#------------------------------------------------------------------------------
#$Date: 2016-03-25 09:13:15 +0100 (vie 25 de mar de 2016) $
#$Revision: 179744 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/40/7004017.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7004017
loop_
_publ_author_name
'Spannhoff, Kirsten'
'Kehr, Gerald'
'Kehr, Seda'
'Fröhlich, Roland'
'Erker, Gerhard'
_publ_section_title
;
 Functionalized phosphorus analogues of the β-diketiminato ligand
 systems: bis(N-arylphosphinimino)acetonitrile-derived complexes of
 rhodium and iridium
;
_journal_issue                   25
_journal_name_full               'Dalton Transactions'
_journal_page_first              3339
_journal_page_last               3344
_journal_paper_doi               10.1039/b802032a
_journal_year                    2008
_chemical_formula_sum            'C40 H30 N3 O2 P2 Rh'
_chemical_formula_weight         749.52
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 102.278(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   9.8125(2)
_cell_length_b                   20.4272(5)
_cell_length_c                   17.5318(2)
_cell_measurement_reflns_used    19338
_cell_measurement_temperature    198(2)
_cell_measurement_theta_max      27.88
_cell_measurement_theta_min      0.41
_cell_volume                     3433.73(12)
_computing_cell_refinement       'Collect (Nonius B.V., 1998)'
_computing_data_collection       'Collect (Nonius B.V., 1998)'
_computing_data_reduction        'Denzo-SMN (Otwinowski & Minor, 1997)'
_computing_molecular_graphics    'SCHAKAL (Keller, 1997)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      198(2)
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'Nonius KappaCCD'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'rotating anode Nonius FR591'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0555
_diffrn_reflns_av_sigmaI/netI    0.0685
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -26
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            22757
_diffrn_reflns_theta_full        27.86
_diffrn_reflns_theta_max         27.86
_diffrn_reflns_theta_min         1.99
_exptl_absorpt_coefficient_mu    0.631
_exptl_absorpt_correction_T_max  0.9692
_exptl_absorpt_correction_T_min  0.8843
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SORTAV (Blessing, 1995 & 1997)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.450
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             1528
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.05
_refine_diff_density_max         0.878
_refine_diff_density_min         -0.591
_refine_diff_density_rms         0.085
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.018
_refine_ls_hydrogen_treatment    riding
_refine_ls_matrix_type           full
_refine_ls_number_parameters     433
_refine_ls_number_reflns         8114
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.018
_refine_ls_R_factor_all          0.0780
_refine_ls_R_factor_gt           0.0439
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0400P)²+2.4045P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0891
_refine_ls_wR_factor_ref         0.1003
_reflns_number_gt                5740
_reflns_number_total             8114
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b802032a.txt
_cod_data_source_block           erk4173
_cod_original_sg_symbol_H-M      P21/c
_cod_database_code               7004017
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.07548(2) 0.689543(11) 0.200315(13) 0.02353(8) Uani 1 1 d . . .
C1 C 0.3727(3) 0.69200(14) 0.17673(16) 0.0226(6) Uani 1 1 d . . .
C2 C 0.4466(4) 0.69136(16) 0.1163(2) 0.0410(9) Uani 1 1 d . . .
N3 N 0.5056(5) 0.69257(18) 0.0668(2) 0.0847(14) Uani 1 1 d . . .
C3 C -0.0499(4) 0.62885(17) 0.1482(2) 0.0432(9) Uani 1 1 d . . .
O3 O -0.1248(3) 0.59150(15) 0.11513(19) 0.0796(11) Uani 1 1 d . . .
C4 C -0.0485(3) 0.75466(16) 0.15848(18) 0.0315(7) Uani 1 1 d . . .
O4 O -0.1273(3) 0.79305(12) 0.13120(15) 0.0515(7) Uani 1 1 d . . .
N1 N 0.2232(2) 0.75680(11) 0.26288(13) 0.0213(5) Uani 1 1 d . . .
C11 C 0.1792(3) 0.80659(14) 0.31006(16) 0.0221(6) Uani 1 1 d . . .
C12 C 0.1826(4) 0.79389(17) 0.38860(18) 0.0358(8) Uani 1 1 d . . .
H12 H 0.2139 0.7526 0.4103 0.043 Uiso 1 1 calc R . .
C13 C 0.1402(4) 0.8415(2) 0.43506(19) 0.0431(9) Uani 1 1 d . . .
H13 H 0.1455 0.8329 0.4889 0.052 Uiso 1 1 calc R . .
C14 C 0.0907(3) 0.90088(18) 0.4043(2) 0.0385(8) Uani 1 1 d . . .
H14 H 0.0601 0.9328 0.4363 0.046 Uiso 1 1 calc R . .
C15 C 0.0860(3) 0.91352(16) 0.3272(2) 0.0344(8) Uani 1 1 d . . .
H15 H 0.0516 0.9545 0.3056 0.041 Uiso 1 1 calc R . .
C16 C 0.1305(3) 0.86742(15) 0.28025(18) 0.0278(7) Uani 1 1 d . . .
H16 H 0.1279 0.8773 0.2270 0.033 Uiso 1 1 calc R . .
N2 N 0.2136(2) 0.61353(11) 0.24892(13) 0.0228(5) Uani 1 1 d . . .
C21 C 0.1707(3) 0.56060(14) 0.28993(16) 0.0223(6) Uani 1 1 d . . .
C22 C 0.0489(3) 0.56693(15) 0.31859(17) 0.0285(7) Uani 1 1 d . . .
H22 H -0.0025 0.6066 0.3100 0.034 Uiso 1 1 calc R . .
C23 C 0.0014(3) 0.51690(16) 0.35902(18) 0.0335(7) Uani 1 1 d . . .
H23 H -0.0823 0.5225 0.3773 0.040 Uiso 1 1 calc R . .
C24 C 0.0743(3) 0.45865(16) 0.37316(18) 0.0328(7) Uani 1 1 d . . .
H24 H 0.0419 0.4243 0.4012 0.039 Uiso 1 1 calc R . .
C25 C 0.1950(3) 0.45160(15) 0.34573(17) 0.0306(7) Uani 1 1 d . . .
H25 H 0.2463 0.4119 0.3554 0.037 Uiso 1 1 calc R . .
C26 C 0.2431(3) 0.50099(14) 0.30453(17) 0.0276(7) Uani 1 1 d . . .
H26 H 0.3262 0.4946 0.2858 0.033 Uiso 1 1 calc R . .
P1 P 0.35294(8) 0.76738(4) 0.22074(4) 0.02155(17) Uani 1 1 d . . .
C31 C 0.5120(3) 0.79067(14) 0.28802(17) 0.0261(7) Uani 1 1 d . . .
C32 C 0.6292(4) 0.80582(18) 0.2581(2) 0.0401(8) Uani 1 1 d . . .
H32 H 0.6219 0.8083 0.2032 0.048 Uiso 1 1 calc R . .
C33 C 0.7559(4) 0.8171(2) 0.3083(2) 0.0510(10) Uani 1 1 d . . .
H33 H 0.8355 0.8275 0.2879 0.061 Uiso 1 1 calc R . .
C34 C 0.7674(4) 0.81344(19) 0.3879(2) 0.0485(10) Uani 1 1 d . . .
H34 H 0.8547 0.8218 0.4221 0.058 Uiso 1 1 calc R . .
C35 C 0.6535(4) 0.79777(17) 0.41803(19) 0.0382(8) Uani 1 1 d . . .
H35 H 0.6626 0.7947 0.4729 0.046 Uiso 1 1 calc R . .
C36 C 0.5248(3) 0.78638(16) 0.36857(18) 0.0302(7) Uani 1 1 d . . .
H36 H 0.4460 0.7757 0.3896 0.036 Uiso 1 1 calc R . .
C41 C 0.3251(3) 0.82999(15) 0.14511(17) 0.0272(7) Uani 1 1 d . . .
C42 C 0.2341(4) 0.81693(16) 0.07387(18) 0.0353(8) Uani 1 1 d . . .
H42 H 0.1962 0.7743 0.0631 0.042 Uiso 1 1 calc R . .
C43 C 0.1993(4) 0.86643(19) 0.01895(19) 0.0443(9) Uani 1 1 d . . .
H43 H 0.1372 0.8576 -0.0294 0.053 Uiso 1 1 calc R . .
C44 C 0.2543(4) 0.92826(17) 0.0341(2) 0.0426(9) Uani 1 1 d . . .
H44 H 0.2308 0.9618 -0.0040 0.051 Uiso 1 1 calc R . .
C45 C 0.3424(4) 0.94146(17) 0.1038(2) 0.0426(9) Uani 1 1 d . . .
H45 H 0.3792 0.9843 0.1141 0.051 Uiso 1 1 calc R . .
C46 C 0.3789(4) 0.89279(16) 0.15958(19) 0.0354(8) Uani 1 1 d . . .
H46 H 0.4407 0.9024 0.2078 0.042 Uiso 1 1 calc R . .
P2 P 0.36700(8) 0.61972(4) 0.22913(4) 0.02084(16) Uani 1 1 d . . .
C51 C 0.4031(3) 0.55427(14) 0.16718(16) 0.0263(7) Uani 1 1 d . . .
C52 C 0.2981(4) 0.53876(18) 0.1037(2) 0.0449(9) Uani 1 1 d . . .
H52 H 0.2126 0.5623 0.0949 0.054 Uiso 1 1 calc R . .
C53 C 0.3166(4) 0.4891(2) 0.0529(2) 0.0546(11) Uani 1 1 d . . .
H53 H 0.2439 0.4791 0.0093 0.066 Uiso 1 1 calc R . .
C54 C 0.4377(4) 0.45473(17) 0.0648(2) 0.0453(9) Uani 1 1 d . . .
H54 H 0.4499 0.4209 0.0298 0.054 Uiso 1 1 calc R . .
C55 C 0.5422(4) 0.46922(18) 0.1279(2) 0.0469(9) Uani 1 1 d . . .
H55 H 0.6267 0.4450 0.1365 0.056 Uiso 1 1 calc R . .
C56 C 0.5263(4) 0.51859(17) 0.1790(2) 0.0379(8) Uani 1 1 d . . .
H56 H 0.5997 0.5282 0.2224 0.045 Uiso 1 1 calc R . .
C61 C 0.5020(3) 0.62073(14) 0.31748(16) 0.0248(6) Uani 1 1 d . . .
C62 C 0.6394(3) 0.63442(16) 0.31316(19) 0.0334(7) Uani 1 1 d . . .
H62 H 0.6632 0.6395 0.2637 0.040 Uiso 1 1 calc R . .
C63 C 0.7409(4) 0.64064(18) 0.3807(2) 0.0416(9) Uani 1 1 d . . .
H63 H 0.8344 0.6501 0.3776 0.050 Uiso 1 1 calc R . .
C64 C 0.7071(4) 0.63315(19) 0.4522(2) 0.0488(10) Uani 1 1 d . . .
H64 H 0.7779 0.6367 0.4983 0.059 Uiso 1 1 calc R . .
C65 C 0.5730(4) 0.62062(19) 0.4580(2) 0.0466(9) Uani 1 1 d . . .
H65 H 0.5507 0.6158 0.5079 0.056 Uiso 1 1 calc R . .
C66 C 0.4685(4) 0.61492(16) 0.39037(17) 0.0335(7) Uani 1 1 d . . .
H66 H 0.3748 0.6071 0.3942 0.040 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C3 Rh1 C4 88.49(14) . . ?
C3 Rh1 N2 90.50(13) . . ?
C4 Rh1 N2 178.59(12) . . ?
C3 Rh1 N1 178.03(12) . . ?
C4 Rh1 N1 93.37(11) . . ?
N2 Rh1 N1 87.63(9) . . ?
C2 C1 P2 117.9(2) . . ?
C2 C1 P1 117.6(2) . . ?
P2 C1 P1 119.51(15) . . ?
N3 C2 C1 178.1(4) . . ?
O3 C3 Rh1 178.4(4) . . ?
O4 C4 Rh1 177.6(3) . . ?
C11 N1 P1 122.10(19) . . ?
C11 N1 Rh1 120.05(17) . . ?
P1 N1 Rh1 111.56(12) . . ?
C16 C11 C12 118.1(3) . . ?
C16 C11 N1 122.5(3) . . ?
C12 C11 N1 119.4(3) . . ?
C13 C12 C11 120.1(3) . . ?
C14 C13 C12 120.9(3) . . ?
C15 C14 C13 119.3(3) . . ?
C14 C15 C16 120.8(3) . . ?
C15 C16 C11 120.8(3) . . ?
C21 N2 P2 124.05(19) . . ?
C21 N2 Rh1 122.18(18) . . ?
P2 N2 Rh1 113.63(12) . . ?
C22 C21 C26 116.9(3) . . ?
C22 C21 N2 118.8(3) . . ?
C26 C21 N2 124.2(3) . . ?
C23 C22 C21 121.6(3) . . ?
C22 C23 C24 120.7(3) . . ?
C25 C24 C23 118.5(3) . . ?
C24 C25 C26 121.4(3) . . ?
C25 C26 C21 120.8(3) . . ?
N1 P1 C1 104.82(13) . . ?
N1 P1 C31 113.04(13) . . ?
C1 P1 C31 110.94(14) . . ?
N1 P1 C41 114.57(13) . . ?
C1 P1 C41 108.08(13) . . ?
C31 P1 C41 105.39(14) . . ?
C36 C31 C32 119.4(3) . . ?
C36 C31 P1 121.6(2) . . ?
C32 C31 P1 118.6(2) . . ?
C33 C32 C31 119.9(3) . . ?
C34 C33 C32 120.4(3) . . ?
C35 C34 C33 120.3(3) . . ?
C34 C35 C36 120.4(3) . . ?
C35 C36 C31 119.7(3) . . ?
C46 C41 C42 119.0(3) . . ?
C46 C41 P1 121.5(2) . . ?
C42 C41 P1 119.0(2) . . ?
C43 C42 C41 119.8(3) . . ?
C44 C43 C42 120.4(3) . . ?
C45 C44 C43 120.1(3) . . ?
C44 C45 C46 120.6(3) . . ?
C45 C46 C41 120.1(3) . . ?
N2 P2 C1 108.30(13) . . ?
N2 P2 C51 112.41(14) . . ?
C1 P2 C51 106.11(13) . . ?
N2 P2 C61 111.20(13) . . ?
C1 P2 C61 109.92(14) . . ?
C51 P2 C61 108.77(14) . . ?
C52 C51 C56 118.4(3) . . ?
C52 C51 P2 116.5(2) . . ?
C56 C51 P2 125.1(2) . . ?
C51 C52 C53 120.5(3) . . ?
C54 C53 C52 120.6(3) . . ?
C53 C54 C55 119.5(3) . . ?
C54 C55 C56 120.9(3) . . ?
C55 C56 C51 120.1(3) . . ?
C66 C61 C62 119.2(3) . . ?
C66 C61 P2 120.8(2) . . ?
C62 C61 P2 119.7(2) . . ?
C63 C62 C61 120.1(3) . . ?
C64 C63 C62 120.2(3) . . ?
C65 C64 C63 120.9(3) . . ?
C64 C65 C66 119.8(3) . . ?
C61 C66 C65 119.9(3) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 C3 1.846(3) . ?
Rh1 C4 1.846(3) . ?
Rh1 N2 2.117(2) . ?
Rh1 N1 2.125(2) . ?
C1 C2 1.405(4) . ?
C1 P2 1.746(3) . ?
C1 P1 1.752(3) . ?
C2 N3 1.140(4) . ?
C3 O3 1.130(4) . ?
C4 O4 1.133(4) . ?
N1 C11 1.434(3) . ?
N1 P1 1.617(2) . ?
C11 C16 1.393(4) . ?
C11 C12 1.395(4) . ?
C12 C13 1.388(5) . ?
C13 C14 1.374(5) . ?
C14 C15 1.368(5) . ?
C15 C16 1.381(4) . ?
N2 C21 1.411(4) . ?
N2 P2 1.620(2) . ?
C21 C22 1.398(4) . ?
C21 C26 1.406(4) . ?
C22 C23 1.380(4) . ?
C23 C24 1.384(5) . ?
C24 C25 1.377(5) . ?
C25 C26 1.381(4) . ?
P1 C31 1.808(3) . ?
P1 C41 1.821(3) . ?
C31 C36 1.394(4) . ?
C31 C32 1.397(4) . ?
C32 C33 1.382(5) . ?
C33 C34 1.378(5) . ?
C34 C35 1.372(5) . ?
C35 C36 1.392(4) . ?
C41 C46 1.390(4) . ?
C41 C42 1.398(4) . ?
C42 C43 1.388(5) . ?
C43 C44 1.377(5) . ?
C44 C45 1.365(5) . ?
C45 C46 1.387(5) . ?
P2 C51 1.804(3) . ?
P2 C61 1.812(3) . ?
C51 C52 1.383(4) . ?
C51 C56 1.389(4) . ?
C52 C53 1.387(5) . ?
C53 C54 1.358(5) . ?
C54 C55 1.371(5) . ?
C55 C56 1.380(5) . ?
C61 C66 1.391(4) . ?
C61 C62 1.395(4) . ?
C62 C63 1.382(4) . ?
C63 C64 1.371(5) . ?
C64 C65 1.366(5) . ?
C65 C66 1.398(5) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C4 Rh1 N1 C11 49.2(2) . . . . ?
N2 Rh1 N1 C11 -129.8(2) . . . . ?
C4 Rh1 N1 P1 -103.53(15) . . . . ?
N2 Rh1 N1 P1 77.47(13) . . . . ?
P1 N1 C11 C16 62.0(3) . . . . ?
Rh1 N1 C11 C16 -87.8(3) . . . . ?
P1 N1 C11 C12 -119.2(3) . . . . ?
Rh1 N1 C11 C12 91.1(3) . . . . ?
C16 C11 C12 C13 -1.0(5) . . . . ?
N1 C11 C12 C13 -179.9(3) . . . . ?
C11 C12 C13 C14 1.9(5) . . . . ?
C12 C13 C14 C15 -1.3(5) . . . . ?
C13 C14 C15 C16 -0.1(5) . . . . ?
C14 C15 C16 C11 1.0(5) . . . . ?
C12 C11 C16 C15 -0.5(4) . . . . ?
N1 C11 C16 C15 178.4(3) . . . . ?
C3 Rh1 N2 C21 -53.2(2) . . . . ?
N1 Rh1 N2 C21 126.1(2) . . . . ?
C3 Rh1 N2 P2 122.71(17) . . . . ?
N1 Rh1 N2 P2 -57.93(13) . . . . ?
P2 N2 C21 C22 166.0(2) . . . . ?
Rh1 N2 C21 C22 -18.5(3) . . . . ?
P2 N2 C21 C26 -13.7(4) . . . . ?
Rh1 N2 C21 C26 161.7(2) . . . . ?
C26 C21 C22 C23 -0.3(4) . . . . ?
N2 C21 C22 C23 179.9(3) . . . . ?
C21 C22 C23 C24 0.6(5) . . . . ?
C22 C23 C24 C25 -0.2(5) . . . . ?
C23 C24 C25 C26 -0.4(5) . . . . ?
C24 C25 C26 C21 0.7(5) . . . . ?
C22 C21 C26 C25 -0.3(4) . . . . ?
N2 C21 C26 C25 179.5(3) . . . . ?
C11 N1 P1 C1 175.9(2) . . . . ?
Rh1 N1 P1 C1 -32.00(15) . . . . ?
C11 N1 P1 C31 55.0(2) . . . . ?
Rh1 N1 P1 C31 -152.96(13) . . . . ?
C11 N1 P1 C41 -65.8(2) . . . . ?
Rh1 N1 P1 C41 86.28(16) . . . . ?
C2 C1 P1 N1 160.5(3) . . . . ?
P2 C1 P1 N1 -44.9(2) . . . . ?
C2 C1 P1 C31 -77.2(3) . . . . ?
P2 C1 P1 C31 77.4(2) . . . . ?
C2 C1 P1 C41 37.9(3) . . . . ?
P2 C1 P1 C41 -167.49(17) . . . . ?
N1 P1 C31 C36 12.2(3) . . . . ?
C1 P1 C31 C36 -105.3(3) . . . . ?
C41 P1 C31 C36 138.0(3) . . . . ?
N1 P1 C31 C32 -175.5(2) . . . . ?
C1 P1 C31 C32 67.1(3) . . . . ?
C41 P1 C31 C32 -49.7(3) . . . . ?
C36 C31 C32 C33 -0.8(5) . . . . ?
P1 C31 C32 C33 -173.3(3) . . . . ?
C31 C32 C33 C34 0.1(6) . . . . ?
C32 C33 C34 C35 0.7(6) . . . . ?
C33 C34 C35 C36 -0.9(6) . . . . ?
C34 C35 C36 C31 0.3(5) . . . . ?
C32 C31 C36 C35 0.6(5) . . . . ?
P1 C31 C36 C35 172.8(3) . . . . ?
N1 P1 C41 C46 99.5(3) . . . . ?
C1 P1 C41 C46 -144.1(3) . . . . ?
C31 P1 C41 C46 -25.4(3) . . . . ?
N1 P1 C41 C42 -72.9(3) . . . . ?
C1 P1 C41 C42 43.6(3) . . . . ?
C31 P1 C41 C42 162.2(3) . . . . ?
C46 C41 C42 C43 0.2(5) . . . . ?
P1 C41 C42 C43 172.7(3) . . . . ?
C41 C42 C43 C44 0.2(5) . . . . ?
C42 C43 C44 C45 -0.7(5) . . . . ?
C43 C44 C45 C46 0.7(5) . . . . ?
C44 C45 C46 C41 -0.3(5) . . . . ?
C42 C41 C46 C45 -0.1(5) . . . . ?
P1 C41 C46 C45 -172.5(3) . . . . ?
C21 N2 P2 C1 179.1(2) . . . . ?
Rh1 N2 P2 C1 3.31(17) . . . . ?
C21 N2 P2 C51 62.2(3) . . . . ?
Rh1 N2 P2 C51 -113.59(14) . . . . ?
C21 N2 P2 C61 -60.0(3) . . . . ?
Rh1 N2 P2 C61 124.18(13) . . . . ?
C2 C1 P2 N2 -142.5(3) . . . . ?
P1 C1 P2 N2 63.0(2) . . . . ?
C2 C1 P2 C51 -21.6(3) . . . . ?
P1 C1 P2 C51 -176.15(17) . . . . ?
C2 C1 P2 C61 95.8(3) . . . . ?
P1 C1 P2 C61 -58.7(2) . . . . ?
N2 P2 C51 C52 45.2(3) . . . . ?
C1 P2 C51 C52 -73.0(3) . . . . ?
C61 P2 C51 C52 168.8(3) . . . . ?
N2 P2 C51 C56 -134.1(3) . . . . ?
C1 P2 C51 C56 107.7(3) . . . . ?
C61 P2 C51 C56 -10.6(3) . . . . ?
C56 C51 C52 C53 -0.6(6) . . . . ?
P2 C51 C52 C53 180.0(3) . . . . ?
C51 C52 C53 C54 0.4(6) . . . . ?
C52 C53 C54 C55 0.2(6) . . . . ?
C53 C54 C55 C56 -0.5(6) . . . . ?
C54 C55 C56 C51 0.2(6) . . . . ?
C52 C51 C56 C55 0.3(5) . . . . ?
P2 C51 C56 C55 179.7(3) . . . . ?
N2 P2 C61 C66 1.6(3) . . . . ?
C1 P2 C61 C66 121.5(3) . . . . ?
C51 P2 C61 C66 -122.8(3) . . . . ?
N2 P2 C61 C62 -171.6(2) . . . . ?
C1 P2 C61 C62 -51.7(3) . . . . ?
C51 P2 C61 C62 64.1(3) . . . . ?
C66 C61 C62 C63 1.4(5) . . . . ?
P2 C61 C62 C63 174.6(3) . . . . ?
C61 C62 C63 C64 0.2(5) . . . . ?
C62 C63 C64 C65 -1.1(6) . . . . ?
C63 C64 C65 C66 0.4(6) . . . . ?
C62 C61 C66 C65 -2.1(5) . . . . ?
P2 C61 C66 C65 -175.3(3) . . . . ?
C64 C65 C66 C61 1.3(5) . . . . ?
