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Information card for entry 4065492
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Coordinates | 4065492.cif |
---|---|
Original paper (by DOI) | HTML |
Chemical name | bis[{<i>η</i>^5^-(cyclopentadienylphosphane‒<i>κ^2^</i>P)-tungsten(IV)-\ (<i>η</i>^5^-cyclopentadienyl)] |
---|---|
Formula | C20 H18 P2 W2 |
Calculated formula | C20 H18 P2 W2 |
SMILES | [c]123P4[W]56789%10%113([cH]1[cH]5[cH]6[cH]27)([cH]1[cH]8[cH]9[cH]%10[cH]%111)P1[c]23[cH]5[cH]6[cH]7[cH]2[W]289%10413567[cH]1[cH]2[cH]8[cH]9[cH]%101 |
Title of publication | Reactions of Lithiated Diphosphanes R2P‒P(SiMe3)Li (R =tBu,iPr,iPr2N, Et2N) with [Cp2WCl2]. Syntheses and Structures of the First Terminal Phosphanylphosphido Complexes of Tungsten(IV) |
Authors of publication | Grubba, Rafał; Baranowska, Katarzyna; Gudat, Dietrich; Pikies, Jerzy |
Journal of publication | Organometallics |
Year of publication | 2011 |
Journal volume | 30 |
Journal issue | 24 |
Pages of publication | 6655 |
a | 13.361 ± 0.003 Å |
b | 7.6649 ± 0.0006 Å |
c | 16.3727 ± 0.0014 Å |
α | 90° |
β | 95.075 ± 0.015° |
γ | 90° |
Cell volume | 1670.2 ± 0.4 Å3 |
Cell temperature | 120 ± 2 K |
Ambient diffraction temperature | 120 ± 2 K |
Number of distinct elements | 4 |
Space group number | 15 |
Hermann-Mauguin space group symbol | C 1 2/c 1 |
Hall space group symbol | -C 2yc |
Residual factor for all reflections | 0.0544 |
Residual factor for significantly intense reflections | 0.0479 |
Weighted residual factors for significantly intense reflections | 0.1253 |
Weighted residual factors for all reflections included in the refinement | 0.1283 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.089 |
Diffraction radiation probe | x-ray |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/4065492.html
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