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#$Date: 2016-02-13 20:28:24 +0100 (Sat 13 de Feb de 2016) $
#$Revision: 176429 $
#$URL: svn://www.crystallography.net/cod/cif/4/00/25/4002572.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4002572
loop_
_publ_author_name
'Cario, L.'
'Palvadeau, P.'
'Moelo, Y.'
'Lafond, A.'
'Meerschaut, A.'
'Deudon, C.'
'Corraze, B.'
_publ_section_title
;
 Mixed-valence state of europium in the misfit layer compound (Eu S)1.173
 Nb S2
;
_journal_name_full               'Chemistry of Materials (1,1989-)'
_journal_page_first              943
_journal_page_last               950
_journal_volume                  15
_journal_year                    2003
_chemical_formula_sum            'Eu1.173 Nb S3.173'
_chemical_name_systematic        '(Eu S)1.173 Nb S2'
_space_group_IT_number           42
_symmetry_space_group_name_Hall  'F -2 -2'
_symmetry_space_group_name_H-M   'F m 2 m'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   3.3251
_cell_length_b                   5.7432
_cell_length_c                   22.939
_cell_volume                     438.060
_citation_journal_id_ASTM        CMATEX
_cod_data_source_file            Cario_CMATEX_2003_60.cif
_cod_data_source_block           Eu1.173Nb1S3.173
_cod_original_cell_volume        438.0595
_cod_original_sg_symbol_Hall     'F 2 -2 (y,z,x)'
_cod_original_formula_sum        'Eu1.173 Nb1 S3.173'
_cod_database_code               4002572
loop_
_symmetry_equiv_pos_as_xyz
x,y,z
-x,y,-z
x,y,-z
-x,y,z
x+1/2,y+1/2,z
-x+1/2,y+1/2,-z
x+1/2,y+1/2,-z
-x+1/2,y+1/2,z
x,y+1/2,z+1/2
-x,y+1/2,-z+1/2
x,y+1/2,-z+1/2
-x,y+1/2,z+1/2
x+1/2,y,z+1/2
-x+1/2,y,-z+1/2
x+1/2,y,-z+1/2
-x+1/2,y,z+1/2
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
Eu1 Eu+2 0 0 0.32322 0.5865 0.0
S1 S-2 0 0.255 0.06815 1 0.0
Nb1 Nb+4 0 -0.0784 0 1 0.0
S2 S-2 0 0.0029 0.19853 0.5865 0.0
