#------------------------------------------------------------------------------
#$Date: 2016-03-21 13:40:50 +0100 (lun 21 de mar de 2016) $
#$Revision: 178719 $
#$URL: svn://www.crystallography.net/cod/cif/4/08/30/4083026.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4083026
loop_
_publ_author_name
'Jiang, Yinyin'
'Zhu, Xi'
'Chen, Muzi'
'Wang, Yaorong'
'Yao, Yingming'
'Wu, Bing'
'Shen, Qi'
_publ_section_title
;
 Synthesis and Structural Characterization of Mixed-Valent Ytterbium and
 Europium Complexes Supported by a Phenoxy(quinolinyl)amide Ligand
;
_journal_issue                   8
_journal_name_full               Organometallics
_journal_page_first              1972
_journal_paper_doi               10.1021/om5000198
_journal_volume                  33
_journal_year                    2014
_chemical_formula_moiety         'C96 H112 N8 O4 Yb3, 6(C7 H8)'
_chemical_formula_sum            'C138 H160 N8 O4 Yb3'
_chemical_formula_weight         2513.86
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      15
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 105.884(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   27.873(2)
_cell_length_b                   14.3664(10)
_cell_length_c                   31.753(3)
_cell_measurement_reflns_used    26389
_cell_measurement_temperature    223(2)
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.0
_cell_volume                     12229.5(17)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure 3.7.0'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      223(2)
_diffrn_detector_area_resol_mean 14.63
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Rigaku Saturn'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71075
_diffrn_reflns_av_R_equivalents  0.0526
_diffrn_reflns_av_sigmaI/netI    0.0772
_diffrn_reflns_limit_h_max       36
_diffrn_reflns_limit_h_min       -35
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       41
_diffrn_reflns_limit_l_min       -35
_diffrn_reflns_number            34649
_diffrn_reflns_theta_full        27.49
_diffrn_reflns_theta_max         27.49
_diffrn_reflns_theta_min         3.04
_exptl_absorpt_coefficient_mu    2.331
_exptl_absorpt_correction_T_max  0.792
_exptl_absorpt_correction_T_min  0.492
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Jacobson, R. (1998) Private communication'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.365
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       platelet
_exptl_crystal_F_000             5144
_exptl_crystal_size_max          0.50
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.10
_refine_diff_density_max         1.172
_refine_diff_density_min         -1.220
_refine_diff_density_rms         0.120
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.133
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     680
_refine_ls_number_reflns         13947
_refine_ls_number_restraints     128
_refine_ls_restrained_S_all      1.135
_refine_ls_R_factor_all          0.1022
_refine_ls_R_factor_gt           0.0749
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0505P)²+63.7968P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1493
_refine_ls_wR_factor_ref         0.1660
_reflns_number_gt                10641
_reflns_number_total             13947
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            om5000198_si_002.cif
_cod_data_source_block           shelxl
_cod_depositor_comments
'Adding full bibliography for 4083026--4083029.cif.'
_cod_original_cell_volume        12229.8(16)
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               4083026
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Yb1 Yb 0.5000 0.69986(3) 0.2500 0.04179(13) Uani 1 2 d S . .
Yb2 Yb 0.5000 0.95222(3) 0.2500 0.04176(12) Uani 1 2 d S . .
Yb3 Yb 0.5000 1.20435(3) 0.2500 0.04134(13) Uani 1 2 d S . .
O1 O 0.46991(18) 0.8217(3) 0.20820(15) 0.0428(12) Uani 1 1 d . . .
O2 O 0.54092(18) 1.0834(3) 0.23432(16) 0.0444(12) Uani 1 1 d . . .
N1 N 0.4182(2) 0.6791(4) 0.24303(19) 0.0440(14) Uani 1 1 d . . .
N2 N 0.4876(2) 0.5917(4) 0.3035(2) 0.0499(15) Uani 1 1 d . . .
N3 N 0.4843(2) 1.2254(4) 0.17746(19) 0.0447(14) Uani 1 1 d . . .
N4 N 0.4337(2) 1.3134(4) 0.2246(2) 0.0476(15) Uani 1 1 d . . .
C1 C 0.4406(3) 0.7902(5) 0.1683(2) 0.0418(16) Uani 1 1 d . . .
C2 C 0.4553(3) 0.7997(5) 0.1295(2) 0.0470(18) Uani 1 1 d . . .
C3 C 0.4234(3) 0.7602(6) 0.0917(2) 0.055(2) Uani 1 1 d . . .
H3 H 0.4327 0.7653 0.0655 0.066 Uiso 1 1 calc R . .
C4 C 0.3793(3) 0.7142(6) 0.0901(3) 0.055(2) Uani 1 1 d . . .
C5 C 0.3662(3) 0.7064(6) 0.1290(3) 0.053(2) Uani 1 1 d . . .
H5 H 0.3366 0.6752 0.1292 0.064 Uiso 1 1 calc R . .
C6 C 0.3961(3) 0.7439(5) 0.1683(2) 0.0458(17) Uani 1 1 d . . .
C7 C 0.3802(3) 0.7313(6) 0.2096(2) 0.0500(18) Uani 1 1 d . . .
H7A H 0.3750 0.7924 0.2213 0.060 Uiso 1 1 calc R . .
H7B H 0.3485 0.6975 0.2028 0.060 Uiso 1 1 calc R . .
C8 C 0.4025(3) 0.6370(5) 0.2745(2) 0.0457(17) Uani 1 1 d . . .
C9 C 0.3550(3) 0.6383(6) 0.2815(3) 0.057(2) Uani 1 1 d . . .
H9 H 0.3298 0.6745 0.2630 0.068 Uiso 1 1 calc R . .
C10 C 0.3437(4) 0.5871(7) 0.3156(3) 0.074(3) Uani 1 1 d . . .
H10 H 0.3112 0.5901 0.3189 0.089 Uiso 1 1 calc R . .
C11 C 0.3781(4) 0.5340(7) 0.3434(3) 0.076(3) Uani 1 1 d . . .
H11 H 0.3691 0.4979 0.3648 0.091 Uiso 1 1 calc R . .
C12 C 0.4277(4) 0.5330(6) 0.3404(3) 0.061(2) Uani 1 1 d . . .
C13 C 0.4401(3) 0.5855(5) 0.3073(2) 0.0456(17) Uani 1 1 d . . .
C14 C 0.4680(4) 0.4841(6) 0.3686(3) 0.074(3) Uani 1 1 d . . .
H14 H 0.4619 0.4458 0.3906 0.089 Uiso 1 1 calc R . .
C15 C 0.5145(4) 0.4909(7) 0.3650(3) 0.071(3) Uani 1 1 d . . .
H15 H 0.5408 0.4589 0.3845 0.085 Uiso 1 1 calc R . .
C16 C 0.5234(3) 0.5452(6) 0.3322(3) 0.064(2) Uani 1 1 d . . .
H16 H 0.5562 0.5498 0.3300 0.077 Uiso 1 1 calc R . .
C17 C 0.5032(3) 0.8465(6) 0.1247(2) 0.0491(18) Uani 1 1 d . . .
C18 C 0.4899(4) 0.9154(7) 0.0868(3) 0.079(3) Uani 1 1 d . . .
H18A H 0.5199 0.9471 0.0846 0.118 Uiso 1 1 calc R . .
H18B H 0.4663 0.9607 0.0918 0.118 Uiso 1 1 calc R . .
H18C H 0.4751 0.8822 0.0597 0.118 Uiso 1 1 calc R . .
C19 C 0.5319(4) 0.9034(8) 0.1643(3) 0.090(4) Uani 1 1 d . . .
H19A H 0.5411 0.8636 0.1899 0.135 Uiso 1 1 calc R . .
H19B H 0.5111 0.9539 0.1694 0.135 Uiso 1 1 calc R . .
H19C H 0.5618 0.9288 0.1587 0.135 Uiso 1 1 calc R . .
C20 C 0.5379(4) 0.7724(7) 0.1151(4) 0.083(3) Uani 1 1 d . . .
H20A H 0.5668 0.8022 0.1095 0.124 Uiso 1 1 calc R . .
H20B H 0.5204 0.7368 0.0895 0.124 Uiso 1 1 calc R . .
H20C H 0.5487 0.7311 0.1400 0.124 Uiso 1 1 calc R . .
C21 C 0.3478(4) 0.6705(7) 0.0468(3) 0.067(2) Uani 1 1 d . . .
C22 C 0.3372(4) 0.7456(8) 0.0108(3) 0.096(4) Uani 1 1 d . . .
H22A H 0.3172 0.7191 -0.0164 0.145 Uiso 1 1 calc R . .
H22B H 0.3685 0.7681 0.0069 0.145 Uiso 1 1 calc R . .
H22C H 0.3193 0.7969 0.0194 0.145 Uiso 1 1 calc R . .
C23 C 0.3776(4) 0.5920(8) 0.0338(3) 0.088(3) Uani 1 1 d . . .
H23A H 0.3835 0.5435 0.0559 0.133 Uiso 1 1 calc R . .
H23B H 0.4093 0.6159 0.0315 0.133 Uiso 1 1 calc R . .
H23C H 0.3590 0.5664 0.0059 0.133 Uiso 1 1 calc R . .
C24 C 0.2984(4) 0.6340(8) 0.0506(3) 0.091(3) Uani 1 1 d . . .
H24A H 0.2794 0.6093 0.0226 0.137 Uiso 1 1 calc R . .
H24B H 0.2798 0.6842 0.0593 0.137 Uiso 1 1 calc R . .
H24C H 0.3041 0.5850 0.0725 0.137 Uiso 1 1 calc R . .
C25 C 0.5787(3) 1.1137(5) 0.2172(2) 0.0422(16) Uani 1 1 d . . .
C26 C 0.6294(3) 1.1035(5) 0.2407(3) 0.0483(18) Uani 1 1 d . A .
C27 C 0.6642(3) 1.1416(6) 0.2209(3) 0.058(2) Uani 1 1 d . . .
H27 H 0.6981 1.1361 0.2361 0.070 Uiso 1 1 calc R . .
C28 C 0.6526(3) 1.1866(6) 0.1807(3) 0.053(2) Uani 1 1 d . . .
C29 C 0.6024(3) 1.1946(6) 0.1593(3) 0.0510(19) Uani 1 1 d . . .
H29 H 0.5929 1.2250 0.1321 0.061 Uiso 1 1 calc R . .
C30 C 0.5656(3) 1.1594(5) 0.1764(2) 0.0435(17) Uani 1 1 d . . .
C31 C 0.5117(3) 1.1732(5) 0.1515(2) 0.0475(18) Uani 1 1 d . . .
H31A H 0.5100 1.2072 0.1244 0.057 Uiso 1 1 calc R . .
H31B H 0.4959 1.1124 0.1437 0.057 Uiso 1 1 calc R . .
C32 C 0.4423(3) 1.2709(5) 0.1541(2) 0.0458(17) Uani 1 1 d . . .
C33 C 0.4226(3) 1.2733(6) 0.1087(3) 0.057(2) Uani 1 1 d . . .
H33 H 0.4371 1.2377 0.0907 0.068 Uiso 1 1 calc R . .
C34 C 0.3809(3) 1.3293(7) 0.0903(3) 0.067(2) Uani 1 1 d . . .
H34 H 0.3688 1.3317 0.0597 0.080 Uiso 1 1 calc R . .
C35 C 0.3571(3) 1.3801(7) 0.1145(3) 0.075(3) Uani 1 1 d . . .
H35 H 0.3292 1.4165 0.1007 0.090 Uiso 1 1 calc R . .
C36 C 0.3748(3) 1.3777(6) 0.1603(3) 0.059(2) Uani 1 1 d . . .
C37 C 0.4165(3) 1.3223(5) 0.1797(3) 0.0486(19) Uani 1 1 d . . .
C38 C 0.3519(4) 1.4260(6) 0.1885(4) 0.074(3) Uani 1 1 d . . .
H38 H 0.3242 1.4643 0.1765 0.089 Uiso 1 1 calc R . .
C39 C 0.3694(4) 1.4179(6) 0.2324(4) 0.068(3) Uani 1 1 d . . .
H39 H 0.3544 1.4513 0.2509 0.082 Uiso 1 1 calc R . .
C40 C 0.4101(3) 1.3594(6) 0.2501(3) 0.063(2) Uani 1 1 d . . .
H40 H 0.4213 1.3519 0.2807 0.075 Uiso 1 1 calc R . .
C41 C 0.6493(3) 1.0596(5) 0.2866(3) 0.0531(19) Uani 1 1 d D . .
C42 C 0.6102(5) 1.0084(9) 0.3049(4) 0.077(4) Uiso 0.771(16) 1 d PD A 1
C43 C 0.6741(5) 1.1350(9) 0.3188(4) 0.079(4) Uiso 0.771(16) 1 d PD A 1
C44 C 0.6873(5) 0.9844(9) 0.2840(4) 0.075(4) Uiso 0.771(16) 1 d PD A 1
C42' C 0.6404(15) 1.123(2) 0.3214(10) 0.059(11) Uiso 0.229(16) 1 d PD A 2
C43' C 0.7062(7) 1.055(3) 0.2994(14) 0.075(14) Uiso 0.229(16) 1 d PD A 2
C44' C 0.6333(15) 0.9588(16) 0.2837(14) 0.068(13) Uiso 0.229(16) 1 d PD A 2
C45 C 0.6943(3) 1.2274(8) 0.1634(3) 0.074(3) Uani 1 1 d . . .
C46 C 0.6741(4) 1.2645(10) 0.1168(4) 0.103(4) Uani 1 1 d . . .
H46A H 0.6592 1.2138 0.0974 0.155 Uiso 1 1 calc R . .
H46B H 0.7011 1.2915 0.1071 0.155 Uiso 1 1 calc R . .
H46C H 0.6490 1.3117 0.1163 0.155 Uiso 1 1 calc R . .
C47 C 0.7329(4) 1.1518(10) 0.1628(4) 0.110(4) Uani 1 1 d . . .
H47A H 0.7485 1.1311 0.1925 0.164 Uiso 1 1 calc R . .
H47B H 0.7582 1.1769 0.1502 0.164 Uiso 1 1 calc R . .
H47C H 0.7166 1.0995 0.1454 0.164 Uiso 1 1 calc R . .
C48 C 0.7186(5) 1.3062(9) 0.1937(4) 0.119(5) Uani 1 1 d . . .
H48A H 0.6946 1.3558 0.1922 0.178 Uiso 1 1 calc R . .
H48B H 0.7469 1.3298 0.1848 0.178 Uiso 1 1 calc R . .
H48C H 0.7298 1.2832 0.2236 0.178 Uiso 1 1 calc R . .
C49 C 0.5531(6) 0.7061(12) 1.0083(8) 0.101(5) Uiso 0.60(2) 1 d PDU B 1
C50 C 0.5693(6) 0.7970(13) 1.0064(8) 0.095(5) Uiso 0.60(2) 1 d PDU B 1
C51 C 0.5366(7) 0.8674(11) 0.9860(8) 0.095(5) Uiso 0.60(2) 1 d PDU B 1
C52 C 0.4873(7) 0.8412(13) 0.9672(8) 0.096(5) Uiso 0.60(2) 1 d PDU B 1
C53 C 0.4706(6) 0.7506(14) 0.9687(9) 0.100(5) Uiso 0.60(2) 1 d PDU B 1
C54 C 0.5035(7) 0.6803(12) 0.9881(9) 0.103(5) Uiso 0.60(2) 1 d PDU B 1
C55 C 0.5882(9) 0.6309(16) 1.0316(8) 0.142(9) Uiso 0.60(2) 1 d PDU B 1
C49' C 0.5311(10) 0.6798(15) 0.9968(13) 0.107(7) Uiso 0.40(2) 1 d PDU B 2
C50' C 0.5673(9) 0.7495(19) 1.0085(13) 0.105(7) Uiso 0.40(2) 1 d PDU B 2
C51' C 0.5544(10) 0.8411(17) 0.9963(14) 0.105(7) Uiso 0.40(2) 1 d PDU B 2
C52' C 0.5055(11) 0.8662(16) 0.9746(13) 0.104(7) Uiso 0.40(2) 1 d PDU B 2
C53' C 0.4689(8) 0.7976(19) 0.9657(13) 0.102(7) Uiso 0.40(2) 1 d PDU B 2
C54' C 0.4820(9) 0.7060(17) 0.9771(13) 0.103(7) Uiso 0.40(2) 1 d PDU B 2
C55' C 0.5447(15) 0.5805(16) 1.0081(13) 0.138(11) Uiso 0.40(2) 1 d PDU B 2
C56 C 0.2536(7) 0.9264(12) 0.5598(5) 0.145(6) Uiso 0.647(19) 1 d PDU C 1
C57 C 0.2977(7) 0.8936(14) 0.5543(6) 0.143(6) Uiso 0.647(19) 1 d PDU C 1
C58 C 0.3407(7) 0.9501(14) 0.5635(7) 0.138(6) Uiso 0.647(19) 1 d PDU C 1
C59 C 0.3359(7) 1.0394(14) 0.5783(6) 0.132(6) Uiso 0.647(19) 1 d PDU C 1
C60 C 0.2911(7) 1.0718(12) 0.5838(7) 0.133(6) Uiso 0.647(19) 1 d PDU C 1
C61 C 0.2483(7) 1.0161(13) 0.5746(7) 0.136(6) Uiso 0.647(19) 1 d PDU C 1
C62 C 0.2088(8) 0.8673(17) 0.5502(8) 0.188(9) Uiso 0.647(19) 1 d PDU C 1
C56' C 0.2457(9) 0.8771(16) 0.5520(8) 0.119(8) Uiso 0.353(19) 1 d PDU C 2
C57' C 0.2943(9) 0.8944(19) 0.5524(10) 0.111(8) Uiso 0.353(19) 1 d PDU C 2
C58' C 0.3152(9) 0.9799(19) 0.5678(10) 0.102(8) Uiso 0.353(19) 1 d PDU C 2
C59' C 0.2856(10) 1.0436(18) 0.5820(9) 0.101(8) Uiso 0.353(19) 1 d PDU C 2
C60' C 0.2364(10) 1.0281(18) 0.5820(10) 0.106(8) Uiso 0.353(19) 1 d PDU C 2
C61' C 0.2168(9) 0.9422(18) 0.5666(9) 0.111(8) Uiso 0.353(19) 1 d PDU C 2
C62' C 0.2247(13) 0.7876(19) 0.5359(12) 0.158(12) Uiso 0.353(19) 1 d PDU C 2
C63 C 0.1971(15) 0.381(3) 0.1282(10) 0.123(8) Uiso 0.45(3) 1 d PDU D 1
C64 C 0.2158(14) 0.390(3) 0.0920(11) 0.123(8) Uiso 0.45(3) 1 d PDU D 1
C65 C 0.1958(13) 0.454(3) 0.0587(10) 0.124(8) Uiso 0.45(3) 1 d PDU D 1
C66 C 0.1535(14) 0.505(3) 0.0592(10) 0.119(8) Uiso 0.45(3) 1 d PDU D 1
C67 C 0.1346(11) 0.497(2) 0.0955(10) 0.116(8) Uiso 0.45(3) 1 d PDU D 1
C68 C 0.1573(12) 0.438(2) 0.1303(9) 0.115(8) Uiso 0.45(3) 1 d PDU D 1
C69 C 0.2219(13) 0.318(2) 0.1658(10) 0.136(11) Uiso 0.45(3) 1 d PDU D 1
C63' C 0.1853(12) 0.398(3) 0.1298(8) 0.123(7) Uiso 0.55(3) 1 d PDU D 2
C64' C 0.2177(11) 0.370(2) 0.1052(8) 0.120(7) Uiso 0.55(3) 1 d PDU D 2
C65' C 0.2138(10) 0.415(2) 0.0653(8) 0.118(7) Uiso 0.55(3) 1 d PDU D 2
C66' C 0.1782(11) 0.485(2) 0.0495(8) 0.121(7) Uiso 0.55(3) 1 d PDU D 2
C67' C 0.1436(11) 0.506(2) 0.0726(9) 0.121(7) Uiso 0.55(3) 1 d PDU D 2
C68' C 0.1483(10) 0.463(2) 0.1131(8) 0.119(7) Uiso 0.55(3) 1 d PDU D 2
C69' C 0.1938(11) 0.359(2) 0.1755(7) 0.142(10) Uiso 0.55(3) 1 d PDU D 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Yb Yb -0.3850 5.5486 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Yb1 O1 75.8(2) 2_655 .
O1 Yb1 N1 80.7(2) 2_655 2_655
O1 Yb1 N1 111.7(2) . 2_655
O1 Yb1 N1 111.7(2) 2_655 .
O1 Yb1 N1 80.7(2) . .
N1 Yb1 N1 164.8(3) 2_655 .
O1 Yb1 N2 146.3(2) 2_655 2_655
O1 Yb1 N2 101.1(2) . 2_655
N1 Yb1 N2 69.2(2) 2_655 2_655
N1 Yb1 N2 100.6(2) . 2_655
O1 Yb1 N2 101.1(2) 2_655 .
O1 Yb1 N2 146.3(2) . .
N1 Yb1 N2 100.6(2) 2_655 .
N1 Yb1 N2 69.2(2) . .
N2 Yb1 N2 99.1(3) 2_655 .
O1 Yb1 C1 26.20(18) 2_655 2_655
O1 Yb1 C1 101.97(19) . 2_655
N1 Yb1 C1 70.3(2) 2_655 2_655
N1 Yb1 C1 116.9(2) . 2_655
N2 Yb1 C1 138.5(2) 2_655 2_655
N2 Yb1 C1 79.5(2) . 2_655
O1 Yb1 C1 101.97(19) 2_655 .
O1 Yb1 C1 26.20(18) . .
N1 Yb1 C1 116.9(2) 2_655 .
N1 Yb1 C1 70.3(2) . .
N2 Yb1 C1 79.5(2) 2_655 .
N2 Yb1 C1 138.5(2) . .
C1 Yb1 C1 128.2(3) 2_655 .
O1 Yb1 C8 99.39(19) 2_655 2_655
O1 Yb1 C8 106.76(18) . 2_655
N1 Yb1 C8 21.3(2) 2_655 2_655
N1 Yb1 C8 148.9(2) . 2_655
N2 Yb1 C8 48.6(2) 2_655 2_655
N2 Yb1 C8 106.9(2) . 2_655
C1 Yb1 C8 91.6(2) 2_655 2_655
C1 Yb1 C8 102.81(19) . 2_655
O1 Yb1 C8 106.76(18) 2_655 .
O1 Yb1 C8 99.39(19) . .
N1 Yb1 C8 148.9(2) 2_655 .
N1 Yb1 C8 21.3(2) . .
N2 Yb1 C8 106.9(2) 2_655 .
N2 Yb1 C8 48.6(2) . .
C1 Yb1 C8 102.81(19) 2_655 .
C1 Yb1 C8 91.6(2) . .
C8 Yb1 C8 146.8(3) 2_655 .
O1 Yb1 Yb2 37.88(12) 2_655 .
O1 Yb1 Yb2 37.88(12) . .
N1 Yb1 Yb2 97.60(16) 2_655 .
N1 Yb1 Yb2 97.60(16) . .
N2 Yb1 Yb2 130.44(15) 2_655 .
N2 Yb1 Yb2 130.44(15) . .
C1 Yb1 Yb2 64.08(14) 2_655 .
C1 Yb1 Yb2 64.08(14) . .
C8 Yb1 Yb2 106.62(14) 2_655 .
C8 Yb1 Yb2 106.62(14) . .
O1 Yb2 O1 72.0(2) . 2_655
O1 Yb2 O2 130.89(16) . .
O1 Yb2 O2 131.01(17) 2_655 .
O1 Yb2 O2 131.01(17) . 2_655
O1 Yb2 O2 130.89(16) 2_655 2_655
O2 Yb2 O2 71.8(2) . 2_655
O1 Yb2 C19 99.8(3) . 2_655
O1 Yb2 C19 58.1(2) 2_655 2_655
O2 Yb2 C19 129.3(3) . 2_655
O2 Yb2 C19 74.1(2) 2_655 2_655
O1 Yb2 C42 75.5(3) . 2_655
O1 Yb2 C42 131.3(3) 2_655 2_655
O2 Yb2 C42 97.6(3) . 2_655
O2 Yb2 C42 57.1(3) 2_655 2_655
C19 Yb2 C42 94.1(3) 2_655 2_655
O1 Yb2 Yb3 144.00(11) . .
O1 Yb2 Yb3 144.00(11) 2_655 .
O2 Yb2 Yb3 35.89(11) . .
O2 Yb2 Yb3 35.89(11) 2_655 .
C19 Yb2 Yb3 102.8(2) 2_655 .
C42 Yb2 Yb3 75.3(2) 2_655 .
O1 Yb2 Yb1 36.00(11) . .
O1 Yb2 Yb1 36.00(11) 2_655 .
O2 Yb2 Yb1 144.11(11) . .
O2 Yb2 Yb1 144.11(11) 2_655 .
C19 Yb2 Yb1 77.2(2) 2_655 .
C42 Yb2 Yb1 104.7(2) 2_655 .
Yb3 Yb2 Yb1 180.0 . .
O2 Yb3 O2 76.3(2) . 2_655
O2 Yb3 N3 80.9(2) . .
O2 Yb3 N3 111.7(2) 2_655 .
O2 Yb3 N3 111.7(2) . 2_655
O2 Yb3 N3 80.9(2) 2_655 2_655
N3 Yb3 N3 164.5(3) . 2_655
O2 Yb3 N4 101.10(19) . 2_655
O2 Yb3 N4 147.1(2) 2_655 2_655
N3 Yb3 N4 100.0(2) . 2_655
N3 Yb3 N4 69.5(2) 2_655 2_655
O2 Yb3 N4 147.1(2) . .
O2 Yb3 N4 101.10(19) 2_655 .
N3 Yb3 N4 69.5(2) . .
N3 Yb3 N4 100.0(2) 2_655 .
N4 Yb3 N4 98.0(3) 2_655 .
O2 Yb3 C25 25.93(18) . .
O2 Yb3 C25 102.16(19) 2_655 .
N3 Yb3 C25 69.8(2) . .
N3 Yb3 C25 117.6(2) 2_655 .
N4 Yb3 C25 80.1(2) 2_655 .
N4 Yb3 C25 138.2(2) . .
O2 Yb3 C25 102.16(19) . 2_655
O2 Yb3 C25 25.93(18) 2_655 2_655
N3 Yb3 C25 117.6(2) . 2_655
N3 Yb3 C25 69.8(2) 2_655 2_655
N4 Yb3 C25 138.2(2) 2_655 2_655
N4 Yb3 C25 80.1(2) . 2_655
C25 Yb3 C25 128.1(3) . 2_655
O2 Yb3 C32 100.26(19) . .
O2 Yb3 C32 107.19(18) 2_655 .
N3 Yb3 C32 21.7(2) . .
N3 Yb3 C32 148.0(2) 2_655 .
N4 Yb3 C32 105.5(2) 2_655 .
N4 Yb3 C32 48.5(2) . .
C25 Yb3 C32 91.41(19) . .
C25 Yb3 C32 103.82(19) 2_655 .
O2 Yb3 C32 107.19(18) . 2_655
O2 Yb3 C32 100.26(19) 2_655 2_655
N3 Yb3 C32 148.0(2) . 2_655
N3 Yb3 C32 21.7(2) 2_655 2_655
N4 Yb3 C32 48.5(2) 2_655 2_655
N4 Yb3 C32 105.5(2) . 2_655
C25 Yb3 C32 103.82(19) . 2_655
C25 Yb3 C32 91.41(19) 2_655 2_655
C32 Yb3 C32 145.0(3) . 2_655
O2 Yb3 Yb2 38.13(12) . .
O2 Yb3 Yb2 38.13(12) 2_655 .
N3 Yb3 Yb2 97.73(16) . .
N3 Yb3 Yb2 97.73(16) 2_655 .
N4 Yb3 Yb2 131.01(15) 2_655 .
N4 Yb3 Yb2 131.01(15) . .
C25 Yb3 Yb2 64.04(14) . .
C25 Yb3 Yb2 64.04(14) 2_655 .
C32 Yb3 Yb2 107.52(14) . .
C32 Yb3 Yb2 107.52(14) 2_655 .
C1 O1 Yb1 108.8(4) . .
C1 O1 Yb2 145.1(4) . .
Yb1 O1 Yb2 106.11(18) . .
C25 O2 Yb3 109.7(4) . .
C25 O2 Yb2 144.2(4) . .
Yb3 O2 Yb2 105.98(18) . .
C8 N1 C7 116.6(6) . .
C8 N1 Yb1 121.0(5) . .
C7 N1 Yb1 120.6(4) . .
C16 N2 C13 117.9(7) . .
C16 N2 Yb1 125.8(6) . .
C13 N2 Yb1 116.0(5) . .
C32 N3 C31 116.0(6) . .
C32 N3 Yb3 121.1(5) . .
C31 N3 Yb3 121.4(4) . .
C40 N4 C37 119.1(7) . .
C40 N4 Yb3 125.4(6) . .
C37 N4 Yb3 115.3(5) . .
O1 C1 C6 117.1(6) . .
O1 C1 C2 121.9(6) . .
C6 C1 C2 121.0(7) . .
O1 C1 Yb1 45.0(3) . .
C6 C1 Yb1 94.3(4) . .
C2 C1 Yb1 125.5(5) . .
C3 C2 C1 116.0(7) . .
C3 C2 C17 117.2(7) . .
C1 C2 C17 126.8(7) . .
C4 C3 C2 125.0(7) . .
C4 C3 H3 117.5 . .
C2 C3 H3 117.5 . .
C3 C4 C5 116.9(7) . .
C3 C4 C21 120.6(8) . .
C5 C4 C21 122.4(8) . .
C4 C5 C6 121.6(8) . .
C4 C5 H5 119.2 . .
C6 C5 H5 119.2 . .
C5 C6 C1 119.4(7) . .
C5 C6 C7 118.9(7) . .
C1 C6 C7 121.7(7) . .
N1 C7 C6 111.3(6) . .
N1 C7 H7A 109.4 . .
C6 C7 H7A 109.4 . .
N1 C7 H7B 109.4 . .
C6 C7 H7B 109.4 . .
H7A C7 H7B 108.0 . .
N1 C8 C9 129.0(7) . .
N1 C8 C13 116.3(6) . .
C9 C8 C13 114.7(7) . .
N1 C8 Yb1 37.6(3) . .
C9 C8 Yb1 161.8(6) . .
C13 C8 Yb1 79.7(4) . .
C8 C9 C10 122.2(8) . .
C8 C9 H9 118.9 . .
C10 C9 H9 118.9 . .
C11 C10 C9 122.0(9) . .
C11 C10 H10 119.0 . .
C9 C10 H10 119.0 . .
C10 C11 C12 119.6(9) . .
C10 C11 H11 120.2 . .
C12 C11 H11 120.2 . .
C13 C12 C11 119.4(8) . .
C13 C12 C14 114.9(8) . .
C11 C12 C14 125.7(9) . .
N2 C13 C12 122.9(8) . .
N2 C13 C8 115.3(7) . .
C12 C13 C8 121.7(7) . .
C15 C14 C12 122.0(9) . .
C15 C14 H14 119.0 . .
C12 C14 H14 119.0 . .
C14 C15 C16 119.1(9) . .
C14 C15 H15 120.5 . .
C16 C15 H15 120.5 . .
N2 C16 C15 123.2(9) . .
N2 C16 H16 118.4 . .
C15 C16 H16 118.4 . .
C18 C17 C20 108.9(7) . .
C18 C17 C19 105.2(8) . .
C20 C17 C19 108.6(8) . .
C18 C17 C2 109.5(7) . .
C20 C17 C2 109.3(7) . .
C19 C17 C2 115.2(6) . .
C17 C18 H18A 109.5 . .
C17 C18 H18B 109.5 . .
H18A C18 H18B 109.5 . .
C17 C18 H18C 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
C17 C19 H19A 109.5 . .
C17 C19 H19B 109.5 . .
H19A C19 H19B 109.5 . .
C17 C19 H19C 109.5 . .
H19A C19 H19C 109.5 . .
H19B C19 H19C 109.5 . .
C17 C20 H20A 109.5 . .
C17 C20 H20B 109.5 . .
H20A C20 H20B 109.5 . .
C17 C20 H20C 109.5 . .
H20A C20 H20C 109.5 . .
H20B C20 H20C 109.5 . .
C24 C21 C23 109.9(9) . .
C24 C21 C22 108.0(9) . .
C23 C21 C22 109.1(8) . .
C24 C21 C4 112.2(8) . .
C23 C21 C4 108.8(8) . .
C22 C21 C4 108.8(8) . .
C21 C22 H22A 109.5 . .
C21 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
C21 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
C21 C23 H23A 109.5 . .
C21 C23 H23B 109.5 . .
H23A C23 H23B 109.5 . .
C21 C23 H23C 109.5 . .
H23A C23 H23C 109.5 . .
H23B C23 H23C 109.5 . .
C21 C24 H24A 109.5 . .
C21 C24 H24B 109.5 . .
H24A C24 H24B 109.5 . .
C21 C24 H24C 109.5 . .
H24A C24 H24C 109.5 . .
H24B C24 H24C 109.5 . .
O2 C25 C30 118.3(6) . .
O2 C25 C26 121.2(6) . .
C30 C25 C26 120.5(6) . .
O2 C25 Yb3 44.3(3) . .
C30 C25 Yb3 95.0(4) . .
C26 C25 Yb3 125.8(5) . .
C27 C26 C25 115.7(7) . .
C27 C26 C41 117.9(7) . .
C25 C26 C41 126.3(7) . .
C28 C27 C26 125.4(7) . .
C28 C27 H27 117.3 . .
C26 C27 H27 117.3 . .
C29 C28 C27 116.1(7) . .
C29 C28 C45 123.8(8) . .
C27 C28 C45 120.1(8) . .
C30 C29 C28 122.4(8) . .
C30 C29 H29 118.8 . .
C28 C29 H29 118.8 . .
C29 C30 C25 119.9(7) . .
C29 C30 C31 119.0(7) . .
C25 C30 C31 121.1(6) . .
N3 C31 C30 111.6(6) . .
N3 C31 H31A 109.3 . .
C30 C31 H31A 109.3 . .
N3 C31 H31B 109.3 . .
C30 C31 H31B 109.3 . .
H31A C31 H31B 108.0 . .
N3 C32 C33 127.4(7) . .
N3 C32 C37 115.4(7) . .
C33 C32 C37 117.3(7) . .
N3 C32 Yb3 37.2(3) . .
C33 C32 Yb3 161.8(6) . .
C37 C32 Yb3 79.2(4) . .
C32 C33 C34 119.4(8) . .
C32 C33 H33 120.3 . .
C34 C33 H33 120.3 . .
C35 C34 C33 123.4(9) . .
C35 C34 H34 118.3 . .
C33 C34 H34 118.3 . .
C34 C35 C36 119.1(9) . .
C34 C35 H35 120.5 . .
C36 C35 H35 120.5 . .
C35 C36 C37 118.8(8) . .
C35 C36 C38 123.6(8) . .
C37 C36 C38 117.6(8) . .
N4 C37 C36 121.1(8) . .
N4 C37 C32 117.0(7) . .
C36 C37 C32 121.9(8) . .
C39 C38 C36 120.9(9) . .
C39 C38 H38 119.6 . .
C36 C38 H38 119.6 . .
C38 C39 C40 119.4(9) . .
C38 C39 H39 120.3 . .
C40 C39 H39 120.3 . .
N4 C40 C39 121.9(9) . .
N4 C40 H40 119.1 . .
C39 C40 H40 119.1 . .
C42' C41 C44' 121(2) . .
C42' C41 C43 37.8(14) . .
C44' C41 C43 142.7(18) . .
C42' C41 C43' 101(2) . .
C44' C41 C43' 104(2) . .
C43 C41 C43' 66.6(18) . .
C42' C41 C44 136.2(16) . .
C44' C41 C44 61.2(17) . .
C43 C41 C44 110.2(9) . .
C43' C41 C44 45.7(17) . .
C42' C41 C26 110.8(15) . .
C44' C41 C26 108.2(17) . .
C43 C41 C26 108.8(8) . .
C43' C41 C26 110.5(18) . .
C44 C41 C26 108.4(7) . .
C42' C41 C42 74.8(17) . .
C44' C41 C42 48.9(16) . .
C43 C41 C42 108.7(9) . .
C43' C41 C42 131.6(18) . .
C44 C41 C42 104.7(8) . .
C26 C41 C42 115.9(7) . .
C48 C45 C46 109.6(10) . .
C48 C45 C28 108.0(8) . .
C46 C45 C28 111.5(8) . .
C48 C45 C47 110.0(9) . .
C46 C45 C47 108.0(9) . .
C28 C45 C47 109.7(9) . .
C45 C46 H46A 109.5 . .
C45 C46 H46B 109.5 . .
H46A C46 H46B 109.5 . .
C45 C46 H46C 109.5 . .
H46A C46 H46C 109.5 . .
H46B C46 H46C 109.5 . .
C45 C47 H47A 109.5 . .
C45 C47 H47B 109.5 . .
H47A C47 H47B 109.5 . .
C45 C47 H47C 109.5 . .
H47A C47 H47C 109.5 . .
H47B C47 H47C 109.5 . .
C45 C48 H48A 109.5 . .
C45 C48 H48B 109.5 . .
H48A C48 H48B 109.5 . .
C45 C48 H48C 109.5 . .
H48A C48 H48C 109.5 . .
H48B C48 H48C 109.5 . .
C50 C49 C54 121.3(12) . .
C50 C49 C55 121.3(12) . .
C54 C49 C55 117.3(12) . .
C49 C50 C51 121.5(13) . .
C52 C51 C50 116.4(13) . .
C53 C52 C51 122.7(14) . .
C52 C53 C54 120.7(13) . .
C53 C54 C49 117.2(13) . .
C54' C49' C50' 118.4(15) . .
C54' C49' C55' 121.3(14) . .
C50' C49' C55' 120.1(14) . .
C51' C50' C49' 119.4(16) . .
C50' C51' C52' 121.7(16) . .
C53' C52' C51' 118.6(16) . .
C54' C53' C52' 119.5(16) . .
C53' C54' C49' 122.0(16) . .
C57 C56 C61 122.7(14) . .
C57 C56 C62 121.1(13) . .
C61 C56 C62 116.2(13) . .
C56 C57 C58 121.2(16) . .
C59 C58 C57 116.5(15) . .
C58 C59 C60 121.9(16) . .
C59 C60 C61 121.8(14) . .
C56 C61 C60 116.0(14) . .
C57' C56' C61' 122.2(16) . .
C57' C56' C62' 117.8(14) . .
C61' C56' C62' 120.0(14) . .
C56' C57' C58' 118.7(17) . .
C59' C58' C57' 117.9(16) . .
C58' C59' C60' 124.7(18) . .
C61' C60' C59' 115.9(17) . .
C60' C61' C56' 120.5(17) . .
C64 C63 C68 118.0(15) . .
C64 C63 C69 121.1(14) . .
C68 C63 C69 120.7(14) . .
C63 C64 C65 121.9(17) . .
C64 C65 C66 120.1(16) . .
C67 C66 C65 117.9(16) . .
C68 C67 C66 121.2(15) . .
C63 C68 C67 120.5(16) . .
C68' C63' C64' 120.4(14) . .
C68' C63' C69' 121.4(13) . .
C64' C63' C69' 118.1(13) . .
C65' C64' C63' 118.0(15) . .
C64' C65' C66' 121.6(14) . .
C67' C66' C65' 119.4(15) . .
C66' C67' C68' 119.0(15) . .
C63' C68' C67' 121.3(15) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Yb1 O1 2.218(5) 2_655
Yb1 O1 2.218(5) .
Yb1 N1 2.250(6) 2_655
Yb1 N1 2.250(6) .
Yb1 N2 2.395(6) 2_655
Yb1 N2 2.395(6) .
Yb1 C1 2.968(7) 2_655
Yb1 C1 2.968(7) .
Yb1 C8 3.158(7) 2_655
Yb1 C8 3.158(7) .
Yb1 Yb2 3.6254(7) .
Yb2 O1 2.317(5) .
Yb2 O1 2.317(5) 2_655
Yb2 O2 2.327(5) .
Yb2 O2 2.327(5) 2_655
Yb2 C19 3.165(9) 2_655
Yb2 C42 3.192(13) 2_655
Yb2 Yb3 3.6223(7) .
Yb3 O2 2.209(5) .
Yb3 O2 2.209(5) 2_655
Yb3 N3 2.244(6) .
Yb3 N3 2.244(6) 2_655
Yb3 N4 2.388(6) 2_655
Yb3 N4 2.388(6) .
Yb3 C25 2.975(7) .
Yb3 C25 2.975(7) 2_655
Yb3 C32 3.177(8) .
Yb3 C32 3.177(8) 2_655
O1 C1 1.384(8) .
O2 C25 1.383(8) .
N1 C8 1.340(9) .
N1 C7 1.480(9) .
N2 C16 1.333(10) .
N2 C13 1.364(9) .
N3 C32 1.370(9) .
N3 C31 1.471(9) .
N4 C40 1.347(10) .
N4 C37 1.381(10) .
C1 C6 1.406(10) .
C1 C2 1.407(10) .
C2 C3 1.404(10) .
C2 C17 1.537(10) .
C3 C4 1.383(11) .
C3 H3 0.9400 .
C4 C5 1.387(11) .
C4 C21 1.547(11) .
C5 C6 1.403(10) .
C5 H5 0.9400 .
C6 C7 1.507(10) .
C7 H7A 0.9800 .
C7 H7B 0.9800 .
C8 C9 1.401(10) .
C8 C13 1.462(10) .
C9 C10 1.412(12) .
C9 H9 0.9400 .
C10 C11 1.349(13) .
C10 H10 0.9400 .
C11 C12 1.413(13) .
C11 H11 0.9400 .
C12 C13 1.412(11) .
C12 C14 1.417(13) .
C14 C15 1.336(13) .
C14 H14 0.9400 .
C15 C16 1.375(12) .
C15 H15 0.9400 .
C16 H16 0.9400 .
C17 C18 1.524(11) .
C17 C20 1.527(12) .
C17 C19 1.528(11) .
C18 H18A 0.9700 .
C18 H18B 0.9700 .
C18 H18C 0.9700 .
C19 H19A 0.9700 .
C19 H19B 0.9700 .
C19 H19C 0.9700 .
C20 H20A 0.9700 .
C20 H20B 0.9700 .
C20 H20C 0.9700 .
C21 C24 1.511(13) .
C21 C23 1.523(13) .
C21 C22 1.540(13) .
C22 H22A 0.9700 .
C22 H22B 0.9700 .
C22 H22C 0.9700 .
C23 H23A 0.9700 .
C23 H23B 0.9700 .
C23 H23C 0.9700 .
C24 H24A 0.9700 .
C24 H24B 0.9700 .
C24 H24C 0.9700 .
C25 C30 1.406(10) .
C25 C26 1.413(10) .
C26 C27 1.405(11) .
C26 C41 1.543(10) .
C27 C28 1.386(11) .
C27 H27 0.9400 .
C28 C29 1.385(11) .
C28 C45 1.531(11) .
C29 C30 1.382(10) .
C29 H29 0.9400 .
C30 C31 1.507(10) .
C31 H31A 0.9800 .
C31 H31B 0.9800 .
C32 C33 1.395(10) .
C32 C37 1.428(11) .
C33 C34 1.403(12) .
C33 H33 0.9400 .
C34 C35 1.355(13) .
C34 H34 0.9400 .
C35 C36 1.404(12) .
C35 H35 0.9400 .
C36 C37 1.405(11) .
C36 C38 1.414(12) .
C38 C39 1.351(14) .
C38 H38 0.9400 .
C39 C40 1.401(12) .
C39 H39 0.9400 .
C40 H40 0.9400 .
C41 C42' 1.506(18) .
C41 C44' 1.511(19) .
C41 C43 1.520(12) .
C41 C43' 1.525(19) .
C41 C44 1.529(12) .
C41 C42 1.555(12) .
C45 C48 1.520(14) .
C45 C46 1.529(14) .
C45 C47 1.534(15) .
C46 H46A 0.9700 .
C46 H46B 0.9700 .
C46 H46C 0.9700 .
C47 H47A 0.9700 .
C47 H47B 0.9700 .
C47 H47C 0.9700 .
C48 H48A 0.9700 .
C48 H48B 0.9700 .
C48 H48C 0.9700 .
C49 C50 1.388(9) .
C49 C54 1.406(10) .
C49 C55 1.508(13) .
C50 C51 1.397(9) .
C51 C52 1.392(9) .
C52 C53 1.387(10) .
C53 C54 1.389(9) .
C49' C54' 1.391(10) .
C49' C50' 1.397(10) .
C49' C55' 1.495(14) .
C50' C51' 1.391(10) .
C51' C52' 1.396(10) .
C52' C53' 1.391(10) .
C53' C54' 1.387(10) .
C56 C57 1.374(10) .
C56 C61 1.393(10) .
C56 C62 1.470(14) .
C57 C58 1.410(10) .
C58 C59 1.386(10) .
C59 C60 1.388(10) .
C60 C61 1.398(10) .
C56' C57' 1.374(10) .
C56' C61' 1.393(10) .
C56' C62' 1.447(15) .
C57' C58' 1.389(10) .
C58' C59' 1.387(10) .
C59' C60' 1.388(10) .
C60' C61' 1.383(10) .
C63 C64 1.389(10) .
C63 C68 1.393(10) .
C63 C69 1.509(14) .
C64 C65 1.390(10) .
C65 C66 1.400(10) .
C66 C67 1.399(10) .
C67 C68 1.394(10) .
C63' C68' 1.385(10) .
C63' C64' 1.404(10) .
C63' C69' 1.512(14) .
C64' C65' 1.398(10) .
C65' C66' 1.404(10) .
C66' C67' 1.395(10) .
C67' C68' 1.398(10) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O1 Yb1 Yb2 O1 180.000(1) 2_655 .
N1 Yb1 Yb2 O1 115.9(3) 2_655 .
N1 Yb1 Yb2 O1 -64.1(3) . .
N2 Yb1 Yb2 O1 46.8(3) 2_655 .
N2 Yb1 Yb2 O1 -133.2(3) . .
C1 Yb1 Yb2 O1 179.7(3) 2_655 .
C1 Yb1 Yb2 O1 -0.3(3) . .
C8 Yb1 Yb2 O1 96.1(2) 2_655 .
C8 Yb1 Yb2 O1 -83.9(2) . .
O1 Yb1 Yb2 O1 180.000(1) . 2_655
N1 Yb1 Yb2 O1 -64.1(3) 2_655 2_655
N1 Yb1 Yb2 O1 115.9(3) . 2_655
N2 Yb1 Yb2 O1 -133.2(3) 2_655 2_655
N2 Yb1 Yb2 O1 46.8(3) . 2_655
C1 Yb1 Yb2 O1 -0.3(3) 2_655 2_655
C1 Yb1 Yb2 O1 179.7(3) . 2_655
C8 Yb1 Yb2 O1 -83.9(2) 2_655 2_655
C8 Yb1 Yb2 O1 96.1(2) . 2_655
O1 Yb1 Yb2 O2 90.1(3) 2_655 .
O1 Yb1 Yb2 O2 -89.9(3) . .
N1 Yb1 Yb2 O2 26.0(3) 2_655 .
N1 Yb1 Yb2 O2 -154.0(3) . .
N2 Yb1 Yb2 O2 -43.0(3) 2_655 .
N2 Yb1 Yb2 O2 137.0(3) . .
C1 Yb1 Yb2 O2 89.8(3) 2_655 .
C1 Yb1 Yb2 O2 -90.2(3) . .
C8 Yb1 Yb2 O2 6.2(3) 2_655 .
C8 Yb1 Yb2 O2 -173.8(3) . .
O1 Yb1 Yb2 O2 -89.9(3) 2_655 2_655
O1 Yb1 Yb2 O2 90.1(3) . 2_655
N1 Yb1 Yb2 O2 -154.0(3) 2_655 2_655
N1 Yb1 Yb2 O2 26.0(3) . 2_655
N2 Yb1 Yb2 O2 137.0(3) 2_655 2_655
N2 Yb1 Yb2 O2 -43.0(3) . 2_655
C1 Yb1 Yb2 O2 -90.2(3) 2_655 2_655
C1 Yb1 Yb2 O2 89.8(3) . 2_655
C8 Yb1 Yb2 O2 -173.8(3) 2_655 2_655
C8 Yb1 Yb2 O2 6.2(3) . 2_655
O1 Yb1 Yb2 C19 -52.4(3) 2_655 2_655
O1 Yb1 Yb2 C19 127.6(3) . 2_655
N1 Yb1 Yb2 C19 -116.5(3) 2_655 2_655
N1 Yb1 Yb2 C19 63.5(3) . 2_655
N2 Yb1 Yb2 C19 174.4(3) 2_655 2_655
N2 Yb1 Yb2 C19 -5.6(3) . 2_655
C1 Yb1 Yb2 C19 -52.7(3) 2_655 2_655
C1 Yb1 Yb2 C19 127.3(3) . 2_655
C8 Yb1 Yb2 C19 -136.3(2) 2_655 2_655
C8 Yb1 Yb2 C19 43.7(2) . 2_655
O1 Yb1 Yb2 C42 -143.3(3) 2_655 2_655
O1 Yb1 Yb2 C42 36.7(3) . 2_655
N1 Yb1 Yb2 C42 152.6(3) 2_655 2_655
N1 Yb1 Yb2 C42 -27.4(3) . 2_655
N2 Yb1 Yb2 C42 83.5(3) 2_655 2_655
N2 Yb1 Yb2 C42 -96.5(3) . 2_655
C1 Yb1 Yb2 C42 -143.6(3) 2_655 2_655
C1 Yb1 Yb2 C42 36.4(3) . 2_655
C8 Yb1 Yb2 C42 132.8(3) 2_655 2_655
C8 Yb1 Yb2 C42 -47.2(3) . 2_655
O1 Yb1 Yb2 Yb3 -110(100) 2_655 .
O1 Yb1 Yb2 Yb3 70(100) . .
N1 Yb1 Yb2 Yb3 -175(100) 2_655 .
N1 Yb1 Yb2 Yb3 5(100) . .
N2 Yb1 Yb2 Yb3 116(100) 2_655 .
N2 Yb1 Yb2 Yb3 -64(100) . .
C1 Yb1 Yb2 Yb3 -111(100) 2_655 .
C1 Yb1 Yb2 Yb3 69(100) . .
C8 Yb1 Yb2 Yb3 166(100) 2_655 .
C8 Yb1 Yb2 Yb3 -14(100) . .
O1 Yb2 Yb3 O2 -89.9(3) . .
O1 Yb2 Yb3 O2 90.1(3) 2_655 .
O2 Yb2 Yb3 O2 180.0 2_655 .
C19 Yb2 Yb3 O2 142.5(3) 2_655 .
C42 Yb2 Yb3 O2 -126.6(3) 2_655 .
Yb1 Yb2 Yb3 O2 -159(100) . .
O1 Yb2 Yb3 O2 90.1(3) . 2_655
O1 Yb2 Yb3 O2 -89.9(3) 2_655 2_655
O2 Yb2 Yb3 O2 180.0 . 2_655
C19 Yb2 Yb3 O2 -37.5(3) 2_655 2_655
C42 Yb2 Yb3 O2 53.4(3) 2_655 2_655
Yb1 Yb2 Yb3 O2 21(100) . 2_655
O1 Yb2 Yb3 N3 -25.4(3) . .
O1 Yb2 Yb3 N3 154.6(3) 2_655 .
O2 Yb2 Yb3 N3 64.4(3) . .
O2 Yb2 Yb3 N3 -115.6(3) 2_655 .
C19 Yb2 Yb3 N3 -153.0(3) 2_655 .
C42 Yb2 Yb3 N3 -62.1(3) 2_655 .
Yb1 Yb2 Yb3 N3 -95(100) . .
O1 Yb2 Yb3 N3 154.6(3) . 2_655
O1 Yb2 Yb3 N3 -25.4(3) 2_655 2_655
O2 Yb2 Yb3 N3 -115.6(3) . 2_655
O2 Yb2 Yb3 N3 64.4(3) 2_655 2_655
C19 Yb2 Yb3 N3 27.0(3) 2_655 2_655
C42 Yb2 Yb3 N3 117.9(3) 2_655 2_655
Yb1 Yb2 Yb3 N3 85(100) . 2_655
O1 Yb2 Yb3 N4 -135.9(3) . 2_655
O1 Yb2 Yb3 N4 44.1(3) 2_655 2_655
O2 Yb2 Yb3 N4 -46.0(3) . 2_655
O2 Yb2 Yb3 N4 134.0(3) 2_655 2_655
C19 Yb2 Yb3 N4 96.5(3) 2_655 2_655
C42 Yb2 Yb3 N4 -172.6(3) 2_655 2_655
Yb1 Yb2 Yb3 N4 155(100) . 2_655
O1 Yb2 Yb3 N4 44.1(3) . .
O1 Yb2 Yb3 N4 -135.9(3) 2_655 .
O2 Yb2 Yb3 N4 134.0(3) . .
O2 Yb2 Yb3 N4 -46.0(3) 2_655 .
C19 Yb2 Yb3 N4 -83.5(3) 2_655 .
C42 Yb2 Yb3 N4 7.4(3) 2_655 .
Yb1 Yb2 Yb3 N4 -25(100) . .
O1 Yb2 Yb3 C25 -88.4(3) . .
O1 Yb2 Yb3 C25 91.6(3) 2_655 .
O2 Yb2 Yb3 C25 1.5(3) . .
O2 Yb2 Yb3 C25 -178.5(3) 2_655 .
C19 Yb2 Yb3 C25 144.0(3) 2_655 .
C42 Yb2 Yb3 C25 -125.1(3) 2_655 .
Yb1 Yb2 Yb3 C25 -158(100) . .
O1 Yb2 Yb3 C25 91.6(3) . 2_655
O1 Yb2 Yb3 C25 -88.4(3) 2_655 2_655
O2 Yb2 Yb3 C25 -178.5(3) . 2_655
O2 Yb2 Yb3 C25 1.5(3) 2_655 2_655
C19 Yb2 Yb3 C25 -36.0(3) 2_655 2_655
C42 Yb2 Yb3 C25 54.9(3) 2_655 2_655
Yb1 Yb2 Yb3 C25 22(100) . 2_655
O1 Yb2 Yb3 C32 -5.6(2) . .
O1 Yb2 Yb3 C32 174.4(2) 2_655 .
O2 Yb2 Yb3 C32 84.3(2) . .
O2 Yb2 Yb3 C32 -95.7(2) 2_655 .
C19 Yb2 Yb3 C32 -133.2(2) 2_655 .
C42 Yb2 Yb3 C32 -42.3(3) 2_655 .
Yb1 Yb2 Yb3 C32 -75(100) . .
O1 Yb2 Yb3 C32 174.4(2) . 2_655
O1 Yb2 Yb3 C32 -5.6(2) 2_655 2_655
O2 Yb2 Yb3 C32 -95.7(2) . 2_655
O2 Yb2 Yb3 C32 84.3(2) 2_655 2_655
C19 Yb2 Yb3 C32 46.8(2) 2_655 2_655
C42 Yb2 Yb3 C32 137.7(3) 2_655 2_655
Yb1 Yb2 Yb3 C32 105(100) . 2_655
O1 Yb1 O1 C1 -179.3(5) 2_655 .
N1 Yb1 O1 C1 107.0(4) 2_655 .
N1 Yb1 O1 C1 -63.9(4) . .
N2 Yb1 O1 C1 35.1(4) 2_655 .
N2 Yb1 O1 C1 -90.6(5) . .
C1 Yb1 O1 C1 -179.6(3) 2_655 .
C8 Yb1 O1 C1 85.0(4) 2_655 .
C8 Yb1 O1 C1 -74.3(4) . .
Yb2 Yb1 O1 C1 -179.3(5) . .
O1 Yb1 O1 Yb2 0.0 2_655 .
N1 Yb1 O1 Yb2 -73.7(2) 2_655 .
N1 Yb1 O1 Yb2 115.4(2) . .
N2 Yb1 O1 Yb2 -145.5(2) 2_655 .
N2 Yb1 O1 Yb2 88.7(4) . .
C1 Yb1 O1 Yb2 -0.3(2) 2_655 .
C1 Yb1 O1 Yb2 179.3(5) . .
C8 Yb1 O1 Yb2 -95.7(2) 2_655 .
C8 Yb1 O1 Yb2 105.0(2) . .
O1 Yb2 O1 C1 178.9(9) 2_655 .
O2 Yb2 O1 C1 -52.0(8) . .
O2 Yb2 O1 C1 49.8(8) 2_655 .
C19 Yb2 O1 C1 127.2(8) 2_655 .
C42 Yb2 O1 C1 35.5(8) 2_655 .
Yb3 Yb2 O1 C1 -1.1(9) . .
Yb1 Yb2 O1 C1 178.9(9) . .
O1 Yb2 O1 Yb1 0.0 2_655 .
O2 Yb2 O1 Yb1 129.2(2) . .
O2 Yb2 O1 Yb1 -129.0(2) 2_655 .
C19 Yb2 O1 Yb1 -51.6(2) 2_655 .
C42 Yb2 O1 Yb1 -143.3(3) 2_655 .
Yb3 Yb2 O1 Yb1 180.0 . .
O2 Yb3 O2 C25 177.0(5) 2_655 .
N3 Yb3 O2 C25 61.9(4) . .
N3 Yb3 O2 C25 -108.8(4) 2_655 .
N4 Yb3 O2 C25 -36.6(4) 2_655 .
N4 Yb3 O2 C25 87.7(5) . .
C25 Yb3 O2 C25 178.3(3) 2_655 .
C32 Yb3 O2 C25 71.6(4) . .
C32 Yb3 O2 C25 -86.3(4) 2_655 .
Yb2 Yb3 O2 C25 177.0(5) . .
O2 Yb3 O2 Yb2 0.0 2_655 .
N3 Yb3 O2 Yb2 -115.1(2) . .
N3 Yb3 O2 Yb2 74.2(2) 2_655 .
N4 Yb3 O2 Yb2 146.4(2) 2_655 .
N4 Yb3 O2 Yb2 -89.3(4) . .
C25 Yb3 O2 Yb2 -177.0(5) . .
C25 Yb3 O2 Yb2 1.3(2) 2_655 .
C32 Yb3 O2 Yb2 -105.4(2) . .
C32 Yb3 O2 Yb2 96.7(2) 2_655 .
O1 Yb2 O2 C25 -46.2(8) . .
O1 Yb2 O2 C25 56.0(8) 2_655 .
O2 Yb2 O2 C25 -175.2(9) 2_655 .
C19 Yb2 O2 C25 134.8(7) 2_655 .
C42 Yb2 O2 C25 -123.6(8) 2_655 .
Yb3 Yb2 O2 C25 -175.2(9) . .
Yb1 Yb2 O2 C25 4.8(9) . .
O1 Yb2 O2 Yb3 129.0(2) . .
O1 Yb2 O2 Yb3 -128.8(2) 2_655 .
O2 Yb2 O2 Yb3 0.0 2_655 .
C19 Yb2 O2 Yb3 -50.0(3) 2_655 .
C42 Yb2 O2 Yb3 51.6(3) 2_655 .
Yb1 Yb2 O2 Yb3 180.0 . .
O1 Yb1 N1 C8 -80.3(6) 2_655 .
O1 Yb1 N1 C8 -150.9(6) . .
N1 Yb1 N1 C8 63.2(5) 2_655 .
N2 Yb1 N1 C8 109.5(6) 2_655 .
N2 Yb1 N1 C8 13.7(5) . .
C1 Yb1 N1 C8 -52.1(6) 2_655 .
C1 Yb1 N1 C8 -175.8(6) . .
C8 Yb1 N1 C8 102.0(7) 2_655 .
Yb2 Yb1 N1 C8 -116.8(5) . .
O1 Yb1 N1 C7 84.2(5) 2_655 .
O1 Yb1 N1 C7 13.7(5) . .
N1 Yb1 N1 C7 -132.2(5) 2_655 .
N2 Yb1 N1 C7 -85.9(5) 2_655 .
N2 Yb1 N1 C7 178.3(6) . .
C1 Yb1 N1 C7 112.5(5) 2_655 .
C1 Yb1 N1 C7 -11.2(5) . .
C8 Yb1 N1 C7 -93.4(6) 2_655 .
C8 Yb1 N1 C7 164.6(9) . .
Yb2 Yb1 N1 C7 47.8(5) . .
O1 Yb1 N2 C16 -74.2(7) 2_655 .
O1 Yb1 N2 C16 -155.2(6) . .
N1 Yb1 N2 C16 8.2(7) 2_655 .
N1 Yb1 N2 C16 176.5(7) . .
N2 Yb1 N2 C16 78.6(7) 2_655 .
C1 Yb1 N2 C16 -59.3(7) 2_655 .
C1 Yb1 N2 C16 163.1(6) . .
C8 Yb1 N2 C16 29.2(7) 2_655 .
C8 Yb1 N2 C16 -176.9(8) . .
Yb2 Yb1 N2 C16 -101.4(7) . .
O1 Yb1 N2 C13 98.6(5) 2_655 .
O1 Yb1 N2 C13 17.6(7) . .
N1 Yb1 N2 C13 -178.9(5) 2_655 .
N1 Yb1 N2 C13 -10.7(5) . .
N2 Yb1 N2 C13 -108.6(6) 2_655 .
C1 Yb1 N2 C13 113.5(5) 2_655 .
C1 Yb1 N2 C13 -24.1(7) . .
C8 Yb1 N2 C13 -157.9(5) 2_655 .
C8 Yb1 N2 C13 -4.1(5) . .
Yb2 Yb1 N2 C13 71.4(6) . .
O2 Yb3 N3 C32 153.1(6) . .
O2 Yb3 N3 C32 81.9(6) 2_655 .
N3 Yb3 N3 C32 -61.2(5) 2_655 .
N4 Yb3 N3 C32 -107.1(6) 2_655 .
N4 Yb3 N3 C32 -12.2(5) . .
C25 Yb3 N3 C32 177.4(6) . .
C25 Yb3 N3 C32 54.1(6) 2_655 .
C32 Yb3 N3 C32 -98.9(7) 2_655 .
Yb2 Yb3 N3 C32 118.8(5) . .
O2 Yb3 N3 C31 -12.5(5) . .
O2 Yb3 N3 C31 -83.6(5) 2_655 .
N3 Yb3 N3 C31 133.2(5) 2_655 .
N4 Yb3 N3 C31 87.3(5) 2_655 .
N4 Yb3 N3 C31 -177.8(6) . .
C25 Yb3 N3 C31 11.8(5) . .
C25 Yb3 N3 C31 -111.5(5) 2_655 .
C32 Yb3 N3 C31 -165.6(9) . .
C32 Yb3 N3 C31 95.5(6) 2_655 .
Yb2 Yb3 N3 C31 -46.8(5) . .
O2 Yb3 N4 C40 155.2(6) . .
O2 Yb3 N4 C40 73.4(7) 2_655 .
N3 Yb3 N4 C40 -177.4(7) . .
N3 Yb3 N4 C40 -9.2(7) 2_655 .
N4 Yb3 N4 C40 -79.7(6) 2_655 .
C25 Yb3 N4 C40 -163.8(6) . .
C25 Yb3 N4 C40 58.0(6) 2_655 .
C32 Yb3 N4 C40 176.6(8) . .
C32 Yb3 N4 C40 -30.7(7) 2_655 .
Yb2 Yb3 N4 C40 100.3(6) . .
O2 Yb3 N4 C37 -19.1(7) . .
O2 Yb3 N4 C37 -100.9(5) 2_655 .
N3 Yb3 N4 C37 8.3(5) . .
N3 Yb3 N4 C37 176.5(5) 2_655 .
N4 Yb3 N4 C37 106.0(5) 2_655 .
C25 Yb3 N4 C37 21.9(7) . .
C25 Yb3 N4 C37 -116.3(5) 2_655 .
C32 Yb3 N4 C37 2.3(4) . .
C32 Yb3 N4 C37 155.0(5) 2_655 .
Yb2 Yb3 N4 C37 -74.0(5) . .
Yb1 O1 C1 C6 66.9(7) . .
Yb2 O1 C1 C6 -111.9(8) . .
Yb1 O1 C1 C2 -110.2(6) . .
Yb2 O1 C1 C2 71.0(10) . .
Yb2 O1 C1 Yb1 -178.8(9) . .
O1 Yb1 C1 O1 0.7(5) 2_655 .
N1 Yb1 C1 O1 -84.9(4) 2_655 .
N1 Yb1 C1 O1 109.7(5) . .
N2 Yb1 C1 O1 -144.9(4) 2_655 .
N2 Yb1 C1 O1 123.1(4) . .
C1 Yb1 C1 O1 0.5(4) 2_655 .
C8 Yb1 C1 O1 -102.0(4) 2_655 .
C8 Yb1 C1 O1 108.2(4) . .
Yb2 Yb1 C1 O1 0.5(4) . .
O1 Yb1 C1 C6 -124.1(4) 2_655 .
O1 Yb1 C1 C6 -124.8(7) . .
N1 Yb1 C1 C6 150.4(4) 2_655 .
N1 Yb1 C1 C6 -15.0(4) . .
N2 Yb1 C1 C6 90.3(5) 2_655 .
N2 Yb1 C1 C6 -1.7(6) . .
C1 Yb1 C1 C6 -124.3(5) 2_655 .
C8 Yb1 C1 C6 133.3(4) 2_655 .
C8 Yb1 C1 C6 -16.6(5) . .
Yb2 Yb1 C1 C6 -124.3(5) . .
O1 Yb1 C1 C2 102.5(6) 2_655 .
O1 Yb1 C1 C2 101.8(8) . .
N1 Yb1 C1 C2 17.0(7) 2_655 .
N1 Yb1 C1 C2 -148.4(7) . .
N2 Yb1 C1 C2 -43.1(6) 2_655 .
N2 Yb1 C1 C2 -135.1(6) . .
C1 Yb1 C1 C2 102.3(6) 2_655 .
C8 Yb1 C1 C2 -0.2(6) 2_655 .
C8 Yb1 C1 C2 -150.0(6) . .
Yb2 Yb1 C1 C2 102.3(6) . .
O1 C1 C2 C3 176.6(7) . .
C6 C1 C2 C3 -0.4(11) . .
Yb1 C1 C2 C3 122.0(7) . .
O1 C1 C2 C17 -1.7(12) . .
C6 C1 C2 C17 -178.7(7) . .
Yb1 C1 C2 C17 -56.4(10) . .
C1 C2 C3 C4 0.5(12) . .
C17 C2 C3 C4 179.0(8) . .
C2 C3 C4 C5 -0.6(13) . .
C2 C3 C4 C21 -178.0(8) . .
C3 C4 C5 C6 0.5(12) . .
C21 C4 C5 C6 177.9(8) . .
C4 C5 C6 C1 -0.4(12) . .
C4 C5 C6 C7 -178.8(7) . .
O1 C1 C6 C5 -176.8(7) . .
C2 C1 C6 C5 0.3(11) . .
Yb1 C1 C6 C5 -136.0(6) . .
O1 C1 C6 C7 1.6(10) . .
C2 C1 C6 C7 178.7(7) . .
Yb1 C1 C6 C7 42.3(7) . .
C8 N1 C7 C6 -158.5(7) . .
Yb1 N1 C7 C6 36.2(8) . .
C5 C6 C7 N1 119.4(8) . .
C1 C6 C7 N1 -59.0(10) . .
C7 N1 C8 C9 -3.0(12) . .
Yb1 N1 C8 C9 162.2(7) . .
C7 N1 C8 C13 179.8(6) . .
Yb1 N1 C8 C13 -15.0(9) . .
C7 N1 C8 Yb1 -165.2(9) . .
O1 Yb1 C8 N1 107.0(6) 2_655 .
O1 Yb1 C8 N1 29.1(6) . .
N1 Yb1 C8 N1 -153.1(6) 2_655 .
N2 Yb1 C8 N1 -75.6(6) 2_655 .
N2 Yb1 C8 N1 -162.9(7) . .
C1 Yb1 C8 N1 133.8(6) 2_655 .
C1 Yb1 C8 N1 4.0(6) . .
C8 Yb1 C8 N1 -112.6(6) 2_655 .
Yb2 Yb1 C8 N1 67.4(6) . .
O1 Yb1 C8 C9 57.4(18) 2_655 .
O1 Yb1 C8 C9 -20.4(18) . .
N1 Yb1 C8 C9 157.4(16) 2_655 .
N1 Yb1 C8 C9 -49.5(16) . .
N2 Yb1 C8 C9 -125.1(17) 2_655 .
N2 Yb1 C8 C9 147.6(18) . .
C1 Yb1 C8 C9 84.3(17) 2_655 .
C1 Yb1 C8 C9 -45.6(17) . .
C8 Yb1 C8 C9 -162.2(18) 2_655 .
Yb2 Yb1 C8 C9 17.8(18) . .
O1 Yb1 C8 C13 -86.6(4) 2_655 .
O1 Yb1 C8 C13 -164.5(4) . .
N1 Yb1 C8 C13 13.3(6) 2_655 .
N1 Yb1 C8 C13 166.4(8) . .
N2 Yb1 C8 C13 90.8(4) 2_655 .
N2 Yb1 C8 C13 3.5(4) . .
C1 Yb1 C8 C13 -59.8(4) 2_655 .
C1 Yb1 C8 C13 170.3(4) . .
C8 Yb1 C8 C13 53.7(4) 2_655 .
Yb2 Yb1 C8 C13 -126.3(4) . .
N1 C8 C9 C10 177.6(8) . .
C13 C8 C9 C10 -5.2(12) . .
Yb1 C8 C9 C10 -145.7(14) . .
C8 C9 C10 C11 0.2(15) . .
C9 C10 C11 C12 3.6(16) . .
C10 C11 C12 C13 -2.0(14) . .
C10 C11 C12 C14 176.9(10) . .
C16 N2 C13 C12 0.6(11) . .
Yb1 N2 C13 C12 -172.8(6) . .
C16 N2 C13 C8 -179.3(7) . .
Yb1 N2 C13 C8 7.3(8) . .
C11 C12 C13 N2 176.8(8) . .
C14 C12 C13 N2 -2.2(12) . .
C11 C12 C13 C8 -3.3(12) . .
C14 C12 C13 C8 177.7(7) . .
N1 C8 C13 N2 4.2(10) . .
C9 C8 C13 N2 -173.4(7) . .
Yb1 C8 C13 N2 -5.1(6) . .
N1 C8 C13 C12 -175.7(7) . .
C9 C8 C13 C12 6.7(11) . .
Yb1 C8 C13 C12 175.0(7) . .
C13 C12 C14 C15 2.6(14) . .
C11 C12 C14 C15 -176.3(10) . .
C12 C14 C15 C16 -1.4(16) . .
C13 N2 C16 C15 0.8(13) . .
Yb1 N2 C16 C15 173.5(7) . .
C14 C15 C16 N2 -0.4(15) . .
C3 C2 C17 C18 51.3(10) . .
C1 C2 C17 C18 -130.4(8) . .
C3 C2 C17 C20 -67.9(9) . .
C1 C2 C17 C20 110.5(9) . .
C3 C2 C17 C19 169.5(8) . .
C1 C2 C17 C19 -12.1(12) . .
C3 C4 C21 C24 -173.1(9) . .
C5 C4 C21 C24 9.5(12) . .
C3 C4 C21 C23 65.0(11) . .
C5 C4 C21 C23 -112.4(10) . .
C3 C4 C21 C22 -53.7(11) . .
C5 C4 C21 C22 128.9(9) . .
Yb3 O2 C25 C30 -65.7(7) . .
Yb2 O2 C25 C30 109.4(8) . .
Yb3 O2 C25 C26 111.1(6) . .
Yb2 O2 C25 C26 -73.8(10) . .
Yb2 O2 C25 Yb3 175.1(9) . .
O2 Yb3 C25 O2 -3.0(5) 2_655 .
N3 Yb3 C25 O2 -111.9(5) . .
N3 Yb3 C25 O2 83.0(5) 2_655 .
N4 Yb3 C25 O2 143.6(4) 2_655 .
N4 Yb3 C25 O2 -125.5(4) . .
C25 Yb3 C25 O2 -2.1(4) 2_655 .
C32 Yb3 C25 O2 -110.9(4) . .
C32 Yb3 C25 O2 101.0(4) 2_655 .
Yb2 Yb3 C25 O2 -2.1(4) . .
O2 Yb3 C25 C30 126.3(7) . .
O2 Yb3 C25 C30 123.4(4) 2_655 .
N3 Yb3 C25 C30 14.5(4) . .
N3 Yb3 C25 C30 -150.6(4) 2_655 .
N4 Yb3 C25 C30 -90.1(5) 2_655 .
N4 Yb3 C25 C30 0.9(6) . .
C25 Yb3 C25 C30 124.3(5) 2_655 .
C32 Yb3 C25 C30 15.4(5) . .
C32 Yb3 C25 C30 -132.7(4) 2_655 .
Yb2 Yb3 C25 C30 124.3(5) . .
O2 Yb3 C25 C26 -100.0(8) . .
O2 Yb3 C25 C26 -103.0(6) 2_655 .
N3 Yb3 C25 C26 148.1(7) . .
N3 Yb3 C25 C26 -17.0(7) 2_655 .
N4 Yb3 C25 C26 43.5(6) 2_655 .
N4 Yb3 C25 C26 134.5(6) . .
C25 Yb3 C25 C26 -102.1(6) 2_655 .
C32 Yb3 C25 C26 149.1(6) . .
C32 Yb3 C25 C26 0.9(7) 2_655 .
Yb2 Yb3 C25 C26 -102.1(6) . .
O2 C25 C26 C27 -176.6(7) . .
C30 C25 C26 C27 0.1(11) . .
Yb3 C25 C26 C27 -123.1(7) . .
O2 C25 C26 C41 0.1(11) . .
C30 C25 C26 C41 176.9(7) . .
Yb3 C25 C26 C41 53.6(10) . .
C25 C26 C27 C28 -0.5(12) . .
C41 C26 C27 C28 -177.5(8) . .
C26 C27 C28 C29 0.7(13) . .
C26 C27 C28 C45 178.2(8) . .
C27 C28 C29 C30 -0.5(12) . .
C45 C28 C29 C30 -177.9(8) . .
C28 C29 C30 C25 0.1(12) . .
C28 C29 C30 C31 178.4(7) . .
O2 C25 C30 C29 176.9(7) . .
C26 C25 C30 C29 0.1(11) . .
Yb3 C25 C30 C29 137.1(6) . .
O2 C25 C30 C31 -1.4(10) . .
C26 C25 C30 C31 -178.2(7) . .
Yb3 C25 C30 C31 -41.1(7) . .
C32 N3 C31 C30 156.8(6) . .
Yb3 N3 C31 C30 -36.9(8) . .
C29 C30 C31 N3 -120.3(8) . .
C25 C30 C31 N3 58.0(9) . .
C31 N3 C32 C33 0.1(11) . .
Yb3 N3 C32 C33 -166.2(6) . .
C31 N3 C32 C37 -179.2(6) . .
Yb3 N3 C32 C37 14.5(9) . .
C31 N3 C32 Yb3 166.3(9) . .
O2 Yb3 C32 N3 -27.0(6) . .
O2 Yb3 C32 N3 -105.7(6) 2_655 .
N3 Yb3 C32 N3 153.8(6) 2_655 .
N4 Yb3 C32 N3 77.7(6) 2_655 .
N4 Yb3 C32 N3 164.6(7) . .
C25 Yb3 C32 N3 -2.5(6) . .
C25 Yb3 C32 N3 -132.4(6) 2_655 .
C32 Yb3 C32 N3 114.4(6) 2_655 .
Yb2 Yb3 C32 N3 -65.6(6) . .
O2 Yb3 C32 C33 10.4(18) . .
O2 Yb3 C32 C33 -68.3(18) 2_655 .
N3 Yb3 C32 C33 37.4(16) . .
N3 Yb3 C32 C33 -168.8(16) 2_655 .
N4 Yb3 C32 C33 115.1(17) 2_655 .
N4 Yb3 C32 C33 -158.0(18) . .
C25 Yb3 C32 C33 34.9(17) . .
C25 Yb3 C32 C33 -95.0(17) 2_655 .
C32 Yb3 C32 C33 151.8(18) 2_655 .
Yb2 Yb3 C32 C33 -28.2(18) . .
O2 Yb3 C32 C37 166.4(4) . .
O2 Yb3 C32 C37 87.7(4) 2_655 .
N3 Yb3 C32 C37 -166.6(8) . .
N3 Yb3 C32 C37 -12.8(6) 2_655 .
N4 Yb3 C32 C37 -89.0(4) 2_655 .
N4 Yb3 C32 C37 -2.0(4) . .
C25 Yb3 C32 C37 -169.1(4) . .
C25 Yb3 C32 C37 61.0(4) 2_655 .
C32 Yb3 C32 C37 -52.3(4) 2_655 .
Yb2 Yb3 C32 C37 127.7(4) . .
N3 C32 C33 C34 -175.5(8) . .
C37 C32 C33 C34 3.8(12) . .
Yb3 C32 C33 C34 157.0(14) . .
C32 C33 C34 C35 -2.1(14) . .
C33 C34 C35 C36 0.3(15) . .
C34 C35 C36 C37 -0.2(14) . .
C34 C35 C36 C38 -178.2(9) . .
C40 N4 C37 C36 -0.4(11) . .
Yb3 N4 C37 C36 174.3(6) . .
C40 N4 C37 C32 -179.0(7) . .
Yb3 N4 C37 C32 -4.3(8) . .
C35 C36 C37 N4 -176.5(8) . .
C38 C36 C37 N4 1.7(12) . .
C35 C36 C37 C32 2.0(12) . .
C38 C36 C37 C32 -179.8(8) . .
N3 C32 C37 N4 -5.9(10) . .
C33 C32 C37 N4 174.7(7) . .
Yb3 C32 C37 N4 3.0(6) . .
N3 C32 C37 C36 175.5(7) . .
C33 C32 C37 C36 -3.8(11) . .
Yb3 C32 C37 C36 -175.6(7) . .
C35 C36 C38 C39 177.2(9) . .
C37 C36 C38 C39 -0.8(14) . .
C36 C38 C39 C40 -1.3(15) . .
C37 N4 C40 C39 -1.8(12) . .
Yb3 N4 C40 C39 -175.9(6) . .
C38 C39 C40 N4 2.6(14) . .
C27 C26 C41 C42' 104.1(18) . .
C25 C26 C41 C42' -72.6(19) . .
C27 C26 C41 C44' -120.9(18) . .
C25 C26 C41 C44' 62.4(19) . .
C27 C26 C41 C43 63.9(10) . .
C25 C26 C41 C43 -112.8(9) . .
C27 C26 C41 C43' -7(2) . .
C25 C26 C41 C43' 176(2) . .
C27 C26 C41 C44 -56.0(10) . .
C25 C26 C41 C44 127.3(9) . .
C27 C26 C41 C42 -173.3(8) . .
C25 C26 C41 C42 10.0(12) . .
C29 C28 C45 C48 111.8(11) . .
C27 C28 C45 C48 -65.5(12) . .
C29 C28 C45 C46 -8.7(13) . .
C27 C28 C45 C46 174.0(9) . .
C29 C28 C45 C47 -128.2(9) . .
C27 C28 C45 C47 54.4(11) . .
C54 C49 C50 C51 3(4) . .
C55 C49 C50 C51 -178(3) . .
C49 C50 C51 C52 -1(3) . .
C50 C51 C52 C53 1(3) . .
C51 C52 C53 C54 -2(4) . .
C52 C53 C54 C49 4(4) . .
C50 C49 C54 C53 -4(3) . .
C55 C49 C54 C53 177(3) . .
C54' C49' C50' C51' -6(5) . .
C55' C49' C50' C51' 178(4) . .
C49' C50' C51' C52' 3(6) . .
C50' C51' C52' C53' 1(5) . .
C51' C52' C53' C54' -2(5) . .
C52' C53' C54' C49' -1(6) . .
C50' C49' C54' C53' 5(6) . .
C55' C49' C54' C53' -179(4) . .
C61 C56 C57 C58 0.1(3) . .
C62 C56 C57 C58 -179.9(3) . .
C56 C57 C58 C59 0.0(3) . .
C57 C58 C59 C60 0.1(6) . .
C58 C59 C60 C61 -0.3(9) . .
C57 C56 C61 C60 -0.2(6) . .
C62 C56 C61 C60 179.8(5) . .
C59 C60 C61 C56 0.3(8) . .
C61' C56' C57' C58' -0.1(3) . .
C62' C56' C57' C58' 179.9(3) . .
C56' C57' C58' C59' 0.0(3) . .
C57' C58' C59' C60' 0.0(7) . .
C58' C59' C60' C61' 0.2(9) . .
C59' C60' C61' C56' -0.3(8) . .
C57' C56' C61' C60' 0.2(7) . .
C62' C56' C61' C60' -179.8(5) . .
C68 C63 C64 C65 0(7) . .
C69 C63 C64 C65 -175(5) . .
C63 C64 C65 C66 -5(7) . .
C64 C65 C66 C67 5(6) . .
C65 C66 C67 C68 0(5) . .
C64 C63 C68 C67 5(6) . .
C69 C63 C68 C67 180(4) . .
C66 C67 C68 C63 -5(5) . .
C68' C63' C64' C65' 5(5) . .
C69' C63' C64' C65' -172(3) . .
C63' C64' C65' C66' -1(5) . .
C64' C65' C66' C67' -5(4) . .
C65' C66' C67' C68' 6(5) . .
C64' C63' C68' C67' -3(6) . .
C69' C63' C68' C67' 174(4) . .
C66' C67' C68' C63' -2(5) . .
