#------------------------------------------------------------------------------
#$Date: 2016-03-25 09:32:45 +0100 (vie 25 de mar de 2016) $
#$Revision: 179753 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/49/7004916.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7004916
loop_
_publ_author_name
'Levason, William'
'Nirwan, Manisha'
'Ratnani, Raju'
'Reid, Gillian'
'Tsoureas, Nikolaos'
'Webster, Michael'
_publ_section_title
;
 Transition metal complexes with wide-angle dithio-, diseleno- and
 ditelluroethers: properties and structural systematics.
;
_journal_issue                   4
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              439
_journal_page_last               448
_journal_paper_doi               10.1039/b613501c
_journal_year                    2007
_chemical_formula_moiety         'C20 H28 Cl2 Rh Se4 1+, F6 P 1-'
_chemical_formula_sum            'C20 H28 Cl2 F6 P Rh Se4'
_chemical_formula_weight         903.04
_chemical_name_common
;
cis-dichlorobis(1,2-
bis(methylselenomethyl)benzene)rhodium(iii) hexafluorophosphate
;
_chemical_name_systematic
;
cis-dichlorobis(1,2-bis(methylselenomethyl)benzene)rhodium(III)
hexafluorophosphate
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_date             2006-03-16
_audit_creation_method           'SHELXL-97 + hand edit'
_cell_angle_alpha                90.00
_cell_angle_beta                 95.422(8)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   12.515(2)
_cell_length_b                   12.0649(16)
_cell_length_c                   18.630(3)
_cell_measurement_reflns_used    10717
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      27.48
_cell_measurement_theta_min      2.91
_cell_volume                     2800.4(7)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      120(2)
_diffrn_measured_fraction_theta_full 0.990
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_device_type  'area detector, Nonius Kappa ccd'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  '10cm confocal mirrors'
_diffrn_radiation_source         'Nonius rotating anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1597
_diffrn_reflns_av_sigmaI/netI    0.1218
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            45493
_diffrn_reflns_theta_full        27.58
_diffrn_reflns_theta_max         27.58
_diffrn_reflns_theta_min         3.11
_diffrn_standards_decay_%        0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    6.107
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.6234
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
'G.M. Sheldrick, (2003). SADABS. Version 2.10. Bruker AXS Inc.'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.142
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             1728
_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.03
_exptl_crystal_size_min          0.01
_refine_diff_density_max         0.798
_refine_diff_density_min         -1.224
_refine_diff_density_rms         0.200
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.020
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_parameters     311
_refine_ls_number_reflns         6423
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.020
_refine_ls_R_factor_all          0.1308
_refine_ls_R_factor_gt           0.0672
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0043P)²+20.6816P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0878
_refine_ls_wR_factor_ref         0.1016
_reflns_number_gt                4051
_reflns_number_total             6423
_reflns_threshold_expression     I>2sigma(I)
_cod_data_source_file            b613501c.txt
_cod_data_source_block           06nts004
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7004916
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.88026(5) 0.08821(5) 0.19024(3) 0.02069(16) Uani 1 1 d . . .
Cl1 Cl 1.01848(16) -0.03877(16) 0.22990(10) 0.0260(5) Uani 1 1 d . . .
Cl2 Cl 0.73694(16) -0.03267(16) 0.20746(11) 0.0282(5) Uani 1 1 d . . .
Se1 Se 1.03405(7) 0.19410(7) 0.15357(5) 0.0287(2) Uani 1 1 d . . .
Se2 Se 0.87302(6) 0.15347(6) 0.31620(4) 0.02211(19) Uani 1 1 d . . .
Se3 Se 0.89860(7) -0.00506(6) 0.07216(4) 0.0236(2) Uani 1 1 d . . .
Se4 Se 0.75250(7) 0.23799(6) 0.16014(4) 0.0245(2) Uani 1 1 d . . .
P1 P 0.83333(18) 0.17555(17) 0.56300(12) 0.0259(5) Uani 1 1 d . . .
F1 F 0.7884(4) 0.1046(4) 0.6265(3) 0.0458(14) Uani 1 1 d . . .
F2 F 0.7524(4) 0.2742(4) 0.5785(2) 0.0346(12) Uani 1 1 d . . .
F3 F 0.9218(4) 0.2286(4) 0.6194(3) 0.0425(13) Uani 1 1 d . . .
F4 F 0.9135(4) 0.0769(4) 0.5480(3) 0.0476(15) Uani 1 1 d . . .
F5 F 0.7444(4) 0.1227(4) 0.5064(3) 0.0453(14) Uani 1 1 d . . .
F6 F 0.8767(4) 0.2471(4) 0.5001(3) 0.0479(14) Uani 1 1 d . . .
C1 C 0.9938(8) 0.3444(7) 0.1248(5) 0.050(3) Uani 1 1 d . . .
H1A H 0.9726 0.3854 0.1666 0.075 Uiso 1 1 calc R . .
H1B H 0.9335 0.3422 0.0872 0.075 Uiso 1 1 calc R . .
H1C H 1.0550 0.3815 0.1060 0.075 Uiso 1 1 calc R . .
C2 C 1.1428(6) 0.2308(7) 0.2341(4) 0.028(2) Uani 1 1 d . . .
H2A H 1.1582 0.1630 0.2632 0.033 Uiso 1 1 calc R . .
H2B H 1.2099 0.2523 0.2136 0.033 Uiso 1 1 calc R . .
C3 C 1.1131(6) 0.3221(7) 0.2838(4) 0.028(2) Uani 1 1 d . . .
C4 C 1.1457(7) 0.4307(6) 0.2714(5) 0.031(2) Uani 1 1 d . . .
H4 H 1.1854 0.4462 0.2316 0.037 Uiso 1 1 calc R . .
C5 C 1.1208(7) 0.5154(7) 0.3164(5) 0.032(2) Uani 1 1 d . . .
H5 H 1.1445 0.5886 0.3079 0.039 Uiso 1 1 calc R . .
C6 C 1.0618(7) 0.4948(7) 0.3734(5) 0.031(2) Uani 1 1 d . . .
H6 H 1.0438 0.5540 0.4037 0.037 Uiso 1 1 calc R . .
C7 C 1.0282(7) 0.3873(6) 0.3872(4) 0.028(2) Uani 1 1 d . . .
H7 H 0.9883 0.3732 0.4271 0.034 Uiso 1 1 calc R . .
C8 C 1.0532(6) 0.3007(6) 0.3424(4) 0.0215(18) Uani 1 1 d . . .
C9 C 1.0187(6) 0.1848(6) 0.3597(4) 0.0241(19) Uani 1 1 d . . .
H9A H 1.0212 0.1760 0.4127 0.029 Uiso 1 1 calc R . .
H9B H 1.0693 0.1309 0.3416 0.029 Uiso 1 1 calc R . .
C10 C 0.8591(7) 0.0156(6) 0.3679(4) 0.032(2) Uani 1 1 d . . .
H10A H 0.9118 -0.0380 0.3534 0.048 Uiso 1 1 calc R . .
H10B H 0.7866 -0.0142 0.3567 0.048 Uiso 1 1 calc R . .
H10C H 0.8718 0.0292 0.4199 0.048 Uiso 1 1 calc R . .
C11 C 0.8693(7) -0.1614(6) 0.0862(4) 0.029(2) Uani 1 1 d . . .
H11A H 0.7963 -0.1702 0.1002 0.043 Uiso 1 1 calc R . .
H11B H 0.9208 -0.1911 0.1243 0.043 Uiso 1 1 calc R . .
H11C H 0.8762 -0.2017 0.0412 0.043 Uiso 1 1 calc R . .
C12 C 0.7763(7) 0.0208(6) 0.0008(4) 0.027(2) Uani 1 1 d . . .
H12A H 0.7777 -0.0330 -0.0393 0.033 Uiso 1 1 calc R . .
H12B H 0.7084 0.0105 0.0233 0.033 Uiso 1 1 calc R . .
C13 C 0.7821(7) 0.1368(6) -0.0278(4) 0.026(2) Uani 1 1 d . . .
C14 C 0.8369(7) 0.1597(7) -0.0862(4) 0.031(2) Uani 1 1 d . . .
H14 H 0.8693 0.1004 -0.1097 0.038 Uiso 1 1 calc R . .
C15 C 0.8468(7) 0.2659(8) -0.1122(5) 0.036(2) Uani 1 1 d . . .
H15 H 0.8858 0.2794 -0.1527 0.043 Uiso 1 1 calc R . .
C16 C 0.7995(7) 0.3521(7) -0.0786(5) 0.035(2) Uani 1 1 d . . .
H16 H 0.8069 0.4257 -0.0955 0.042 Uiso 1 1 calc R . .
C17 C 0.7412(7) 0.3323(7) -0.0204(5) 0.033(2) Uani 1 1 d . . .
H17 H 0.7076 0.3919 0.0020 0.039 Uiso 1 1 calc R . .
C18 C 0.7322(6) 0.2249(7) 0.0051(4) 0.028(2) Uani 1 1 d . . .
C19 C 0.6664(7) 0.2082(7) 0.0684(4) 0.033(2) Uani 1 1 d . . .
H19A H 0.6396 0.1310 0.0682 0.039 Uiso 1 1 calc R . .
H19B H 0.6036 0.2584 0.0635 0.039 Uiso 1 1 calc R . .
C20 C 0.6339(6) 0.2183(7) 0.2192(4) 0.027(2) Uani 1 1 d . . .
H20A H 0.5807 0.2770 0.2081 0.041 Uiso 1 1 calc R . .
H20B H 0.6607 0.2222 0.2702 0.041 Uiso 1 1 calc R . .
H20C H 0.6004 0.1459 0.2089 0.041 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Se Se -0.0929 2.2259 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Cl2 Rh1 Cl1 95.72(7) . . ?
Cl2 Rh1 Se4 89.94(6) . . ?
Cl1 Rh1 Se4 171.90(6) . . ?
Cl2 Rh1 Se1 169.91(6) . . ?
Cl1 Rh1 Se1 81.69(6) . . ?
Se4 Rh1 Se1 93.69(4) . . ?
Cl2 Rh1 Se2 88.36(6) . . ?
Cl1 Rh1 Se2 90.06(5) . . ?
Se4 Rh1 Se2 84.31(3) . . ?
Se1 Rh1 Se2 101.36(4) . . ?
Cl2 Rh1 Se3 88.60(6) . . ?
Cl1 Rh1 Se3 81.88(5) . . ?
Se4 Rh1 Se3 104.09(3) . . ?
Se1 Rh1 Se3 81.38(3) . . ?
Se2 Rh1 Se3 171.06(4) . . ?
C1 Se1 C2 98.2(4) . . ?
C1 Se1 Rh1 111.8(3) . . ?
C2 Se1 Rh1 113.9(2) . . ?
C10 Se2 C9 94.8(3) . . ?
C10 Se2 Rh1 102.2(2) . . ?
C9 Se2 Rh1 109.7(2) . . ?
C11 Se3 C12 95.8(3) . . ?
C11 Se3 Rh1 106.5(2) . . ?
C12 Se3 Rh1 113.3(3) . . ?
C20 Se4 C19 94.9(4) . . ?
C20 Se4 Rh1 107.4(2) . . ?
C19 Se4 Rh1 110.9(3) . . ?
F3 P1 F6 90.2(3) . . ?
F3 P1 F5 179.8(3) . . ?
F6 P1 F5 89.8(3) . . ?
F3 P1 F4 90.3(3) . . ?
F6 P1 F4 90.7(3) . . ?
F5 P1 F4 89.8(3) . . ?
F3 P1 F1 89.9(3) . . ?
F6 P1 F1 179.2(3) . . ?
F5 P1 F1 90.1(3) . . ?
F4 P1 F1 90.1(3) . . ?
F3 P1 F2 89.7(3) . . ?
F6 P1 F2 89.7(3) . . ?
F5 P1 F2 90.1(3) . . ?
F4 P1 F2 179.6(3) . . ?
F1 P1 F2 89.5(3) . . ?
Se1 C1 H1A 109.5 . . ?
Se1 C1 H1B 109.5 . . ?
H1A C1 H1B 109.5 . . ?
Se1 C1 H1C 109.5 . . ?
H1A C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
C3 C2 Se1 116.0(5) . . ?
C3 C2 H2A 108.3 . . ?
Se1 C2 H2A 108.3 . . ?
C3 C2 H2B 108.3 . . ?
Se1 C2 H2B 108.3 . . ?
H2A C2 H2B 107.4 . . ?
C4 C3 C8 119.1(8) . . ?
C4 C3 C2 119.3(8) . . ?
C8 C3 C2 121.6(7) . . ?
C5 C4 C3 120.6(9) . . ?
C5 C4 H4 119.7 . . ?
C3 C4 H4 119.7 . . ?
C6 C5 C4 120.4(8) . . ?
C6 C5 H5 119.8 . . ?
C4 C5 H5 119.8 . . ?
C5 C6 C7 120.3(8) . . ?
C5 C6 H6 119.9 . . ?
C7 C6 H6 119.9 . . ?
C8 C7 C6 120.0(8) . . ?
C8 C7 H7 120.0 . . ?
C6 C7 H7 120.0 . . ?
C7 C8 C3 119.6(7) . . ?
C7 C8 C9 118.9(7) . . ?
C3 C8 C9 121.4(7) . . ?
C8 C9 Se2 111.4(5) . . ?
C8 C9 H9A 109.4 . . ?
Se2 C9 H9A 109.4 . . ?
C8 C9 H9B 109.4 . . ?
Se2 C9 H9B 109.4 . . ?
H9A C9 H9B 108.0 . . ?
Se2 C10 H10A 109.5 . . ?
Se2 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
Se2 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
Se3 C11 H11A 109.5 . . ?
Se3 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
Se3 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
C13 C12 Se3 109.2(5) . . ?
C13 C12 H12A 109.8 . . ?
Se3 C12 H12A 109.8 . . ?
C13 C12 H12B 109.8 . . ?
Se3 C12 H12B 109.8 . . ?
H12A C12 H12B 108.3 . . ?
C14 C13 C18 118.2(8) . . ?
C14 C13 C12 121.0(8) . . ?
C18 C13 C12 120.9(8) . . ?
C13 C14 C15 122.3(8) . . ?
C13 C14 H14 118.8 . . ?
C15 C14 H14 118.8 . . ?
C16 C15 C14 119.1(9) . . ?
C16 C15 H15 120.5 . . ?
C14 C15 H15 120.5 . . ?
C15 C16 C17 120.5(8) . . ?
C15 C16 H16 119.8 . . ?
C17 C16 H16 119.8 . . ?
C16 C17 C18 119.7(8) . . ?
C16 C17 H17 120.2 . . ?
C18 C17 H17 120.2 . . ?
C17 C18 C13 120.2(8) . . ?
C17 C18 C19 117.3(8) . . ?
C13 C18 C19 122.4(7) . . ?
C18 C19 Se4 111.0(6) . . ?
C18 C19 H19A 109.4 . . ?
Se4 C19 H19A 109.4 . . ?
C18 C19 H19B 109.4 . . ?
Se4 C19 H19B 109.4 . . ?
H19A C19 H19B 108.0 . . ?
Se4 C20 H20A 109.5 . . ?
Se4 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
Se4 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 Cl2 2.357(2) . ?
Rh1 Cl1 2.376(2) . ?
Rh1 Se4 2.4427(10) . ?
Rh1 Se1 2.4601(11) . ?
Rh1 Se2 2.4849(11) . ?
Rh1 Se3 2.5005(11) . ?
Se1 C1 1.944(9) . ?
Se1 C2 1.978(7) . ?
Se2 C10 1.939(7) . ?
Se2 C9 1.961(7) . ?
Se3 C11 1.944(7) . ?
Se3 C12 1.956(7) . ?
Se4 C20 1.944(8) . ?
Se4 C19 1.966(8) . ?
P1 F3 1.587(5) . ?
P1 F6 1.591(5) . ?
P1 F5 1.592(5) . ?
P1 F4 1.599(5) . ?
P1 F1 1.604(5) . ?
P1 F2 1.607(5) . ?
C1 H1A 0.9800 . ?
C1 H1B 0.9800 . ?
C1 H1C 0.9800 . ?
C2 C3 1.508(11) . ?
C2 H2A 0.9900 . ?
C2 H2B 0.9900 . ?
C3 C4 1.399(11) . ?
C3 C8 1.404(11) . ?
C4 C5 1.376(11) . ?
C4 H4 0.9500 . ?
C5 C6 1.372(12) . ?
C5 H5 0.9500 . ?
C6 C7 1.395(11) . ?
C6 H6 0.9500 . ?
C7 C8 1.390(11) . ?
C7 H7 0.9500 . ?
C8 C9 1.507(10) . ?
C9 H9A 0.9900 . ?
C9 H9B 0.9900 . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C12 C13 1.501(10) . ?
C12 H12A 0.9900 . ?
C12 H12B 0.9900 . ?
C13 C14 1.369(12) . ?
C13 C18 1.403(11) . ?
C14 C15 1.379(12) . ?
C14 H14 0.9500 . ?
C15 C16 1.375(12) . ?
C15 H15 0.9500 . ?
C16 C17 1.384(12) . ?
C16 H16 0.9500 . ?
C17 C18 1.388(11) . ?
C17 H17 0.9500 . ?
C18 C19 1.513(12) . ?
C19 H19A 0.9900 . ?
C19 H19B 0.9900 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Cl2 Rh1 Se1 C1 114.7(5) . . . . ?
Cl1 Rh1 Se1 C1 -169.5(3) . . . . ?
Se4 Rh1 Se1 C1 3.8(3) . . . . ?
Se2 Rh1 Se1 C1 -81.2(3) . . . . ?
Se3 Rh1 Se1 C1 107.5(3) . . . . ?
Cl2 Rh1 Se1 C2 -135.1(4) . . . . ?
Cl1 Rh1 Se1 C2 -59.3(3) . . . . ?
Se4 Rh1 Se1 C2 114.0(3) . . . . ?
Se2 Rh1 Se1 C2 29.0(3) . . . . ?
Se3 Rh1 Se1 C2 -142.3(3) . . . . ?
Cl2 Rh1 Se2 C10 44.4(3) . . . . ?
Cl1 Rh1 Se2 C10 -51.3(3) . . . . ?
Se4 Rh1 Se2 C10 134.5(3) . . . . ?
Se1 Rh1 Se2 C10 -132.8(3) . . . . ?
Cl2 Rh1 Se2 C9 144.1(2) . . . . ?
Cl1 Rh1 Se2 C9 48.4(2) . . . . ?
Se4 Rh1 Se2 C9 -125.8(2) . . . . ?
Se1 Rh1 Se2 C9 -33.2(2) . . . . ?
Cl2 Rh1 Se3 C11 -36.8(3) . . . . ?
Cl1 Rh1 Se3 C11 59.2(3) . . . . ?
Se4 Rh1 Se3 C11 -126.4(3) . . . . ?
Se1 Rh1 Se3 C11 141.9(3) . . . . ?
Cl2 Rh1 Se3 C12 67.2(3) . . . . ?
Cl1 Rh1 Se3 C12 163.2(3) . . . . ?
Se4 Rh1 Se3 C12 -22.4(3) . . . . ?
Se1 Rh1 Se3 C12 -114.1(3) . . . . ?
Cl2 Rh1 Se4 C20 34.8(3) . . . . ?
Se1 Rh1 Se4 C20 -154.6(2) . . . . ?
Se2 Rh1 Se4 C20 -53.6(2) . . . . ?
Se3 Rh1 Se4 C20 123.3(2) . . . . ?
Cl2 Rh1 Se4 C19 -67.6(3) . . . . ?
Se1 Rh1 Se4 C19 103.0(3) . . . . ?
Se2 Rh1 Se4 C19 -156.0(3) . . . . ?
Se3 Rh1 Se4 C19 20.9(3) . . . . ?
C1 Se1 C2 C3 43.4(7) . . . . ?
Rh1 Se1 C2 C3 -74.9(6) . . . . ?
Se1 C2 C3 C4 -94.4(8) . . . . ?
Se1 C2 C3 C8 85.5(8) . . . . ?
C8 C3 C4 C5 0.8(12) . . . . ?
C2 C3 C4 C5 -179.3(7) . . . . ?
C3 C4 C5 C6 -1.2(13) . . . . ?
C4 C5 C6 C7 1.2(13) . . . . ?
C5 C6 C7 C8 -0.9(12) . . . . ?
C6 C7 C8 C3 0.6(11) . . . . ?
C6 C7 C8 C9 178.2(7) . . . . ?
C4 C3 C8 C7 -0.5(11) . . . . ?
C2 C3 C8 C7 179.6(7) . . . . ?
C4 C3 C8 C9 -178.1(7) . . . . ?
C2 C3 C8 C9 2.0(11) . . . . ?
C7 C8 C9 Se2 87.5(7) . . . . ?
C3 C8 C9 Se2 -94.9(8) . . . . ?
C10 Se2 C9 C8 -169.7(6) . . . . ?
Rh1 Se2 C9 C8 85.6(6) . . . . ?
C11 Se3 C12 C13 -174.4(6) . . . . ?
Rh1 Se3 C12 C13 74.9(6) . . . . ?
Se3 C12 C13 C14 88.9(8) . . . . ?
Se3 C12 C13 C18 -90.5(8) . . . . ?
C18 C13 C14 C15 1.7(12) . . . . ?
C12 C13 C14 C15 -177.7(7) . . . . ?
C13 C14 C15 C16 -0.4(13) . . . . ?
C14 C15 C16 C17 -1.1(13) . . . . ?
C15 C16 C17 C18 1.2(12) . . . . ?
C16 C17 C18 C13 0.2(12) . . . . ?
C16 C17 C18 C19 -179.3(7) . . . . ?
C14 C13 C18 C17 -1.6(11) . . . . ?
C12 C13 C18 C17 177.9(7) . . . . ?
C14 C13 C18 C19 177.9(7) . . . . ?
C12 C13 C18 C19 -2.7(11) . . . . ?
C17 C18 C19 Se4 -83.5(8) . . . . ?
C13 C18 C19 Se4 97.0(8) . . . . ?
C20 Se4 C19 C18 175.5(6) . . . . ?
Rh1 Se4 C19 C18 -73.8(6) . . . . ?
