#------------------------------------------------------------------------------
#$Date: 2016-02-14 05:40:26 +0100 (dom 14 de feb de 2016) $
#$Revision: 176432 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/42/7004237.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7004237
loop_
_publ_author_name
'MacDonald, Daniel G.'
'Corrigan, John F.'
_publ_section_title
;
 New reagents for the synthesis of a series of ferrocenoyl
 functionalized copper and silver chalcogenolate complexes
;
_journal_issue                   37
_journal_name_full               'Dalton Transactions'
_journal_page_first              5048
_journal_page_last               5053
_journal_paper_doi               10.1039/b804597f
_journal_year                    2008
_chemical_formula_moiety         'C116 H96 Ag4 Fe4 O4 P4 S4, 2(C H2 Cl2)'
_chemical_formula_sum            'C118 H100 Ag4 Cl4 Fe4 O4 P4 S4'
_chemical_formula_weight         2630.78
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     heavy
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                94.993(1)
_cell_angle_beta                 114.451(1)
_cell_angle_gamma                106.023(1)
_cell_formula_units_Z            1
_cell_length_a                   13.8164(3)
_cell_length_b                   14.4554(3)
_cell_length_c                   15.5570(3)
_cell_measurement_reflns_used    19681
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      28.70
_cell_measurement_theta_min      2.04
_cell_volume                     2645.62(10)
_computing_cell_refinement       'DENZO-SMN (Otwinowski & Minor, 1997)'
_computing_data_collection       'COLLECT (Nonius, 1997-2001)'
_computing_data_reduction        DENZO-SMN
_computing_molecular_graphics    'SHELXTL/PC (Sheldrick, 2001)'
_computing_publication_material  SHELXTL/PC
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Nonius Kappa-CCD'
_diffrn_measurement_method       'φ scans, and ω scans with κ offsets'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0733
_diffrn_reflns_av_sigmaI/netI    0.0718
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            47730
_diffrn_reflns_theta_full        28.79
_diffrn_reflns_theta_max         28.79
_diffrn_reflns_theta_min         2.08
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.551
_exptl_absorpt_correction_T_max  0.8603
_exptl_absorpt_correction_T_min  0.8298
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'DENZO-SMN (Otwinowski & Minor, 1997)'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.651
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       blocks
_exptl_crystal_F_000             1324
_exptl_crystal_size_max          0.13
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.10
_refine_diff_density_max         1.893
_refine_diff_density_min         -1.943
_refine_diff_density_rms         0.144
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.045
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     640
_refine_ls_number_reflns         13690
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.045
_refine_ls_R_factor_all          0.0927
_refine_ls_R_factor_gt           0.0548
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0787P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1299
_refine_ls_wR_factor_ref         0.1485
_reflns_number_gt                9155
_reflns_number_total             13690
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            b804597f.txt
_cod_data_source_block           07189d
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_Hall     -P1
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7004237
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.39014(3) 0.30591(2) 0.33404(2) 0.02801(9) Uani 1 1 d . . .
S1 S 0.38163(9) 0.39688(7) 0.47481(8) 0.0273(2) Uani 1 1 d . . .
O1 O 0.5396(3) 0.1779(2) 0.3822(2) 0.0368(7) Uani 1 1 d . . .
Fe1 Fe 0.80282(5) 0.19556(4) 0.36169(4) 0.02856(15) Uani 1 1 d . . .
C1 C 0.7347(4) 0.2566(3) 0.4356(3) 0.0269(9) Uani 1 1 d . . .
C2 C 0.7727(4) 0.1804(3) 0.4777(3) 0.0335(10) Uani 1 1 d . . .
H2A H 0.7242 0.1188 0.4847 0.040 Uiso 1 1 calc R . .
C3 C 0.8901(4) 0.2077(3) 0.5081(3) 0.0384(11) Uani 1 1 d . . .
H3A H 0.9389 0.1684 0.5394 0.046 Uiso 1 1 calc R . .
C4 C 0.9266(4) 0.2995(3) 0.4848(3) 0.0379(11) Uani 1 1 d . . .
H4A H 1.0055 0.3360 0.4967 0.045 Uiso 1 1 calc R . .
C5 C 0.8322(4) 0.3301(3) 0.4413(3) 0.0319(10) Uani 1 1 d . . .
H5A H 0.8331 0.3920 0.4171 0.038 Uiso 1 1 calc R . .
C6 C 0.8302(5) 0.0873(4) 0.2909(3) 0.0438(12) Uani 1 1 d . . .
H6A H 0.8768 0.0465 0.3221 0.053 Uiso 1 1 calc R . .
C7 C 0.8695(5) 0.1781(4) 0.2683(4) 0.0460(12) Uani 1 1 d . . .
H7A H 0.9491 0.2131 0.2809 0.055 Uiso 1 1 calc R . .
C8 C 0.7780(5) 0.2110(4) 0.2257(3) 0.0468(13) Uani 1 1 d . . .
H8A H 0.7811 0.2737 0.2027 0.056 Uiso 1 1 calc R . .
C9 C 0.6800(4) 0.1410(4) 0.2217(3) 0.0450(12) Uani 1 1 d . . .
H9A H 0.6022 0.1451 0.1946 0.054 Uiso 1 1 calc R . .
C10 C 0.7127(5) 0.0644(4) 0.2625(4) 0.0460(13) Uani 1 1 d . . .
H10A H 0.6620 0.0043 0.2696 0.055 Uiso 1 1 calc R . .
C11 C 0.6159(4) 0.2525(3) 0.3917(3) 0.0284(9) Uani 1 1 d . . .
Ag2 Ag 0.62733(3) 0.43129(2) 0.52842(2) 0.03191(10) Uani 1 1 d . . .
S2 S 0.59278(9) 0.36156(7) 0.35920(8) 0.0273(2) Uani 1 1 d . . .
O2 O 0.1643(3) 0.3499(2) 0.4290(3) 0.0439(8) Uani 1 1 d . . .
Fe2 Fe 0.26755(5) 0.21017(4) 0.61807(5) 0.02926(15) Uani 1 1 d . . .
C12 C 0.2368(4) 0.2247(3) 0.4814(3) 0.0281(9) Uani 1 1 d . . .
C13 C 0.1371(4) 0.1595(3) 0.4802(3) 0.0366(11) Uani 1 1 d . . .
H13A H 0.0623 0.1692 0.4574 0.044 Uiso 1 1 calc R . .
C14 C 0.1636(4) 0.0783(3) 0.5177(3) 0.0426(12) Uani 1 1 d . . .
H14A H 0.1108 0.0214 0.5266 0.051 Uiso 1 1 calc R . .
C15 C 0.2782(5) 0.0937(3) 0.5424(4) 0.0434(12) Uani 1 1 d . . .
H15A H 0.3204 0.0491 0.5715 0.052 Uiso 1 1 calc R . .
C16 C 0.3242(4) 0.1840(3) 0.5197(3) 0.0309(9) Uani 1 1 d . . .
H16A H 0.4035 0.2132 0.5291 0.037 Uiso 1 1 calc R . .
C17 C 0.3216(5) 0.3495(3) 0.6997(4) 0.0484(14) Uani 1 1 d . . .
H17A H 0.3322 0.4123 0.6768 0.058 Uiso 1 1 calc R . .
C18 C 0.2203(5) 0.2883(4) 0.6985(4) 0.0587(16) Uani 1 1 d . . .
H18A H 0.1468 0.3006 0.6750 0.070 Uiso 1 1 calc R . .
C19 C 0.2431(5) 0.2079(4) 0.7379(4) 0.0573(16) Uani 1 1 d . . .
H19A H 0.1877 0.1527 0.7461 0.069 Uiso 1 1 calc R . .
C20 C 0.3565(5) 0.2178(4) 0.7632(4) 0.0506(14) Uani 1 1 d . . .
H20A H 0.3958 0.1714 0.7924 0.061 Uiso 1 1 calc R . .
C21 C 0.4038(4) 0.3047(3) 0.7390(3) 0.0409(11) Uani 1 1 d . . .
H21A H 0.4831 0.3302 0.7475 0.049 Uiso 1 1 calc R . .
C22 C 0.2458(4) 0.3224(3) 0.4578(3) 0.0288(9) Uani 1 1 d . . .
P1 P 0.23355(9) 0.18171(7) 0.19649(8) 0.0251(2) Uani 1 1 d . . .
C23 C 0.2729(3) 0.1243(3) 0.1121(3) 0.0279(9) Uani 1 1 d . . .
C24 C 0.3665(4) 0.1787(3) 0.1037(3) 0.0368(11) Uani 1 1 d . . .
H24A H 0.4096 0.2440 0.1424 0.044 Uiso 1 1 calc R . .
C25 C 0.3985(4) 0.1391(4) 0.0392(4) 0.0446(12) Uani 1 1 d . . .
H25A H 0.4612 0.1781 0.0321 0.053 Uiso 1 1 calc R . .
C26 C 0.3388(4) 0.0430(4) -0.0144(3) 0.0425(12) Uani 1 1 d . . .
H26A H 0.3615 0.0150 -0.0572 0.051 Uiso 1 1 calc R . .
C27 C 0.2456(4) -0.0125(3) -0.0055(3) 0.0393(11) Uani 1 1 d . . .
H27A H 0.2039 -0.0786 -0.0427 0.047 Uiso 1 1 calc R . .
C28 C 0.2134(4) 0.0282(3) 0.0573(3) 0.0342(10) Uani 1 1 d . . .
H28A H 0.1493 -0.0104 0.0630 0.041 Uiso 1 1 calc R . .
C29 C 0.1195(3) 0.2230(3) 0.1218(3) 0.0254(8) Uani 1 1 d . . .
C30 C 0.0594(4) 0.1903(3) 0.0215(3) 0.0313(9) Uani 1 1 d . . .
H30A H 0.0821 0.1491 -0.0118 0.038 Uiso 1 1 calc R . .
C31 C -0.0328(4) 0.2171(3) -0.0301(3) 0.0375(11) Uani 1 1 d . . .
H31A H -0.0734 0.1941 -0.0986 0.045 Uiso 1 1 calc R . .
C32 C -0.0668(4) 0.2774(3) 0.0172(4) 0.0406(11) Uani 1 1 d . . .
H32A H -0.1308 0.2952 -0.0186 0.049 Uiso 1 1 calc R . .
C33 C -0.0070(4) 0.3115(3) 0.1169(4) 0.0368(10) Uani 1 1 d . . .
H33A H -0.0298 0.3531 0.1495 0.044 Uiso 1 1 calc R . .
C34 C 0.0865(4) 0.2851(3) 0.1695(3) 0.0309(9) Uani 1 1 d . . .
H34A H 0.1279 0.3093 0.2379 0.037 Uiso 1 1 calc R . .
C35 C 0.1578(3) 0.0752(3) 0.2265(3) 0.0268(9) Uani 1 1 d . . .
C36 C 0.0406(4) 0.0383(3) 0.1872(3) 0.0309(9) Uani 1 1 d . . .
H36A H -0.0035 0.0704 0.1445 0.037 Uiso 1 1 calc R . .
C37 C -0.0124(4) -0.0451(3) 0.2101(3) 0.0375(11) Uani 1 1 d . . .
H37A H -0.0926 -0.0697 0.1835 0.045 Uiso 1 1 calc R . .
C38 C 0.0512(5) -0.0925(3) 0.2717(3) 0.0405(12) Uani 1 1 d . . .
H38A H 0.0145 -0.1502 0.2865 0.049 Uiso 1 1 calc R . .
C39 C 0.1677(4) -0.0564(3) 0.3116(3) 0.0399(11) Uani 1 1 d . . .
H39A H 0.2114 -0.0890 0.3540 0.048 Uiso 1 1 calc R . .
C40 C 0.2207(4) 0.0279(3) 0.2894(3) 0.0337(10) Uani 1 1 d . . .
H40A H 0.3010 0.0533 0.3176 0.040 Uiso 1 1 calc R . .
P2 P 0.71253(9) 0.37806(7) 0.67648(8) 0.0271(2) Uani 1 1 d . . .
C41 C 0.8597(4) 0.3980(3) 0.7061(3) 0.0283(9) Uani 1 1 d . . .
C42 C 0.9137(4) 0.4766(3) 0.6780(3) 0.0364(10) Uani 1 1 d . . .
H42A H 0.8721 0.5141 0.6413 0.044 Uiso 1 1 calc R . .
C43 C 1.0279(5) 0.5010(4) 0.7030(4) 0.0489(13) Uani 1 1 d . . .
H43A H 1.0643 0.5548 0.6833 0.059 Uiso 1 1 calc R . .
C44 C 1.0885(4) 0.4469(4) 0.7566(4) 0.0464(13) Uani 1 1 d . . .
H44A H 1.1670 0.4643 0.7750 0.056 Uiso 1 1 calc R . .
C45 C 1.0359(4) 0.3682(4) 0.7834(4) 0.0442(12) Uani 1 1 d . . .
H45A H 1.0778 0.3304 0.8191 0.053 Uiso 1 1 calc R . .
C46 C 0.9217(4) 0.3433(3) 0.7586(3) 0.0338(10) Uani 1 1 d . . .
H46A H 0.8858 0.2887 0.7777 0.041 Uiso 1 1 calc R . .
C47 C 0.7231(4) 0.4595(3) 0.7787(3) 0.0283(9) Uani 1 1 d . . .
C48 C 0.8118(4) 0.4823(3) 0.8729(3) 0.0339(10) Uani 1 1 d . . .
H48A H 0.8725 0.4581 0.8854 0.041 Uiso 1 1 calc R . .
C49 C 0.8102(4) 0.5407(3) 0.9480(3) 0.0391(11) Uani 1 1 d . . .
H49A H 0.8693 0.5552 1.0122 0.047 Uiso 1 1 calc R . .
C50 C 0.7233(4) 0.5777(3) 0.9299(4) 0.0425(12) Uani 1 1 d . . .
H50A H 0.7237 0.6182 0.9816 0.051 Uiso 1 1 calc R . .
C51 C 0.6359(4) 0.5563(3) 0.8373(4) 0.0407(12) Uani 1 1 d . . .
H51A H 0.5759 0.5813 0.8253 0.049 Uiso 1 1 calc R . .
C52 C 0.6363(4) 0.4980(3) 0.7618(3) 0.0327(10) Uani 1 1 d . . .
H52A H 0.5768 0.4842 0.6978 0.039 Uiso 1 1 calc R . .
C53 C 0.6579(3) 0.2551(3) 0.6953(3) 0.0291(9) Uani 1 1 d . . .
C54 C 0.6656(4) 0.2397(3) 0.7846(3) 0.0380(11) Uani 1 1 d . . .
H54A H 0.6998 0.2947 0.8384 0.046 Uiso 1 1 calc R . .
C55 C 0.6236(4) 0.1446(3) 0.7964(4) 0.0442(12) Uani 1 1 d . . .
H55A H 0.6314 0.1351 0.8582 0.053 Uiso 1 1 calc R . .
C56 C 0.5711(4) 0.0647(3) 0.7186(4) 0.0429(12) Uani 1 1 d . . .
H56A H 0.5419 0.0000 0.7263 0.051 Uiso 1 1 calc R . .
C57 C 0.5613(4) 0.0794(3) 0.6306(4) 0.0469(13) Uani 1 1 d . . .
H57A H 0.5250 0.0241 0.5771 0.056 Uiso 1 1 calc R . .
C58 C 0.6028(4) 0.1730(3) 0.6165(3) 0.0368(11) Uani 1 1 d . . .
H58A H 0.5938 0.1812 0.5541 0.044 Uiso 1 1 calc R . .
C1S C 0.4338(6) 0.6193(5) 1.0064(5) 0.074(2) Uani 1 1 d . . .
H1SA H 0.5139 0.6635 1.0401 0.089 Uiso 1 1 calc R . .
H1SB H 0.4217 0.5749 1.0488 0.089 Uiso 1 1 calc R . .
Cl1 Cl 0.34745(16) 0.69064(14) 0.99032(13) 0.0793(5) Uani 1 1 d . . .
Cl2 Cl 0.40968(17) 0.5492(3) 0.90031(17) 0.1693(16) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Fe Fe 0.3463 0.8444 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Ag1 S1 126.55(4) . . ?
P1 Ag1 S2 124.03(4) . . ?
S1 Ag1 S2 109.40(3) . . ?
P1 Ag1 Ag2 166.24(3) . . ?
S1 Ag1 Ag2 61.18(3) . . ?
S2 Ag1 Ag2 49.65(2) . . ?
C22 S1 Ag1 100.20(13) . . ?
C22 S1 Ag2 105.20(14) . 2_666 ?
Ag1 S1 Ag2 117.55(4) . 2_666 ?
C2 Fe1 C10 107.08(19) . . ?
C2 Fe1 C9 123.3(2) . . ?
C10 Fe1 C9 40.6(2) . . ?
C2 Fe1 C1 41.49(16) . . ?
C10 Fe1 C1 121.48(19) . . ?
C9 Fe1 C1 106.63(18) . . ?
C2 Fe1 C8 160.4(2) . . ?
C10 Fe1 C8 68.2(2) . . ?
C9 Fe1 C8 40.8(2) . . ?
C1 Fe1 C8 123.40(19) . . ?
C2 Fe1 C6 122.12(19) . . ?
C10 Fe1 C6 40.9(2) . . ?
C9 Fe1 C6 68.3(2) . . ?
C1 Fe1 C6 158.09(19) . . ?
C8 Fe1 C6 67.6(2) . . ?
C2 Fe1 C7 157.8(2) . . ?
C10 Fe1 C7 68.4(2) . . ?
C9 Fe1 C7 68.3(2) . . ?
C1 Fe1 C7 159.6(2) . . ?
C8 Fe1 C7 40.0(2) . . ?
C6 Fe1 C7 40.29(19) . . ?
C2 Fe1 C5 68.65(18) . . ?
C10 Fe1 C5 157.9(2) . . ?
C9 Fe1 C5 122.3(2) . . ?
C1 Fe1 C5 40.92(16) . . ?
C8 Fe1 C5 108.1(2) . . ?
C6 Fe1 C5 159.8(2) . . ?
C7 Fe1 C5 123.80(19) . . ?
C2 Fe1 C3 40.42(18) . . ?
C10 Fe1 C3 123.7(2) . . ?
C9 Fe1 C3 159.8(2) . . ?
C1 Fe1 C3 68.85(17) . . ?
C8 Fe1 C3 157.9(2) . . ?
C6 Fe1 C3 108.1(2) . . ?
C7 Fe1 C3 122.7(2) . . ?
C5 Fe1 C3 67.98(18) . . ?
C2 Fe1 C4 68.22(19) . . ?
C10 Fe1 C4 160.2(2) . . ?
C9 Fe1 C4 158.0(2) . . ?
C1 Fe1 C4 68.62(17) . . ?
C8 Fe1 C4 122.6(2) . . ?
C6 Fe1 C4 124.0(2) . . ?
C7 Fe1 C4 108.3(2) . . ?
C5 Fe1 C4 40.22(17) . . ?
C3 Fe1 C4 40.40(18) . . ?
C5 C1 C2 106.5(4) . . ?
C5 C1 C11 128.9(4) . . ?
C2 C1 C11 124.5(4) . . ?
C5 C1 Fe1 70.0(2) . . ?
C2 C1 Fe1 68.8(2) . . ?
C11 C1 Fe1 123.6(3) . . ?
C3 C2 C1 108.4(4) . . ?
C3 C2 Fe1 70.7(3) . . ?
C1 C2 Fe1 69.7(2) . . ?
C3 C2 H2A 125.8 . . ?
C1 C2 H2A 125.8 . . ?
Fe1 C2 H2A 125.8 . . ?
C2 C3 C4 108.1(4) . . ?
C2 C3 Fe1 68.9(3) . . ?
C4 C3 Fe1 69.9(3) . . ?
C2 C3 H3A 125.9 . . ?
C4 C3 H3A 125.9 . . ?
Fe1 C3 H3A 125.9 . . ?
C5 C4 C3 108.3(4) . . ?
C5 C4 Fe1 69.8(2) . . ?
C3 C4 Fe1 69.7(2) . . ?
C5 C4 H4A 125.8 . . ?
C3 C4 H4A 125.8 . . ?
Fe1 C4 H4A 125.8 . . ?
C4 C5 C1 108.6(4) . . ?
C4 C5 Fe1 70.0(2) . . ?
C1 C5 Fe1 69.1(2) . . ?
C4 C5 H5A 125.7 . . ?
C1 C5 H5A 125.7 . . ?
Fe1 C5 H5A 125.7 . . ?
C7 C6 C10 108.1(5) . . ?
C7 C6 Fe1 70.1(3) . . ?
C10 C6 Fe1 69.1(3) . . ?
C7 C6 H6A 126.0 . . ?
C10 C6 H6A 126.0 . . ?
Fe1 C6 H6A 126.0 . . ?
C8 C7 C6 108.1(5) . . ?
C8 C7 Fe1 69.7(3) . . ?
C6 C7 Fe1 69.6(3) . . ?
C8 C7 H7A 126.0 . . ?
C6 C7 H7A 126.0 . . ?
Fe1 C7 H7A 126.0 . . ?
C7 C8 C9 108.7(5) . . ?
C7 C8 Fe1 70.3(3) . . ?
C9 C8 Fe1 69.4(3) . . ?
C7 C8 H8A 125.7 . . ?
C9 C8 H8A 125.7 . . ?
Fe1 C8 H8A 125.7 . . ?
C10 C9 C8 107.3(5) . . ?
C10 C9 Fe1 69.4(3) . . ?
C8 C9 Fe1 69.8(3) . . ?
C10 C9 H9A 126.3 . . ?
C8 C9 H9A 126.3 . . ?
Fe1 C9 H9A 126.3 . . ?
C9 C10 C6 107.9(5) . . ?
C9 C10 Fe1 69.9(3) . . ?
C6 C10 Fe1 70.0(3) . . ?
C9 C10 H10A 126.1 . . ?
C6 C10 H10A 126.1 . . ?
Fe1 C10 H10A 126.1 . . ?
O1 C11 C1 120.7(4) . . ?
O1 C11 S2 123.3(3) . . ?
C1 C11 S2 116.0(3) . . ?
P2 Ag2 S1 123.45(4) . 2_666 ?
P2 Ag2 S2 129.10(4) . . ?
S1 Ag2 S2 104.50(3) 2_666 . ?
P2 Ag2 Ag1 127.08(3) . . ?
S1 Ag2 Ag1 99.30(3) 2_666 . ?
S2 Ag2 Ag1 49.80(2) . . ?
C11 S2 Ag2 91.50(13) . . ?
C11 S2 Ag1 94.50(14) . . ?
Ag2 S2 Ag1 80.55(3) . . ?
C18 Fe2 C19 40.7(2) . . ?
C18 Fe2 C12 121.4(2) . . ?
C19 Fe2 C12 158.0(2) . . ?
C18 Fe2 C16 156.8(2) . . ?
C19 Fe2 C16 160.4(2) . . ?
C12 Fe2 C16 40.88(17) . . ?
C18 Fe2 C21 68.3(2) . . ?
C19 Fe2 C21 67.8(2) . . ?
C12 Fe2 C21 123.02(18) . . ?
C16 Fe2 C21 106.68(19) . . ?
C18 Fe2 C17 41.1(2) . . ?
C19 Fe2 C17 68.4(2) . . ?
C12 Fe2 C17 106.43(19) . . ?
C16 Fe2 C17 120.43(19) . . ?
C21 Fe2 C17 40.4(2) . . ?
C18 Fe2 C15 161.0(2) . . ?
C19 Fe2 C15 124.6(2) . . ?
C12 Fe2 C15 68.61(18) . . ?
C16 Fe2 C15 40.95(17) . . ?
C21 Fe2 C15 121.9(2) . . ?
C17 Fe2 C15 156.7(2) . . ?
C18 Fe2 C13 107.7(2) . . ?
C19 Fe2 C13 122.8(2) . . ?
C12 Fe2 C13 41.09(16) . . ?
C16 Fe2 C13 68.87(18) . . ?
C21 Fe2 C13 160.13(19) . . ?
C17 Fe2 C13 123.9(2) . . ?
C15 Fe2 C13 68.3(2) . . ?
C18 Fe2 C20 68.5(2) . . ?
C19 Fe2 C20 40.4(2) . . ?
C12 Fe2 C20 159.5(2) . . ?
C16 Fe2 C20 123.3(2) . . ?
C21 Fe2 C20 40.28(19) . . ?
C17 Fe2 C20 68.3(2) . . ?
C15 Fe2 C20 108.0(2) . . ?
C13 Fe2 C20 158.23(19) . . ?
C18 Fe2 C14 124.8(2) . . ?
C19 Fe2 C14 109.0(2) . . ?
C12 Fe2 C14 68.60(17) . . ?
C16 Fe2 C14 68.51(18) . . ?
C21 Fe2 C14 157.6(2) . . ?
C17 Fe2 C14 161.1(2) . . ?
C15 Fe2 C14 40.2(2) . . ?
C13 Fe2 C14 40.59(19) . . ?
C20 Fe2 C14 122.7(2) . . ?
C16 C12 C13 108.1(4) . . ?
C16 C12 C22 128.0(4) . . ?
C13 C12 C22 123.5(4) . . ?
C16 C12 Fe2 69.8(2) . . ?
C13 C12 Fe2 70.0(2) . . ?
C22 C12 Fe2 120.0(3) . . ?
C14 C13 C12 107.8(4) . . ?
C14 C13 Fe2 70.3(3) . . ?
C12 C13 Fe2 68.9(2) . . ?
C14 C13 H13A 126.1 . . ?
C12 C13 H13A 126.1 . . ?
Fe2 C13 H13A 126.1 . . ?
C15 C14 C13 108.0(4) . . ?
C15 C14 Fe2 69.2(3) . . ?
C13 C14 Fe2 69.1(2) . . ?
C15 C14 H14A 126.0 . . ?
C13 C14 H14A 126.0 . . ?
Fe2 C14 H14A 126.0 . . ?
C14 C15 C16 108.7(4) . . ?
C14 C15 Fe2 70.5(3) . . ?
C16 C15 Fe2 69.3(2) . . ?
C14 C15 H15A 125.7 . . ?
C16 C15 H15A 125.7 . . ?
Fe2 C15 H15A 125.7 . . ?
C12 C16 C15 107.4(4) . . ?
C12 C16 Fe2 69.3(2) . . ?
C15 C16 Fe2 69.8(3) . . ?
C12 C16 H16A 126.3 . . ?
C15 C16 H16A 126.3 . . ?
Fe2 C16 H16A 126.3 . . ?
C21 C17 C18 107.2(5) . . ?
C21 C17 Fe2 69.7(3) . . ?
C18 C17 Fe2 68.9(3) . . ?
C21 C17 H17A 126.4 . . ?
C18 C17 H17A 126.4 . . ?
Fe2 C17 H17A 126.4 . . ?
C19 C18 C17 107.5(5) . . ?
C19 C18 Fe2 69.8(3) . . ?
C17 C18 Fe2 70.0(3) . . ?
C19 C18 H18A 126.2 . . ?
C17 C18 H18A 126.2 . . ?
Fe2 C18 H18A 126.2 . . ?
C18 C19 C20 108.8(5) . . ?
C18 C19 Fe2 69.5(3) . . ?
C20 C19 Fe2 70.6(3) . . ?
C18 C19 H19A 125.6 . . ?
C20 C19 H19A 125.6 . . ?
Fe2 C19 H19A 125.6 . . ?
C21 C20 C19 107.1(5) . . ?
C21 C20 Fe2 69.3(3) . . ?
C19 C20 Fe2 68.9(3) . . ?
C21 C20 H20A 126.4 . . ?
C19 C20 H20A 126.4 . . ?
Fe2 C20 H20A 126.4 . . ?
C20 C21 C17 109.3(5) . . ?
C20 C21 Fe2 70.4(3) . . ?
C17 C21 Fe2 70.0(3) . . ?
C20 C21 H21A 125.4 . . ?
C17 C21 H21A 125.4 . . ?
Fe2 C21 H21A 125.4 . . ?
O2 C22 C12 121.1(4) . . ?
O2 C22 S1 122.6(3) . . ?
C12 C22 S1 116.3(3) . . ?
C29 P1 C35 101.96(18) . . ?
C29 P1 C23 105.44(19) . . ?
C35 P1 C23 102.62(18) . . ?
C29 P1 Ag1 115.49(12) . . ?
C35 P1 Ag1 115.08(14) . . ?
C23 P1 Ag1 114.61(13) . . ?
C24 C23 C28 118.7(4) . . ?
C24 C23 P1 118.6(3) . . ?
C28 C23 P1 122.7(3) . . ?
C23 C24 C25 120.8(4) . . ?
C23 C24 H24A 119.6 . . ?
C25 C24 H24A 119.6 . . ?
C26 C25 C24 119.8(4) . . ?
C26 C25 H25A 120.1 . . ?
C24 C25 H25A 120.1 . . ?
C25 C26 C27 119.7(4) . . ?
C25 C26 H26A 120.1 . . ?
C27 C26 H26A 120.1 . . ?
C28 C27 C26 119.9(4) . . ?
C28 C27 H27A 120.0 . . ?
C26 C27 H27A 120.0 . . ?
C27 C28 C23 121.0(4) . . ?
C27 C28 H28A 119.5 . . ?
C23 C28 H28A 119.5 . . ?
C30 C29 C34 119.1(4) . . ?
C30 C29 P1 123.2(3) . . ?
C34 C29 P1 117.5(3) . . ?
C31 C30 C29 120.4(4) . . ?
C31 C30 H30A 119.8 . . ?
C29 C30 H30A 119.8 . . ?
C30 C31 C32 120.6(4) . . ?
C30 C31 H31A 119.7 . . ?
C32 C31 H31A 119.7 . . ?
C33 C32 C31 119.7(4) . . ?
C33 C32 H32A 120.2 . . ?
C31 C32 H32A 120.2 . . ?
C32 C33 C34 120.2(4) . . ?
C32 C33 H33A 119.9 . . ?
C34 C33 H33A 119.9 . . ?
C33 C34 C29 120.0(4) . . ?
C33 C34 H34A 120.0 . . ?
C29 C34 H34A 120.0 . . ?
C40 C35 C36 119.0(4) . . ?
C40 C35 P1 118.0(3) . . ?
C36 C35 P1 122.9(3) . . ?
C37 C36 C35 120.3(4) . . ?
C37 C36 H36A 119.9 . . ?
C35 C36 H36A 119.9 . . ?
C38 C37 C36 120.1(4) . . ?
C38 C37 H37A 119.9 . . ?
C36 C37 H37A 119.9 . . ?
C39 C38 C37 120.2(4) . . ?
C39 C38 H38A 119.9 . . ?
C37 C38 H38A 119.9 . . ?
C38 C39 C40 119.6(5) . . ?
C38 C39 H39A 120.2 . . ?
C40 C39 H39A 120.2 . . ?
C35 C40 C39 120.8(4) . . ?
C35 C40 H40A 119.6 . . ?
C39 C40 H40A 119.6 . . ?
C41 P2 C47 103.21(19) . . ?
C41 P2 C53 105.55(19) . . ?
C47 P2 C53 102.54(18) . . ?
C41 P2 Ag2 108.29(14) . . ?
C47 P2 Ag2 110.38(14) . . ?
C53 P2 Ag2 124.78(15) . . ?
C42 C41 C46 118.8(4) . . ?
C42 C41 P2 116.8(3) . . ?
C46 C41 P2 124.3(3) . . ?
C43 C42 C41 120.6(5) . . ?
C43 C42 H42A 119.7 . . ?
C41 C42 H42A 119.7 . . ?
C44 C43 C42 119.6(5) . . ?
C44 C43 H43A 120.2 . . ?
C42 C43 H43A 120.2 . . ?
C45 C44 C43 120.3(5) . . ?
C45 C44 H44A 119.8 . . ?
C43 C44 H44A 119.8 . . ?
C44 C45 C46 120.3(5) . . ?
C44 C45 H45A 119.8 . . ?
C46 C45 H45A 119.8 . . ?
C45 C46 C41 120.2(4) . . ?
C45 C46 H46A 119.9 . . ?
C41 C46 H46A 119.9 . . ?
C52 C47 C48 119.2(4) . . ?
C52 C47 P2 117.7(3) . . ?
C48 C47 P2 123.1(3) . . ?
C49 C48 C47 119.5(4) . . ?
C49 C48 H48A 120.3 . . ?
C47 C48 H48A 120.3 . . ?
C50 C49 C48 120.5(5) . . ?
C50 C49 H49A 119.7 . . ?
C48 C49 H49A 119.7 . . ?
C51 C50 C49 120.5(4) . . ?
C51 C50 H50A 119.8 . . ?
C49 C50 H50A 119.8 . . ?
C50 C51 C52 119.6(5) . . ?
C50 C51 H51A 120.2 . . ?
C52 C51 H51A 120.2 . . ?
C51 C52 C47 120.7(4) . . ?
C51 C52 H52A 119.6 . . ?
C47 C52 H52A 119.6 . . ?
C54 C53 C58 118.1(4) . . ?
C54 C53 P2 122.5(3) . . ?
C58 C53 P2 119.3(3) . . ?
C53 C54 C55 120.9(4) . . ?
C53 C54 H54A 119.6 . . ?
C55 C54 H54A 119.6 . . ?
C56 C55 C54 120.2(5) . . ?
C56 C55 H55A 119.9 . . ?
C54 C55 H55A 119.9 . . ?
C57 C56 C55 119.2(4) . . ?
C57 C56 H56A 120.4 . . ?
C55 C56 H56A 120.4 . . ?
C56 C57 C58 122.1(4) . . ?
C56 C57 H57A 119.0 . . ?
C58 C57 H57A 119.0 . . ?
C57 C58 C53 119.5(4) . . ?
C57 C58 H58A 120.3 . . ?
C53 C58 H58A 120.3 . . ?
Cl2 C1S Cl1 113.7(4) . . ?
Cl2 C1S H1SA 108.8 . . ?
Cl1 C1S H1SA 108.8 . . ?
Cl2 C1S H1SB 108.8 . . ?
Cl1 C1S H1SB 108.8 . . ?
H1SA C1S H1SB 107.7 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 P1 2.4162(11) . ?
Ag1 S1 2.5171(10) . ?
Ag1 S2 2.5364(11) . ?
Ag1 Ag2 3.2760(5) . ?
S1 C22 1.782(4) . ?
S1 Ag2 2.5245(10) 2_666 ?
O1 C11 1.230(5) . ?
Fe1 C2 2.030(4) . ?
Fe1 C10 2.030(5) . ?
Fe1 C9 2.037(5) . ?
Fe1 C1 2.041(4) . ?
Fe1 C8 2.041(5) . ?
Fe1 C6 2.043(4) . ?
Fe1 C7 2.048(4) . ?
Fe1 C5 2.052(4) . ?
Fe1 C3 2.053(5) . ?
Fe1 C4 2.054(4) . ?
C1 C5 1.431(6) . ?
C1 C2 1.442(6) . ?
C1 C11 1.475(6) . ?
C2 C3 1.411(6) . ?
C2 H2A 1.0000 . ?
C3 C4 1.418(6) . ?
C3 H3A 1.0000 . ?
C4 C5 1.412(6) . ?
C4 H4A 1.0000 . ?
C5 H5A 1.0000 . ?
C6 C7 1.409(7) . ?
C6 C10 1.422(7) . ?
C6 H6A 1.0000 . ?
C7 C8 1.399(7) . ?
C7 H7A 1.0000 . ?
C8 C9 1.423(7) . ?
C8 H8A 1.0000 . ?
C9 C10 1.413(7) . ?
C9 H9A 1.0000 . ?
C10 H10A 1.0000 . ?
C11 S2 1.767(4) . ?
Ag2 P2 2.4181(11) . ?
Ag2 S1 2.5245(10) 2_666 ?
Ag2 S2 2.5310(11) . ?
O2 C22 1.220(5) . ?
Fe2 C18 2.026(5) . ?
Fe2 C19 2.029(5) . ?
Fe2 C12 2.030(4) . ?
Fe2 C16 2.037(4) . ?
Fe2 C21 2.037(5) . ?
Fe2 C17 2.041(4) . ?
Fe2 C15 2.044(4) . ?
Fe2 C13 2.045(5) . ?
Fe2 C20 2.051(5) . ?
Fe2 C14 2.061(4) . ?
C12 C16 1.421(6) . ?
C12 C13 1.430(6) . ?
C12 C22 1.475(6) . ?
C13 C14 1.424(7) . ?
C13 H13A 1.0000 . ?
C14 C15 1.412(7) . ?
C14 H14A 1.0000 . ?
C15 C16 1.428(6) . ?
C15 H15A 1.0000 . ?
C16 H16A 1.0000 . ?
C17 C21 1.408(7) . ?
C17 C18 1.427(7) . ?
C17 H17A 1.0000 . ?
C18 C19 1.411(8) . ?
C18 H18A 1.0000 . ?
C19 C20 1.410(8) . ?
C19 H19A 1.0000 . ?
C20 C21 1.408(7) . ?
C20 H20A 1.0000 . ?
C21 H21A 1.0000 . ?
P1 C29 1.820(4) . ?
P1 C35 1.823(4) . ?
P1 C23 1.833(4) . ?
C23 C24 1.380(6) . ?
C23 C28 1.384(5) . ?
C24 C25 1.392(6) . ?
C24 H24A 0.9500 . ?
C25 C26 1.379(7) . ?
C25 H25A 0.9500 . ?
C26 C27 1.384(7) . ?
C26 H26A 0.9500 . ?
C27 C28 1.380(6) . ?
C27 H27A 0.9500 . ?
C28 H28A 0.9500 . ?
C29 C30 1.390(6) . ?
C29 C34 1.398(5) . ?
C30 C31 1.378(6) . ?
C30 H30A 0.9500 . ?
C31 C32 1.387(6) . ?
C31 H31A 0.9500 . ?
C32 C33 1.382(7) . ?
C32 H32A 0.9500 . ?
C33 C34 1.391(6) . ?
C33 H33A 0.9500 . ?
C34 H34A 0.9500 . ?
C35 C40 1.387(6) . ?
C35 C36 1.389(6) . ?
C36 C37 1.385(6) . ?
C36 H36A 0.9500 . ?
C37 C38 1.383(7) . ?
C37 H37A 0.9500 . ?
C38 C39 1.379(7) . ?
C38 H38A 0.9500 . ?
C39 C40 1.390(6) . ?
C39 H39A 0.9500 . ?
C40 H40A 0.9500 . ?
P2 C41 1.819(4) . ?
P2 C47 1.823(4) . ?
P2 C53 1.830(4) . ?
C41 C42 1.389(6) . ?
C41 C46 1.390(6) . ?
C42 C43 1.388(7) . ?
C42 H42A 0.9500 . ?
C43 C44 1.381(8) . ?
C43 H43A 0.9500 . ?
C44 C45 1.367(7) . ?
C44 H44A 0.9500 . ?
C45 C46 1.388(6) . ?
C45 H45A 0.9500 . ?
C46 H46A 0.9500 . ?
C47 C52 1.397(6) . ?
C47 C48 1.401(6) . ?
C48 C49 1.391(6) . ?
C48 H48A 0.9500 . ?
C49 C50 1.381(7) . ?
C49 H49A 0.9500 . ?
C50 C51 1.381(7) . ?
C50 H50A 0.9500 . ?
C51 C52 1.387(6) . ?
C51 H51A 0.9500 . ?
C52 H52A 0.9500 . ?
C53 C54 1.392(6) . ?
C53 C58 1.402(6) . ?
C54 C55 1.397(6) . ?
C54 H54A 0.9500 . ?
C55 C56 1.375(6) . ?
C55 H55A 0.9500 . ?
C56 C57 1.361(7) . ?
C56 H56A 0.9500 . ?
C57 C58 1.390(6) . ?
C57 H57A 0.9500 . ?
C58 H58A 0.9500 . ?
C1S Cl2 1.711(6) . ?
C1S Cl1 1.740(7) . ?
C1S H1SA 0.9900 . ?
C1S H1SB 0.9900 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
P1 Ag1 S1 C22 14.19(15) . . . . ?
S2 Ag1 S1 C22 -164.51(14) . . . . ?
Ag2 Ag1 S1 C22 -152.25(15) . . . . ?
P1 Ag1 S1 Ag2 -99.04(5) . . . 2_666 ?
S2 Ag1 S1 Ag2 82.27(5) . . . 2_666 ?
Ag2 Ag1 S1 Ag2 94.53(4) . . . 2_666 ?
C2 Fe1 C1 C5 117.7(4) . . . . ?
C10 Fe1 C1 C5 -162.2(3) . . . . ?
C9 Fe1 C1 C5 -120.4(3) . . . . ?
C8 Fe1 C1 C5 -78.9(3) . . . . ?
C6 Fe1 C1 C5 166.4(5) . . . . ?
C7 Fe1 C1 C5 -48.2(6) . . . . ?
C3 Fe1 C1 C5 80.4(3) . . . . ?
C4 Fe1 C1 C5 36.9(3) . . . . ?
C10 Fe1 C1 C2 80.1(3) . . . . ?
C9 Fe1 C1 C2 121.8(3) . . . . ?
C8 Fe1 C1 C2 163.4(3) . . . . ?
C6 Fe1 C1 C2 48.7(6) . . . . ?
C7 Fe1 C1 C2 -165.9(5) . . . . ?
C5 Fe1 C1 C2 -117.7(4) . . . . ?
C3 Fe1 C1 C2 -37.4(3) . . . . ?
C4 Fe1 C1 C2 -80.9(3) . . . . ?
C2 Fe1 C1 C11 -118.2(4) . . . . ?
C10 Fe1 C1 C11 -38.1(4) . . . . ?
C9 Fe1 C1 C11 3.7(4) . . . . ?
C8 Fe1 C1 C11 45.2(4) . . . . ?
C6 Fe1 C1 C11 -69.5(7) . . . . ?
C7 Fe1 C1 C11 75.9(7) . . . . ?
C5 Fe1 C1 C11 124.1(5) . . . . ?
C3 Fe1 C1 C11 -155.5(4) . . . . ?
C4 Fe1 C1 C11 161.0(4) . . . . ?
C5 C1 C2 C3 0.1(5) . . . . ?
C11 C1 C2 C3 177.3(4) . . . . ?
Fe1 C1 C2 C3 60.3(3) . . . . ?
C5 C1 C2 Fe1 -60.1(3) . . . . ?
C11 C1 C2 Fe1 117.0(4) . . . . ?
C10 Fe1 C2 C3 122.3(3) . . . . ?
C9 Fe1 C2 C3 163.9(3) . . . . ?
C1 Fe1 C2 C3 -119.2(4) . . . . ?
C8 Fe1 C2 C3 -164.7(5) . . . . ?
C6 Fe1 C2 C3 80.1(3) . . . . ?
C7 Fe1 C2 C3 47.9(6) . . . . ?
C5 Fe1 C2 C3 -80.7(3) . . . . ?
C4 Fe1 C2 C3 -37.3(3) . . . . ?
C10 Fe1 C2 C1 -118.5(3) . . . . ?
C9 Fe1 C2 C1 -76.9(3) . . . . ?
C8 Fe1 C2 C1 -45.6(7) . . . . ?
C6 Fe1 C2 C1 -160.7(3) . . . . ?
C7 Fe1 C2 C1 167.0(5) . . . . ?
C5 Fe1 C2 C1 38.5(2) . . . . ?
C3 Fe1 C2 C1 119.2(4) . . . . ?
C4 Fe1 C2 C1 81.9(3) . . . . ?
C1 C2 C3 C4 -0.6(5) . . . . ?
Fe1 C2 C3 C4 59.0(3) . . . . ?
C1 C2 C3 Fe1 -59.6(3) . . . . ?
C10 Fe1 C3 C2 -76.2(3) . . . . ?
C9 Fe1 C3 C2 -42.3(7) . . . . ?
C1 Fe1 C3 C2 38.3(3) . . . . ?
C8 Fe1 C3 C2 166.4(5) . . . . ?
C6 Fe1 C3 C2 -118.6(3) . . . . ?
C7 Fe1 C3 C2 -160.6(3) . . . . ?
C5 Fe1 C3 C2 82.5(3) . . . . ?
C4 Fe1 C3 C2 119.8(4) . . . . ?
C2 Fe1 C3 C4 -119.8(4) . . . . ?
C10 Fe1 C3 C4 164.0(3) . . . . ?
C9 Fe1 C3 C4 -162.1(5) . . . . ?
C1 Fe1 C3 C4 -81.5(3) . . . . ?
C8 Fe1 C3 C4 46.6(6) . . . . ?
C6 Fe1 C3 C4 121.6(3) . . . . ?
C7 Fe1 C3 C4 79.7(3) . . . . ?
C5 Fe1 C3 C4 -37.3(3) . . . . ?
C2 C3 C4 C5 0.9(5) . . . . ?
Fe1 C3 C4 C5 59.3(3) . . . . ?
C2 C3 C4 Fe1 -58.4(3) . . . . ?
C2 Fe1 C4 C5 -82.3(3) . . . . ?
C10 Fe1 C4 C5 -162.1(5) . . . . ?
C9 Fe1 C4 C5 44.0(6) . . . . ?
C1 Fe1 C4 C5 -37.5(3) . . . . ?
C8 Fe1 C4 C5 79.3(3) . . . . ?
C6 Fe1 C4 C5 162.8(3) . . . . ?
C7 Fe1 C4 C5 121.1(3) . . . . ?
C3 Fe1 C4 C5 -119.6(4) . . . . ?
C2 Fe1 C4 C3 37.3(3) . . . . ?
C10 Fe1 C4 C3 -42.6(7) . . . . ?
C9 Fe1 C4 C3 163.5(5) . . . . ?
C1 Fe1 C4 C3 82.1(3) . . . . ?
C8 Fe1 C4 C3 -161.1(3) . . . . ?
C6 Fe1 C4 C3 -77.6(3) . . . . ?
C7 Fe1 C4 C3 -119.4(3) . . . . ?
C5 Fe1 C4 C3 119.6(4) . . . . ?
C3 C4 C5 C1 -0.8(5) . . . . ?
Fe1 C4 C5 C1 58.5(3) . . . . ?
C3 C4 C5 Fe1 -59.3(3) . . . . ?
C2 C1 C5 C4 0.4(5) . . . . ?
C11 C1 C5 C4 -176.6(4) . . . . ?
Fe1 C1 C5 C4 -59.0(3) . . . . ?
C2 C1 C5 Fe1 59.4(3) . . . . ?
C11 C1 C5 Fe1 -117.5(4) . . . . ?
C2 Fe1 C5 C4 81.1(3) . . . . ?
C10 Fe1 C5 C4 164.0(5) . . . . ?
C9 Fe1 C5 C4 -162.1(3) . . . . ?
C1 Fe1 C5 C4 120.1(4) . . . . ?
C8 Fe1 C5 C4 -119.4(3) . . . . ?
C6 Fe1 C5 C4 -45.1(7) . . . . ?
C7 Fe1 C5 C4 -78.1(3) . . . . ?
C3 Fe1 C5 C4 37.5(3) . . . . ?
C2 Fe1 C5 C1 -39.0(3) . . . . ?
C10 Fe1 C5 C1 43.8(6) . . . . ?
C9 Fe1 C5 C1 77.8(3) . . . . ?
C8 Fe1 C5 C1 120.5(3) . . . . ?
C6 Fe1 C5 C1 -165.3(5) . . . . ?
C7 Fe1 C5 C1 161.8(3) . . . . ?
C3 Fe1 C5 C1 -82.7(3) . . . . ?
C4 Fe1 C5 C1 -120.1(4) . . . . ?
C2 Fe1 C6 C7 -161.8(3) . . . . ?
C10 Fe1 C6 C7 119.4(5) . . . . ?
C9 Fe1 C6 C7 81.5(3) . . . . ?
C1 Fe1 C6 C7 162.2(5) . . . . ?
C8 Fe1 C6 C7 37.3(3) . . . . ?
C5 Fe1 C6 C7 -44.3(7) . . . . ?
C3 Fe1 C6 C7 -119.6(3) . . . . ?
C4 Fe1 C6 C7 -77.9(4) . . . . ?
C2 Fe1 C6 C10 78.7(4) . . . . ?
C9 Fe1 C6 C10 -37.9(3) . . . . ?
C1 Fe1 C6 C10 42.8(7) . . . . ?
C8 Fe1 C6 C10 -82.1(3) . . . . ?
C7 Fe1 C6 C10 -119.4(5) . . . . ?
C5 Fe1 C6 C10 -163.8(5) . . . . ?
C3 Fe1 C6 C10 121.0(3) . . . . ?
C4 Fe1 C6 C10 162.7(3) . . . . ?
C10 C6 C7 C8 -0.5(5) . . . . ?
Fe1 C6 C7 C8 -59.3(3) . . . . ?
C10 C6 C7 Fe1 58.8(3) . . . . ?
C2 Fe1 C7 C8 163.7(5) . . . . ?
C10 Fe1 C7 C8 81.5(3) . . . . ?
C9 Fe1 C7 C8 37.6(3) . . . . ?
C1 Fe1 C7 C8 -41.5(7) . . . . ?
C6 Fe1 C7 C8 119.3(5) . . . . ?
C5 Fe1 C7 C8 -77.5(4) . . . . ?
C3 Fe1 C7 C8 -161.4(3) . . . . ?
C4 Fe1 C7 C8 -119.3(3) . . . . ?
C2 Fe1 C7 C6 44.4(7) . . . . ?
C10 Fe1 C7 C6 -37.8(3) . . . . ?
C9 Fe1 C7 C6 -81.7(3) . . . . ?
C1 Fe1 C7 C6 -160.9(5) . . . . ?
C8 Fe1 C7 C6 -119.3(5) . . . . ?
C5 Fe1 C7 C6 163.1(3) . . . . ?
C3 Fe1 C7 C6 79.2(4) . . . . ?
C4 Fe1 C7 C6 121.4(3) . . . . ?
C6 C7 C8 C9 0.3(5) . . . . ?
Fe1 C7 C8 C9 -59.0(3) . . . . ?
C6 C7 C8 Fe1 59.3(3) . . . . ?
C2 Fe1 C8 C7 -161.5(5) . . . . ?
C10 Fe1 C8 C7 -81.8(3) . . . . ?
C9 Fe1 C8 C7 -119.9(4) . . . . ?
C1 Fe1 C8 C7 163.9(3) . . . . ?
C6 Fe1 C8 C7 -37.6(3) . . . . ?
C5 Fe1 C8 C7 121.4(3) . . . . ?
C3 Fe1 C8 C7 45.5(6) . . . . ?
C4 Fe1 C8 C7 79.5(3) . . . . ?
C2 Fe1 C8 C9 -41.7(7) . . . . ?
C10 Fe1 C8 C9 38.0(3) . . . . ?
C1 Fe1 C8 C9 -76.2(3) . . . . ?
C6 Fe1 C8 C9 82.3(3) . . . . ?
C7 Fe1 C8 C9 119.9(4) . . . . ?
C5 Fe1 C8 C9 -118.8(3) . . . . ?
C3 Fe1 C8 C9 165.3(5) . . . . ?
C4 Fe1 C8 C9 -160.6(3) . . . . ?
C7 C8 C9 C10 0.0(5) . . . . ?
Fe1 C8 C9 C10 -59.5(3) . . . . ?
C7 C8 C9 Fe1 59.5(3) . . . . ?
C2 Fe1 C9 C10 -76.9(3) . . . . ?
C1 Fe1 C9 C10 -119.3(3) . . . . ?
C8 Fe1 C9 C10 118.5(4) . . . . ?
C6 Fe1 C9 C10 38.1(3) . . . . ?
C7 Fe1 C9 C10 81.7(3) . . . . ?
C5 Fe1 C9 C10 -161.2(3) . . . . ?
C3 Fe1 C9 C10 -45.5(7) . . . . ?
C4 Fe1 C9 C10 166.8(4) . . . . ?
C2 Fe1 C9 C8 164.5(3) . . . . ?
C10 Fe1 C9 C8 -118.5(4) . . . . ?
C1 Fe1 C9 C8 122.2(3) . . . . ?
C6 Fe1 C9 C8 -80.4(3) . . . . ?
C7 Fe1 C9 C8 -36.9(3) . . . . ?
C5 Fe1 C9 C8 80.3(3) . . . . ?
C3 Fe1 C9 C8 -164.0(5) . . . . ?
C4 Fe1 C9 C8 48.2(6) . . . . ?
C8 C9 C10 C6 -0.3(5) . . . . ?
Fe1 C9 C10 C6 -60.0(3) . . . . ?
C8 C9 C10 Fe1 59.7(3) . . . . ?
C7 C6 C10 C9 0.5(5) . . . . ?
Fe1 C6 C10 C9 59.9(3) . . . . ?
C7 C6 C10 Fe1 -59.5(3) . . . . ?
C2 Fe1 C10 C9 121.6(3) . . . . ?
C1 Fe1 C10 C9 78.6(3) . . . . ?
C8 Fe1 C10 C9 -38.2(3) . . . . ?
C6 Fe1 C10 C9 -118.7(4) . . . . ?
C7 Fe1 C10 C9 -81.4(3) . . . . ?
C5 Fe1 C10 C9 46.4(6) . . . . ?
C3 Fe1 C10 C9 162.8(3) . . . . ?
C4 Fe1 C10 C9 -165.4(5) . . . . ?
C2 Fe1 C10 C6 -119.7(3) . . . . ?
C9 Fe1 C10 C6 118.7(4) . . . . ?
C1 Fe1 C10 C6 -162.7(3) . . . . ?
C8 Fe1 C10 C6 80.5(3) . . . . ?
C7 Fe1 C10 C6 37.3(3) . . . . ?
C5 Fe1 C10 C6 165.1(5) . . . . ?
C3 Fe1 C10 C6 -78.5(3) . . . . ?
C4 Fe1 C10 C6 -46.7(7) . . . . ?
C5 C1 C11 O1 170.9(4) . . . . ?
C2 C1 C11 O1 -5.5(6) . . . . ?
Fe1 C1 C11 O1 80.5(5) . . . . ?
C5 C1 C11 S2 -11.5(6) . . . . ?
C2 C1 C11 S2 172.1(3) . . . . ?
Fe1 C1 C11 S2 -101.9(3) . . . . ?
P1 Ag1 Ag2 P2 -45.77(13) . . . . ?
S1 Ag1 Ag2 P2 81.88(5) . . . . ?
S2 Ag1 Ag2 P2 -113.35(5) . . . . ?
P1 Ag1 Ag2 S1 168.75(12) . . . 2_666 ?
S1 Ag1 Ag2 S1 -63.59(4) . . . 2_666 ?
S2 Ag1 Ag2 S1 101.18(4) . . . 2_666 ?
P1 Ag1 Ag2 S2 67.58(12) . . . . ?
S1 Ag1 Ag2 S2 -164.77(4) . . . . ?
O1 C11 S2 Ag2 91.3(4) . . . . ?
C1 C11 S2 Ag2 -86.2(3) . . . . ?
O1 C11 S2 Ag1 10.7(4) . . . . ?
C1 C11 S2 Ag1 -166.8(3) . . . . ?
P2 Ag2 S2 C11 14.98(15) . . . . ?
S1 Ag2 S2 C11 175.69(14) 2_666 . . . ?
Ag1 Ag2 S2 C11 -94.32(14) . . . . ?
P2 Ag2 S2 Ag1 109.29(4) . . . . ?
S1 Ag2 S2 Ag1 -90.00(3) 2_666 . . . ?
P1 Ag1 S2 C11 -73.83(14) . . . . ?
S1 Ag1 S2 C11 104.90(14) . . . . ?
Ag2 Ag1 S2 C11 90.77(14) . . . . ?
P1 Ag1 S2 Ag2 -164.61(4) . . . . ?
S1 Ag1 S2 Ag2 14.13(4) . . . . ?
C18 Fe2 C12 C16 160.0(3) . . . . ?
C19 Fe2 C12 C16 -169.3(5) . . . . ?
C21 Fe2 C12 C16 76.8(3) . . . . ?
C17 Fe2 C12 C16 117.8(3) . . . . ?
C15 Fe2 C12 C16 -38.1(3) . . . . ?
C13 Fe2 C12 C16 -119.1(4) . . . . ?
C20 Fe2 C12 C16 46.0(6) . . . . ?
C14 Fe2 C12 C16 -81.5(3) . . . . ?
C18 Fe2 C12 C13 -80.9(3) . . . . ?
C19 Fe2 C12 C13 -50.1(6) . . . . ?
C16 Fe2 C12 C13 119.1(4) . . . . ?
C21 Fe2 C12 C13 -164.0(3) . . . . ?
C17 Fe2 C12 C13 -123.1(3) . . . . ?
C15 Fe2 C12 C13 81.0(3) . . . . ?
C20 Fe2 C12 C13 165.2(5) . . . . ?
C14 Fe2 C12 C13 37.7(3) . . . . ?
C18 Fe2 C12 C22 37.0(4) . . . . ?
C19 Fe2 C12 C22 67.7(6) . . . . ?
C16 Fe2 C12 C22 -123.0(4) . . . . ?
C21 Fe2 C12 C22 -46.1(4) . . . . ?
C17 Fe2 C12 C22 -5.2(4) . . . . ?
C15 Fe2 C12 C22 -161.1(4) . . . . ?
C13 Fe2 C12 C22 117.9(5) . . . . ?
C20 Fe2 C12 C22 -76.9(7) . . . . ?
C14 Fe2 C12 C22 155.5(4) . . . . ?
C16 C12 C13 C14 -0.2(5) . . . . ?
C22 C12 C13 C14 -173.2(4) . . . . ?
Fe2 C12 C13 C14 -59.8(3) . . . . ?
C16 C12 C13 Fe2 59.6(3) . . . . ?
C22 C12 C13 Fe2 -113.4(4) . . . . ?
C18 Fe2 C13 C14 -123.2(3) . . . . ?
C19 Fe2 C13 C14 -81.0(4) . . . . ?
C12 Fe2 C13 C14 119.0(4) . . . . ?
C16 Fe2 C13 C14 81.2(3) . . . . ?
C21 Fe2 C13 C14 161.8(5) . . . . ?
C17 Fe2 C13 C14 -165.5(3) . . . . ?
C15 Fe2 C13 C14 37.1(3) . . . . ?
C20 Fe2 C13 C14 -47.0(7) . . . . ?
C18 Fe2 C13 C12 117.8(3) . . . . ?
C19 Fe2 C13 C12 160.0(3) . . . . ?
C16 Fe2 C13 C12 -37.8(2) . . . . ?
C21 Fe2 C13 C12 42.8(7) . . . . ?
C17 Fe2 C13 C12 75.4(3) . . . . ?
C15 Fe2 C13 C12 -81.9(3) . . . . ?
C20 Fe2 C13 C12 -166.0(5) . . . . ?
C14 Fe2 C13 C12 -119.0(4) . . . . ?
C12 C13 C14 C15 0.5(5) . . . . ?
Fe2 C13 C14 C15 -58.5(3) . . . . ?
C12 C13 C14 Fe2 58.9(3) . . . . ?
C18 Fe2 C14 C15 -164.1(3) . . . . ?
C19 Fe2 C14 C15 -121.6(3) . . . . ?
C12 Fe2 C14 C15 81.8(3) . . . . ?
C16 Fe2 C14 C15 37.7(3) . . . . ?
C21 Fe2 C14 C15 -44.0(6) . . . . ?
C17 Fe2 C14 C15 159.8(6) . . . . ?
C13 Fe2 C14 C15 119.9(4) . . . . ?
C20 Fe2 C14 C15 -78.9(4) . . . . ?
C18 Fe2 C14 C13 76.1(4) . . . . ?
C19 Fe2 C14 C13 118.6(3) . . . . ?
C12 Fe2 C14 C13 -38.1(3) . . . . ?
C16 Fe2 C14 C13 -82.2(3) . . . . ?
C21 Fe2 C14 C13 -163.9(5) . . . . ?
C17 Fe2 C14 C13 39.9(7) . . . . ?
C15 Fe2 C14 C13 -119.9(4) . . . . ?
C20 Fe2 C14 C13 161.2(3) . . . . ?
C13 C14 C15 C16 -0.6(5) . . . . ?
Fe2 C14 C15 C16 -59.0(3) . . . . ?
C13 C14 C15 Fe2 58.4(3) . . . . ?
C18 Fe2 C15 C14 43.8(8) . . . . ?
C19 Fe2 C15 C14 78.2(4) . . . . ?
C12 Fe2 C15 C14 -81.7(3) . . . . ?
C16 Fe2 C15 C14 -119.8(4) . . . . ?
C21 Fe2 C15 C14 161.8(3) . . . . ?
C17 Fe2 C15 C14 -163.6(5) . . . . ?
C13 Fe2 C15 C14 -37.4(3) . . . . ?
C20 Fe2 C15 C14 119.8(3) . . . . ?
C18 Fe2 C15 C16 163.6(7) . . . . ?
C19 Fe2 C15 C16 -162.0(3) . . . . ?
C12 Fe2 C15 C16 38.1(3) . . . . ?
C21 Fe2 C15 C16 -78.4(3) . . . . ?
C17 Fe2 C15 C16 -43.8(7) . . . . ?
C13 Fe2 C15 C16 82.4(3) . . . . ?
C20 Fe2 C15 C16 -120.4(3) . . . . ?
C14 Fe2 C15 C16 119.8(4) . . . . ?
C13 C12 C16 C15 -0.2(5) . . . . ?
C22 C12 C16 C15 172.5(4) . . . . ?
Fe2 C12 C16 C15 59.6(3) . . . . ?
C13 C12 C16 Fe2 -59.7(3) . . . . ?
C22 C12 C16 Fe2 112.9(4) . . . . ?
C14 C15 C16 C12 0.5(5) . . . . ?
Fe2 C15 C16 C12 -59.3(3) . . . . ?
C14 C15 C16 Fe2 59.7(3) . . . . ?
C18 Fe2 C16 C12 -47.8(6) . . . . ?
C19 Fe2 C16 C12 168.0(5) . . . . ?
C21 Fe2 C16 C12 -121.5(3) . . . . ?
C17 Fe2 C16 C12 -79.8(3) . . . . ?
C15 Fe2 C16 C12 118.7(4) . . . . ?
C13 Fe2 C16 C12 38.0(2) . . . . ?
C20 Fe2 C16 C12 -162.4(2) . . . . ?
C14 Fe2 C16 C12 81.7(3) . . . . ?
C18 Fe2 C16 C15 -166.5(5) . . . . ?
C19 Fe2 C16 C15 49.3(7) . . . . ?
C12 Fe2 C16 C15 -118.7(4) . . . . ?
C21 Fe2 C16 C15 119.7(3) . . . . ?
C17 Fe2 C16 C15 161.5(3) . . . . ?
C13 Fe2 C16 C15 -80.8(3) . . . . ?
C20 Fe2 C16 C15 78.8(3) . . . . ?
C14 Fe2 C16 C15 -37.0(3) . . . . ?
C18 Fe2 C17 C21 118.7(5) . . . . ?
C19 Fe2 C17 C21 80.6(3) . . . . ?
C12 Fe2 C17 C21 -122.0(3) . . . . ?
C16 Fe2 C17 C21 -79.8(3) . . . . ?
C15 Fe2 C17 C21 -48.1(7) . . . . ?
C13 Fe2 C17 C21 -163.6(3) . . . . ?
C20 Fe2 C17 C21 37.0(3) . . . . ?
C14 Fe2 C17 C21 166.3(5) . . . . ?
C19 Fe2 C17 C18 -38.1(4) . . . . ?
C12 Fe2 C17 C18 119.3(4) . . . . ?
C16 Fe2 C17 C18 161.5(3) . . . . ?
C21 Fe2 C17 C18 -118.7(5) . . . . ?
C15 Fe2 C17 C18 -166.8(5) . . . . ?
C13 Fe2 C17 C18 77.7(4) . . . . ?
C20 Fe2 C17 C18 -81.7(4) . . . . ?
C14 Fe2 C17 C18 47.5(7) . . . . ?
C21 C17 C18 C19 0.5(6) . . . . ?
Fe2 C17 C18 C19 59.9(4) . . . . ?
C21 C17 C18 Fe2 -59.4(3) . . . . ?
C12 Fe2 C18 C19 162.9(3) . . . . ?
C16 Fe2 C18 C19 -162.5(5) . . . . ?
C21 Fe2 C18 C19 -80.7(4) . . . . ?
C17 Fe2 C18 C19 -118.4(5) . . . . ?
C15 Fe2 C18 C19 45.5(9) . . . . ?
C13 Fe2 C18 C19 120.0(3) . . . . ?
C20 Fe2 C18 C19 -37.2(3) . . . . ?
C14 Fe2 C18 C19 78.5(4) . . . . ?
C19 Fe2 C18 C17 118.4(5) . . . . ?
C12 Fe2 C18 C17 -78.7(4) . . . . ?
C16 Fe2 C18 C17 -44.0(7) . . . . ?
C21 Fe2 C18 C17 37.7(3) . . . . ?
C15 Fe2 C18 C17 163.9(6) . . . . ?
C13 Fe2 C18 C17 -121.6(3) . . . . ?
C20 Fe2 C18 C17 81.2(4) . . . . ?
C14 Fe2 C18 C17 -163.1(3) . . . . ?
C17 C18 C19 C20 -0.2(6) . . . . ?
Fe2 C18 C19 C20 59.9(4) . . . . ?
C17 C18 C19 Fe2 -60.1(3) . . . . ?
C12 Fe2 C19 C18 -42.0(7) . . . . ?
C16 Fe2 C19 C18 159.3(5) . . . . ?
C21 Fe2 C19 C18 82.1(4) . . . . ?
C17 Fe2 C19 C18 38.4(3) . . . . ?
C15 Fe2 C19 C18 -163.6(3) . . . . ?
C13 Fe2 C19 C18 -78.9(4) . . . . ?
C20 Fe2 C19 C18 119.8(5) . . . . ?
C14 Fe2 C19 C18 -121.7(3) . . . . ?
C18 Fe2 C19 C20 -119.8(5) . . . . ?
C12 Fe2 C19 C20 -161.8(4) . . . . ?
C16 Fe2 C19 C20 39.5(7) . . . . ?
C21 Fe2 C19 C20 -37.7(3) . . . . ?
C17 Fe2 C19 C20 -81.4(3) . . . . ?
C15 Fe2 C19 C20 76.6(4) . . . . ?
C13 Fe2 C19 C20 161.4(3) . . . . ?
C14 Fe2 C19 C20 118.6(3) . . . . ?
C18 C19 C20 C21 -0.2(6) . . . . ?
Fe2 C19 C20 C21 59.0(3) . . . . ?
C18 C19 C20 Fe2 -59.2(4) . . . . ?
C18 Fe2 C20 C21 -81.4(3) . . . . ?
C19 Fe2 C20 C21 -118.9(5) . . . . ?
C12 Fe2 C20 C21 41.6(7) . . . . ?
C16 Fe2 C20 C21 75.9(4) . . . . ?
C17 Fe2 C20 C21 -37.1(3) . . . . ?
C15 Fe2 C20 C21 118.4(3) . . . . ?
C13 Fe2 C20 C21 -165.3(5) . . . . ?
C14 Fe2 C20 C21 160.2(3) . . . . ?
C18 Fe2 C20 C19 37.5(3) . . . . ?
C12 Fe2 C20 C19 160.5(5) . . . . ?
C16 Fe2 C20 C19 -165.2(3) . . . . ?
C21 Fe2 C20 C19 118.9(5) . . . . ?
C17 Fe2 C20 C19 81.8(4) . . . . ?
C15 Fe2 C20 C19 -122.7(3) . . . . ?
C13 Fe2 C20 C19 -46.5(7) . . . . ?
C14 Fe2 C20 C19 -80.9(4) . . . . ?
C19 C20 C21 C17 0.5(6) . . . . ?
Fe2 C20 C21 C17 59.3(3) . . . . ?
C19 C20 C21 Fe2 -58.8(3) . . . . ?
C18 C17 C21 C20 -0.7(5) . . . . ?
Fe2 C17 C21 C20 -59.6(3) . . . . ?
C18 C17 C21 Fe2 58.9(3) . . . . ?
C18 Fe2 C21 C20 81.9(4) . . . . ?
C19 Fe2 C21 C20 37.8(3) . . . . ?
C12 Fe2 C21 C20 -163.9(3) . . . . ?
C16 Fe2 C21 C20 -122.2(3) . . . . ?
C17 Fe2 C21 C20 120.2(5) . . . . ?
C15 Fe2 C21 C20 -80.1(4) . . . . ?
C13 Fe2 C21 C20 164.0(5) . . . . ?
C14 Fe2 C21 C20 -48.2(7) . . . . ?
C18 Fe2 C21 C17 -38.3(3) . . . . ?
C19 Fe2 C21 C17 -82.4(3) . . . . ?
C12 Fe2 C21 C17 75.9(3) . . . . ?
C16 Fe2 C21 C17 117.6(3) . . . . ?
C15 Fe2 C21 C17 159.7(3) . . . . ?
C13 Fe2 C21 C17 43.8(7) . . . . ?
C20 Fe2 C21 C17 -120.2(5) . . . . ?
C14 Fe2 C21 C17 -168.4(5) . . . . ?
C16 C12 C22 O2 -176.8(4) . . . . ?
C13 C12 C22 O2 -5.2(7) . . . . ?
Fe2 C12 C22 O2 -89.9(5) . . . . ?
C16 C12 C22 S1 2.6(6) . . . . ?
C13 C12 C22 S1 174.2(3) . . . . ?
Fe2 C12 C22 S1 89.5(3) . . . . ?
Ag1 S1 C22 O2 -107.8(4) . . . . ?
Ag2 S1 C22 O2 14.6(4) 2_666 . . . ?
Ag1 S1 C22 C12 72.8(3) . . . . ?
Ag2 S1 C22 C12 -164.8(3) 2_666 . . . ?
S1 Ag1 P1 C29 61.54(15) . . . . ?
S2 Ag1 P1 C29 -119.94(14) . . . . ?
Ag2 Ag1 P1 C29 -178.16(15) . . . . ?
S1 Ag1 P1 C35 -56.92(16) . . . . ?
S2 Ag1 P1 C35 121.60(15) . . . . ?
Ag2 Ag1 P1 C35 63.4(2) . . . . ?
S1 Ag1 P1 C23 -175.58(15) . . . . ?
S2 Ag1 P1 C23 2.93(16) . . . . ?
Ag2 Ag1 P1 C23 -55.3(2) . . . . ?
C29 P1 C23 C24 99.3(4) . . . . ?
C35 P1 C23 C24 -154.3(4) . . . . ?
Ag1 P1 C23 C24 -28.8(4) . . . . ?
C29 P1 C23 C28 -81.5(4) . . . . ?
C35 P1 C23 C28 24.9(4) . . . . ?
Ag1 P1 C23 C28 150.4(3) . . . . ?
C28 C23 C24 C25 2.0(7) . . . . ?
P1 C23 C24 C25 -178.7(4) . . . . ?
C23 C24 C25 C26 -2.5(8) . . . . ?
C24 C25 C26 C27 1.7(8) . . . . ?
C25 C26 C27 C28 -0.4(8) . . . . ?
C26 C27 C28 C23 0.0(7) . . . . ?
C24 C23 C28 C27 -0.8(7) . . . . ?
P1 C23 C28 C27 -180.0(4) . . . . ?
C35 P1 C29 C30 -91.1(3) . . . . ?
C23 P1 C29 C30 15.7(4) . . . . ?
Ag1 P1 C29 C30 143.4(3) . . . . ?
C35 P1 C29 C34 84.2(3) . . . . ?
C23 P1 C29 C34 -169.0(3) . . . . ?
Ag1 P1 C29 C34 -41.4(3) . . . . ?
C34 C29 C30 C31 -1.3(6) . . . . ?
P1 C29 C30 C31 173.9(3) . . . . ?
C29 C30 C31 C32 0.3(6) . . . . ?
C30 C31 C32 C33 0.6(7) . . . . ?
C31 C32 C33 C34 -0.3(7) . . . . ?
C32 C33 C34 C29 -0.7(6) . . . . ?
C30 C29 C34 C33 1.5(6) . . . . ?
P1 C29 C34 C33 -174.0(3) . . . . ?
C29 P1 C35 C40 -175.9(3) . . . . ?
C23 P1 C35 C40 75.1(4) . . . . ?
Ag1 P1 C35 C40 -50.1(4) . . . . ?
C29 P1 C35 C36 6.0(4) . . . . ?
C23 P1 C35 C36 -103.1(4) . . . . ?
Ag1 P1 C35 C36 131.8(3) . . . . ?
C40 C35 C36 C37 -0.5(6) . . . . ?
P1 C35 C36 C37 177.6(3) . . . . ?
C35 C36 C37 C38 -0.5(7) . . . . ?
C36 C37 C38 C39 0.8(7) . . . . ?
C37 C38 C39 C40 -0.1(7) . . . . ?
C36 C35 C40 C39 1.2(6) . . . . ?
P1 C35 C40 C39 -177.0(3) . . . . ?
C38 C39 C40 C35 -0.9(7) . . . . ?
S1 Ag2 P2 C41 -92.87(14) 2_666 . . . ?
S2 Ag2 P2 C41 64.59(14) . . . . ?
Ag1 Ag2 P2 C41 129.22(13) . . . . ?
S1 Ag2 P2 C47 19.44(15) 2_666 . . . ?
S2 Ag2 P2 C47 176.90(14) . . . . ?
Ag1 Ag2 P2 C47 -118.46(14) . . . . ?
S1 Ag2 P2 C53 142.14(17) 2_666 . . . ?
S2 Ag2 P2 C53 -60.40(18) . . . . ?
Ag1 Ag2 P2 C53 4.23(18) . . . . ?
C47 P2 C41 C42 -86.2(3) . . . . ?
C53 P2 C41 C42 166.5(3) . . . . ?
Ag2 P2 C41 C42 30.8(3) . . . . ?
C47 P2 C41 C46 90.3(4) . . . . ?
C53 P2 C41 C46 -17.0(4) . . . . ?
Ag2 P2 C41 C46 -152.7(3) . . . . ?
C46 C41 C42 C43 -0.8(6) . . . . ?
P2 C41 C42 C43 175.9(3) . . . . ?
C41 C42 C43 C44 -0.3(7) . . . . ?
C42 C43 C44 C45 1.4(7) . . . . ?
C43 C44 C45 C46 -1.3(7) . . . . ?
C44 C45 C46 C41 0.2(7) . . . . ?
C42 C41 C46 C45 0.8(6) . . . . ?
P2 C41 C46 C45 -175.6(3) . . . . ?
C41 P2 C47 C52 150.8(3) . . . . ?
C53 P2 C47 C52 -99.6(3) . . . . ?
Ag2 P2 C47 C52 35.3(3) . . . . ?
C41 P2 C47 C48 -31.1(4) . . . . ?
C53 P2 C47 C48 78.5(4) . . . . ?
Ag2 P2 C47 C48 -146.6(3) . . . . ?
C52 C47 C48 C49 1.6(6) . . . . ?
P2 C47 C48 C49 -176.4(3) . . . . ?
C47 C48 C49 C50 -1.3(6) . . . . ?
C48 C49 C50 C51 0.9(7) . . . . ?
C49 C50 C51 C52 -0.7(7) . . . . ?
C50 C51 C52 C47 1.1(6) . . . . ?
C48 C47 C52 C51 -1.5(6) . . . . ?
P2 C47 C52 C51 176.6(3) . . . . ?
C41 P2 C53 C54 88.4(4) . . . . ?
C47 P2 C53 C54 -19.3(4) . . . . ?
Ag2 P2 C53 C54 -145.4(3) . . . . ?
C41 P2 C53 C58 -93.7(4) . . . . ?
C47 P2 C53 C58 158.5(4) . . . . ?
Ag2 P2 C53 C58 32.4(4) . . . . ?
C58 C53 C54 C55 2.6(7) . . . . ?
P2 C53 C54 C55 -179.5(4) . . . . ?
C53 C54 C55 C56 -1.8(8) . . . . ?
C54 C55 C56 C57 0.5(8) . . . . ?
C55 C56 C57 C58 0.0(8) . . . . ?
C56 C57 C58 C53 0.9(8) . . . . ?
C54 C53 C58 C57 -2.1(7) . . . . ?
P2 C53 C58 C57 179.9(4) . . . . ?
