Information card for entry 1574267

Structure parameters

• Formula: C103 H136 B Cl Ge2 O3
• Calculated formula: C103 H136 B Cl Ge2 O3
• Title of publication: Boradigermaallyl: inhibition of CH bond activation by borane CO adduct formation followed by CO insertion
• Authors of publication: Kern, Ralf H.; Hiller, Noemi; Eichele, Klaus; Schubert, Hartmut; Tönshoff, Christina; Bettinger, Holger F.; Wesemann, Lars
• Journal of publication: Chemical Science
• Year of publication: 2025
• Journal volume: 16
• Journal issue: 18
• Pages of publication: 7759 - 7765
• a: 14.4877 ± 0.0004 Å
• b: 18.0318 ± 0.0004 Å
• c: 18.9385 ± 0.0005 Å
• α: 77.231 ± 0.001°
• β: 89.503 ± 0.001°
• γ: 73.895 ± 0.001°
• Cell volume: 4628.4 ± 0.2 ų
• Cell temperature: 130 ± 2 K
• Ambient diffraction temperature: 130 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0463
• Residual factor for significantly intense reflections: 0.0378
• Weighted residual factors for significantly intense reflections: 0.0977
• Weighted residual factors for all reflections included in the refinement: 0.1041
• Goodness-of-fit parameter for all reflections included in the refinement: 1.032
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No