Information card for entry 4123151

Structure parameters

• Formula: C21 H43 P3 Si W
• Calculated formula: C21 H43 P3 Si W
• SMILES: [WH5]([P](C)(C)C)([P](C)(C)C)([P](C)(C)C)[SiH](c1ccccc1)c1ccccc1
• Title of publication: σ-Silane, Disilanyl, and [W(μ-H)Si(μ-H)W] Bridging Silylene Complexes via the Reactions of W(PMe3)4(η(2)-CH2PMe2)H with Phenylsilanes.
• Authors of publication: Zuzek, Ashley A.; Neary, Michelle C.; Parkin, Gerard
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2014
• Pages of publication: 141217070549000
• a: 9.5594 ± 0.0007 Å
• b: 9.4055 ± 0.0007 Å
• c: 29.378 ± 0.002 Å
• α: 90°
• β: 91.234 ± 0.001°
• γ: 90°
• Cell volume: 2640.8 ± 0.3 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0487
• Residual factor for significantly intense reflections: 0.0382
• Weighted residual factors for significantly intense reflections: 0.0696
• Weighted residual factors for all reflections included in the refinement: 0.0724
• Goodness-of-fit parameter for all reflections included in the refinement: 1.154
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No