#------------------------------------------------------------------------------
#$Date: 2016-03-25 08:50:59 +0100 (vie 25 de mar de 2016) $
#$Revision: 179734 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/30/7003072.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7003072
loop_
_publ_author_name
'Zhou, Yongbo'
'Chen, Wanzhi'
'Wang, Daqi'
_publ_section_title
;
 Mononuclear, dinuclear, hexanuclear, and one-dimensional polymeric
 silver complexes having ligand-supported and unsupported argentophilic
 interactions stabilized by pincer-like 2,6-bis(5-pyrazolyl)pyridine
 ligands
;
_journal_issue                   11
_journal_name_full               'Dalton Transactions'
_journal_page_first              1444
_journal_page_last               1453
_journal_paper_doi               10.1039/b710916d
_journal_year                    2008
_chemical_formula_moiety         'C19 H25 Ag N6 O3'
_chemical_formula_sum            'C19 H25 Ag N6 O3'
_chemical_formula_weight         493.32
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 117.224(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   23.981(4)
_cell_length_b                   9.1046(17)
_cell_length_c                   21.983(4)
_cell_measurement_reflns_used    2214
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      19.562
_cell_measurement_theta_min      2.467
_cell_volume                     4268.0(13)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type
'Bruker SMART CCD area-detector diffractometer'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0843
_diffrn_reflns_av_sigmaI/netI    0.1701
_diffrn_reflns_limit_h_max       27
_diffrn_reflns_limit_h_min       -28
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            21593
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         1.85
_exptl_absorpt_coefficient_mu    0.976
_exptl_absorpt_correction_T_max  0.9260
_exptl_absorpt_correction_T_min  0.8438
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.535
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2016
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.14
_exptl_crystal_size_min          0.08
_refine_diff_density_max         0.526
_refine_diff_density_min         -0.552
_refine_diff_density_rms         0.096
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.024
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     523
_refine_ls_number_reflns         7455
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.024
_refine_ls_R_factor_all          0.1715
_refine_ls_R_factor_gt           0.0616
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0000P)²+3.1914P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1493
_refine_ls_wR_factor_ref         0.2201
_reflns_number_gt                3108
_reflns_number_total             7455
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b710916d.txt
_cod_data_source_block           complex_2
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_cell_volume        4268.1(14)
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               7003072
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.40991(4) 0.41391(9) 0.35429(4) 0.0709(3) Uani 1 1 d . . .
Ag2 Ag 0.08220(4) 0.90782(9) 0.42958(5) 0.0737(3) Uani 1 1 d . . .
N1 N 0.5045(3) 0.5306(8) 0.4149(4) 0.0458(18) Uani 1 1 d . . .
N2 N 0.4992(3) 0.2787(9) 0.3417(4) 0.056(2) Uani 1 1 d . . .
N3 N 0.5132(4) 0.1700(9) 0.3089(4) 0.059(2) Uani 1 1 d . . .
N4 N 0.3927(4) 0.6670(9) 0.3884(4) 0.062(2) Uani 1 1 d . . .
N5 N 0.3467(3) 0.7499(9) 0.3930(4) 0.065(2) Uani 1 1 d . . .
N6 N 0.3015(5) 0.2254(13) 0.2952(6) 0.081(3) Uani 1 1 d . . .
N7 N -0.0105(3) 1.0252(8) 0.4063(4) 0.0463(18) Uani 1 1 d . . .
N8 N 0.1026(4) 1.1648(9) 0.4829(5) 0.071(2) Uani 1 1 d . . .
N9 N 0.1497(4) 1.2509(10) 0.5284(5) 0.073(2) Uani 1 1 d . . .
N10 N -0.0103(3) 0.7681(9) 0.3366(4) 0.057(2) Uani 1 1 d . . .
N11 N -0.0280(4) 0.6530(9) 0.2934(4) 0.062(2) Uani 1 1 d . . .
N12 N 0.1944(4) 0.7322(11) 0.4778(5) 0.066(2) Uani 1 1 d . . .
O1 O 0.3471(4) 0.2137(9) 0.3490(4) 0.092(2) Uani 1 1 d . . .
O2 O 0.2982(5) 0.3249(13) 0.2568(5) 0.131(4) Uani 1 1 d . . .
O3 O 0.2583(4) 0.1355(13) 0.2793(6) 0.149(4) Uani 1 1 d . . .
O4 O 0.1829(4) 0.8251(10) 0.4329(5) 0.099(3) Uani 1 1 d . . .
O5 O 0.1535(4) 0.7096(10) 0.4957(5) 0.109(3) Uani 1 1 d . . .
O6 O 0.2436(4) 0.6620(11) 0.5032(5) 0.115(3) Uani 1 1 d . . .
C1 C 0.5062(4) 0.6524(10) 0.4511(4) 0.045(2) Uani 1 1 d . . .
C2 C 0.5631(4) 0.7129(11) 0.4978(5) 0.062(3) Uani 1 1 d . . .
H2 H 0.5640 0.7954 0.5232 0.074 Uiso 1 1 calc R . .
C3 C 0.6176(4) 0.6490(12) 0.5058(5) 0.061(3) Uani 1 1 d . . .
H3 H 0.6561 0.6891 0.5360 0.074 Uiso 1 1 calc R . .
C4 C 0.6154(4) 0.5270(11) 0.4696(5) 0.058(3) Uani 1 1 d . . .
H4 H 0.6525 0.4807 0.4770 0.070 Uiso 1 1 calc R . .
C5 C 0.5589(4) 0.4706(10) 0.4218(4) 0.047(2) Uani 1 1 d . . .
C6 C 0.5540(4) 0.3425(10) 0.3794(5) 0.049(2) Uani 1 1 d . . .
C7 C 0.6016(4) 0.2749(11) 0.3715(5) 0.062(3) Uani 1 1 d . . .
H7 H 0.6439 0.2996 0.3933 0.074 Uiso 1 1 calc R . .
C8 C 0.5749(6) 0.1662(12) 0.3259(6) 0.070(3) Uani 1 1 d . . .
C9 C 0.6034(6) 0.0587(13) 0.2959(7) 0.102(4) Uani 1 1 d . . .
H9A H 0.5713 -0.0046 0.2641 0.152 Uiso 1 1 calc R . .
H9B H 0.6346 0.0008 0.3319 0.152 Uiso 1 1 calc R . .
H9C H 0.6226 0.1115 0.2726 0.152 Uiso 1 1 calc R . .
C10 C 0.4463(4) 0.7132(9) 0.4391(5) 0.049(2) Uani 1 1 d . . .
C11 C 0.4342(4) 0.8281(10) 0.4746(5) 0.052(2) Uani 1 1 d . . .
H11 H 0.4636 0.8811 0.5115 0.062 Uiso 1 1 calc R . .
C12 C 0.3714(4) 0.8455(11) 0.4444(5) 0.059(3) Uani 1 1 d . . .
C13 C 0.3318(5) 0.9501(11) 0.4598(6) 0.075(3) Uani 1 1 d . . .
H13A H 0.2885 0.9342 0.4284 0.112 Uiso 1 1 calc R . .
H13B H 0.3433 1.0490 0.4553 0.112 Uiso 1 1 calc R . .
H13C H 0.3382 0.9344 0.5058 0.112 Uiso 1 1 calc R . .
C14 C 0.4646(5) 0.0638(12) 0.2695(6) 0.073(3) Uani 1 1 d . . .
H14 H 0.4821 -0.0008 0.2468 0.087 Uiso 1 1 calc R . .
C15 C 0.4084(6) 0.1320(14) 0.2152(7) 0.099(4) Uani 1 1 d . . .
H15A H 0.4200 0.1896 0.1862 0.148 Uiso 1 1 calc R . .
H15B H 0.3890 0.1942 0.2354 0.148 Uiso 1 1 calc R . .
H15C H 0.3794 0.0569 0.1886 0.148 Uiso 1 1 calc R . .
C16 C 0.4479(7) -0.0329(13) 0.3147(7) 0.115(5) Uani 1 1 d . . .
H16A H 0.4852 -0.0788 0.3487 0.172 Uiso 1 1 calc R . .
H16B H 0.4188 -0.1071 0.2873 0.172 Uiso 1 1 calc R . .
H16C H 0.4291 0.0258 0.3367 0.172 Uiso 1 1 calc R . .
C17 C 0.2809(5) 0.7282(14) 0.3408(7) 0.093(4) Uani 1 1 d . . .
H17 H 0.2554 0.8031 0.3484 0.111 Uiso 1 1 calc R . .
C18 C 0.2745(6) 0.7512(19) 0.2696(6) 0.135(6) Uani 1 1 d . . .
H18A H 0.2888 0.8481 0.2663 0.203 Uiso 1 1 calc R . .
H18B H 0.2314 0.7406 0.2364 0.203 Uiso 1 1 calc R . .
H18C H 0.2994 0.6797 0.2609 0.203 Uiso 1 1 calc R . .
C19 C 0.2583(6) 0.5819(15) 0.3502(7) 0.108(4) Uani 1 1 d . . .
H19A H 0.2625 0.5748 0.3957 0.162 Uiso 1 1 calc R . .
H19B H 0.2827 0.5062 0.3433 0.162 Uiso 1 1 calc R . .
H19C H 0.2150 0.5704 0.3176 0.162 Uiso 1 1 calc R . .
C20 C -0.0652(4) 0.9645(11) 0.3649(5) 0.053(2) Uani 1 1 d . . .
C21 C -0.1217(4) 1.0206(12) 0.3577(5) 0.063(3) Uani 1 1 d . . .
H21 H -0.1596 0.9765 0.3286 0.076 Uiso 1 1 calc R . .
C22 C -0.1198(5) 1.1422(13) 0.3945(6) 0.071(3) Uani 1 1 d . . .
H22 H -0.1571 1.1834 0.3897 0.086 Uiso 1 1 calc R . .
C23 C -0.0638(4) 1.2053(11) 0.4386(5) 0.060(3) Uani 1 1 d . . .
H23 H -0.0625 1.2859 0.4652 0.071 Uiso 1 1 calc R . .
C24 C -0.0085(4) 1.1450(10) 0.4425(5) 0.050(2) Uani 1 1 d . . .
C25 C 0.0523(4) 1.2126(11) 0.4867(5) 0.056(2) Uani 1 1 d . . .
C26 C 0.0660(5) 1.3250(11) 0.5343(5) 0.059(3) Uani 1 1 d . . .
H26 H 0.0383 1.3740 0.5461 0.071 Uiso 1 1 calc R . .
C27 C 0.1297(5) 1.3479(12) 0.5600(6) 0.068(3) Uani 1 1 d . . .
C28 C 0.1710(6) 1.4537(12) 0.6130(6) 0.092(4) Uani 1 1 d . . .
H28A H 0.2134 1.4421 0.6202 0.138 Uiso 1 1 calc R . .
H28B H 0.1692 1.4352 0.6550 0.138 Uiso 1 1 calc R . .
H28C H 0.1571 1.5521 0.5980 0.138 Uiso 1 1 calc R . .
C29 C -0.0641(4) 0.8342(11) 0.3266(5) 0.053(2) Uani 1 1 d . . .
C30 C -0.1147(5) 0.7558(13) 0.2775(5) 0.073(3) Uani 1 1 d . . .
H30 H -0.1570 0.7778 0.2613 0.088 Uiso 1 1 calc R . .
C31 C -0.0909(5) 0.6437(13) 0.2582(6) 0.073(3) Uani 1 1 d . . .
C32 C -0.1236(6) 0.5226(15) 0.2066(7) 0.119(5) Uani 1 1 d . . .
H32A H -0.0929 0.4570 0.2053 0.178 Uiso 1 1 calc R . .
H32B H -0.1478 0.5650 0.1622 0.178 Uiso 1 1 calc R . .
H32C H -0.1509 0.4693 0.2198 0.178 Uiso 1 1 calc R . .
C33 C 0.2140(5) 1.2412(19) 0.5349(10) 0.127(6) Uani 1 1 d . . .
H33 H 0.2382 1.3247 0.5625 0.152 Uiso 1 1 calc R . .
C34 C 0.2120(6) 1.253(2) 0.4658(10) 0.157(7) Uani 1 1 d . . .
H34A H 0.1942 1.3453 0.4454 0.236 Uiso 1 1 calc R . .
H34B H 0.1869 1.1744 0.4371 0.236 Uiso 1 1 calc R . .
H34C H 0.2538 1.2453 0.4707 0.236 Uiso 1 1 calc R . .
C35 C 0.2440(6) 1.1028(19) 0.5731(8) 0.138(6) Uani 1 1 d . . .
H35A H 0.2438 1.1034 0.6167 0.208 Uiso 1 1 calc R . .
H35B H 0.2864 1.0973 0.5799 0.208 Uiso 1 1 calc R . .
H35C H 0.2209 1.0193 0.5471 0.208 Uiso 1 1 calc R . .
C36 C 0.0199(5) 0.5494(11) 0.2961(6) 0.069(3) Uani 1 1 d . . .
H36 H -0.0006 0.4856 0.2559 0.083 Uiso 1 1 calc R . .
C37 C 0.0722(5) 0.6248(13) 0.2897(7) 0.097(4) Uani 1 1 d . . .
H37A H 0.0555 0.6820 0.2484 0.146 Uiso 1 1 calc R . .
H37B H 0.1008 0.5528 0.2882 0.146 Uiso 1 1 calc R . .
H37C H 0.0940 0.6882 0.3283 0.146 Uiso 1 1 calc R . .
C38 C 0.0399(7) 0.4520(15) 0.3578(7) 0.125(6) Uani 1 1 d . . .
H38A H 0.0036 0.4071 0.3576 0.187 Uiso 1 1 calc R . .
H38B H 0.0613 0.5096 0.3986 0.187 Uiso 1 1 calc R . .
H38C H 0.0675 0.3770 0.3566 0.187 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ag1 O1 146.4(3) . . ?
N1 Ag1 N4 70.0(2) . . ?
O1 Ag1 N4 122.7(3) . . ?
N1 Ag1 N2 68.7(2) . . ?
O1 Ag1 N2 99.7(3) . . ?
N4 Ag1 N2 136.4(2) . . ?
N1 Ag1 O2 164.6(3) . . ?
O1 Ag1 O2 48.5(3) . . ?
N4 Ag1 O2 106.0(3) . . ?
N2 Ag1 O2 110.1(3) . . ?
N7 Ag2 O5 144.4(3) . . ?
N7 Ag2 O4 165.5(3) . . ?
O5 Ag2 O4 50.1(3) . . ?
N7 Ag2 N10 70.0(3) . . ?
O5 Ag2 N10 102.8(3) . . ?
O4 Ag2 N10 110.2(3) . . ?
N7 Ag2 N8 68.9(3) . . ?
O5 Ag2 N8 117.7(3) . . ?
O4 Ag2 N8 106.4(3) . . ?
N10 Ag2 N8 137.1(3) . . ?
C5 N1 C1 119.7(7) . . ?
C5 N1 Ag1 121.4(5) . . ?
C1 N1 Ag1 118.3(5) . . ?
C6 N2 N3 103.7(7) . . ?
C6 N2 Ag1 110.9(6) . . ?
N3 N2 Ag1 145.4(6) . . ?
C8 N3 N2 112.3(8) . . ?
C8 N3 C14 128.7(9) . . ?
N2 N3 C14 118.4(8) . . ?
C10 N4 N5 105.4(7) . . ?
C10 N4 Ag1 108.2(6) . . ?
N5 N4 Ag1 140.4(6) . . ?
C12 N5 N4 111.1(7) . . ?
C12 N5 C17 130.4(8) . . ?
N4 N5 C17 118.4(8) . . ?
O1 N6 O2 119.6(12) . . ?
O1 N6 O3 119.4(13) . . ?
O2 N6 O3 121.0(12) . . ?
C20 N7 C24 120.2(8) . . ?
C20 N7 Ag2 120.6(6) . . ?
C24 N7 Ag2 118.5(6) . . ?
C25 N8 N9 103.8(8) . . ?
C25 N8 Ag2 110.0(7) . . ?
N9 N8 Ag2 141.4(6) . . ?
C27 N9 N8 112.8(8) . . ?
C27 N9 C33 126.2(10) . . ?
N8 N9 C33 120.8(10) . . ?
C29 N10 N11 105.3(8) . . ?
C29 N10 Ag2 108.9(6) . . ?
N11 N10 Ag2 145.9(6) . . ?
N10 N11 C31 111.3(8) . . ?
N10 N11 C36 119.0(8) . . ?
C31 N11 C36 129.3(9) . . ?
O4 N12 O5 117.0(9) . . ?
O4 N12 O6 122.3(10) . . ?
O5 N12 O6 120.6(10) . . ?
N6 O1 Ag1 104.9(8) . . ?
N6 O2 Ag1 86.9(7) . . ?
N12 O4 Ag2 95.0(6) . . ?
N12 O5 Ag2 97.4(7) . . ?
N1 C1 C2 120.8(8) . . ?
N1 C1 C10 116.5(7) . . ?
C2 C1 C10 122.7(9) . . ?
C3 C2 C1 118.9(9) . . ?
C3 C2 H2 120.5 . . ?
C1 C2 H2 120.5 . . ?
C4 C3 C2 119.8(9) . . ?
C4 C3 H3 120.1 . . ?
C2 C3 H3 120.1 . . ?
C3 C4 C5 120.9(9) . . ?
C3 C4 H4 119.5 . . ?
C5 C4 H4 119.5 . . ?
N1 C5 C4 119.7(8) . . ?
N1 C5 C6 117.2(7) . . ?
C4 C5 C6 123.1(8) . . ?
N2 C6 C7 111.5(9) . . ?
N2 C6 C5 121.0(8) . . ?
C7 C6 C5 127.5(9) . . ?
C8 C7 C6 106.5(9) . . ?
C8 C7 H7 126.7 . . ?
C6 C7 H7 126.7 . . ?
N3 C8 C7 106.0(9) . . ?
N3 C8 C9 123.7(11) . . ?
C7 C8 C9 130.3(12) . . ?
C8 C9 H9A 109.5 . . ?
C8 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
C8 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
N4 C10 C11 109.5(8) . . ?
N4 C10 C1 122.1(8) . . ?
C11 C10 C1 128.4(9) . . ?
C12 C11 C10 106.3(8) . . ?
C12 C11 H11 126.9 . . ?
C10 C11 H11 126.9 . . ?
N5 C12 C11 107.8(8) . . ?
N5 C12 C13 121.9(9) . . ?
C11 C12 C13 130.3(10) . . ?
C12 C13 H13A 109.5 . . ?
C12 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
C12 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
N3 C14 C15 113.0(10) . . ?
N3 C14 C16 112.0(9) . . ?
C15 C14 C16 111.0(11) . . ?
N3 C14 H14 106.8 . . ?
C15 C14 H14 106.8 . . ?
C16 C14 H14 106.8 . . ?
C14 C15 H15A 109.5 . . ?
C14 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C14 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C14 C16 H16A 109.5 . . ?
C14 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C14 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C19 C17 N5 109.9(11) . . ?
C19 C17 C18 113.3(11) . . ?
N5 C17 C18 110.4(10) . . ?
C19 C17 H17 107.7 . . ?
N5 C17 H17 107.7 . . ?
C18 C17 H17 107.7 . . ?
C17 C18 H18A 109.5 . . ?
C17 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C17 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C17 C19 H19A 109.5 . . ?
C17 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
C17 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
N7 C20 C21 122.1(9) . . ?
N7 C20 C29 117.4(8) . . ?
C21 C20 C29 120.5(9) . . ?
C22 C21 C20 117.8(10) . . ?
C22 C21 H21 121.1 . . ?
C20 C21 H21 121.1 . . ?
C21 C22 C23 121.1(9) . . ?
C21 C22 H22 119.4 . . ?
C23 C22 H22 119.4 . . ?
C22 C23 C24 118.2(10) . . ?
C22 C23 H23 120.9 . . ?
C24 C23 H23 120.9 . . ?
N7 C24 C23 120.5(9) . . ?
N7 C24 C25 119.3(8) . . ?
C23 C24 C25 120.2(9) . . ?
N8 C25 C26 112.5(9) . . ?
N8 C25 C24 118.7(9) . . ?
C26 C25 C24 128.8(9) . . ?
C27 C26 C25 104.8(9) . . ?
C27 C26 H26 127.6 . . ?
C25 C26 H26 127.6 . . ?
N9 C27 C26 106.2(9) . . ?
N9 C27 C28 124.4(10) . . ?
C26 C27 C28 129.3(11) . . ?
C27 C28 H28A 109.5 . . ?
C27 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
C27 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
N10 C29 C30 109.0(9) . . ?
N10 C29 C20 122.5(9) . . ?
C30 C29 C20 128.5(9) . . ?
C31 C30 C29 107.0(9) . . ?
C31 C30 H30 126.5 . . ?
C29 C30 H30 126.5 . . ?
C30 C31 N11 107.4(10) . . ?
C30 C31 C32 130.2(11) . . ?
N11 C31 C32 122.4(10) . . ?
C31 C32 H32A 109.5 . . ?
C31 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
C31 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
N9 C33 C35 108.3(14) . . ?
N9 C33 C34 110.4(12) . . ?
C35 C33 C34 114.1(14) . . ?
N9 C33 H33 107.9 . . ?
C35 C33 H33 107.9 . . ?
C34 C33 H33 107.9 . . ?
C33 C34 H34A 109.5 . . ?
C33 C34 H34B 109.5 . . ?
H34A C34 H34B 109.5 . . ?
C33 C34 H34C 109.5 . . ?
H34A C34 H34C 109.5 . . ?
H34B C34 H34C 109.5 . . ?
C33 C35 H35A 109.5 . . ?
C33 C35 H35B 109.5 . . ?
H35A C35 H35B 109.5 . . ?
C33 C35 H35C 109.5 . . ?
H35A C35 H35C 109.5 . . ?
H35B C35 H35C 109.5 . . ?
N11 C36 C38 109.7(9) . . ?
N11 C36 C37 112.1(9) . . ?
C38 C36 C37 114.9(11) . . ?
N11 C36 H36 106.5 . . ?
C38 C36 H36 106.5 . . ?
C37 C36 H36 106.5 . . ?
C36 C37 H37A 109.5 . . ?
C36 C37 H37B 109.5 . . ?
H37A C37 H37B 109.5 . . ?
C36 C37 H37C 109.5 . . ?
H37A C37 H37C 109.5 . . ?
H37B C37 H37C 109.5 . . ?
C36 C38 H38A 109.5 . . ?
C36 C38 H38B 109.5 . . ?
H38A C38 H38B 109.5 . . ?
C36 C38 H38C 109.5 . . ?
H38A C38 H38C 109.5 . . ?
H38B C38 H38C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N1 2.299(7) . ?
Ag1 O1 2.333(8) . ?
Ag1 N4 2.515(8) . ?
Ag1 N2 2.592(7) . ?
Ag1 O2 2.678(11) . ?
Ag2 N7 2.304(7) . ?
Ag2 O5 2.454(8) . ?
Ag2 O4 2.499(8) . ?
Ag2 N10 2.563(8) . ?
Ag2 N8 2.561(9) . ?
N1 C5 1.356(10) . ?
N1 C1 1.356(11) . ?
N2 C6 1.326(10) . ?
N2 N3 1.354(10) . ?
N3 C8 1.349(12) . ?
N3 C14 1.456(12) . ?
N4 C10 1.328(11) . ?
N4 N5 1.377(9) . ?
N5 C12 1.331(11) . ?
N5 C17 1.479(12) . ?
N6 O1 1.193(11) . ?
N6 O2 1.216(13) . ?
N6 O3 1.239(12) . ?
N7 C20 1.327(11) . ?
N7 C24 1.338(11) . ?
N8 C25 1.319(11) . ?
N8 N9 1.363(11) . ?
N9 C27 1.340(12) . ?
N9 C33 1.485(14) . ?
N10 C29 1.347(10) . ?
N10 N11 1.346(10) . ?
N11 C31 1.348(12) . ?
N11 C36 1.467(12) . ?
N12 O4 1.232(10) . ?
N12 O5 1.228(10) . ?
N12 O6 1.230(10) . ?
C1 C2 1.392(11) . ?
C1 C10 1.446(11) . ?
C2 C3 1.367(12) . ?
C2 H2 0.9300 . ?
C3 C4 1.354(13) . ?
C3 H3 0.9300 . ?
C4 C5 1.380(12) . ?
C4 H4 0.9300 . ?
C5 C6 1.463(12) . ?
C6 C7 1.375(12) . ?
C7 C8 1.344(14) . ?
C7 H7 0.9300 . ?
C8 C9 1.508(14) . ?
C9 H9A 0.9600 . ?
C9 H9B 0.9600 . ?
C9 H9C 0.9600 . ?
C10 C11 1.413(12) . ?
C11 C12 1.347(12) . ?
C11 H11 0.9300 . ?
C12 C13 1.491(12) . ?
C13 H13A 0.9600 . ?
C13 H13B 0.9600 . ?
C13 H13C 0.9600 . ?
C14 C15 1.468(15) . ?
C14 C16 1.513(15) . ?
C14 H14 0.9800 . ?
C15 H15A 0.9600 . ?
C15 H15B 0.9600 . ?
C15 H15C 0.9600 . ?
C16 H16A 0.9600 . ?
C16 H16B 0.9600 . ?
C16 H16C 0.9600 . ?
C17 C19 1.488(16) . ?
C17 C18 1.518(17) . ?
C17 H17 0.9800 . ?
C18 H18A 0.9600 . ?
C18 H18B 0.9600 . ?
C18 H18C 0.9600 . ?
C19 H19A 0.9600 . ?
C19 H19B 0.9600 . ?
C19 H19C 0.9600 . ?
C20 C21 1.387(12) . ?
C20 C29 1.463(13) . ?
C21 C22 1.360(14) . ?
C21 H21 0.9300 . ?
C22 C23 1.372(13) . ?
C22 H22 0.9300 . ?
C23 C24 1.400(12) . ?
C23 H23 0.9300 . ?
C24 C25 1.467(12) . ?
C25 C26 1.391(13) . ?
C26 C27 1.381(13) . ?
C26 H26 0.9300 . ?
C27 C28 1.487(14) . ?
C28 H28A 0.9600 . ?
C28 H28B 0.9600 . ?
C28 H28C 0.9600 . ?
C29 C30 1.396(13) . ?
C30 C31 1.329(14) . ?
C30 H30 0.9300 . ?
C31 C32 1.517(15) . ?
C32 H32A 0.9600 . ?
C32 H32B 0.9600 . ?
C32 H32C 0.9600 . ?
C33 C35 1.50(2) . ?
C33 C34 1.502(19) . ?
C33 H33 0.9800 . ?
C34 H34A 0.9600 . ?
C34 H34B 0.9600 . ?
C34 H34C 0.9600 . ?
C35 H35A 0.9600 . ?
C35 H35B 0.9600 . ?
C35 H35C 0.9600 . ?
C36 C38 1.504(15) . ?
C36 C37 1.492(14) . ?
C36 H36 0.9800 . ?
C37 H37A 0.9600 . ?
C37 H37B 0.9600 . ?
C37 H37C 0.9600 . ?
C38 H38A 0.9600 . ?
C38 H38B 0.9600 . ?
C38 H38C 0.9600 . ?
