Information card for entry 4110415

Structure parameters

• Formula: C34 H70 Co N P2 Si5
• Calculated formula: C34 H70 Co N P2 Si5
• SMILES: [CoH3]1([P](C[Si](N2[Si](C)(C)C[P+]([SiH]12)(C(C)(C)C)C(C)(C)C)(C)C)(C(C)(C)C)C(C)(C)C)([SiH2]c1ccccc1)[SiH2]c1ccccc1
• Title of publication: Three-Coordinate Co(I) Provides Access to Unsaturated Dihydrido-Co(III) and Seven-Coordinate Co(V)
• Authors of publication: Michael Ingleson; Hongjun Fan; Maren Pink; John Tomaszewski; Kenneth G. Caulton
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2006
• Journal volume: 128
• Pages of publication: 1804 - 1805
• a: 18.9727 ± 0.0007 Å
• b: 11.871 ± 0.0004 Å
• c: 18.5326 ± 0.0006 Å
• α: 90°
• β: 93.429 ± 0.001°
• γ: 90°
• Cell volume: 4166.5 ± 0.2 ų
• Cell temperature: 130 ± 2 K
• Ambient diffraction temperature: 130 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0624
• Residual factor for significantly intense reflections: 0.0413
• Weighted residual factors for significantly intense reflections: 0.1
• Weighted residual factors for all reflections included in the refinement: 0.1132
• Goodness-of-fit parameter for all reflections included in the refinement: 1.018
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No