#------------------------------------------------------------------------------
#$Date: 2016-03-25 09:44:48 +0100 (vie 25 de mar de 2016) $
#$Revision: 179762 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/58/7005859.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7005859
loop_
_publ_author_name
'Sun, Yan-Qiong'
'Yang, Guo-Yu'
_publ_section_title
;
 Organic-inorganic hybrid materials constructed from inorganic
 lanthanide sulfate skeletons and organic 4,5-imidazoledicarboxylic
 acid.
;
_journal_issue                   34
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              3771
_journal_page_last               3781
_journal_paper_doi               10.1039/b706072f
_journal_year                    2007
_chemical_formula_sum            'C20 H36 Cu Eu6 N8 O54 S6'
_chemical_formula_weight         2420.23
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                96.778(2)
_cell_angle_beta                 94.307(4)
_cell_angle_gamma                97.886(4)
_cell_formula_units_Z            1
_cell_length_a                   6.6280(5)
_cell_length_b                   9.4648(7)
_cell_length_c                   21.5033(15)
_cell_measurement_reflns_used    3751
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.4835
_cell_measurement_theta_min      3.0910
_cell_volume                     1321.14(17)
_computing_cell_refinement       'CrystalClear (Rigaku Corp., 2000)'
_computing_data_collection       'CrystalClear (Rigaku Corp., 2000)'
_computing_data_reduction        'CrystalClear (Rigaku Corp., 2000)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 14.6306
_diffrn_measured_fraction_theta_full 0.982
_diffrn_measured_fraction_theta_max 0.982
_diffrn_measurement_device_type
;
Mercury70 (2x2 bin mode)
;
_diffrn_measurement_method       dtprofit.ref
_diffrn_radiation_monochromator  'Graphite Monochromator'
_diffrn_radiation_source         'Rotating Anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0240
_diffrn_reflns_av_sigmaI/netI    0.0387
_diffrn_reflns_limit_h_max       7
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            10190
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_reflns_theta_min         3.09
_exptl_absorpt_coefficient_mu    7.791
_exptl_absorpt_correction_T_max  0.459
_exptl_absorpt_correction_T_min  0.256
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            blue
_exptl_crystal_density_diffrn    3.042
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1147
_exptl_crystal_size_max          0.3000
_exptl_crystal_size_mid          0.1500
_exptl_crystal_size_min          0.1000
_refine_diff_density_max         2.156
_refine_diff_density_min         -2.175
_refine_diff_density_rms         0.212
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.065
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     430
_refine_ls_number_reflns         5932
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.065
_refine_ls_R_factor_all          0.0354
_refine_ls_R_factor_gt           0.0308
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0388P)²+3.1974P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0745
_refine_ls_wR_factor_ref         0.0790
_reflns_number_gt                5340
_reflns_number_total             5932
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b706072f.txt
_cod_data_source_block           syq-160
_cod_depositor_comments
;
The following automatic conversions were performed:
'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
'/home/saulius/struct/CIF-dictionaries/cif_core.dic' dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7005859
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.93626(4) 0.11837(3) 0.321871(11) 0.01092(7) Uani 1 1 d . . .
Eu2 Eu 0.65242(4) -0.29082(2) 0.422202(11) 0.01019(7) Uani 1 1 d . . .
Eu3 Eu 1.67536(4) -0.01347(3) 0.138756(12) 0.01554(8) Uani 1 1 d . . .
Cu Cu 1.0000 0.5000 0.0000 0.0180(2) Uani 1 2 d S . .
S1 S 1.2323(2) 0.06525(15) 0.18550(6) 0.0182(3) Uani 1 1 d . . .
S2 S 1.33150(19) 0.35751(13) 0.43562(5) 0.0110(2) Uani 1 1 d . . .
S3 S 1.15329(19) -0.18125(13) 0.37622(6) 0.0125(2) Uani 1 1 d . . .
C1 C 1.0796(9) 0.6167(6) 0.1493(3) 0.0208(11) Uani 1 1 d . . .
H1A H 1.1444 0.7105 0.1498 0.025 Uiso 1 1 calc R . .
C2 C 0.9280(8) 0.4011(5) 0.1174(2) 0.0143(10) Uani 1 1 d . . .
C3 C 0.9421(8) 0.4170(6) 0.1822(2) 0.0149(10) Uani 1 1 d . . .
C4 C 0.8903(8) 0.3198(5) 0.2303(2) 0.0147(10) Uani 1 1 d . . .
C5 C 0.8214(8) 0.2886(5) 0.0675(2) 0.0155(10) Uani 1 1 d . . .
C6 C 0.4776(8) -0.5286(5) 0.2819(2) 0.0166(11) Uani 1 1 d . . .
H6A H 0.4311 -0.6049 0.3032 0.020 Uiso 1 1 calc R . .
C7 C 0.5516(8) -0.4047(5) 0.2044(2) 0.0134(10) Uani 1 1 d . . .
C8 C 0.6018(8) -0.3187(5) 0.2612(2) 0.0135(10) Uani 1 1 d . . .
C9 C 0.5662(8) -0.3836(6) 0.1374(2) 0.0160(10) Uani 1 1 d . . .
C10 C 0.7015(7) -0.1688(5) 0.2806(2) 0.0121(9) Uani 1 1 d . . .
N1 N 1.0159(7) 0.5261(5) 0.0975(2) 0.0170(9) Uani 1 1 d . . .
N2 N 1.0379(7) 0.5548(5) 0.2008(2) 0.0173(9) Uani 1 1 d . . .
H2A H 1.0666 0.5950 0.2390 0.021 Uiso 1 1 calc R . .
N3 N 0.4743(7) -0.5370(5) 0.2190(2) 0.0163(9) Uani 1 1 d . . .
H3A H 0.4311 -0.6125 0.1925 0.020 Uiso 1 1 calc R . .
N4 N 0.5549(7) -0.3986(4) 0.30956(19) 0.0138(9) Uani 1 1 d . . .
O1 O 0.9510(6) 0.3646(4) 0.28647(18) 0.0224(9) Uani 1 1 d . . .
O2 O 0.7955(6) 0.1929(4) 0.21474(17) 0.0160(7) Uani 1 1 d . . .
O3 O 0.7257(7) 0.1748(4) 0.08115(19) 0.0245(9) Uani 1 1 d . . .
O4 O 0.8271(6) 0.3147(4) 0.01171(17) 0.0216(9) Uani 1 1 d . . .
O5 O 0.5301(7) -0.4940(4) 0.09811(18) 0.0238(9) Uani 1 1 d . . .
O6 O 0.6156(7) -0.2597(4) 0.12448(18) 0.0258(9) Uani 1 1 d . . .
O7 O 0.7708(6) -0.0866(4) 0.24256(16) 0.0146(7) Uani 1 1 d . . .
O8 O 0.7221(5) -0.1254(4) 0.33919(16) 0.0143(7) Uani 1 1 d . . .
O9 O 1.1905(6) 0.1247(4) 0.24923(18) 0.0223(9) Uani 1 1 d . . .
O10 O 1.3346(10) 0.1772(6) 0.1542(2) 0.0603(19) Uani 1 1 d . . .
O11 O 1.3701(7) -0.0432(6) 0.1923(2) 0.0441(13) Uani 1 1 d . . .
O12 O 1.0418(6) -0.0032(5) 0.14949(18) 0.0252(9) Uani 1 1 d . . .
O13 O 1.4908(6) 0.2846(4) 0.46372(19) 0.0227(8) Uani 1 1 d . . .
O14 O 1.4127(6) 0.4994(4) 0.42151(18) 0.0203(8) Uani 1 1 d . . .
O15 O 1.2281(6) 0.2709(4) 0.37810(16) 0.0181(8) Uani 1 1 d . . .
O16 O 1.1811(6) 0.3705(4) 0.48352(16) 0.0158(7) Uani 1 1 d . . .
O17 O 1.0088(6) -0.2047(5) 0.42445(19) 0.0234(9) Uani 1 1 d . . .
O18 O 1.1528(6) -0.0336(4) 0.3602(2) 0.0300(10) Uani 1 1 d . . .
O19 O 1.3586(6) -0.1873(4) 0.40534(19) 0.0226(8) Uani 1 1 d . . .
O20 O 1.0970(7) -0.2856(5) 0.3212(2) 0.0365(11) Uani 1 1 d . . .
O1W O 0.8425(6) -0.4977(4) 0.39729(18) 0.0252(9) Uani 1 1 d . . .
O2W O 0.5713(6) 0.1353(5) 0.32367(19) 0.0253(9) Uani 1 1 d . . .
O3W O 1.3964(7) -0.0690(4) 0.05513(19) 0.0259(9) Uani 1 1 d . . .
O4W O 1.2634(7) 0.3867(5) 0.00165(19) 0.0317(10) Uani 1 1 d . . .
O5W O 0.7250(7) -0.0579(4) 0.48745(19) 0.0280(10) Uani 1 1 d . . .
O6W O 1.8267(8) -0.0951(5) 0.0340(2) 0.0343(11) Uani 1 1 d . . .
O7W O 0.8475(6) 0.1856(4) 0.42874(18) 0.0202(8) Uani 1 1 d . . .
H11 H 0.9044 -0.5114 0.4314 0.080 Uiso 1 1 d R . .
H12 H 0.9193 -0.5131 0.3672 0.080 Uiso 1 1 d R . .
H21 H 0.4949 0.1209 0.2873 0.080 Uiso 1 1 d R . .
H22 H 0.4997 0.0817 0.3528 0.080 Uiso 1 1 d R . .
H31 H 1.2749 -0.0692 0.0757 0.080 Uiso 1 1 d R . .
H32 H 1.3996 0.0102 0.0321 0.080 Uiso 1 1 d R . .
H41 H 1.3419 0.4212 0.0382 0.080 Uiso 1 1 d R . .
H42 H 1.3437 0.3931 -0.0310 0.080 Uiso 1 1 d R . .
H51 H 0.7929 0.0180 0.4789 0.080 Uiso 1 1 d R . .
H52 H 0.6770 -0.0388 0.5227 0.080 Uiso 1 1 d R . .
H61 H 1.7687 -0.1800 0.0222 0.080 Uiso 1 1 d R . .
H62 H 1.9450 -0.0965 0.0488 0.080 Uiso 1 1 d R . .
H72 H 0.9254 0.2489 0.4575 0.080 Uiso 1 1 d R . .
H71 H 0.7201 0.2052 0.4280 0.080 Uiso 1 1 d R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O18 Eu1 O9 77.99(16) . . ?
O18 Eu1 O15 73.38(14) . . ?
O9 Eu1 O15 75.41(12) . . ?
O18 Eu1 O7W 89.92(16) . . ?
O9 Eu1 O7W 147.98(13) . . ?
O15 Eu1 O7W 72.73(12) . . ?
O18 Eu1 O2W 134.87(15) . . ?
O9 Eu1 O2W 139.02(14) . . ?
O15 Eu1 O2W 130.02(14) . . ?
O7W Eu1 O2W 68.36(13) . . ?
O18 Eu1 O7 88.73(14) . . ?
O9 Eu1 O7 81.31(12) . . ?
O15 Eu1 O7 153.02(13) . . ?
O7W Eu1 O7 128.47(12) . . ?
O2W Eu1 O7 76.86(13) . . ?
O18 Eu1 O1 140.42(14) . . ?
O9 Eu1 O1 75.59(14) . . ?
O15 Eu1 O1 71.79(13) . . ?
O7W Eu1 O1 97.16(13) . . ?
O2W Eu1 O1 83.10(14) . . ?
O7 Eu1 O1 115.44(12) . . ?
O18 Eu1 O8 69.98(13) . . ?
O9 Eu1 O8 120.96(13) . . ?
O15 Eu1 O8 134.34(12) . . ?
O7W Eu1 O8 80.84(12) . . ?
O2W Eu1 O8 67.85(13) . . ?
O7 Eu1 O8 50.68(11) . . ?
O1 Eu1 O8 149.58(13) . . ?
O18 Eu1 O2 140.18(15) . . ?
O9 Eu1 O2 69.03(13) . . ?
O15 Eu1 O2 116.97(12) . . ?
O7W Eu1 O2 129.76(13) . . ?
O2W Eu1 O2 70.41(13) . . ?
O7 Eu1 O2 65.27(11) . . ?
O1 Eu1 O2 50.19(11) . . ?
O8 Eu1 O2 108.60(11) . . ?
O18 Eu1 C4 143.80(15) . . ?
O9 Eu1 C4 66.15(15) . . ?
O15 Eu1 C4 92.32(14) . . ?
O7W Eu1 C4 117.95(14) . . ?
O2W Eu1 C4 79.73(15) . . ?
O7 Eu1 C4 90.55(13) . . ?
O1 Eu1 C4 25.14(13) . . ?
O8 Eu1 C4 133.21(13) . . ?
O2 Eu1 C4 25.76(12) . . ?
O18 Eu1 C10 77.58(14) . . ?
O9 Eu1 C10 100.89(14) . . ?
O15 Eu1 C10 150.87(14) . . ?
O7W Eu1 C10 105.31(13) . . ?
O2W Eu1 C10 71.41(14) . . ?
O7 Eu1 C10 25.18(12) . . ?
O1 Eu1 C10 136.12(13) . . ?
O8 Eu1 C10 25.53(12) . . ?
O2 Eu1 C10 87.16(12) . . ?
C4 Eu1 C10 112.91(14) . . ?
O18 Eu1 Eu3 114.54(12) . 1_455 ?
O9 Eu1 Eu3 68.94(9) . 1_455 ?
O15 Eu1 Eu3 140.13(9) . 1_455 ?
O7W Eu1 Eu3 141.99(9) . 1_455 ?
O2W Eu1 Eu3 73.89(10) . 1_455 ?
O7 Eu1 Eu3 33.15(8) . 1_455 ?
O1 Eu1 Eu3 82.39(8) . 1_455 ?
O8 Eu1 Eu3 81.08(7) . 1_455 ?
O2 Eu1 Eu3 32.44(8) . 1_455 ?
C4 Eu1 Eu3 57.41(10) . 1_455 ?
C10 Eu1 Eu3 56.82(10) . 1_455 ?
O19 Eu2 O14 82.57(14) 1_455 1_445 ?
O19 Eu2 O17 133.62(14) 1_455 . ?
O14 Eu2 O17 143.41(15) 1_445 . ?
O19 Eu2 O5W 75.78(15) 1_455 . ?
O14 Eu2 O5W 134.66(14) 1_445 . ?
O17 Eu2 O5W 71.62(15) . . ?
O19 Eu2 O16 132.84(13) 1_455 2_756 ?
O14 Eu2 O16 84.46(13) 1_445 2_756 ?
O17 Eu2 O16 73.73(12) . 2_756 ?
O5W Eu2 O16 82.04(14) . 2_756 ?
O19 Eu2 O1W 148.37(14) 1_455 . ?
O14 Eu2 O1W 74.08(14) 1_445 . ?
O17 Eu2 O1W 70.38(14) . . ?
O5W Eu2 O1W 135.82(15) . . ?
O16 Eu2 O1W 66.39(12) 2_756 . ?
O19 Eu2 N4 81.96(15) 1_455 . ?
O14 Eu2 N4 72.08(13) 1_445 . ?
O17 Eu2 N4 103.50(14) . . ?
O5W Eu2 N4 140.67(14) . . ?
O16 Eu2 N4 135.38(13) 2_756 . ?
O1W Eu2 N4 70.83(14) . . ?
O19 Eu2 O8 73.60(13) 1_455 . ?
O14 Eu2 O8 131.53(12) 1_445 . ?
O17 Eu2 O8 68.69(13) . . ?
O5W Eu2 O8 79.31(12) . . ?
O16 Eu2 O8 141.66(11) 2_756 . ?
O1W Eu2 O8 106.50(13) . . ?
N4 Eu2 O8 63.35(12) . . ?
O19 Eu2 O13 78.81(13) 1_455 2_756 ?
O14 Eu2 O13 71.93(13) 1_445 2_756 ?
O17 Eu2 O13 114.43(13) . 2_756 ?
O5W Eu2 O13 65.11(13) . 2_756 ?
O16 Eu2 O13 54.07(12) 2_756 2_756 ?
O1W Eu2 O13 112.65(13) . 2_756 ?
N4 Eu2 O13 140.92(13) . 2_756 ?
O8 Eu2 O13 139.27(12) . 2_756 ?
O19 Eu2 S2 106.05(10) 1_455 2_756 ?
O14 Eu2 S2 74.55(9) 1_445 2_756 ?
O17 Eu2 S2 95.70(10) . 2_756 ?
O5W Eu2 S2 73.98(10) . 2_756 ?
O16 Eu2 S2 26.98(8) 2_756 2_756 ?
O1W Eu2 S2 88.19(9) . 2_756 ?
N4 Eu2 S2 144.29(9) . 2_756 ?
O8 Eu2 S2 152.33(8) . 2_756 ?
O13 Eu2 S2 27.28(9) 2_756 2_756 ?
O3 Eu3 O6 139.85(14) 1_655 1_655 ?
O3 Eu3 O2 75.08(13) 1_655 1_655 ?
O6 Eu3 O2 143.68(13) 1_655 1_655 ?
O3 Eu3 O11 118.16(17) 1_655 . ?
O6 Eu3 O11 82.32(18) 1_655 . ?
O2 Eu3 O11 87.40(15) 1_655 . ?
O3 Eu3 O12 87.04(15) 1_655 1_655 ?
O6 Eu3 O12 93.61(16) 1_655 1_655 ?
O2 Eu3 O12 75.39(13) 1_655 1_655 ?
O11 Eu3 O12 144.91(15) . 1_655 ?
O3 Eu3 O3W 76.26(14) 1_655 . ?
O6 Eu3 O3W 76.75(15) 1_655 . ?
O2 Eu3 O3W 133.68(14) 1_655 . ?
O11 Eu3 O3W 75.15(15) . . ?
O12 Eu3 O3W 137.97(14) 1_655 . ?
O3 Eu3 O7 142.17(12) 1_655 1_655 ?
O6 Eu3 O7 74.53(13) 1_655 1_655 ?
O2 Eu3 O7 69.15(12) 1_655 1_655 ?
O11 Eu3 O7 72.70(14) . 1_655 ?
O12 Eu3 O7 72.63(13) 1_655 1_655 ?
O3W Eu3 O7 139.10(13) . 1_655 ?
O3 Eu3 O6W 69.94(15) 1_655 . ?
O6 Eu3 O6W 73.67(14) 1_655 . ?
O2 Eu3 O6W 128.50(13) 1_655 . ?
O11 Eu3 O6W 142.56(16) . . ?
O12 Eu3 O6W 66.35(14) 1_655 . ?
O3W Eu3 O6W 71.70(15) . . ?
O7 Eu3 O6W 125.32(14) 1_655 . ?
O3 Eu3 O10 69.33(14) 1_655 . ?
O6 Eu3 O10 123.67(14) 1_655 . ?
O2 Eu3 O10 70.21(13) 1_655 . ?
O11 Eu3 O10 49.03(16) . . ?
O12 Eu3 O10 142.10(13) 1_655 . ?
O3W Eu3 O10 65.94(14) . . ?
O7 Eu3 O10 108.23(13) 1_655 . ?
O6W Eu3 O10 126.38(15) . . ?
O3 Eu3 S1 94.63(12) 1_655 . ?
O6 Eu3 S1 101.48(12) 1_655 . ?
O2 Eu3 S1 79.96(9) 1_655 . ?
O11 Eu3 S1 23.54(14) . . ?
O12 Eu3 S1 153.99(10) 1_655 . ?
O3W Eu3 S1 66.95(11) . . ?
O7 Eu3 S1 91.00(9) 1_655 . ?
O6W Eu3 S1 138.28(11) . . ?
O10 Eu3 S1 25.63(9) . . ?
O3 Eu3 Eu1 109.28(10) 1_655 1_655 ?
O6 Eu3 Eu1 107.71(10) 1_655 1_655 ?
O2 Eu3 Eu1 36.07(9) 1_655 1_655 ?
O11 Eu3 Eu1 81.32(11) . 1_655 ?
O12 Eu3 Eu1 66.69(9) 1_655 1_655 ?
O3W Eu3 Eu1 155.29(10) . 1_655 ?
O7 Eu3 Eu1 33.44(8) 1_655 1_655 ?
O6W Eu3 Eu1 133.00(11) . 1_655 ?
O10 Eu3 Eu1 92.92(9) . 1_655 ?
S1 Eu3 Eu1 88.43(2) . 1_655 ?
O4 Cu O4 180.0(2) . 2_765 ?
O4 Cu N1 98.85(15) . 2_765 ?
O4 Cu N1 81.15(15) 2_765 2_765 ?
O4 Cu N1 81.15(15) . . ?
O4 Cu N1 98.85(15) 2_765 . ?
N1 Cu N1 180.0(2) 2_765 . ?
O4 Cu O4W 88.04(17) . . ?
O4 Cu O4W 91.96(17) 2_765 . ?
N1 Cu O4W 89.22(17) 2_765 . ?
N1 Cu O4W 90.78(17) . . ?
O4 Cu O4W 91.96(17) . 2_765 ?
O4 Cu O4W 88.04(17) 2_765 2_765 ?
N1 Cu O4W 90.78(17) 2_765 2_765 ?
N1 Cu O4W 89.22(17) . 2_765 ?
O4W Cu O4W 180.0 . 2_765 ?
O10 S1 O12 111.1(3) . . ?
O10 S1 O11 108.2(4) . . ?
O12 S1 O11 109.4(3) . . ?
O10 S1 O9 110.2(3) . . ?
O12 S1 O9 109.9(2) . . ?
O11 S1 O9 108.0(3) . . ?
O10 S1 Eu3 68.1(3) . . ?
O12 S1 Eu3 119.47(17) . . ?
O11 S1 Eu3 40.5(2) . . ?
O9 S1 Eu3 127.57(17) . . ?
O14 S2 O15 109.4(2) . . ?
O14 S2 O13 112.2(2) . . ?
O15 S2 O13 110.8(2) . . ?
O14 S2 O16 109.8(2) . . ?
O15 S2 O16 109.0(2) . . ?
O13 S2 O16 105.6(2) . . ?
O14 S2 Eu2 120.04(16) . 2_756 ?
O15 S2 Eu2 130.10(16) . 2_756 ?
O13 S2 Eu2 57.14(17) . 2_756 ?
O16 S2 Eu2 48.91(15) . 2_756 ?
O20 S3 O19 112.5(3) . . ?
O20 S3 O18 110.8(3) . . ?
O19 S3 O18 107.0(2) . . ?
O20 S3 O17 110.8(3) . . ?
O19 S3 O17 107.3(2) . . ?
O18 S3 O17 108.3(3) . . ?
N1 C1 N2 110.9(5) . . ?
N1 C1 H1A 124.6 . . ?
N2 C1 H1A 124.6 . . ?
N1 C2 C3 109.6(4) . . ?
N1 C2 C5 116.0(4) . . ?
C3 C2 C5 134.0(5) . . ?
N2 C3 C2 105.1(4) . . ?
N2 C3 C4 119.9(4) . . ?
C2 C3 C4 134.9(5) . . ?
O1 C4 O2 120.7(5) . . ?
O1 C4 C3 117.8(5) . . ?
O2 C4 C3 121.4(4) . . ?
O1 C4 Eu1 59.3(3) . . ?
O2 C4 Eu1 64.0(3) . . ?
C3 C4 Eu1 160.3(4) . . ?
O3 C5 O4 122.1(5) . . ?
O3 C5 C2 120.8(5) . . ?
O4 C5 C2 117.1(4) . . ?
N4 C6 N3 111.5(4) . . ?
N4 C6 H6A 124.2 . . ?
N3 C6 H6A 124.2 . . ?
N3 C7 C8 105.5(4) . . ?
N3 C7 C9 119.5(4) . . ?
C8 C7 C9 135.0(5) . . ?
C7 C8 N4 109.4(4) . . ?
C7 C8 C10 134.7(5) . . ?
N4 C8 C10 115.8(4) . . ?
O6 C9 O5 124.9(5) . . ?
O6 C9 C7 118.6(4) . . ?
O5 C9 C7 116.5(5) . . ?
O7 C10 O8 119.9(4) . . ?
O7 C10 C8 123.5(4) . . ?
O8 C10 C8 116.6(4) . . ?
O7 C10 Eu1 57.2(2) . . ?
O8 C10 Eu1 62.8(2) . . ?
C8 C10 Eu1 174.6(4) . . ?
C1 N1 C2 105.9(4) . . ?
C1 N1 Cu 144.7(4) . . ?
C2 N1 Cu 109.4(3) . . ?
C1 N2 C3 108.6(4) . . ?
C1 N2 H2A 125.7 . . ?
C3 N2 H2A 125.7 . . ?
C6 N3 C7 108.1(4) . . ?
C6 N3 H3A 125.9 . . ?
C7 N3 H3A 125.9 . . ?
C6 N4 C8 105.5(4) . . ?
C6 N4 Eu2 133.9(3) . . ?
C8 N4 Eu2 120.3(3) . . ?
C4 O1 Eu1 95.6(3) . . ?
C4 O2 Eu3 151.9(3) . 1_455 ?
C4 O2 Eu1 90.2(3) . . ?
Eu3 O2 Eu1 111.49(14) 1_455 . ?
C5 O3 Eu3 154.1(4) . 1_455 ?
C5 O4 Cu 115.6(3) . . ?
C9 O6 Eu3 158.3(4) . 1_455 ?
C10 O7 Eu3 140.4(3) . 1_455 ?
C10 O7 Eu1 97.6(3) . . ?
Eu3 O7 Eu1 113.41(13) 1_455 . ?
C10 O8 Eu2 123.3(3) . . ?
C10 O8 Eu1 91.6(3) . . ?
Eu2 O8 Eu1 142.05(14) . . ?
S1 O9 Eu1 142.9(2) . . ?
S1 O10 Eu3 86.3(3) . . ?
S1 O11 Eu3 116.0(3) . . ?
S1 O12 Eu3 145.3(3) . 1_455 ?
S2 O13 Eu2 95.58(19) . 2_756 ?
S2 O14 Eu2 158.0(3) . 1_665 ?
S2 O15 Eu1 151.1(2) . . ?
S2 O16 Eu2 104.11(19) . 2_756 ?
S3 O17 Eu2 135.0(2) . . ?
S3 O18 Eu1 142.1(2) . . ?
S3 O19 Eu2 154.8(3) . 1_655 ?
Eu2 O1W H11 107.0 . . ?
Eu2 O1W H12 129.0 . . ?
H11 O1W H12 108.7 . . ?
Eu1 O2W H21 117.9 . . ?
Eu1 O2W H22 116.1 . . ?
H21 O2W H22 108.2 . . ?
Eu3 O3W H31 105.4 . . ?
Eu3 O3W H32 108.0 . . ?
H31 O3W H32 104.6 . . ?
Cu O4W H41 107.0 . . ?
Cu O4W H42 117.1 . . ?
H41 O4W H42 108.6 . . ?
Eu2 O5W H51 127.5 . . ?
Eu2 O5W H52 124.3 . . ?
H51 O5W H52 108.0 . . ?
Eu3 O6W H61 105.7 . . ?
Eu3 O6W H62 97.9 . . ?
H61 O6W H62 109.5 . . ?
Eu1 O7W H72 124.5 . . ?
Eu1 O7W H71 110.5 . . ?
H72 O7W H71 108.6 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O18 2.340(4) . ?
Eu1 O9 2.382(4) . ?
Eu1 O15 2.400(4) . ?
Eu1 O7W 2.448(4) . ?
Eu1 O2W 2.449(4) . ?
Eu1 O7 2.496(3) . ?
Eu1 O1 2.527(4) . ?
Eu1 O8 2.619(3) . ?
Eu1 O2 2.630(4) . ?
Eu1 C4 2.925(5) . ?
Eu1 C10 2.943(5) . ?
Eu1 Eu3 4.1566(4) 1_455 ?
Eu2 O19 2.320(4) 1_455 ?
Eu2 O14 2.364(4) 1_445 ?
Eu2 O17 2.386(4) . ?
Eu2 O5W 2.437(4) . ?
Eu2 O16 2.480(4) 2_756 ?
Eu2 O1W 2.498(4) . ?
Eu2 N4 2.515(4) . ?
Eu2 O8 2.537(3) . ?
Eu2 O13 2.693(4) 2_756 ?
Eu2 S2 3.1909(12) 2_756 ?
Eu3 O3 2.289(4) 1_655 ?
Eu3 O6 2.290(4) 1_655 ?
Eu3 O2 2.397(3) 1_655 ?
Eu3 O11 2.402(5) . ?
Eu3 O12 2.410(4) 1_655 ?
Eu3 O3W 2.437(4) . ?
Eu3 O7 2.477(3) 1_655 ?
Eu3 O6W 2.612(5) . ?
Eu3 O10 3.091(7) . ?
Eu3 S1 3.3253(14) . ?
Eu3 Eu1 4.1566(4) 1_655 ?
Cu O4 2.012(4) . ?
Cu O4 2.012(4) 2_765 ?
Cu N1 2.075(4) 2_765 ?
Cu N1 2.075(4) . ?
Cu O4W 2.171(5) . ?
Cu O4W 2.171(5) 2_765 ?
S1 O10 1.441(5) . ?
S1 O12 1.457(4) . ?
S1 O11 1.477(5) . ?
S1 O9 1.479(4) . ?
S2 O14 1.452(4) . ?
S2 O15 1.466(4) . ?
S2 O13 1.470(4) . ?
S2 O16 1.493(4) . ?
S2 Eu2 3.1909(12) 2_756 ?
S3 O20 1.439(4) . ?
S3 O19 1.466(4) . ?
S3 O18 1.479(4) . ?
S3 O17 1.479(4) . ?
C1 N1 1.326(7) . ?
C1 N2 1.342(7) . ?
C1 H1A 0.9300 . ?
C2 N1 1.375(6) . ?
C2 C3 1.380(7) . ?
C2 C5 1.481(7) . ?
C3 N2 1.370(6) . ?
C3 C4 1.492(7) . ?
C4 O1 1.248(6) . ?
C4 O2 1.271(6) . ?
C5 O3 1.251(6) . ?
C5 O4 1.256(6) . ?
C6 N4 1.319(6) . ?
C6 N3 1.343(6) . ?
C6 H6A 0.9300 . ?
C7 N3 1.368(7) . ?
C7 C8 1.376(7) . ?
C7 C9 1.487(7) . ?
C8 N4 1.386(6) . ?
C8 C10 1.478(7) . ?
C9 O6 1.242(7) . ?
C9 O5 1.247(6) . ?
C10 O7 1.263(6) . ?
C10 O8 1.269(6) . ?
N2 H2A 0.8600 . ?
N3 H3A 0.8600 . ?
O2 Eu3 2.397(3) 1_455 ?
O3 Eu3 2.289(4) 1_455 ?
O6 Eu3 2.290(4) 1_455 ?
O7 Eu3 2.477(3) 1_455 ?
O12 Eu3 2.410(4) 1_455 ?
O13 Eu2 2.693(4) 2_756 ?
O14 Eu2 2.364(4) 1_665 ?
O16 Eu2 2.480(4) 2_756 ?
O19 Eu2 2.320(4) 1_655 ?
O1W H11 0.8447 . ?
O1W H12 0.8635 . ?
O2W H21 0.8858 . ?
O2W H22 0.9632 . ?
O3W H31 0.9475 . ?
O3W H32 0.9453 . ?
O4W H41 0.9083 . ?
O4W H42 0.9142 . ?
O5W H51 0.8411 . ?
O5W H52 0.8539 . ?
O6W H61 0.8425 . ?
O6W H62 0.8265 . ?
O7W H72 0.8874 . ?
O7W H71 0.8887 . ?
