Information card for entry 4324041

Structure parameters

• Formula: C54 H35 Au O12 P2 Rh2 Ru2
• Calculated formula: C54 H35 Au O12 P2 Rh2 Ru2
• SMILES: [Ru]12345([Ru]678([Rh]9%101([Rh]26(C#[O])(C4=O)(C8=O)(C9=O)[Au]5%10[P](c1ccccc1)(c1ccccc1)c1ccccc1)(C#[O])(C3=O)C7=O)(C#[O])(C#[O])C#[O])(C#[O])C#[O].[P+](c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1
• Title of publication: Mixed Ruthenium-Rhodium Carbonyl Clusters. Synthesis and Crystal Structure of the [PPh4]+ Salts of the Anions [Ru2Rh2(CO)7(μ-CO)5]2-, [Ru2Rh2(CO)9(μ-CO)3(μ-H)]-, and [Ru2Rh2(CO)7(μ-CO)5(μ3-AuPPh3)]-
• Authors of publication: Alessandro Fumagalli; Davide Italia; Maria Carlotta Malatesta; Gianfranco Ciani; Massimo Moret; Angelo Sironi
• Journal of publication: Inorganic Chemistry
• Year of publication: 1996
• Journal volume: 35
• Pages of publication: 1765 - 1772
• a: 11.72 ± 0.002 Å
• b: 13.133 ± 0.003 Å
• c: 35.614 ± 0.002 Å
• α: 90°
• β: 95.7 ± 0.01°
• γ: 90°
• Cell volume: 5454.6 ± 1.6 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0539
• Residual factor for significantly intense reflections: 0.0522
• Weighted residual factors for all reflections: 0.1268
• Weighted residual factors for significantly intense reflections: 0.1156
• Goodness-of-fit parameter for all reflections: 1.074
• Goodness-of-fit parameter for significantly intense reflections: 1.074
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No