Information card for entry 4324048

Structure parameters

• Common name: Ditechnetium tetrachloro tetra(dimethylphenylphosphine) hexafluorophosphate
• Chemical name: Ditechnetium tetrachloro tetra(dimethylphenylphosphine) hexafluorophosphate
• Formula: C34 H48 Cl4 F6 O0.5 P5 Tc2
• Calculated formula: C34 H48 Cl4 F6 O0.5 P5 Tc2
• Title of publication: Metal-Metal Multiply-Bonded Complexes of Technetium. 3.1 Preparation and Characterization of Phosphine Complexes of Technetium Possessing a Metal-Metal Bond Order of 3.5
• Authors of publication: F. Albert Cotton; Steven C. Haefner; Alfred P. Sattelberger
• Journal of publication: Inorganic Chemistry
• Year of publication: 1996
• Journal volume: 35
• Pages of publication: 1831 - 1838
• a: 10.58 ± 0.003 Å
• b: 33.327 ± 0.003 Å
• c: 13.861 ± 0.003 Å
• α: 90°
• β: 111.04 ± 0.02°
• γ: 90°
• Cell volume: 4561.5 ± 1.8 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0681
• Residual factor for significantly intense reflections: 0.0504
• Weighted residual factors for all reflections: 0.1545
• Weighted residual factors for significantly intense reflections: 0.1412
• Goodness-of-fit parameter for all reflections: 1.079
• Goodness-of-fit parameter for significantly intense reflections: 1.111
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No