Information card for entry 4064860

Structure parameters

• Formula: C24 H50 O Os P2
• Calculated formula: C24 H50 O Os P2
• SMILES: [OsH3]([P](C(C)C)(C(C)C)C(C)C)([P](C(C)C)(C(C)C)C(C)C)Oc1ccccc1
• Title of publication: Preparation of Half-Sandwich Osmium Complexes by Deprotonation of Aromatic and Pro-aromatic Acids with a Hexahydride Brønsted Base
• Authors of publication: Esteruelas, Miguel A.; García-Raboso, Jorge; Oliván, Montserrat
• Journal of publication: Organometallics
• Year of publication: 2011
• Journal volume: 30
• Journal issue: 14
• Pages of publication: 3844
• a: 8.965 ± 0.003 Å
• b: 40.469 ± 0.011 Å
• c: 8.409 ± 0.002 Å
• α: 90°
• β: 115.301 ± 0.004°
• γ: 90°
• Cell volume: 2758.2 ± 1.4 ų
• Cell temperature: 120 ± 2 K
• Ambient diffraction temperature: 120 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0894
• Residual factor for significantly intense reflections: 0.0356
• Weighted residual factors for significantly intense reflections: 0.041
• Weighted residual factors for all reflections included in the refinement: 0.0482
• Goodness-of-fit parameter for all reflections included in the refinement: 0.675
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No