#------------------------------------------------------------------------------
#$Date: 2016-02-19 23:18:51 +0100 (vie 19 de feb de 2016) $
#$Revision: 176760 $
#$URL: svn://www.crystallography.net/cod/cif/2/01/79/2017971.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2017971
loop_
_publ_author_name
'Chu, Qingxin'
'Wang, Xiaofeng'
'Li, Qiliang'
'Liu, Xiaoyang'
_publ_section_title
;
 The tunnel manganese oxide Na~4.32~Mn₉O₁₈: a new Na⁺ site
 discovered by single-crystal X-ray diffraction
;
_journal_coeditor_code           BI3006
_journal_issue                   2
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              i10
_journal_page_last               i12
_journal_paper_doi               10.1107/S0108270110052856
_journal_volume                  67
_journal_year                    2011
_chemical_formula_iupac          'Na4.32 Mn9 O18'
_chemical_formula_moiety         'Mn9 Na4.32 O18'
_chemical_formula_sum            'Mn9 Na4.32 O18'
_chemical_formula_weight         881.78
_chemical_name_systematic
;
Tetrasodium nonamanganese octadecaoxide
;
_space_group_IT_number           55
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-P 2 2ab'
_symmetry_space_group_name_H-M   'P b a m'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   9.084(4)
_cell_length_b                   26.311(10)
_cell_length_c                   2.8223(11)
_cell_measurement_reflns_used    108
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      25
_cell_measurement_theta_min      3
_cell_volume                     674.6(5)
_computing_cell_refinement       'SAINT (Bruker 2009)'
_computing_data_collection       'APEX2 (Bruker, 2009)'
_computing_data_reduction        'SAINT (Bruker 2009)'
_computing_molecular_graphics
;
SHELXL97 (Sheldrick, 2008) and Materials Studio (Accelrys 2005)
;
_computing_publication_material
;
SHELXL97 (Sheldrick, 2008) and publCIF (Westrip, 2010)
;
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.967
_diffrn_measured_fraction_theta_max 0.967
_diffrn_measurement_device_type  'Bruker SMART APEXII CCD'
_diffrn_measurement_method       'φ and ω'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0345
_diffrn_reflns_av_sigmaI/netI    0.0349
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       28
_diffrn_reflns_limit_k_min       -36
_diffrn_reflns_limit_l_max       3
_diffrn_reflns_limit_l_min       -3
_diffrn_reflns_number            4301
_diffrn_reflns_theta_full        29.79
_diffrn_reflns_theta_max         29.79
_diffrn_reflns_theta_min         1.55
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    8.381
_exptl_absorpt_correction_T_max  0.7459
_exptl_absorpt_correction_T_min  0.6562
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker, 2009)'
_exptl_crystal_colour            black
_exptl_crystal_density_diffrn    4.341
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             833
_exptl_crystal_size_max          0.3
_exptl_crystal_size_mid          0.01
_exptl_crystal_size_min          0.005
_refine_diff_density_max         0.943
_refine_diff_density_min         -0.718
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.093
_refine_ls_matrix_type           full
_refine_ls_number_parameters     111
_refine_ls_number_reflns         1099
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.093
_refine_ls_R_factor_all          0.0441
_refine_ls_R_factor_gt           0.0315
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[σ²(Fo²)+(0.0221P)²+2.1043P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0632
_refine_ls_wR_factor_ref         0.0677
_reflns_number_gt                912
_reflns_number_total             1099
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            bi3006.cif
_cod_data_source_block           I
_cod_database_code               2017971
_cod_database_fobs_code          2017971
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, z'
'-x+1/2, y+1/2, -z'
'x+1/2, -y+1/2, -z'
'-x, -y, -z'
'x, y, -z'
'x-1/2, -y-1/2, z'
'-x-1/2, y-1/2, z'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Na Na1 0.2187(3) 0.20229(9) 0.0000 0.0262(9) Uani d SP 0.922(9) . .
Na Na2 0.7053(5) 0.08465(18) 0.5000 0.0230(17) Uani d SP 0.474(9) . .
Na Na3 0.1233(5) 0.00419(16) 0.0000 0.0298(17) Uani d SP 0.532(9) . .
Na Na4 0.7440(11) 0.0623(4) 0.0000 0.027(4) Uani d SP 0.233(9) . .
Mn Mn1 0.86356(8) 0.19353(3) 0.5000 0.00746(17) Uani d S 1 . .
Mn Mn2 0.5000 0.0000 0.0000 0.0102(2) Uani d S 1 . .
Mn Mn3 0.54351(8) 0.19491(3) 0.0000 0.00920(18) Uani d S 1 . .
Mn Mn4 0.36271(8) 0.08892(3) 0.5000 0.00872(17) Uani d S 1 . .
Mn Mn5 0.01709(8) 0.10997(3) 0.0000 0.00859(17) Uani d S 1 . .
O O1 0.9700(4) 0.06632(12) 0.5000 0.0122(7) Uani d S 1 . .
O O2 0.9184(4) 0.23592(12) 0.0000 0.0078(7) Uani d S 1 . .
O O3 0.0484(4) 0.15959(12) 0.5000 0.0097(7) Uani d S 1 . .
O O4 0.4998(4) 0.07295(13) 0.0000 0.0104(7) Uani d S 1 . .
O O5 0.2264(4) 0.09600(13) 0.0000 0.0134(8) Uani d S 1 . .
O O6 0.3600(4) 0.00300(13) 0.5000 0.0119(7) Uani d S 1 . .
O O7 0.4321(4) 0.16637(13) 0.5000 0.0129(8) Uani d S 1 . .
O O8 0.6685(4) 0.21980(14) 0.5000 0.0122(7) Uani d S 1 . .
O O9 0.8152(4) 0.14674(13) 0.0000 0.0165(8) Uani d S 1 . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Na Na 0.0362 0.0249 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mn Mn 0.3368 0.7283 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
Na1 Na1 Na1 1_556 1_554 180.00(19) ?
Na4 Na2 Na2 . 1_556 154.1(3) ?
Na4 Na2 Na2 1_556 1_556 25.9(3) ?
Na4 Na2 Na2 . 1_554 25.9(3) ?
Na4 Na2 Na2 1_556 1_554 154.1(3) ?
Na4 Na2 Na3 . 5_655 37.5(3) ?
Na4 Na2 Na3 1_556 5_655 90.8(4) ?
Na2 Na2 Na3 1_556 5_655 116.68(5) ?
Na2 Na2 Na3 1_554 5_655 63.32(5) ?
Mn4 Na2 Na3 . 5_655 121.46(15) ?
Na4 Na3 Na3 5_655 5 118.9(4) ?
Na4 Na3 Na3 5_655 1_554 90.0 ?
Na3 Na3 Na3 5 1_554 90.0 ?
Na4 Na3 Na3 5_655 1_556 90.0 ?
Na3 Na3 Na3 5 1_556 90.0 ?
Na2 Na4 Na2 1_554 . 128.2(7) ?
Na2 Na4 Na3 1_554 5_655 115.8(4) ?
Na2 Na4 Na3 . 5_655 115.8(4) ?
Na2 Na4 Na4 1_554 1_554 25.9(3) ?
Na2 Na4 Na4 . 1_554 154.1(4) ?
Na3 Na4 Na4 5_655 1_554 90.0 ?
O2 Mn1 O2 1_556 . 98.25(15) ?
O2 Mn1 O3 1_556 1_655 92.59(13) ?
O2 Mn1 O3 . 1_655 92.59(13) ?
O2 Mn1 O8 1_556 . 91.80(13) ?
O2 Mn1 O8 . . 91.80(13) ?
O3 Mn1 O8 1_655 . 173.29(15) ?
O2 Mn1 O9 1_556 . 176.48(15) ?
O2 Mn1 O9 . . 83.61(11) ?
O3 Mn1 O9 1_655 . 84.32(14) ?
O8 Mn1 O9 . . 91.13(15) ?
O2 Mn1 O9 1_556 1_556 83.61(11) ?
O2 Mn1 O9 . 1_556 176.48(15) ?
O3 Mn1 O9 1_655 1_556 84.32(14) ?
O8 Mn1 O9 . 1_556 91.13(15) ?
O9 Mn1 O9 . 1_556 94.38(16) ?
Mn1 Mn1 Mn1 1_556 1_554 180.00(8) ?
Mn1 Mn1 Mn5 1_556 1_655 118.457(15) ?
Mn1 Mn1 Mn5 1_554 1_655 61.543(15) ?
Mn1 Mn1 Mn5 1_556 1_656 61.543(15) ?
Mn1 Mn1 Mn5 1_554 1_656 118.457(15) ?
Mn5 Mn1 Mn5 1_655 1_656 56.91(3) ?
Mn1 Mn1 Mn3 1_556 . 115.889(15) ?
Mn1 Mn1 Mn3 1_554 . 64.111(15) ?
Mn5 Mn1 Mn3 1_655 . 102.94(3) ?
Mn5 Mn1 Mn3 1_656 . 129.79(3) ?
O6 Mn2 O6 5_656 1_554 180.0(3) ?
O6 Mn2 O6 5_656 5_655 95.83(15) ?
O6 Mn2 O6 1_554 5_655 84.17(15) ?
O6 Mn2 O6 5_656 . 84.17(15) ?
O6 Mn2 O6 1_554 . 95.83(15) ?
O6 Mn2 O6 5_655 . 180.0(3) ?
O6 Mn2 O4 5_656 5_655 87.59(13) ?
O6 Mn2 O4 1_554 5_655 92.41(13) ?
O6 Mn2 O4 5_655 5_655 87.59(13) ?
O6 Mn2 O4 . 5_655 92.41(13) ?
O6 Mn2 O4 5_656 . 92.41(13) ?
O6 Mn2 O4 1_554 . 87.59(13) ?
O6 Mn2 O4 5_655 . 92.41(13) ?
O6 Mn2 O4 . . 87.59(13) ?
O4 Mn2 O4 5_655 . 180.0(2) ?
Mn2 Mn2 Mn2 1_556 1_554 180.0 ?
Mn2 Mn2 Mn4 1_556 . 61.976(14) ?
Mn2 Mn2 Mn4 1_554 . 118.024(14) ?
Mn2 Mn2 Mn4 1_556 5_655 118.024(14) ?
Mn2 Mn2 Mn4 1_554 5_655 61.976(14) ?
Mn4 Mn2 Mn4 . 5_655 180.00(3) ?
O7 Mn3 O7 1_554 . 96.45(16) ?
O7 Mn3 O8 1_554 . 175.42(16) ?
O7 Mn3 O8 . . 84.49(11) ?
O7 Mn3 O8 1_554 1_554 84.49(11) ?
O7 Mn3 O8 . 1_554 175.42(16) ?
O8 Mn3 O8 . 1_554 94.23(16) ?
O7 Mn3 O2 1_554 7_565 93.05(12) ?
O7 Mn3 O2 . 7_565 93.05(12) ?
O8 Mn3 O2 . 7_565 91.37(13) ?
O8 Mn3 O2 1_554 7_565 91.37(13) ?
Mn3 Mn3 Mn3 1_556 1_554 180.0 ?
Mn3 Mn3 Mn1 1_556 . 64.111(15) ?
Mn3 Mn3 Mn1 1_554 . 115.889(15) ?
O7 Mn3 Mn1 1_554 1_554 98.70(10) ?
O7 Mn3 Mn1 . 1_554 143.37(11) ?
O8 Mn3 Mn1 . 1_554 78.08(9) ?
O8 Mn3 Mn1 1_554 1_554 32.17(10) ?
O2 Mn3 Mn1 7_565 1_554 119.09(8) ?
Mn3 Mn3 Mn1 1_556 1_554 115.889(15) ?
Mn3 Mn3 Mn1 1_554 1_554 64.111(15) ?
Mn1 Mn3 Mn1 . 1_554 51.78(3) ?
O5 Mn4 O5 . 1_556 96.85(17) ?
O5 Mn4 O4 . 1_556 173.07(15) ?
O5 Mn4 O4 1_556 1_556 84.14(12) ?
O5 Mn4 O4 . . 84.14(12) ?
O5 Mn4 O4 1_556 . 173.07(15) ?
O4 Mn4 O4 1_556 . 94.06(15) ?
O5 Mn4 O7 . . 95.72(12) ?
O5 Mn4 O7 1_556 . 95.72(12) ?
O4 Mn4 O7 1_556 . 91.00(12) ?
O4 Mn4 O7 . . 91.00(12) ?
O5 Mn4 O6 . . 95.24(12) ?
O5 Mn4 O6 1_556 . 95.24(12) ?
O4 Mn4 O6 1_556 . 77.83(12) ?
O4 Mn4 O6 . . 77.83(12) ?
O7 Mn4 O6 . . 163.45(13) ?
Mn4 Mn4 Mn4 1_556 1_554 180.00(6) ?
Mn4 Mn4 Mn2 1_556 . 118.024(14) ?
Mn4 Mn4 Mn2 1_554 . 61.976(14) ?
Mn4 Mn4 Mn2 1_556 1_556 61.976(14) ?
Mn4 Mn4 Mn2 1_554 1_556 118.024(14) ?
Mn2 Mn4 Mn2 . 1_556 56.05(3) ?
O1 Mn5 O1 1_454 1_455 98.05(16) ?
O1 Mn5 O5 1_454 . 96.21(13) ?
O1 Mn5 O5 1_455 . 96.21(13) ?
O1 Mn5 O3 1_454 . 173.99(14) ?
O1 Mn5 O3 1_455 . 84.15(11) ?
O5 Mn5 O3 . . 89.08(12) ?
O1 Mn5 O3 1_454 1_554 84.15(11) ?
O1 Mn5 O3 1_455 1_554 173.99(14) ?
O5 Mn5 O3 . 1_554 89.08(12) ?
O3 Mn5 O3 . 1_554 93.13(15) ?
O1 Mn5 O9 1_454 1_455 94.82(13) ?
O1 Mn5 O9 1_455 1_455 94.82(13) ?
O5 Mn5 O9 . 1_455 163.13(15) ?
O3 Mn5 O9 . 1_455 79.39(12) ?
O3 Mn5 O9 1_554 1_455 79.39(12) ?
Mn5 Mn5 Mn1 1_556 1_455 61.543(15) ?
Mn5 Mn5 Mn1 1_554 1_455 118.457(15) ?
Mn5 Mn5 Mn1 1_556 1_454 118.457(15) ?
Mn5 Mn5 Mn1 1_554 1_454 61.543(15) ?
Mn1 Mn5 Mn1 1_455 1_454 56.91(3) ?
Mn5 O1 Mn5 1_656 1_655 98.05(16) ?
Mn1 O2 Mn1 1_554 . 98.25(15) ?
Mn1 O2 Mn3 1_554 7_665 130.40(8) ?
Mn1 O2 Mn3 . 7_665 130.40(8) ?
Mn1 O3 Mn5 1_455 . 100.74(13) ?
Mn1 O3 Mn5 1_455 1_556 100.74(13) ?
Mn5 O3 Mn5 . 1_556 93.13(15) ?
Mn2 O4 Mn4 . 1_554 102.62(13) ?
Mn2 O4 Mn4 . . 102.62(13) ?
Mn4 O4 Mn4 1_554 . 94.06(15) ?
Mn4 O5 Mn4 . 1_554 96.85(17) ?
Mn4 O5 Mn5 . . 131.53(8) ?
Mn4 O5 Mn5 1_554 . 131.53(8) ?
Mn2 O6 Mn2 1_556 . 95.83(15) ?
Mn2 O6 Mn4 1_556 . 91.96(12) ?
Mn2 O6 Mn4 . . 91.96(12) ?
Mn3 O7 Mn3 1_556 . 96.45(16) ?
Mn3 O7 Mn4 1_556 . 122.50(11) ?
Mn3 O7 Mn4 . . 122.50(11) ?
Mn1 O8 Mn3 . . 115.20(14) ?
Mn1 O8 Mn3 . 1_556 115.20(14) ?
Mn3 O8 Mn3 . 1_556 94.23(16) ?
Mn1 O9 Mn1 . 1_554 94.38(16) ?
Mn1 O9 Mn5 . 1_655 95.54(14) ?
Mn1 O9 Mn5 1_554 1_655 95.54(14) ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Mn1 O2 . 1.866(2) y
Mn1 O8 . 1.902(4) y
Mn1 O9 . 1.924(2) y
Mn1 O2 1_556 1.866(2) y
Mn1 O3 1_655 1.902(3) y
Mn1 O9 1_556 1.924(2) ?
Mn1 Mn1 1_556 2.8223(11) ?
Mn1 Mn1 1_554 2.8223(11) ?
Mn1 Mn5 1_655 2.9615(11) ?
Mn1 Mn5 1_656 2.9615(11) ?
Mn1 Mn3 . 3.2319(14) ?
Mn2 O4 . 1.919(3) y
Mn2 O6 . 1.901(2) y
Mn2 O4 5_655 1.919(3) y
Mn2 O6 1_554 1.901(2) y
Mn2 O6 5_656 1.901(2) y
Mn2 O6 5_655 1.901(2) ?
Mn2 Mn2 1_556 2.8223(11) ?
Mn2 Mn2 1_554 2.8223(11) ?
Mn2 Mn4 . 3.0035(10) ?
Mn2 Mn4 5_655 3.0035(10) ?
Mn3 O7 . 1.892(2) y
Mn3 O8 . 1.926(2) y
Mn3 O2 7_565 2.146(3) y
Mn3 O7 1_554 1.892(2) ?
Mn3 O8 1_554 1.926(2) ?
Mn3 Mn3 1_556 2.8223(11) ?
Mn3 Mn3 1_554 2.8223(11) ?
Mn3 Mn1 1_554 3.2319(14) ?
Mn4 O4 . 1.928(2) y
Mn4 O5 . 1.886(2) y
Mn4 O6 . 2.261(4) y
Mn4 O7 . 2.133(3) y
Mn4 O5 1_556 1.886(2) ?
Mn4 O4 1_556 1.928(2) ?
Mn4 Mn4 1_556 2.8223(11) ?
Mn4 Mn4 1_554 2.8223(11) ?
Mn4 Mn2 1_556 3.0035(10) ?
Mn5 O3 . 1.943(2) y
Mn5 O5 . 1.937(4) y
Mn5 O1 1_454 1.869(2) y
Mn5 O1 1_455 1.869(2) y
Mn5 O3 1_554 1.943(2) ?
Mn5 O9 1_455 2.074(4) ?
Mn5 Mn5 1_556 2.8223(11) ?
Mn5 Mn5 1_554 2.8223(11) ?
Mn5 Mn1 1_455 2.9615(12) ?
Mn5 Mn1 1_454 2.9615(11) ?
Na1 O3 1_554 2.376(3) ?
Na1 O3 . 2.376(3) ?
Na1 O2 7_565 2.436(4) ?
Na1 O8 7_565 2.530(4) ?
Na1 O8 7_564 2.530(4) ?
Na1 O7 . 2.577(4) ?
Na1 O7 1_554 2.577(4) ?
Na1 O5 . 2.798(4) ?
Na1 O2 1_455 2.868(4) ?
Na1 Na1 1_556 2.8223(11) ?
Na1 Na1 1_554 2.8223(11) ?
Na2 Na4 . 1.569(5) ?
Na2 Na4 1_556 1.569(5) ?
Na2 O4 . 2.360(5) ?
Na2 O4 1_556 2.360(5) ?
Na2 O9 1_556 2.378(5) ?
Na2 O9 . 2.378(5) ?
Na2 O6 5_656 2.381(6) ?
Na2 O1 . 2.452(6) ?
Na2 Na2 1_556 2.8223(11) ?
Na2 Na2 1_554 2.8223(11) ?
Na2 Na3 5_655 3.143(6) ?
Na3 Na4 5_655 2.125(11) ?
Na3 Na3 5 2.251(9) ?
Na3 O1 5_655 2.480(4) ?
Na3 O1 5_656 2.480(4) ?
Na3 O1 1_455 2.570(5) ?
Na3 O1 1_454 2.570(5) ?
Na3 O6 . 2.572(5) ?
Na3 O6 1_554 2.572(5) ?
Na3 O5 . 2.591(6) ?
Na3 Na3 1_554 2.8223(11) ?
Na3 Na3 1_556 2.8223(11) ?
Na4 Na2 1_554 1.569(5) ?
Na4 Na3 5_655 2.125(11) ?
Na4 O4 . 2.236(11) ?
Na4 O9 . 2.314(10) ?
Na4 O6 5_655 2.415(8) ?
Na4 O6 5_656 2.415(8) ?
Na4 O1 . 2.493(9) ?
Na4 O1 1_554 2.493(9) ?
Na4 Na4 1_554 2.8223(11) ?
O1 Mn5 1_656 1.869(2) ?
O1 Mn5 1_655 1.869(2) ?
O1 Na3 5_655 2.480(4) ?
O1 Na3 5_656 2.480(4) ?
O1 Na4 1_556 2.493(9) ?
O1 Na3 1_655 2.570(5) ?
O1 Na3 1_656 2.570(5) ?
O2 Mn1 1_554 1.866(2) ?
O2 Mn3 7_665 2.146(3) ?
O2 Na1 7_665 2.436(4) ?
O2 Na1 1_655 2.868(4) ?
O3 Mn1 1_455 1.902(3) ?
O3 Mn5 1_556 1.943(2) ?
O3 Na1 1_556 2.376(3) ?
O4 Mn4 1_554 1.928(2) ?
O4 Na2 1_554 2.360(5) ?
O5 Mn4 1_554 1.886(2) ?
O6 Mn2 1_556 1.901(2) ?
O6 Na2 5_656 2.381(6) ?
O6 Na4 5_655 2.415(8) ?
O6 Na4 5_656 2.415(8) ?
O6 Na3 1_556 2.572(5) ?
O7 Mn3 1_556 1.892(2) ?
O7 Na1 1_556 2.577(4) ?
O8 Mn3 1_556 1.926(2) ?
O8 Na1 7_666 2.530(4) ?
O8 Na1 7_665 2.530(4) ?
O9 Mn1 1_554 1.924(2) ?
O9 Mn5 1_655 2.074(4) ?
O9 Na2 1_554 2.378(5) ?
