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Information card for entry 4065491
Preview
Coordinates | 4065491.cif |
---|---|
Original paper (by DOI) | HTML |
Chemical name | [{<i>η</i>^5^-1-[2-bis(diethylamino)diphosphane‒<i>κ</i>P] cyclopentadienyl}-\ (<i>η</i>^5^-cyclopentadienyl)-hydrido-tungsten(IV)] |
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Formula | C18 H30 N2 P2 W |
Calculated formula | C18 H30 N2 P2 W |
SMILES | [cH]12[cH]3[cH]4[cH]5[cH]1[WH]167892345[cH]2[cH]1[cH]6[cH]7[c]82P9P(N(CC)CC)N(CC)CC |
Title of publication | Reactions of Lithiated Diphosphanes R2P‒P(SiMe3)Li (R =tBu,iPr,iPr2N, Et2N) with [Cp2WCl2]. Syntheses and Structures of the First Terminal Phosphanylphosphido Complexes of Tungsten(IV) |
Authors of publication | Grubba, Rafał; Baranowska, Katarzyna; Gudat, Dietrich; Pikies, Jerzy |
Journal of publication | Organometallics |
Year of publication | 2011 |
Journal volume | 30 |
Journal issue | 24 |
Pages of publication | 6655 |
a | 16.323 ± 0.0007 Å |
b | 8.6258 ± 0.0003 Å |
c | 14.0541 ± 0.001 Å |
α | 90° |
β | 97.857 ± 0.005° |
γ | 90° |
Cell volume | 1960.23 ± 0.18 Å3 |
Cell temperature | 120 ± 2 K |
Ambient diffraction temperature | 120 ± 2 K |
Number of distinct elements | 5 |
Space group number | 14 |
Hermann-Mauguin space group symbol | P 1 21/c 1 |
Hall space group symbol | -P 2ybc |
Residual factor for all reflections | 0.0505 |
Residual factor for significantly intense reflections | 0.0356 |
Weighted residual factors for significantly intense reflections | 0.0815 |
Weighted residual factors for all reflections included in the refinement | 0.0861 |
Goodness-of-fit parameter for all reflections included in the refinement | 0.963 |
Diffraction radiation probe | x-ray |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/4065491.html
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Users of the data should acknowledge the original authors of the
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