#------------------------------------------------------------------------------
#$Date: 2016-03-25 09:32:45 +0100 (vie 25 de mar de 2016) $
#$Revision: 179753 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/49/7004942.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7004942
loop_
_publ_author_name
'Bröring, Martin'
'Prikhodovski, Serguei'
'Brandt, Carsten D.'
'Tejero, Esther Cónsul'
'Köhler, Silke'
_publ_section_title
;
 Monomeric and polymeric copper and zinc tripyrrins.
;
_journal_issue                   2
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              200
_journal_page_last               208
_journal_paper_doi               10.1039/b613800d
_journal_year                    2007
_chemical_formula_sum            'C28 H34 N6 Zn'
_chemical_formula_weight         519.98
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                112.0490(10)
_cell_angle_beta                 102.3180(10)
_cell_angle_gamma                95.4420(10)
_cell_formula_units_Z            2
_cell_length_a                   10.3015(8)
_cell_length_b                   11.2634(9)
_cell_length_c                   12.6692(10)
_cell_measurement_reflns_used    8110
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      28.155
_cell_measurement_theta_min      2.344
_cell_volume                     1306.06(18)
_computing_cell_refinement       'SAINT-NT V6.0'
_computing_data_collection       'SMART-NT V5.6'
_computing_data_reduction        'SAINT-NT V6.0'
_computing_molecular_graphics    'Mercury 1.4.1'
_computing_publication_material  'XSHELL in SHELXTL-97'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker Smart Apex with D8-Goniometer'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0293
_diffrn_reflns_av_sigmaI/netI    0.0206
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            25569
_diffrn_reflns_theta_full        25.35
_diffrn_reflns_theta_max         25.35
_diffrn_reflns_theta_min         2.34
_exptl_absorpt_coefficient_mu    0.968
_exptl_absorpt_correction_T_max  0.953
_exptl_absorpt_correction_T_min  0.770
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'SADABS2.0 (Sheldrick 2000)'
_exptl_crystal_colour            violet
_exptl_crystal_density_diffrn    1.322
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             548
_exptl_crystal_size_max          0.43
_exptl_crystal_size_mid          0.23
_exptl_crystal_size_min          0.05
_refine_diff_density_max         0.354
_refine_diff_density_min         -0.281
_refine_diff_density_rms         0.059
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.111
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     324
_refine_ls_number_reflns         4783
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.111
_refine_ls_R_factor_all          0.0374
_refine_ls_R_factor_gt           0.0361
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0405P)²+0.9650P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0876
_refine_ls_wR_factor_ref         0.0884
_reflns_number_gt                4629
_reflns_number_total             4783
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b613800d.txt
_cod_data_source_block           sp2ec
_cod_original_cell_volume        1306.05(18)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7004942
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C -0.2484(3) 0.1159(3) 0.6773(2) 0.0389(6) Uani 1 1 d . . .
H1A H -0.1681 0.1791 0.6903 0.058 Uiso 1 1 calc R . .
H1B H -0.3295 0.1532 0.6643 0.058 Uiso 1 1 calc R . .
H1C H -0.2552 0.0358 0.6077 0.058 Uiso 1 1 calc R . .
C2 C -0.2369(2) 0.0848(2) 0.78346(19) 0.0283(5) Uani 1 1 d . . .
C3 C -0.3277(2) -0.0143(2) 0.7926(2) 0.0284(5) Uani 1 1 d . . .
C4 C -0.2795(2) -0.0099(2) 0.90353(19) 0.0264(5) Uani 1 1 d . . .
C5 C -0.1578(2) 0.0910(2) 0.96145(18) 0.0249(4) Uani 1 1 d . . .
C6 C -0.0748(2) 0.1226(2) 1.07190(19) 0.0252(4) Uani 1 1 d . . .
H6 H -0.1003 0.0727 1.1128 0.030 Uiso 1 1 calc R . .
C7 C 0.0450(2) 0.2205(2) 1.13347(18) 0.0245(4) Uani 1 1 d . . .
C8 C 0.1238(2) 0.2627(2) 1.25352(18) 0.0254(4) Uani 1 1 d . . .
C9 C 0.2236(2) 0.3666(2) 1.27390(18) 0.0252(4) Uani 1 1 d . . .
C10 C 0.2035(2) 0.3843(2) 1.16567(18) 0.0251(4) Uani 1 1 d . . .
C11 C 0.2756(2) 0.4817(2) 1.14227(19) 0.0270(5) Uani 1 1 d . . .
H11 H 0.3535 0.5363 1.2031 0.032 Uiso 1 1 calc R . .
C12 C 0.2463(2) 0.5064(2) 1.04268(19) 0.0266(5) Uani 1 1 d . . .
C13 C 0.3244(2) 0.6037(2) 1.0201(2) 0.0285(5) Uani 1 1 d . . .
C14 C 0.2586(2) 0.5952(2) 0.9108(2) 0.0275(5) Uani 1 1 d . . .
C15 C 0.1420(2) 0.4915(2) 0.86631(19) 0.0270(5) Uani 1 1 d . . .
C16 C 0.0427(2) 0.4436(2) 0.7482(2) 0.0333(5) Uani 1 1 d . . .
H16A H 0.0848 0.3948 0.6870 0.050 Uiso 1 1 calc R . .
H16B H 0.0144 0.5181 0.7338 0.050 Uiso 1 1 calc R . .
H16C H -0.0365 0.3863 0.7460 0.050 Uiso 1 1 calc R . .
C17 C -0.4477(2) -0.1062(2) 0.6960(2) 0.0347(5) Uani 1 1 d . . .
H17A H -0.4555 -0.1921 0.7010 0.042 Uiso 1 1 calc R . .
H17B H -0.4312 -0.1188 0.6186 0.042 Uiso 1 1 calc R . .
C18 C -0.5804(3) -0.0606(3) 0.7001(3) 0.0695(11) Uani 1 1 d . . .
H18A H -0.5967 -0.0456 0.7771 0.104 Uiso 1 1 calc R . .
H18B H -0.6541 -0.1274 0.6373 0.104 Uiso 1 1 calc R . .
H18C H -0.5765 0.0209 0.6887 0.104 Uiso 1 1 calc R . .
C19 C -0.3374(2) -0.0921(2) 0.9575(2) 0.0326(5) Uani 1 1 d . . .
H19A H -0.4066 -0.0524 0.9933 0.049 Uiso 1 1 calc R . .
H19B H -0.2652 -0.0984 1.0184 0.049 Uiso 1 1 calc R . .
H19C H -0.3785 -0.1797 0.8961 0.049 Uiso 1 1 calc R . .
C20 C 0.0989(2) 0.2048(2) 1.3383(2) 0.0310(5) Uani 1 1 d . . .
H20A H 0.1860 0.2178 1.3964 0.037 Uiso 1 1 calc R . .
H20B H 0.0653 0.1096 1.2938 0.037 Uiso 1 1 calc R . .
C21 C -0.0023(3) 0.2627(3) 1.4048(3) 0.0541(8) Uani 1 1 d . . .
H21A H 0.0306 0.3569 1.4500 0.081 Uiso 1 1 calc R . .
H21B H -0.0125 0.2215 1.4590 0.081 Uiso 1 1 calc R . .
H21C H -0.0900 0.2472 1.3482 0.081 Uiso 1 1 calc R . .
C22 C 0.3291(2) 0.4512(2) 1.38741(19) 0.0305(5) Uani 1 1 d . . .
H22A H 0.4163 0.4676 1.3695 0.037 Uiso 1 1 calc R . .
H22B H 0.3418 0.4037 1.4395 0.037 Uiso 1 1 calc R . .
C23 C 0.2918(3) 0.5817(3) 1.4530(2) 0.0466(7) Uani 1 1 d . . .
H23A H 0.2784 0.6290 1.4018 0.070 Uiso 1 1 calc R . .
H23B H 0.3649 0.6336 1.5247 0.070 Uiso 1 1 calc R . .
H23C H 0.2080 0.5663 1.4748 0.070 Uiso 1 1 calc R . .
C24 C 0.4553(2) 0.6921(2) 1.1003(2) 0.0387(6) Uani 1 1 d . . .
H24A H 0.5300 0.6453 1.0886 0.058 Uiso 1 1 calc R . .
H24B H 0.4520 0.7202 1.1827 0.058 Uiso 1 1 calc R . .
H24C H 0.4694 0.7688 1.0820 0.058 Uiso 1 1 calc R . .
C25 C 0.3001(2) 0.6694(2) 0.8431(2) 0.0334(5) Uani 1 1 d . . .
H25A H 0.3527 0.7570 0.8993 0.040 Uiso 1 1 calc R . .
H25B H 0.2182 0.6813 0.7937 0.040 Uiso 1 1 calc R . .
C26 C 0.3849(3) 0.5991(3) 0.7646(3) 0.0542(8) Uani 1 1 d . . .
H26A H 0.4671 0.5890 0.8134 0.081 Uiso 1 1 calc R . .
H26B H 0.4098 0.6499 0.7214 0.081 Uiso 1 1 calc R . .
H26C H 0.3326 0.5128 0.7082 0.081 Uiso 1 1 calc R . .
C27 C 0.1615(3) 0.1464(2) 0.7111(2) 0.0380(6) Uani 1 1 d . . .
C28 C 0.3043(3) 0.1962(3) 0.6128(2) 0.0481(7) Uani 1 1 d . . .
N1 N -0.13782(18) 0.14755(17) 0.88186(16) 0.0264(4) Uani 1 1 d . . .
N2 N 0.09634(18) 0.29381(17) 1.08215(15) 0.0249(4) Uani 1 1 d . . .
N3 N 0.13328(18) 0.43891(18) 0.94285(16) 0.0262(4) Uani 1 1 d . . .
N4 N 0.1240(2) 0.1515(2) 0.79208(18) 0.0377(5) Uani 1 1 d . . .
N5 N 0.1924(3) 0.1296(3) 0.6134(2) 0.0538(6) Uani 1 1 d . . .
N6 N 0.3987(3) 0.2480(3) 0.6013(2) 0.0710(8) Uani 1 1 d . . .
Zn Zn 0.03736(2) 0.26291(2) 0.91461(2) 0.02480(9) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 C2 C3 111.9(2) . . ?
N1 C2 C1 122.3(2) . . ?
C3 C2 C1 125.8(2) . . ?
C4 C3 C2 106.38(19) . . ?
C4 C3 C17 127.9(2) . . ?
C2 C3 C17 125.7(2) . . ?
C3 C4 C5 107.05(19) . . ?
C3 C4 C19 127.7(2) . . ?
C5 C4 C19 125.2(2) . . ?
C6 C5 N1 126.2(2) . . ?
C6 C5 C4 125.8(2) . . ?
N1 C5 C4 107.98(18) . . ?
C5 C6 C7 128.4(2) . . ?
N2 C7 C6 121.56(19) . . ?
N2 C7 C8 110.04(18) . . ?
C6 C7 C8 128.3(2) . . ?
C9 C8 C7 106.21(18) . . ?
C9 C8 C20 128.2(2) . . ?
C7 C8 C20 125.6(2) . . ?
C8 C9 C10 106.52(18) . . ?
C8 C9 C22 128.2(2) . . ?
C10 C9 C22 125.2(2) . . ?
N2 C10 C11 121.66(19) . . ?
N2 C10 C9 109.79(19) . . ?
C11 C10 C9 128.51(19) . . ?
C12 C11 C10 127.9(2) . . ?
C11 C12 N3 125.2(2) . . ?
C11 C12 C13 126.5(2) . . ?
N3 C12 C13 108.25(18) . . ?
C14 C13 C12 107.04(19) . . ?
C14 C13 C24 127.2(2) . . ?
C12 C13 C24 125.7(2) . . ?
C13 C14 C15 106.36(19) . . ?
C13 C14 C25 128.7(2) . . ?
C15 C14 C25 124.8(2) . . ?
N3 C15 C14 111.96(19) . . ?
N3 C15 C16 122.3(2) . . ?
C14 C15 C16 125.7(2) . . ?
C3 C17 C18 114.3(2) . . ?
C8 C20 C21 113.9(2) . . ?
C9 C22 C23 112.97(19) . . ?
C14 C25 C26 111.6(2) . . ?
N4 C27 N5 173.6(3) . . ?
N6 C28 N5 173.8(3) . . ?
C2 N1 C5 106.65(18) . . ?
C2 N1 Zn 131.46(16) . . ?
C5 N1 Zn 120.00(14) . . ?
C7 N2 C10 107.42(17) . . ?
C7 N2 Zn 125.88(14) . . ?
C10 N2 Zn 126.46(14) . . ?
C15 N3 C12 106.38(18) . . ?
C15 N3 Zn 129.54(15) . . ?
C12 N3 Zn 120.13(14) . . ?
C27 N4 Zn 142.7(2) . . ?
C27 N5 C28 121.3(3) . . ?
N2 Zn N1 94.92(7) . . ?
N2 Zn N3 93.18(7) . . ?
N1 Zn N3 147.37(8) . . ?
N2 Zn N4 122.59(8) . . ?
N1 Zn N4 103.06(8) . . ?
N3 Zn N4 98.94(8) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C2 1.497(3) . ?
C2 N1 1.325(3) . ?
C2 C3 1.442(3) . ?
C3 C4 1.367(3) . ?
C3 C17 1.503(3) . ?
C4 C5 1.454(3) . ?
C4 C19 1.491(3) . ?
C5 C6 1.369(3) . ?
C5 N1 1.418(3) . ?
C6 C7 1.426(3) . ?
C7 N2 1.360(3) . ?
C7 C8 1.434(3) . ?
C8 C9 1.387(3) . ?
C8 C20 1.503(3) . ?
C9 C10 1.434(3) . ?
C9 C22 1.505(3) . ?
C10 N2 1.362(3) . ?
C10 C11 1.424(3) . ?
C11 C12 1.370(3) . ?
C12 N3 1.420(3) . ?
C12 C13 1.448(3) . ?
C13 C14 1.369(3) . ?
C13 C24 1.498(3) . ?
C14 C15 1.441(3) . ?
C14 C25 1.498(3) . ?
C15 N3 1.326(3) . ?
C15 C16 1.487(3) . ?
C17 C18 1.510(4) . ?
C20 C21 1.521(3) . ?
C22 C23 1.525(3) . ?
C25 C26 1.513(4) . ?
C27 N4 1.155(3) . ?
C27 N5 1.294(3) . ?
C28 N6 1.151(4) . ?
C28 N5 1.318(4) . ?
N1 Zn 1.9870(18) . ?
N2 Zn 1.9623(17) . ?
N3 Zn 1.9947(18) . ?
N4 Zn 2.031(2) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 C2 C3 C4 0.2(3) . . . . ?
C1 C2 C3 C4 179.6(2) . . . . ?
N1 C2 C3 C17 -177.8(2) . . . . ?
C1 C2 C3 C17 1.7(4) . . . . ?
C2 C3 C4 C5 -0.9(2) . . . . ?
C17 C3 C4 C5 177.0(2) . . . . ?
C2 C3 C4 C19 179.6(2) . . . . ?
C17 C3 C4 C19 -2.4(4) . . . . ?
C3 C4 C5 C6 -176.7(2) . . . . ?
C19 C4 C5 C6 2.8(3) . . . . ?
C3 C4 C5 N1 1.3(2) . . . . ?
C19 C4 C5 N1 -179.2(2) . . . . ?
N1 C5 C6 C7 2.8(4) . . . . ?
C4 C5 C6 C7 -179.6(2) . . . . ?
C5 C6 C7 N2 -3.6(3) . . . . ?
C5 C6 C7 C8 172.8(2) . . . . ?
N2 C7 C8 C9 1.2(2) . . . . ?
C6 C7 C8 C9 -175.5(2) . . . . ?
N2 C7 C8 C20 -179.56(19) . . . . ?
C6 C7 C8 C20 3.7(4) . . . . ?
C7 C8 C9 C10 -0.4(2) . . . . ?
C20 C8 C9 C10 -179.5(2) . . . . ?
C7 C8 C9 C22 176.5(2) . . . . ?
C20 C8 C9 C22 -2.6(4) . . . . ?
C8 C9 C10 N2 -0.6(2) . . . . ?
C22 C9 C10 N2 -177.63(19) . . . . ?
C8 C9 C10 C11 177.0(2) . . . . ?
C22 C9 C10 C11 -0.1(4) . . . . ?
N2 C10 C11 C12 5.0(4) . . . . ?
C9 C10 C11 C12 -172.3(2) . . . . ?
C10 C11 C12 N3 1.6(4) . . . . ?
C10 C11 C12 C13 -177.8(2) . . . . ?
C11 C12 C13 C14 -179.7(2) . . . . ?
N3 C12 C13 C14 0.7(2) . . . . ?
C11 C12 C13 C24 2.6(4) . . . . ?
N3 C12 C13 C24 -177.0(2) . . . . ?
C12 C13 C14 C15 -0.9(2) . . . . ?
C24 C13 C14 C15 176.7(2) . . . . ?
C12 C13 C14 C25 -176.8(2) . . . . ?
C24 C13 C14 C25 0.8(4) . . . . ?
C13 C14 C15 N3 0.8(3) . . . . ?
C25 C14 C15 N3 176.9(2) . . . . ?
C13 C14 C15 C16 -177.7(2) . . . . ?
C25 C14 C15 C16 -1.5(4) . . . . ?
C4 C3 C17 C18 87.8(3) . . . . ?
C2 C3 C17 C18 -94.7(3) . . . . ?
C9 C8 C20 C21 92.7(3) . . . . ?
C7 C8 C20 C21 -86.3(3) . . . . ?
C8 C9 C22 C23 -99.7(3) . . . . ?
C10 C9 C22 C23 76.6(3) . . . . ?
C13 C14 C25 C26 90.3(3) . . . . ?
C15 C14 C25 C26 -84.9(3) . . . . ?
C3 C2 N1 C5 0.6(2) . . . . ?
C1 C2 N1 C5 -178.9(2) . . . . ?
C3 C2 N1 Zn 164.50(16) . . . . ?
C1 C2 N1 Zn -15.0(3) . . . . ?
C6 C5 N1 C2 176.8(2) . . . . ?
C4 C5 N1 C2 -1.2(2) . . . . ?
C6 C5 N1 Zn 10.7(3) . . . . ?
C4 C5 N1 Zn -167.26(13) . . . . ?
C6 C7 N2 C10 175.37(19) . . . . ?
C8 C7 N2 C10 -1.6(2) . . . . ?
C6 C7 N2 Zn -10.1(3) . . . . ?
C8 C7 N2 Zn 172.95(14) . . . . ?
C11 C10 N2 C7 -176.40(19) . . . . ?
C9 C10 N2 C7 1.4(2) . . . . ?
C11 C10 N2 Zn 9.1(3) . . . . ?
C9 C10 N2 Zn -173.16(14) . . . . ?
C14 C15 N3 C12 -0.3(2) . . . . ?
C16 C15 N3 C12 178.2(2) . . . . ?
C14 C15 N3 Zn -157.42(15) . . . . ?
C16 C15 N3 Zn 21.1(3) . . . . ?
C11 C12 N3 C15 -179.8(2) . . . . ?
C13 C12 N3 C15 -0.2(2) . . . . ?
C11 C12 N3 Zn -20.1(3) . . . . ?
C13 C12 N3 Zn 159.46(14) . . . . ?
N5 C27 N4 Zn -112(2) . . . . ?
N4 C27 N5 C28 -172(2) . . . . ?
N6 C28 N5 C27 178(3) . . . . ?
C7 N2 Zn N1 17.69(18) . . . . ?
C10 N2 Zn N1 -168.76(18) . . . . ?
C7 N2 Zn N3 166.05(18) . . . . ?
C10 N2 Zn N3 -20.40(18) . . . . ?
C7 N2 Zn N4 -91.23(19) . . . . ?
C10 N2 Zn N4 82.32(19) . . . . ?
C2 N1 Zn N2 -179.2(2) . . . . ?
C5 N1 Zn N2 -17.09(16) . . . . ?
C2 N1 Zn N3 77.1(2) . . . . ?
C5 N1 Zn N3 -120.84(17) . . . . ?
C2 N1 Zn N4 -54.1(2) . . . . ?
C5 N1 Zn N4 108.01(16) . . . . ?
C15 N3 Zn N2 178.88(19) . . . . ?
C12 N3 Zn N2 24.48(16) . . . . ?
C15 N3 Zn N1 -76.9(2) . . . . ?
C12 N3 Zn N1 128.72(17) . . . . ?
C15 N3 Zn N4 55.2(2) . . . . ?
C12 N3 Zn N4 -99.23(16) . . . . ?
C27 N4 Zn N2 -138.3(3) . . . . ?
C27 N4 Zn N1 117.1(3) . . . . ?
C27 N4 Zn N3 -38.6(3) . . . . ?
