#------------------------------------------------------------------------------
#$Date: 2016-03-23 21:19:03 +0100 (Wed 23 de Mar de 2016) $
#$Revision: 179476 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/73/4337369.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4337369
loop_
_publ_author_name
'Naik, Susmita'
'Kumaravel, Maruthai'
'Mague, Joel T.'
'Balakrishna, Maravanji S.'
_publ_section_title
;
 Novel Trisphosphine Ligand Containing 1,3,5-Triazine Core,
 [2,4,6-C3N3{C6H4PPh2-p}3]: Synthesis and Transition Metal Chemistry.
;
_journal_issue                   3
_journal_name_full               'Inorganic chemistry'
_journal_page_first              1370
_journal_page_last               1381
_journal_paper_doi               10.1021/ic402150k
_journal_volume                  53
_journal_year                    2014
_chemical_formula_moiety         'C114 H84 Cl6 N6 P6 Pt3'
_chemical_formula_sum            'C114 H84 Cl6 N6 P6 Pt3'
_chemical_formula_weight         2521.66
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     heavy
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 123.357(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   34.660(6)
_cell_length_b                   19.562(4)
_cell_length_c                   20.249(4)
_cell_measurement_reflns_used    9925
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      25.78
_cell_measurement_theta_min      2.35
_cell_volume                     11467(4)
_computing_cell_refinement       'Bruker SAINT (Bruker-AXS, 2009)'
_computing_data_collection       'Bruker APEX2 (Bruker-AXS, 2010)'
_computing_data_reduction        'Bruker SAINT (Bruker-AXS, 2009)'
_computing_molecular_graphics    'Bruker SHELXTL (Bruker-AXS, 2008)'
_computing_publication_material  'Bruker SHELXTL (Bruker-AXS, 2008)'
_computing_structure_refinement  'SHELXL (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS (Sheldrick, 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'Bruker Smart APEX CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0712
_diffrn_reflns_av_sigmaI/netI    0.0694
_diffrn_reflns_limit_h_max       42
_diffrn_reflns_limit_h_min       -42
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            41889
_diffrn_reflns_theta_full        25.79
_diffrn_reflns_theta_max         25.79
_diffrn_reflns_theta_min         1.26
_exptl_absorpt_coefficient_mu    3.921
_exptl_absorpt_correction_T_max  0.6098
_exptl_absorpt_correction_T_min  0.4244
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick, 2009)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.461
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             4944
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.14
_refine_diff_density_max         7.071
_refine_diff_density_min         -3.428
_refine_diff_density_rms         0.249
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.066
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     597
_refine_ls_number_reflns         10923
_refine_ls_number_restraints     73
_refine_ls_restrained_S_all      1.064
_refine_ls_R_factor_all          0.0951
_refine_ls_R_factor_gt           0.0702
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1315P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1866
_refine_ls_wR_factor_ref         0.2080
_reflns_number_gt                7451
_reflns_number_total             10923
_reflns_threshold_expression     >2σ(I)
_cod_data_source_file            ic402150k_si_001.cif
_cod_data_source_block           msb494_0m
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/usr/data/users/saulius/automatic-downloads/current/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 
;
_cod_original_cell_volume        11468(4)
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               4337369
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.760601(12) 0.559793(19) 0.34744(2) 0.03054(15) Uani 1 1 d . A .
Pt2 Pt 1.0000 1.19869(2) 0.7500 0.03004(17) Uani 1 2 d S . .
Cl1 Cl 0.69638(8) 0.49315(13) 0.31432(15) 0.0389(6) Uani 1 1 d . . .
Cl2 Cl 0.73106(9) 0.57075(17) 0.21143(15) 0.0503(7) Uani 1 1 d . . .
Cl3 Cl 1.05218(9) 1.28422(13) 0.76797(18) 0.0470(7) Uani 1 1 d . . .
P1 P 0.78142(8) 0.54258(11) 0.47302(14) 0.0246(5) Uani 1 1 d . . .
P2 P 0.81806(9) 0.62428(14) 0.35895(15) 0.0329(6) Uani 1 1 d D . .
P3 P 1.05536(8) 1.12981(11) 0.76191(14) 0.0236(5) Uani 1 1 d . . .
N1 N 1.0290(2) 0.6849(4) 0.7001(4) 0.0240(16) Uani 1 1 d . . .
N2 N 1.0742(2) 0.7823(4) 0.7695(4) 0.0246(16) Uani 1 1 d . . .
N3 N 0.9974(2) 0.7968(3) 0.6579(4) 0.0245(16) Uani 1 1 d . . .
C1 C 0.8260(3) 0.5927(4) 0.5557(5) 0.0212(18) Uani 1 1 d . . .
C2 C 0.8155(3) 0.6536(4) 0.5792(5) 0.026(2) Uani 1 1 d . . .
H2 H 0.7843 0.6686 0.5518 0.032 Uiso 1 1 calc R . .
C3 C 0.8492(3) 0.6922(4) 0.6412(5) 0.0257(19) Uani 1 1 d . . .
H3 H 0.8414 0.7332 0.6564 0.031 Uiso 1 1 calc R . .
C4 C 0.8950(3) 0.6706(4) 0.6812(5) 0.0211(18) Uani 1 1 d . . .
C5 C 0.9067(3) 0.6093(4) 0.6611(5) 0.026(2) Uani 1 1 d . . .
H5 H 0.9377 0.5938 0.6899 0.032 Uiso 1 1 calc R . .
C6 C 0.8719(3) 0.5713(4) 0.5978(5) 0.0236(19) Uani 1 1 d . . .
H6 H 0.8797 0.5300 0.5832 0.028 Uiso 1 1 calc R . .
C7 C 0.8014(3) 0.4561(4) 0.5038(6) 0.028(2) Uani 1 1 d . . .
C8 C 0.8006(4) 0.4114(5) 0.4507(6) 0.042(3) Uani 1 1 d . . .
H8 H 0.7878 0.4264 0.3979 0.051 Uiso 1 1 calc R . .
C9 C 0.8179(4) 0.3445(6) 0.4712(7) 0.057(3) Uani 1 1 d . . .
H9 H 0.8166 0.3145 0.4331 0.068 Uiso 1 1 calc R . .
C10 C 0.8371(4) 0.3234(5) 0.5488(7) 0.051(3) Uani 1 1 d . . .
H10 H 0.8503 0.2791 0.5648 0.061 Uiso 1 1 calc R . .
C11 C 0.8371(4) 0.3668(5) 0.6032(6) 0.042(3) Uani 1 1 d . . .
H11 H 0.8488 0.3514 0.6555 0.051 Uiso 1 1 calc R . .
C12 C 0.8198(3) 0.4329(5) 0.5807(6) 0.034(2) Uani 1 1 d . . .
H12 H 0.8206 0.4628 0.6185 0.041 Uiso 1 1 calc R . .
C13 C 0.7327(3) 0.5606(5) 0.4833(5) 0.027(2) Uani 1 1 d . . .
C14 C 0.7077(3) 0.6197(5) 0.4474(5) 0.027(2) Uani 1 1 d . . .
H14 H 0.7124 0.6442 0.4119 0.032 Uiso 1 1 calc R . .
C15 C 0.6763(3) 0.6426(5) 0.4630(6) 0.032(2) Uani 1 1 d . . .
H15 H 0.6589 0.6827 0.4378 0.039 Uiso 1 1 calc R . .
C16 C 0.6697(3) 0.6079(5) 0.5152(6) 0.041(3) Uani 1 1 d . . .
H16 H 0.6490 0.6250 0.5281 0.049 Uiso 1 1 calc R . .
C17 C 0.6936(4) 0.5479(6) 0.5483(7) 0.045(3) Uani 1 1 d . . .
H17 H 0.6877 0.5225 0.5819 0.054 Uiso 1 1 calc R . .
C18 C 0.7260(3) 0.5235(5) 0.5339(6) 0.034(2) Uani 1 1 d . . .
H18 H 0.7429 0.4828 0.5582 0.040 Uiso 1 1 calc R . .
C19 C 0.8472(4) 0.5802(6) 0.3185(6) 0.042(3) Uani 1 1 d . A .
C20 C 0.8812(4) 0.6129(7) 0.3143(7) 0.058(3) Uani 1 1 d . . .
H20 H 0.8848 0.6611 0.3210 0.069 Uiso 1 1 calc R A .
C21 C 0.9105(4) 0.5748(7) 0.3000(7) 0.056(3) Uani 1 1 d . A .
H21 H 0.9339 0.5971 0.2972 0.067 Uiso 1 1 calc R . .
C22 C 0.9049(4) 0.5045(7) 0.2902(7) 0.058(3) Uani 1 1 d . . .
H22 H 0.9258 0.4781 0.2843 0.070 Uiso 1 1 calc R A .
C23 C 0.8693(5) 0.4733(8) 0.2888(9) 0.068(4) Uani 1 1 d . A .
H23 H 0.8636 0.4259 0.2772 0.082 Uiso 1 1 calc R . .
C24 C 0.8411(5) 0.5121(6) 0.3050(8) 0.058(3) Uani 1 1 d . . .
H24 H 0.8172 0.4898 0.3064 0.069 Uiso 1 1 calc R A .
C25 C 0.7931(3) 0.7077(3) 0.3102(5) 0.044(3) Uani 0.50 1 d PGDU A 1
C26 C 0.8182(3) 0.7568(5) 0.2996(7) 0.052(4) Uani 0.50 1 d PGU A 1
H26 H 0.8478 0.7459 0.3101 0.063 Uiso 0.50 1 calc PR A 1
C27 C 0.8001(3) 0.8220(4) 0.2737(8) 0.059(5) Uani 0.50 1 d PGU A 1
H27 H 0.8172 0.8555 0.2665 0.071 Uiso 0.50 1 calc PR A 1
C28 C 0.7568(3) 0.8380(4) 0.2583(6) 0.059(3) Uani 0.50 1 d PGU A 1
H28 H 0.7444 0.8825 0.2406 0.071 Uiso 0.50 1 calc PR A 1
C29 C 0.7316(3) 0.7889(5) 0.2689(7) 0.051(4) Uani 0.50 1 d PGU A 1
H29 H 0.7021 0.7998 0.2584 0.061 Uiso 0.50 1 calc PR A 1
C30 C 0.7498(3) 0.7237(4) 0.2948(7) 0.054(5) Uani 0.50 1 d PGU A 1
H30 H 0.7326 0.6901 0.3020 0.065 Uiso 0.50 1 calc PR A 1
C25A C 0.7922(3) 0.7079(3) 0.3107(5) 0.044(3) Uani 0.50 1 d PGDU A 2
C26A C 0.8016(4) 0.7429(5) 0.2613(7) 0.052(4) Uani 0.50 1 d PGU A 2
H26A H 0.8195 0.7217 0.2445 0.063 Uiso 0.50 1 calc PR A 2
C27A C 0.7849(4) 0.8088(5) 0.2366(7) 0.059(5) Uani 0.50 1 d PGU A 2
H27A H 0.7914 0.8327 0.2029 0.071 Uiso 0.50 1 calc PR A 2
C28A C 0.7588(3) 0.8398(3) 0.2612(6) 0.059(3) Uani 0.50 1 d PGU A 2
H28A H 0.7474 0.8849 0.2443 0.071 Uiso 0.50 1 calc PR A 2
C29A C 0.7494(4) 0.8048(5) 0.3106(7) 0.051(4) Uani 0.50 1 d PGU A 2
H29A H 0.7316 0.8260 0.3274 0.061 Uiso 0.50 1 calc PR A 2
C30A C 0.7661(4) 0.7389(5) 0.3353(6) 0.054(5) Uani 0.50 1 d PGU A 2
H30A H 0.7597 0.7150 0.3690 0.065 Uiso 0.50 1 calc PR A 2
C31 C 0.8699(3) 0.6498(6) 0.4529(5) 0.035(2) Uani 1 1 d . A .
C32 C 0.9099(4) 0.6103(5) 0.4884(5) 0.034(2) Uani 1 1 d . . .
H32 H 0.9091 0.5665 0.4675 0.041 Uiso 1 1 calc R A .
C33 C 0.9511(4) 0.6343(4) 0.5543(6) 0.031(2) Uani 1 1 d . A .
H33 H 0.9785 0.6075 0.5781 0.037 Uiso 1 1 calc R . .
C34 C 0.9514(3) 0.6995(4) 0.5849(5) 0.025(2) Uani 1 1 d . . .
C35 C 0.9114(3) 0.7368(5) 0.5516(5) 0.032(2) Uani 1 1 d . A .
H35 H 0.9121 0.7804 0.5729 0.038 Uiso 1 1 calc R . .
C36 C 0.8701(3) 0.7123(5) 0.4876(6) 0.034(2) Uani 1 1 d . . .
H36 H 0.8422 0.7373 0.4674 0.041 Uiso 1 1 calc R A .
C37 C 0.9947(3) 0.7281(5) 0.6508(5) 0.0243(19) Uani 1 1 d . A .
C38 C 1.0673(3) 0.7138(4) 0.7583(5) 0.0234(18) Uani 1 1 d . . .
C39 C 1.0376(3) 0.8214(4) 0.7169(5) 0.0266(19) Uani 1 1 d . . .
C40 C 1.0418(3) 0.8966(4) 0.7280(5) 0.0239(19) Uani 1 1 d . . .
C41 C 1.0082(3) 0.9382(4) 0.6700(5) 0.0237(19) Uani 1 1 d . . .
H41 H 0.9828 0.9196 0.6224 0.028 Uiso 1 1 calc R . .
C42 C 1.0129(3) 1.0087(4) 0.6836(5) 0.027(2) Uani 1 1 d . . .
H42 H 0.9904 1.0385 0.6439 0.033 Uiso 1 1 calc R . .
C43 C 1.0499(3) 1.0370(4) 0.7544(5) 0.0249(19) Uani 1 1 d . . .
C44 C 1.0836(3) 0.9934(5) 0.8123(6) 0.030(2) Uani 1 1 d . . .
H44 H 1.1091 1.0114 0.8602 0.036 Uiso 1 1 calc R . .
C45 C 1.0791(3) 0.9231(5) 0.7986(5) 0.028(2) Uani 1 1 d . . .
H45 H 1.1017 0.8930 0.8376 0.034 Uiso 1 1 calc R . .
C46 C 1.0634(3) 1.1424(5) 0.6806(6) 0.031(2) Uani 1 1 d . . .
C47 C 1.0935(4) 1.1004(5) 0.6749(7) 0.041(2) Uani 1 1 d . . .
H47 H 1.1132 1.0701 0.7170 0.049 Uiso 1 1 calc R . .
C48 C 1.0953(4) 1.1024(6) 0.6066(8) 0.054(3) Uani 1 1 d . . .
H48 H 1.1162 1.0737 0.6029 0.065 Uiso 1 1 calc R . .
C49 C 1.0668(5) 1.1457(7) 0.5462(8) 0.067(4) Uani 1 1 d . . .
H49 H 1.0676 1.1461 0.5001 0.080 Uiso 1 1 calc R . .
C50 C 1.0368(4) 1.1891(7) 0.5508(7) 0.053(3) Uani 1 1 d . . .
H50 H 1.0175 1.2195 0.5085 0.064 Uiso 1 1 calc R . .
C51 C 1.0354(4) 1.1876(6) 0.6187(7) 0.044(3) Uani 1 1 d . . .
H51 H 1.0151 1.2175 0.6227 0.053 Uiso 1 1 calc R . .
C52 C 1.1090(3) 1.1428(5) 0.8585(6) 0.035(2) Uani 1 1 d . . .
C53 C 1.1517(4) 1.1462(6) 0.8685(7) 0.053(3) Uani 1 1 d . . .
H53 H 1.1536 1.1466 0.8235 0.064 Uiso 1 1 calc R . .
C54 C 1.1914(4) 1.1491(8) 0.9432(8) 0.067(4) Uani 1 1 d . . .
H54 H 1.2208 1.1510 0.9501 0.080 Uiso 1 1 calc R . .
C55 C 1.1879(5) 1.1493(5) 1.0068(8) 0.059(4) Uani 1 1 d . . .
H55 H 1.2154 1.1505 1.0583 0.071 Uiso 1 1 calc R . .
C56 C 1.1473(5) 1.1477(6) 1.0000(7) 0.057(3) Uani 1 1 d . . .
H56 H 1.1455 1.1486 1.0452 0.068 Uiso 1 1 calc R . .
C57 C 1.1069(4) 1.1447(6) 0.9219(7) 0.052(3) Uani 1 1 d . . .
H57 H 1.0775 1.1439 0.9150 0.063 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
P1 Pt1 P2 104.47(9) . .
P1 Pt1 Cl1 84.49(9) . .
P2 Pt1 Cl1 171.02(9) . .
P1 Pt1 Cl2 173.46(9) . .
P2 Pt1 Cl2 82.06(9) . .
Cl1 Pt1 Cl2 88.98(9) . .
P3 Pt2 P3 106.30(12) . 2_756
P3 Pt2 Cl3 82.57(9) . .
P3 Pt2 Cl3 170.66(9) 2_756 .
P3 Pt2 Cl3 170.66(9) . 2_756
P3 Pt2 Cl3 82.57(9) 2_756 2_756
Cl3 Pt2 Cl3 88.74(13) . 2_756
C7 P1 C1 102.6(4) . .
C7 P1 C13 109.9(4) . .
C1 P1 C13 99.2(4) . .
C7 P1 Pt1 110.7(3) . .
C1 P1 Pt1 122.7(3) . .
C13 P1 Pt1 110.7(3) . .
C31 P2 C19 97.3(5) . .
C31 P2 C25 102.6(5) . .
C19 P2 C25 112.8(5) . .
C31 P2 C25A 102.7(5) . .
C19 P2 C25A 113.8(5) . .
C25 P2 C25A 1.1 . .
C31 P2 Pt1 124.5(3) . .
C19 P2 Pt1 111.3(4) . .
C25 P2 Pt1 108.0(3) . .
C25A P2 Pt1 107.1(3) . .
C43 P3 C52 103.0(4) . .
C43 P3 C46 96.8(4) . .
C52 P3 C46 112.0(5) . .
C43 P3 Pt2 123.1(3) . .
C52 P3 Pt2 109.7(3) . .
C46 P3 Pt2 111.5(3) . .
C38 N1 C37 115.8(7) . .
C39 N2 C38 115.0(7) . .
C39 N3 C37 115.7(7) . .
C6 C1 C2 118.0(8) . .
C6 C1 P1 120.5(6) . .
C2 C1 P1 121.5(7) . .
C3 C2 C1 121.7(8) . .
C3 C2 H2 119.2 . .
C1 C2 H2 119.2 . .
C2 C3 C4 119.3(8) . .
C2 C3 H3 120.4 . .
C4 C3 H3 120.4 . .
C3 C4 C5 120.8(8) . .
C3 C4 C38 121.1(8) . 2_756
C5 C4 C38 118.0(8) . 2_756
C4 C5 C6 118.9(8) . .
C4 C5 H5 120.6 . .
C6 C5 H5 120.6 . .
C1 C6 C5 121.4(8) . .
C1 C6 H6 119.3 . .
C5 C6 H6 119.3 . .
C8 C7 C12 117.8(9) . .
C8 C7 P1 119.2(8) . .
C12 C7 P1 123.0(7) . .
C7 C8 C9 122.7(11) . .
C7 C8 H8 118.7 . .
C9 C8 H8 118.7 . .
C10 C9 C8 118.2(11) . .
C10 C9 H9 120.9 . .
C8 C9 H9 120.9 . .
C9 C10 C11 120.4(10) . .
C9 C10 H10 119.8 . .
C11 C10 H10 119.8 . .
C10 C11 C12 119.7(10) . .
C10 C11 H11 120.2 . .
C12 C11 H11 120.2 . .
C11 C12 C7 121.2(9) . .
C11 C12 H12 119.4 . .
C7 C12 H12 119.4 . .
C18 C13 C14 121.2(9) . .
C18 C13 P1 121.6(7) . .
C14 C13 P1 116.4(7) . .
C15 C14 C13 119.9(9) . .
C15 C14 H14 120.0 . .
C13 C14 H14 120.0 . .
C14 C15 C16 120.4(9) . .
C14 C15 H15 119.8 . .
C16 C15 H15 119.8 . .
C15 C16 C17 119.0(10) . .
C15 C16 H16 120.5 . .
C17 C16 H16 120.5 . .
C16 C17 C18 121.8(10) . .
C16 C17 H17 119.1 . .
C18 C17 H17 119.1 . .
C13 C18 C17 117.5(9) . .
C13 C18 H18 121.2 . .
C17 C18 H18 121.2 . .
C24 C19 C20 119.0(11) . .
C24 C19 P2 119.6(9) . .
C20 C19 P2 120.5(10) . .
C19 C20 C21 120.0(12) . .
C19 C20 H20 120.0 . .
C21 C20 H20 120.0 . .
C22 C21 C20 119.5(12) . .
C22 C21 H21 120.2 . .
C20 C21 H21 120.2 . .
C23 C22 C21 120.0(13) . .
C23 C22 H22 120.0 . .
C21 C22 H22 120.0 . .
C22 C23 C24 119.3(13) . .
C22 C23 H23 120.4 . .
C24 C23 H23 120.4 . .
C19 C24 C23 121.8(12) . .
C19 C24 H24 119.1 . .
C23 C24 H24 119.1 . .
C26 C25 C30 120.0 . .
C26 C25 P2 122.8(5) . .
C30 C25 P2 116.6(5) . .
C27 C26 C25 120.0 . .
C27 C26 H26 120.0 . .
C25 C26 H26 120.0 . .
C28 C27 C26 120.0 . .
C28 C27 H27 120.0 . .
C26 C27 H27 120.0 . .
C27 C28 C29 120.0 . .
C27 C28 H28 120.0 . .
C29 C28 H28 120.0 . .
C30 C29 C28 120.0 . .
C30 C29 H29 120.0 . .
C28 C29 H29 120.0 . .
C29 C30 C25 120.0 . .
C29 C30 H30 120.0 . .
C25 C30 H30 120.0 . .
C30A C25A C26A 120.0 . .
C30A C25A P2 114.5(5) . .
C26A C25A P2 125.1(5) . .
C27A C26A C25A 120.0 . .
C27A C26A H26A 120.0 . .
C25A C26A H26A 120.0 . .
C26A C27A C28A 120.0 . .
C26A C27A H27A 120.0 . .
C28A C27A H27A 120.0 . .
C29A C28A C27A 120.0 . .
C29A C28A H28A 120.0 . .
C27A C28A H28A 120.0 . .
C30A C29A C28A 120.0 . .
C30A C29A H29A 120.0 . .
C28A C29A H29A 120.0 . .
C25A C30A C29A 120.0 . .
C25A C30A H30A 120.0 . .
C29A C30A H30A 120.0 . .
C32 C31 C36 119.6(9) . .
C32 C31 P2 121.1(8) . .
C36 C31 P2 119.3(8) . .
C33 C32 C31 120.9(9) . .
C33 C32 H32 119.6 . .
C31 C32 H32 119.6 . .
C32 C33 C34 118.6(9) . .
C32 C33 H33 120.7 . .
C34 C33 H33 120.7 . .
C35 C34 C33 120.2(8) . .
C35 C34 C37 119.8(8) . .
C33 C34 C37 120.0(8) . .
C34 C35 C36 121.4(9) . .
C34 C35 H35 119.3 . .
C36 C35 H35 119.3 . .
C35 C36 C31 119.1(9) . .
C35 C36 H36 120.5 . .
C31 C36 H36 120.5 . .
N1 C37 N3 124.3(8) . .
N1 C37 C34 118.6(8) . .
N3 C37 C34 117.1(8) . .
N1 C38 N2 124.6(8) . .
N1 C38 C4 119.5(8) . 2_756
N2 C38 C4 115.8(7) . 2_756
N3 C39 N2 124.4(8) . .
N3 C39 C40 117.6(8) . .
N2 C39 C40 117.9(8) . .
C41 C40 C45 121.8(8) . .
C41 C40 C39 119.3(8) . .
C45 C40 C39 118.9(8) . .
C40 C41 C42 117.5(8) . .
C40 C41 H41 121.2 . .
C42 C41 H41 121.2 . .
C41 C42 C43 122.0(8) . .
C41 C42 H42 119.0 . .
C43 C42 H42 119.0 . .
C44 C43 C42 119.1(8) . .
C44 C43 P3 122.5(7) . .
C42 C43 P3 118.1(6) . .
C45 C44 C43 119.0(8) . .
C45 C44 H44 120.5 . .
C43 C44 H44 120.5 . .
C44 C45 C40 120.5(8) . .
C44 C45 H45 119.7 . .
C40 C45 H45 119.7 . .
C47 C46 C51 119.1(10) . .
C47 C46 P3 119.4(8) . .
C51 C46 P3 121.0(8) . .
C46 C47 C48 120.3(11) . .
C46 C47 H47 119.8 . .
C48 C47 H47 119.8 . .
C49 C48 C47 119.5(12) . .
C49 C48 H48 120.3 . .
C47 C48 H48 120.3 . .
C48 C49 C50 121.5(12) . .
C48 C49 H49 119.3 . .
C50 C49 H49 119.3 . .
C49 C50 C51 119.0(11) . .
C49 C50 H50 120.5 . .
C51 C50 H50 120.5 . .
C46 C51 C50 120.6(11) . .
C46 C51 H51 119.7 . .
C50 C51 H51 119.7 . .
C57 C52 C53 118.9(11) . .
C57 C52 P3 118.3(9) . .
C53 C52 P3 122.7(9) . .
C54 C53 C52 120.4(12) . .
C54 C53 H53 119.8 . .
C52 C53 H53 119.8 . .
C55 C54 C53 118.9(11) . .
C55 C54 H54 120.5 . .
C53 C54 H54 120.5 . .
C56 C55 C54 122.7(11) . .
C56 C55 H55 118.6 . .
C54 C55 H55 118.6 . .
C55 C56 C57 116.9(12) . .
C55 C56 H56 121.6 . .
C57 C56 H56 121.6 . .
C52 C57 C56 122.1(12) . .
C52 C57 H57 119.0 . .
C56 C57 H57 119.0 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt1 P1 2.254(2) .
Pt1 P2 2.259(3) .
Pt1 Cl1 2.337(2) .
Pt1 Cl2 2.362(3) .
Pt2 P3 2.247(2) .
Pt2 P3 2.247(2) 2_756
Pt2 Cl3 2.341(2) .
Pt2 Cl3 2.341(2) 2_756
P1 C7 1.803(9) .
P1 C1 1.819(9) .
P1 C13 1.847(9) .
P2 C31 1.827(9) .
P2 C19 1.828(11) .
P2 C25 1.857(7) .
P2 C25A 1.863(7) .
P3 C43 1.823(9) .
P3 C52 1.830(10) .
P3 C46 1.832(10) .
N1 C38 1.325(11) .
N1 C37 1.349(11) .
N2 C39 1.358(11) .
N2 C38 1.357(11) .
N3 C39 1.330(11) .
N3 C37 1.349(11) .
C1 C6 1.394(12) .
C1 C2 1.404(12) .
C2 C3 1.379(12) .
C2 H2 0.9500 .
C3 C4 1.391(12) .
C3 H3 0.9500 .
C4 C5 1.396(11) .
C4 C38 1.470(11) 2_756
C5 C6 1.395(12) .
C5 H5 0.9500 .
C6 H6 0.9500 .
C7 C8 1.375(14) .
C7 C12 1.395(14) .
C8 C9 1.404(15) .
C8 H8 0.9500 .
C9 C10 1.390(17) .
C9 H9 0.9500 .
C10 C11 1.390(16) .
C10 H10 0.9500 .
C11 C12 1.392(13) .
C11 H11 0.9500 .
C12 H12 0.9500 .
C13 C18 1.374(13) .
C13 C14 1.387(12) .
C14 C15 1.365(13) .
C14 H14 0.9500 .
C15 C16 1.376(14) .
C15 H15 0.9500 .
C16 C17 1.379(15) .
C16 H16 0.9500 .
C17 C18 1.391(14) .
C17 H17 0.9500 .
C18 H18 0.9500 .
C19 C24 1.352(15) .
C19 C20 1.384(16) .
C20 C21 1.414(17) .
C20 H20 0.9500 .
C21 C22 1.388(17) .
C21 H21 0.9500 .
C22 C23 1.362(17) .
C22 H22 0.9500 .
C23 C24 1.410(17) .
C23 H23 0.9500 .
C24 H24 0.9500 .
C25 C26 1.3900 .
C25 C30 1.3900 .
C26 C27 1.3900 .
C26 H26 0.9500 .
C27 C28 1.3900 .
C27 H27 0.9500 .
C28 C29 1.3900 .
C28 H28 0.9500 .
C29 C30 1.3900 .
C29 H29 0.9500 .
C30 H30 0.9500 .
C25A C30A 1.3900 .
C25A C26A 1.3900 .
C26A C27A 1.3900 .
C26A H26A 0.9500 .
C27A C28A 1.3900 .
C27A H27A 0.9500 .
C28A C29A 1.3900 .
C28A H28A 0.9500 .
C29A C30A 1.3900 .
C29A H29A 0.9500 .
C30A H30A 0.9500 .
C31 C32 1.393(14) .
C31 C36 1.408(14) .
C32 C33 1.395(13) .
C32 H32 0.9500 .
C33 C34 1.415(12) .
C33 H33 0.9500 .
C34 C35 1.371(12) .
C34 C37 1.464(12) .
C35 C36 1.386(13) .
C35 H35 0.9500 .
C36 H36 0.9500 .
C38 C4 1.470(11) 2_756
C39 C40 1.483(12) .
C40 C41 1.377(12) .
C40 C45 1.397(13) .
C41 C42 1.400(12) .
C41 H41 0.9500 .
C42 C43 1.409(12) .
C42 H42 0.9500 .
C43 C44 1.400(12) .
C44 C45 1.394(12) .
C44 H44 0.9500 .
C45 H45 0.9500 .
C46 C47 1.381(14) .
C46 C51 1.400(14) .
C47 C48 1.419(16) .
C47 H47 0.9500 .
C48 C49 1.364(17) .
C48 H48 0.9500 .
C49 C50 1.384(18) .
C49 H49 0.9500 .
C50 C51 1.404(16) .
C50 H50 0.9500 .
C51 H51 0.9500 .
C52 C57 1.326(15) .
C52 C53 1.380(15) .
C53 C54 1.377(17) .
C53 H53 0.9500 .
C54 C55 1.361(18) .
C54 H54 0.9500 .
C55 C56 1.335(18) .
C55 H55 0.9500 .
C56 C57 1.426(16) .
C56 H56 0.9500 .
C57 H57 0.9500 .
