#------------------------------------------------------------------------------
#$Date: 2016-03-21 05:56:37 +0100 (lun 21 de mar de 2016) $
#$Revision: 178541 $
#$URL: svn://www.crystallography.net/cod/cif/4/06/47/4064797.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4064797
loop_
_publ_author_name
'Li, Baolin'
'Matsuo, Tsukasa'
'Fukunaga, Takeo'
'Hashizume, Daisuke'
'Fueno, Hiroyuki'
'Tanaka, Kazuyoshi'
'Tamao, Kohei'
_publ_section_title
;
 Neutral and Cationic Gold(I) Complexes with π-Conjugated Phosphasilene
 Ligands
;
_journal_issue                   13
_journal_name_full               Organometallics
_journal_page_first              3453
_journal_paper_doi               10.1021/om2003442
_journal_volume                  30
_journal_year                    2011
_chemical_formula_moiety         'C108 H158 Au P2 Si2, C24 B F20, 2(C H2 Cl2)'
_chemical_formula_sum            'C134 H162 Au B Cl4 F20 P2 Si2'
_chemical_formula_weight         2620.33
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      15
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90
_cell_angle_beta                 111.718(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   26.492(5)
_cell_length_b                   18.531(3)
_cell_length_c                   27.352(5)
_cell_measurement_reflns_used    15991
_cell_measurement_temperature    100
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.0
_cell_volume                     12475(4)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalClear
_computing_molecular_graphics    'ORTEP-3 for Windows'
_computing_publication_material  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    SIR-2004
_diffrn_ambient_temperature      100
_diffrn_detector_area_resol_mean 7.31
_diffrn_measured_fraction_theta_full 0.990
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_device_type  'Rigaku Saturn'
_diffrn_measurement_method       ω-scan
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus rotating anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0515
_diffrn_reflns_av_sigmaI/netI    0.0561
_diffrn_reflns_limit_h_max       34
_diffrn_reflns_limit_h_min       -29
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       35
_diffrn_reflns_limit_l_min       -35
_diffrn_reflns_number            50517
_diffrn_reflns_theta_full        27.53
_diffrn_reflns_theta_max         27.53
_diffrn_reflns_theta_min         3.02
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.389
_exptl_absorpt_correction_T_max  0.895
_exptl_absorpt_correction_T_min  0.752
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Jacobson, R. (1998) Private communication'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.395
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             5424
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.08
_refine_diff_density_max         1.765
_refine_diff_density_min         -1.509
_refine_diff_density_rms         0.110
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.097
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     811
_refine_ls_number_reflns         14209
_refine_ls_number_restraints     12
_refine_ls_restrained_S_all      1.096
_refine_ls_R_factor_all          0.0756
_refine_ls_R_factor_gt           0.0626
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0727P)²+40.1514P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1511
_refine_ls_wR_factor_ref         0.1608
_reflns_number_gt                12038
_reflns_number_total             14209
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            om2003442_si_002.cif
_cod_data_source_block           4
_cod_original_cell_volume        12474(4)
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               4064797
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.5000 0.178981(13) 0.2500 0.03340(9) Uani 1 2 d S . .
P1 P 0.52014(5) 0.18099(6) 0.33860(5) 0.0320(3) Uani 1 1 d . . .
Si1 Si 0.59500(5) 0.13917(6) 0.38752(5) 0.0282(3) Uani 1 1 d . . .
C1 C 0.64659(16) 0.1090(2) 0.36015(17) 0.0278(9) Uani 1 1 d . . .
C2 C 0.68556(17) 0.1577(2) 0.35434(17) 0.0303(9) Uani 1 1 d . . .
C3 C 0.68807(18) 0.2398(2) 0.36035(18) 0.0318(9) Uani 1 1 d . . .
C4 C 0.7441(2) 0.2594(3) 0.3580(2) 0.0396(11) Uani 1 1 d . . .
H4A H 0.7398 0.2997 0.3331 0.048 Uiso 1 1 calc R . .
H4B H 0.7692 0.2751 0.3932 0.048 Uiso 1 1 calc R . .
C5 C 0.76781(18) 0.1928(3) 0.34002(19) 0.0348(10) Uani 1 1 d . . .
C6 C 0.72900(17) 0.1331(2) 0.34138(17) 0.0309(9) Uani 1 1 d . . .
C7 C 0.73475(17) 0.0596(2) 0.33324(17) 0.0323(10) Uani 1 1 d . . .
H7 H 0.7650 0.0428 0.3257 0.039 Uiso 1 1 calc R . .
C8 C 0.69596(17) 0.0116(2) 0.33628(17) 0.0303(9) Uani 1 1 d . . .
C9 C 0.69550(17) -0.0698(2) 0.32808(18) 0.0331(10) Uani 1 1 d . . .
C10 C 0.65312(18) -0.0938(2) 0.35133(19) 0.0343(10) Uani 1 1 d . . .
H10A H 0.6718 -0.1110 0.3879 0.041 Uiso 1 1 calc R . .
H10B H 0.6309 -0.1338 0.3302 0.041 Uiso 1 1 calc R . .
C11 C 0.61609(17) -0.0283(2) 0.35056(17) 0.0292(9) Uani 1 1 d . . .
C12 C 0.65259(16) 0.0349(2) 0.34916(16) 0.0268(8) Uani 1 1 d . . .
C13 C 0.68668(19) 0.2649(2) 0.41326(19) 0.0355(10) Uani 1 1 d . . .
H13A H 0.6907 0.3175 0.4160 0.053 Uiso 1 1 calc R . .
H13B H 0.7165 0.2422 0.4420 0.053 Uiso 1 1 calc R . .
H13C H 0.6520 0.2511 0.4156 0.053 Uiso 1 1 calc R . .
C14 C 0.64187(19) 0.2747(3) 0.3142(2) 0.0377(10) Uani 1 1 d . . .
H14A H 0.6448 0.2600 0.2809 0.057 Uiso 1 1 calc R . .
H14B H 0.6446 0.3273 0.3174 0.057 Uiso 1 1 calc R . .
H14C H 0.6068 0.2590 0.3147 0.057 Uiso 1 1 calc R . .
C15 C 0.8261(2) 0.1763(3) 0.3783(2) 0.0462(13) Uani 1 1 d . . .
H15A H 0.8391 0.1327 0.3656 0.055 Uiso 1 1 calc R . .
H15B H 0.8499 0.2169 0.3769 0.055 Uiso 1 1 calc R . .
C16 C 0.8329(3) 0.1645(3) 0.4350(3) 0.0620(17) Uani 1 1 d . . .
H16A H 0.8240 0.2090 0.4493 0.093 Uiso 1 1 calc R . .
H16B H 0.8706 0.1510 0.4555 0.093 Uiso 1 1 calc R . .
H16C H 0.8086 0.1257 0.4370 0.093 Uiso 1 1 calc R . .
C17 C 0.7662(2) 0.2091(4) 0.2830(2) 0.0528(14) Uani 1 1 d . . .
H17A H 0.7281 0.2201 0.2605 0.063 Uiso 1 1 calc R . .
H17B H 0.7875 0.2537 0.2849 0.063 Uiso 1 1 calc R . .
C18 C 0.7858(3) 0.1548(3) 0.2557(3) 0.0577(15) Uani 1 1 d . . .
H18A H 0.8246 0.1460 0.2753 0.086 Uiso 1 1 calc R . .
H18B H 0.7805 0.1720 0.2202 0.086 Uiso 1 1 calc R . .
H18C H 0.7655 0.1098 0.2532 0.086 Uiso 1 1 calc R . .
C19 C 0.7518(2) -0.1011(3) 0.3581(2) 0.0423(12) Uani 1 1 d . . .
H19A H 0.7778 -0.0799 0.3437 0.051 Uiso 1 1 calc R . .
H19B H 0.7635 -0.0864 0.3954 0.051 Uiso 1 1 calc R . .
C20 C 0.7549(2) -0.1830(3) 0.3555(3) 0.0550(16) Uani 1 1 d . . .
H20A H 0.7276 -0.2046 0.3672 0.082 Uiso 1 1 calc R . .
H20B H 0.7912 -0.1992 0.3783 0.082 Uiso 1 1 calc R . .
H20C H 0.7480 -0.1978 0.3191 0.082 Uiso 1 1 calc R . .
C21 C 0.67559(19) -0.0908(3) 0.26867(19) 0.0361(10) Uani 1 1 d . . .
H21A H 0.6686 -0.1434 0.2656 0.043 Uiso 1 1 calc R . .
H21B H 0.6406 -0.0661 0.2500 0.043 Uiso 1 1 calc R . .
C22 C 0.7140(2) -0.0728(3) 0.2410(2) 0.0406(11) Uani 1 1 d . . .
H22A H 0.7207 -0.0206 0.2429 0.061 Uiso 1 1 calc R . .
H22B H 0.6976 -0.0875 0.2040 0.061 Uiso 1 1 calc R . .
H22C H 0.7484 -0.0984 0.2580 0.061 Uiso 1 1 calc R . .
C23 C 0.60132(19) -0.0298(3) 0.39913(18) 0.0355(10) Uani 1 1 d . . .
H23A H 0.6344 -0.0247 0.4307 0.053 Uiso 1 1 calc R . .
H23B H 0.5836 -0.0757 0.4006 0.053 Uiso 1 1 calc R . .
H23C H 0.5765 0.0101 0.3975 0.053 Uiso 1 1 calc R . .
C24 C 0.56377(17) -0.0283(2) 0.30094(18) 0.0319(9) Uani 1 1 d . . .
H24A H 0.5414 -0.0701 0.3018 0.048 Uiso 1 1 calc R . .
H24B H 0.5732 -0.0309 0.2696 0.048 Uiso 1 1 calc R . .
H24C H 0.5433 0.0162 0.2999 0.048 Uiso 1 1 calc R . .
C25 C 0.47312(17) 0.2063(2) 0.37095(19) 0.0319(9) Uani 1 1 d . A .
C26 C 0.47459(18) 0.2761(2) 0.3920(2) 0.0373(11) Uani 1 1 d D . .
C30 C 0.44379(17) 0.2913(2) 0.4230(2) 0.0354(10) Uani 1 1 d D A .
C31 C 0.41075(18) 0.2387(2) 0.4323(2) 0.0347(10) Uani 1 1 d . . .
H31 H 0.3922 0.2482 0.4553 0.042 Uiso 1 1 calc R A .
C32 C 0.40543(17) 0.1729(2) 0.40758(19) 0.0305(9) Uani 1 1 d . A .
C33 C 0.36641(17) 0.1134(2) 0.40952(19) 0.0318(9) Uani 1 1 d . . .
C34 C 0.37197(19) 0.0577(3) 0.36936(19) 0.0351(10) Uani 1 1 d . A .
H34A H 0.3363 0.0513 0.3404 0.042 Uiso 1 1 calc R . .
H34B H 0.3834 0.0105 0.3869 0.042 Uiso 1 1 calc R . .
C35 C 0.41452(17) 0.0839(2) 0.34658(18) 0.0305(9) Uani 1 1 d . . .
C36 C 0.43500(17) 0.1555(2) 0.37653(18) 0.0294(9) Uani 1 1 d . A .
C43 C 0.38407(19) 0.0825(3) 0.46572(19) 0.0362(10) Uani 1 1 d . A .
H43A H 0.3810 0.1211 0.4895 0.043 Uiso 1 1 calc R . .
H43B H 0.3583 0.0438 0.4658 0.043 Uiso 1 1 calc R . .
C44 C 0.4412(2) 0.0521(3) 0.48804(19) 0.0398(11) Uani 1 1 d . . .
H44A H 0.4441 0.0111 0.4665 0.060 Uiso 1 1 calc R A .
H44B H 0.4494 0.0359 0.5243 0.060 Uiso 1 1 calc R . .
H44C H 0.4672 0.0895 0.4877 0.060 Uiso 1 1 calc R . .
C45 C 0.30805(19) 0.1429(3) 0.3914(2) 0.0447(12) Uani 1 1 d . A .
H45A H 0.3067 0.1803 0.4168 0.054 Uiso 1 1 calc R . .
H45B H 0.2994 0.1669 0.3569 0.054 Uiso 1 1 calc R . .
C46 C 0.2639(2) 0.0871(3) 0.3861(3) 0.0520(14) Uani 1 1 d . . .
H46A H 0.2633 0.0511 0.3597 0.078 Uiso 1 1 calc R A .
H46B H 0.2285 0.1111 0.3753 0.078 Uiso 1 1 calc R . .
H46C H 0.2716 0.0631 0.4201 0.078 Uiso 1 1 calc R . .
C47 C 0.45739(19) 0.0258(3) 0.3539(2) 0.0381(11) Uani 1 1 d . A .
H47A H 0.4395 -0.0199 0.3392 0.057 Uiso 1 1 calc R . .
H47B H 0.4788 0.0196 0.3915 0.057 Uiso 1 1 calc R . .
H47C H 0.4814 0.0402 0.3357 0.057 Uiso 1 1 calc R . .
C48 C 0.3860(2) 0.1025(3) 0.28830(19) 0.0401(11) Uani 1 1 d . A .
H48A H 0.4127 0.1207 0.2743 0.060 Uiso 1 1 calc R . .
H48B H 0.3584 0.1396 0.2844 0.060 Uiso 1 1 calc R . .
H48C H 0.3685 0.0591 0.2688 0.060 Uiso 1 1 calc R . .
C49 C 0.61495(18) 0.1355(2) 0.46001(18) 0.0313(9) Uani 1 1 d . . .
C50 C 0.6674(2) 0.1111(2) 0.49053(18) 0.0355(10) Uani 1 1 d . . .
H50 H 0.6922 0.0988 0.4741 0.043 Uiso 1 1 calc R . .
C51 C 0.6831(2) 0.1048(3) 0.5449(2) 0.0444(12) Uani 1 1 d . . .
H51 H 0.7185 0.0879 0.5655 0.053 Uiso 1 1 calc R . .
C52 C 0.6472(2) 0.1231(3) 0.5686(2) 0.0457(13) Uani 1 1 d . . .
H52 H 0.6580 0.1189 0.6057 0.055 Uiso 1 1 calc R . .
C53 C 0.5961(2) 0.1472(3) 0.5393(2) 0.0472(13) Uani 1 1 d . . .
H53 H 0.5718 0.1600 0.5561 0.057 Uiso 1 1 calc R . .
C54 C 0.5796(2) 0.1531(3) 0.4851(2) 0.0397(11) Uani 1 1 d . . .
H54 H 0.5439 0.1694 0.4650 0.048 Uiso 1 1 calc R . .
C27A C 0.4989(7) 0.3438(4) 0.3754(7) 0.033(3) Uani 0.514(5) 1 d PD A 1
C28A C 0.4721(4) 0.4052(4) 0.3959(4) 0.0316(14) Uani 0.514(5) 1 d PD A 1
H28A H 0.4991 0.4431 0.4131 0.038 Uiso 0.514(5) 1 calc PR A 1
H28B H 0.4421 0.4273 0.3662 0.038 Uiso 0.514(5) 1 calc PR A 1
C29A C 0.4497(10) 0.3722(4) 0.4359(7) 0.030(3) Uani 0.514(5) 1 d PD A 1
C37A C 0.5601(12) 0.3466(17) 0.3961(6) 0.027(3) Uani 0.514(5) 1 d P A 1
H37A H 0.5747 0.3263 0.4317 0.041 Uiso 0.514(5) 1 calc PR A 1
H37B H 0.5720 0.3969 0.3971 0.041 Uiso 0.514(5) 1 calc PR A 1
H37C H 0.5735 0.3186 0.3730 0.041 Uiso 0.514(5) 1 calc PR A 1
C38A C 0.4883(5) 0.3582(6) 0.3163(4) 0.0410(18) Uani 0.514(5) 1 d P A 1
H38A H 0.4976 0.4084 0.3119 0.062 Uiso 0.514(5) 1 calc PR A 1
H38B H 0.4498 0.3498 0.2952 0.062 Uiso 0.514(5) 1 calc PR A 1
H38C H 0.5107 0.3256 0.3046 0.062 Uiso 0.514(5) 1 calc PR A 1
C39A C 0.4928(4) 0.3787(5) 0.4921(4) 0.0358(15) Uani 0.514(5) 1 d P A 1
H39A H 0.5272 0.3573 0.4925 0.043 Uiso 0.514(5) 1 calc PR A 1
H39B H 0.4996 0.4306 0.5008 0.043 Uiso 0.514(5) 1 calc PR A 1
C40A C 0.4782(5) 0.3433(7) 0.5345(4) 0.0487(19) Uani 0.514(5) 1 d P A 1
H40A H 0.4448 0.3650 0.5354 0.073 Uiso 0.514(5) 1 calc PR A 1
H40B H 0.5078 0.3503 0.5686 0.073 Uiso 0.514(5) 1 calc PR A 1
H40C H 0.4725 0.2916 0.5271 0.073 Uiso 0.514(5) 1 calc PR A 1
C41A C 0.3937(13) 0.404(3) 0.4301(15) 0.034(3) Uani 0.514(5) 1 d PD A 1
H41A H 0.3680 0.3964 0.3934 0.040 Uiso 0.514(5) 1 calc PR A 1
H41B H 0.3794 0.3770 0.4536 0.040 Uiso 0.514(5) 1 calc PR A 1
C42A C 0.396(4) 0.484(3) 0.443(3) 0.045(7) Uani 0.514(5) 1 d PD A 1
H42A H 0.4095 0.4906 0.4816 0.068 Uiso 0.514(5) 1 calc PR A 1
H42B H 0.3590 0.5048 0.4279 0.068 Uiso 0.514(5) 1 calc PR A 1
H42C H 0.4197 0.5092 0.4288 0.068 Uiso 0.514(5) 1 calc PR A 1
C27B C 0.5045(8) 0.3476(5) 0.3907(7) 0.033(3) Uani 0.486(5) 1 d PD A 2
C28B C 0.4933(4) 0.3992(5) 0.4302(4) 0.0316(14) Uani 0.486(5) 1 d PD A 2
H28C H 0.4803 0.4463 0.4131 0.038 Uiso 0.486(5) 1 calc PR A 2
H28D H 0.5272 0.4074 0.4609 0.038 Uiso 0.486(5) 1 calc PR A 2
C29B C 0.4497(9) 0.3655(5) 0.4485(9) 0.030(3) Uani 0.486(5) 1 d PD A 2
C37B C 0.5652(14) 0.3424(19) 0.4112(6) 0.027(3) Uani 0.486(5) 1 d P A 2
H37D H 0.5762 0.3102 0.3885 0.041 Uiso 0.486(5) 1 calc PR A 2
H37E H 0.5784 0.3231 0.4471 0.041 Uiso 0.486(5) 1 calc PR A 2
H37F H 0.5807 0.3905 0.4113 0.041 Uiso 0.486(5) 1 calc PR A 2
C38B C 0.4729(5) 0.3694(6) 0.3336(5) 0.0410(18) Uani 0.486(5) 1 d P A 2
H38D H 0.4860 0.4163 0.3266 0.062 Uiso 0.486(5) 1 calc PR A 2
H38E H 0.4342 0.3728 0.3276 0.062 Uiso 0.486(5) 1 calc PR A 2
H38F H 0.4783 0.3330 0.3100 0.062 Uiso 0.486(5) 1 calc PR A 2
C39B C 0.4664(4) 0.3702(6) 0.5085(4) 0.0358(15) Uani 0.486(5) 1 d P A 2
H39C H 0.4736 0.4214 0.5191 0.043 Uiso 0.486(5) 1 calc PR A 2
H39D H 0.4353 0.3543 0.5177 0.043 Uiso 0.486(5) 1 calc PR A 2
C40B C 0.5160(5) 0.3259(6) 0.5403(4) 0.0487(19) Uani 0.486(5) 1 d P A 2
H40D H 0.5080 0.2745 0.5333 0.073 Uiso 0.486(5) 1 calc PR A 2
H40E H 0.5254 0.3354 0.5779 0.073 Uiso 0.486(5) 1 calc PR A 2
H40F H 0.5467 0.3393 0.5302 0.073 Uiso 0.486(5) 1 calc PR A 2
C41B C 0.3949(14) 0.405(3) 0.4217(15) 0.034(3) Uani 0.486(5) 1 d PD A 2
H41C H 0.3842 0.3997 0.3832 0.040 Uiso 0.486(5) 1 calc PR A 2
H41D H 0.3673 0.3800 0.4317 0.040 Uiso 0.486(5) 1 calc PR A 2
C42B C 0.392(4) 0.484(3) 0.433(3) 0.045(7) Uani 0.486(5) 1 d PD A 2
H42D H 0.4102 0.4936 0.4705 0.068 Uiso 0.486(5) 1 calc PR A 2
H42E H 0.3533 0.4987 0.4220 0.068 Uiso 0.486(5) 1 calc PR A 2
H42F H 0.4088 0.5126 0.4129 0.068 Uiso 0.486(5) 1 calc PR A 2
F1 F 0.60319(12) 0.67887(14) 0.34724(12) 0.0406(7) Uani 1 1 d . . .
F2 F 0.60471(13) 0.77282(17) 0.42020(13) 0.0519(8) Uani 1 1 d . . .
F3 F 0.51307(14) 0.84443(17) 0.41513(13) 0.0511(8) Uani 1 1 d . . .
F4 F 0.41819(14) 0.82030(16) 0.33259(13) 0.0502(8) Uani 1 1 d . . .
F5 F 0.41441(12) 0.72537(16) 0.25804(11) 0.0463(7) Uani 1 1 d . . .
F6 F 0.44041(12) 0.59557(17) 0.32385(12) 0.0462(7) Uani 1 1 d . . .
F7 F 0.35780(12) 0.50523(17) 0.30127(13) 0.0508(8) Uani 1 1 d . . .
F8 F 0.31511(13) 0.44115(16) 0.20474(15) 0.0566(9) Uani 1 1 d . . .
F9 F 0.36176(13) 0.46460(17) 0.13272(14) 0.0556(9) Uani 1 1 d . . .
F10 F 0.44851(12) 0.55066(15) 0.15565(12) 0.0426(7) Uani 1 1 d . . .
C55 C 0.5079(2) 0.6940(3) 0.29909(18) 0.0341(10) Uani 1 1 d . . .
C56 C 0.55473(19) 0.7111(3) 0.3408(2) 0.0362(10) Uani 1 1 d . . .
C57 C 0.5579(2) 0.7606(3) 0.3799(2) 0.0411(11) Uani 1 1 d . . .
C58 C 0.5115(2) 0.7974(3) 0.3771(2) 0.0401(11) Uani 1 1 d . . .
C59 C 0.4641(2) 0.7849(3) 0.3358(2) 0.0398(11) Uani 1 1 d . . .
C60 C 0.4630(2) 0.7352(3) 0.29777(19) 0.0378(11) Uani 1 1 d . . .
C61 C 0.44781(19) 0.5814(2) 0.2398(2) 0.0358(10) Uani 1 1 d . . .
C62 C 0.4235(2) 0.5649(3) 0.2758(2) 0.0387(11) Uani 1 1 d . . .
C63 C 0.3797(2) 0.5176(3) 0.2644(2) 0.0424(12) Uani 1 1 d . . .
C64 C 0.3586(2) 0.4846(3) 0.2167(2) 0.0424(12) Uani 1 1 d . . .
C65 C 0.3820(2) 0.4967(3) 0.1798(2) 0.0416(12) Uani 1 1 d . . .
C66 C 0.42648(19) 0.5428(2) 0.1932(2) 0.0364(10) Uani 1 1 d . . .
B1 B 0.5000 0.6374(4) 0.2500 0.0346(16) Uani 1 2 d S . .
Cl1 Cl 0.28407(15) 0.50818(17) 0.00262(12) 0.1336(11) Uani 1 1 d . . .
Cl2 Cl 0.2842(2) 0.6652(2) 0.00467(14) 0.182(2) Uani 1 1 d . . .
C67 C 0.3205(4) 0.5856(5) 0.0328(4) 0.104(3) Uani 1 1 d . . .
H67A H 0.3561 0.5860 0.0286 0.124 Uiso 1 1 calc R . .
H67B H 0.3274 0.5845 0.0709 0.124 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
P1 Au1 P1 178.13(6) 2_655 .
C25 P1 Si1 116.03(16) . .
C25 P1 Au1 125.64(15) . .
Si1 P1 Au1 117.91(6) . .
C49 Si1 C1 117.1(2) . .
C49 Si1 P1 121.75(16) . .
C1 Si1 P1 121.06(15) . .
C2 C1 C12 116.4(4) . .
C2 C1 Si1 121.5(3) . .
C12 C1 Si1 121.8(3) . .
C6 C2 C1 121.3(4) . .
C6 C2 C3 110.1(4) . .
C1 C2 C3 128.6(4) . .
C2 C3 C13 112.8(4) . .
C2 C3 C14 109.9(4) . .
C13 C3 C14 111.0(4) . .
C2 C3 C4 103.4(4) . .
C13 C3 C4 109.0(4) . .
C14 C3 C4 110.5(4) . .
C5 C4 C3 109.6(4) . .
C5 C4 H4A 109.8 . .
C3 C4 H4A 109.8 . .
C5 C4 H4B 109.8 . .
C3 C4 H4B 109.8 . .
H4A C4 H4B 108.2 . .
C6 C5 C15 110.9(4) . .
C6 C5 C4 102.4(4) . .
C15 C5 C4 111.4(4) . .
C6 C5 C17 113.2(4) . .
C15 C5 C17 111.3(4) . .
C4 C5 C17 107.3(4) . .
C7 C6 C2 120.4(4) . .
C7 C6 C5 126.2(4) . .
C2 C6 C5 113.3(4) . .
C8 C7 C6 119.3(4) . .
C8 C7 H7 120.3 . .
C6 C7 H7 120.3 . .
C7 C8 C12 121.2(4) . .
C7 C8 C9 126.3(4) . .
C12 C8 C9 112.5(4) . .
C8 C9 C19 110.1(4) . .
C8 C9 C10 101.0(4) . .
C19 C9 C10 112.6(4) . .
C8 C9 C21 112.4(4) . .
C19 C9 C21 110.6(4) . .
C10 C9 C21 109.9(4) . .
C9 C10 C11 108.7(4) . .
C9 C10 H10A 109.9 . .
C11 C10 H10A 109.9 . .
C9 C10 H10B 109.9 . .
C11 C10 H10B 109.9 . .
H10A C10 H10B 108.3 . .
C23 C11 C12 114.0(4) . .
C23 C11 C24 109.4(4) . .
C12 C11 C24 110.4(3) . .
C23 C11 C10 109.9(4) . .
C12 C11 C10 101.3(3) . .
C24 C11 C10 111.7(4) . .
C8 C12 C1 121.3(4) . .
C8 C12 C11 111.0(4) . .
C1 C12 C11 127.7(4) . .
C3 C13 H13A 109.5 . .
C3 C13 H13B 109.5 . .
H13A C13 H13B 109.5 . .
C3 C13 H13C 109.5 . .
H13A C13 H13C 109.5 . .
H13B C13 H13C 109.5 . .
C3 C14 H14A 109.5 . .
C3 C14 H14B 109.5 . .
H14A C14 H14B 109.5 . .
C3 C14 H14C 109.5 . .
H14A C14 H14C 109.5 . .
H14B C14 H14C 109.5 . .
C16 C15 C5 115.7(5) . .
C16 C15 H15A 108.3 . .
C5 C15 H15A 108.3 . .
C16 C15 H15B 108.3 . .
C5 C15 H15B 108.3 . .
H15A C15 H15B 107.4 . .
C15 C16 H16A 109.5 . .
C15 C16 H16B 109.5 . .
H16A C16 H16B 109.5 . .
C15 C16 H16C 109.5 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
C18 C17 C5 119.4(5) . .
C18 C17 H17A 107.5 . .
C5 C17 H17A 107.5 . .
C18 C17 H17B 107.5 . .
C5 C17 H17B 107.5 . .
H17A C17 H17B 107.0 . .
C17 C18 H18A 109.5 . .
C17 C18 H18B 109.5 . .
H18A C18 H18B 109.5 . .
C17 C18 H18C 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
C20 C19 C9 114.3(4) . .
C20 C19 H19A 108.7 . .
C9 C19 H19A 108.7 . .
C20 C19 H19B 108.7 . .
C9 C19 H19B 108.7 . .
H19A C19 H19B 107.6 . .
C19 C20 H20A 109.5 . .
C19 C20 H20B 109.5 . .
H20A C20 H20B 109.5 . .
C19 C20 H20C 109.5 . .
H20A C20 H20C 109.5 . .
H20B C20 H20C 109.5 . .
C22 C21 C9 115.8(4) . .
C22 C21 H21A 108.3 . .
C9 C21 H21A 108.3 . .
C22 C21 H21B 108.3 . .
C9 C21 H21B 108.3 . .
H21A C21 H21B 107.4 . .
C21 C22 H22A 109.5 . .
C21 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
C21 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
C11 C23 H23A 109.5 . .
C11 C23 H23B 109.5 . .
H23A C23 H23B 109.5 . .
C11 C23 H23C 109.5 . .
H23A C23 H23C 109.5 . .
H23B C23 H23C 109.5 . .
C11 C24 H24A 109.5 . .
C11 C24 H24B 109.5 . .
H24A C24 H24B 109.5 . .
C11 C24 H24C 109.5 . .
H24A C24 H24C 109.5 . .
H24B C24 H24C 109.5 . .
C26 C25 C36 118.3(4) . .
C26 C25 P1 120.6(3) . .
C36 C25 P1 121.0(3) . .
C30 C26 C25 119.7(4) . .
C30 C26 C27B 104.9(5) . .
C25 C26 C27B 135.4(5) . .
C30 C26 C27A 114.2(5) . .
C25 C26 C27A 125.0(5) . .
C31 C30 C26 120.9(4) . .
C31 C30 C29B 120.7(5) . .
C26 C30 C29B 118.3(5) . .
C31 C30 C29A 131.1(6) . .
C26 C30 C29A 107.6(5) . .
C32 C31 C30 119.2(4) . .
C32 C31 H31 120.4 . .
C30 C31 H31 120.4 . .
C31 C32 C36 121.8(4) . .
C31 C32 C33 124.8(4) . .
C36 C32 C33 113.3(4) . .
C32 C33 C45 110.2(4) . .
C32 C33 C43 110.1(4) . .
C45 C33 C43 110.5(4) . .
C32 C33 C34 102.3(4) . .
C45 C33 C34 110.8(4) . .
C43 C33 C34 112.6(4) . .
C33 C34 C35 110.4(4) . .
C33 C34 H34A 109.6 . .
C35 C34 H34A 109.6 . .
C33 C34 H34B 109.6 . .
C35 C34 H34B 109.6 . .
H34A C34 H34B 108.1 . .
C47 C35 C48 110.7(4) . .
C47 C35 C36 116.0(4) . .
C48 C35 C36 107.5(4) . .
C47 C35 C34 110.0(4) . .
C48 C35 C34 109.6(4) . .
C36 C35 C34 102.7(4) . .
C32 C36 C25 119.5(4) . .
C32 C36 C35 110.9(4) . .
C25 C36 C35 129.1(4) . .
C44 C43 C33 115.4(4) . .
C44 C43 H43A 108.4 . .
C33 C43 H43A 108.4 . .
C44 C43 H43B 108.4 . .
C33 C43 H43B 108.4 . .
H43A C43 H43B 107.5 . .
C43 C44 H44A 109.5 . .
C43 C44 H44B 109.5 . .
H44A C44 H44B 109.5 . .
C43 C44 H44C 109.5 . .
H44A C44 H44C 109.5 . .
H44B C44 H44C 109.5 . .
C46 C45 C33 115.6(4) . .
C46 C45 H45A 108.4 . .
C33 C45 H45A 108.4 . .
C46 C45 H45B 108.4 . .
C33 C45 H45B 108.4 . .
H45A C45 H45B 107.4 . .
C45 C46 H46A 109.5 . .
C45 C46 H46B 109.5 . .
H46A C46 H46B 109.5 . .
C45 C46 H46C 109.5 . .
H46A C46 H46C 109.5 . .
H46B C46 H46C 109.5 . .
C35 C47 H47A 109.5 . .
C35 C47 H47B 109.5 . .
H47A C47 H47B 109.5 . .
C35 C47 H47C 109.5 . .
H47A C47 H47C 109.5 . .
H47B C47 H47C 109.5 . .
C35 C48 H48A 109.5 . .
C35 C48 H48B 109.5 . .
H48A C48 H48B 109.5 . .
C35 C48 H48C 109.5 . .
H48A C48 H48C 109.5 . .
H48B C48 H48C 109.5 . .
C54 C49 C50 118.8(4) . .
C54 C49 Si1 122.8(4) . .
C50 C49 Si1 118.4(3) . .
C51 C50 C49 120.0(5) . .
C51 C50 H50 120.0 . .
C49 C50 H50 120.0 . .
C52 C51 C50 119.8(5) . .
C52 C51 H51 120.1 . .
C50 C51 H51 120.1 . .
C53 C52 C51 120.6(5) . .
C53 C52 H52 119.7 . .
C51 C52 H52 119.7 . .
C52 C53 C54 120.5(5) . .
C52 C53 H53 119.8 . .
C54 C53 H53 119.8 . .
C53 C54 C49 120.3(5) . .
C53 C54 H54 119.8 . .
C49 C54 H54 119.8 . .
C37A C27A C26 115.1(15) . .
C37A C27A C28A 114.3(14) . .
C26 C27A C28A 101.1(6) . .
C37A C27A C38A 98.1(8) . .
C26 C27A C38A 120.4(11) . .
C28A C27A C38A 108.5(11) . .
C29A C28A C27A 108.1(7) . .
C30 C29A C39A 106.4(13) . .
C30 C29A C41A 109(2) . .
C39A C29A C41A 113.6(17) . .
C30 C29A C28A 104.8(6) . .
C39A C29A C28A 109.7(12) . .
C41A C29A C28A 112.3(15) . .
C40A C39A C29A 115.3(8) . .
C42A C41A C29A 113(4) . .
C37B C27B C38B 120.4(10) . .
C37B C27B C28B 103.6(15) . .
C38B C27B C28B 112.0(13) . .
C37B C27B C26 115.1(17) . .
C38B C27B C26 99.0(11) . .
C28B C27B C26 106.2(6) . .
C27B C28B C29B 109.6(7) . .
C27B C28B H28C 109.8 . .
C29B C28B H28C 109.8 . .
C27B C28B H28D 109.8 . .
C29B C28B H28D 109.8 . .
H28C C28B H28D 108.2 . .
C30 C29B C39B 118.9(13) . .
C30 C29B C41B 107(3) . .
C39B C29B C41B 109.1(16) . .
C30 C29B C28B 100.1(6) . .
C39B C29B C28B 111.6(14) . .
C41B C29B C28B 109.5(19) . .
C27B C37B H37D 109.5 . .
C27B C37B H37E 109.5 . .
H37D C37B H37E 109.5 . .
C27B C37B H37F 109.5 . .
H37D C37B H37F 109.5 . .
H37E C37B H37F 109.5 . .
C27B C38B H38D 109.5 . .
C27B C38B H38E 109.5 . .
H38D C38B H38E 109.5 . .
C27B C38B H38F 109.5 . .
H38D C38B H38F 109.5 . .
H38E C38B H38F 109.5 . .
C40B C39B C29B 115.2(11) . .
C40B C39B H39C 108.5 . .
C29B C39B H39C 108.5 . .
C40B C39B H39D 108.5 . .
C29B C39B H39D 108.5 . .
H39C C39B H39D 107.5 . .
C39B C40B H40D 109.5 . .
C39B C40B H40E 109.5 . .
H40D C40B H40E 109.5 . .
C39B C40B H40F 109.5 . .
H40D C40B H40F 109.5 . .
H40E C40B H40F 109.5 . .
C42B C41B C29B 119(5) . .
C42B C41B H41C 107.6 . .
C29B C41B H41C 107.6 . .
C42B C41B H41D 107.6 . .
C29B C41B H41D 107.6 . .
H41C C41B H41D 107.0 . .
C41B C42B H42D 111.0 . .
C41B C42B H42E 109.5 . .
H42D C42B H42E 109.5 . .
C41B C42B H42F 109.5 . .
H42D C42B H42F 109.5 . .
H42E C42B H42F 108.0 . .
C56 C55 C60 113.1(4) . .
C56 C55 B1 128.5(4) . .
C60 C55 B1 118.2(4) . .
F1 C56 C55 121.5(4) . .
F1 C56 C57 113.7(4) . .
C55 C56 C57 124.7(5) . .
F2 C57 C58 119.8(5) . .
F2 C57 C56 121.3(5) . .
C58 C57 C56 118.9(5) . .
F3 C58 C59 120.4(5) . .
F3 C58 C57 120.2(5) . .
C59 C58 C57 119.4(5) . .
F4 C59 C58 120.0(4) . .
F4 C59 C60 120.4(5) . .
C58 C59 C60 119.6(5) . .
F5 C60 C59 116.2(4) . .
F5 C60 C55 119.5(4) . .
C59 C60 C55 124.2(5) . .
C66 C61 C62 113.5(4) . .
C66 C61 B1 120.3(4) . .
C62 C61 B1 126.1(4) . .
F6 C62 C61 121.5(4) . .
F6 C62 C63 115.5(4) . .
C61 C62 C63 123.0(5) . .
F7 C63 C64 120.1(5) . .
F7 C63 C62 119.4(5) . .
C64 C63 C62 120.5(4) . .
F8 C64 C63 120.9(5) . .
F8 C64 C65 119.7(5) . .
C63 C64 C65 119.4(4) . .
F9 C65 C64 120.1(4) . .
F9 C65 C66 121.7(5) . .
C64 C65 C66 118.2(5) . .
F10 C66 C61 119.7(4) . .
F10 C66 C65 115.2(4) . .
C61 C66 C65 125.1(4) . .
C55 B1 C55 101.3(5) . 2_655
C55 B1 C61 114.3(2) . 2_655
C55 B1 C61 112.2(2) 2_655 2_655
C55 B1 C61 112.2(2) . .
C55 B1 C61 114.3(2) 2_655 .
C61 B1 C61 103.0(5) 2_655 .
Cl1 C67 Cl2 111.1(6) . .
Cl1 C67 H67A 109.4 . .
Cl2 C67 H67A 109.4 . .
Cl1 C67 H67B 109.4 . .
Cl2 C67 H67B 109.4 . .
H67A C67 H67B 108.0 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Au1 P1 2.2806(13) 2_655
Au1 P1 2.2807(13) .
P1 C25 1.836(5) .
P1 Si1 2.0881(17) .
Si1 C49 1.855(5) .
Si1 C1 1.871(4) .
C1 C2 1.424(6) .
C1 C12 1.427(6) .
C2 C6 1.400(6) .
C2 C3 1.530(6) .
C3 C13 1.533(6) .
C3 C14 1.538(6) .
C3 C4 1.551(6) .
C4 C5 1.545(7) .
C4 H4A 0.9900 .
C4 H4B 0.9900 .
C5 C6 1.520(6) .
C5 C15 1.543(7) .
C5 C17 1.575(7) .
C6 C7 1.397(6) .
C7 C8 1.385(6) .
C7 H7 0.9500 .
C8 C12 1.389(6) .
C8 C9 1.524(6) .
C9 C19 1.526(6) .
C9 C10 1.546(7) .
C9 C21 1.561(6) .
C10 C11 1.555(6) .
C10 H10A 0.9900 .
C10 H10B 0.9900 .
C11 C23 1.518(6) .
C11 C12 1.528(6) .
C11 C24 1.540(6) .
C13 H13A 0.9800 .
C13 H13B 0.9800 .
C13 H13C 0.9800 .
C14 H14A 0.9800 .
C14 H14B 0.9800 .
C14 H14C 0.9800 .
C15 C16 1.509(9) .
C15 H15A 0.9900 .
C15 H15B 0.9900 .
C16 H16A 0.9800 .
C16 H16B 0.9800 .
C16 H16C 0.9800 .
C17 C18 1.458(9) .
C17 H17A 0.9900 .
C17 H17B 0.9900 .
C18 H18A 0.9800 .
C18 H18B 0.9800 .
C18 H18C 0.9800 .
C19 C20 1.523(7) .
C19 H19A 0.9900 .
C19 H19B 0.9900 .
C20 H20A 0.9800 .
C20 H20B 0.9800 .
C20 H20C 0.9800 .
C21 C22 1.513(7) .
C21 H21A 0.9900 .
C21 H21B 0.9900 .
C22 H22A 0.9800 .
C22 H22B 0.9800 .
C22 H22C 0.9800 .
C23 H23A 0.9800 .
C23 H23B 0.9800 .
C23 H23C 0.9800 .
C24 H24A 0.9800 .
C24 H24B 0.9800 .
C24 H24C 0.9800 .
C25 C26 1.411(6) .
C25 C36 1.430(6) .
C26 C30 1.406(7) .
C26 C27B 1.551(5) .
C26 C27A 1.552(5) .
C30 C31 1.395(6) .
C30 C29B 1.524(5) .
C30 C29A 1.534(5) .
C31 C32 1.376(6) .
C31 H31 0.9500 .
C32 C36 1.390(6) .
C32 C33 1.525(6) .
C33 C45 1.539(6) .
C33 C43 1.542(7) .
C33 C34 1.553(6) .
C34 C35 1.554(6) .
C34 H34A 0.9900 .
C34 H34B 0.9900 .
C35 C47 1.524(6) .
C35 C48 1.529(6) .
C35 C36 1.547(6) .
C43 C44 1.516(7) .
C43 H43A 0.9900 .
C43 H43B 0.9900 .
C44 H44A 0.9800 .
C44 H44B 0.9800 .
C44 H44C 0.9800 .
C45 C46 1.528(7) .
C45 H45A 0.9900 .
C45 H45B 0.9900 .
C46 H46A 0.9800 .
C46 H46B 0.9800 .
C46 H46C 0.9800 .
C47 H47A 0.9800 .
C47 H47B 0.9800 .
C47 H47C 0.9800 .
C48 H48A 0.9800 .
C48 H48B 0.9800 .
C48 H48C 0.9800 .
C49 C54 1.390(7) .
C49 C50 1.405(6) .
C50 C51 1.392(7) .
C50 H50 0.9500 .
C51 C52 1.380(8) .
C51 H51 0.9500 .
C52 C53 1.368(8) .
C52 H52 0.9500 .
C53 C54 1.385(7) .
C53 H53 0.9500 .
C54 H54 0.9500 .
C27A C37A 1.51(4) .
C27A C28A 1.552(5) .
C27A C38A 1.559(19) .
C28A C29A 1.551(5) .
C28A H28A 0.9900 .
C28A H28B 0.9900 .
C29A C39A 1.54(2) .
C29A C41A 1.548(5) .
C37A H37A 0.9800 .
C37A H37B 0.9800 .
C37A H37C 0.9800 .
C38A H38A 0.9800 .
C38A H38B 0.9800 .
C38A H38C 0.9800 .
C39A C40A 1.501(15) .
C39A H39A 0.9900 .
C39A H39B 0.9900 .
C40A H40A 0.9800 .
C40A H40B 0.9800 .
C40A H40C 0.9800 .
C41A C42A 1.533(5) .
C41A H41A 0.9900 .
C41A H41B 0.9900 .
C42A H42A 0.9800 .
C42A H42B 0.9800 .
C42A H42C 0.9800 .
C27B C37B 1.50(4) .
C27B C38B 1.53(2) .
C27B C28B 1.551(5) .
C28B C29B 1.552(5) .
C28B H28C 0.9900 .
C28B H28D 0.9900 .
C29B C39B 1.53(2) .
C29B C41B 1.548(5) .
C37B H37D 0.9800 .
C37B H37E 0.9800 .
C37B H37F 0.9800 .
C38B H38D 0.9800 .
C38B H38E 0.9800 .
C38B H38F 0.9800 .
C39B C40B 1.522(15) .
C39B H39C 0.9900 .
C39B H39D 0.9900 .
C40B H40D 0.9800 .
C40B H40E 0.9800 .
C40B H40F 0.9800 .
C41B C42B 1.506(5) .
C41B H41C 0.9900 .
C41B H41D 0.9900 .
C42B H42D 0.9800 .
C42B H42E 0.9800 .
C42B H42F 0.9800 .
F1 C56 1.367(5) .
F2 C57 1.338(6) .
F3 C58 1.346(6) .
F4 C59 1.356(6) .
F5 C60 1.355(6) .
F6 C62 1.348(6) .
F7 C63 1.355(5) .
F8 C64 1.342(5) .
F9 C65 1.338(6) .
F10 C66 1.363(5) .
C55 C56 1.375(7) .
C55 C60 1.402(7) .
C55 B1 1.655(7) .
C56 C57 1.389(7) .
C57 C58 1.383(7) .
C58 C59 1.363(7) .
C59 C60 1.381(7) .
C61 C66 1.387(7) .
C61 C62 1.394(6) .
C61 B1 1.668(7) .
C62 C63 1.395(7) .
C63 C64 1.360(8) .
C64 C65 1.385(7) .
C65 C66 1.390(7) .
B1 C55 1.656(7) 2_655
B1 C61 1.668(7) 2_655
Cl1 C67 1.756(9) .
Cl2 C67 1.774(11) .
C67 H67A 0.9900 .
C67 H67B 0.9900 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_4
C25 P1 Si1 C49 -5.2(2) .
Au1 P1 Si1 C49 -178.17(16) .
C25 P1 Si1 C1 178.6(2) .
Au1 P1 Si1 C1 5.60(19) .
C49 Si1 C1 C2 -88.0(4) .
P1 Si1 C1 C2 88.4(4) .
C49 Si1 C1 C12 85.4(4) .
P1 Si1 C1 C12 -98.2(3) .
C12 C1 C2 C6 -3.4(6) .
Si1 C1 C2 C6 170.3(3) .
C12 C1 C2 C3 176.5(4) .
Si1 C1 C2 C3 -9.8(6) .
C6 C2 C3 C13 -126.4(4) .
C1 C2 C3 C13 53.7(6) .
C6 C2 C3 C14 109.2(4) .
C1 C2 C3 C14 -70.7(6) .
C6 C2 C3 C4 -8.8(5) .
C1 C2 C3 C4 171.3(5) .
C2 C3 C4 C5 11.1(5) .
C13 C3 C4 C5 131.3(4) .
C14 C3 C4 C5 -106.4(5) .
C3 C4 C5 C6 -9.2(5) .
C3 C4 C5 C15 -127.7(5) .
C3 C4 C5 C17 110.2(4) .
C1 C2 C6 C7 0.7(7) .
C3 C2 C6 C7 -179.2(4) .
C1 C2 C6 C5 -176.8(4) .
C3 C2 C6 C5 3.3(5) .
C15 C5 C6 C7 -54.6(6) .
C4 C5 C6 C7 -173.6(4) .
C17 C5 C6 C7 71.2(6) .
C15 C5 C6 C2 122.6(5) .
C4 C5 C6 C2 3.7(5) .
C17 C5 C6 C2 -111.5(5) .
C2 C6 C7 C8 2.3(7) .
C5 C6 C7 C8 179.4(4) .
C6 C7 C8 C12 -2.4(7) .
C6 C7 C8 C9 179.4(4) .
C7 C8 C9 C19 45.8(6) .
C12 C8 C9 C19 -132.5(4) .
C7 C8 C9 C10 165.1(4) .
C12 C8 C9 C10 -13.3(5) .
C7 C8 C9 C21 -77.9(5) .
C12 C8 C9 C21 103.8(4) .
C8 C9 C10 C11 22.2(4) .
C19 C9 C10 C11 139.7(4) .
C21 C9 C10 C11 -96.6(4) .
C9 C10 C11 C23 -143.7(4) .
C9 C10 C11 C12 -22.8(4) .
C9 C10 C11 C24 94.7(4) .
C7 C8 C12 C1 -0.5(6) .
C9 C8 C12 C1 177.9(4) .
C7 C8 C12 C11 -179.3(4) .
C9 C8 C12 C11 -0.9(5) .
C2 C1 C12 C8 3.3(6) .
Si1 C1 C12 C8 -170.4(3) .
C2 C1 C12 C11 -178.1(4) .
Si1 C1 C12 C11 8.2(6) .
C23 C11 C12 C8 132.5(4) .
C24 C11 C12 C8 -103.9(4) .
C10 C11 C12 C8 14.6(4) .
C23 C11 C12 C1 -46.2(6) .
C24 C11 C12 C1 77.4(5) .
C10 C11 C12 C1 -164.1(4) .
C6 C5 C15 C16 -56.8(6) .
C4 C5 C15 C16 56.5(6) .
C17 C5 C15 C16 176.3(5) .
C6 C5 C17 C18 -67.2(6) .
C15 C5 C17 C18 58.4(6) .
C4 C5 C17 C18 -179.4(5) .
C8 C9 C19 C20 176.1(5) .
C10 C9 C19 C20 64.3(6) .
C21 C9 C19 C20 -59.1(6) .
C8 C9 C21 C22 70.3(5) .
C19 C9 C21 C22 -53.2(6) .
C10 C9 C21 C22 -178.1(4) .
Si1 P1 C25 C26 88.5(4) .
Au1 P1 C25 C26 -99.2(4) .
Si1 P1 C25 C36 -90.1(4) .
Au1 P1 C25 C36 82.2(4) .
C36 C25 C26 C30 7.6(7) .
P1 C25 C26 C30 -171.1(4) .
C36 C25 C26 C27B -173.5(13) .
P1 C25 C26 C27B 7.8(14) .
C36 C25 C26 C27A -159.9(10) .
P1 C25 C26 C27A 21.4(11) .
C25 C26 C30 C31 -1.5(7) .
C27B C26 C30 C31 179.3(10) .
C27A C26 C30 C31 167.3(9) .
C25 C26 C30 C29B 175.3(12) .
C27B C26 C30 C29B -3.8(16) .
C27A C26 C30 C29B -15.8(15) .
C25 C26 C30 C29A -175.2(11) .
C27B C26 C30 C29A 5.6(14) .
C27A C26 C30 C29A -6.4(14) .
C26 C30 C31 C32 -4.7(7) .
C29B C30 C31 C32 178.6(13) .
C29A C30 C31 C32 167.3(13) .
C30 C31 C32 C36 4.6(7) .
C30 C31 C32 C33 -173.4(4) .
C31 C32 C33 C45 54.6(6) .
C36 C32 C33 C45 -123.5(4) .
C31 C32 C33 C43 -67.6(6) .
C36 C32 C33 C43 114.3(4) .
C31 C32 C33 C34 172.5(4) .
C36 C32 C33 C34 -5.6(5) .
C32 C33 C34 C35 1.8(5) .
C45 C33 C34 C35 119.2(4) .
C43 C33 C34 C35 -116.4(4) .
C33 C34 C35 C47 126.1(4) .
C33 C34 C35 C48 -112.0(4) .
C33 C34 C35 C36 2.0(5) .
C31 C32 C36 C25 1.7(7) .
C33 C32 C36 C25 179.8(4) .
C31 C32 C36 C35 -170.8(4) .
C33 C32 C36 C35 7.4(5) .
C26 C25 C36 C32 -7.7(7) .
P1 C25 C36 C32 170.9(3) .
C26 C25 C36 C35 163.2(4) .
P1 C25 C36 C35 -18.2(7) .
C47 C35 C36 C32 -125.6(4) .
C48 C35 C36 C32 110.0(4) .
C34 C35 C36 C32 -5.6(5) .
C47 C35 C36 C25 62.9(6) .
C48 C35 C36 C25 -61.5(6) .
C34 C35 C36 C25 -177.1(4) .
C32 C33 C43 C44 -57.7(5) .
C45 C33 C43 C44 -179.6(4) .
C34 C33 C43 C44 55.8(5) .
C32 C33 C45 C46 174.1(5) .
C43 C33 C45 C46 -64.0(6) .
C34 C33 C45 C46 61.6(6) .
C1 Si1 C49 C54 -176.9(4) .
P1 Si1 C49 C54 6.7(4) .
C1 Si1 C49 C50 0.6(4) .
P1 Si1 C49 C50 -175.8(3) .
C54 C49 C50 C51 0.1(7) .
Si1 C49 C50 C51 -177.4(4) .
C49 C50 C51 C52 -0.5(7) .
C50 C51 C52 C53 0.1(7) .
C51 C52 C53 C54 0.5(8) .
C52 C53 C54 C49 -0.8(8) .
C50 C49 C54 C53 0.5(7) .
Si1 C49 C54 C53 178.0(4) .
C30 C26 C27A C37A 117.1(11) .
C25 C26 C27A C37A -74.8(16) .
C27B C26 C27A C37A 64(5) .
C30 C26 C27A C28A -6.6(14) .
C25 C26 C27A C28A 161.5(7) .
C27B C26 C27A C28A -59(4) .
C30 C26 C27A C38A -125.9(9) .
C25 C26 C27A C38A 42.2(16) .
C27B C26 C27A C38A -179(6) .
C37A C27A C28A C29A -107.4(14) .
C26 C27A C28A C29A 16.8(16) .
C38A C27A C28A C29A 144.4(12) .
C31 C30 C29A C39A 87.7(15) .
C26 C30 C29A C39A -99.5(7) .
C29B C30 C29A C39A 43(7) .
C31 C30 C29A C41A -35.5(18) .
C26 C30 C29A C41A 137.4(13) .
C29B C30 C29A C41A -80(7) .
C31 C30 C29A C28A -156.1(7) .
C26 C30 C29A C28A 16.7(16) .
C29B C30 C29A C28A 159(8) .
C27A C28A C29A C30 -21.1(18) .
C27A C28A C29A C39A 92.7(11) .
C27A C28A C29A C41A -140(2) .
C30 C29A C39A C40A -62.4(12) .
C41A C29A C39A C40A 58(2) .
C28A C29A C39A C40A -175.2(9) .
C30 C29A C41A C42A 179(3) .
C39A C29A C41A C42A 60(4) .
C28A C29A C41A C42A -65(4) .
C30 C26 C27B C37B 121.8(11) .
C25 C26 C27B C37B -57.2(19) .
C27A C26 C27B C37B -107(4) .
C30 C26 C27B C38B -108.5(7) .
C25 C26 C27B C38B 72.5(15) .
C27A C26 C27B C38B 23(4) .
C30 C26 C27B C28B 7.8(15) .
C25 C26 C27B C28B -171.2(7) .
C27A C26 C27B C28B 139(6) .
C37B C27B C28B C29B -130.9(16) .
C38B C27B C28B C29B 97.8(14) .
C26 C27B C28B C29B -9.3(19) .
C31 C30 C29B C39B 53.4(19) .
C26 C30 C29B C39B -123.4(9) .
C29A C30 C29B C39B -165(8) .
C31 C30 C29B C41B -70.7(17) .
C26 C30 C29B C41B 112.4(14) .
C29A C30 C29B C41B 71(8) .
C31 C30 C29B C28B 175.1(8) .
C26 C30 C29B C28B -1.8(19) .
C29A C30 C29B C28B -43(6) .
C27B C28B C29B C30 6.7(19) .
C27B C28B C29B C39B 133.4(12) .
C27B C28B C29B C41B -106(2) .
C30 C29B C39B C40B 49.9(16) .
C41B C29B C39B C40B 173(2) .
C28B C29B C39B C40B -65.8(13) .
C30 C29B C41B C42B -170(4) .
C39B C29B C41B C42B 60(4) .
C28B C29B C41B C42B -62(4) .
C60 C55 C56 F1 -177.1(4) .
B1 C55 C56 F1 -2.1(8) .
C60 C55 C56 C57 3.7(7) .
B1 C55 C56 C57 178.7(5) .
F1 C56 C57 F2 -1.4(7) .
C55 C56 C57 F2 177.9(4) .
F1 C56 C57 C58 179.1(4) .
C55 C56 C57 C58 -1.6(8) .
F2 C57 C58 F3 -1.1(7) .
C56 C57 C58 F3 178.4(4) .
F2 C57 C58 C59 179.6(5) .
C56 C57 C58 C59 -0.9(8) .
F3 C58 C59 F4 0.4(8) .
C57 C58 C59 F4 179.7(5) .
F3 C58 C59 C60 -178.5(5) .
C57 C58 C59 C60 0.8(8) .
F4 C59 C60 F5 0.7(7) .
C58 C59 C60 F5 179.6(4) .
F4 C59 C60 C55 -177.2(4) .
C58 C59 C60 C55 1.7(8) .
C56 C55 C60 F5 178.4(4) .
B1 C55 C60 F5 2.8(7) .
C56 C55 C60 C59 -3.8(7) .
B1 C55 C60 C59 -179.3(5) .
C66 C61 C62 F6 177.8(4) .
B1 C61 C62 F6 1.4(8) .
C66 C61 C62 C63 -3.9(7) .
B1 C61 C62 C63 179.7(5) .
F6 C62 C63 F7 -0.5(7) .
C61 C62 C63 F7 -179.0(4) .
F6 C62 C63 C64 178.7(4) .
C61 C62 C63 C64 0.2(8) .
F7 C63 C64 F8 1.7(7) .
C62 C63 C64 F8 -177.5(4) .
F7 C63 C64 C65 -178.8(4) .
C62 C63 C64 C65 2.1(8) .
F8 C64 C65 F9 -0.6(7) .
C63 C64 C65 F9 179.9(5) .
F8 C64 C65 C66 179.1(4) .
C63 C64 C65 C66 -0.5(7) .
C62 C61 C66 F10 -176.4(4) .
B1 C61 C66 F10 0.3(7) .
C62 C61 C66 C65 5.7(7) .
B1 C61 C66 C65 -177.7(5) .
F9 C65 C66 F10 -2.1(7) .
C64 C65 C66 F10 178.2(4) .
F9 C65 C66 C61 175.9(5) .
C64 C65 C66 C61 -3.7(8) .
C56 C55 B1 C55 -105.8(5) 2_655
C60 C55 B1 C55 69.0(4) 2_655
C56 C55 B1 C61 15.1(7) 2_655
C60 C55 B1 C61 -170.2(4) 2_655
C56 C55 B1 C61 131.9(5) .
C60 C55 B1 C61 -53.3(6) .
C66 C61 B1 C55 163.9(4) .
C62 C61 B1 C55 -19.9(7) .
C66 C61 B1 C55 49.3(6) 2_655
C62 C61 B1 C55 -134.5(5) 2_655
C66 C61 B1 C61 -72.7(4) 2_655
C62 C61 B1 C61 103.5(5) 2_655
