#------------------------------------------------------------------------------
#$Date: 2016-03-25 09:11:39 +0100 (vie 25 de mar de 2016) $
#$Revision: 179743 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/39/7003959.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7003959
loop_
_publ_author_name
'Xu, Hai-Bing'
'Zhang, Li-Yi'
'Chen, Zhong-Hui'
'Shi, Lin-Xi'
'Chen, Zhong-Ning'
_publ_section_title
;
 Sensitization of lanthanide luminescence by two different Pt
 → Ln energy transfer pathways in PtLn3 heterotetranuclear
 complexes with 5-ethynyl-2,2′-bipyridine
;
_journal_issue                   34
_journal_name_full               'Dalton Transactions'
_journal_page_first              4664
_journal_paper_doi               10.1039/b801573b
_journal_year                    2008
_chemical_formula_sum            'C66 H34 Cl4 F36 N6 O13 Pt Yb2'
_chemical_formula_weight         2485.96
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                93.737(3)
_cell_angle_beta                 102.395(5)
_cell_angle_gamma                108.026(5)
_cell_formula_units_Z            2
_cell_length_a                   13.4096(17)
_cell_length_b                   18.491(2)
_cell_length_c                   19.671(2)
_cell_measurement_reflns_used    6150
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.4835
_cell_measurement_theta_min      2.5206
_cell_volume                     4484.3(9)
_computing_cell_refinement       'Bruker XSCANS'
_computing_data_collection       'Bruker XSCANS'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.988
_diffrn_measured_fraction_theta_max 0.988
_diffrn_measurement_device_type  'RIGAKU MERCURY CCD/AFC'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Rotating Anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0402
_diffrn_reflns_av_sigmaI/netI    0.0566
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            27930
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.52
_exptl_absorpt_coefficient_mu    3.875
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.4520
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            Colorless
_exptl_crystal_density_diffrn    1.841
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Prism
_exptl_crystal_F_000             2372
_exptl_crystal_size_max          0.70
_exptl_crystal_size_mid          0.60
_exptl_crystal_size_min          0.40
_refine_diff_density_max         3.490
_refine_diff_density_min         -2.128
_refine_diff_density_rms         0.187
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.044
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1090
_refine_ls_number_reflns         15580
_refine_ls_number_restraints     523
_refine_ls_restrained_S_all      1.042
_refine_ls_R_factor_all          0.1038
_refine_ls_R_factor_gt           0.0812
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1717P)²+0.3542P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2259
_refine_ls_wR_factor_ref         0.2546
_reflns_number_gt                11141
_reflns_number_total             15580
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b801573b.txt
_cod_data_source_block           compound_4
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'Multi-scan' changed
to 'multi-scan' according to
'/home/saulius/struct/CIF-dictionaries/cif_core.dic' dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_cell_volume        4484.4(9)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7003959
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Yb1 Yb 1.18757(5) -0.24407(3) -0.37792(3) 0.0784(2) Uani 1 1 d . A .
Yb2 Yb 0.40849(4) -0.35813(3) 0.13442(3) 0.0736(2) Uani 1 1 d . D .
Pt Pt 0.93366(3) -0.15001(2) -0.02846(2) 0.06453(18) Uani 1 1 d . . .
F1 F 1.4448(18) -0.1056(11) -0.1692(12) 0.148(7) Uiso 0.50 1 d PDU A 1
F2 F 1.4586(17) -0.1979(13) -0.1100(12) 0.153(8) Uiso 0.50 1 d PDU A 1
F3 F 1.3217(17) -0.1574(15) -0.1143(13) 0.166(9) Uiso 0.50 1 d PDU A 1
F1' F 1.4134(17) -0.2019(11) -0.0924(9) 0.125(6) Uiso 0.50 1 d PDU A 2
F2' F 1.341(2) -0.1199(14) -0.1372(13) 0.167(9) Uiso 0.50 1 d PDU A 2
F3' F 1.4804(17) -0.1343(16) -0.1682(15) 0.185(10) Uiso 0.50 1 d PDU A 2
F4 F 1.1151(10) -0.4934(11) -0.2842(9) 0.117(5) Uiso 0.50 1 d PDU A 1
F5 F 1.2291(15) -0.4531(13) -0.1873(6) 0.127(5) Uiso 0.50 1 d PDU A 1
F6 F 1.2837(14) -0.4714(13) -0.2780(10) 0.150(5) Uiso 0.50 1 d PDU A 1
F4' F 1.2671(15) -0.4628(13) -0.1995(8) 0.137(5) Uiso 0.50 1 d PDU A 2
F5' F 1.2354(16) -0.4830(12) -0.3095(8) 0.138(5) Uiso 0.50 1 d PDU A 2
F6' F 1.1080(9) -0.4785(12) -0.2646(10) 0.115(5) Uiso 0.50 1 d PDU A 2
F7 F 1.196(2) -0.0006(15) -0.2890(9) 0.163(8) Uiso 0.50 1 d PDU B 1
F8 F 1.0490(14) -0.0121(18) -0.3660(15) 0.195(10) Uiso 0.50 1 d PDU B 1
F9 F 1.205(2) 0.0535(12) -0.3811(13) 0.167(8) Uiso 0.50 1 d PDU B 1
F7' F 1.128(2) 0.0393(15) -0.4009(12) 0.179(9) Uiso 0.50 1 d PDU B 2
F8' F 1.2434(17) 0.0247(17) -0.3107(13) 0.189(9) Uiso 0.50 1 d PDU B 2
F9' F 1.0714(19) -0.0298(18) -0.3250(16) 0.201(10) Uiso 0.50 1 d PDU B 2
F10 F 1.202(2) -0.1902(13) -0.6108(12) 0.153(8) Uiso 0.50 1 d PD A 1
F11 F 1.1896(19) -0.0791(9) -0.6034(11) 0.138(7) Uiso 0.50 1 d PD A 1
F12 F 1.0478(14) -0.1783(15) -0.6255(13) 0.177(10) Uiso 0.50 1 d PD A 1
F10' F 1.107(2) -0.0989(14) -0.6158(15) 0.193(11) Uiso 0.50 1 d PD A 2
F11' F 1.0976(19) -0.2163(11) -0.6265(12) 0.153(8) Uiso 0.50 1 d PD A 2
F12' F 1.2506(14) -0.1279(15) -0.5929(13) 0.160(8) Uiso 0.50 1 d PD A 2
F13 F 1.453(2) -0.0095(14) -0.4052(14) 0.173(9) Uiso 0.50 1 d PDU C 1
F14 F 1.558(2) -0.0590(16) -0.4451(12) 0.175(9) Uiso 0.50 1 d PDU C 1
F15 F 1.563(2) -0.0503(17) -0.3349(10) 0.181(9) Uiso 0.50 1 d PDU C 1
F13' F 1.5941(15) -0.0623(16) -0.4062(14) 0.168(8) Uiso 0.50 1 d PDU C 2
F14' F 1.511(2) -0.0261(16) -0.3358(10) 0.175(9) Uiso 0.50 1 d PDU C 2
F15' F 1.4550(19) -0.0275(15) -0.4461(12) 0.162(8) Uiso 0.50 1 d PDU C 2
F16 F 1.3012(14) -0.3883(13) -0.5429(10) 0.141(7) Uiso 0.50 1 d PDU A 1
F17 F 1.4110(18) -0.3899(13) -0.4459(10) 0.146(8) Uiso 0.50 1 d PDU A 1
F18 F 1.4662(14) -0.3210(13) -0.5247(11) 0.142(8) Uiso 0.50 1 d PDU A 1
F16' F 1.4907(11) -0.3236(13) -0.4955(13) 0.139(7) Uiso 0.50 1 d PDU A 2
F17' F 1.3260(18) -0.3572(16) -0.5575(9) 0.178(10) Uiso 0.50 1 d PDU A 2
F18' F 1.3650(17) -0.4133(10) -0.4694(11) 0.132(6) Uiso 0.50 1 d PDU A 2
F19 F 0.7985(16) -0.2703(12) 0.1864(8) 0.130(6) Uiso 0.50 1 d PD D 1
F20 F 0.838(2) -0.3198(15) 0.2787(12) 0.169(9) Uiso 0.50 1 d PD D 1
F21 F 0.781(2) -0.2239(12) 0.2828(12) 0.173(9) Uiso 0.50 1 d PD D 1
F19' F 0.8224(19) -0.2846(15) 0.3100(8) 0.164(9) Uiso 0.50 1 d PD D 2
F20' F 0.779(2) -0.2190(10) 0.2306(13) 0.163(9) Uiso 0.50 1 d PD D 2
F21' F 0.8151(19) -0.3205(13) 0.2036(11) 0.152(8) Uiso 0.50 1 d PD D 2
F22 F 0.3752(14) -0.5022(17) 0.3200(14) 0.171(8) Uiso 0.50 1 d PDU D 1
F23 F 0.5401(18) -0.4635(15) 0.3813(10) 0.168(8) Uiso 0.50 1 d PDU D 1
F24 F 0.488(2) -0.5550(12) 0.2939(14) 0.178(9) Uiso 0.50 1 d PDU D 1
F22' F 0.5620(13) -0.4954(13) 0.3610(11) 0.141(7) Uiso 0.50 1 d PDU D 2
F23' F 0.4157(19) -0.5597(11) 0.2831(13) 0.174(8) Uiso 0.50 1 d PDU D 2
F24' F 0.4183(18) -0.4624(15) 0.3512(13) 0.161(8) Uiso 0.50 1 d PDU D 2
F25 F 0.1017(19) -0.4810(12) 0.2273(12) 0.140(7) Uiso 0.50 1 d PD E 1
F26 F -0.0219(16) -0.4574(17) 0.1478(14) 0.192(12) Uiso 0.50 1 d PD E 1
F27 F 0.084(3) -0.3680(14) 0.2324(16) 0.225(16) Uiso 0.50 1 d PD E 1
F25' F -0.0128(17) -0.4168(17) 0.1651(15) 0.184(12) Uiso 0.50 1 d PD E 2
F26' F 0.123(3) -0.3947(17) 0.2565(11) 0.213(15) Uiso 0.50 1 d PD E 2
F27' F 0.0677(17) -0.5032(9) 0.1880(12) 0.128(6) Uiso 0.50 1 d PD E 2
F28 F 0.195(2) -0.345(2) -0.0912(16) 0.217(11) Uiso 0.50 1 d PDU D 1
F29 F 0.117(3) -0.2819(15) -0.0355(19) 0.228(11) Uiso 0.50 1 d PDU D 1
F30 F 0.0364(19) -0.4008(17) -0.0770(19) 0.235(12) Uiso 0.50 1 d PDU D 1
F28' F 0.0275(17) -0.364(2) -0.057(2) 0.240(12) Uiso 0.50 1 d PDU D 2
F29' F 0.153(3) -0.3991(17) -0.0885(16) 0.213(11) Uiso 0.50 1 d PDU D 2
F30' F 0.174(2) -0.2794(14) -0.0659(18) 0.203(10) Uiso 0.50 1 d PDU D 2
F31 F 0.496(3) -0.1292(12) 0.3530(18) 0.215(11) Uiso 0.50 1 d PDU F 1
F32 F 0.5726(19) -0.2129(18) 0.3849(15) 0.181(9) Uiso 0.50 1 d PDU F 1
F33 F 0.3989(19) -0.2435(19) 0.3610(19) 0.222(11) Uiso 0.50 1 d PDU F 1
F31' F 0.514(3) -0.2559(16) 0.3790(17) 0.206(10) Uiso 0.50 1 d PDU F 2
F32' F 0.408(2) -0.188(2) 0.3675(18) 0.216(11) Uiso 0.50 1 d PDU F 2
F33' F 0.574(2) -0.1379(14) 0.3660(16) 0.196(10) Uiso 0.50 1 d PDU F 2
F34 F 0.5838(19) -0.1190(13) 0.0649(11) 0.136(7) Uiso 0.50 1 d PD D 1
F35 F 0.614(2) -0.0466(15) 0.1624(12) 0.193(12) Uiso 0.50 1 d PD D 1
F36 F 0.4581(19) -0.0789(19) 0.0887(16) 0.205(13) Uiso 0.50 1 d PD D 1
F34' F 0.550(3) -0.0441(16) 0.1600(15) 0.228(16) Uiso 0.50 1 d PD D 2
F35' F 0.472(2) -0.105(2) 0.0554(13) 0.198(13) Uiso 0.50 1 d PD D 2
F36' F 0.6328(15) -0.1052(13) 0.1063(13) 0.138(7) Uiso 0.50 1 d PD D 2
N1 N 0.9453(9) -0.0896(6) 0.0651(5) 0.081(3) Uani 1 1 d . . .
N2 N 1.0922(8) -0.0793(5) -0.0039(5) 0.078(3) Uani 1 1 d . . .
N3 N 1.0259(8) -0.2825(5) -0.3309(4) 0.073(2) Uani 1 1 d . . .
N4 N 1.0361(9) -0.3496(6) -0.4509(5) 0.082(3) Uani 1 1 d . . .
N5 N 0.4750(7) -0.3704(5) 0.0292(5) 0.066(2) Uani 1 1 d . . .
N6 N 0.3244(7) -0.4838(5) 0.0601(5) 0.071(2) Uani 1 1 d . . .
C1 C 0.8619(14) -0.1010(11) 0.0953(8) 0.115(5) Uani 1 1 d . . .
H1A H 0.7955 -0.1388 0.0750 0.137 Uiso 1 1 calc R . .
C2 C 0.878(2) -0.0548(14) 0.1575(12) 0.167(10) Uani 1 1 d . . .
H2A H 0.8215 -0.0619 0.1794 0.200 Uiso 1 1 calc R . .
C3 C 0.972(2) -0.0007(13) 0.1868(10) 0.155(9) Uani 1 1 d . . .
H3A H 0.9806 0.0301 0.2283 0.186 Uiso 1 1 calc R . .
C4 C 1.0580(17) 0.0098(10) 0.1553(9) 0.124(6) Uani 1 1 d . . .
H4A H 1.1252 0.0464 0.1760 0.148 Uiso 1 1 calc R . .
C5 C 1.0416(12) -0.0337(7) 0.0951(7) 0.086(4) Uani 1 1 d . . .
C6 C 1.1248(12) -0.0283(7) 0.0561(7) 0.089(4) Uani 1 1 d . . .
C7 C 1.2237(13) 0.0221(8) 0.0778(9) 0.109(5) Uani 1 1 d . . .
H7A H 1.2421 0.0555 0.1194 0.131 Uiso 1 1 calc R . .
C8 C 1.2977(14) 0.0258(11) 0.0411(12) 0.141(7) Uani 1 1 d . . .
H8A H 1.3659 0.0629 0.0557 0.169 Uiso 1 1 calc R . .
C9 C 1.2697(15) -0.0299(11) -0.0231(12) 0.145(8) Uani 1 1 d . . .
H9A H 1.3206 -0.0315 -0.0483 0.174 Uiso 1 1 calc R . .
C10 C 1.1621(11) -0.0806(8) -0.0444(9) 0.101(4) Uani 1 1 d . . .
H10A H 1.1391 -0.1147 -0.0859 0.121 Uiso 1 1 calc R . .
C11 C 0.9371(9) -0.2025(6) -0.1154(5) 0.064(2) Uani 1 1 d . . .
C12 C 0.9461(10) -0.2331(7) -0.1677(7) 0.075(3) Uani 1 1 d . . .
C13 C 0.9425(9) -0.2758(6) -0.2331(6) 0.069(3) Uani 1 1 d . . .
C14 C 0.8680(11) -0.3436(8) -0.2606(7) 0.091(4) Uani 1 1 d . . .
H14A H 0.8153 -0.3663 -0.2374 0.109 Uiso 1 1 calc R . .
C15 C 0.8689(14) -0.3805(8) -0.3244(8) 0.110(5) Uani 1 1 d . . .
H15A H 0.8154 -0.4273 -0.3441 0.132 Uiso 1 1 calc R . .
C16 C 0.9466(10) -0.3493(7) -0.3581(6) 0.076(3) Uani 1 1 d . . .
C17 C 1.0227(10) -0.2466(7) -0.2687(6) 0.074(3) Uani 1 1 d . . .
H17A H 1.0768 -0.2001 -0.2491 0.089 Uiso 1 1 calc R . .
C18 C 0.9512(13) -0.3807(8) -0.4262(6) 0.093(4) Uani 1 1 d . . .
C19 C 0.8647(16) -0.4435(11) -0.4654(9) 0.138(7) Uani 1 1 d . . .
H19A H 0.8048 -0.4664 -0.4482 0.165 Uiso 1 1 calc R . .
C20 C 0.872(2) -0.4712(12) -0.5327(10) 0.163(9) Uani 1 1 d . . .
H20A H 0.8180 -0.5148 -0.5587 0.196 Uiso 1 1 calc R . .
C21 C 0.9582(18) -0.4351(12) -0.5606(8) 0.141(8) Uani 1 1 d . . .
H21A H 0.9611 -0.4490 -0.6063 0.170 Uiso 1 1 calc R . .
C22 C 1.0390(13) -0.3769(9) -0.5141(7) 0.108(5) Uani 1 1 d . . .
H22A H 1.1018 -0.3544 -0.5285 0.130 Uiso 1 1 calc R . .
C31 C 0.7868(10) -0.2138(6) -0.0413(6) 0.069(3) Uani 1 1 d . . .
C32 C 0.6930(9) -0.2577(6) -0.0454(6) 0.069(3) Uani 1 1 d . . .
C33 C 0.5978(9) -0.3155(7) -0.0414(6) 0.067(3) Uani 1 1 d . . .
C34 C 0.5438(10) -0.3805(7) -0.0926(6) 0.076(3) Uani 1 1 d . . .
H34A H 0.5668 -0.3847 -0.1336 0.092 Uiso 1 1 calc R . .
C35 C 0.4570(9) -0.4380(7) -0.0821(7) 0.074(3) Uani 1 1 d . . .
H35A H 0.4191 -0.4802 -0.1166 0.088 Uiso 1 1 calc R . .
C36 C 0.4269(8) -0.4323(6) -0.0196(6) 0.066(3) Uani 1 1 d . . .
C37 C 0.5588(8) -0.3143(6) 0.0186(6) 0.064(2) Uani 1 1 d . . .
H37A H 0.5930 -0.2720 0.0534 0.076 Uiso 1 1 calc R . .
C38 C 0.3378(8) -0.4934(6) -0.0051(7) 0.067(3) Uani 1 1 d . . .
C39 C 0.2738(10) -0.5575(8) -0.0497(9) 0.097(4) Uani 1 1 d . . .
H39A H 0.2812 -0.5625 -0.0956 0.116 Uiso 1 1 calc R . .
C40 C 0.1992(11) -0.6147(8) -0.0299(11) 0.101(5) Uani 1 1 d . . .
H40A H 0.1574 -0.6589 -0.0613 0.122 Uiso 1 1 calc R . .
C41 C 0.1869(10) -0.6066(7) 0.0349(12) 0.104(5) Uani 1 1 d . . .
H41A H 0.1370 -0.6455 0.0497 0.125 Uiso 1 1 calc R . .
C42 C 0.2478(9) -0.5410(7) 0.0796(8) 0.086(4) Uani 1 1 d . . .
H42A H 0.2370 -0.5349 0.1245 0.103 Uiso 1 1 calc R . .
C111 C 1.3904(11) -0.1695(8) -0.1490(6) 0.172(10) Uani 1 1 d D . .
C112 C 1.3140(11) -0.2269(7) -0.2127(7) 0.098(4) Uani 1 1 d D A .
O1 O 1.2739(8) -0.2006(5) -0.2643(5) 0.094(3) Uani 1 1 d D . .
C113 C 1.3019(12) -0.3050(7) -0.2090(7) 0.102(4) Uani 1 1 d D . .
H11A H 1.3392 -0.3187 -0.1691 0.122 Uiso 1 1 calc R A .
C114 C 1.2356(9) -0.3614(6) -0.2636(6) 0.082(3) Uani 1 1 d D A .
O2 O 1.1912(7) -0.3520(5) -0.3237(4) 0.082(2) Uani 1 1 d D . .
C115 C 1.2136(9) -0.4464(6) -0.2561(5) 0.116(5) Uani 1 1 d D . .
C121 C 1.1506(13) -0.0073(8) -0.3566(8) 0.143(8) Uani 1 1 d D . .
C122 C 1.1500(15) -0.0810(7) -0.3977(7) 0.110(5) Uani 1 1 d D A .
O3 O 1.1478(8) -0.1339(5) -0.3641(5) 0.099(3) Uani 1 1 d D . .
C123 C 1.1559(17) -0.0815(8) -0.4686(7) 0.122(6) Uani 1 1 d D . .
H12A H 1.1622 -0.0370 -0.4892 0.147 Uiso 1 1 calc R A .
C124 C 1.1526(14) -0.1467(8) -0.5072(6) 0.111(5) Uani 1 1 d D A .
O4 O 1.1554(9) -0.2080(5) -0.4871(5) 0.098(3) Uani 1 1 d D . .
C125 C 1.1493(13) -0.1491(8) -0.5877(8) 0.187(12) Uani 1 1 d D . .
C131 C 1.4991(11) -0.0625(9) -0.3984(9) 0.192(13) Uani 1 1 d D . .
C132 C 1.4211(11) -0.1444(8) -0.4047(9) 0.103(4) Uani 1 1 d D A .
O5 O 1.3446(9) -0.1492(6) -0.3779(6) 0.111(3) Uani 1 1 d D . .
C133 C 1.4366(12) -0.2053(8) -0.4423(10) 0.131(6) Uani 1 1 d D . .
H13A H 1.4963 -0.1954 -0.4615 0.157 Uiso 1 1 calc R A .
C134 C 1.3655(12) -0.2800(7) -0.4518(8) 0.107(5) Uani 1 1 d D A .
O6 O 1.2816(7) -0.3020(5) -0.4317(5) 0.097(3) Uani 1 1 d D . .
C135 C 1.3872(9) -0.3467(7) -0.4935(7) 0.140(8) Uani 1 1 d D . .
C141 C 0.7684(11) -0.2892(9) 0.2443(7) 0.140(7) Uani 1 1 d D . .
C142 C 0.6494(10) -0.3396(8) 0.2279(8) 0.102(4) Uani 1 1 d D D .
O7 O 0.5910(7) -0.3306(5) 0.1735(5) 0.088(2) Uani 1 1 d D . .
C143 C 0.6125(12) -0.3864(9) 0.2774(8) 0.115(5) Uani 1 1 d D . .
H14B H 0.6602 -0.3843 0.3201 0.138 Uiso 1 1 calc R D .
C144 C 0.5062(11) -0.4356(7) 0.2634(7) 0.094(4) Uani 1 1 d D D .
O8 O 0.4331(7) -0.4430(5) 0.2108(5) 0.095(3) Uani 1 1 d D . .
C145 C 0.4759(12) -0.4911(9) 0.3178(7) 0.143(7) Uani 1 1 d D . .
C151 C 0.0777(10) -0.4288(8) 0.1905(9) 0.172(11) Uani 1 1 d D . .
C152 C 0.1568(14) -0.4053(12) 0.1416(9) 0.172(12) Uani 1 1 d D D .
O9 O 0.2535(8) -0.3929(6) 0.1695(7) 0.112(4) Uani 1 1 d D . .
C153 C 0.1139(12) -0.3936(14) 0.0720(10) 0.180(9) Uani 1 1 d DU . .
H15B H 0.0394 -0.4061 0.0557 0.216 Uiso 1 1 calc R D .
C154 C 0.1795(11) -0.3642(11) 0.0277(9) 0.131(6) Uani 1 1 d DU D .
O10 O 0.2789(6) -0.3443(5) 0.0448(5) 0.088(2) Uani 1 1 d D . .
C155 C 0.1324(15) -0.3484(12) -0.0480(9) 0.195(11) Uiso 1 1 d D . .
C161 C 0.4885(15) -0.2015(10) 0.3461(8) 0.162(9) Uani 1 1 d D . .
C162 C 0.4738(16) -0.2215(11) 0.2670(7) 0.145(9) Uani 1 1 d D D .
O11 O 0.4419(10) -0.2882(7) 0.2422(6) 0.121(4) Uani 1 1 d D . .
C163 C 0.5085(18) -0.1607(10) 0.2278(8) 0.142(7) Uani 1 1 d D . .
H16A H 0.5389 -0.1107 0.2513 0.170 Uiso 1 1 calc R D .
C164 C 0.4988(14) -0.1727(8) 0.1570(9) 0.137(7) Uani 1 1 d D D .
O12 O 0.4666(7) -0.2348(5) 0.1170(5) 0.090(2) Uani 1 1 d D . .
C165 C 0.5391(13) -0.1032(8) 0.1156(8) 0.158(9) Uani 1 1 d D . .
O01 O 0.843(3) -0.234(2) -0.507(2) 0.343(16) Uiso 1 1 d . . .
C01 C 0.175(3) -0.1958(13) 0.2177(19) 0.201(17) Uiso 0.671(15) 1 d PD G 1
Cl1 Cl 0.2459(15) -0.0966(11) 0.2284(10) 0.284(10) Uiso 0.671(15) 1 d PD G 1
Cl2 Cl 0.0560(17) -0.2208(13) 0.1487(13) 0.323(11) Uiso 0.671(15) 1 d PD G 1
C01' C 0.102(2) -0.207(2) 0.1263(14) 0.091(12) Uiso 0.329(15) 1 d PD G 2
Cl1' Cl 0.2444(19) -0.1680(17) 0.1434(14) 0.211(12) Uiso 0.329(15) 1 d PD G 2
Cl2' Cl 0.060(2) -0.1867(17) 0.2023(14) 0.203(11) Uiso 0.329(15) 1 d PD G 2
C02 C 0.358(3) -0.820(2) 0.228(2) 0.32(2) Uiso 1 1 d D . .
Cl4 Cl 0.2709(19) -0.8283(14) 0.2855(14) 0.479(13) Uiso 1 1 d D . .
Cl3 Cl 0.460(2) -0.7293(17) 0.2487(17) 0.565(17) Uiso 1 1 d D . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Yb Yb -0.3850 5.5486 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Yb1 O6 111.0(4) . . ?
O1 Yb1 O3 79.8(4) . . ?
O6 Yb1 O3 143.8(3) . . ?
O1 Yb1 O4 143.7(3) . . ?
O6 Yb1 O4 79.0(4) . . ?
O3 Yb1 O4 73.9(3) . . ?
O1 Yb1 O5 73.9(4) . . ?
O6 Yb1 O5 74.4(3) . . ?
O3 Yb1 O5 76.0(4) . . ?
O4 Yb1 O5 75.8(4) . . ?
O1 Yb1 O2 73.6(3) . . ?
O6 Yb1 O2 73.2(3) . . ?
O3 Yb1 O2 141.5(3) . . ?
O4 Yb1 O2 140.8(3) . . ?
O5 Yb1 O2 120.8(4) . . ?
O1 Yb1 N4 140.6(3) . . ?
O6 Yb1 N4 81.3(3) . . ?
O3 Yb1 N4 112.8(4) . . ?
O4 Yb1 N4 74.0(4) . . ?
O5 Yb1 N4 144.2(4) . . ?
O2 Yb1 N4 75.0(3) . . ?
O1 Yb1 N3 83.3(3) . . ?
O6 Yb1 N3 137.7(3) . . ?
O3 Yb1 N3 76.2(3) . . ?
O4 Yb1 N3 113.4(4) . . ?
O5 Yb1 N3 146.6(3) . . ?
O2 Yb1 N3 73.5(3) . . ?
N4 Yb1 N3 65.4(3) . . ?
O12 Yb2 O9 114.4(4) . . ?
O12 Yb2 O10 73.8(3) . . ?
O9 Yb2 O10 73.7(3) . . ?
O12 Yb2 O7 79.9(3) . . ?
O9 Yb2 O7 142.7(4) . . ?
O10 Yb2 O7 142.6(3) . . ?
O12 Yb2 O11 74.9(4) . . ?
O9 Yb2 O11 72.7(5) . . ?
O10 Yb2 O11 118.0(4) . . ?
O7 Yb2 O11 78.8(4) . . ?
O12 Yb2 O8 144.3(3) . . ?
O9 Yb2 O8 76.8(3) . . ?
O10 Yb2 O8 140.1(3) . . ?
O7 Yb2 O8 73.5(3) . . ?
O11 Yb2 O8 76.9(4) . . ?
O12 Yb2 N5 79.3(3) . . ?
O9 Yb2 N5 140.3(4) . . ?
O10 Yb2 N5 75.3(3) . . ?
O7 Yb2 N5 74.1(3) . . ?
O11 Yb2 N5 145.3(4) . . ?
O8 Yb2 N5 114.6(3) . . ?
O12 Yb2 N6 136.4(3) . . ?
O9 Yb2 N6 83.0(4) . . ?
O10 Yb2 N6 73.8(3) . . ?
O7 Yb2 N6 111.0(3) . . ?
O11 Yb2 N6 147.4(4) . . ?
O8 Yb2 N6 76.5(3) . . ?
N5 Yb2 N6 64.9(3) . . ?
C31 Pt C11 89.3(4) . . ?
C31 Pt N1 96.0(4) . . ?
C11 Pt N1 174.6(4) . . ?
C31 Pt N2 174.1(4) . . ?
C11 Pt N2 96.2(4) . . ?
N1 Pt N2 78.5(4) . . ?
C1 N1 C5 120.4(12) . . ?
C1 N1 Pt 122.8(10) . . ?
C5 N1 Pt 116.7(9) . . ?
C10 N2 C6 120.4(12) . . ?
C10 N2 Pt 123.7(9) . . ?
C6 N2 Pt 115.9(9) . . ?
C16 N3 C17 116.9(10) . . ?
C16 N3 Yb1 119.7(7) . . ?
C17 N3 Yb1 122.0(7) . . ?
C18 N4 C22 119.9(12) . . ?
C18 N4 Yb1 119.1(8) . . ?
C22 N4 Yb1 121.0(9) . . ?
C36 N5 C37 118.6(10) . . ?
C36 N5 Yb2 120.7(7) . . ?
C37 N5 Yb2 120.6(7) . . ?
C38 N6 C42 118.3(11) . . ?
C38 N6 Yb2 120.7(7) . . ?
C42 N6 Yb2 120.0(9) . . ?
N1 C1 C2 117.7(18) . . ?
N1 C1 H1A 121.1 . . ?
C2 C1 H1A 121.1 . . ?
C3 C2 C1 122(2) . . ?
C3 C2 H2A 119.2 . . ?
C1 C2 H2A 119.2 . . ?
C2 C3 C4 119.9(16) . . ?
C2 C3 H3A 120.0 . . ?
C4 C3 H3A 120.0 . . ?
C5 C4 C3 118.2(17) . . ?
C5 C4 H4A 120.9 . . ?
C3 C4 H4A 120.9 . . ?
C4 C5 N1 122.0(15) . . ?
C4 C5 C6 123.9(14) . . ?
N1 C5 C6 114.1(11) . . ?
C7 C6 N2 122.8(15) . . ?
C7 C6 C5 122.5(13) . . ?
N2 C6 C5 114.7(12) . . ?
C6 C7 C8 121.1(16) . . ?
C6 C7 H7A 119.4 . . ?
C8 C7 H7A 119.4 . . ?
C7 C8 C9 119.2(14) . . ?
C7 C8 H8A 120.4 . . ?
C9 C8 H8A 120.4 . . ?
C10 C9 C8 116.6(15) . . ?
C10 C9 H9A 121.7 . . ?
C8 C9 H9A 121.7 . . ?
N2 C10 C9 119.7(15) . . ?
N2 C10 H10A 120.1 . . ?
C9 C10 H10A 120.1 . . ?
C12 C11 Pt 175.9(11) . . ?
C11 C12 C13 172.7(12) . . ?
C14 C13 C17 117.3(10) . . ?
C14 C13 C12 123.3(10) . . ?
C17 C13 C12 119.3(10) . . ?
C13 C14 C15 119.9(12) . . ?
C13 C14 H14A 120.1 . . ?
C15 C14 H14A 120.1 . . ?
C16 C15 C14 120.9(12) . . ?
C16 C15 H15A 119.6 . . ?
C14 C15 H15A 119.6 . . ?
N3 C16 C15 121.3(11) . . ?
N3 C16 C18 113.5(11) . . ?
C15 C16 C18 125.2(12) . . ?
N3 C17 C13 123.6(11) . . ?
N3 C17 H17A 118.2 . . ?
C13 C17 H17A 118.2 . . ?
N4 C18 C19 120.7(13) . . ?
N4 C18 C16 119.8(12) . . ?
C19 C18 C16 119.5(14) . . ?
C18 C19 C20 117.2(18) . . ?
C18 C19 H19A 121.4 . . ?
C20 C19 H19A 121.4 . . ?
C21 C20 C19 122.0(16) . . ?
C21 C20 H20A 119.0 . . ?
C19 C20 H20A 119.0 . . ?
C22 C21 C20 113.4(13) . . ?
C22 C21 H21A 123.3 . . ?
C20 C21 H21A 123.3 . . ?
N4 C22 C21 126.5(15) . . ?
N4 C22 H22A 116.7 . . ?
C21 C22 H22A 116.7 . . ?
C32 C31 Pt 175.5(10) . . ?
C31 C32 C33 168.5(12) . . ?
C37 C33 C34 116.2(10) . . ?
C37 C33 C32 120.2(11) . . ?
C34 C33 C32 123.3(10) . . ?
C35 C34 C33 120.1(11) . . ?
C35 C34 H34A 120.0 . . ?
C33 C34 H34A 120.0 . . ?
C34 C35 C36 119.1(11) . . ?
C34 C35 H35A 120.5 . . ?
C36 C35 H35A 120.5 . . ?
N5 C36 C35 122.0(10) . . ?
N5 C36 C38 117.0(11) . . ?
C35 C36 C38 120.9(11) . . ?
N5 C37 C33 123.9(10) . . ?
N5 C37 H37A 118.0 . . ?
C33 C37 H37A 118.0 . . ?
N6 C38 C39 119.3(11) . . ?
N6 C38 C36 114.5(10) . . ?
C39 C38 C36 126.1(13) . . ?
C38 C39 C40 122.3(17) . . ?
C38 C39 H39A 118.9 . . ?
C40 C39 H39A 118.9 . . ?
C41 C40 C39 118.8(16) . . ?
C41 C40 H40A 120.6 . . ?
C39 C40 H40A 120.6 . . ?
C40 C41 C42 119.7(14) . . ?
C40 C41 H41A 120.2 . . ?
C42 C41 H41A 120.2 . . ?
C41 C42 N6 121.6(15) . . ?
C41 C42 H42A 119.2 . . ?
N6 C42 H42A 119.2 . . ?
F1 C111 F3 111.0(12) . . ?
F1 C111 F2' 74.8(13) . . ?
F3 C111 F2' 37.7(12) . . ?
F1 C111 F2 109.7(11) . . ?
F3 C111 F2 110.7(12) . . ?
F2' C111 F2 135.6(18) . . ?
F1 C111 F1' 131.3(17) . . ?
F3 C111 F1' 78.9(12) . . ?
F2' C111 F1' 110.7(12) . . ?
F2 C111 F1' 32.8(11) . . ?
F1 C111 F3' 35.9(12) . . ?
F3 C111 F3' 142.8(19) . . ?
F2' C111 F3' 110.0(12) . . ?
F2 C111 F3' 79.7(13) . . ?
F1' C111 F3' 110.0(12) . . ?
F1 C111 C112 110.7(14) . . ?
F3 C111 C112 101.8(16) . . ?
F2' C111 C112 105.7(15) . . ?
F2 C111 C112 112.7(16) . . ?
F1' C111 C112 113.5(14) . . ?
F3' C111 C112 106.6(17) . . ?
O1 C112 C113 125.9(10) . . ?
O1 C112 C111 117.7(11) . . ?
C113 C112 C111 116.2(11) . . ?
C112 O1 Yb1 137.1(8) . . ?
C114 C113 C112 121.0(11) . . ?
C114 C113 H11A 119.5 . . ?
C112 C113 H11A 119.5 . . ?
O2 C114 C113 127.1(10) . . ?
O2 C114 C115 112.2(9) . . ?
C113 C114 C115 120.6(10) . . ?
C114 O2 Yb1 133.8(7) . . ?
F4' C115 F6 76.7(12) . . ?
F4' C115 F4 117.2(17) . . ?
F6 C115 F4 110.2(12) . . ?
F4' C115 F6' 111.1(11) . . ?
F6 C115 F6' 131.1(16) . . ?
F4 C115 F6' 21.9(12) . . ?
F4' C115 F5 29.4(11) . . ?
F6 C115 F5 106.0(11) . . ?
F4 C115 F5 104.1(11) . . ?
F6' C115 F5 89.8(13) . . ?
F4' C115 F5' 105.2(11) . . ?
F6 C115 F5' 33.2(11) . . ?
F4 C115 F5' 82.2(12) . . ?
F6' C115 F5' 104.2(11) . . ?
F5 C115 F5' 132.0(15) . . ?
F4' C115 C114 117.5(14) . . ?
F6 C115 C114 110.6(14) . . ?
F4 C115 C114 117.0(13) . . ?
F6' C115 C114 107.4(12) . . ?
F5 C115 C114 108.2(13) . . ?
F5' C115 C114 110.7(13) . . ?
F8' C121 F8 140(2) . . ?
F8' C121 F9' 110.8(14) . . ?
F8 C121 F9' 40.8(13) . . ?
F8' C121 F7 38.9(13) . . ?
F8 C121 F7 110.1(13) . . ?
F9' C121 F7 73.2(14) . . ?
F8' C121 F7' 112.3(13) . . ?
F8 C121 F7' 70.1(13) . . ?
F9' C121 F7' 108.6(13) . . ?
F7 C121 F7' 136(2) . . ?
F8' C121 F9 72.7(14) . . ?
F8 C121 F9 110.9(13) . . ?
F9' C121 F9 141(2) . . ?
F7 C121 F9 107.9(13) . . ?
F7' C121 F9 43.0(13) . . ?
F8' C121 C122 110.2(19) . . ?
F8 C121 C122 105.9(19) . . ?
F9' C121 C122 105.1(18) . . ?
F7 C121 C122 112.1(15) . . ?
F7' C121 C122 109.5(17) . . ?
F9 C121 C122 110.0(17) . . ?
O3 C122 C123 125.6(12) . . ?
O3 C122 C121 115.0(11) . . ?
C123 C122 C121 119.3(11) . . ?
C122 O3 Yb1 134.5(8) . . ?
C124 C123 C122 120.7(12) . . ?
C124 C123 H12A 119.6 . . ?
C122 C123 H12A 119.6 . . ?
O4 C124 C123 128.5(12) . . ?
O4 C124 C125 110.9(11) . . ?
C123 C124 C125 120.5(12) . . ?
C124 O4 Yb1 132.5(8) . . ?
F10 C125 F11' 59.1(12) . . ?
F10 C125 F10' 132(2) . . ?
F11' C125 F10' 108.0(13) . . ?
F10 C125 F12' 50.4(12) . . ?
F11' C125 F12' 107.6(13) . . ?
F10' C125 F12' 106.6(13) . . ?
F10 C125 F11 106.6(12) . . ?
F11' C125 F11 132.8(19) . . ?
F10' C125 F11 45.2(12) . . ?
F12' C125 F11 63.5(12) . . ?
F10 C125 F12 106.5(13) . . ?
F11' C125 F12 49.9(12) . . ?
F10' C125 F12 64.7(13) . . ?
F12' C125 F12 143(2) . . ?
F11 C125 F12 107.3(12) . . ?
F10 C125 C124 115.2(15) . . ?
F11' C125 C124 115.6(15) . . ?
F10' C125 C124 111.5(18) . . ?
F12' C125 C124 107.1(16) . . ?
F11 C125 C124 111.0(15) . . ?
F12 C125 C124 109.8(18) . . ?
F13 C131 F15' 38.3(13) . . ?
F13 C131 F13' 131(2) . . ?
F15' C131 F13' 111.0(13) . . ?
F13 C131 F15 109.6(13) . . ?
F15' C131 F15 142(2) . . ?
F13' C131 F15 73.3(13) . . ?
F13 C131 F14' 70.6(14) . . ?
F15' C131 F14' 108.4(13) . . ?
F13' C131 F14' 109.3(13) . . ?
F15 C131 F14' 41.6(13) . . ?
F13 C131 F14 109.2(13) . . ?
F15' C131 F14 77.6(13) . . ?
F13' C131 F14 36.6(13) . . ?
F15 C131 F14 108.9(13) . . ?
F14' C131 F14 137(2) . . ?
F13 C131 C132 114.8(17) . . ?
F15' C131 C132 108.2(17) . . ?
F13' C131 C132 111.5(17) . . ?
F15 C131 C132 104.0(18) . . ?
F14' C131 C132 108.4(17) . . ?
F14 C131 C132 110.0(17) . . ?
O5 C132 C133 125.7(12) . . ?
O5 C132 C131 114.2(12) . . ?
C133 C132 C131 119.9(11) . . ?
C132 O5 Yb1 135.2(9) . . ?
C134 C133 C132 121.9(12) . . ?
C134 C133 H13A 119.0 . . ?
C132 C133 H13A 119.0 . . ?
O6 C134 C133 126.9(12) . . ?
O6 C134 C135 112.9(10) . . ?
C133 C134 C135 120.1(11) . . ?
C134 O6 Yb1 135.2(8) . . ?
F17' C135 F18 83.2(14) . . ?
F17' C135 F16 30.1(13) . . ?
F18 C135 F16 106.9(12) . . ?
F17' C135 F18' 108.0(13) . . ?
F18 C135 F18' 123.4(17) . . ?
F16 C135 F18' 79.4(13) . . ?
F17' C135 F17 137.2(18) . . ?
F18 C135 F17 111.4(12) . . ?
F16 C135 F17 109.4(12) . . ?
F18' C135 F17 30.0(12) . . ?
F17' C135 F16' 109.4(12) . . ?
F18 C135 F16' 26.7(13) . . ?
F16 C135 F16' 129.1(18) . . ?
F18' C135 F16' 108.2(11) . . ?
F17 C135 F16' 87.9(13) . . ?
F17' C135 C134 105.9(16) . . ?
F18 C135 C134 112.4(14) . . ?
F16 C135 C134 112.1(14) . . ?
F18' C135 C134 116.6(13) . . ?
F17 C135 C134 104.8(15) . . ?
F16' C135 C134 108.6(14) . . ?
F20' C141 F19 62.5(11) . . ?
F20' C141 F20 132(2) . . ?
F19 C141 F20 107.1(12) . . ?
F20' C141 F21' 108.6(12) . . ?
F19 C141 F21' 48.2(10) . . ?
F20 C141 F21' 66.1(11) . . ?
F20' C141 F19' 108.0(13) . . ?
F19 C141 F19' 133.3(18) . . ?
F20 C141 F19' 42.8(11) . . ?
F21' C141 F19' 107.1(12) . . ?
F20' C141 F21 46.1(11) . . ?
F19 C141 F21 106.3(12) . . ?
F20 C141 F21 107.6(13) . . ?
F21' C141 F21 142.1(19) . . ?
F19' C141 F21 67.9(12) . . ?
F20' C141 C142 111.6(16) . . ?
F19 C141 C142 111.4(13) . . ?
F20 C141 C142 115.1(17) . . ?
F21' C141 C142 107.2(15) . . ?
F19' C141 C142 114.1(16) . . ?
F21 C141 C142 108.9(16) . . ?
O7 C142 C143 125.2(11) . . ?
O7 C142 C141 115.4(11) . . ?
C143 C142 C141 119.1(12) . . ?
C142 O7 Yb2 133.3(8) . . ?
C144 C143 C142 121.1(12) . . ?
C144 C143 H14B 119.5 . . ?
C142 C143 H14B 119.5 . . ?
O8 C144 C143 127.1(11) . . ?
O8 C144 C145 115.4(11) . . ?
C143 C144 C145 117.4(11) . . ?
C144 O8 Yb2 130.5(7) . . ?
F22' C145 F22 135.3(19) . . ?
F22' C145 F24 74.4(12) . . ?
F22 C145 F24 111.3(13) . . ?
F22' C145 F24' 111.6(12) . . ?
F22 C145 F24' 39.2(13) . . ?
F24 C145 F24' 144(2) . . ?
F22' C145 F23' 110.2(12) . . ?
F22 C145 F23' 71.7(13) . . ?
F24 C145 F23' 41.1(12) . . ?
F24' C145 F23' 109.8(13) . . ?
F22' C145 F23 37.7(12) . . ?
F22 C145 F23 109.4(12) . . ?
F24 C145 F23 110.4(12) . . ?
F24' C145 F23 75.8(13) . . ?
F23' C145 F23 136(2) . . ?
F22' C145 C144 111.6(15) . . ?
F22 C145 C144 109.4(16) . . ?
F24 C145 C144 104.6(17) . . ?
F24' C145 C144 105.0(16) . . ?
F23' C145 C144 108.5(16) . . ?
F23 C145 C144 111.6(17) . . ?
F25' C151 F25 133(2) . . ?
F25' C151 F27 76.4(16) . . ?
F25 C151 F27 110.8(13) . . ?
F25' C151 F26' 111.8(13) . . ?
F25 C151 F26' 73.0(13) . . ?
F27 C151 F26' 40.1(14) . . ?
F25' C151 F27' 113.6(13) . . ?
F25 C151 F27' 35.8(11) . . ?
F27 C151 F27' 143.2(19) . . ?
F26' C151 F27' 108.6(12) . . ?
F25' C151 F26 33.7(15) . . ?
F25 C151 F26 111.1(13) . . ?
F27 C151 F26 109.0(13) . . ?
F26' C151 F26 137(2) . . ?
F27' C151 F26 82.3(14) . . ?
F25' C151 C152 111.0(18) . . ?
F25 C151 C152 109.3(15) . . ?
F27 C151 C152 110(2) . . ?
F26' C151 C152 112(2) . . ?
F27' C151 C152 99.0(16) . . ?
F26 C151 C152 106.1(19) . . ?
O9 C152 C153 125.8(13) . . ?
O9 C152 C151 115.7(13) . . ?
C153 C152 C151 118.3(13) . . ?
C152 O9 Yb2 135.8(10) . . ?
C154 C153 C152 122.3(13) . . ?
C154 C153 H15B 118.9 . . ?
C152 C153 H15B 118.9 . . ?
O10 C154 C153 123.8(13) . . ?
O10 C154 C155 113.9(12) . . ?
C153 C154 C155 122.2(13) . . ?
C154 O10 Yb2 137.1(9) . . ?
F28 C155 F28' 133(3) . . ?
F28 C155 F29 111.3(15) . . ?
F28' C155 F29 73.4(17) . . ?
F28 C155 F29' 44.5(15) . . ?
F28' C155 F29' 110.9(15) . . ?
F29 C155 F29' 152(2) . . ?
F28 C155 F30 109.0(15) . . ?
F28' C155 F30 36.1(18) . . ?
F29 C155 F30 107.9(14) . . ?
F29' C155 F30 75.4(17) . . ?
F28 C155 F30' 64.7(15) . . ?
F28' C155 F30' 108.2(14) . . ?
F29 C155 F30' 46.8(15) . . ?
F29' C155 F30' 108.1(14) . . ?
F30 C155 F30' 128(3) . . ?
F28 C155 C154 115(2) . . ?
F28' C155 C154 109(2) . . ?
F29 C155 C154 103(2) . . ?
F29' C155 C154 102(2) . . ?
F30 C155 C154 111(2) . . ?
F30' C155 C154 119(2) . . ?
F32 C161 F31 112.0(14) . . ?
F32 C161 F32' 127(3) . . ?
F31 C161 F32' 66.0(15) . . ?
F32 C161 F33 110.7(14) . . ?
F31 C161 F33 110.1(14) . . ?
F32' C161 F33 44.1(16) . . ?
F32 C161 F31' 40.4(15) . . ?
F31 C161 F31' 144(2) . . ?
F32' C161 F31' 109.1(14) . . ?
F33 C161 F31' 74.6(15) . . ?
F32 C161 F33' 67.1(14) . . ?
F31 C161 F33' 48.6(14) . . ?
F32' C161 F33' 107.4(14) . . ?
F33 C161 F33' 145(3) . . ?
F31' C161 F33' 107.1(14) . . ?
F32 C161 C162 114(2) . . ?
F31 C161 C162 103(2) . . ?
F32' C161 C162 118(2) . . ?
F33 C161 C162 107(2) . . ?
F31' C161 C162 109.4(19) . . ?
F33' C161 C162 105.3(19) . . ?
O11 C162 C163 122.9(13) . . ?
O11 C162 C161 118.4(14) . . ?
C163 C162 C161 118.4(14) . . ?
C162 O11 Yb2 137.4(10) . . ?
C164 C163 C162 122.7(14) . . ?
C164 C163 H16A 118.6 . . ?
C162 C163 H16A 118.6 . . ?
O12 C164 C163 128.7(13) . . ?
O12 C164 C165 110.3(12) . . ?
C163 C164 C165 120.9(13) . . ?
C164 O12 Yb2 133.1(9) . . ?
F34' C165 F35' 110.2(13) . . ?
F34' C165 F36' 112.5(14) . . ?
F35' C165 F36' 111.2(13) . . ?
F34' C165 F36 74.7(15) . . ?
F35' C165 F36 38.5(14) . . ?
F36' C165 F36 142(2) . . ?
F34' C165 F34 138(2) . . ?
F35' C165 F34 73.0(13) . . ?
F36' C165 F34 39.5(11) . . ?
F36 C165 F34 109.3(13) . . ?
F34' C165 F35 38.4(15) . . ?
F35' C165 F35 133(2) . . ?
F36' C165 F35 74.7(13) . . ?
F36 C165 F35 108.4(13) . . ?
F34 C165 F35 107.9(13) . . ?
F34' C165 C164 102(2) . . ?
F35' C165 C164 115(2) . . ?
F36' C165 C164 105.0(15) . . ?
F36 C165 C164 110.1(19) . . ?
F34 C165 C164 114.2(15) . . ?
F35 C165 C164 106.8(19) . . ?
Cl1 C01 Cl2 110.7(12) . . ?
Cl1' C01' Cl2' 109.6(12) . . ?
Cl3 C02 Cl4 110.0(12) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Yb1 O1 2.250(9) . ?
Yb1 O6 2.262(8) . ?
Yb1 O3 2.273(9) . ?
Yb1 O4 2.283(9) . ?
Yb1 O5 2.286(10) . ?
Yb1 O2 2.331(8) . ?
Yb1 N4 2.434(10) . ?
Yb1 N3 2.461(9) . ?
Yb2 O12 2.245(8) . ?
Yb2 O9 2.248(9) . ?
Yb2 O10 2.282(9) . ?
Yb2 O7 2.283(9) . ?
Yb2 O11 2.290(12) . ?
Yb2 O8 2.290(8) . ?
Yb2 N5 2.448(9) . ?
Yb2 N6 2.457(9) . ?
Pt C31 1.909(12) . ?
Pt C11 1.927(10) . ?
Pt N1 2.039(10) . ?
Pt N2 2.054(10) . ?
F1 C111 1.319(9) . ?
F2 C111 1.322(9) . ?
F3 C111 1.320(10) . ?
F1' C111 1.323(9) . ?
F2' C111 1.322(10) . ?
F3' C111 1.329(10) . ?
F4 C115 1.312(9) . ?
F5 C115 1.343(9) . ?
F6 C115 1.303(9) . ?
F4' C115 1.296(9) . ?
F5' C115 1.345(9) . ?
F6' C115 1.324(9) . ?
F7 C121 1.318(9) . ?
F8 C121 1.309(10) . ?
F9 C121 1.321(10) . ?
F7' C121 1.318(10) . ?
F8' C121 1.306(10) . ?
F9' C121 1.315(10) . ?
F10 C125 1.312(9) . ?
F11 C125 1.323(9) . ?
F12 C125 1.325(10) . ?
F10' C125 1.319(10) . ?
F11' C125 1.313(9) . ?
F12' C125 1.320(10) . ?
F13 C131 1.313(10) . ?
F14 C131 1.325(10) . ?
F15 C131 1.315(10) . ?
F13' C131 1.315(10) . ?
F14' C131 1.318(10) . ?
F15' C131 1.314(10) . ?
F16 C135 1.318(9) . ?
F17 C135 1.320(9) . ?
F18 C135 1.315(9) . ?
F16' C135 1.330(9) . ?
F17' C135 1.311(10) . ?
F18' C135 1.319(9) . ?
F19 C141 1.320(9) . ?
F20 C141 1.321(9) . ?
F21 C141 1.325(10) . ?
F19' C141 1.323(9) . ?
F20' C141 1.312(9) . ?
F21' C141 1.321(9) . ?
F22 C145 1.313(9) . ?
F23 C145 1.320(9) . ?
F24 C145 1.313(10) . ?
F22' C145 1.306(9) . ?
F23' C145 1.320(10) . ?
F24' C145 1.318(9) . ?
F25 C151 1.321(9) . ?
F26 C151 1.338(10) . ?
F27 C151 1.322(10) . ?
F25' C151 1.301(10) . ?
F26' C151 1.331(10) . ?
F27' C151 1.335(9) . ?
F28 C155 1.313(10) . ?
F29 C155 1.323(10) . ?
F30 C155 1.327(10) . ?
F28' C155 1.314(10) . ?
F29' C155 1.324(10) . ?
F30' C155 1.328(10) . ?
F31 C161 1.305(10) . ?
F32 C161 1.302(10) . ?
F33 C161 1.317(10) . ?
F31' C161 1.323(10) . ?
F32' C161 1.317(10) . ?
F33' C161 1.327(10) . ?
F34 C165 1.329(9) . ?
F35 C165 1.333(10) . ?
F36 C165 1.322(10) . ?
F34' C165 1.306(10) . ?
F35' C165 1.317(10) . ?
F36' C165 1.319(9) . ?
N1 C1 1.343(17) . ?
N1 C5 1.361(16) . ?
N2 C10 1.359(16) . ?
N2 C6 1.360(16) . ?
N3 C16 1.342(14) . ?
N3 C17 1.368(13) . ?
N4 C18 1.316(18) . ?
N4 C22 1.324(16) . ?
N5 C36 1.333(14) . ?
N5 C37 1.338(13) . ?
N6 C38 1.342(15) . ?
N6 C42 1.367(14) . ?
C1 C2 1.38(2) . ?
C1 H1A 0.9300 . ?
C2 C3 1.32(3) . ?
C2 H2A 0.9300 . ?
C3 C4 1.39(3) . ?
C3 H3A 0.9300 . ?
C4 C5 1.33(2) . ?
C4 H4A 0.9300 . ?
C5 C6 1.47(2) . ?
C6 C7 1.324(19) . ?
C7 C8 1.34(2) . ?
C7 H7A 0.9300 . ?
C8 C9 1.48(3) . ?
C8 H8A 0.9300 . ?
C9 C10 1.41(2) . ?
C9 H9A 0.9300 . ?
C10 H10A 0.9300 . ?
C11 C12 1.189(15) . ?
C12 C13 1.449(16) . ?
C13 C14 1.329(17) . ?
C13 C17 1.397(15) . ?
C14 C15 1.394(18) . ?
C14 H14A 0.9300 . ?
C15 C16 1.353(18) . ?
C15 H15A 0.9300 . ?
C16 C18 1.446(16) . ?
C17 H17A 0.9300 . ?
C18 C19 1.40(2) . ?
C19 C20 1.42(2) . ?
C19 H19A 0.9300 . ?
C20 C21 1.38(3) . ?
C20 H20A 0.9300 . ?
C21 C22 1.38(2) . ?
C21 H21A 0.9300 . ?
C22 H22A 0.9300 . ?
C31 C32 1.250(15) . ?
C32 C33 1.411(15) . ?
C33 C37 1.391(15) . ?
C33 C34 1.405(16) . ?
C34 C35 1.376(17) . ?
C34 H34A 0.9300 . ?
C35 C36 1.382(17) . ?
C35 H35A 0.9300 . ?
C36 C38 1.461(14) . ?
C37 H37A 0.9300 . ?
C38 C39 1.350(17) . ?
C39 C40 1.36(2) . ?
C39 H39A 0.9300 . ?
C40 C41 1.32(2) . ?
C40 H40A 0.9300 . ?
C41 C42 1.36(2) . ?
C41 H41A 0.9300 . ?
C42 H42A 0.9300 . ?
C111 C112 1.531(5) . ?
C112 O1 1.243(12) . ?
C112 C113 1.412(14) . ?
C113 C114 1.380(13) . ?
C113 H11A 0.9300 . ?
C114 O2 1.255(11) . ?
C114 C115 1.529(5) . ?
C121 C122 1.535(14) . ?
C122 O3 1.214(12) . ?
C122 C123 1.413(14) . ?
C123 C124 1.366(14) . ?
C123 H12A 0.9300 . ?
C124 O4 1.232(13) . ?
C124 C125 1.574(14) . ?
C131 C132 1.531(14) . ?
C132 O5 1.233(12) . ?
C132 C133 1.399(15) . ?
C133 C134 1.388(14) . ?
C133 H13A 0.9300 . ?
C134 O6 1.231(12) . ?
C134 C135 1.572(13) . ?
C141 C142 1.530(13) . ?
C142 O7 1.237(13) . ?
C142 C143 1.413(14) . ?
C143 C144 1.390(14) . ?
C143 H14B 0.9300 . ?
C144 O8 1.231(12) . ?
C144 C145 1.560(13) . ?
C151 C152 1.564(14) . ?
C152 O9 1.237(15) . ?
C152 C153 1.424(16) . ?
C153 C154 1.386(14) . ?
C153 H15B 0.9300 . ?
C154 O10 1.231(13) . ?
C154 C155 1.570(15) . ?
C161 C162 1.530(14) . ?
C162 O11 1.204(14) . ?
C162 C163 1.420(16) . ?
C163 C164 1.368(15) . ?
C163 H16A 0.9300 . ?
C164 O12 1.246(14) . ?
C164 C165 1.582(14) . ?
C01 Cl1 1.761(10) . ?
C01 Cl2 1.765(10) . ?
C01' Cl1' 1.762(10) . ?
C01' Cl2' 1.769(10) . ?
C02 Cl3 1.761(10) . ?
C02 Cl4 1.775(10) . ?
