#------------------------------------------------------------------------------
#$Date: 2016-03-21 12:17:54 +0100 (lun 21 de mar de 2016) $
#$Revision: 178697 $
#$URL: svn://www.crystallography.net/cod/cif/4/08/08/4080831.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4080831
loop_
_publ_author_name
'Baquero, Edwin A.'
'Silbestri, Gustavo F.'
'Gómez-Sal, Pilar'
'Flores, Juan C.'
'de Jesús, Ernesto'
_publ_section_title
;
 Sulfonated Water-Soluble N-Heterocyclic Carbene Silver(I) Complexes:
 Behavior in Aqueous Medium and as NHC-Transfer Agents to Platinum(II)
;
_journal_issue                   9
_journal_name_full               Organometallics
_journal_page_first              2814
_journal_paper_doi               10.1021/om400228s
_journal_volume                  32
_journal_year                    2013
_chemical_compound_source        'synthesis as described'
_chemical_formula_sum            'C31 H49 Ag Cl N2 Na2 O8 S4'
_chemical_formula_weight         895.26
_chemical_name_common            Na[Ag(NHC)Cl].2SOMe2
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           'APEX2 v2010.9-1'
_cell_angle_alpha                90
_cell_angle_beta                 91.9910(10)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   10.2882(3)
_cell_length_b                   14.4724(4)
_cell_length_c                   31.0300(9)
_cell_measurement_temperature    296.(2)
_cell_volume                     4617.4(2)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      296.(2)
_diffrn_measured_fraction_theta_full 0.985
_diffrn_measured_fraction_theta_max 0.985
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0801
_diffrn_reflns_av_sigmaI/netI    0.0579
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       37
_diffrn_reflns_limit_l_min       -37
_diffrn_reflns_number            67891
_diffrn_reflns_theta_full        25.39
_diffrn_reflns_theta_max         25.39
_diffrn_reflns_theta_min         1.31
_exptl_absorpt_coefficient_mu    0.735
_exptl_absorpt_correction_T_max  0.93
_exptl_absorpt_correction_T_min  0.77
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            'clear pale yellow'
_exptl_crystal_density_diffrn    1.288
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prismatic
_exptl_crystal_F_000             1852
_exptl_crystal_size_max          0.370
_exptl_crystal_size_mid          0.180
_exptl_crystal_size_min          0.100
_refine_diff_density_max         1.353
_refine_diff_density_min         -0.969
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.132
_refine_ls_hydrogen_treatment    refxyz
_refine_ls_matrix_type           full
_refine_ls_number_parameters     487
_refine_ls_number_reflns         8389
_refine_ls_number_restraints     28
_refine_ls_restrained_S_all      1.131
_refine_ls_R_factor_all          0.1390
_refine_ls_R_factor_gt           0.0822
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1646P)²+5.8423P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2467
_refine_ls_wR_factor_ref         0.2975
_reflns_number_gt                4984
_reflns_number_total             8389
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om400228s_si_002.cif
_cod_data_source_block           3e
_cod_database_code               4080831
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag Ag1 0.33509(7) 0.14813(4) 0.758533(19) 0.0668(3) Uani d . 1.0 . .
C C1 0.2429(7) 0.0412(5) 0.7260(2) 0.0442(16) Uani d . 1.0 . .
C C2 0.1282(9) -0.0886(6) 0.7147(2) 0.065(2) Uani d . 1.0 . .
H H2 0.0798 -0.1415 0.7201 0.078 Uiso calc R 1.0 . .
C C3 0.1630(9) -0.0568(6) 0.6757(3) 0.064(2) Uani d . 1.0 . .
H H3 0.1429 -0.0832 0.649 0.077 Uiso calc R 1.0 . .
C C4 0.2807(8) 0.0834(5) 0.6509(2) 0.0467(18) Uani d . 1.0 . .
C C5 0.1965(8) 0.1543(5) 0.6364(2) 0.0501(18) Uani d . 1.0 . .
C C6 0.2413(8) 0.2140(5) 0.6045(2) 0.0545(19) Uani d . 1.0 . .
H H6 0.1885 0.2614 0.5937 0.065 Uiso calc R 1.0 . .
C C7 0.3640(8) 0.2016(5) 0.5893(2) 0.0507(18) Uani d . 1.0 . .
C C8 0.4469(8) 0.1318(5) 0.6044(3) 0.0551(19) Uani d . 1.0 . .
H H8 0.5303 0.1267 0.5939 0.066 Uiso calc R 1.0 . .
C C9 0.4049(8) 0.0699(5) 0.6351(2) 0.0489(18) Uani d . 1.0 . .
C C10 0.4908(8) -0.0091(6) 0.6511(3) 0.061(2) Uani d . 1.0 . .
H H10 0.4351 -0.0516 0.6667 0.073 Uiso calc R 1.0 . .
C C11 0.5508(16) -0.0630(11) 0.6164(5) 0.140(3) Uani d . 1.0 . .
H H11A 0.5351 -0.1277 0.6209 0.211 Uiso calc R 1.0 . .
H H11B 0.6428 -0.0518 0.617 0.211 Uiso calc R 1.0 . .
H H11C 0.5134 -0.0446 0.589 0.211 Uiso calc R 1.0 . .
C C12 0.5929(16) 0.0249(11) 0.6828(5) 0.140(3) Uani d . 1.0 . .
H H12A 0.6499 -0.0251 0.691 0.211 Uiso calc R 1.0 . .
H H12B 0.5521 0.0484 0.708 0.211 Uiso calc R 1.0 . .
H H12C 0.6422 0.0733 0.6699 0.211 Uiso calc R 1.0 . .
C C13 0.0612(10) 0.1682(7) 0.6537(3) 0.077(3) Uani d . 1.0 . .
H H13 0.0469 0.1206 0.6755 0.092 Uiso calc R 1.0 . .
C C14 0.0530(17) 0.2638(11) 0.6757(5) 0.140(3) Uani d . 1.0 . .
H H14A 0.1277 0.2724 0.6947 0.211 Uiso calc R 1.0 . .
H H14B -0.0246 0.2668 0.692 0.211 Uiso calc R 1.0 . .
H H14C 0.0507 0.3114 0.6542 0.211 Uiso calc R 1.0 . .
C C15 -0.0470(17) 0.1587(10) 0.6178(5) 0.140(3) Uani d . 1.0 . .
H H15A -0.0398 0.2085 0.5976 0.211 Uiso calc R 1.0 . .
H H15B -0.1306 0.161 0.6305 0.211 Uiso calc R 1.0 . .
H H15C -0.0373 0.1009 0.6032 0.211 Uiso calc R 1.0 . .
C C16 0.1576(7) -0.0353(5) 0.7907(2) 0.0450(17) Uani d . 1.0 . .
C C17 0.0461(8) 0.0069(5) 0.8062(2) 0.0512(18) Uani d . 1.0 . .
C C18 0.9710(7) 0.5021(5) 0.6498(2) 0.0510(18) Uani d . 1.0 . .
H H18 1.0439 0.5292 0.6382 0.061 Uiso calc R 1.0 . .
C C19 0.8812(7) 0.4574(5) 0.6227(2) 0.0421(16) Uani d . 1.0 . .
C C20 0.7713(7) 0.4180(5) 0.6386(2) 0.0497(18) Uani d . 1.0 . .
H H20 0.7114 0.3892 0.62 0.06 Uiso calc R 1.0 . .
C C21 0.2510(7) -0.0790(5) 0.8168(2) 0.0447(17) Uani d . 1.0 . .
C C22 -0.0540(10) 0.0571(7) 0.7783(3) 0.078(3) Uani d . 1.0 . .
H H22 -0.0269 0.0496 0.7485 0.093 Uiso calc R 1.0 . .
C C23 -0.1880(13) 0.0093(12) 0.7806(6) 0.153(7) Uani d . 1.0 . .
H H23A -0.2076 -0.0013 0.8102 0.23 Uiso calc R 1.0 . .
H H23B -0.1859 -0.0487 0.7656 0.23 Uiso calc R 1.0 . .
H H23C -0.2537 0.0482 0.7674 0.23 Uiso calc R 1.0 . .
C C24 -0.0510(16) 0.1596(8) 0.7873(5) 0.127(5) Uani d . 1.0 . .
H H24A 0.0351 0.1829 0.7831 0.19 Uiso calc R 1.0 . .
H H24B -0.0747 0.1706 0.8165 0.19 Uiso calc R 1.0 . .
H H24C -0.1115 0.1905 0.7679 0.19 Uiso calc R 1.0 . .
C C25 0.3716(8) -0.1266(6) 0.7991(3) 0.058(2) Uani d . 1.0 . .
H H25 0.3676 -0.1199 0.7677 0.07 Uiso calc R 1.0 . .
C C26 0.3714(12) -0.2303(8) 0.8095(4) 0.100(4) Uani d . 1.0 . .
H H26A 0.3915 -0.2391 0.8397 0.15 Uiso calc R 1.0 . .
H H26B 0.4356 -0.2609 0.7929 0.15 Uiso calc R 1.0 . .
H H26C 0.2872 -0.2556 0.8025 0.15 Uiso calc R 1.0 . .
C C27 0.4931(10) -0.0799(10) 0.8158(4) 0.116(5) Uani d . 1.0 . .
H H27A 0.4992 -0.0852 0.8467 0.174 Uiso calc R 1.0 . .
H H27B 0.4907 -0.0158 0.8079 0.174 Uiso calc R 1.0 . .
H H27C 0.5673 -0.1088 0.8036 0.174 Uiso calc R 1.0 . .
Cl Cl1 0.4383(5) 0.2619(3) 0.79843(11) 0.1489(18) Uani d . 1.0 . .
N N1 0.2335(6) 0.0219(4) 0.68349(17) 0.0477(15) Uani d . 1.0 . .
N N2 0.1776(6) -0.0286(4) 0.74444(16) 0.0465(15) Uani d . 1.0 . .
Na Na1 0.7844(3) 0.5318(3) 0.47591(10) 0.0687(9) Uani d . 1.0 . .
Na Na2 0.7114(5) 0.2941(3) 0.51771(13) 0.0910(12) Uani d . 1.0 A .
O O1 0.3308(9) 0.3471(7) 0.5423(4) 0.155(5) Uani d . 1.0 . .
O O2 0.4452(13) 0.2249(7) 0.5115(2) 0.144(4) Uani d . 1.0 . .
O O3 0.5452(8) 0.3140(7) 0.5657(3) 0.125(3) Uani d . 1.0 . .
O O4 1.0404(8) 0.4739(10) 0.5623(2) 0.170(6) Uani d . 1.0 . .
O O5 0.8190(8) 0.5073(6) 0.5460(2) 0.1083(19) Uani d . 1.0 A .
O O6 0.8882(11) 0.3567(5) 0.5551(2) 0.120(3) Uani d . 1.0 . .
O O9 1.018(3) 0.833(2) 0.5965(6) 0.224(17) Uani d P 0.5 . .
S S1 0.4233(2) 0.27908(16) 0.54903(7) 0.0632(6) Uani d . 1.0 A .
S S2 0.91138(19) 0.44836(15) 0.56688(6) 0.0533(5) Uani d . 1.0 A .
O O7 0.6820(8) 0.3926(7) 0.4585(2) 0.1083(19) Uani d . 1.0 A .
S S3A 0.6301(5) 0.3957(5) 0.41179(16) 0.094(3) Uani d P 0.637(14) A 1
C C29A 0.631(5) 0.283(2) 0.3982(12) 0.214(19) Uani d PU 0.637(14) A 1
C C28 0.4625(12) 0.4128(11) 0.4176(5) 0.124(4) Uani d . 1.0 A 1
S S3B 0.5954(8) 0.3360(7) 0.4256(3) 0.078(4) Uani d P 0.363(14) A 2
C C29B 0.683(4) 0.369(5) 0.3787(9) 0.16(2) Uani d PU 0.363(14) A 2
S S4A 0.7251(8) 0.0711(5) 0.4761(4) 0.077(4) Uani d PD 0.319(11) A 3
C C30 0.8387(19) -0.0043(13) 0.4629(7) 0.107(9) Uani d PDU 0.5 A 3
C C31 0.632(3) 0.008(2) 0.5080(11) 0.166(15) Uani d PDU 0.5 A 3
S S4B 0.781(3) 0.0604(13) 0.5043(6) 0.141(13) Uani d PD 0.181(11) A 4
O O8 0.7795(13) 0.1498(8) 0.5013(6) 0.102(6) Uani d P 0.5 . .
S S5 0.9499(9) 0.7909(8) 0.5821(3) 0.158(4) Uani d P 0.5 . .
C C32 0.947(3) 0.743(2) 0.5305(9) 0.124(4) Uani d P 0.5 . .
H H32A 1.0082 0.7741 0.5132 0.185 Uiso calc PR 0.5 . .
H H32B 0.861 0.7489 0.5176 0.185 Uiso calc PR 0.5 . .
H H32C 0.9691 0.6783 0.5325 0.185 Uiso calc PR 0.5 . .
C C33 0.822(2) 0.7351(17) 0.6053(7) 0.098(7) Uani d P 0.5 . .
H H33A 0.8334 0.7369 0.6362 0.148 Uiso calc PR 0.5 . .
H H33B 0.8189 0.672 0.5959 0.148 Uiso calc PR 0.5 . .
H H33C 0.7418 0.7654 0.597 0.148 Uiso calc PR 0.5 . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Na Na 0.0362 0.0249 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
C1 Ag1 Cl1 . . 176.6(2)
N1 C1 N2 . . 103.9(6)
N1 C1 Ag1 . . 130.7(5)
N2 C1 Ag1 . . 125.4(5)
C3 C2 N2 . . 106.6(7)
C2 C3 N1 . . 106.3(7)
C9 C4 C5 . . 123.3(6)
C9 C4 N1 . . 119.6(6)
C5 C4 N1 . . 117.1(7)
C6 C5 C4 . . 117.5(7)
C6 C5 C13 . . 119.6(7)
C4 C5 C13 . . 123.0(7)
C7 C6 C5 . . 119.3(7)
C6 C7 C8 . . 122.6(7)
C6 C7 S1 . . 119.6(6)
C8 C7 S1 . . 117.8(6)
C7 C8 C9 . . 119.8(8)
C8 C9 C4 . . 117.5(7)
C8 C9 C10 . . 121.3(7)
C4 C9 C10 . . 121.3(7)
C11 C10 C12 . . 110.5(11)
C11 C10 C9 . . 114.3(8)
C12 C10 C9 . . 110.8(8)
C5 C13 C14 . . 109.8(10)
C5 C13 C15 . . 112.2(9)
C14 C13 C15 . . 110.3(9)
C17 C16 C21 . . 123.7(6)
C17 C16 N2 . . 117.1(6)
C21 C16 N2 . . 119.1(6)
C18 C17 C16 2_646 . 116.9(7)
C18 C17 C22 2_646 . 118.9(7)
C16 C17 C22 . . 124.2(7)
C17 C18 C19 2_656 . 121.1(7)
C20 C19 C18 . . 121.0(6)
C20 C19 S2 . . 119.7(5)
C18 C19 S2 . . 119.3(5)
C19 C20 C21 . 2_656 120.3(7)
C16 C21 C20 . 2_646 117.1(7)
C16 C21 C25 . . 123.1(6)
C20 C21 C25 2_646 . 119.8(7)
C24 C22 C17 . . 110.9(9)
C24 C22 C23 . . 116.3(12)
C17 C22 C23 . . 110.5(9)
C27 C25 C21 . . 110.5(8)
C27 C25 C26 . . 112.0(10)
C21 C25 C26 . . 110.8(7)
C1 N1 C3 . . 111.4(6)
C1 N1 C4 . . 122.8(6)
C3 N1 C4 . . 125.4(6)
C1 N2 C2 . . 111.8(6)
C1 N2 C16 . . 123.8(6)
C2 N2 C16 . . 124.3(6)
O1 Na1 O4 3_666 3_766 109.9(5)
O1 Na1 O5 3_666 . 116.7(4)
O4 Na1 O5 3_766 . 114.6(4)
O1 Na1 O7 3_666 . 113.5(4)
O4 Na1 O7 3_766 . 102.5(4)
O5 Na1 O7 . . 98.4(3)
O1 Na1 S3A 3_666 . 94.6(4)
O4 Na1 S3A 3_766 . 92.3(3)
O5 Na1 S3A . . 125.0(3)
O7 Na1 S3A . . 26.9(2)
O1 Na1 S2 3_666 . 135.4(4)
O4 Na1 S2 3_766 . 98.1(3)
O5 Na1 S2 . . 19.6(2)
O7 Na1 S2 . . 92.6(2)
S3A Na1 S2 . . 118.85(17)
O1 Na1 Na2 3_666 . 135.4(3)
O4 Na1 Na2 3_766 . 109.3(4)
O5 Na1 Na2 . . 62.8(3)
O7 Na1 Na2 . . 36.35(18)
S3A Na1 Na2 . . 63.16(15)
S2 Na1 Na2 . . 56.49(9)
O8 Na2 O6 . . 103.3(5)
O8 Na2 O3 . . 119.9(5)
O6 Na2 O3 . . 102.4(3)
O8 Na2 O7 . . 114.7(6)
O6 Na2 O7 . . 103.5(3)
O3 Na2 O7 . . 110.5(3)
O8 Na2 O2 . . 88.0(4)
O6 Na2 O2 . . 152.8(3)
O3 Na2 O2 . . 51.3(3)
O7 Na2 O2 . . 93.6(3)
O8 Na2 S3B . . 94.9(5)
O6 Na2 S3B . . 130.8(3)
O3 Na2 S3B . . 107.2(3)
O7 Na2 S3B . . 29.1(3)
O2 Na2 S3B . . 71.2(3)
O8 Na2 S1 . . 107.9(4)
O6 Na2 S1 . . 127.2(3)
O3 Na2 S1 . . 24.8(2)
O7 Na2 S1 . . 100.8(3)
O2 Na2 S1 . . 26.81(18)
S3B Na2 S1 . . 87.8(2)
O8 Na2 S2 . . 121.6(4)
O6 Na2 S2 . . 18.8(2)
O3 Na2 S2 . . 94.5(2)
O7 Na2 S2 . . 90.7(3)
O2 Na2 S2 . . 144.6(2)
S3B Na2 S2 . . 119.7(2)
S1 Na2 S2 . . 118.13(13)
O8 Na2 Na1 . . 134.3(5)
O6 Na2 Na1 . . 69.6(2)
O3 Na2 Na1 . . 105.5(3)
O7 Na2 Na1 . . 36.2(2)
O2 Na2 Na1 . . 119.3(2)
S3B Na2 Na1 . . 65.2(2)
S1 Na2 Na1 . . 111.71(14)
S2 Na2 Na1 . . 54.79(9)
S1 O1 Na1 . 3_666 168.2(5)
S1 O2 Na2 . . 86.1(5)
S1 O3 Na2 . . 112.3(6)
S2 O4 Na1 . 3_766 148.3(6)
S2 O5 Na1 . . 128.8(5)
S2 O6 Na2 . . 129.1(7)
O1 S1 O2 . . 113.4(8)
O1 S1 O3 . . 113.2(7)
O2 S1 O3 . . 109.1(7)
O1 S1 C7 . . 107.5(4)
O2 S1 C7 . . 106.9(5)
O3 S1 C7 . . 106.5(4)
O1 S1 Na2 . . 123.6(3)
O2 S1 Na2 . . 67.1(5)
O3 S1 Na2 . . 42.9(4)
C7 S1 Na2 . . 126.9(3)
O4 S2 O6 . . 112.5(7)
O4 S2 O5 . . 114.9(7)
O6 S2 O5 . . 110.3(6)
O4 S2 C19 . . 106.3(4)
O6 S2 C19 . . 107.0(4)
O5 S2 C19 . . 105.3(4)
O4 S2 Na1 . . 99.6(5)
O6 S2 Na1 . . 93.7(4)
O5 S2 Na1 . . 31.7(3)
C19 S2 Na1 . . 137.0(2)
O4 S2 Na2 . . 134.5(5)
O6 S2 Na2 . . 32.2(5)
O5 S2 Na2 . . 78.6(4)
C19 S2 Na2 . . 111.5(3)
Na1 S2 Na2 . . 68.71(10)
S3A O7 S3B . . 39.0(4)
S3A O7 Na1 . . 109.6(5)
S3B O7 Na1 . . 148.0(6)
S3A O7 Na2 . . 142.6(7)
S3B O7 Na2 . . 104.4(6)
Na1 O7 Na2 . . 107.5(3)
O7 S3A C29A . . 101.8(12)
O7 S3A C28 . . 102.6(7)
C29A S3A C28 . . 100.1(19)
O7 S3A Na1 . . 43.5(4)
C29A S3A Na1 . . 138.5(12)
C28 S3A Na1 . . 108.5(6)
O7 S3B C29B . . 95.6(16)
O7 S3B Na2 . . 46.5(4)
C29B S3B Na2 . . 127.3(13)
O8 S4A C31 . . 108.7(15)
O8 S4A C30 . . 112.3(9)
C31 S4A C30 . . 102.2(15)
S4B O8 S4A . . 43.5(9)
S4B O8 Na2 . . 155.1(15)
S4A O8 Na2 . . 135.5(9)
O9 S5 C32 . . 129.3(15)
O9 S5 C33 . . 128.2(15)
C32 S5 C33 . . 101.9(13)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
Ag1 C1 . 2.061(7)
Ag1 Cl1 . 2.298(3)
C1 N1 . 1.347(8)
C1 N2 . 1.352(9)
C2 C3 . 1.355(11)
C2 N2 . 1.353(9)
C3 N1 . 1.367(10)
C4 C9 . 1.398(11)
C4 C5 . 1.407(10)
C4 N1 . 1.445(9)
C5 C6 . 1.403(10)
C5 C13 . 1.523(12)
C6 C7 . 1.374(11)
C7 C8 . 1.393(11)
C7 S1 . 1.802(7)
C8 C9 . 1.387(11)
C9 C10 . 1.517(11)
C10 C11 . 1.481(16)
C10 C12 . 1.498(18)
C13 C14 . 1.547(18)
C13 C15 . 1.552(19)
C16 C17 . 1.400(11)
C16 C21 . 1.388(10)
C16 N2 . 1.459(8)
C17 C18 2_646 1.383(10)
C17 C22 . 1.510(12)
C18 C17 2_656 1.383(10)
C18 C19 . 1.387(10)
C19 C20 . 1.373(10)
C19 S2 . 1.775(7)
C20 C21 2_656 1.409(9)
C21 C20 2_646 1.409(9)
C21 C25 . 1.537(11)
C22 C24 . 1.510(15)
C22 C23 . 1.546(17)
C25 C27 . 1.497(14)
C25 C26 . 1.535(13)
Na1 O1 3_666 2.179(8)
Na1 O4 3_766 2.193(8)
Na1 O5 . 2.221(7)
Na1 O7 . 2.327(11)
Na1 S3A . 3.184(7)
Na1 S2 . 3.298(4)
Na1 Na2 . 3.761(6)
Na2 O8 . 2.266(11)
Na2 O6 . 2.308(11)
Na2 O3 . 2.324(11)
Na2 O7 . 2.337(8)
Na2 O2 . 2.916(13)
Na2 S3B . 3.119(9)
Na2 S1 . 3.158(5)
Na2 S2 . 3.366(5)
O1 S1 . 1.381(8)
O1 Na1 3_666 2.179(8)
O2 S1 . 1.428(9)
O3 S1 . 1.431(8)
O4 S2 . 1.390(8)
O4 Na1 3_766 2.193(8)
O5 S2 . 1.416(8)
O6 S2 . 1.394(8)
O9 S5 . 1.02(2)
O7 S3A . 1.528(8)
O7 S3B . 1.565(11)
S3A C29A . 1.69(3)
S3A C28 . 1.758(14)
S3B C29B . 1.80(3)
S4A O8 . 1.480(15)
S4A C31 . 1.667(17)
S4A C30 . 1.661(16)
S4B O8 . 1.30(2)
S5 C32 . 1.75(3)
S5 C33 . 1.72(2)
