#------------------------------------------------------------------------------
#$Date: 2016-03-25 09:47:24 +0100 (vie 25 de mar de 2016) $
#$Revision: 179764 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/60/7006035.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7006035
loop_
_publ_author_name
'Hrib, Cristian G.'
'Jeske, Jörg'
'Jones, Peter G.'
'du Mont, Wolf-W'
_publ_section_title
;
 Telluroselenophosphonium ions: their unusual soft-soft interactions
 with iodotellurate anions.
;
_journal_issue                   32
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              3483
_journal_page_last               3485
_journal_paper_doi               10.1039/b708370j
_journal_year                    2007
_chemical_formula_sum            'C19 H41 Cl2 I8 P2 Se2 Te3'
_chemical_formula_weight         1958.28
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.470(3)
_cell_angle_beta                 92.610(3)
_cell_angle_gamma                92.474(3)
_cell_formula_units_Z            2
_cell_length_a                   10.9947(8)
_cell_length_b                   12.4377(10)
_cell_length_c                   16.7112(14)
_cell_measurement_reflns_used    7943
_cell_measurement_temperature    133(2)
_cell_measurement_theta_max      2
_cell_measurement_theta_min      60
_cell_volume                     2280.6(3)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Siemens XP'
_computing_publication_material  SHELXL-97
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      133(2)
_diffrn_detector_area_resol_mean 8.192
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'Bruker SMART 1000 CCD'
_diffrn_measurement_method       'ω- and φ-scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0389
_diffrn_reflns_av_sigmaI/netI    0.0429
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            49396
_diffrn_reflns_theta_full        30.00
_diffrn_reflns_theta_max         30.52
_diffrn_reflns_theta_min         1.64
_diffrn_standards_decay_%        0
_exptl_absorpt_coefficient_mu    9.117
_exptl_absorpt_correction_T_max  0.4625
_exptl_absorpt_correction_T_min  0.3129
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    2.852
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       tablet
_exptl_crystal_F_000             1734
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.10
_refine_diff_density_max         3.225
_refine_diff_density_min         -2.254
_refine_diff_density_rms         0.239
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.031
_refine_ls_hydrogen_treatment    'methyls rigid and other riding'
_refine_ls_matrix_type           full
_refine_ls_number_parameters     331
_refine_ls_number_reflns         13835
_refine_ls_number_restraints     91
_refine_ls_restrained_S_all      1.028
_refine_ls_R_factor_all          0.0644
_refine_ls_R_factor_gt           0.0370
_refine_ls_shift/su_max          0.009
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0451P)²+5.9270P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0827
_refine_ls_wR_factor_ref         0.0950
_reflns_number_gt                10090
_reflns_number_total             13835
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b708370j.txt
_cod_data_source_block           alun
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7006035
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Te1 Te 0.62119(4) 0.85613(3) 0.318990(19) 0.02428(8) Uani 1 1 d . . .
Te2 Te 0.32615(3) 0.97251(3) 0.04094(2) 0.01868(7) Uani 1 1 d . . .
Te3 Te 0.22224(3) 0.76267(3) 0.255487(19) 0.02345(8) Uani 1 1 d . . .
I1 I 0.73936(4) 1.05880(3) 0.34603(2) 0.03044(9) Uani 1 1 d . . .
I2 I 0.27996(4) 0.95006(3) -0.12216(2) 0.03011(9) Uani 1 1 d . . .
I3 I 0.45974(4) 0.63777(3) 0.28825(3) 0.03456(10) Uani 1 1 d . . .
I4 I 0.01149(4) 0.88008(3) 0.22334(2) 0.03422(9) Uani 1 1 d . . .
I5 I 0.21961(6) 0.79838(4) 0.42538(2) 0.05059(13) Uani 1 1 d . . .
I6 I 0.08340(4) 0.56512(3) 0.26726(3) 0.03914(11) Uani 1 1 d . . .
I7 I 0.24549(4) 0.71703(3) 0.07815(2) 0.02469(8) Uani 1 1 d . . .
I8 I 0.37517(4) 0.97277(3) 0.23853(2) 0.02629(8) Uani 1 1 d . . .
Se1 Se 0.79393(6) 0.75005(6) 0.38355(3) 0.03444(15) Uani 1 1 d . . .
Se2 Se 0.40637(5) 1.16905(5) 0.03201(5) 0.03625(16) Uani 1 1 d . . .
P1 P 0.74656(15) 0.73322(14) 0.51108(9) 0.0309(3) Uani 1 1 d . . .
P2 P 0.24564(12) 1.26962(10) 0.04328(8) 0.0189(3) Uani 1 1 d . . .
C11 C 0.8703(10) 0.8018(9) 0.5688(5) 0.075(3) Uani 1 1 d U . .
H11 H 0.9432 0.7614 0.5549 0.090 Uiso 1 1 calc R . .
C12 C 0.9033(13) 0.9089(9) 0.5504(7) 0.108(5) Uani 1 1 d U . .
H12A H 0.8344 0.9545 0.5587 0.129 Uiso 1 1 calc R . .
H12B H 0.9256 0.9130 0.4944 0.129 Uiso 1 1 calc R . .
H12C H 0.9730 0.9338 0.5854 0.129 Uiso 1 1 calc R . .
C13 C 0.8613(9) 0.7830(9) 0.6604(4) 0.075(3) Uani 1 1 d U . .
H13A H 0.9415 0.7974 0.6873 0.091 Uiso 1 1 calc R . .
H13B H 0.8342 0.7082 0.6696 0.091 Uiso 1 1 calc R . .
H13C H 0.8027 0.8315 0.6820 0.091 Uiso 1 1 calc R . .
C14 C 0.7518(7) 0.5879(7) 0.5309(5) 0.0514(19) Uani 1 1 d U . .
H14 H 0.7326 0.5761 0.5882 0.062 Uiso 1 1 calc R . .
C15 C 0.6578(9) 0.5236(6) 0.4789(6) 0.064(2) Uani 1 1 d U . .
H15A H 0.6811 0.5258 0.4230 0.077 Uiso 1 1 calc R . .
H15B H 0.5779 0.5546 0.4832 0.077 Uiso 1 1 calc R . .
H15C H 0.6537 0.4488 0.4969 0.077 Uiso 1 1 calc R . .
C16 C 0.8782(8) 0.5469(8) 0.5186(6) 0.069(3) Uani 1 1 d U . .
H16A H 0.8809 0.4718 0.5358 0.083 Uiso 1 1 calc R . .
H16B H 0.9390 0.5909 0.5503 0.083 Uiso 1 1 calc R . .
H16C H 0.8960 0.5514 0.4617 0.083 Uiso 1 1 calc R . .
C17 C 0.5912(6) 0.7712(5) 0.5301(3) 0.0332(13) Uani 1 1 d U . .
H17 H 0.5385 0.7460 0.4827 0.040 Uiso 1 1 calc R . .
C18 C 0.5811(8) 0.8930(6) 0.5356(4) 0.050(2) Uani 1 1 d U . .
H18A H 0.4952 0.9108 0.5298 0.060 Uiso 1 1 calc R . .
H18B H 0.6265 0.9273 0.4929 0.060 Uiso 1 1 calc R . .
H18C H 0.6152 0.9190 0.5878 0.060 Uiso 1 1 calc R . .
C19 C 0.5398(7) 0.7145(7) 0.6040(4) 0.0461(17) Uani 1 1 d U . .
C21 C 0.1879(6) 1.3135(5) -0.0559(3) 0.0328(13) Uani 1 1 d U . .
H21 H 0.1301 1.2548 -0.0771 0.039 Uiso 1 1 calc R . .
C22 C 0.2872(8) 1.3271(6) -0.1173(4) 0.0518(19) Uani 1 1 d U . .
H22A H 0.2495 1.3437 -0.1698 0.062 Uiso 1 1 calc R . .
H22B H 0.3307 1.2602 -0.1212 0.062 Uiso 1 1 calc R . .
H22C H 0.3448 1.3860 -0.1002 0.062 Uiso 1 1 calc R . .
C23 C 0.1132(7) 1.4135(6) -0.0478(4) 0.0456(17) Uani 1 1 d U . .
H23A H 0.1668 1.4743 -0.0290 0.055 Uiso 1 1 calc R . .
H23B H 0.0499 1.3997 -0.0093 0.055 Uiso 1 1 calc R . .
H23C H 0.0750 1.4305 -0.1001 0.055 Uiso 1 1 calc R . .
C24 C 0.3034(5) 1.3841(4) 0.1060(3) 0.0217(10) Uani 1 1 d U . .
H24 H 0.2348 1.4330 0.1132 0.026 Uiso 1 1 calc R . .
C25 C 0.3458(6) 1.3441(5) 0.1888(3) 0.0344(14) Uani 1 1 d U . .
H25A H 0.4217 1.3064 0.1843 0.041 Uiso 1 1 calc R . .
H25B H 0.2830 1.2947 0.2093 0.041 Uiso 1 1 calc R . .
H25C H 0.3599 1.4056 0.2256 0.041 Uiso 1 1 calc R . .
C26 C 0.4056(5) 1.4479(4) 0.0665(3) 0.0263(11) Uani 1 1 d U . .
H26A H 0.4360 1.5070 0.1021 0.032 Uiso 1 1 calc R . .
H26B H 0.3744 1.4773 0.0157 0.032 Uiso 1 1 calc R . .
H26C H 0.4721 1.4004 0.0562 0.032 Uiso 1 1 calc R . .
C27 C 0.1212(5) 1.1982(4) 0.0933(3) 0.0234(11) Uani 1 1 d U . .
H27 H 0.1593 1.1511 0.1348 0.028 Uiso 1 1 calc R . .
C28 C 0.0455(5) 1.1245(5) 0.0342(4) 0.0287(12) Uani 1 1 d U . .
H28A H -0.0021 1.0712 0.0640 0.034 Uiso 1 1 calc R . .
H28B H 0.1000 1.0875 -0.0006 0.034 Uiso 1 1 calc R . .
H28C H -0.0098 1.1678 0.0015 0.034 Uiso 1 1 calc R . .
C29 C 0.0373(5) 1.2733(5) 0.1369(4) 0.0325(13) Uani 1 1 d U . .
H29A H -0.0060 1.3174 0.0975 0.039 Uiso 1 1 calc R . .
H29B H 0.0865 1.3202 0.1744 0.039 Uiso 1 1 calc R . .
H29C H -0.0219 1.2301 0.1665 0.039 Uiso 1 1 calc R . .
Cl1 Cl 0.8230(3) 1.3577(2) 0.3265(2) 0.0835(8) Uani 1 1 d D . .
Cl2 Cl 0.7179(3) 1.3673(2) 0.1591(2) 0.0960(10) Uani 1 1 d D . .
C99 C 0.703(2) 1.4041(18) 0.2585(8) 0.199(9) Uiso 1 1 d D . .
H99A H 0.6231 1.3746 0.2760 0.239 Uiso 1 1 calc R . .
H99B H 0.7016 1.4835 0.2622 0.239 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Se Se -0.0929 2.2259 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Te Te -0.5308 1.6751 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
I I -0.4742 1.8119 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Se1 Te1 I1 94.97(2) . . ?
Se1 Te1 I3 90.49(2) . . ?
I1 Te1 I3 173.921(18) . . ?
Se1 Te1 I8 173.95(2) . . ?
I1 Te1 I8 90.572(15) . . ?
I3 Te1 I8 83.859(14) . . ?
Se2 Te2 I2 94.04(2) . . ?
Se2 Te2 I8 91.76(2) . . ?
I2 Te2 I8 174.156(16) . . ?
Se2 Te2 I7 171.58(2) . . ?
I2 Te2 I7 93.759(14) . . ?
I8 Te2 I7 80.414(12) . . ?
Se2 Te2 Se2 100.074(18) . 2_675 ?
I2 Te2 Se2 75.330(17) . 2_675 ?
I8 Te2 Se2 102.893(16) . 2_675 ?
I7 Te2 Se2 78.851(14) . 2_675 ?
I4 Te3 I6 92.393(18) . . ?
I4 Te3 I5 93.510(18) . . ?
I6 Te3 I5 91.457(18) . . ?
I4 Te3 I7 91.171(14) . . ?
I6 Te3 I7 89.048(15) . . ?
I5 Te3 I7 175.27(2) . . ?
I4 Te3 I8 88.322(16) . . ?
I6 Te3 I8 178.339(18) . . ?
I5 Te3 I8 89.996(16) . . ?
I7 Te3 I8 89.438(14) . . ?
I4 Te3 I3 178.326(19) . . ?
I6 Te3 I3 89.089(17) . . ?
I5 Te3 I3 87.227(17) . . ?
I7 Te3 I3 88.075(15) . . ?
I8 Te3 I3 90.176(15) . . ?
Te1 I1 I2 79.513(13) . 2_675 ?
Te1 I1 I5 122.416(16) . 2_676 ?
I2 I1 I5 156.555(15) 2_675 2_676 ?
Te3 I3 Te1 92.286(15) . . ?
Te3 I7 Te2 92.571(13) . . ?
Te3 I8 Te2 92.245(12) . . ?
Te3 I8 Te1 90.422(14) . . ?
Te2 I8 Te1 119.711(14) . . ?
P1 Se1 Te1 104.62(5) . . ?
P2 Se2 Te2 106.14(4) . . ?
C11 P1 C17 117.4(5) . . ?
C11 P1 C14 108.3(5) . . ?
C17 P1 C14 106.4(3) . . ?
C11 P1 Se1 105.5(3) . . ?
C17 P1 Se1 113.52(19) . . ?
C14 P1 Se1 104.8(3) . . ?
C24 P2 C27 109.2(2) . . ?
C24 P2 C21 111.6(3) . . ?
C27 P2 C21 108.8(3) . . ?
C24 P2 Se2 104.15(18) . . ?
C27 P2 Se2 112.20(18) . . ?
C21 P2 Se2 110.8(2) . . ?
C12 C11 C13 112.9(9) . . ?
C12 C11 P1 119.1(8) . . ?
C13 C11 P1 112.2(6) . . ?
C15 C14 C16 109.8(8) . . ?
C15 C14 P1 111.5(5) . . ?
C16 C14 P1 111.4(6) . . ?
C18 C17 C19 111.5(5) . . ?
C18 C17 P1 112.1(5) . . ?
C19 C17 P1 112.5(4) . . ?
C23 C21 C22 112.9(6) . . ?
C23 C21 P2 110.6(4) . . ?
C22 C21 P2 113.7(5) . . ?
C26 C24 C25 111.1(5) . . ?
C26 C24 P2 111.5(4) . . ?
C25 C24 P2 109.7(4) . . ?
C28 C27 C29 110.1(5) . . ?
C28 C27 P2 111.0(4) . . ?
C29 C27 P2 113.7(4) . . ?
Cl2 C99 Cl1 113.9(12) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Te1 Se1 2.5622(7) . ?
Te1 I1 2.8092(6) . ?
Te1 I3 3.2045(6) . ?
Te1 I8 3.3570(6) . ?
Te2 Se2 2.5705(7) . ?
Te2 I2 2.7593(5) . ?
Te2 I8 3.3212(5) . ?
Te2 I7 3.3331(5) . ?
Te2 Se2 3.7381(7) 2_675 ?
Te3 I4 2.8252(6) . ?
Te3 I6 2.8491(6) . ?
Te3 I5 2.8716(6) . ?
Te3 I7 3.0370(5) . ?
Te3 I8 3.0679(5) . ?
Te3 I3 3.1250(6) . ?
I1 I2 3.7379(6) 2_675 ?
I1 I5 4.1970(6) 2_676 ?
Se1 P1 2.2262(16) . ?
Se2 P2 2.2226(14) . ?
P1 C11 1.810(8) . ?
P1 C17 1.833(7) . ?
P1 C14 1.843(8) . ?
P2 C24 1.834(5) . ?
P2 C27 1.837(6) . ?
P2 C21 1.843(6) . ?
C11 C12 1.406(13) . ?
C11 C13 1.557(11) . ?
C14 C15 1.517(12) . ?
C14 C16 1.523(11) . ?
C17 C18 1.525(9) . ?
C17 C19 1.544(9) . ?
C21 C23 1.527(9) . ?
C21 C22 1.537(10) . ?
C24 C26 1.525(8) . ?
C24 C25 1.534(8) . ?
C27 C28 1.533(7) . ?
C27 C29 1.542(8) . ?
Cl1 C99 1.822(15) . ?
Cl2 C99 1.736(15) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Se1 Te1 I1 I2 116.281(18) . . . 2_675 ?
I3 Te1 I1 I2 -89.73(16) . . . 2_675 ?
I8 Te1 I1 I2 -66.132(12) . . . 2_675 ?
Se1 Te1 I1 I5 -72.71(2) . . . 2_676 ?
I3 Te1 I1 I5 81.28(16) . . . 2_676 ?
I8 Te1 I1 I5 104.875(18) . . . 2_676 ?
I4 Te3 I3 Te1 40.5(6) . . . . ?
I6 Te3 I3 Te1 -167.186(15) . . . . ?
I5 Te3 I3 Te1 -75.683(17) . . . . ?
I7 Te3 I3 Te1 103.736(14) . . . . ?
I8 Te3 I3 Te1 14.304(14) . . . . ?
Se1 Te1 I3 Te3 164.708(19) . . . . ?
I1 Te1 I3 Te3 10.61(16) . . . . ?
I8 Te1 I3 Te3 -13.126(13) . . . . ?
I4 Te3 I7 Te2 70.319(15) . . . . ?
I6 Te3 I7 Te2 162.693(15) . . . . ?
I5 Te3 I7 Te2 -101.1(2) . . . . ?
I8 Te3 I7 Te2 -17.991(13) . . . . ?
I3 Te3 I7 Te2 -108.186(14) . . . . ?
Se2 Te2 I7 Te3 38.65(14) . . . . ?
I2 Te2 I7 Te3 -163.639(15) . . . . ?
I8 Te2 I7 Te3 16.818(13) . . . . ?
Se2 Te2 I7 Te3 122.122(17) 2_675 . . . ?
I4 Te3 I8 Te2 -73.136(14) . . . . ?
I6 Te3 I8 Te2 42.4(6) . . . . ?
I5 Te3 I8 Te2 -166.647(16) . . . . ?
I7 Te3 I8 Te2 18.053(13) . . . . ?
I3 Te3 I8 Te2 106.125(14) . . . . ?
I4 Te3 I8 Te1 167.108(14) . . . . ?
I6 Te3 I8 Te1 -77.4(6) . . . . ?
I5 Te3 I8 Te1 73.596(16) . . . . ?
I7 Te3 I8 Te1 -101.704(14) . . . . ?
I3 Te3 I8 Te1 -13.631(13) . . . . ?
Se2 Te2 I8 Te3 166.486(18) . . . . ?
I2 Te2 I8 Te3 -21.13(16) . . . . ?
I7 Te2 I8 Te3 -16.640(13) . . . . ?
Se2 Te2 I8 Te3 -92.763(16) 2_675 . . . ?
Se2 Te2 I8 Te1 -101.75(2) . . . . ?
I2 Te2 I8 Te1 70.64(16) . . . . ?
I7 Te2 I8 Te1 75.129(17) . . . . ?
Se2 Te2 I8 Te1 -1.00(2) 2_675 . . . ?
Se1 Te1 I8 Te3 -7.66(19) . . . . ?
I1 Te1 I8 Te3 -164.192(14) . . . . ?
I3 Te1 I8 Te3 13.364(13) . . . . ?
Se1 Te1 I8 Te2 -100.49(19) . . . . ?
I1 Te1 I8 Te2 102.982(17) . . . . ?
I3 Te1 I8 Te2 -79.462(17) . . . . ?
I1 Te1 Se1 P1 91.85(5) . . . . ?
I3 Te1 Se1 P1 -85.49(5) . . . . ?
I8 Te1 Se1 P1 -64.6(2) . . . . ?
I2 Te2 Se2 P2 90.25(5) . . . . ?
I8 Te2 Se2 P2 -90.53(5) . . . . ?
I7 Te2 Se2 P2 -112.05(14) . . . . ?
Se2 Te2 Se2 P2 166.05(5) 2_675 . . . ?
Te1 Se1 P1 C11 -118.2(4) . . . . ?
Te1 Se1 P1 C17 11.8(2) . . . . ?
Te1 Se1 P1 C14 127.5(3) . . . . ?
Te2 Se2 P2 C24 140.43(18) . . . . ?
Te2 Se2 P2 C27 22.40(19) . . . . ?
Te2 Se2 P2 C21 -99.4(2) . . . . ?
C17 P1 C11 C12 -74.1(11) . . . . ?
C14 P1 C11 C12 165.4(10) . . . . ?
Se1 P1 C11 C12 53.6(11) . . . . ?
C17 P1 C11 C13 61.0(10) . . . . ?
C14 P1 C11 C13 -59.6(10) . . . . ?
Se1 P1 C11 C13 -171.4(8) . . . . ?
C11 P1 C14 C15 -174.9(6) . . . . ?
C17 P1 C14 C15 58.0(7) . . . . ?
Se1 P1 C14 C15 -62.6(6) . . . . ?
C11 P1 C14 C16 -51.8(7) . . . . ?
C17 P1 C14 C16 -178.9(6) . . . . ?
Se1 P1 C14 C16 60.5(6) . . . . ?
C11 P1 C17 C18 44.8(6) . . . . ?
C14 P1 C17 C18 166.3(5) . . . . ?
Se1 P1 C17 C18 -79.0(4) . . . . ?
C11 P1 C17 C19 -81.9(6) . . . . ?
C14 P1 C17 C19 39.6(6) . . . . ?
Se1 P1 C17 C19 154.4(4) . . . . ?
C24 P2 C21 C23 -42.8(6) . . . . ?
C27 P2 C21 C23 77.8(5) . . . . ?
Se2 P2 C21 C23 -158.3(4) . . . . ?
C24 P2 C21 C22 85.4(5) . . . . ?
C27 P2 C21 C22 -154.0(5) . . . . ?
Se2 P2 C21 C22 -30.2(5) . . . . ?
C27 P2 C24 C26 -178.9(4) . . . . ?
C21 P2 C24 C26 -58.5(5) . . . . ?
Se2 P2 C24 C26 61.1(4) . . . . ?
C27 P2 C24 C25 57.5(5) . . . . ?
C21 P2 C24 C25 177.9(4) . . . . ?
Se2 P2 C24 C25 -62.5(4) . . . . ?
C24 P2 C27 C28 163.0(4) . . . . ?
C21 P2 C27 C28 41.0(5) . . . . ?
Se2 P2 C27 C28 -82.0(4) . . . . ?
C24 P2 C27 C29 38.2(5) . . . . ?
C21 P2 C27 C29 -83.8(5) . . . . ?
Se2 P2 C27 C29 153.2(4) . . . . ?
