#------------------------------------------------------------------------------
#$Date: 2021-04-12 10:27:20 +0200 (lun 12 de abr de 2021) $
#$Revision: 264049 $
#$URL: svn://www.crystallography.net/cod/cif/1/56/16/1561651.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1561651
loop_
_publ_author_name
'Baranets, Sviatoslav'
'Darone, Gregory M.'
'Bobev, Svilen'
_publ_section_title
;
 Synthesis and structure of Sr14Zn1+As11 and Eu14Zn1+As11 (x ≤
 0.5). New members of the family of pnictides isotypic with Ca14AlSb11,
 exhibiting a new type of structural disorder
;
_journal_name_full               'Journal of Solid State Chemistry'
_journal_page_first              120990
_journal_paper_doi               10.1016/j.jssc.2019.120990
_journal_volume                  280
_journal_year                    2019
_chemical_formula_sum            'As11 Eu14 Zn1.14'
_chemical_formula_weight         3026.08
_space_group_crystal_system      tetragonal
_space_group_IT_number           142
_space_group_name_Hall           '-I 4bd 2c'
_space_group_name_H-M_alt        'I 41/a c d :2'
_atom_sites_solution_hydrogens   .
_atom_sites_solution_primary     dual
_audit_contact_author_name
;
;
_audit_creation_date             2019-08-13
_audit_creation_method
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   16.2717(6)
_cell_length_b                   16.2717(6)
_cell_length_c                   21.6878(9)
_cell_measurement_reflns_used    4094
_cell_measurement_temperature    200(2)
_cell_measurement_theta_max      29.22
_cell_measurement_theta_min      5.01
_cell_volume                     5742.2(4)
_computing_cell_refinement       'SAINT V8.38A (?, 2016)'
_computing_data_reduction        'SAINT V8.38A (?, 2016)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_diffrn_ambient_temperature      200.0
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0770
_diffrn_reflns_av_unetI/netI     0.0317
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            35514
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         29.615
_diffrn_reflns_theta_min         2.503
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    43.565
_exptl_absorpt_correction_T_max  0.2644
_exptl_absorpt_correction_T_min  0.1128
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
'SADABS-2016/2 (Bruker,2016/2) was used for absorption correction. wR2(int) was 0.1944 before and 0.0700 after correction. The Ratio of minimum to maximum transmission is 0.4266. The λ/2 correction factor is Not present.'
_exptl_crystal_colour            grey
_exptl_crystal_density_diffrn    7.001
_exptl_crystal_description       block
_exptl_crystal_F_000             10234
_exptl_crystal_size_max          0.106
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.051
_refine_diff_density_max         1.556
_refine_diff_density_min         -1.330
_refine_diff_density_rms         0.333
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.083
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     75
_refine_ls_number_reflns         2028
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.083
_refine_ls_R_factor_all          0.0363
_refine_ls_R_factor_gt           0.0268
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0194P)²+99.6403P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0553
_refine_ls_wR_factor_ref         0.0584
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                1713
_reflns_number_total             2028
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            JSSC-2019-120990.cif
_cod_data_source_block           I
_cod_original_cell_volume        5742.2(5)
_cod_original_sg_symbol_H-M      'I 41/a c d'
_cod_database_code               1561651
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.215
_shelx_estimated_absorpt_t_min   0.091
_olex2_refinement_description
;
1. Uiso/Uaniso restraints and constraints
Uanis(Eu4A) = Uanis(Eu4B)
Uanis(Eu2A) = Uanis(Eu2B)
2. Others
 Sof(Eu2B)=Sof(Eu4B)=1-FVAR(1)
 Sof(Eu2A)=Sof(Eu4A)=FVAR(1)
 Fixed Sof: As4(0.25)
;
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-y+1/4, x+3/4, z+1/4'
'y+1/4, -x+1/4, z+3/4'
'-x+1/2, y, -z'
'x, -y, -z+1/2'
'y+1/4, x+3/4, -z+3/4'
'-y+1/4, -x+1/4, -z+1/4'
'x+1/2, y+1/2, z+1/2'
'-x+1, -y+1/2, z+1'
'-y+3/4, x+5/4, z+3/4'
'y+3/4, -x+3/4, z+5/4'
'-x+1, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z+1'
'y+3/4, x+5/4, -z+5/4'
'-y+3/4, -x+3/4, -z+3/4'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'y-1/4, -x-3/4, -z-1/4'
'-y-1/4, x-1/4, -z-3/4'
'x-1/2, -y, z'
'-x, y, z-1/2'
'-y-1/4, -x-3/4, z-3/4'
'y-1/4, x-1/4, z-1/4'
'-x+1/2, -y+1/2, -z+1/2'
'x, y+1/2, -z'
'y+1/4, -x-1/4, -z+1/4'
'-y+1/4, x+1/4, -z-1/4'
'x, -y+1/2, z+1/2'
'-x+1/2, y+1/2, z'
'-y+1/4, -x-1/4, z-1/4'
'y+1/4, x+1/4, z+1/4'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.04408(2) 0.07200(2) 0.17178(2) 0.01389(9) Uani 1 1 d . . . . .
Eu2A Eu 0.02233(3) 0.37539(3) 0.00176(2) 0.01555(11) Uani 0.9612(10) 1 d . . .
. .
Eu2B Eu 0.0110(10) 0.3675(10) 0.0173(7) 0.01555(11) Uani 0.0388(10) 1 d . . . .
.
Eu3 Eu 0.35325(3) 0.000000 0.250000 0.01544(12) Uani 1 2 d S T P . .
Eu4A Eu 0.34650(3) 0.07115(2) 0.09448(2) 0.01612(11) Uani 0.9612(10) 1 d . . .
. .
Eu4B Eu 0.3147(7) 0.0347(6) 0.0689(4) 0.01612(11) Uani 0.0388(10) 1 d . . . . .
Zn1 Zn 0.000000 0.250000 0.375000 0.0158(3) Uani 1 4 d S T P . .
Zn2 Zn 0.3601(16) 0.1591(16) 0.1429(11) 0.017(8) Uiso 0.035(4) 1 d . . . . .
As1 As 0.13210(5) 0.38210(5) 0.125000 0.0143(2) Uani 1 2 d S T P . .
As2 As 0.36325(5) 0.25319(5) 0.05998(3) 0.01373(16) Uani 1 1 d . . . . .
As3 As 0.13025(5) 0.02561(5) 0.04720(3) 0.01618(17) Uani 1 1 d . . . . .
As4 As 0.01259(8) 0.26259(8) 0.125000 0.0131(6) Uani 0.5 2 d S T P . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
As As 0.0499 2.0058 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Eu2B Eu1 Eu2B 101.1(4) 15_444 10_454
Eu2B Eu1 Eu4B 104.8(3) 15_444 8
Eu4A Eu1 Eu2B 105.9(3) 8 10_454
Eu4A Eu1 Eu2B 120.0(3) 8 15_444
Eu4A Eu1 Eu4B 15.57(17) 8 8
Eu4B Eu1 Eu2B 114.6(3) 8 10_454
Zn2 Eu1 Eu2B 147.2(5) 8 15_444
Zn2 Eu1 Eu2B 84.8(5) 8 10_454
Zn2 Eu1 Eu4A 30.0(4) 8 8
Zn2 Eu1 Eu4B 45.5(5) 8 8
As1 Eu1 Eu2B 53.6(3) 10_454 10_454
As1 Eu1 Eu2B 102.8(3) 10_454 15_444
As1 Eu1 Eu4A 136.214(19) 10_454 8
As1 Eu1 Eu4B 151.78(17) 10_454 8
As1 Eu1 Zn2 106.4(4) 10_454 8
As1 Eu1 As2 91.936(17) 10_454 3_545
As1 Eu1 As2 92.62(2) 10_454 8
As1 Eu1 As3 100.814(18) 10_454 .
As1 Eu1 As4 62.26(3) 10_454 .
As2 Eu1 Eu2B 150.1(3) 8 15_444
As2 Eu1 Eu2B 108.6(3) 8 10_454
As2 Eu1 Eu2B 139.6(3) 3_545 10_454
As2 Eu1 Eu2B 63.0(3) 3_545 15_444
As2 Eu1 Eu4A 54.416(16) 8 8
As2 Eu1 Eu4A 114.219(18) 3_545 8
As2 Eu1 Eu4B 65.50(17) 8 8
As2 Eu1 Eu4B 105.54(15) 3_545 8
As2 Eu1 Zn2 42.4(4) 8 8
As2 Eu1 Zn2 129.5(4) 3_545 8
As2 Eu1 As2 91.42(2) 8 3_545
As2 Eu1 As3 89.25(2) 8 .
As2 Eu1 As4 93.097(17) 3_545 .
As2 Eu1 As4 154.59(3) 8 .
As3 Eu1 Eu2B 52.1(3) 8 15_444
As3 Eu1 Eu2B 51.4(3) . 10_454
As3 Eu1 Eu2B 112.2(3) . 15_444
As3 Eu1 Eu2B 111.6(3) 8 10_454
As3 Eu1 Eu4A 56.568(16) . 8
As3 Eu1 Eu4A 68.241(18) 8 8
As3 Eu1 Eu4B 53.64(18) 8 8
As3 Eu1 Eu4B 63.26(14) . 8
As3 Eu1 Zn2 95.6(4) 8 8
As3 Eu1 Zn2 47.8(4) . 8
As3 Eu1 As1 150.99(3) 8 10_454
As3 Eu1 As2 88.36(2) 8 3_545
As3 Eu1 As2 116.38(2) 8 8
As3 Eu1 As2 167.19(2) . 3_545
As3 Eu1 As3 79.90(3) 8 .
As3 Eu1 As4 88.75(3) 8 .
As3 Eu1 As4 91.761(18) . .
As4 Eu1 Eu2B 50.9(3) 10_454 10_454
As4 Eu1 Eu2B 54.5(3) . 10_454
As4 Eu1 Eu2B 49.8(3) . 15_444
As4 Eu1 Eu2B 57.1(3) 10_454 15_444
As4 Eu1 Eu4A 148.05(2) 10_454 8
As4 Eu1 Eu4A 142.68(2) . 8
As4 Eu1 Eu4B 136.34(17) . 8
As4 Eu1 Eu4B 144.33(16) 10_454 8
As4 Eu1 Zn2 135.5(4) 10_454 8
As4 Eu1 Zn2 137.2(4) . 8
As4 Eu1 As1 53.07(4) 10_454 10_454
As4 Eu1 As2 145.49(4) 10_454 8
As4 Eu1 As2 93.147(17) 10_454 3_545
As4 Eu1 As3 93.531(18) 10_454 .
As4 Eu1 As3 97.93(4) 10_454 8
As4 Eu1 As4 9.19(6) 10_454 .
Eu3 Eu2A Eu1 150.527(16) 27_565 15_444
Eu4A Eu2A Eu1 70.587(13) 14_454 15_444
Eu4A Eu2A Eu3 138.843(16) 14_454 27_565
Zn1 Eu2A Eu1 92.889(14) 29_554 15_444
Zn1 Eu2A Eu3 98.756(13) 29_554 27_565
Zn1 Eu2A Eu4A 66.517(11) 29_554 14_454
Zn1 Eu2A As2 43.962(13) 29_554 14_454
Zn1 Eu2A As4 102.14(2) 29_554 10_454
Zn2 Eu2A Eu1 140.5(6) 31_565 15_444
Zn2 Eu2A Eu3 63.8(6) 31_565 27_565
Zn2 Eu2A Eu4A 78.3(6) 31_565 14_454
Zn2 Eu2A Zn1 51.6(6) 31_565 29_554
Zn2 Eu2A As1 120.6(6) 31_565 .
Zn2 Eu2A As2 53.2(6) 31_565 5
Zn2 Eu2A As2 91.3(6) 31_565 14_454
Zn2 Eu2A As3 52.9(6) 31_565 26
Zn2 Eu2A As3 125.2(6) 31_565 10_454
Zn2 Eu2A As4 144.4(6) 31_565 .
Zn2 Eu2A As4 143.7(6) 31_565 10_454
As1 Eu2A Eu1 97.05(2) . 15_444
As1 Eu2A Eu3 56.804(15) . 27_565
As1 Eu2A Eu4A 154.579(18) . 14_454
As1 Eu2A Zn1 137.923(18) . 29_554
As1 Eu2A As2 136.94(3) . 14_454
As1 Eu2A As4 50.37(4) . .
As1 Eu2A As4 58.85(3) . 10_454
As2 Eu2A Eu1 49.910(14) 14_454 15_444
As2 Eu2A Eu1 118.64(2) 5 15_444
As2 Eu2A Eu3 140.26(2) 14_454 27_565
As2 Eu2A Eu3 56.359(18) 5 27_565
As2 Eu2A Eu4A 50.164(15) 14_454 14_454
As2 Eu2A Eu4A 112.64(2) 5 14_454
As2 Eu2A Zn1 47.486(15) 5 29_554
As2 Eu2A As1 92.76(2) 5 .
As2 Eu2A As2 84.02(2) 5 14_454
As2 Eu2A As3 91.00(2) 5 26
As2 Eu2A As3 164.99(3) 5 10_454
As2 Eu2A As4 90.92(2) 5 10_454
As2 Eu2A As4 91.30(2) 5 .
As3 Eu2A Eu1 51.235(18) 10_454 15_444
As3 Eu2A Eu1 149.72(2) 26 15_444
As3 Eu2A Eu3 138.37(2) 10_454 27_565
As3 Eu2A Eu3 51.484(18) 26 27_565
As3 Eu2A Eu4A 55.476(18) 10_454 14_454
As3 Eu2A Eu4A 93.36(2) 26 14_454
As3 Eu2A Zn1 118.32(2) 10_454 29_554
As3 Eu2A Zn1 104.256(18) 26 29_554
As3 Eu2A As1 99.318(19) 10_454 .
As3 Eu2A As1 86.84(3) 26 .
As3 Eu2A As2 81.07(2) 10_454 14_454
As3 Eu2A As2 136.01(2) 26 14_454
As3 Eu2A As3 98.49(2) 10_454 26
As3 Eu2A As4 89.598(19) 10_454 .
As3 Eu2A As4 145.70(3) 26 10_454
As3 Eu2A As4 137.21(4) 26 .
As3 Eu2A As4 87.775(19) 10_454 10_454
As4 Eu2A Eu1 54.25(3) . 15_444
As4 Eu2A Eu1 47.71(2) 10_454 15_444
As4 Eu2A Eu3 103.12(2) 10_454 27_565
As4 Eu2A Eu3 96.31(3) . 27_565
As4 Eu2A Eu4A 124.60(3) . 14_454
As4 Eu2A Eu4A 117.26(3) 10_454 14_454
As4 Eu2A Zn1 108.50(3) . 29_554
As4 Eu2A As2 86.70(3) . 14_454
As4 Eu2A As2 78.23(3) 10_454 14_454
As4 Eu2A As4 8.49(6) . 10_454
Eu1 Eu2B Eu1 62.0(2) 15_444 10_454
Eu1 Eu2B Eu4A 110.5(4) 10_454 14_454
Eu1 Eu2B Eu4A 73.3(3) 15_444 14_454
Eu1 Eu2B Zn1 95.5(4) 15_444 29_554
Eu1 Eu2B Zn1 157.0(5) 10_454 29_554
Zn1 Eu2B Eu4A 63.6(3) 29_554 14_454
Zn2 Eu2B Eu1 154.8(8) 31_565 10_454
Zn2 Eu2B Eu1 138.2(7) 31_565 15_444
Zn2 Eu2B Eu4A 72.4(6) 31_565 14_454
Zn2 Eu2B Zn1 47.6(5) 31_565 29_554
Zn2 Eu2B As1 113.3(7) 31_565 .
Zn2 Eu2B As2 48.2(5) 31_565 5
Zn2 Eu2B As2 86.3(6) 31_565 14_454
Zn2 Eu2B As3 47.0(5) 31_565 26
Zn2 Eu2B As4 142.2(8) 31_565 10_454
As1 Eu2B Eu1 55.3(3) . 10_454
As1 Eu2B Eu1 107.4(4) . 15_444
As1 Eu2B Eu4A 158.7(6) . 14_454
As1 Eu2B Zn1 136.0(5) . 29_554
As1 Eu2B As2 91.9(4) . 5
As1 Eu2B As2 147.5(5) . 14_454
As1 Eu2B As3 83.8(4) . 26
As1 Eu2B As4 64.5(3) . 10_454
As2 Eu2B Eu1 123.2(5) 5 15_444
As2 Eu2B Eu1 142.8(5) 5 10_454
As2 Eu2B Eu1 53.1(2) 14_454 15_444
As2 Eu2B Eu1 115.1(4) 14_454 10_454
As2 Eu2B Eu4A 49.8(2) 14_454 14_454
As2 Eu2B Eu4A 105.7(4) 5 14_454
As2 Eu2B Zn1 43.1(2) 14_454 29_554
As2 Eu2B Zn1 44.6(2) 5 29_554
As2 Eu2B As2 82.2(4) 5 14_454
As2 Eu2B As3 82.3(3) 5 26
As3 Eu2B Eu1 107.9(5) 26 10_454
As3 Eu2B Eu1 150.7(5) 26 15_444
As3 Eu2B Eu1 56.1(3) 10_454 10_454
As3 Eu2B Eu1 56.2(3) 10_454 15_444
As3 Eu2B Eu4A 86.7(3) 26 14_454
As3 Eu2B Eu4A 55.2(3) 10_454 14_454
As3 Eu2B Zn1 94.3(3) 26 29_554
As3 Eu2B Zn1 117.2(5) 10_454 29_554
As3 Eu2B Zn2 117.4(7) 10_454 31_565
As3 Eu2B As1 106.7(5) 10_454 .
As3 Eu2B As2 160.9(6) 10_454 5
As3 Eu2B As2 126.5(4) 26 14_454
As3 Eu2B As2 84.4(4) 10_454 14_454
As3 Eu2B As3 94.9(4) 10_454 26
As3 Eu2B As4 97.9(4) 10_454 10_454
As4 Eu2B Eu1 53.0(2) 10_454 15_444
As4 Eu2B Eu1 60.6(3) . 15_444
As4 Eu2B Eu1 54.1(2) . 10_454
As4 Eu2B Eu1 57.9(2) 10_454 10_454
As4 Eu2B Eu4A 133.3(5) . 14_454
As4 Eu2B Eu4A 124.5(5) 10_454 14_454
As4 Eu2B Zn1 112.1(5) . 29_554
As4 Eu2B Zn1 105.5(5) 10_454 29_554
As4 Eu2B Zn2 142.1(8) . 31_565
As4 Eu2B As1 54.9(3) . .
As4 Eu2B As2 94.2(5) . 5
As4 Eu2B As2 93.5(4) . 14_454
As4 Eu2B As2 94.3(4) 10_454 5
As4 Eu2B As2 84.0(4) 10_454 14_454
As4 Eu2B As3 100.2(4) . 10_454
As4 Eu2B As3 138.5(6) . 26
As4 Eu2B As3 148.0(6) 10_454 26
As4 Eu2B As4 9.57(8) . 10_454
Eu4A Eu3 Eu4A 176.48(2) 6 .
Eu4B Eu3 Eu4A 110.24(18) 3_545 .
Eu4B Eu3 Eu4A 66.82(18) 8 .
Eu4B Eu3 Eu4A 110.24(18) 8 6
Eu4B Eu3 Eu4A 66.82(18) 3_545 6
Eu4B Eu3 Eu4B 78.3(4) 8 3_545
Eu4B Eu3 Zn2 95.6(5) 8 6
Eu4B Eu3 Zn2 87.2(5) 8 .
Eu4B Eu3 Zn2 87.2(5) 3_545 6
Eu4B Eu3 Zn2 95.7(5) 3_545 .
Eu4B Eu3 As1 133.26(19) 3_545 20_656
Eu4B Eu3 As1 133.26(19) 8 25
Eu4B Eu3 As1 54.95(19) 8 20_656
Eu4B Eu3 As1 54.95(19) 3_545 25
Eu4B Eu3 As2 123.9(2) 8 23_666
Eu4B Eu3 As2 123.9(2) 3_545 20_656
Eu4B Eu3 As2 123.89(18) 3_545 23_666
Eu4B Eu3 As2 123.89(18) 8 20_656
Eu4B Eu3 As3 53.54(18) 8 3_545
Eu4B Eu3 As3 53.54(18) 3_545 8
Eu4B Eu3 As3 61.6(2) 3_545 3_545
Eu4B Eu3 As3 61.6(2) 8 8
Zn2 Eu3 Eu4A 29.4(4) 6 6
Zn2 Eu3 Eu4A 150.8(4) 6 .
Zn2 Eu3 Eu4A 29.4(4) . .
Zn2 Eu3 Eu4A 150.8(4) . 6
Zn2 Eu3 Zn2 176.3(8) . 6
As1 Eu3 Eu4A 54.509(14) 20_656 .
As1 Eu3 Eu4A 125.801(13) 25 .
As1 Eu3 Eu4A 54.510(14) 25 6
As1 Eu3 Eu4A 125.800(13) 20_656 6
As1 Eu3 Zn2 83.3(4) 20_656 .
As1 Eu3 Zn2 96.5(4) 20_656 6
As1 Eu3 Zn2 83.3(4) 25 6
As1 Eu3 Zn2 96.5(4) 25 .
As1 Eu3 As1 171.79(3) 25 20_656
As2 Eu3 Eu4A 125.801(19) 23_666 .
As2 Eu3 Eu4A 125.801(19) 20_656 6
As2 Eu3 Eu4A 57.267(15) 20_656 .
As2 Eu3 Eu4A 57.266(15) 23_666 6
As2 Eu3 Zn2 44.6(4) 20_656 .
As2 Eu3 Zn2 131.8(4) 20_656 6
As2 Eu3 Zn2 131.8(4) 23_666 .
As2 Eu3 Zn2 44.6(4) 23_666 6
As2 Eu3 As1 87.00(2) 20_656 25
As2 Eu3 As1 87.00(2) 23_666 20_656
As2 Eu3 As1 87.094(15) 23_666 25
As2 Eu3 As1 87.094(15) 20_656 20_656
As2 Eu3 As2 87.99(3) 20_656 23_666
As3 Eu3 Eu4A 120.34(2) 8 6
As3 Eu3 Eu4A 56.799(16) 3_545 6
As3 Eu3 Eu4A 120.34(2) 3_545 .
As3 Eu3 Eu4A 56.799(16) 8 .
As3 Eu3 Zn2 47.2(4) 3_545 6
As3 Eu3 Zn2 47.2(4) 8 .
As3 Eu3 Zn2 136.4(4) 8 6
As3 Eu3 Zn2 136.4(4) 3_545 .
As3 Eu3 As1 98.31(2) 3_545 25
As3 Eu3 As1 87.379(16) 8 25
As3 Eu3 As1 98.31(2) 8 20_656
As3 Eu3 As1 87.379(16) 3_545 20_656
As3 Eu3 As2 89.86(2) 8 20_656
As3 Eu3 As2 174.17(2) 8 23_666
As3 Eu3 As2 174.17(2) 3_545 20_656
As3 Eu3 As2 89.86(2) 3_545 23_666
As3 Eu3 As3 92.78(3) 3_545 8
Eu1 Eu4A Eu2A 113.840(14) 8 14_554
Eu1 Eu4A Eu2B 109.0(2) 8 14_554
Eu1 Eu4A Eu3 108.664(13) 8 .
Eu1 Eu4A Eu4B 88.45(16) 8 8
Eu2A Eu4A Eu2B 6.1(2) 14_554 14_554
Eu3 Eu4A Eu2A 126.468(17) . 14_554
Eu3 Eu4A Eu2B 132.5(2) . 14_554
Eu3 Eu4A Eu4B 47.62(16) . 8
Eu4B Eu4A Eu1 84.7(6) . 8
Eu4B Eu4A Eu2A 155.50(16) 8 14_554
Eu4B Eu4A Eu2A 103.8(6) . 14_554
Eu4B Eu4A Eu2B 100.1(6) . 14_554
Eu4B Eu4A Eu2B 157.6(3) 8 14_554
Eu4B Eu4A Eu3 111.2(5) . .
Eu4B Eu4A Eu4B 66.7(6) . 8
Eu4B Eu4A Zn2 153.8(10) . .
Eu4B Eu4A As1 65.3(6) . 20_656
Eu4B Eu4A As2 120.1(6) . .
Eu4B Eu4A As2 153.4(6) . 20_656
Eu4B Eu4A As3 50.5(6) . 5
Eu4B Eu4A As3 104.1(6) . 8
Zn2 Eu4A Eu1 70.0(8) . 8
Zn2 Eu4A Eu2A 92.8(8) . 14_554
Zn2 Eu4A Eu2B 94.5(8) . 14_554
Zn2 Eu4A Eu3 72.6(8) . .
Zn2 Eu4A Eu4B 104.9(8) . 8
Zn2 Eu4A As1 129.9(8) . 20_656
Zn2 Eu4A As2 50.2(8) . .
Zn2 Eu4A As2 50.9(8) . 20_656
Zn2 Eu4A As3 137.6(8) . 5
Zn2 Eu4A As3 56.2(8) . 8
As1 Eu4A Eu1 135.252(19) 20_656 8
As1 Eu4A Eu2A 105.380(18) 20_656 14_554
As1 Eu4A Eu2B 108.4(3) 20_656 14_554
As1 Eu4A Eu3 58.910(7) 20_656 .
As1 Eu4A Eu4B 50.19(16) 20_656 8
As1 Eu4A As2 89.360(18) 20_656 20_656
As1 Eu4A As3 98.98(2) 20_656 8
As1 Eu4A As3 87.857(18) 20_656 5
As2 Eu4A Eu1 120.867(18) 20_656 8
As2 Eu4A Eu1 56.254(17) . 8
As2 Eu4A Eu2A 74.133(17) 20_656 14_554
As2 Eu4A Eu2A 63.917(18) . 14_554
As2 Eu4A Eu2B 79.6(2) 20_656 14_554
As2 Eu4A Eu2B 61.4(3) . 14_554
As2 Eu4A Eu3 122.769(18) . .
As2 Eu4A Eu3 56.444(16) 20_656 .
As2 Eu4A Eu4B 103.94(16) 20_656 8
As2 Eu4A Eu4B 140.58(17) . 8
As2 Eu4A As1 168.41(2) . 20_656
As2 Eu4A As2 83.46(3) . 20_656
As2 Eu4A As3 88.78(2) . 5
As2 Eu4A As3 89.75(2) . 8
As3 Eu4A Eu1 98.079(19) 5 8
As3 Eu4A Eu1 55.470(16) 8 8
As3 Eu4A Eu2A 53.831(17) 5 14_554
As3 Eu4A Eu2A 148.71(2) 8 14_554
As3 Eu4A Eu2B 49.7(2) 5 14_554
As3 Eu4A Eu2B 149.2(3) 8 14_554
As3 Eu4A Eu3 146.44(2) 5 .
As3 Eu4A Eu3 53.196(16) 8 .
As3 Eu4A Eu4B 52.87(17) 8 8
As3 Eu4A Eu4B 115.53(17) 5 8
As3 Eu4A As2 124.76(2) 5 20_656
As3 Eu4A As2 86.97(2) 8 20_656
As3 Eu4A As3 147.78(3) 8 5
Eu1 Eu4B Eu4A 92.9(2) 8 8
Eu1 Eu4B Eu4B 71.8(2) 8 5
Eu1 Eu4B As2 51.50(14) 8 .
Eu3 Eu4B Eu1 114.1(3) 4_554 8
Eu3 Eu4B Eu4A 65.6(2) 4_554 8
Eu3 Eu4B Eu4B 79.9(4) 4_554 8
Eu3 Eu4B Eu4B 50.85(19) 4_554 5
Eu3 Eu4B As1 70.2(2) 4_554 20_656
Eu3 Eu4B As2 143.8(3) 4_554 .
Eu3 Eu4B As3 125.2(3) 4_554 8
Eu3 Eu4B As3 61.5(2) 4_554 .
Eu4A Eu4B Eu1 79.7(6) . 8
Eu4A Eu4B Eu3 166.0(8) . 4_554
Eu4A Eu4B Eu4A 113.2(6) . 8
Eu4A Eu4B Eu4B 94.2(3) 8 5
Eu4A Eu4B Eu4B 98.0(7) . 8
Eu4A Eu4B Eu4B 141.3(6) . 5
Eu4A Eu4B Zn2 17.1(7) . .
Eu4A Eu4B As1 97.2(6) . 20_656
Eu4A Eu4B As2 46.7(5) . .
Eu4A Eu4B As2 137.6(3) 8 .
Eu4A Eu4B As3 130.5(7) . .
Eu4A Eu4B As3 60.6(5) . 8
Eu4A Eu4B As3 113.4(7) . 5
Eu4B Eu4B Eu1 91.99(15) 8 8
Eu4B Eu4B Eu4A 15.3(2) 8 8
Eu4B Eu4B Eu4B 108.4(5) 8 5
Eu4B Eu4B As2 128.0(3) 8 .
Eu4B Eu4B As3 52.4(2) 8 8
Zn2 Eu4B Eu1 63.2(6) . 8
Zn2 Eu4B Eu3 173.0(7) . 4_554
Zn2 Eu4B Eu4A 107.7(6) . 8
Zn2 Eu4B Eu4B 130.3(6) . 5
Zn2 Eu4B Eu4B 93.6(6) . 8
Zn2 Eu4B As1 108.2(6) . 20_656
Zn2 Eu4B As2 40.3(6) . .
Zn2 Eu4B As3 113.6(6) . .
Zn2 Eu4B As3 47.8(6) . 8
As1 Eu4B Eu1 146.2(3) 20_656 8
As1 Eu4B Eu4A 57.06(17) 20_656 8
As1 Eu4B Eu4B 54.80(19) 20_656 8
As1 Eu4B Eu4B 121.0(2) 20_656 5
As1 Eu4B As2 142.5(4) 20_656 .
As1 Eu4B As3 96.6(2) 20_656 8
As1 Eu4B As3 108.5(3) 20_656 .
As2 Eu4B Eu4B 94.67(16) . 5
As3 Eu4B Eu1 55.39(17) . 8
As3 Eu4B Eu1 52.36(14) 8 8
As3 Eu4B Eu1 107.8(3) 5 8
As3 Eu4B Eu3 66.0(2) 5 4_554
As3 Eu4B Eu4A 131.5(4) 5 8
As3 Eu4B Eu4A 56.37(18) . 8
As3 Eu4B Eu4A 63.16(16) 8 8
As3 Eu4B Eu4B 145.1(5) 5 8
As3 Eu4B Eu4B 46.0(2) . 5
As3 Eu4B Eu4B 54.8(2) 5 5
As3 Eu4B Eu4B 115.6(4) 8 5
As3 Eu4B Eu4B 67.1(3) . 8
As3 Eu4B Zn2 120.8(7) 5 .
As3 Eu4B As1 104.3(3) 5 20_656
As3 Eu4B As2 86.1(2) 5 .
As3 Eu4B As2 104.7(3) . .
As3 Eu4B As2 75.65(19) 8 .
As3 Eu4B As3 158.9(4) 5 8
As3 Eu4B As3 100.5(3) 5 .
As3 Eu4B As3 74.7(2) . 8
Eu2A Zn1 Eu2A 129.617(11) 22_556 15_444
Eu2A Zn1 Eu2A 129.617(11) 8 29
Eu2A Zn1 Eu2A 74.019(17) 22_556 29
Eu2A Zn1 Eu2A 74.019(17) 8 15_444
Eu2A Zn1 Eu2A 129.617(11) 8 22_556
Eu2A Zn1 Eu2A 129.617(11) 29 15_444
Zn2 Zn1 Eu2A 48.5(5) 18_556 8
Zn2 Zn1 Eu2A 115.8(5) 18_556 15_444
Zn2 Zn1 Eu2A 83.2(5) 25 22_556
Zn2 Zn1 Eu2A 83.2(5) 12_454 8
Zn2 Zn1 Eu2A 110.2(5) 12_454 15_444
Zn2 Zn1 Eu2A 83.2(5) 18_556 29
Zn2 Zn1 Eu2A 110.2(5) 18_556 22_556
Zn2 Zn1 Eu2A 110.2(5) 25 29
Zn2 Zn1 Eu2A 48.5(5) 25 15_444
Zn2 Zn1 Eu2A 115.8(5) 12_454 29
Zn2 Zn1 Eu2A 83.2(5) 3_545 15_444
Zn2 Zn1 Eu2A 48.5(5) 3_545 29
Zn2 Zn1 Eu2A 48.5(5) 12_454 22_556
Zn2 Zn1 Eu2A 110.2(5) 3_545 8
Zn2 Zn1 Eu2A 115.8(5) 3_545 22_556
Zn2 Zn1 Eu2A 115.8(5) 25 8
Zn2 Zn1 Zn2 91.15(14) 18_556 3_545
Zn2 Zn1 Zn2 163.7(10) 18_556 25
Zn2 Zn1 Zn2 91.15(14) 25 12_454
Zn2 Zn1 Zn2 91.15(14) 25 3_545
Zn2 Zn1 Zn2 163.7(10) 12_454 3_545
Zn2 Zn1 Zn2 91.15(14) 18_556 12_454
As2 Zn1 Eu2A 58.120(18) 25 29
As2 Zn1 Eu2A 58.120(18) 3_545 8
As2 Zn1 Eu2A 85.927(18) 25 15_444
As2 Zn1 Eu2A 157.784(19) 25 8
As2 Zn1 Eu2A 85.927(18) 3_545 29
As2 Zn1 Eu2A 58.120(18) 12_454 15_444
As2 Zn1 Eu2A 157.784(19) 12_454 29
As2 Zn1 Eu2A 70.938(19) 12_454 8
As2 Zn1 Eu2A 70.938(19) 3_545 15_444
As2 Zn1 Eu2A 157.784(19) 3_545 22_556
As2 Zn1 Eu2A 157.784(19) 18_556 15_444
As2 Zn1 Eu2A 70.938(19) 25 22_556
As2 Zn1 Eu2A 85.927(18) 18_556 8
As2 Zn1 Eu2A 58.120(18) 18_556 22_556
As2 Zn1 Eu2A 85.927(18) 12_454 22_556
As2 Zn1 Eu2A 70.938(19) 18_556 29
As2 Zn1 Zn2 140.0(5) 18_556 25
As2 Zn1 Zn2 113.3(5) 25 12_454
As2 Zn1 Zn2 113.3(5) 3_545 25
As2 Zn1 Zn2 56.8(5) 12_454 25
As2 Zn1 Zn2 52.1(5) 12_454 12_454
As2 Zn1 Zn2 140.0(5) 25 18_556
As2 Zn1 Zn2 52.1(5) 25 25
As2 Zn1 Zn2 52.1(5) 18_556 18_556
As2 Zn1 Zn2 56.8(5) 18_556 12_454
As2 Zn1 Zn2 140.0(5) 12_454 3_545
As2 Zn1 Zn2 56.8(5) 3_545 18_556
As2 Zn1 Zn2 113.3(5) 18_556 3_545
As2 Zn1 Zn2 52.1(5) 3_545 3_545
As2 Zn1 Zn2 56.8(5) 25 3_545
As2 Zn1 Zn2 140.0(5) 3_545 12_454
As2 Zn1 Zn2 113.3(5) 12_454 18_556
As2 Zn1 As2 106.644(15) 18_556 12_454
As2 Zn1 As2 106.644(15) 25 12_454
As2 Zn1 As2 115.29(3) 3_545 12_454
As2 Zn1 As2 106.644(15) 3_545 25
As2 Zn1 As2 106.644(15) 3_545 18_556
As2 Zn1 As2 115.29(3) 25 18_556
Eu1 Zn2 Eu3 114.7(7) 8 .
Eu2A Zn2 Eu1 111.0(8) 23_666 8
Eu2A Zn2 Eu2B 1.8(3) 23_666 23_666
Eu2A Zn2 Eu3 73.7(6) 23_666 .
Eu2A Zn2 Eu4B 152.1(11) 23_666 .
Eu2A Zn2 Zn1 79.8(7) 23_666 25
Eu2A Zn2 As3 74.7(6) 23_666 8
Eu2B Zn2 Eu1 112.5(8) 23_666 8
Eu2B Zn2 Eu3 74.2(6) 23_666 .
Eu4A Zn2 Eu1 80.1(8) . 8
Eu4A Zn2 Eu2A 151.7(13) . 23_666
Eu4A Zn2 Eu2B 152.2(13) . 23_666
Eu4A Zn2 Eu3 78.0(9) . .
Eu4A Zn2 Eu4B 9.1(4) . .
Eu4A Zn2 Zn1 116.8(11) . 25
Eu4A Zn2 As2 96.2(11) . 20_656
Eu4A Zn2 As2 94.2(10) . .
Eu4A Zn2 As3 89.5(10) . 8
Eu4B Zn2 Eu1 71.3(6) . 8
Eu4B Zn2 Eu2B 153.2(11) . 23_666
Eu4B Zn2 Eu3 80.2(7) . .
Eu4B Zn2 Zn1 123.3(9) . 25
Zn1 Zn2 Eu1 123.3(9) 25 8
Zn1 Zn2 Eu2B 78.1(7) 25 23_666
Zn1 Zn2 Eu3 121.5(8) 25 .
As2 Zn2 Eu1 63.6(6) . 8
As2 Zn2 Eu1 176.1(10) 20_656 8
As2 Zn2 Eu2A 71.7(6) 20_656 23_666
As2 Zn2 Eu2A 114.1(10) . 23_666
As2 Zn2 Eu2B 70.3(7) 20_656 23_666
As2 Zn2 Eu2B 113.5(10) . 23_666
As2 Zn2 Eu3 172.3(10) . .
As2 Zn2 Eu3 62.9(5) 20_656 .
As2 Zn2 Eu4B 104.9(9) 20_656 .
As2 Zn2 Eu4B 92.2(8) . .
As2 Zn2 Zn1 59.5(5) 20_656 25
As2 Zn2 Zn1 61.6(6) . 25
As2 Zn2 As2 118.3(10) . 20_656
As2 Zn2 As3 123.4(10) . 8
As2 Zn2 As3 117.4(9) 20_656 8
As3 Zn2 Eu1 61.6(5) 8 8
As3 Zn2 Eu2B 76.5(7) 8 23_666
As3 Zn2 Eu3 57.6(5) 8 .
As3 Zn2 Eu4B 83.2(8) 8 .
As3 Zn2 Zn1 153.5(10) 8 25
Eu1 As1 Eu1 122.80(4) 8 10_454
Eu1 As1 Eu2A 80.337(19) 8 .
Eu1 As1 Eu2A 76.640(18) 8 15_444
Eu1 As1 Eu2A 80.337(19) 10_454 15_444
Eu1 As1 Eu2A 76.640(18) 10_454 .
Eu1 As1 Eu3 70.387(11) 10_454 25
Eu1 As1 Eu3 140.732(8) 8 25
Eu1 As1 Eu4A 86.367(12) 8 27_565
Eu1 As1 Eu4A 142.712(19) 10_454 27_565
Eu1 As1 Eu4A 142.712(19) 8 30
Eu1 As1 Eu4A 86.367(12) 10_454 30
Eu2A As1 Eu2A 130.75(4) 15_444 .
Eu2A As1 Eu3 137.381(12) . 25
Eu2A As1 Eu3 69.258(9) 15_444 25
Eu2B As1 Eu1 71.2(3) . 10_454
Eu2B As1 Eu1 80.5(3) . 8
Eu2B As1 Eu1 80.5(3) 15_444 10_454
Eu2B As1 Eu1 71.2(3) 15_444 8
Eu2B As1 Eu2A 6.9(3) . .
Eu2B As1 Eu2A 6.9(3) 15_444 15_444
Eu2B As1 Eu2A 124.6(3) 15_444 .
Eu2B As1 Eu2A 124.6(3) . 15_444
Eu2B As1 Eu2B 118.8(6) . 15_444
Eu2B As1 Eu3 135.3(3) . 25
Eu2B As1 Eu3 75.8(3) 15_444 25
Eu2B As1 Eu4A 89.2(3) . 30
Eu2B As1 Eu4A 142.4(3) . 27_565
Eu2B As1 Eu4A 142.4(3) 15_444 30
Eu2B As1 Eu4A 89.2(3) 15_444 27_565
Eu4A As1 Eu2A 85.428(13) 30 .
Eu4A As1 Eu2A 85.428(13) 27_565 15_444
Eu4A As1 Eu2A 135.81(2) 27_565 .
Eu4A As1 Eu2A 135.81(2) 30 15_444
Eu4A As1 Eu3 72.35(2) 27_565 25
Eu4A As1 Eu3 66.579(17) 30 25
Eu4A As1 Eu4A 80.21(3) 27_565 30
Eu4B As1 Eu1 125.3(2) 27_565 10_454
Eu4B As1 Eu1 125.3(2) 30 8
Eu4B As1 Eu1 101.8(2) 27_565 8
Eu4B As1 Eu1 101.8(2) 30 10_454
Eu4B As1 Eu2A 146.62(18) 27_565 .
Eu4B As1 Eu2A 146.62(18) 30 15_444
Eu4B As1 Eu2A 81.14(18) 30 .
Eu4B As1 Eu2A 81.14(18) 27_565 15_444
Eu4B As1 Eu2B 153.4(3) 30 15_444
Eu4B As1 Eu2B 153.4(3) 27_565 .
Eu4B As1 Eu2B 86.5(4) 27_565 15_444
Eu4B As1 Eu2B 86.5(4) 30 .
Eu4B As1 Eu3 80.02(19) 30 25
Eu4B As1 Eu3 54.9(2) 27_565 25
Eu4B As1 Eu4A 72.8(2) 27_565 30
Eu4B As1 Eu4A 17.6(2) 27_565 27_565
Eu4B As1 Eu4A 17.6(2) 30 30
Eu4B As1 Eu4A 72.8(2) 30 27_565
Eu4B As1 Eu4B 70.4(4) 27_565 30
As4 As1 Eu1 61.400(19) . 10_454
As4 As1 Eu1 61.400(19) . 8
As4 As1 Eu2A 65.38(2) . .
As4 As1 Eu2A 65.38(2) . 15_444
As4 As1 Eu2B 59.4(3) . .
As4 As1 Eu2B 59.4(3) . 15_444
As4 As1 Eu3 117.261(18) . 25
As4 As1 Eu4A 139.893(15) . 30
As4 As1 Eu4A 139.893(15) . 27_565
As4 As1 Eu4B 144.80(19) . 30
As4 As1 Eu4B 144.80(19) . 27_565
Eu1 As2 Eu1 81.73(2) 8 4_554
Eu1 As2 Eu2A 126.70(3) 8 14_554
Eu1 As2 Eu2A 70.001(18) 4_554 14_554
Eu1 As2 Eu2B 144.6(3) 8 5
Eu1 As2 Eu2B 125.3(3) 8 14_554
Eu1 As2 Eu2B 63.9(2) 4_554 14_554
Eu1 As2 Eu2B 77.5(3) 4_554 5
Eu1 As2 Eu3 71.428(18) 8 27_565
Eu1 As2 Eu3 71.050(17) 4_554 27_565
Eu1 As2 Eu4A 137.34(3) 4_554 27_565
Eu1 As2 Eu4A 84.40(2) 8 27_565
Eu2A As2 Eu1 82.62(2) 5 4_554
Eu2A As2 Eu1 143.70(3) 5 8
Eu2A As2 Eu2A 76.99(2) 5 14_554
Eu2A As2 Eu2B 74.8(3) 5 14_554
Eu2A As2 Eu2B 6.5(3) 5 5
Eu2A As2 Eu3 72.55(2) 5 27_565
Eu2A As2 Eu4A 142.63(3) 5 .
Eu2A As2 Eu4A 85.31(2) 5 27_565
Eu2B As2 Eu2A 71.7(3) 5 14_554
Eu2B As2 Eu2A 6.4(2) 14_554 14_554
Eu2B As2 Eu2B 69.1(5) 5 14_554
Eu2B As2 Eu3 74.8(3) 5 27_565
Eu2B As2 Eu4A 91.8(3) 5 27_565
Eu3 As2 Eu2A 132.80(2) 27_565 14_554
Eu3 As2 Eu2B 126.7(2) 27_565 14_554
Eu3 As2 Eu4A 66.289(17) 27_565 27_565
Eu4A As2 Eu1 69.329(19) . 8
Eu4A As2 Eu1 88.71(2) . 4_554
Eu4A As2 Eu2A 65.918(18) . 14_554
Eu4A As2 Eu2A 145.27(3) 27_565 14_554
Eu4A As2 Eu2B 149.1(3) 27_565 14_554
Eu4A As2 Eu2B 68.8(3) . 14_554
Eu4A As2 Eu2B 137.6(3) . 5
Eu4A As2 Eu3 137.90(3) . 27_565
Eu4A As2 Eu4A 123.22(2) . 27_565
Zn1 As2 Eu1 137.68(3) 25 8
Zn1 As2 Eu1 132.91(3) 25 4_554
Zn1 As2 Eu2A 65.100(18) 25 14_554
Zn1 As2 Eu2A 74.39(2) 25 5
Zn1 As2 Eu2B 70.6(2) 25 14_554
Zn1 As2 Eu2B 75.8(3) 25 5
Zn1 As2 Eu3 135.05(3) 25 27_565
Zn1 As2 Eu4A 81.54(2) 25 27_565
Zn1 As2 Eu4A 85.73(2) 25 .
Zn2 As2 Eu1 130.6(5) 27_565 4_554
Zn2 As2 Eu1 124.0(6) . 4_554
Zn2 As2 Eu1 116.3(6) 27_565 8
Zn2 As2 Eu1 74.0(6) . 8
Zn2 As2 Eu2A 140.7(6) . 5
Zn2 As2 Eu2A 55.1(5) 27_565 5
Zn2 As2 Eu2A 85.5(6) . 14_554
Zn2 As2 Eu2A 116.5(6) 27_565 14_554
Zn2 As2 Eu2B 61.5(6) 27_565 5
Zn2 As2 Eu2B 90.9(7) . 14_554
Zn2 As2 Eu2B 118.3(6) 27_565 14_554
Zn2 As2 Eu2B 141.4(7) . 5
Zn2 As2 Eu3 139.3(6) . 27_565
Zn2 As2 Eu3 72.5(6) 27_565 27_565
Zn2 As2 Eu4A 35.6(6) . .
Zn2 As2 Eu4A 89.9(6) . 27_565
Zn2 As2 Eu4A 140.2(5) 27_565 .
Zn2 As2 Eu4A 32.9(6) 27_565 27_565
Zn2 As2 Zn1 63.7(6) 27_565 25
Zn2 As2 Zn1 66.3(6) . 25
Zn2 As2 Zn2 105.4(7) . 27_565
Eu1 As3 Eu1 72.43(2) 8 .
Eu1 As3 Eu2A 103.00(3) . 26_545
Eu1 As3 Eu2A 77.29(2) 8 10_454
Eu1 As3 Eu2A 158.80(3) 8 26_545
Eu1 As3 Eu2B 156.3(3) 8 26_545
Eu1 As3 Eu2B 105.8(3) . 26_545
Eu1 As3 Eu4A 111.60(3) 8 8
Eu1 As3 Eu4A 145.96(3) . 5
Eu1 As3 Eu4A 87.68(2) 8 5
Eu1 As3 Eu4A 67.962(18) . 8
Eu2A As3 Eu1 78.00(2) 10_454 .
Eu2A As3 Eu2A 81.52(2) 10_454 26_545
Eu2A As3 Eu2B 79.2(3) 10_454 26_545
Eu2A As3 Eu2B 4.2(3) 26_545 26_545
Eu2A As3 Eu4A 139.00(3) 10_454 8
Eu2A As3 Eu4A 70.69(2) 10_454 5
Eu2B As3 Eu1 71.7(3) 10_454 8
Eu2B As3 Eu1 72.5(3) 10_454 .
Eu2B As3 Eu2A 87.1(3) 10_454 26_545
Eu2B As3 Eu2A 7.0(3) 10_454 10_454
Eu2B As3 Eu2B 85.1(4) 10_454 26_545
Eu2B As3 Eu3 146.2(3) 10_454 4_554
Eu2B As3 Eu4A 136.4(3) 10_454 8
Eu2B As3 Eu4A 75.1(3) 10_454 5
Eu2B As3 Eu4B 140.6(4) 10_454 .
Eu3 As3 Eu1 124.31(3) 4_554 8
Eu3 As3 Eu1 137.96(3) 4_554 .
Eu3 As3 Eu2A 139.46(3) 4_554 10_454
Eu3 As3 Eu2A 73.28(2) 4_554 26_545
Eu3 As3 Eu2B 73.4(3) 4_554 26_545
Eu3 As3 Eu4A 70.005(18) 4_554 8
Eu3 As3 Eu4A 76.075(19) 4_554 5
Eu3 As3 Eu4B 56.85(19) 4_554 .
Eu4A As3 Eu2A 85.55(2) 5 26_545
Eu4A As3 Eu2A 84.49(2) 8 26_545
Eu4A As3 Eu2B 88.5(3) 8 26_545
Eu4A As3 Eu2B 81.5(3) 5 26_545
Eu4A As3 Eu4A 146.08(3) 8 5
Eu4B As3 Eu1 161.2(2) 5 .
Eu4B As3 Eu1 70.97(19) . 8
Eu4B As3 Eu1 93.9(2) 5 8
Eu4B As3 Eu1 107.23(17) . .
Eu4B As3 Eu2A 129.18(19) . 26_545
Eu4B As3 Eu2A 144.00(18) . 10_454
Eu4B As3 Eu2A 85.0(2) 5 26_545
Eu4B As3 Eu2A 86.6(2) 5 10_454
Eu4B As3 Eu2B 130.0(3) . 26_545
Eu4B As3 Eu2B 81.4(3) 5 26_545
Eu4B As3 Eu2B 91.2(4) 5 10_454
Eu4B As3 Eu3 60.5(2) 5 4_554
Eu4B As3 Eu4A 130.3(2) 5 8
Eu4B As3 Eu4A 70.77(17) . 8
Eu4B As3 Eu4A 16.1(2) 5 5
Eu4B As3 Eu4A 91.18(17) . 5
Eu4B As3 Eu4B 79.2(3) 5 .
Zn2 As3 Eu1 138.0(5) 8 8
Zn2 As3 Eu1 70.7(5) 8 .
Zn2 As3 Eu2A 113.2(6) 8 10_454
Zn2 As3 Eu2A 52.4(5) 8 26_545
Zn2 As3 Eu2B 56.6(6) 8 26_545
Zn2 As3 Eu2B 114.3(7) 8 10_454
Zn2 As3 Eu3 75.2(6) 8 4_554
Zn2 As3 Eu4A 134.3(5) 8 5
Zn2 As3 Eu4A 34.3(6) 8 8
Zn2 As3 Eu4B 101.8(6) 8 .
Zn2 As3 Eu4B 126.2(6) 8 5
Eu1 As4 Eu1 71.236(14) 8 .
Eu1 As4 Eu1 112.68(6) . 15_444
Eu1 As4 Eu1 71.236(14) 10_454 15_444
Eu1 As4 Eu1 141.337(19) 8 15_444
Eu1 As4 Eu1 141.337(19) 10_454 .
Eu1 As4 Eu1 131.06(7) 10_454 8
Eu1 As4 Eu2A 81.52(3) 8 .
Eu1 As4 Eu2A 77.74(3) 10_454 .
Eu1 As4 Eu2A 81.52(3) 10_454 15_444
Eu1 As4 Eu2A 77.74(3) 8 15_444
Eu1 As4 Eu2B 70.0(3) 10_454 8
Eu1 As4 Eu2B 143.5(3) 10_454 10_454
Eu1 As4 Eu2B 70.0(3) 8 10_454
Eu1 As4 Eu2B 143.5(3) 8 8
Eu2A As4 Eu1 72.855(12) . 15_444
Eu2A As4 Eu1 140.916(16) . .
Eu2A As4 Eu1 140.917(16) 15_444 15_444
Eu2A As4 Eu1 72.857(12) 15_444 .
Eu2A As4 Eu2A 128.51(6) 15_444 .
Eu2B As4 Eu1 85.2(3) . 8
Eu2B As4 Eu1 75.1(3) . 10_454
Eu2B As4 Eu1 67.6(3) 10_454 .
Eu2B As4 Eu1 67.6(3) 8 15_444
Eu2B As4 Eu1 69.6(3) . 15_444
Eu2B As4 Eu1 75.1(3) 15_444 8
Eu2B As4 Eu1 76.3(3) 8 .
Eu2B As4 Eu1 76.3(3) 10_454 15_444
Eu2B As4 Eu1 85.2(3) 15_444 10_454
Eu2B As4 Eu1 143.4(3) . .
Eu2B As4 Eu1 143.4(3) 15_444 15_444
Eu2B As4 Eu1 69.6(3) 15_444 .
Eu2B As4 Eu2A 135.0(3) 10_454 15_444
Eu2B As4 Eu2A 135.0(3) 8 .
Eu2B As4 Eu2A 129.9(3) . 15_444
Eu2B As4 Eu2A 77.1(3) 8 15_444
Eu2B As4 Eu2A 3.7(3) 15_444 15_444
Eu2B As4 Eu2A 129.9(3) 15_444 .
Eu2B As4 Eu2A 3.7(3) . .
Eu2B As4 Eu2A 77.1(3) 10_454 .
Eu2B As4 Eu2B 78.4(6) 15_444 8
Eu2B As4 Eu2B 131.2(6) 15_444 10_454
Eu2B As4 Eu2B 131.5(7) 15_444 .
Eu2B As4 Eu2B 78.4(6) . 10_454
Eu2B As4 Eu2B 112.3(6) 10_454 8
Eu2B As4 Eu2B 131.2(6) . 8
As1 As4 Eu1 123.66(3) . .
As1 As4 Eu1 123.66(3) . 15_444
As1 As4 Eu1 65.53(3) . 8
As1 As4 Eu1 65.53(3) . 10_454
As1 As4 Eu2A 64.26(3) . 15_444
As1 As4 Eu2A 64.26(3) . .
As1 As4 Eu2B 123.8(3) . 8
As1 As4 Eu2B 123.8(3) . 10_454
As1 As4 Eu2B 65.7(3) . .
As1 As4 Eu2B 65.7(3) . 15_444
As4 As4 Eu1 114.47(3) 10_454 8
As4 As4 Eu1 56.34(3) 10_454 .
As4 As4 Eu1 114.47(3) 10_454 10_454
As4 As4 Eu1 56.34(3) 10_454 15_444
As4 As4 Eu2A 115.74(3) 10_454 .
As4 As4 Eu2A 115.74(3) 10_454 15_444
As4 As4 Eu2B 114.3(3) 10_454 15_444
As4 As4 Eu2B 56.2(3) 10_454 8
As4 As4 Eu2B 56.2(3) 10_454 10_454
As4 As4 Eu2B 114.3(3) 10_454 .
As4 As4 As1 180.0(4) 10_454 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 Eu2B 3.605(15) 10_454
Eu1 Eu2B 3.554(15) 15_444
Eu1 Eu4A 3.5286(6) 8
Eu1 Eu4B 3.571(10) 8
Eu1 Zn2 3.37(3) 8
Eu1 As1 3.1313(7) 10_454
Eu1 As2 3.1359(8) 8
Eu1 As2 3.1664(8) 3_545
Eu1 As3 3.1361(8) .
Eu1 As3 3.1088(9) 8
Eu1 As4 3.0206(9) 10_454
Eu1 As4 3.3029(11) .
Eu2A Eu3 3.7211(5) 27_565
Eu2A Eu4A 3.6466(7) 14_454
Eu2A Zn1 3.4428(5) 29_554
Eu2A Zn2 2.62(2) 31_565
Eu2A As1 3.2166(7) .
Eu2A As2 3.0354(9) 5
Eu2A As2 3.5875(10) 14_454
Eu2A As3 3.1193(9) 10_454
Eu2A As3 3.1916(10) 26
Eu2A As4 3.5366(12) 10_454
Eu2A As4 3.2462(10) .
Eu2B Eu4A 3.747(17) 14_454
Eu2B Zn1 3.634(16) 29_554
Eu2B Zn2 3.02(3) 31_565
Eu2B As1 3.065(17) .
Eu2B As2 3.528(17) 14_454
Eu2B As2 3.233(16) 5
Eu2B As3 3.513(16) 26
Eu2B As3 2.955(17) 10_454
Eu2B As4 2.894(15) .
Eu2B As4 3.176(15) 10_454
Eu3 Eu4A 3.5678(4) .
Eu3 Eu4A 3.5678(4) 6
Eu3 Eu4B 2.895(10) 8
Eu3 Eu4B 2.895(10) 3_545
Eu3 Zn2 3.48(3) .
Eu3 Zn2 3.48(3) 6
Eu3 As1 3.3296(5) 20_656
Eu3 As1 3.3296(5) 25
Eu3 As2 3.2474(8) 23_666
Eu3 As2 3.2474(8) 20_656
Eu3 As3 3.0400(9) 3_545
Eu3 As3 3.0400(9) 8
Eu4A Eu4B 0.963(11) .
Eu4A Eu4B 3.603(10) 8
Eu4A Zn2 1.79(3) .
Eu4A As1 3.1658(9) 20_656
Eu4A As2 3.0672(9) .
Eu4A As2 3.2780(9) 20_656
Eu4A As3 3.1769(8) 8
Eu4A As3 3.1834(8) 5
Eu4B Eu4B 3.341(19) 8
Eu4B Eu4B 3.66(2) 5
Eu4B Zn2 2.69(3) .
Eu4B As1 2.898(10) 20_656
Eu4B As2 3.646(10) .
Eu4B As3 3.537(9) 8
Eu4B As3 3.042(11) .
Eu4B As3 2.676(9) 5
Zn1 Zn2 2.74(3) 25
Zn1 Zn2 2.74(3) 3_545
Zn1 Zn2 2.74(3) 12_454
Zn1 Zn2 2.74(3) 18_556
Zn1 As2 2.6349(7) 3_545
Zn1 As2 2.6349(7) 12_454
Zn1 As2 2.6349(7) 25
Zn1 As2 2.6349(7) 18_556
Zn2 As2 2.56(3) 20_656
Zn2 As2 2.36(3) .
Zn2 As3 2.64(3) 8
As1 As4 2.750(2) .
As4 As4 0.579(4) 10_454
