#------------------------------------------------------------------------------
#$Date: 2018-08-11 20:20:43 +0200 (Sat 11 de Aug de 2018) $
#$Revision: 209587 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/10/7001013.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7001013
loop_
_publ_author_name
'Mendoza, Carolina'
'Benet-Buchholz, Jordi'
'Pericás, Miquel A.'
'Vilar, Ramón'
_publ_section_title
;
 Di-platinum complexes containing thiolato-urea ligands: structural and
 anion binding studies
;
_journal_coden_ASTM              DTARAF
_journal_issue                   16
_journal_name_full               'Dalton Transactions'
_journal_page_first              2974
_journal_page_last               2985
_journal_paper_doi               10.1039/b819612e
_journal_year                    2009
_chemical_formula_sum            'C68 H82 Cl14 N4 O2 P4 Pb2 Pt2 S2'
_chemical_formula_weight         2476.24
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 98.512(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   12.9783(11)
_cell_length_b                   18.2889(14)
_cell_length_c                   35.672(3)
_cell_measurement_reflns_used    8710
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      39.30
_cell_measurement_theta_min      2.73
_cell_volume                     8373.8(12)
_computing_cell_refinement       'Bruker-Nonius Apex v1.0-22 2002'
_computing_data_collection       'Bruker-Nonius Apex v1.0-22 2002'
_computing_data_reduction        'SAINT+ Version 7.06A Bruker-Nonius, 2004'
_computing_molecular_graphics    'Shelxtl Version 6.12 (Sheldrick, 2001)'
_computing_publication_material  'Shelxtl Version 6.12 (Sheldrick, 2001)'
_computing_structure_refinement  'Shelxtl Version 6.12 (Sheldrick, 2001)'
_computing_structure_solution    'Shelxtl Version 6.12 (Sheldrick, 2001)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 512
_diffrn_detector_type            '4K CCD area detector APEX II'
_diffrn_measured_fraction_theta_full 0.839
_diffrn_measured_fraction_theta_max 0.839
_diffrn_measurement_device_type  'Kappa 4-axis goniometer bruker-nonius'
_diffrn_measurement_method
;
Fullsphere data collection, phi and omega scans
;
_diffrn_measurement_specimen_support
'magnetic support whith 10 micron nylon fiber cryoloop'
_diffrn_radiation_monochromator  'Multilayer Montel 200 mirrors'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0482
_diffrn_reflns_av_sigmaI/netI    0.0499
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -22
_diffrn_reflns_limit_k_max       32
_diffrn_reflns_limit_k_min       -32
_diffrn_reflns_limit_l_max       52
_diffrn_reflns_limit_l_min       -63
_diffrn_reflns_number            168281
_diffrn_reflns_theta_full        39.60
_diffrn_reflns_theta_max         39.60
_diffrn_reflns_theta_min         2.60
_diffrn_source                   'rotating anode X-ray tube'
_diffrn_source_current           90
_diffrn_source_power             50
_diffrn_source_size              '3 mm x 0.3 mm fine focus'
_diffrn_source_type              'Bruker-Nonius FR 591'
_exptl_absorpt_coefficient_mu    7.957
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.34103
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details
;
SADABS Version 2.1 2003 Bruker-Nonius
Blessing, Acta Cryst. (1995) A51 33-38
;
_exptl_crystal_colour            translucent
_exptl_crystal_density_diffrn    1.964
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             4736
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.10
_refine_diff_density_max         4.462
_refine_diff_density_min         -5.001
_refine_diff_density_rms         0.240
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.118
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_parameters     885
_refine_ls_number_reflns         42493
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.118
_refine_ls_R_factor_all          0.0696
_refine_ls_R_factor_gt           0.0488
_refine_ls_shift/su_max          0.007
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0221P)²+60.8430P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0943
_refine_ls_wR_factor_ref         0.0998
_reflns_number_gt                33542
_reflns_number_total             42493
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            B819612E.txt
_cod_data_source_block           cm-55_0m
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               7001013
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.300995(11) 0.662561(7) 0.363771(4) 0.00768(3) Uani 1 1 d . . .
Pb1 Pb 0.420779(13) 0.569320(8) 0.536675(5) 0.01364(3) Uani 1 1 d . . .
S1 S 0.21488(7) 0.74894(5) 0.39704(3) 0.00981(16) Uani 1 1 d . . .
P1 P 0.38382(8) 0.58978(5) 0.32609(3) 0.00946(18) Uani 1 1 d . . .
Cl1 Cl 0.27599(9) 0.48012(6) 0.54946(3) 0.0193(2) Uani 1 1 d . . .
N1 N 0.2546(3) 0.79295(19) 0.50970(11) 0.0160(7) Uani 1 1 d . . .
H1A H 0.2627 0.8393 0.5162 0.019 Uiso 1 1 calc R . .
O1 O 0.2813(3) 0.67419(17) 0.52647(10) 0.0186(6) Uani 1 1 d . . .
C1 C 0.3748(3) 0.4926(2) 0.33516(13) 0.0131(7) Uani 1 1 d . . .
H1B H 0.4102 0.4655 0.3167 0.016 Uiso 1 1 calc R . .
H1C H 0.4121 0.4818 0.3608 0.016 Uiso 1 1 calc R . .
P2 P 0.16816(8) 0.58246(5) 0.36576(3) 0.01005(18) Uani 1 1 d . . .
Pt2 Pt 0.294799(11) 0.841877(7) 0.365021(4) 0.00763(3) Uani 1 1 d . . .
Pb2 Pb 0.635142(14) 0.941907(8) 0.504871(5) 0.01676(3) Uani 1 1 d . . .
S2 S 0.42950(7) 0.75519(5) 0.36521(3) 0.00907(16) Uani 1 1 d . . .
Cl2 Cl 0.56029(9) 0.45244(6) 0.55445(4) 0.0207(2) Uani 1 1 d . . .
O2 O 0.6884(3) 0.83420(17) 0.46685(11) 0.0216(7) Uani 1 1 d . . .
N2 N 0.3353(4) 0.7620(2) 0.56979(12) 0.0220(9) Uani 1 1 d . . .
H2A H 0.3469 0.7278 0.5873 0.026 Uiso 1 1 calc R . .
C2 C 0.2624(4) 0.4649(2) 0.33244(13) 0.0153(8) Uani 1 1 d . . .
H2B H 0.2624 0.4109 0.3305 0.018 Uiso 1 1 calc R . .
H2C H 0.2214 0.4843 0.3089 0.018 Uiso 1 1 calc R . .
P3 P 0.14833(8) 0.91197(5) 0.35785(3) 0.01049(18) Uani 1 1 d . . .
N3 N 0.6833(3) 0.71826(19) 0.44433(12) 0.0152(7) Uani 1 1 d . . .
H3A H 0.7046 0.6727 0.4473 0.018 Uiso 1 1 calc R . .
Cl3 Cl 0.45507(11) 0.61955(6) 0.60923(3) 0.0239(2) Uani 1 1 d . . .
C3 C 0.2090(3) 0.4871(2) 0.36636(13) 0.0144(8) Uani 1 1 d . . .
H3B H 0.2576 0.4779 0.3900 0.017 Uiso 1 1 calc R . .
H3C H 0.1471 0.4557 0.3668 0.017 Uiso 1 1 calc R . .
P4 P 0.38575(8) 0.92348(5) 0.33515(3) 0.01006(18) Uani 1 1 d . . .
Cl4 Cl 0.78207(10) 1.02174(6) 0.48346(4) 0.0241(2) Uani 1 1 d . . .
N4 N 0.7567(4) 0.7437(2) 0.50640(12) 0.0205(8) Uani 1 1 d . . .
H4A H 0.7831 0.7771 0.5228 0.025 Uiso 1 1 calc R . .
C4 C 0.5226(3) 0.6064(2) 0.32889(12) 0.0112(7) Uani 1 1 d . . .
Cl5 Cl 0.59525(11) 1.05851(6) 0.55211(4) 0.0242(2) Uani 1 1 d . . .
C5 C 0.5937(3) 0.5730(2) 0.35724(12) 0.0132(7) Uani 1 1 d . . .
H5A H 0.5693 0.5413 0.3751 0.016 Uiso 1 1 calc R . .
Cl6 Cl 0.75646(13) 0.88099(6) 0.56344(4) 0.0291(3) Uani 1 1 d . . .
C6 C 0.7000(4) 0.5864(2) 0.35921(13) 0.0147(8) Uani 1 1 d . . .
H6A H 0.7482 0.5629 0.3780 0.018 Uiso 1 1 calc R . .
C7 C 0.7355(4) 0.6342(3) 0.33368(14) 0.0178(8) Uani 1 1 d . . .
H7A H 0.8081 0.6430 0.3351 0.021 Uiso 1 1 calc R . .
C8 C 0.6663(4) 0.6689(3) 0.30627(14) 0.0196(9) Uani 1 1 d . . .
H8A H 0.6914 0.7022 0.2893 0.024 Uiso 1 1 calc R . .
C9 C 0.5597(4) 0.6554(2) 0.30351(13) 0.0163(8) Uani 1 1 d . . .
H9A H 0.5122 0.6791 0.2846 0.020 Uiso 1 1 calc R . .
C10 C 0.3335(3) 0.5999(2) 0.27604(12) 0.0128(7) Uani 1 1 d . . .
C11 C 0.3710(4) 0.5560(2) 0.24883(14) 0.0185(9) Uani 1 1 d . . .
H11A H 0.4235 0.5207 0.2567 0.022 Uiso 1 1 calc R . .
C12 C 0.3327(4) 0.5634(3) 0.21070(15) 0.0236(10) Uani 1 1 d . . .
H12A H 0.3596 0.5336 0.1926 0.028 Uiso 1 1 calc R . .
C13 C 0.2555(5) 0.6139(3) 0.19884(15) 0.0256(10) Uani 1 1 d . . .
H13A H 0.2285 0.6186 0.1727 0.031 Uiso 1 1 calc R . .
C14 C 0.2175(5) 0.6584(3) 0.22598(16) 0.0279(11) Uani 1 1 d . . .
H14A H 0.1652 0.6938 0.2181 0.034 Uiso 1 1 calc R . .
C15 C 0.2557(4) 0.6508(2) 0.26387(14) 0.0188(9) Uani 1 1 d . . .
H15A H 0.2287 0.6806 0.2820 0.023 Uiso 1 1 calc R . .
C16 C 0.0636(3) 0.5922(2) 0.32602(12) 0.0119(7) Uani 1 1 d . . .
C17 C 0.0029(4) 0.5323(2) 0.31128(15) 0.0194(9) Uani 1 1 d . . .
H17A H 0.0167 0.4850 0.3218 0.023 Uiso 1 1 calc R . .
C18 C -0.0771(4) 0.5423(3) 0.28136(17) 0.0252(11) Uani 1 1 d . . .
H18A H -0.1170 0.5013 0.2712 0.030 Uiso 1 1 calc R . .
C19 C -0.0998(4) 0.6111(3) 0.26608(14) 0.0213(9) Uani 1 1 d . . .
H19A H -0.1548 0.6173 0.2456 0.026 Uiso 1 1 calc R . .
C20 C -0.0411(4) 0.6712(3) 0.28094(14) 0.0201(9) Uani 1 1 d . . .
H20A H -0.0569 0.7187 0.2710 0.024 Uiso 1 1 calc R . .
C21 C 0.0404(4) 0.6611(2) 0.31033(13) 0.0166(8) Uani 1 1 d . . .
H21A H 0.0811 0.7019 0.3200 0.020 Uiso 1 1 calc R . .
C22 C 0.1033(3) 0.5906(2) 0.40746(12) 0.0130(7) Uani 1 1 d . . .
C23 C 0.0030(4) 0.6196(2) 0.40511(14) 0.0178(8) Uani 1 1 d . . .
H23A H -0.0318 0.6370 0.3815 0.021 Uiso 1 1 calc R . .
C24 C -0.0462(4) 0.6231(3) 0.43705(15) 0.0211(10) Uani 1 1 d . . .
H24A H -0.1146 0.6426 0.4353 0.025 Uiso 1 1 calc R . .
C25 C 0.0045(4) 0.5982(3) 0.47146(15) 0.0216(10) Uani 1 1 d . . .
H25A H -0.0296 0.5999 0.4932 0.026 Uiso 1 1 calc R . .
C26 C 0.1051(4) 0.5707(3) 0.47443(14) 0.0207(9) Uani 1 1 d . . .
H26A H 0.1401 0.5543 0.4982 0.025 Uiso 1 1 calc R . .
C27 C 0.1543(4) 0.5673(2) 0.44230(14) 0.0178(8) Uani 1 1 d . . .
H27A H 0.2233 0.5488 0.4443 0.021 Uiso 1 1 calc R . .
C28 C 0.1696(4) 1.0097(2) 0.36032(13) 0.0152(8) Uani 1 1 d . . .
H28A H 0.1014 1.0346 0.3545 0.018 Uiso 1 1 calc R . .
H28B H 0.1994 1.0227 0.3867 0.018 Uiso 1 1 calc R . .
C29 C 0.2420(4) 1.0393(2) 0.33355(14) 0.0166(8) Uani 1 1 d . . .
H29A H 0.2184 1.0204 0.3077 0.020 Uiso 1 1 calc R . .
H29B H 0.2364 1.0932 0.3326 0.020 Uiso 1 1 calc R . .
C30 C 0.3563(4) 1.0182(2) 0.34536(13) 0.0153(8) Uani 1 1 d . . .
H30A H 0.3752 1.0268 0.3729 0.018 Uiso 1 1 calc R . .
H30B H 0.4003 1.0506 0.3321 0.018 Uiso 1 1 calc R . .
C31 C 0.0684(3) 0.8985(2) 0.31226(12) 0.0117(7) Uani 1 1 d . . .
C32 C 0.1012(4) 0.8539(2) 0.28436(13) 0.0148(8) Uani 1 1 d . . .
H32A H 0.1662 0.8293 0.2895 0.018 Uiso 1 1 calc R . .
C33 C 0.0401(4) 0.8450(2) 0.24933(14) 0.0200(9) Uani 1 1 d . . .
H33A H 0.0641 0.8156 0.2304 0.024 Uiso 1 1 calc R . .
C34 C -0.0570(4) 0.8795(3) 0.24195(15) 0.0218(9) Uani 1 1 d . . .
H34A H -0.1001 0.8723 0.2183 0.026 Uiso 1 1 calc R . .
C35 C -0.0902(4) 0.9241(3) 0.26923(16) 0.0231(10) Uani 1 1 d . . .
H35A H -0.1558 0.9480 0.2640 0.028 Uiso 1 1 calc R . .
C36 C -0.0287(4) 0.9340(3) 0.30400(15) 0.0211(9) Uani 1 1 d . . .
H36A H -0.0521 0.9650 0.3224 0.025 Uiso 1 1 calc R . .
C37 C 0.0602(3) 0.8947(2) 0.39195(12) 0.0137(8) Uani 1 1 d . . .
C38 C 0.0633(4) 0.9388(3) 0.42422(14) 0.0203(9) Uani 1 1 d . . .
H38A H 0.1111 0.9783 0.4285 0.024 Uiso 1 1 calc R . .
C39 C -0.0051(4) 0.9238(3) 0.45013(15) 0.0239(11) Uani 1 1 d . . .
H39A H -0.0053 0.9545 0.4716 0.029 Uiso 1 1 calc R . .
C40 C -0.0725(4) 0.8645(3) 0.44479(16) 0.0283(13) Uani 1 1 d . . .
H40A H -0.1182 0.8546 0.4627 0.034 Uiso 1 1 calc R . .
C41 C -0.0731(4) 0.8200(3) 0.41350(16) 0.0243(11) Uani 1 1 d . . .
H41A H -0.1184 0.7790 0.4102 0.029 Uiso 1 1 calc R . .
C42 C -0.0078(4) 0.8346(2) 0.38662(15) 0.0196(9) Uani 1 1 d . . .
H42A H -0.0094 0.8043 0.3649 0.024 Uiso 1 1 calc R . .
C43 C 0.3652(3) 0.9145(2) 0.28400(12) 0.0142(8) Uani 1 1 d . . .
C44 C 0.3647(4) 0.9757(3) 0.26024(14) 0.0193(9) Uani 1 1 d . . .
H44A H 0.3696 1.0234 0.2709 0.023 Uiso 1 1 calc R . .
C45 C 0.3571(5) 0.9669(3) 0.22134(15) 0.0286(12) Uani 1 1 d . . .
H45A H 0.3559 1.0086 0.2054 0.034 Uiso 1 1 calc R . .
C46 C 0.3514(5) 0.8974(4) 0.20566(15) 0.0316(13) Uani 1 1 d . . .
H46A H 0.3479 0.8917 0.1790 0.038 Uiso 1 1 calc R . .
C47 C 0.3507(5) 0.8362(3) 0.22868(15) 0.0266(11) Uani 1 1 d . . .
H47A H 0.3459 0.7886 0.2179 0.032 Uiso 1 1 calc R . .
C48 C 0.3572(4) 0.8452(2) 0.26769(13) 0.0180(8) Uani 1 1 d . . .
H48A H 0.3561 0.8034 0.2834 0.022 Uiso 1 1 calc R . .
C49 C 0.5274(3) 0.9187(2) 0.34656(12) 0.0129(7) Uani 1 1 d . . .
C50 C 0.5872(4) 0.8831(2) 0.32266(15) 0.0190(9) Uani 1 1 d . . .
H50A H 0.5540 0.8576 0.3010 0.023 Uiso 1 1 calc R . .
C51 C 0.6954(4) 0.8848(3) 0.33055(17) 0.0237(10) Uani 1 1 d . . .
H51A H 0.7358 0.8603 0.3143 0.028 Uiso 1 1 calc R . .
C52 C 0.7443(4) 0.9218(3) 0.36190(16) 0.0235(10) Uani 1 1 d . . .
H52A H 0.8182 0.9243 0.3666 0.028 Uiso 1 1 calc R . .
C53 C 0.6856(4) 0.9556(3) 0.38668(15) 0.0244(10) Uani 1 1 d . . .
H53A H 0.7193 0.9802 0.4086 0.029 Uiso 1 1 calc R . .
C54 C 0.5771(4) 0.9532(3) 0.37920(14) 0.0211(9) Uani 1 1 d . . .
H54A H 0.5369 0.9751 0.3964 0.025 Uiso 1 1 calc R . .
C55 C 0.2817(3) 0.7532(2) 0.44626(11) 0.0128(7) Uani 1 1 d . . .
H55A H 0.3127 0.7050 0.4540 0.015 Uiso 1 1 calc R . .
H55B H 0.3385 0.7898 0.4484 0.015 Uiso 1 1 calc R . .
C56 C 0.2023(3) 0.7745(2) 0.47200(12) 0.0145(8) Uani 1 1 d . . .
H56A H 0.1612 0.8170 0.4610 0.017 Uiso 1 1 calc R . .
H56B H 0.1538 0.7333 0.4737 0.017 Uiso 1 1 calc R . .
C57 C 0.2913(4) 0.7407(2) 0.53509(12) 0.0147(8) Uani 1 1 d . . .
C58 C 0.3657(5) 0.8361(3) 0.58127(15) 0.0246(10) Uani 1 1 d . . .
H58A H 0.3777 0.8390 0.6093 0.030 Uiso 1 1 calc R . .
H58B H 0.3083 0.8700 0.5718 0.030 Uiso 1 1 calc R . .
C59 C 0.4644(6) 0.8598(4) 0.5660(3) 0.052(2) Uani 1 1 d . . .
H59A H 0.4788 0.9113 0.5723 0.078 Uiso 1 1 calc R . .
H59B H 0.4545 0.8536 0.5384 0.078 Uiso 1 1 calc R . .
H59C H 0.5232 0.8298 0.5775 0.078 Uiso 1 1 calc R . .
C60 C 0.5064(3) 0.7486(2) 0.41283(12) 0.0141(7) Uani 1 1 d . . .
H60A H 0.4951 0.7927 0.4278 0.017 Uiso 1 1 calc R . .
H60B H 0.4840 0.7053 0.4262 0.017 Uiso 1 1 calc R . .
C61 C 0.6216(3) 0.7418(2) 0.40891(13) 0.0150(8) Uani 1 1 d . . .
H61A H 0.6297 0.7060 0.3887 0.018 Uiso 1 1 calc R . .
H61B H 0.6476 0.7896 0.4014 0.018 Uiso 1 1 calc R . .
C62 C 0.7077(4) 0.7679(2) 0.47304(14) 0.0169(8) Uani 1 1 d . . .
C63 C 0.7707(4) 0.6682(2) 0.51829(15) 0.0208(9) Uani 1 1 d . . .
H63A H 0.8276 0.6654 0.5400 0.025 Uiso 1 1 calc R . .
H63B H 0.7919 0.6392 0.4973 0.025 Uiso 1 1 calc R . .
C64 C 0.6726(5) 0.6349(4) 0.52970(18) 0.0351(14) Uani 1 1 d . . .
H64A H 0.6875 0.5852 0.5391 0.053 Uiso 1 1 calc R . .
H64B H 0.6178 0.6335 0.5076 0.053 Uiso 1 1 calc R . .
H64C H 0.6492 0.6647 0.5497 0.053 Uiso 1 1 calc R . .
Cl1C Cl 0.06469(18) 0.20168(11) 0.32096(5) 0.0524(5) Uani 1 1 d . . .
C1C C 0.0964(5) 0.2288(3) 0.36836(16) 0.0298(12) Uani 1 1 d . . .
H1CA H 0.1173 0.1853 0.3842 0.036 Uiso 1 1 calc R . .
H1CB H 0.0340 0.2502 0.3771 0.036 Uiso 1 1 calc R . .
Cl2C Cl 0.1989(2) 0.29357(9) 0.37457(7) 0.0603(6) Uani 1 1 d . . .
Cl1A Cl 0.34769(18) 0.31694(12) 0.27308(6) 0.0549(5) Uani 1 1 d . . .
C1A C 0.4069(7) 0.2716(4) 0.3139(2) 0.0483(19) Uani 1 1 d . . .
H1AA H 0.3528 0.2582 0.3295 0.058 Uiso 1 1 calc R . .
H1AB H 0.4563 0.3055 0.3290 0.058 Uiso 1 1 calc R . .
Cl2A Cl 0.47489(18) 0.19155(9) 0.30393(6) 0.0531(5) Uani 1 1 d . . .
Cl1D Cl 0.1609(2) 0.68612(16) 0.63929(7) 0.0772(9) Uani 1 1 d . . .
C1D C 0.1597(5) 0.6250(4) 0.60099(19) 0.0354(14) Uani 1 1 d . . .
H1DA H 0.2126 0.5864 0.6081 0.043 Uiso 1 1 calc R . .
H1DB H 0.1791 0.6518 0.5790 0.043 Uiso 1 1 calc R . .
Cl2D Cl 0.03638(16) 0.58337(10) 0.58777(8) 0.0598(6) Uani 1 1 d . . .
Cl1B Cl 0.91803(13) 0.10955(8) 0.40017(5) 0.0369(3) Uani 1 1 d . . .
C1B C 0.9696(5) 0.1313(3) 0.44706(18) 0.0317(13) Uani 1 1 d . . .
H1BA H 1.0393 0.1087 0.4533 0.038 Uiso 1 1 calc R . .
H1BB H 0.9242 0.1104 0.4643 0.038 Uiso 1 1 calc R . .
Cl2B Cl 0.98075(12) 0.22702(8) 0.45479(5) 0.0328(3) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pb Pb -3.3944 10.1111 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P2 Pt1 P1 93.92(3) . . ?
P2 Pt1 S1 89.88(3) . . ?
P1 Pt1 S1 173.01(3) . . ?
P2 Pt1 S2 173.83(3) . . ?
P1 Pt1 S2 92.21(3) . . ?
S1 Pt1 S2 83.95(3) . . ?
Cl1 Pb1 O1 88.92(8) . . ?
Cl1 Pb1 Cl3 93.80(4) . . ?
O1 Pb1 Cl3 84.12(8) . . ?
Cl1 Pb1 Cl2 86.62(4) . . ?
O1 Pb1 Cl2 173.81(8) . . ?
Cl3 Pb1 Cl2 91.89(4) . . ?
C55 S1 Pt1 108.49(12) . . ?
C55 S1 Pt2 104.54(13) . . ?
Pt1 S1 Pt2 87.94(3) . . ?
C1 P1 C4 104.14(18) . . ?
C1 P1 C10 104.6(2) . . ?
C4 P1 C10 104.27(18) . . ?
C1 P1 Pt1 114.84(12) . . ?
C4 P1 Pt1 114.95(12) . . ?
C10 P1 Pt1 112.88(13) . . ?
C57 N1 C56 121.7(4) . . ?
C57 O1 Pb1 129.0(3) . . ?
C2 C1 P1 113.4(3) . . ?
C16 P2 C22 104.28(19) . . ?
C16 P2 C3 106.6(2) . . ?
C22 P2 C3 103.77(18) . . ?
C16 P2 Pt1 113.22(13) . . ?
C22 P2 Pt1 114.67(14) . . ?
C3 P2 Pt1 113.38(14) . . ?
P4 Pt2 P3 93.48(4) . . ?
P4 Pt2 S2 90.38(3) . . ?
P3 Pt2 S2 170.12(4) . . ?
P4 Pt2 S1 174.21(4) . . ?
P3 Pt2 S1 92.31(3) . . ?
S2 Pt2 S1 83.90(3) . . ?
O2 Pb2 Cl4 90.52(8) . . ?
O2 Pb2 Cl6 85.33(9) . . ?
Cl4 Pb2 Cl6 95.22(5) . . ?
O2 Pb2 Cl5 174.10(10) . . ?
Cl4 Pb2 Cl5 87.62(3) . . ?
Cl6 Pb2 Cl5 89.26(4) . . ?
C60 S2 Pt2 110.30(12) . . ?
C60 S2 Pt1 104.84(13) . . ?
Pt2 S2 Pt1 87.80(3) . . ?
C62 O2 Pb2 136.0(3) . . ?
C57 N2 C58 126.2(4) . . ?
C1 C2 C3 113.5(4) . . ?
C28 P3 C31 103.9(2) . . ?
C28 P3 C37 104.24(18) . . ?
C31 P3 C37 104.1(2) . . ?
C28 P3 Pt2 115.60(15) . . ?
C31 P3 Pt2 112.50(13) . . ?
C37 P3 Pt2 115.16(14) . . ?
C62 N3 C61 119.3(4) . . ?
C2 C3 P2 114.1(3) . . ?
C43 P4 C30 106.5(2) . . ?
C43 P4 C49 102.32(19) . . ?
C30 P4 C49 103.6(2) . . ?
C43 P4 Pt2 113.89(13) . . ?
C30 P4 Pt2 113.16(13) . . ?
C49 P4 Pt2 116.19(12) . . ?
C62 N4 C63 126.7(4) . . ?
C5 C4 C9 119.3(4) . . ?
C5 C4 P1 120.5(3) . . ?
C9 C4 P1 120.1(3) . . ?
C6 C5 C4 120.0(4) . . ?
C7 C6 C5 120.0(4) . . ?
C8 C7 C6 120.7(4) . . ?
C7 C8 C9 120.2(4) . . ?
C8 C9 C4 119.8(4) . . ?
C15 C10 C11 118.5(4) . . ?
C15 C10 P1 120.8(3) . . ?
C11 C10 P1 120.7(3) . . ?
C12 C11 C10 120.9(4) . . ?
C13 C12 C11 120.3(4) . . ?
C12 C13 C14 119.2(5) . . ?
C15 C14 C13 120.3(5) . . ?
C14 C15 C10 120.8(4) . . ?
C21 C16 C17 118.6(4) . . ?
C21 C16 P2 119.6(3) . . ?
C17 C16 P2 121.8(3) . . ?
C18 C17 C16 120.1(4) . . ?
C19 C18 C17 120.8(5) . . ?
C18 C19 C20 119.6(5) . . ?
C21 C20 C19 119.6(5) . . ?
C20 C21 C16 121.3(4) . . ?
C27 C22 C23 119.2(4) . . ?
C27 C22 P2 119.3(3) . . ?
C23 C22 P2 121.5(3) . . ?
C24 C23 C22 120.4(5) . . ?
C25 C24 C23 119.9(4) . . ?
C24 C25 C26 120.4(4) . . ?
C25 C26 C27 119.6(5) . . ?
C22 C27 C26 120.5(4) . . ?
C29 C28 P3 114.9(3) . . ?
C30 C29 C28 113.5(4) . . ?
C29 C30 P4 114.0(3) . . ?
C32 C31 C36 118.4(4) . . ?
C32 C31 P3 121.5(3) . . ?
C36 C31 P3 120.1(3) . . ?
C33 C32 C31 121.0(4) . . ?
C32 C33 C34 119.7(4) . . ?
C35 C34 C33 119.9(5) . . ?
C36 C35 C34 120.5(5) . . ?
C35 C36 C31 120.4(4) . . ?
C38 C37 C42 120.1(4) . . ?
C38 C37 P3 120.4(3) . . ?
C42 C37 P3 119.4(3) . . ?
C39 C38 C37 119.1(5) . . ?
C40 C39 C38 120.7(5) . . ?
C41 C40 C39 119.9(4) . . ?
C40 C41 C42 120.7(5) . . ?
C41 C42 C37 119.4(5) . . ?
C48 C43 C44 118.7(4) . . ?
C48 C43 P4 119.6(3) . . ?
C44 C43 P4 121.5(3) . . ?
C45 C44 C43 120.4(5) . . ?
C44 C45 C46 120.1(5) . . ?
C45 C46 C47 120.4(5) . . ?
C46 C47 C48 119.4(5) . . ?
C47 C48 C43 121.0(4) . . ?
C54 C49 C50 119.3(4) . . ?
C54 C49 P4 119.4(3) . . ?
C50 C49 P4 121.3(4) . . ?
C51 C50 C49 120.1(5) . . ?
C52 C51 C50 120.3(4) . . ?
C51 C52 C53 120.2(5) . . ?
C54 C53 C52 119.7(5) . . ?
C53 C54 C49 120.2(4) . . ?
C56 C55 S1 108.6(3) . . ?
N1 C56 C55 110.5(4) . . ?
O1 C57 N2 121.4(4) . . ?
O1 C57 N1 120.4(4) . . ?
N2 C57 N1 118.2(4) . . ?
N2 C58 C59 111.8(5) . . ?
C61 C60 S2 109.0(3) . . ?
N3 C61 C60 111.3(3) . . ?
O2 C62 N4 122.2(4) . . ?
O2 C62 N3 119.5(5) . . ?
N4 C62 N3 118.2(4) . . ?
N4 C63 C64 112.7(5) . . ?
Cl1C C1C Cl2C 112.0(3) . . ?
Cl1A C1A Cl2A 113.2(4) . . ?
Cl1D C1D Cl2D 112.5(3) . . ?
Cl1B C1B Cl2B 112.5(3) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 P2 2.2715(10) . ?
Pt1 P1 2.2718(9) . ?
Pt1 S1 2.3550(8) . ?
Pt1 S2 2.3725(9) . ?
Pb1 Cl1 2.5794(11) . ?
Pb1 O1 2.625(3) . ?
Pb1 Cl3 2.7202(12) . ?
Pb1 Cl2 2.8125(11) . ?
S1 C55 1.842(5) . ?
S1 Pt2 2.3707(8) . ?
P1 C1 1.814(4) . ?
P1 C4 1.814(4) . ?
P1 C10 1.818(5) . ?
N1 C57 1.354(6) . ?
N1 C56 1.454(6) . ?
O1 C57 1.257(5) . ?
C1 C2 1.533(6) . ?
P2 C16 1.820(5) . ?
P2 C22 1.821(4) . ?
P2 C3 1.821(4) . ?
Pt2 P4 2.2646(9) . ?
Pt2 P3 2.2756(10) . ?
Pt2 S2 2.3592(9) . ?
Pb2 O2 2.545(3) . ?
Pb2 Cl4 2.6044(11) . ?
Pb2 Cl6 2.6667(14) . ?
Pb2 Cl5 2.8132(11) . ?
S2 C60 1.842(5) . ?
O2 C62 1.252(5) . ?
N2 C57 1.342(6) . ?
N2 C58 1.454(6) . ?
C2 C3 1.536(5) . ?
P3 C28 1.810(4) . ?
P3 C31 1.812(5) . ?
P3 C37 1.816(4) . ?
N3 C62 1.370(6) . ?
N3 C61 1.457(6) . ?
P4 C43 1.812(5) . ?
P4 C30 1.822(4) . ?
P4 C49 1.825(5) . ?
N4 C62 1.339(7) . ?
N4 C63 1.448(6) . ?
C4 C5 1.404(6) . ?
C4 C9 1.408(5) . ?
C5 C6 1.393(6) . ?
C6 C7 1.389(6) . ?
C7 C8 1.381(7) . ?
C8 C9 1.395(6) . ?
C10 C15 1.395(6) . ?
C10 C11 1.402(5) . ?
C11 C12 1.384(7) . ?
C12 C13 1.383(8) . ?
C13 C14 1.409(7) . ?
C14 C15 1.376(8) . ?
C16 C21 1.393(6) . ?
C16 C17 1.405(6) . ?
C17 C18 1.387(8) . ?
C18 C19 1.386(8) . ?
C19 C20 1.396(7) . ?
C20 C21 1.387(7) . ?
C22 C27 1.386(7) . ?
C22 C23 1.396(6) . ?
C23 C24 1.387(6) . ?
C24 C25 1.382(7) . ?
C25 C26 1.388(7) . ?
C26 C27 1.393(6) . ?
C28 C29 1.534(5) . ?
C29 C30 1.530(7) . ?
C31 C32 1.402(5) . ?
C31 C36 1.409(6) . ?
C32 C33 1.387(7) . ?
C33 C34 1.399(7) . ?
C34 C35 1.387(7) . ?
C35 C36 1.384(8) . ?
C37 C38 1.401(6) . ?
C37 C42 1.405(6) . ?
C38 C39 1.399(6) . ?
C39 C40 1.389(8) . ?
C40 C41 1.380(8) . ?
C41 C42 1.396(6) . ?
C43 C48 1.393(6) . ?
C43 C44 1.404(6) . ?
C44 C45 1.386(7) . ?
C45 C46 1.386(9) . ?
C46 C47 1.390(8) . ?
C47 C48 1.391(7) . ?
C49 C54 1.396(7) . ?
C49 C50 1.397(5) . ?
C50 C51 1.391(7) . ?
C51 C52 1.379(8) . ?
C52 C53 1.395(7) . ?
C53 C54 1.395(7) . ?
C55 C56 1.529(5) . ?
C58 C59 1.527(9) . ?
C60 C61 1.527(6) . ?
C63 C64 1.520(7) . ?
Cl1C C1C 1.752(6) . ?
C1C Cl2C 1.771(7) . ?
Cl1A C1A 1.751(9) . ?
C1A Cl2A 1.772(7) . ?
Cl1D C1D 1.764(7) . ?
C1D Cl2D 1.772(7) . ?
Cl1B C1B 1.753(7) . ?
C1B Cl2B 1.774(6) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
P2 Pt1 S1 C55 105.34(13) . . . . ?
P1 Pt1 S1 C55 -131.7(3) . . . . ?
S2 Pt1 S1 C55 -74.76(13) . . . . ?
P2 Pt1 S1 Pt2 -150.01(4) . . . . ?
P1 Pt1 S1 Pt2 -27.0(3) . . . . ?
S2 Pt1 S1 Pt2 29.89(3) . . . . ?
P2 Pt1 P1 C1 -35.65(18) . . . . ?
S1 Pt1 P1 C1 -158.4(3) . . . . ?
S2 Pt1 P1 C1 145.08(18) . . . . ?
P2 Pt1 P1 C4 -156.46(15) . . . . ?
S1 Pt1 P1 C4 80.8(4) . . . . ?
S2 Pt1 P1 C4 24.27(15) . . . . ?
P2 Pt1 P1 C10 84.10(14) . . . . ?
S1 Pt1 P1 C10 -38.7(4) . . . . ?
S2 Pt1 P1 C10 -95.16(14) . . . . ?
Cl1 Pb1 O1 C57 144.4(3) . . . . ?
Cl3 Pb1 O1 C57 50.5(3) . . . . ?
Cl2 Pb1 O1 C57 100.6(8) . . . . ?
C4 P1 C1 C2 -177.4(3) . . . . ?
C10 P1 C1 C2 -68.3(3) . . . . ?
Pt1 P1 C1 C2 56.0(3) . . . . ?
P1 Pt1 P2 C16 -85.81(13) . . . . ?
S1 Pt1 P2 C16 88.31(13) . . . . ?
S2 Pt1 P2 C16 87.4(4) . . . . ?
P1 Pt1 P2 C22 154.68(16) . . . . ?
S1 Pt1 P2 C22 -31.19(16) . . . . ?
S2 Pt1 P2 C22 -32.1(4) . . . . ?
P1 Pt1 P2 C3 35.74(17) . . . . ?
S1 Pt1 P2 C3 -150.13(17) . . . . ?
S2 Pt1 P2 C3 -151.1(4) . . . . ?
C55 S1 Pt2 P4 69.7(4) . . . . ?
Pt1 S1 Pt2 P4 -38.8(4) . . . . ?
C55 S1 Pt2 P3 -110.65(13) . . . . ?
Pt1 S1 Pt2 P3 140.78(4) . . . . ?
C55 S1 Pt2 S2 78.49(13) . . . . ?
Pt1 S1 Pt2 S2 -30.07(3) . . . . ?
P4 Pt2 S2 C60 103.94(14) . . . . ?
P3 Pt2 S2 C60 -143.0(2) . . . . ?
S1 Pt2 S2 C60 -75.18(14) . . . . ?
P4 Pt2 S2 Pt1 -151.05(4) . . . . ?
P3 Pt2 S2 Pt1 -38.0(2) . . . . ?
S1 Pt2 S2 Pt1 29.83(3) . . . . ?
P2 Pt1 S2 C60 81.3(4) . . . . ?
P1 Pt1 S2 C60 -105.48(13) . . . . ?
S1 Pt1 S2 C60 80.38(13) . . . . ?
P2 Pt1 S2 Pt2 -29.1(4) . . . . ?
P1 Pt1 S2 Pt2 144.09(4) . . . . ?
S1 Pt1 S2 Pt2 -30.05(3) . . . . ?
Cl4 Pb2 O2 C62 130.6(5) . . . . ?
Cl6 Pb2 O2 C62 35.4(5) . . . . ?
Cl5 Pb2 O2 C62 59.1(10) . . . . ?
P1 C1 C2 C3 -74.2(4) . . . . ?
P4 Pt2 P3 C28 -34.58(17) . . . . ?
S2 Pt2 P3 C28 -147.4(2) . . . . ?
S1 Pt2 P3 C28 145.45(16) . . . . ?
P4 Pt2 P3 C31 84.59(13) . . . . ?
S2 Pt2 P3 C31 -28.2(2) . . . . ?
S1 Pt2 P3 C31 -95.37(13) . . . . ?
P4 Pt2 P3 C37 -156.35(18) . . . . ?
S2 Pt2 P3 C37 90.8(3) . . . . ?
S1 Pt2 P3 C37 23.69(18) . . . . ?
C1 C2 C3 P2 75.8(4) . . . . ?
C16 P2 C3 C2 67.6(4) . . . . ?
C22 P2 C3 C2 177.4(3) . . . . ?
Pt1 P2 C3 C2 -57.6(4) . . . . ?
P3 Pt2 P4 C43 -84.80(16) . . . . ?
S2 Pt2 P4 C43 86.10(16) . . . . ?
S1 Pt2 P4 C43 94.8(4) . . . . ?
P3 Pt2 P4 C30 36.97(19) . . . . ?
S2 Pt2 P4 C30 -152.13(18) . . . . ?
S1 Pt2 P4 C30 -143.4(4) . . . . ?
P3 Pt2 P4 C49 156.65(15) . . . . ?
S2 Pt2 P4 C49 -32.45(15) . . . . ?
S1 Pt2 P4 C49 -23.7(4) . . . . ?
C1 P1 C4 C5 -41.5(4) . . . . ?
C10 P1 C4 C5 -150.8(3) . . . . ?
Pt1 P1 C4 C5 85.0(3) . . . . ?
C1 P1 C4 C9 141.1(3) . . . . ?
C10 P1 C4 C9 31.7(4) . . . . ?
Pt1 P1 C4 C9 -92.4(3) . . . . ?
C9 C4 C5 C6 -2.3(6) . . . . ?
P1 C4 C5 C6 -179.7(3) . . . . ?
C4 C5 C6 C7 1.5(6) . . . . ?
C5 C6 C7 C8 0.2(6) . . . . ?
C6 C7 C8 C9 -1.2(7) . . . . ?
C7 C8 C9 C4 0.3(7) . . . . ?
C5 C4 C9 C8 1.4(6) . . . . ?
P1 C4 C9 C8 178.8(3) . . . . ?
C1 P1 C10 C15 128.5(4) . . . . ?
C4 P1 C10 C15 -122.4(4) . . . . ?
Pt1 P1 C10 C15 3.0(4) . . . . ?
C1 P1 C10 C11 -50.6(4) . . . . ?
C4 P1 C10 C11 58.5(4) . . . . ?
Pt1 P1 C10 C11 -176.1(3) . . . . ?
C15 C10 C11 C12 0.7(7) . . . . ?
P1 C10 C11 C12 179.8(4) . . . . ?
C10 C11 C12 C13 -0.7(7) . . . . ?
C11 C12 C13 C14 0.9(8) . . . . ?
C12 C13 C14 C15 -1.0(9) . . . . ?
C13 C14 C15 C10 0.9(8) . . . . ?
C11 C10 C15 C14 -0.8(7) . . . . ?
P1 C10 C15 C14 -179.9(4) . . . . ?
C22 P2 C16 C21 92.2(3) . . . . ?
C3 P2 C16 C21 -158.4(3) . . . . ?
Pt1 P2 C16 C21 -33.1(3) . . . . ?
C22 P2 C16 C17 -85.7(3) . . . . ?
C3 P2 C16 C17 23.7(4) . . . . ?
Pt1 P2 C16 C17 149.0(3) . . . . ?
C21 C16 C17 C18 1.0(6) . . . . ?
P2 C16 C17 C18 179.0(3) . . . . ?
C16 C17 C18 C19 -1.2(7) . . . . ?
C17 C18 C19 C20 0.1(7) . . . . ?
C18 C19 C20 C21 1.2(7) . . . . ?
C19 C20 C21 C16 -1.5(6) . . . . ?
C17 C16 C21 C20 0.4(6) . . . . ?
P2 C16 C21 C20 -177.6(3) . . . . ?
C16 P2 C22 C27 163.4(3) . . . . ?
C3 P2 C22 C27 52.0(4) . . . . ?
Pt1 P2 C22 C27 -72.3(4) . . . . ?
C16 P2 C22 C23 -16.3(4) . . . . ?
C3 P2 C22 C23 -127.7(4) . . . . ?
Pt1 P2 C22 C23 108.1(4) . . . . ?
C27 C22 C23 C24 -1.7(7) . . . . ?
P2 C22 C23 C24 177.9(4) . . . . ?
C22 C23 C24 C25 0.3(7) . . . . ?
C23 C24 C25 C26 1.0(8) . . . . ?
C24 C25 C26 C27 -1.0(8) . . . . ?
C23 C22 C27 C26 1.8(7) . . . . ?
P2 C22 C27 C26 -177.9(4) . . . . ?
C25 C26 C27 C22 -0.4(7) . . . . ?
C31 P3 C28 C29 -70.8(4) . . . . ?
C37 P3 C28 C29 -179.5(4) . . . . ?
Pt2 P3 C28 C29 53.0(4) . . . . ?
P3 C28 C29 C30 -71.2(5) . . . . ?
C28 C29 C30 P4 75.7(4) . . . . ?
C43 P4 C30 C29 65.6(3) . . . . ?
C49 P4 C30 C29 173.0(3) . . . . ?
Pt2 P4 C30 C29 -60.3(3) . . . . ?
C28 P3 C31 C32 120.8(3) . . . . ?
C37 P3 C31 C32 -130.3(3) . . . . ?
Pt2 P3 C31 C32 -4.9(4) . . . . ?
C28 P3 C31 C36 -58.4(4) . . . . ?
C37 P3 C31 C36 50.5(4) . . . . ?
Pt2 P3 C31 C36 175.8(3) . . . . ?
C36 C31 C32 C33 0.4(6) . . . . ?
P3 C31 C32 C33 -178.9(3) . . . . ?
C31 C32 C33 C34 -1.7(6) . . . . ?
C32 C33 C34 C35 2.0(7) . . . . ?
C33 C34 C35 C36 -0.9(7) . . . . ?
C34 C35 C36 C31 -0.4(7) . . . . ?
C32 C31 C36 C35 0.7(6) . . . . ?
P3 C31 C36 C35 180.0(4) . . . . ?
C28 P3 C37 C38 -30.7(4) . . . . ?
C31 P3 C37 C38 -139.4(4) . . . . ?
Pt2 P3 C37 C38 97.0(4) . . . . ?
C28 P3 C37 C42 152.2(4) . . . . ?
C31 P3 C37 C42 43.6(4) . . . . ?
Pt2 P3 C37 C42 -80.1(4) . . . . ?
C42 C37 C38 C39 -2.5(7) . . . . ?
P3 C37 C38 C39 -179.5(4) . . . . ?
C37 C38 C39 C40 2.3(7) . . . . ?
C38 C39 C40 C41 -0.5(8) . . . . ?
C39 C40 C41 C42 -1.2(8) . . . . ?
C40 C41 C42 C37 1.0(8) . . . . ?
C38 C37 C42 C41 0.8(7) . . . . ?
P3 C37 C42 C41 177.9(4) . . . . ?
C30 P4 C43 C48 -164.7(4) . . . . ?
C49 P4 C43 C48 87.0(4) . . . . ?
Pt2 P4 C43 C48 -39.3(4) . . . . ?
C30 P4 C43 C44 20.1(4) . . . . ?
C49 P4 C43 C44 -88.3(4) . . . . ?
Pt2 P4 C43 C44 145.5(3) . . . . ?
C48 C43 C44 C45 -0.5(7) . . . . ?
P4 C43 C44 C45 174.9(4) . . . . ?
C43 C44 C45 C46 -0.9(8) . . . . ?
C44 C45 C46 C47 1.5(9) . . . . ?
C45 C46 C47 C48 -0.8(9) . . . . ?
C46 C47 C48 C43 -0.6(8) . . . . ?
C44 C43 C48 C47 1.2(7) . . . . ?
P4 C43 C48 C47 -174.2(4) . . . . ?
C43 P4 C49 C54 152.8(3) . . . . ?
C30 P4 C49 C54 42.3(4) . . . . ?
Pt2 P4 C49 C54 -82.5(3) . . . . ?
C43 P4 C49 C50 -25.2(4) . . . . ?
C30 P4 C49 C50 -135.8(3) . . . . ?
Pt2 P4 C49 C50 99.5(3) . . . . ?
C54 C49 C50 C51 -2.8(6) . . . . ?
P4 C49 C50 C51 175.3(3) . . . . ?
C49 C50 C51 C52 -0.2(7) . . . . ?
C50 C51 C52 C53 2.3(7) . . . . ?
C51 C52 C53 C54 -1.4(8) . . . . ?
C52 C53 C54 C49 -1.6(8) . . . . ?
C50 C49 C54 C53 3.7(7) . . . . ?
P4 C49 C54 C53 -174.4(4) . . . . ?
Pt1 S1 C55 C56 -150.8(2) . . . . ?
Pt2 S1 C55 C56 116.4(3) . . . . ?
C57 N1 C56 C55 -78.1(5) . . . . ?
S1 C55 C56 N1 -168.5(3) . . . . ?
Pb1 O1 C57 N2 -49.1(5) . . . . ?
Pb1 O1 C57 N1 133.0(4) . . . . ?
C58 N2 C57 O1 169.8(5) . . . . ?
C58 N2 C57 N1 -12.3(7) . . . . ?
C56 N1 C57 O1 0.4(6) . . . . ?
C56 N1 C57 N2 -177.6(4) . . . . ?
C57 N2 C58 C59 -74.4(8) . . . . ?
Pt2 S2 C60 C61 -139.7(2) . . . . ?
Pt1 S2 C60 C61 127.1(3) . . . . ?
C62 N3 C61 C60 -77.3(5) . . . . ?
S2 C60 C61 N3 -165.8(3) . . . . ?
Pb2 O2 C62 N4 -36.7(7) . . . . ?
Pb2 O2 C62 N3 146.8(3) . . . . ?
C63 N4 C62 O2 171.2(4) . . . . ?
C63 N4 C62 N3 -12.3(7) . . . . ?
C61 N3 C62 O2 -9.0(6) . . . . ?
C61 N3 C62 N4 174.4(4) . . . . ?
C62 N4 C63 C64 -76.9(6) . . . . ?
