#------------------------------------------------------------------------------
#$Date: 2016-03-24 16:31:00 +0100 (jue 24 de mar de 2016) $
#$Revision: 179688 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/10/7001051.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7001051
loop_
_publ_author_name
'Hoshino, Manabu'
'Uekusa, Hidehiro'
'Sonoda, Shintaro'
'Otsuka, Takuhiro'
'Kaizu, Youkoh'
_publ_section_title
;
 Photocrystallographic analysis of [AuCl(PPh3)2] for elucidation of the
 crystal packing effect on the photophysical properties
;
_journal_issue                   16
_journal_name_full               'Dalton Transactions'
_journal_page_first              3085
_journal_page_last               3091
_journal_paper_doi               10.1039/b820066a
_journal_year                    2009
_chemical_formula_sum            'C36 H30 Au Cl P2'
_chemical_formula_weight         756.96
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                113.3174(10)
_cell_angle_beta                 95.3078(8)
_cell_angle_gamma                109.5354(9)
_cell_formula_units_Z            2
_cell_length_a                   10.8650(2)
_cell_length_b                   11.83530(10)
_cell_length_c                   14.2085(2)
_cell_measurement_temperature    177(2)
_cell_volume                     1526.96(4)
_computing_cell_refinement       'HKL Research, Inc. HKL-2000'
_computing_data_collection       'Rigaku RAPID AUTO'
_computing_data_reduction        'HKL Research, Inc. HKL-2000'
_computing_molecular_graphics    'ORTEP-3 for Windows (Farrugia, 1998)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SIR2002 (Giacovazzo, 2003)'
_diffrn_ambient_temperature      177(2)
_diffrn_measured_fraction_theta_full 0.988
_diffrn_measured_fraction_theta_max 0.988
_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID Imaging Plate'
_diffrn_measurement_method       'omega scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Rigaku rotating anode Ultrax18'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.021
_diffrn_reflns_av_sigmaI/netI    0.0155
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            44680
_diffrn_reflns_theta_full        32.33
_diffrn_reflns_theta_max         32.33
_diffrn_reflns_theta_min         2.05
_exptl_absorpt_coefficient_mu    5.034
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.753
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'HKL SCALEPACK (Otwinowski & Minor, 1997)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.646
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             744
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.20
_refine_diff_density_max         1.079
_refine_diff_density_min         -0.659
_refine_diff_density_rms         0.063
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.103
_refine_ls_hydrogen_treatment    refxyz
_refine_ls_matrix_type           full
_refine_ls_number_parameters     451
_refine_ls_number_reflns         10782
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.103
_refine_ls_R_factor_all          0.0147
_refine_ls_R_factor_gt           0.0145
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0055P)²+1.0933P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0360
_refine_ls_wR_factor_ref         0.0361
_reflns_number_gt                10722
_reflns_number_total             10782
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b820066a.txt
_cod_data_source_block           177Koff
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7001051
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.211438(5) 0.244540(5) 0.275229(4) 0.02069(2) Uani 1 1 d . . .
P1 P 0.30664(3) 0.09583(3) 0.27626(3) 0.01934(6) Uani 1 1 d . . .
C111 C 0.25575(13) 0.00315(13) 0.35163(10) 0.0201(2) Uani 1 1 d . . .
C112 C 0.34139(15) -0.04308(16) 0.39011(12) 0.0266(3) Uani 1 1 d . . .
H112 H 0.430(2) -0.024(2) 0.3771(17) 0.032 Uiso 1 1 d . . .
C113 C 0.30013(16) -0.11437(17) 0.44718(13) 0.0302(3) Uani 1 1 d . . .
H113 H 0.354(2) -0.147(2) 0.4705(18) 0.036 Uiso 1 1 d . . .
C114 C 0.17348(16) -0.13940(15) 0.46669(13) 0.0293(3) Uani 1 1 d . . .
H114 H 0.146(2) -0.186(2) 0.5073(17) 0.035 Uiso 1 1 d . . .
C115 C 0.08832(15) -0.09350(15) 0.42911(13) 0.0280(3) Uani 1 1 d . . .
H115 H 0.002(2) -0.110(2) 0.4435(17) 0.034 Uiso 1 1 d . . .
C116 C 0.12886(14) -0.02186(14) 0.37203(11) 0.0237(2) Uani 1 1 d . . .
H116 H 0.071(2) 0.011(2) 0.3512(16) 0.028 Uiso 1 1 d . . .
C121 C 0.29028(14) -0.02850(14) 0.14367(11) 0.0239(2) Uani 1 1 d . . .
C122 C 0.2805(2) -0.15686(17) 0.12071(14) 0.0430(4) Uani 1 1 d . . .
H122 H 0.277(3) -0.185(3) 0.175(2) 0.052 Uiso 1 1 d . . .
C123 C 0.2747(3) -0.24491(19) 0.01834(17) 0.0542(6) Uani 1 1 d . . .
H123 H 0.267(3) -0.332(3) 0.004(2) 0.065 Uiso 1 1 d . . .
C124 C 0.2777(2) -0.2066(2) -0.06089(15) 0.0477(5) Uani 1 1 d . . .
H124 H 0.272(3) -0.268(3) -0.131(2) 0.057 Uiso 1 1 d . . .
C125 C 0.2865(3) -0.0799(3) -0.03878(16) 0.0537(6) Uani 1 1 d . . .
H125 H 0.292(3) -0.051(3) -0.090(2) 0.064 Uiso 1 1 d . . .
C126 C 0.2920(2) 0.0092(2) 0.06272(14) 0.0417(4) Uani 1 1 d . . .
H126 H 0.302(3) 0.097(3) 0.077(2) 0.050 Uiso 1 1 d . . .
C131 C 0.48774(13) 0.19005(13) 0.33298(10) 0.0211(2) Uani 1 1 d . . .
C132 C 0.58288(15) 0.15002(16) 0.28611(12) 0.0286(3) Uani 1 1 d . . .
H132 H 0.554(2) 0.068(2) 0.2233(17) 0.034 Uiso 1 1 d . . .
C133 C 0.72018(15) 0.22885(19) 0.33289(13) 0.0341(3) Uani 1 1 d . . .
H133 H 0.786(2) 0.201(2) 0.3012(19) 0.041 Uiso 1 1 d . . .
C134 C 0.76281(16) 0.34740(18) 0.42569(13) 0.0332(3) Uani 1 1 d . . .
H134 H 0.856(2) 0.399(2) 0.4571(18) 0.040 Uiso 1 1 d . . .
C135 C 0.66885(17) 0.38754(17) 0.47338(13) 0.0325(3) Uani 1 1 d . . .
H135 H 0.693(2) 0.468(2) 0.5326(18) 0.039 Uiso 1 1 d . . .
C136 C 0.53169(15) 0.30928(15) 0.42738(12) 0.0278(3) Uani 1 1 d . . .
H136 H 0.465(2) 0.339(2) 0.4587(17) 0.033 Uiso 1 1 d . . .
P2 P 0.23153(3) 0.38890(4) 0.20000(3) 0.02107(6) Uani 1 1 d . . .
C211 C 0.39859(13) 0.52681(14) 0.25989(11) 0.0231(2) Uani 1 1 d . . .
C212 C 0.50594(16) 0.50158(19) 0.29457(16) 0.0354(3) Uani 1 1 d . . .
H212 H 0.494(2) 0.419(2) 0.2856(19) 0.043 Uiso 1 1 d . . .
C213 C 0.63381(17) 0.6050(2) 0.34623(17) 0.0419(4) Uani 1 1 d . . .
H213 H 0.707(3) 0.587(3) 0.370(2) 0.050 Uiso 1 1 d . . .
C214 C 0.65599(17) 0.7337(2) 0.36239(14) 0.0381(4) Uani 1 1 d . . .
H214 H 0.741(2) 0.801(2) 0.3979(19) 0.046 Uiso 1 1 d . . .
C215 C 0.55140(18) 0.75984(17) 0.32752(16) 0.0389(4) Uani 1 1 d . . .
H215 H 0.565(2) 0.848(3) 0.338(2) 0.047 Uiso 1 1 d . . .
C216 C 0.42236(16) 0.65706(16) 0.27694(14) 0.0317(3) Uani 1 1 d . . .
H216 H 0.348(2) 0.678(2) 0.2566(18) 0.038 Uiso 1 1 d . . .
C221 C 0.11244(13) 0.46698(14) 0.20638(11) 0.0227(2) Uani 1 1 d . . .
C222 C 0.09469(17) 0.52341(17) 0.13936(13) 0.0306(3) Uani 1 1 d . . .
H222 H 0.145(2) 0.516(2) 0.0861(18) 0.037 Uiso 1 1 d . . .
C223 C 0.00636(18) 0.58659(18) 0.14937(14) 0.0348(3) Uani 1 1 d . . .
H223 H -0.005(2) 0.625(2) 0.1041(19) 0.042 Uiso 1 1 d . . .
C224 C -0.06553(17) 0.59317(17) 0.22573(14) 0.0338(3) Uani 1 1 d . . .
H224 H -0.126(2) 0.636(2) 0.2296(18) 0.041 Uiso 1 1 d . . .
C225 C -0.04893(18) 0.53726(18) 0.29229(14) 0.0344(3) Uani 1 1 d . . .
H225 H -0.098(2) 0.543(2) 0.3481(19) 0.041 Uiso 1 1 d . . .
C226 C 0.03976(15) 0.47372(15) 0.28270(12) 0.0271(3) Uani 1 1 d . . .
H226 H 0.049(2) 0.433(2) 0.3249(17) 0.033 Uiso 1 1 d . . .
C231 C 0.22128(15) 0.30524(15) 0.05918(11) 0.0259(2) Uani 1 1 d . . .
C232 C 0.3242(2) 0.3471(2) 0.01461(16) 0.0532(6) Uani 1 1 d . . .
H232 H 0.397(3) 0.419(3) 0.052(2) 0.064 Uiso 1 1 d . . .
C233 C 0.3127(3) 0.2744(3) -0.09253(18) 0.0715(9) Uani 1 1 d . . .
H233 H 0.383(3) 0.302(3) -0.120(3) 0.086 Uiso 1 1 d . . .
C234 C 0.2002(2) 0.1589(3) -0.15547(15) 0.0532(5) Uani 1 1 d . . .
H234 H 0.194(3) 0.106(3) -0.228(2) 0.064 Uiso 1 1 d . . .
C235 C 0.0963(2) 0.1168(2) -0.11213(15) 0.0466(5) Uani 1 1 d . . .
H235 H 0.017(3) 0.037(3) -0.155(2) 0.056 Uiso 1 1 d . . .
C236 C 0.10614(18) 0.1898(2) -0.00535(13) 0.0386(4) Uani 1 1 d . . .
H236 H 0.034(2) 0.156(2) 0.027(2) 0.046 Uiso 1 1 d . . .
Cl1 Cl 0.06765(4) 0.26544(4) 0.40750(3) 0.03302(7) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P2 Au1 P1 136.695(12) . . ?
P2 Au1 Cl1 114.206(12) . . ?
P1 Au1 Cl1 108.733(12) . . ?
P2 Au1 Au1 79.775(9) . 2 ?
P1 Au1 Au1 90.138(8) . 2 ?
Cl1 Au1 Au1 111.215(10) . 2 ?
C111 P1 C131 104.01(6) . . ?
C111 P1 C121 106.09(6) . . ?
C131 P1 C121 104.32(6) . . ?
C111 P1 Au1 119.55(4) . . ?
C131 P1 Au1 108.41(4) . . ?
C121 P1 Au1 113.09(5) . . ?
C116 C111 C112 119.28(12) . . ?
C116 C111 P1 119.38(10) . . ?
C112 C111 P1 121.34(10) . . ?
C113 C112 C111 120.38(13) . . ?
C113 C112 H112 120.4(13) . . ?
C111 C112 H112 119.2(13) . . ?
C114 C113 C112 119.99(14) . . ?
C114 C113 H113 119.2(14) . . ?
C112 C113 H113 120.8(14) . . ?
C115 C114 C113 119.93(13) . . ?
C115 C114 H114 120.2(13) . . ?
C113 C114 H114 119.8(13) . . ?
C114 C115 C116 120.48(13) . . ?
C114 C115 H115 119.9(14) . . ?
C116 C115 H115 119.6(14) . . ?
C115 C116 C111 119.94(13) . . ?
C115 C116 H116 118.1(13) . . ?
C111 C116 H116 121.9(13) . . ?
C122 C121 C126 118.70(14) . . ?
C122 C121 P1 123.17(12) . . ?
C126 C121 P1 118.10(12) . . ?
C121 C122 C123 120.14(17) . . ?
C121 C122 H122 119.5(16) . . ?
C123 C122 H122 120.4(16) . . ?
C124 C123 C122 120.82(19) . . ?
C124 C123 H123 120.2(18) . . ?
C122 C123 H123 119.0(18) . . ?
C123 C124 C125 119.30(17) . . ?
C123 C124 H124 120.1(17) . . ?
C125 C124 H124 120.6(17) . . ?
C124 C125 C126 120.71(19) . . ?
C124 C125 H125 120.8(18) . . ?
C126 C125 H125 118.4(18) . . ?
C121 C126 C125 120.33(18) . . ?
C121 C126 H126 120.4(16) . . ?
C125 C126 H126 119.2(16) . . ?
C132 C131 C136 119.41(13) . . ?
C132 C131 P1 123.20(11) . . ?
C136 C131 P1 117.38(10) . . ?
C133 C132 C131 120.05(14) . . ?
C133 C132 H132 119.9(13) . . ?
C131 C132 H132 120.1(13) . . ?
C134 C133 C132 120.18(15) . . ?
C134 C133 H133 119.4(14) . . ?
C132 C133 H133 120.5(14) . . ?
C133 C134 C135 120.18(14) . . ?
C133 C134 H134 119.1(14) . . ?
C135 C134 H134 120.7(14) . . ?
C136 C135 C134 120.00(15) . . ?
C136 C135 H135 117.1(14) . . ?
C134 C135 H135 122.7(14) . . ?
C135 C136 C131 120.18(14) . . ?
C135 C136 H136 120.5(13) . . ?
C131 C136 H136 119.3(13) . . ?
C221 P2 C231 104.33(7) . . ?
C221 P2 C211 105.83(6) . . ?
C231 P2 C211 105.54(6) . . ?
C221 P2 Au1 119.58(5) . . ?
C231 P2 Au1 111.20(5) . . ?
C211 P2 Au1 109.36(5) . . ?
C216 C211 C212 118.61(14) . . ?
C216 C211 P2 123.01(11) . . ?
C212 C211 P2 118.31(12) . . ?
C213 C212 C211 120.60(17) . . ?
C213 C212 H212 118.2(15) . . ?
C211 C212 H212 121.2(15) . . ?
C214 C213 C212 120.16(17) . . ?
C214 C213 H213 119.9(15) . . ?
C212 C213 H213 120.0(16) . . ?
C215 C214 C213 119.91(16) . . ?
C215 C214 H214 120.9(16) . . ?
C213 C214 H214 119.1(16) . . ?
C214 C215 C216 120.31(17) . . ?
C214 C215 H215 121.3(15) . . ?
C216 C215 H215 118.4(15) . . ?
C211 C216 C215 120.41(16) . . ?
C211 C216 H216 120.0(13) . . ?
C215 C216 H216 119.5(13) . . ?
C226 C221 C222 119.38(13) . . ?
C226 C221 P2 118.60(10) . . ?
C222 C221 P2 122.00(11) . . ?
C223 C222 C221 120.24(15) . . ?
C223 C222 H222 121.7(14) . . ?
C221 C222 H222 118.0(14) . . ?
C222 C223 C224 120.07(15) . . ?
C222 C223 H223 119.8(15) . . ?
C224 C223 H223 120.1(15) . . ?
C225 C224 C223 120.12(15) . . ?
C225 C224 H224 122.0(14) . . ?
C223 C224 H224 117.9(14) . . ?
C224 C225 C226 120.10(16) . . ?
C224 C225 H225 121.0(14) . . ?
C226 C225 H225 118.9(14) . . ?
C221 C226 C225 120.09(14) . . ?
C221 C226 H226 119.3(13) . . ?
C225 C226 H226 120.6(13) . . ?
C232 C231 C236 118.63(15) . . ?
C232 C231 P2 123.47(13) . . ?
C236 C231 P2 117.84(12) . . ?
C231 C232 C233 120.51(19) . . ?
C231 C232 H232 121.7(19) . . ?
C233 C232 H232 117.8(19) . . ?
C234 C233 C232 120.7(2) . . ?
C234 C233 H233 120(2) . . ?
C232 C233 H233 119(2) . . ?
C233 C234 C235 119.30(19) . . ?
C233 C234 H234 120.9(17) . . ?
C235 C234 H234 119.7(17) . . ?
C234 C235 C236 120.41(18) . . ?
C234 C235 H235 120.0(16) . . ?
C236 C235 H235 119.6(16) . . ?
C231 C236 C235 120.41(17) . . ?
C231 C236 H236 119.2(14) . . ?
C235 C236 H236 120.2(14) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 P2 2.3127(3) . ?
Au1 P1 2.3244(3) . ?
Au1 Cl1 2.5432(3) . ?
Au1 Au1 7.45065(18) 2 ?
P1 C111 1.8137(13) . ?
P1 C131 1.8145(13) . ?
P1 C121 1.8206(14) . ?
C111 C116 1.3933(18) . ?
C111 C112 1.3955(19) . ?
C112 C113 1.388(2) . ?
C112 H112 0.97(2) . ?
C113 C114 1.386(2) . ?
C113 H113 0.91(2) . ?
C114 C115 1.382(2) . ?
C114 H114 0.95(2) . ?
C115 C116 1.390(2) . ?
C115 H115 0.95(2) . ?
C116 H116 0.93(2) . ?
C121 C122 1.385(2) . ?
C121 C126 1.388(2) . ?
C122 C123 1.394(2) . ?
C122 H122 0.96(3) . ?
C123 C124 1.370(3) . ?
C123 H123 0.94(3) . ?
C124 C125 1.372(3) . ?
C124 H124 0.95(3) . ?
C125 C126 1.390(3) . ?
C125 H125 0.92(3) . ?
C126 H126 0.94(3) . ?
C131 C132 1.3935(19) . ?
C131 C136 1.3967(19) . ?
C132 C133 1.390(2) . ?
C132 H132 0.95(2) . ?
C133 C134 1.382(3) . ?
C133 H133 0.96(2) . ?
C134 C135 1.387(3) . ?
C134 H134 0.94(2) . ?
C135 C136 1.387(2) . ?
C135 H135 0.92(2) . ?
C136 H136 0.98(2) . ?
P2 C221 1.8143(14) . ?
P2 C231 1.8201(14) . ?
P2 C211 1.8211(14) . ?
C211 C216 1.389(2) . ?
C211 C212 1.391(2) . ?
C212 C213 1.389(2) . ?
C212 H212 0.89(2) . ?
C213 C214 1.378(3) . ?
C213 H213 0.95(3) . ?
C214 C215 1.373(3) . ?
C214 H214 0.92(2) . ?
C215 C216 1.394(2) . ?
C215 H215 0.96(3) . ?
C216 H216 0.97(2) . ?
C221 C226 1.392(2) . ?
C221 C222 1.3948(19) . ?
C222 C223 1.386(2) . ?
C222 H222 0.96(2) . ?
C223 C224 1.387(3) . ?
C223 H223 0.94(2) . ?
C224 C225 1.381(2) . ?
C224 H224 0.95(2) . ?
C225 C226 1.393(2) . ?
C225 H225 0.99(2) . ?
C226 H226 0.92(2) . ?
C231 C232 1.380(2) . ?
C231 C236 1.387(2) . ?
C232 C233 1.389(3) . ?
C232 H232 0.86(3) . ?
C233 C234 1.369(3) . ?
C233 H233 0.91(3) . ?
C234 C235 1.377(3) . ?
C234 H234 0.96(3) . ?
C235 C236 1.389(3) . ?
C235 H235 0.95(3) . ?
C236 H236 0.99(2) . ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
C114 H114 Cl1 0.95(2) 2.78(2) 3.5564(15) 139.9(17) 2_556
C116 H116 Cl1 0.93(2) 2.80(2) 3.5321(14) 136.3(16) .
C226 H226 Cl1 0.92(2) 2.73(2) 3.6295(15) 167.0(17) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
P2 Au1 P1 C111 179.49(5) . . . . ?
Cl1 Au1 P1 C111 7.16(5) . . . . ?
Au1 Au1 P1 C111 -105.35(5) 2 . . . ?
P2 Au1 P1 C131 60.68(5) . . . . ?
Cl1 Au1 P1 C131 -111.65(5) . . . . ?
Au1 Au1 P1 C131 135.83(4) 2 . . . ?
P2 Au1 P1 C121 -54.49(5) . . . . ?
Cl1 Au1 P1 C121 133.18(5) . . . . ?
Au1 Au1 P1 C121 20.67(5) 2 . . . ?
C131 P1 C111 C116 146.56(11) . . . . ?
C121 P1 C111 C116 -103.73(12) . . . . ?
Au1 P1 C111 C116 25.52(13) . . . . ?
C131 P1 C111 C112 -33.11(13) . . . . ?
C121 P1 C111 C112 76.60(13) . . . . ?
Au1 P1 C111 C112 -154.15(10) . . . . ?
C116 C111 C112 C113 0.6(2) . . . . ?
P1 C111 C112 C113 -179.69(12) . . . . ?
C111 C112 C113 C114 -0.3(2) . . . . ?
C112 C113 C114 C115 0.1(3) . . . . ?
C113 C114 C115 C116 -0.2(2) . . . . ?
C114 C115 C116 C111 0.5(2) . . . . ?
C112 C111 C116 C115 -0.7(2) . . . . ?
P1 C111 C116 C115 179.59(11) . . . . ?
C111 P1 C121 C122 -16.95(17) . . . . ?
C131 P1 C121 C122 92.54(16) . . . . ?
Au1 P1 C121 C122 -149.87(14) . . . . ?
C111 P1 C121 C126 165.14(14) . . . . ?
C131 P1 C121 C126 -85.37(15) . . . . ?
Au1 P1 C121 C126 32.22(15) . . . . ?
C126 C121 C122 C123 0.9(3) . . . . ?
P1 C121 C122 C123 -176.95(18) . . . . ?
C121 C122 C123 C124 -0.3(4) . . . . ?
C122 C123 C124 C125 -0.1(4) . . . . ?
C123 C124 C125 C126 -0.1(4) . . . . ?
C122 C121 C126 C125 -1.2(3) . . . . ?
P1 C121 C126 C125 176.86(19) . . . . ?
C124 C125 C126 C121 0.8(4) . . . . ?
C111 P1 C131 C132 100.20(13) . . . . ?
C121 P1 C131 C132 -10.81(14) . . . . ?
Au1 P1 C131 C132 -131.57(12) . . . . ?
C111 P1 C131 C136 -80.83(12) . . . . ?
C121 P1 C131 C136 168.16(11) . . . . ?
Au1 P1 C131 C136 47.40(12) . . . . ?
C136 C131 C132 C133 -0.4(2) . . . . ?
P1 C131 C132 C133 178.57(13) . . . . ?
C131 C132 C133 C134 -0.3(3) . . . . ?
C132 C133 C134 C135 0.8(3) . . . . ?
C133 C134 C135 C136 -0.6(3) . . . . ?
C134 C135 C136 C131 -0.1(2) . . . . ?
C132 C131 C136 C135 0.6(2) . . . . ?
P1 C131 C136 C135 -178.45(12) . . . . ?
P1 Au1 P2 C221 170.22(5) . . . . ?
Cl1 Au1 P2 C221 -17.74(5) . . . . ?
Au1 Au1 P2 C221 91.05(5) 2 . . . ?
P1 Au1 P2 C231 48.52(6) . . . . ?
Cl1 Au1 P2 C231 -139.44(5) . . . . ?
Au1 Au1 P2 C231 -30.65(5) 2 . . . ?
P1 Au1 P2 C211 -67.64(5) . . . . ?
Cl1 Au1 P2 C211 104.39(5) . . . . ?
Au1 Au1 P2 C211 -146.82(5) 2 . . . ?
C221 P2 C211 C216 -15.69(14) . . . . ?
C231 P2 C211 C216 94.54(14) . . . . ?
Au1 P2 C211 C216 -145.75(12) . . . . ?
C221 P2 C211 C212 161.21(13) . . . . ?
C231 P2 C211 C212 -88.55(14) . . . . ?
Au1 P2 C211 C212 31.16(14) . . . . ?
C216 C211 C212 C213 0.7(3) . . . . ?
P2 C211 C212 C213 -176.32(15) . . . . ?
C211 C212 C213 C214 -0.9(3) . . . . ?
C212 C213 C214 C215 0.1(3) . . . . ?
C213 C214 C215 C216 0.8(3) . . . . ?
C212 C211 C216 C215 0.2(2) . . . . ?
P2 C211 C216 C215 177.07(14) . . . . ?
C214 C215 C216 C211 -0.9(3) . . . . ?
C231 P2 C221 C226 145.01(12) . . . . ?
C211 P2 C221 C226 -103.89(12) . . . . ?
Au1 P2 C221 C226 19.97(13) . . . . ?
C231 P2 C221 C222 -36.83(14) . . . . ?
C211 P2 C221 C222 74.27(14) . . . . ?
Au1 P2 C221 C222 -161.87(11) . . . . ?
C226 C221 C222 C223 0.6(2) . . . . ?
P2 C221 C222 C223 -177.59(13) . . . . ?
C221 C222 C223 C224 -0.4(3) . . . . ?
C222 C223 C224 C225 0.2(3) . . . . ?
C223 C224 C225 C226 -0.2(3) . . . . ?
C222 C221 C226 C225 -0.5(2) . . . . ?
P2 C221 C226 C225 177.71(13) . . . . ?
C224 C225 C226 C221 0.3(3) . . . . ?
C221 P2 C231 C232 110.45(19) . . . . ?
C211 P2 C231 C232 -0.8(2) . . . . ?
Au1 P2 C231 C232 -119.34(18) . . . . ?
C221 P2 C231 C236 -72.61(15) . . . . ?
C211 P2 C231 C236 176.09(14) . . . . ?
Au1 P2 C231 C236 57.60(15) . . . . ?
C236 C231 C232 C233 -0.4(4) . . . . ?
P2 C231 C232 C233 176.5(2) . . . . ?
C231 C232 C233 C234 -1.0(5) . . . . ?
C232 C233 C234 C235 1.6(5) . . . . ?
C233 C234 C235 C236 -0.8(4) . . . . ?
C232 C231 C236 C235 1.2(3) . . . . ?
P2 C231 C236 C235 -175.88(17) . . . . ?
C234 C235 C236 C231 -0.6(4) . . . . ?
