#------------------------------------------------------------------------------
#$Date: 2019-11-26 16:15:26 +0100 (mar 26 de nov de 2019) $
#$Revision: 243703 $
#$URL: svn://www.crystallography.net/cod/cif/4/08/96/4089618.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4089618
loop_
_publ_author_name
'Nasser, Nasser'
'Boyle, Paul D.'
'Puddephatt, Richard J.'
_publ_section_title
;
 Organoplatinum Chemistry with a Dicarboxamide--Diphosphine Ligand:
 Hydrogen Bonding, Cyclometalation, and a Complex with Two Metal--Metal
 Donor--Acceptor Bonds
;
_journal_issue                   19
_journal_name_full               Organometallics
_journal_page_first              5504
_journal_paper_doi               10.1021/om400780q
_journal_volume                  32
_journal_year                    2013
_chemical_formula_sum            'C80 H64 Ag4 F12 N4 O12 P4 Pt2'
_chemical_formula_weight         2446.89
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     heavy
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2012
_cell_angle_alpha                90.921(16)
_cell_angle_beta                 102.291(11)
_cell_angle_gamma                119.341(5)
_cell_formula_units_Z            2
_cell_length_a                   13.121(4)
_cell_length_b                   13.167(3)
_cell_length_c                   27.262(6)
_cell_measurement_reflns_used    9912
_cell_measurement_temperature    150
_cell_measurement_theta_max      30.30
_cell_measurement_theta_min      3.10
_cell_volume                     3971.3(18)
_computing_cell_refinement       SAINT
_computing_data_collection       Apex2
_computing_data_reduction        SAINT
_computing_molecular_graphics    NRCVAX
_computing_publication_material  cif2tables.py
_computing_structure_refinement  SHELXL-2013
_computing_structure_solution    DIRDIF-2008
_diffrn_ambient_temperature      150
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.942
_diffrn_measurement_device_type  'Nonius KappaCCD'
_diffrn_measurement_method       'omega and phi scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0559
_diffrn_reflns_av_unetI/netI     0.0703
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.942
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       37
_diffrn_reflns_limit_l_min       -38
_diffrn_reflns_number            88227
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.942
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         30.571
_diffrn_reflns_theta_min         0.772
_diffrn_source                   'sealed tube'
_exptl_absorpt_coefficient_mu    4.650
_exptl_absorpt_correction_T_max  0.7461
_exptl_absorpt_correction_T_min  0.6185
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    2.046
_exptl_crystal_description       plate
_exptl_crystal_F_000             2360
_exptl_crystal_size_max          0.168
_exptl_crystal_size_mid          0.125
_exptl_crystal_size_min          0.048
_refine_diff_density_max         1.385
_refine_diff_density_min         -1.440
_refine_diff_density_rms         0.186
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.040
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1063
_refine_ls_number_reflns         22947
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.040
_refine_ls_R_factor_all          0.0809
_refine_ls_R_factor_gt           0.0431
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
;
 w=1/[σ²(Fo²)+16.8323P]
 where P=(Fo²+2Fc²)/3
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0630
_refine_ls_wR_factor_ref         0.0707
_reflns_Friedel_coverage         0.000
_reflns_number_gt                16311
_reflns_number_total             22947
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            om400780q_si_001.cif
_cod_data_source_block           8
_cod_original_cell_volume        3971(2)
_cod_database_code               4089618
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.509
_shelx_estimated_absorpt_t_max   0.808
_shelxl_version_number           2012-9
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
Pt1 Pt -0.28364(2) 0.11281(2) 0.59492(2) 0.01408(4) Uani 1 1 d . .
Ag1 Ag 0.10796(4) 0.44690(3) 0.50566(2) 0.02603(9) Uani 1 1 d . .
Ag2 Ag 0.09321(4) 0.15396(3) 0.49468(2) 0.02537(9) Uani 1 1 d . .
P1A P -0.33273(11) 0.20540(10) 0.64719(5) 0.0155(2) Uani 1 1 d . .
P2A P -0.36870(11) -0.07424(10) 0.61113(5) 0.0162(2) Uani 1 1 d . .
C1A C -0.2983(4) 0.3433(4) 0.62002(19) 0.0215(11) Uani 1 1 d . .
H1A1 H -0.3654 0.3590 0.6182 0.026 Uiso 1 1 calc R U
H1A2 H -0.2237 0.4102 0.6419 0.026 Uiso 1 1 calc R U
C2A C -0.2814(4) 0.3309(4) 0.56716(19) 0.0210(11) Uani 1 1 d . .
H2A1 H -0.3605 0.2805 0.5426 0.025 Uiso 1 1 calc R U
H2A2 H -0.2410 0.4089 0.5558 0.025 Uiso 1 1 calc R U
N1A N -0.2061(3) 0.2767(3) 0.57112(15) 0.0178(9) Uani 1 1 d . .
C3A C -0.0989(4) 0.3303(4) 0.56243(17) 0.0147(9) Uani 1 1 d . .
O1A O -0.0563(3) 0.4212(3) 0.54021(12) 0.0187(7) Uani 1 1 d . .
C4A C -0.0125(4) 0.2917(4) 0.58769(18) 0.0163(10) Uani 1 1 d . .
C5A C 0.0828(4) 0.3751(4) 0.62671(19) 0.0219(11) Uani 1 1 d . .
H5A H 0.0893 0.4492 0.6339 0.026 Uiso 1 1 calc R U
C6A C 0.1676(4) 0.3522(4) 0.6550(2) 0.0277(12) Uani 1 1 d . .
H6A H 0.2320 0.4099 0.6814 0.033 Uiso 1 1 calc R U
C7A C 0.1581(5) 0.2444(5) 0.6447(2) 0.0295(12) Uani 1 1 d . .
H7A H 0.2155 0.2272 0.6643 0.035 Uiso 1 1 calc R U
C8A C 0.0654(4) 0.1617(4) 0.60586(19) 0.0228(11) Uani 1 1 d . .
H8A H 0.0615 0.0891 0.5982 0.027 Uiso 1 1 calc R U
C9A C -0.0224(4) 0.1826(4) 0.57769(17) 0.0149(9) Uani 1 1 d . .
C10A C -0.1232(4) 0.0818(4) 0.53924(18) 0.0171(10) Uani 1 1 d . .
O2A O -0.0950(3) 0.0329(3) 0.50847(13) 0.0242(8) Uani 1 1 d . .
N2A N -0.2344(3) 0.0442(3) 0.54224(14) 0.0159(8) Uani 1 1 d . .
C11A C -0.3270(4) -0.0764(4) 0.51844(18) 0.0185(10) Uani 1 1 d . .
H11A H -0.2995 -0.1049 0.4931 0.022 Uiso 1 1 calc R U
H11B H -0.4034 -0.0797 0.5014 0.022 Uiso 1 1 calc R U
C12A C -0.3450(5) -0.1508(4) 0.56188(19) 0.0212(11) Uani 1 1 d . .
H12A H -0.2728 -0.1580 0.5752 0.025 Uiso 1 1 calc R U
H12B H -0.4160 -0.2307 0.5500 0.025 Uiso 1 1 calc R U
C13A C -0.4870(4) 0.1393(4) 0.65327(18) 0.0175(10) Uani 1 1 d . .
C14A C -0.5729(4) 0.1481(4) 0.61660(19) 0.0219(11) Uani 1 1 d . .
H14A H -0.5492 0.1944 0.5904 0.026 Uiso 1 1 calc R U
C15A C -0.6930(5) 0.0896(5) 0.6183(2) 0.0287(12) Uani 1 1 d . .
H15A H -0.7517 0.0953 0.5931 0.034 Uiso 1 1 calc R U
C16A C -0.7269(5) 0.0232(5) 0.6565(2) 0.0321(13) Uani 1 1 d . .
H16A H -0.8093 -0.0174 0.6575 0.039 Uiso 1 1 calc R U
C17A C -0.6420(5) 0.0151(4) 0.6935(2) 0.0307(13) Uani 1 1 d . .
H17A H -0.6660 -0.0296 0.7201 0.037 Uiso 1 1 calc R U
C18A C -0.5223(4) 0.0719(4) 0.6918(2) 0.0234(11) Uani 1 1 d . .
H18A H -0.4643 0.0650 0.7168 0.028 Uiso 1 1 calc R U
C19A C -0.2411(4) 0.2480(4) 0.71200(18) 0.0182(10) Uani 1 1 d . .
C20A C -0.1583(4) 0.2115(4) 0.72782(19) 0.0214(11) Uani 1 1 d . .
H20A H -0.1481 0.1651 0.7044 0.026 Uiso 1 1 calc R U
C21A C -0.0905(4) 0.2422(4) 0.7776(2) 0.0241(11) Uani 1 1 d . .
H21A H -0.0351 0.2155 0.7883 0.029 Uiso 1 1 calc R U
C22A C -0.1029(5) 0.3115(4) 0.8118(2) 0.0273(12) Uani 1 1 d . .
H22A H -0.0568 0.3316 0.8461 0.033 Uiso 1 1 calc R U
C23A C -0.1828(5) 0.3513(5) 0.7959(2) 0.0336(13) Uani 1 1 d . .
H23A H -0.1898 0.4009 0.8190 0.040 Uiso 1 1 calc R U
C24A C -0.2530(5) 0.3186(5) 0.7460(2) 0.0280(12) Uani 1 1 d . .
H24A H -0.3090 0.3447 0.7353 0.034 Uiso 1 1 calc R U
C25A C -0.5299(4) -0.1569(4) 0.60261(18) 0.0189(10) Uani 1 1 d . .
C26A C -0.6039(4) -0.1166(4) 0.57729(19) 0.0230(11) Uani 1 1 d . .
H26A H -0.5686 -0.0409 0.5668 0.028 Uiso 1 1 calc R U
C27A C -0.7286(5) -0.1856(5) 0.5672(2) 0.0284(12) Uani 1 1 d . .
H27A H -0.7784 -0.1564 0.5508 0.034 Uiso 1 1 calc R U
C28A C -0.7800(5) -0.2969(4) 0.5812(2) 0.0294(12) Uani 1 1 d . .
H28A H -0.8654 -0.3447 0.5744 0.035 Uiso 1 1 calc R U
C29A C -0.7067(5) -0.3385(4) 0.6050(2) 0.0306(13) Uani 1 1 d . .
H29A H -0.7424 -0.4158 0.6139 0.037 Uiso 1 1 calc R U
C30A C -0.5834(5) -0.2699(4) 0.6161(2) 0.0271(12) Uani 1 1 d . .
H30A H -0.5342 -0.2994 0.6329 0.032 Uiso 1 1 calc R U
C31A C -0.3002(4) -0.0947(4) 0.67235(18) 0.0195(10) Uani 1 1 d . .
C32A C -0.1870(5) -0.0845(4) 0.6812(2) 0.0279(12) Uani 1 1 d . .
H32A H -0.1488 -0.0737 0.6542 0.034 Uiso 1 1 calc R U
C33A C -0.1299(5) -0.0901(5) 0.7289(2) 0.0350(14) Uani 1 1 d . .
H33A H -0.0524 -0.0826 0.7345 0.042 Uiso 1 1 calc R U
C34A C -0.1844(5) -0.1064(5) 0.7685(2) 0.0335(13) Uani 1 1 d . .
H34A H -0.1454 -0.1113 0.8013 0.040 Uiso 1 1 calc R U
C35A C -0.2964(5) -0.1156(5) 0.7598(2) 0.0332(13) Uani 1 1 d . .
H35A H -0.3339 -0.1258 0.7869 0.040 Uiso 1 1 calc R U
C36A C -0.3539(5) -0.1103(4) 0.71269(19) 0.0239(11) Uani 1 1 d . .
H36A H -0.4312 -0.1172 0.7074 0.029 Uiso 1 1 calc R U
O3A O 0.0277(4) 0.2812(3) 0.44135(15) 0.0378(10) Uani 1 1 d . .
O4A O 0.0545(4) 0.1534(3) 0.39946(15) 0.0373(10) Uani 1 1 d . .
C37A C 0.0439(4) 0.2404(5) 0.4045(2) 0.0258(11) Uani 1 1 d . .
C38A C 0.0523(5) 0.3061(5) 0.3590(2) 0.0357(14) Uani 1 1 d . .
F1A F -0.0177(4) 0.2367(4) 0.31566(14) 0.0730(13) Uani 1 1 d . .
F2A F 0.0253(3) 0.3915(3) 0.36254(14) 0.0487(9) Uani 1 1 d . .
F3A F 0.1649(4) 0.3620(4) 0.35394(19) 0.0765(14) Uani 1 1 d . .
O5A O 0.2884(3) 0.4605(3) 0.53489(16) 0.0401(10) Uani 1 1 d . .
O6A O 0.2858(3) 0.2882(3) 0.52960(16) 0.0388(10) Uani 1 1 d . .
C39A C 0.3317(5) 0.3959(4) 0.5402(2) 0.0246(11) Uani 1 1 d . .
C40A C 0.4665(5) 0.4556(5) 0.5673(3) 0.0366(14) Uani 1 1 d . .
F4A F 0.5265(3) 0.4230(3) 0.54329(15) 0.0528(10) Uani 1 1 d . .
F5A F 0.4803(3) 0.4232(3) 0.61372(14) 0.0520(10) Uani 1 1 d . .
F6A F 0.5232(3) 0.5710(3) 0.57399(19) 0.0750(15) Uani 1 1 d . .
Pt2 Pt 0.52279(2) 0.63068(2) 0.90731(2) 0.01567(4) Uani 1 1 d . .
Ag3 Ag 1.05322(4) 0.90299(3) 0.98373(2) 0.02816(9) Uani 1 1 d . .
Ag4 Ag 0.32971(4) 0.89890(3) 0.99198(2) 0.03161(10) Uani 1 1 d . .
P1B P 0.59990(11) 0.53273(10) 0.87545(5) 0.0184(3) Uani 1 1 d . .
P2B P 0.32490(11) 0.53600(10) 0.86730(5) 0.0172(3) Uani 1 1 d . .
C1B C 0.7478(5) 0.5895(4) 0.9213(2) 0.0260(12) Uani 1 1 d . .
H1B1 H 0.7639 0.5245 0.9283 0.031 Uiso 1 1 calc R U
H1B2 H 0.8128 0.6488 0.9073 0.031 Uiso 1 1 calc R U
C2B C 0.7443(4) 0.6448(4) 0.96974(19) 0.0234(11) Uani 1 1 d . .
H2B1 H 0.6920 0.5835 0.9878 0.028 Uiso 1 1 calc R U
H2B2 H 0.8266 0.6912 0.9926 0.028 Uiso 1 1 calc R U
N1B N 0.6953(3) 0.7211(3) 0.95381(15) 0.0176(8) Uani 1 1 d . .
C3B C 0.7674(4) 0.8362(4) 0.96352(18) 0.0177(10) Uani 1 1 d . .
O1B O 0.8712(3) 0.8884(3) 0.99426(13) 0.0211(7) Uani 1 1 d . .
C4B C 0.7305(4) 0.9106(4) 0.93228(18) 0.0190(10) Uani 1 1 d . .
C5B C 0.8138(5) 0.9828(4) 0.90602(19) 0.0243(11) Uani 1 1 d . .
H5B H 0.8871 0.9822 0.9097 0.029 Uiso 1 1 calc R U
C6B C 0.7915(5) 1.0551(4) 0.8748(2) 0.0297(12) Uani 1 1 d . .
H6B H 0.8485 1.1025 0.8567 0.036 Uiso 1 1 calc R U
C7B C 0.6861(5) 1.0585(4) 0.8700(2) 0.0323(13) Uani 1 1 d . .
H7B H 0.6704 1.1082 0.8486 0.039 Uiso 1 1 calc R U
C8B C 0.6037(5) 0.9890(4) 0.8966(2) 0.0288(12) Uani 1 1 d . .
H8B H 0.5326 0.9932 0.8941 0.035 Uiso 1 1 calc R U
C9B C 0.6233(4) 0.9124(4) 0.92710(19) 0.0215(11) Uani 1 1 d . .
C10B C 0.5259(4) 0.8423(4) 0.95314(19) 0.0196(10) Uani 1 1 d . .
O2B O 0.4988(3) 0.9006(3) 0.97976(14) 0.0288(9) Uani 1 1 d . .
N2B N 0.4691(4) 0.7264(3) 0.94426(15) 0.0207(9) Uani 1 1 d . .
C11B C 0.3572(4) 0.6541(4) 0.95882(19) 0.0239(11) Uani 1 1 d . .
H11C H 0.3351 0.7045 0.9759 0.029 Uiso 1 1 calc R U
H11D H 0.3669 0.6015 0.9825 0.029 Uiso 1 1 calc R U
C12B C 0.2587(4) 0.5814(4) 0.91061(19) 0.0248(11) Uani 1 1 d . .
H12C H 0.2255 0.6288 0.8939 0.030 Uiso 1 1 calc R U
H12D H 0.1920 0.5110 0.9192 0.030 Uiso 1 1 calc R U
C13B C 0.5231(4) 0.3752(4) 0.87324(19) 0.0197(10) Uani 1 1 d . .
C14B C 0.4662(4) 0.3252(4) 0.9115(2) 0.0265(12) Uani 1 1 d . .
H14B H 0.4649 0.3743 0.9370 0.032 Uiso 1 1 calc R U
C15B C 0.4114(5) 0.2048(5) 0.9129(2) 0.0334(13) Uani 1 1 d . .
H15B H 0.3732 0.1715 0.9391 0.040 Uiso 1 1 calc R U
C16B C 0.4133(5) 0.1341(5) 0.8755(3) 0.0413(16) Uani 1 1 d . .
H16B H 0.3762 0.0516 0.8761 0.050 Uiso 1 1 calc R U
C17B C 0.4688(5) 0.1825(5) 0.8373(3) 0.0381(15) Uani 1 1 d . .
H17B H 0.4698 0.1332 0.8118 0.046 Uiso 1 1 calc R U
C18B C 0.5227(5) 0.3018(4) 0.8362(2) 0.0310(13) Uani 1 1 d . .
H18B H 0.5601 0.3342 0.8096 0.037 Uiso 1 1 calc R U
C19B C 0.6263(4) 0.5599(4) 0.81317(19) 0.0216(11) Uani 1 1 d . .
C20B C 0.5342(5) 0.5494(5) 0.7743(2) 0.0343(13) Uani 1 1 d . .
H20B H 0.4595 0.5316 0.7810 0.041 Uiso 1 1 calc R U
C21B C 0.5478(5) 0.5640(5) 0.7257(2) 0.0368(14) Uani 1 1 d . .
H21B H 0.4831 0.5562 0.6993 0.044 Uiso 1 1 calc R U
C22B C 0.6562(5) 0.5899(5) 0.7156(2) 0.0346(14) Uani 1 1 d . .
H22B H 0.6656 0.5975 0.6820 0.041 Uiso 1 1 calc R U
C23B C 0.7498(5) 0.6046(5) 0.7541(2) 0.0358(14) Uani 1 1 d . .
H23B H 0.8252 0.6253 0.7473 0.043 Uiso 1 1 calc R U
C24B C 0.7365(5) 0.5899(4) 0.8029(2) 0.0299(12) Uani 1 1 d . .
H24B H 0.8024 0.6001 0.8294 0.036 Uiso 1 1 calc R U
C25B C 0.2405(4) 0.3770(4) 0.85387(18) 0.0185(10) Uani 1 1 d . .
C26B C 0.1853(4) 0.3105(4) 0.8897(2) 0.0262(12) Uani 1 1 d . .
H26B H 0.1845 0.3484 0.9194 0.031 Uiso 1 1 calc R U
C27B C 0.1315(5) 0.1888(5) 0.8816(2) 0.0355(14) Uani 1 1 d . .
H27B H 0.0957 0.1439 0.9064 0.043 Uiso 1 1 calc R U
C28B C 0.1295(5) 0.1331(5) 0.8386(2) 0.0370(15) Uani 1 1 d . .
H28B H 0.0910 0.0496 0.8332 0.044 Uiso 1 1 calc R U
C29B C 0.1836(5) 0.1980(4) 0.8027(2) 0.0331(13) Uani 1 1 d . .
H29B H 0.1834 0.1592 0.7729 0.040 Uiso 1 1 calc R U
C30B C 0.2377(4) 0.3187(4) 0.8103(2) 0.0237(11) Uani 1 1 d . .
H30B H 0.2736 0.3628 0.7853 0.028 Uiso 1 1 calc R U
C31B C 0.2914(4) 0.5898(4) 0.80894(19) 0.0209(10) Uani 1 1 d . .
C32B C 0.1757(5) 0.5361(5) 0.7778(2) 0.0324(13) Uani 1 1 d . .
H32B H 0.1144 0.4644 0.7850 0.039 Uiso 1 1 calc R U
C33B C 0.1480(6) 0.5855(5) 0.7365(2) 0.0381(14) Uani 1 1 d . .
H33B H 0.0679 0.5478 0.7154 0.046 Uiso 1 1 calc R U
C34B C 0.2355(6) 0.6888(6) 0.7256(2) 0.0415(15) Uani 1 1 d . .
H34B H 0.2168 0.7214 0.6966 0.050 Uiso 1 1 calc R U
C35B C 0.3507(6) 0.7449(6) 0.7570(3) 0.0503(18) Uani 1 1 d . .
H35B H 0.4112 0.8173 0.7501 0.060 Uiso 1 1 calc R U
C36B C 0.3785(5) 0.6960(5) 0.7987(2) 0.0381(15) Uani 1 1 d . .
H36B H 0.4578 0.7355 0.8204 0.046 Uiso 1 1 calc R U
O3B O 0.1417(3) 0.7889(3) 1.00752(15) 0.0344(9) Uani 1 1 d . .
O4B O -0.0004(3) 0.6938(3) 1.04938(15) 0.0339(9) Uani 1 1 d . .
C37B C 0.0880(5) 0.7137(4) 1.0342(2) 0.0244(11) Uani 1 1 d . .
C38B C 0.1429(5) 0.6348(5) 1.0486(2) 0.0307(13) Uani 1 1 d . .
F7B F 0.1341(3) 0.5694(3) 1.00815(12) 0.0391(8) Uani 1 1 d . .
F8B F 0.0908(3) 0.5591(3) 1.07947(13) 0.0452(9) Uani 1 1 d . .
F9B F 0.2612(3) 0.6984(3) 1.07213(15) 0.0550(11) Uani 1 1 d . .
O5B O 1.0071(4) 0.8349(4) 0.89397(17) 0.0502(12) Uani 1 1 d . .
O6B O 1.2059(4) 0.9240(4) 0.92074(17) 0.0634(15) Uani 1 1 d . .
C39B C 1.1083(6) 0.8584(5) 0.8909(2) 0.0356(14) Uani 1 1 d . .
C40B C 1.1104(6) 0.7982(6) 0.8425(3) 0.0486(17) Uani 1 1 d . .
F10B F 1.0401(4) 0.6821(4) 0.8360(2) 0.0834(15) Uani 1 1 d . .
F11B F 1.2183(4) 0.8140(4) 0.8441(2) 0.0986(18) Uani 1 1 d . .
F12B F 1.0740(7) 0.8344(5) 0.80249(16) 0.122(2) Uani 1 1 d . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N2A Pt1 N1A 92.03(15) . .
N2A Pt1 P1A 173.26(11) . .
N1A Pt1 P1A 81.47(11) . .
N2A Pt1 P2A 81.27(11) . .
N1A Pt1 P2A 172.78(12) . .
P1A Pt1 P2A 105.14(5) . .
O5A Ag1 O3A 95.95(14) . .
O5A Ag1 O1A 136.67(14) . .
O3A Ag1 O1A 106.97(12) . .
O5A Ag1 O1A 130.13(13) . 2_566
O3A Ag1 O1A 102.27(12) . 2_566
O1A Ag1 O1A 80.71(11) . 2_566
O6A Ag2 O2A 146.19(14) . .
O6A Ag2 O2A 103.26(12) . 2_556
O2A Ag2 O2A 81.59(12) . 2_556
O6A Ag2 O4A 107.98(15) . .
O2A Ag2 O4A 104.91(13) . .
O2A Ag2 O4A 94.41(12) 2_556 .
O6A Ag2 O3A 99.57(14) . .
O2A Ag2 O3A 94.63(13) . .
O2A Ag2 O3A 143.86(12) 2_556 .
O4A Ag2 O3A 51.61(12) . .
C19A P1A C13A 104.4(2) . .
C19A P1A C1A 106.7(2) . .
C13A P1A C1A 106.9(2) . .
C19A P1A Pt1 114.93(16) . .
C13A P1A Pt1 120.43(15) . .
C1A P1A Pt1 102.56(16) . .
C25A P2A C31A 107.3(2) . .
C25A P2A C12A 103.1(2) . .
C31A P2A C12A 108.2(2) . .
C25A P2A Pt1 118.50(16) . .
C31A P2A Pt1 114.90(15) . .
C12A P2A Pt1 103.66(16) . .
C2A C1A P1A 109.1(3) . .
C2A C1A H1A1 109.9 . .
P1A C1A H1A1 109.9 . .
C2A C1A H1A2 109.9 . .
P1A C1A H1A2 109.9 . .
H1A1 C1A H1A2 108.3 . .
N1A C2A C1A 106.1(4) . .
N1A C2A H2A1 110.5 . .
C1A C2A H2A1 110.5 . .
N1A C2A H2A2 110.5 . .
C1A C2A H2A2 110.5 . .
H2A1 C2A H2A2 108.7 . .
C3A N1A C2A 122.3(4) . .
C3A N1A Pt1 124.5(3) . .
C2A N1A Pt1 113.1(3) . .
O1A C3A N1A 126.0(4) . .
O1A C3A C4A 117.1(4) . .
N1A C3A C4A 116.3(4) . .
C3A O1A Ag1 113.7(3) . .
C3A O1A Ag1 143.3(3) . 2_566
Ag1 O1A Ag1 99.29(11) . 2_566
C9A C4A C5A 119.1(4) . .
C9A C4A C3A 126.9(4) . .
C5A C4A C3A 113.9(4) . .
C6A C5A C4A 121.4(4) . .
C6A C5A H5A 119.3 . .
C4A C5A H5A 119.3 . .
C5A C6A C7A 119.3(5) . .
C5A C6A H6A 120.3 . .
C7A C6A H6A 120.3 . .
C8A C7A C6A 120.0(5) . .
C8A C7A H7A 120.0 . .
C6A C7A H7A 120.0 . .
C7A C8A C9A 121.4(4) . .
C7A C8A H8A 119.3 . .
C9A C8A H8A 119.3 . .
C8A C9A C4A 118.8(4) . .
C8A C9A C10A 115.8(4) . .
C4A C9A C10A 125.4(4) . .
O2A C10A N2A 124.1(4) . .
O2A C10A C9A 117.8(4) . .
N2A C10A C9A 117.9(4) . .
C10A O2A Ag2 113.8(3) . .
C10A O2A Ag2 132.0(3) . 2_556
Ag2 O2A Ag2 98.41(12) . 2_556
C10A N2A C11A 117.6(4) . .
C10A N2A Pt1 125.6(3) . .
C11A N2A Pt1 113.8(3) . .
N2A C11A C12A 105.5(4) . .
N2A C11A H11A 110.6 . .
C12A C11A H11A 110.6 . .
N2A C11A H11B 110.6 . .
C12A C11A H11B 110.6 . .
H11A C11A H11B 108.8 . .
C11A C12A P2A 106.3(3) . .
C11A C12A H12A 110.5 . .
P2A C12A H12A 110.5 . .
C11A C12A H12B 110.5 . .
P2A C12A H12B 110.5 . .
H12A C12A H12B 108.7 . .
C14A C13A C18A 119.6(4) . .
C14A C13A P1A 119.5(4) . .
C18A C13A P1A 120.8(4) . .
C15A C14A C13A 120.1(5) . .
C15A C14A H14A 119.9 . .
C13A C14A H14A 119.9 . .
C16A C15A C14A 119.8(5) . .
C16A C15A H15A 120.1 . .
C14A C15A H15A 120.1 . .
C15A C16A C17A 120.6(5) . .
C15A C16A H16A 119.7 . .
C17A C16A H16A 119.7 . .
C18A C17A C16A 120.1(5) . .
C18A C17A H17A 120.0 . .
C16A C17A H17A 120.0 . .
C17A C18A C13A 119.8(5) . .
C17A C18A H18A 120.1 . .
C13A C18A H18A 120.1 . .
C20A C19A C24A 119.6(5) . .
C20A C19A P1A 120.5(4) . .
C24A C19A P1A 119.9(4) . .
C21A C20A C19A 120.2(5) . .
C21A C20A H20A 119.9 . .
C19A C20A H20A 119.9 . .
C22A C21A C20A 120.5(5) . .
C22A C21A H21A 119.8 . .
C20A C21A H21A 119.8 . .
C21A C22A C23A 119.7(5) . .
C21A C22A H22A 120.2 . .
C23A C22A H22A 120.2 . .
C22A C23A C24A 120.0(5) . .
C22A C23A H23A 120.0 . .
C24A C23A H23A 120.0 . .
C19A C24A C23A 120.0(5) . .
C19A C24A H24A 120.0 . .
C23A C24A H24A 120.0 . .
C26A C25A C30A 118.8(4) . .
C26A C25A P2A 121.3(3) . .
C30A C25A P2A 119.4(4) . .
C27A C26A C25A 120.7(5) . .
C27A C26A H26A 119.7 . .
C25A C26A H26A 119.7 . .
C28A C27A C26A 119.7(5) . .
C28A C27A H27A 120.1 . .
C26A C27A H27A 120.1 . .
C27A C28A C29A 119.7(5) . .
C27A C28A H28A 120.2 . .
C29A C28A H28A 120.2 . .
C30A C29A C28A 121.0(5) . .
C30A C29A H29A 119.5 . .
C28A C29A H29A 119.5 . .
C29A C30A C25A 120.0(5) . .
C29A C30A H30A 120.0 . .
C25A C30A H30A 120.0 . .
C32A C31A C36A 118.5(5) . .
C32A C31A P2A 120.1(4) . .
C36A C31A P2A 121.1(4) . .
C33A C32A C31A 120.4(5) . .
C33A C32A H32A 119.8 . .
C31A C32A H32A 119.8 . .
C32A C33A C34A 120.6(5) . .
C32A C33A H33A 119.7 . .
C34A C33A H33A 119.7 . .
C35A C34A C33A 119.0(5) . .
C35A C34A H34A 120.5 . .
C33A C34A H34A 120.5 . .
C36A C35A C34A 121.0(5) . .
C36A C35A H35A 119.5 . .
C34A C35A H35A 119.5 . .
C35A C36A C31A 120.5(5) . .
C35A C36A H36A 119.7 . .
C31A C36A H36A 119.7 . .
C37A O3A Ag1 145.9(4) . .
C37A O3A Ag2 87.8(3) . .
Ag1 O3A Ag2 98.43(14) . .
C37A O4A Ag2 89.6(3) . .
O4A C37A O3A 128.8(5) . .
O4A C37A C38A 114.9(5) . .
O3A C37A C38A 116.3(5) . .
F1A C38A F3A 107.1(5) . .
F1A C38A F2A 107.0(5) . .
F3A C38A F2A 104.1(5) . .
F1A C38A C37A 113.3(5) . .
F3A C38A C37A 110.7(5) . .
F2A C38A C37A 114.0(5) . .
C39A O5A Ag1 139.1(4) . .
C39A O6A Ag2 128.6(3) . .
O5A C39A O6A 132.0(5) . .
O5A C39A C40A 116.0(4) . .
O6A C39A C40A 112.0(4) . .
F6A C40A F4A 107.4(5) . .
F6A C40A F5A 106.5(5) . .
F4A C40A F5A 105.7(4) . .
F6A C40A C39A 114.5(5) . .
F4A C40A C39A 112.2(5) . .
F5A C40A C39A 109.9(5) . .
N2B Pt2 N1B 91.96(16) . .
N2B Pt2 P1B 173.02(12) . .
N1B Pt2 P1B 81.52(11) . .
N2B Pt2 P2B 80.44(12) . .
N1B Pt2 P2B 170.94(11) . .
P1B Pt2 P2B 105.83(5) . .
O3B Ag3 O1B 131.48(12) 1_655 .
O3B Ag3 O1B 130.93(12) 1_655 2_777
O1B Ag3 O1B 81.87(11) . 2_777
O3B Ag3 O5B 92.41(15) 1_655 .
O1B Ag3 O5B 104.01(14) . .
O1B Ag3 O5B 115.75(14) 2_777 .
O2B Ag4 O3B 146.46(13) . .
O2B Ag4 O6B 116.83(16) . 1_455
O3B Ag4 O6B 79.24(15) . 1_455
O2B Ag4 O2B 72.34(13) . 2_677
O3B Ag4 O2B 135.88(12) . 2_677
O6B Ag4 O2B 102.48(14) 1_455 2_677
C13B P1B C19B 105.6(2) . .
C13B P1B C1B 105.8(2) . .
C19B P1B C1B 107.9(2) . .
C13B P1B Pt2 117.93(17) . .
C19B P1B Pt2 116.32(16) . .
C1B P1B Pt2 102.47(16) . .
C31B P2B C25B 106.7(2) . .
C31B P2B C12B 104.3(2) . .
C25B P2B C12B 108.0(2) . .
C31B P2B Pt2 113.54(17) . .
C25B P2B Pt2 120.10(16) . .
C12B P2B Pt2 103.00(17) . .
C2B C1B P1B 108.1(3) . .
C2B C1B H1B1 110.1 . .
P1B C1B H1B1 110.1 . .
C2B C1B H1B2 110.1 . .
P1B C1B H1B2 110.1 . .
H1B1 C1B H1B2 108.4 . .
N1B C2B C1B 105.7(4) . .
N1B C2B H2B1 110.6 . .
C1B C2B H2B1 110.6 . .
N1B C2B H2B2 110.6 . .
C1B C2B H2B2 110.6 . .
H2B1 C2B H2B2 108.7 . .
C3B N1B C2B 119.2(4) . .
C3B N1B Pt2 126.9(3) . .
C2B N1B Pt2 113.1(3) . .
O1B C3B N1B 124.8(4) . .
O1B C3B C4B 117.0(4) . .
N1B C3B C4B 117.9(4) . .
C3B O1B Ag3 128.3(3) . .
C3B O1B Ag3 112.5(3) . 2_777
Ag3 O1B Ag3 98.14(11) . 2_777
C5B C4B C9B 119.2(4) . .
C5B C4B C3B 114.4(4) . .
C9B C4B C3B 126.4(4) . .
C6B C5B C4B 121.2(5) . .
C6B C5B H5B 119.4 . .
C4B C5B H5B 119.4 . .
C5B C6B C7B 120.0(5) . .
C5B C6B H6B 120.0 . .
C7B C6B H6B 120.0 . .
C6B C7B C8B 119.4(5) . .
C6B C7B H7B 120.3 . .
C8B C7B H7B 120.3 . .
C7B C8B C9B 121.2(5) . .
C7B C8B H8B 119.4 . .
C9B C8B H8B 119.4 . .
C4B C9B C8B 119.0(5) . .
C4B C9B C10B 125.9(4) . .
C8B C9B C10B 115.1(4) . .
O2B C10B N2B 124.7(4) . .
O2B C10B C9B 116.1(4) . .
N2B C10B C9B 119.0(4) . .
C10B O2B Ag4 139.3(3) . .
C10B O2B Ag4 110.2(3) . 2_677
Ag4 O2B Ag4 107.66(12) . 2_677
C10B N2B C11B 121.4(4) . .
C10B N2B Pt2 125.0(3) . .
C11B N2B Pt2 113.6(3) . .
N2B C11B C12B 107.8(4) . .
N2B C11B H11C 110.1 . .
C12B C11B H11C 110.1 . .
N2B C11B H11D 110.1 . .
C12B C11B H11D 110.1 . .
H11C C11B H11D 108.5 . .
C11B C12B P2B 108.9(3) . .
C11B C12B H12C 109.9 . .
P2B C12B H12C 109.9 . .
C11B C12B H12D 109.9 . .
P2B C12B H12D 109.9 . .
H12C C12B H12D 108.3 . .
C18B C13B C14B 118.5(5) . .
C18B C13B P1B 122.4(4) . .
C14B C13B P1B 119.0(4) . .
C15B C14B C13B 121.0(5) . .
C15B C14B H14B 119.5 . .
C13B C14B H14B 119.5 . .
C16B C15B C14B 119.1(6) . .
C16B C15B H15B 120.5 . .
C14B C15B H15B 120.5 . .
C15B C16B C17B 120.5(5) . .
C15B C16B H16B 119.8 . .
C17B C16B H16B 119.8 . .
C18B C17B C16B 120.2(5) . .
C18B C17B H17B 119.9 . .
C16B C17B H17B 119.9 . .
C17B C18B C13B 120.8(5) . .
C17B C18B H18B 119.6 . .
C13B C18B H18B 119.6 . .
C20B C19B C24B 118.5(5) . .
C20B C19B P1B 119.1(4) . .
C24B C19B P1B 122.4(4) . .
C19B C20B C21B 121.4(5) . .
C19B C20B H20B 119.3 . .
C21B C20B H20B 119.3 . .
C20B C21B C22B 119.6(6) . .
C20B C21B H21B 120.2 . .
C22B C21B H21B 120.2 . .
C23B C22B C21B 119.7(5) . .
C23B C22B H22B 120.2 . .
C21B C22B H22B 120.2 . .
C22B C23B C24B 121.0(5) . .
C22B C23B H23B 119.5 . .
C24B C23B H23B 119.5 . .
C23B C24B C19B 119.8(5) . .
C23B C24B H24B 120.1 . .
C19B C24B H24B 120.1 . .
C30B C25B C26B 118.6(5) . .
C30B C25B P2B 121.2(4) . .
C26B C25B P2B 119.9(4) . .
C27B C26B C25B 119.8(5) . .
C27B C26B H26B 120.1 . .
C25B C26B H26B 120.1 . .
C28B C27B C26B 120.8(5) . .
C28B C27B H27B 119.6 . .
C26B C27B H27B 119.6 . .
C27B C28B C29B 120.0(5) . .
C27B C28B H28B 120.0 . .
C29B C28B H28B 120.0 . .
C30B C29B C28B 119.7(5) . .
C30B C29B H29B 120.1 . .
C28B C29B H29B 120.1 . .
C29B C30B C25B 121.0(5) . .
C29B C30B H30B 119.5 . .
C25B C30B H30B 119.5 . .
C32B C31B C36B 118.7(5) . .
C32B C31B P2B 121.1(4) . .
C36B C31B P2B 119.6(4) . .
C31B C32B C33B 120.6(5) . .
C31B C32B H32B 119.7 . .
C33B C32B H32B 119.7 . .
C34B C33B C32B 120.4(6) . .
C34B C33B H33B 119.8 . .
C32B C33B H33B 119.8 . .
C33B C34B C35B 119.7(5) . .
C33B C34B H34B 120.2 . .
C35B C34B H34B 120.2 . .
C34B C35B C36B 120.0(6) . .
C34B C35B H35B 120.0 . .
C36B C35B H35B 120.0 . .
C35B C36B C31B 120.6(6) . .
C35B C36B H36B 119.7 . .
C31B C36B H36B 119.7 . .
C37B O3B Ag4 141.3(4) . .
C37B O3B Ag3 112.8(3) . 1_455
Ag4 O3B Ag3 102.28(14) . 1_455
O4B C37B O3B 129.6(5) . .
O4B C37B C38B 117.1(5) . .
O3B C37B C38B 113.3(5) . .
F8B C38B F7B 105.7(4) . .
F8B C38B F9B 106.3(5) . .
F7B C38B F9B 106.3(4) . .
F8B C38B C37B 113.6(5) . .
F7B C38B C37B 112.6(5) . .
F9B C38B C37B 111.8(4) . .
C39B O5B Ag3 99.5(4) . .
C39B O6B Ag4 134.7(4) . 1_655
O6B C39B O5B 128.4(7) . .
O6B C39B C40B 116.9(6) . .
O5B C39B C40B 114.8(5) . .
F12B C40B F11B 109.6(7) . .
F12B C40B F10B 106.8(6) . .
F11B C40B F10B 103.7(5) . .
F12B C40B C39B 111.4(5) . .
F11B C40B C39B 112.3(6) . .
F10B C40B C39B 112.7(6) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt1 N2A 2.055(4) .
Pt1 N1A 2.070(3) .
Pt1 P1A 2.2440(13) .
Pt1 P2A 2.2490(13) .
Ag1 O5A 2.247(4) .
Ag1 O3A 2.405(4) .
Ag1 O1A 2.410(3) .
Ag1 O1A 2.429(3) 2_566
Ag2 O6A 2.227(4) .
Ag2 O2A 2.311(3) .
Ag2 O2A 2.473(3) 2_556
Ag2 O4A 2.536(4) .
Ag2 O3A 2.572(4) .
P1A C19A 1.813(5) .
P1A C13A 1.817(5) .
P1A C1A 1.852(5) .
P2A C25A 1.800(5) .
P2A C31A 1.810(5) .
P2A C12A 1.832(5) .
C1A C2A 1.522(7) .
C1A H1A1 0.9900 .
C1A H1A2 0.9900 .
C2A N1A 1.465(6) .
C2A H2A1 0.9900 .
C2A H2A2 0.9900 .
N1A C3A 1.306(6) .
C3A O1A 1.274(5) .
C3A C4A 1.503(6) .
O1A Ag1 2.429(3) 2_566
C4A C9A 1.395(6) .
C4A C5A 1.397(7) .
C5A C6A 1.377(7) .
C5A H5A 0.9500 .
C6A C7A 1.381(7) .
C6A H6A 0.9500 .
C7A C8A 1.379(7) .
C7A H7A 0.9500 .
C8A C9A 1.390(6) .
C8A H8A 0.9500 .
C9A C10A 1.501(6) .
C10A O2A 1.266(5) .
C10A N2A 1.313(6) .
O2A Ag2 2.473(3) 2_556
N2A C11A 1.469(5) .
C11A C12A 1.533(6) .
C11A H11A 0.9900 .
C11A H11B 0.9900 .
C12A H12A 0.9900 .
C12A H12B 0.9900 .
C13A C14A 1.392(7) .
C13A C18A 1.392(7) .
C14A C15A 1.386(7) .
C14A H14A 0.9500 .
C15A C16A 1.375(8) .
C15A H15A 0.9500 .
C16A C17A 1.383(8) .
C16A H16A 0.9500 .
C17A C18A 1.382(7) .
C17A H17A 0.9500 .
C18A H18A 0.9500 .
C19A C20A 1.383(6) .
C19A C24A 1.388(7) .
C20A C21A 1.383(7) .
C20A H20A 0.9500 .
C21A C22A 1.382(7) .
C21A H21A 0.9500 .
C22A C23A 1.383(7) .
C22A H22A 0.9500 .
C23A C24A 1.394(7) .
C23A H23A 0.9500 .
C24A H24A 0.9500 .
C25A C26A 1.389(7) .
C25A C30A 1.395(6) .
C26A C27A 1.386(7) .
C26A H26A 0.9500 .
C27A C28A 1.381(7) .
C27A H27A 0.9500 .
C28A C29A 1.381(8) .
C28A H28A 0.9500 .
C29A C30A 1.370(7) .
C29A H29A 0.9500 .
C30A H30A 0.9500 .
C31A C32A 1.391(7) .
C31A C36A 1.394(7) .
C32A C33A 1.377(8) .
C32A H32A 0.9500 .
C33A C34A 1.383(8) .
C33A H33A 0.9500 .
C34A C35A 1.381(8) .
C34A H34A 0.9500 .
C35A C36A 1.366(7) .
C35A H35A 0.9500 .
C36A H36A 0.9500 .
O3A C37A 1.237(6) .
O4A C37A 1.229(6) .
C37A C38A 1.516(8) .
C38A F1A 1.324(7) .
C38A F3A 1.329(7) .
C38A F2A 1.341(6) .
O5A C39A 1.229(6) .
O6A C39A 1.237(6) .
C39A C40A 1.534(8) .
C40A F6A 1.312(6) .
C40A F4A 1.333(7) .
C40A F5A 1.345(7) .
Pt2 N2B 2.057(4) .
Pt2 N1B 2.059(4) .
Pt2 P1B 2.2489(13) .
Pt2 P2B 2.2502(15) .
Ag3 O3B 2.333(4) 1_655
Ag3 O1B 2.380(3) .
Ag3 O1B 2.431(3) 2_777
Ag3 O5B 2.434(4) .
Ag4 O2B 2.302(3) .
Ag4 O3B 2.307(4) .
Ag4 O6B 2.392(5) 1_455
Ag4 O2B 2.450(3) 2_677
P1B C13B 1.801(5) .
P1B C19B 1.811(5) .
P1B C1B 1.844(5) .
P2B C31B 1.808(5) .
P2B C25B 1.809(5) .
P2B C12B 1.851(5) .
C1B C2B 1.518(7) .
C1B H1B1 0.9900 .
C1B H1B2 0.9900 .
C2B N1B 1.463(6) .
C2B H2B1 0.9900 .
C2B H2B2 0.9900 .
N1B C3B 1.317(6) .
C3B O1B 1.268(5) .
C3B C4B 1.495(6) .
O1B Ag3 2.431(3) 2_777
C4B C5B 1.396(7) .
C4B C9B 1.396(7) .
C5B C6B 1.381(7) .
C5B H5B 0.9500 .
C6B C7B 1.384(8) .
C6B H6B 0.9500 .
C7B C8B 1.385(8) .
C7B H7B 0.9500 .
C8B C9B 1.402(7) .
C8B H8B 0.9500 .
C9B C10B 1.497(7) .
C10B O2B 1.265(5) .
C10B N2B 1.320(6) .
O2B Ag4 2.450(3) 2_677
N2B C11B 1.452(6) .
C11B C12B 1.529(7) .
C11B H11C 0.9900 .
C11B H11D 0.9900 .
C12B H12C 0.9900 .
C12B H12D 0.9900 .
C13B C18B 1.384(7) .
C13B C14B 1.398(7) .
C14B C15B 1.388(7) .
C14B H14B 0.9500 .
C15B C16B 1.380(8) .
C15B H15B 0.9500 .
C16B C17B 1.383(9) .
C16B H16B 0.9500 .
C17B C18B 1.375(7) .
C17B H17B 0.9500 .
C18B H18B 0.9500 .
C19B C20B 1.375(7) .
C19B C24B 1.394(7) .
C20B C21B 1.378(8) .
C20B H20B 0.9500 .
C21B C22B 1.382(8) .
C21B H21B 0.9500 .
C22B C23B 1.364(8) .
C22B H22B 0.9500 .
C23B C24B 1.382(8) .
C23B H23B 0.9500 .
C24B H24B 0.9500 .
C25B C30B 1.388(7) .
C25B C26B 1.397(7) .
C26B C27B 1.389(7) .
C26B H26B 0.9500 .
C27B C28B 1.362(8) .
C27B H27B 0.9500 .
C28B C29B 1.386(8) .
C28B H28B 0.9500 .
C29B C30B 1.377(7) .
C29B H29B 0.9500 .
C30B H30B 0.9500 .
C31B C32B 1.380(7) .
C31B C36B 1.386(7) .
C32B C33B 1.381(7) .
C32B H32B 0.9500 .
C33B C34B 1.372(8) .
C33B H33B 0.9500 .
C34B C35B 1.377(9) .
C34B H34B 0.9500 .
C35B C36B 1.384(8) .
C35B H35B 0.9500 .
C36B H36B 0.9500 .
O3B C37B 1.251(6) .
O3B Ag3 2.333(4) 1_455
O4B C37B 1.223(6) .
C37B C38B 1.542(7) .
C38B F8B 1.333(6) .
C38B F7B 1.336(6) .
C38B F9B 1.344(6) .
O5B C39B 1.229(7) .
O6B C39B 1.225(7) .
O6B Ag4 2.392(5) 1_655
C39B C40B 1.539(9) .
C40B F12B 1.291(8) .
C40B F11B 1.317(7) .
C40B F10B 1.327(7) .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
C1A H1A1 F4A 0.99 2.62 3.340(6) 129.3 1_455
C1A H1A1 F5A 0.99 2.53 3.517(6) 173.6 1_455
C11A H11A O6A 0.99 2.58 3.384(6) 138.1 2_556
C12A H12B F6A 0.99 2.47 3.254(6) 135.5 1_445
C32A H32A O4A 0.95 2.60 3.434(7) 146.4 2_556
C1B H1B2 O5B 0.99 2.63 3.599(7) 165.3 .
C2B H2B2 O4B 0.99 2.45 3.330(6) 148.5 1_655
C26B H26B O4B 0.95 2.54 3.199(7) 126.8 2_567
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C19A P1A C1A C2A 135.2(3) . .
C13A P1A C1A C2A -113.5(3) . .
Pt1 P1A C1A C2A 14.0(4) . .
P1A C1A C2A N1A -44.3(4) . .
C1A C2A N1A C3A -117.2(5) . .
C1A C2A N1A Pt1 60.0(4) . .
C2A N1A C3A O1A -15.2(7) . .
Pt1 N1A C3A O1A 167.9(3) . .
C2A N1A C3A C4A 155.3(4) . .
Pt1 N1A C3A C4A -21.6(6) . .
N1A C3A O1A Ag1 -158.7(4) . .
C4A C3A O1A Ag1 30.9(5) . .
N1A C3A O1A Ag1 -6.5(8) . 2_566
C4A C3A O1A Ag1 -176.9(3) . 2_566
O1A C3A C4A C9A -121.7(5) . .
N1A C3A C4A C9A 67.0(6) . .
O1A C3A C4A C5A 61.7(6) . .
N1A C3A C4A C5A -109.6(5) . .
C9A C4A C5A C6A 0.7(7) . .
C3A C4A C5A C6A 177.6(4) . .
C4A C5A C6A C7A -0.1(8) . .
C5A C6A C7A C8A 0.9(8) . .
C6A C7A C8A C9A -2.4(8) . .
C7A C8A C9A C4A 3.0(7) . .
C7A C8A C9A C10A -175.5(5) . .
C5A C4A C9A C8A -2.1(7) . .
C3A C4A C9A C8A -178.5(4) . .
C5A C4A C9A C10A 176.3(4) . .
C3A C4A C9A C10A -0.2(8) . .
C8A C9A C10A O2A -51.3(6) . .
C4A C9A C10A O2A 130.4(5) . .
C8A C9A C10A N2A 123.5(5) . .
C4A C9A C10A N2A -54.8(6) . .
N2A C10A O2A Ag2 160.2(4) . .
C9A C10A O2A Ag2 -25.4(5) . .
N2A C10A O2A Ag2 -72.0(6) . 2_556
C9A C10A O2A Ag2 102.4(4) . 2_556
O2A C10A N2A C11A 16.4(7) . .
C9A C10A N2A C11A -158.1(4) . .
O2A C10A N2A Pt1 175.1(3) . .
C9A C10A N2A Pt1 0.7(6) . .
C10A N2A C11A C12A 100.1(5) . .
Pt1 N2A C11A C12A -61.1(4) . .
N2A C11A C12A P2A 50.4(4) . .
C25A P2A C12A C11A 101.4(3) . .
C31A P2A C12A C11A -145.1(3) . .
Pt1 P2A C12A C11A -22.6(3) . .
C19A P1A C13A C14A 148.9(4) . .
C1A P1A C13A C14A 36.1(4) . .
Pt1 P1A C13A C14A -80.1(4) . .
C19A P1A C13A C18A -36.3(4) . .
C1A P1A C13A C18A -149.2(4) . .
Pt1 P1A C13A C18A 94.6(4) . .
C18A C13A C14A C15A -0.4(7) . .
P1A C13A C14A C15A 174.4(4) . .
C13A C14A C15A C16A 0.3(7) . .
C14A C15A C16A C17A 0.5(8) . .
C15A C16A C17A C18A -1.3(8) . .
C16A C17A C18A C13A 1.3(8) . .
C14A C13A C18A C17A -0.4(7) . .
P1A C13A C18A C17A -175.1(4) . .
C13A P1A C19A C20A 126.5(4) . .
C1A P1A C19A C20A -120.5(4) . .
Pt1 P1A C19A C20A -7.6(4) . .
C13A P1A C19A C24A -54.1(4) . .
C1A P1A C19A C24A 58.9(5) . .
Pt1 P1A C19A C24A 171.9(4) . .
C24A C19A C20A C21A 1.9(7) . .
P1A C19A C20A C21A -178.6(4) . .
C19A C20A C21A C22A -1.3(7) . .
C20A C21A C22A C23A -0.7(8) . .
C21A C22A C23A C24A 2.0(8) . .
C20A C19A C24A C23A -0.7(8) . .
P1A C19A C24A C23A 179.9(4) . .
C22A C23A C24A C19A -1.2(8) . .
C31A P2A C25A C26A 144.9(4) . .
C12A P2A C25A C26A -100.9(4) . .
Pt1 P2A C25A C26A 12.7(5) . .
C31A P2A C25A C30A -43.1(5) . .
C12A P2A C25A C30A 71.1(4) . .
Pt1 P2A C25A C30A -175.2(3) . .
C30A C25A C26A C27A 2.4(7) . .
P2A C25A C26A C27A 174.5(4) . .
C25A C26A C27A C28A -1.9(8) . .
C26A C27A C28A C29A 0.0(8) . .
C27A C28A C29A C30A 1.4(8) . .
C28A C29A C30A C25A -0.8(8) . .
C26A C25A C30A C29A -1.0(8) . .
P2A C25A C30A C29A -173.3(4) . .
C25A P2A C31A C32A 153.6(4) . .
C12A P2A C31A C32A 43.0(4) . .
Pt1 P2A C31A C32A -72.2(4) . .
C25A P2A C31A C36A -32.1(4) . .
C12A P2A C31A C36A -142.8(4) . .
Pt1 P2A C31A C36A 102.0(4) . .
C36A C31A C32A C33A 0.1(7) . .
P2A C31A C32A C33A 174.5(4) . .
C31A C32A C33A C34A 0.4(8) . .
C32A C33A C34A C35A -0.8(8) . .
C33A C34A C35A C36A 0.8(8) . .
C34A C35A C36A C31A -0.4(8) . .
C32A C31A C36A C35A -0.1(7) . .
P2A C31A C36A C35A -174.4(4) . .
Ag2 O4A C37A O3A -16.1(6) . .
Ag2 O4A C37A C38A 163.7(4) . .
Ag1 O3A C37A O4A 117.7(7) . .
Ag2 O3A C37A O4A 15.8(6) . .
Ag1 O3A C37A C38A -62.1(8) . .
Ag2 O3A C37A C38A -163.9(4) . .
O4A C37A C38A F1A 49.4(7) . .
O3A C37A C38A F1A -130.8(5) . .
O4A C37A C38A F3A -71.0(6) . .
O3A C37A C38A F3A 108.8(6) . .
O4A C37A C38A F2A 172.0(5) . .
O3A C37A C38A F2A -8.2(7) . .
Ag1 O5A C39A O6A 1.0(11) . .
Ag1 O5A C39A C40A -175.4(4) . .
Ag2 O6A C39A O5A -0.6(10) . .
Ag2 O6A C39A C40A 176.0(4) . .
O5A C39A C40A F6A -10.8(8) . .
O6A C39A C40A F6A 172.1(5) . .
O5A C39A C40A F4A -133.6(5) . .
O6A C39A C40A F4A 49.2(7) . .
O5A C39A C40A F5A 109.1(5) . .
O6A C39A C40A F5A -68.1(6) . .
C13B P1B C1B C2B -105.7(4) . .
C19B P1B C1B C2B 141.7(3) . .
Pt2 P1B C1B C2B 18.5(4) . .
P1B C1B C2B N1B -48.1(4) . .
C1B C2B N1B C3B -108.9(5) . .
C1B C2B N1B Pt2 61.4(4) . .
C2B N1B C3B O1B -14.5(7) . .
Pt2 N1B C3B O1B 176.7(3) . .
C2B N1B C3B C4B 158.7(4) . .
Pt2 N1B C3B C4B -10.1(6) . .
N1B C3B O1B Ag3 73.7(6) . .
C4B C3B O1B Ag3 -99.6(4) . .
N1B C3B O1B Ag3 -164.8(4) . 2_777
C4B C3B O1B Ag3 21.9(5) . 2_777
O1B C3B C4B C5B 52.2(6) . .
N1B C3B C4B C5B -121.5(5) . .
O1B C3B C4B C9B -128.5(5) . .
N1B C3B C4B C9B 57.8(7) . .
C9B C4B C5B C6B -0.5(7) . .
C3B C4B C5B C6B 178.9(4) . .
C4B C5B C6B C7B 1.3(8) . .
C5B C6B C7B C8B 0.0(8) . .
C6B C7B C8B C9B -2.0(8) . .
C5B C4B C9B C8B -1.5(7) . .
C3B C4B C9B C8B 179.2(4) . .
C5B C4B C9B C10B -178.9(4) . .
C3B C4B C9B C10B 1.8(8) . .
C7B C8B C9B C4B 2.8(8) . .
C7B C8B C9B C10B -179.5(5) . .
C4B C9B C10B O2B 123.1(5) . .
C8B C9B C10B O2B -54.4(6) . .
C4B C9B C10B N2B -61.6(7) . .
C8B C9B C10B N2B 120.9(5) . .
N2B C10B O2B Ag4 -42.8(8) . .
C9B C10B O2B Ag4 132.2(4) . .
N2B C10B O2B Ag4 160.0(4) . 2_677
C9B C10B O2B Ag4 -25.0(5) . 2_677
O2B C10B N2B C11B 9.0(8) . .
C9B C10B N2B C11B -165.9(4) . .
O2B C10B N2B Pt2 -173.4(4) . .
C9B C10B N2B Pt2 11.8(6) . .
C10B N2B C11B C12B 119.0(5) . .
Pt2 N2B C11B C12B -59.0(4) . .
N2B C11B C12B P2B 37.4(5) . .
C31B P2B C12B C11B -124.4(4) . .
C25B P2B C12B C11B 122.4(4) . .
Pt2 P2B C12B C11B -5.6(4) . .
C19B P1B C13B C18B 17.3(5) . .
C1B P1B C13B C18B -97.0(5) . .
Pt2 P1B C13B C18B 149.2(4) . .
C19B P1B C13B C14B -165.6(4) . .
C1B P1B C13B C14B 80.2(4) . .
Pt2 P1B C13B C14B -33.6(5) . .
C18B C13B C14B C15B 0.7(8) . .
P1B C13B C14B C15B -176.5(4) . .
C13B C14B C15B C16B -0.3(8) . .
C14B C15B C16B C17B -0.1(8) . .
C15B C16B C17B C18B 0.0(9) . .
C16B C17B C18B C13B 0.5(9) . .
C14B C13B C18B C17B -0.8(8) . .
P1B C13B C18B C17B 176.4(4) . .
C13B P1B C19B C20B 81.3(4) . .
C1B P1B C19B C20B -166.0(4) . .
Pt2 P1B C19B C20B -51.6(4) . .
C13B P1B C19B C24B -98.0(4) . .
C1B P1B C19B C24B 14.8(5) . .
Pt2 P1B C19B C24B 129.2(4) . .
C24B C19B C20B C21B 2.2(8) . .
P1B C19B C20B C21B -177.1(4) . .
C19B C20B C21B C22B -0.1(9) . .
C20B C21B C22B C23B -2.1(9) . .
C21B C22B C23B C24B 2.3(9) . .
C22B C23B C24B C19B -0.2(8) . .
C20B C19B C24B C23B -2.0(8) . .
P1B C19B C24B C23B 177.2(4) . .
C31B P2B C25B C30B 45.1(4) . .
C12B P2B C25B C30B 156.6(4) . .
Pt2 P2B C25B C30B -85.9(4) . .
C31B P2B C25B C26B -140.5(4) . .
C12B P2B C25B C26B -28.9(5) . .
Pt2 P2B C25B C26B 88.6(4) . .
C30B C25B C26B C27B 1.4(7) . .
P2B C25B C26B C27B -173.2(4) . .
C25B C26B C27B C28B -1.5(8) . .
C26B C27B C28B C29B 1.3(8) . .
C27B C28B C29B C30B -1.0(8) . .
C28B C29B C30B C25B 0.9(8) . .
C26B C25B C30B C29B -1.1(7) . .
P2B C25B C30B C29B 173.4(4) . .
C25B P2B C31B C32B 40.8(5) . .
C12B P2B C31B C32B -73.3(5) . .
Pt2 P2B C31B C32B 175.4(4) . .
C25B P2B C31B C36B -148.5(4) . .
C12B P2B C31B C36B 97.4(5) . .
Pt2 P2B C31B C36B -14.0(5) . .
C36B C31B C32B C33B 1.8(8) . .
P2B C31B C32B C33B 172.5(4) . .
C31B C32B C33B C34B 0.2(9) . .
C32B C33B C34B C35B -1.8(10) . .
C33B C34B C35B C36B 1.4(10) . .
C34B C35B C36B C31B 0.6(10) . .
C32B C31B C36B C35B -2.2(9) . .
P2B C31B C36B C35B -173.1(5) . .
Ag4 O3B C37B O4B 152.5(4) . .
Ag3 O3B C37B O4B -1.0(7) 1_455 .
Ag4 O3B C37B C38B -28.6(7) . .
Ag3 O3B C37B C38B 177.9(3) 1_455 .
O4B C37B C38B F8B -4.8(7) . .
O3B C37B C38B F8B 176.2(4) . .
O4B C37B C38B F7B 115.3(5) . .
O3B C37B C38B F7B -63.7(6) . .
O4B C37B C38B F9B -125.1(5) . .
O3B C37B C38B F9B 55.9(6) . .
Ag4 O6B C39B O5B 91.6(9) 1_655 .
Ag4 O6B C39B C40B -89.6(7) 1_655 .
Ag3 O5B C39B O6B -16.7(7) . .
Ag3 O5B C39B C40B 164.4(4) . .
O6B C39B C40B F12B -114.1(7) . .
O5B C39B C40B F12B 64.9(8) . .
O6B C39B C40B F11B 9.2(8) . .
O5B C39B C40B F11B -171.8(6) . .
O6B C39B C40B F10B 125.9(6) . .
O5B C39B C40B F10B -55.1(8) . .
