121
_cell_length_b                   5.121
_cell_length_c                   11.701
_cell_volume                     306.855
_citation_journal_id_ASTM        SSSCFJ
_cod_data_source_file            Uma_SSSCFJ_2002_925.cif
_cod_data_source_block           Bi0.7225Ca0.2775O3.92V1
_cod_original_cell_volume        306.8545
_cod_original_formula_sum        'Bi0.7225 Ca0.2775 O3.92 V1'
_cod_database_code               1532353
loop_
_symmetry_equiv_pos_as_xyz
x,y,z
y,-x,-z
-x,-y,z
-y,x,-z
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
Bi2 Bi+5 0.5 0 0.2501 0.58 0.0
O3 O-2 0.252 0.142 0.167 1 0.0
V1 V+5 0 0 0.5 1 0.0
O4 O-2 0.738 0.379 0.069 1 0.0
Ca2 Ca+2 0.5 0 0.2501 0.42 0.0
O1 O-2 0.132 0.237 0.422 0.92 0.0
Ca1 Ca+2 0 0 0 0.27 0.0
Bi3 Bi+3 0.5 0.5 0.5 1 0.0
O2 O-2 0.36 0.752 0.328 1 0.0
Bi1 Bi+5 0 0 0 0.73 0.0
V2 V+5 0.5 0.5 0 1 0.0
V3 V 0 0.5 0.249 1 0.0
