#------------------------------------------------------------------------------
#$Date: 2016-03-25 11:15:32 +0100 (vie 25 de mar de 2016) $
#$Revision: 179806 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/02/7010212.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7010212
loop_
_publ_author_name
'Chen, Zhen-Feng'
'Xiong, Ren-Gen'
'Zhang, Jing'
'Zuo, Jing-Lin'
'You, Xiao-Zeng'
'Che, Chi-Ming'
'Fun, Hoong-Kun'
_publ_section_title
;
 The first chiral 2-D molecular triangular grid †
;
_journal_issue                   22
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              4010
_journal_paper_doi               10.1039/b007004l
_journal_year                    2000
_chemical_formula_sum            'C70 H64 Cl5 Cu2 N9 O8 P2'
_chemical_formula_weight         1525.57
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           146
_symmetry_cell_setting           trigonal
_symmetry_space_group_name_Hall  'R 3'
_symmetry_space_group_name_H-M   'R 3 :H'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                120.00
_cell_formula_units_Z            3
_cell_length_a                   13.6687(2)
_cell_length_b                   13.6687(2)
_cell_length_c                   32.4627(8)
_cell_measurement_reflns_used    5824
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      29.56
_cell_measurement_theta_min      1.83
_cell_volume                     5252.54(17)
_computing_cell_refinement       'SAINT (Siemens, 1996)'
_computing_data_collection       'SMART (Siemens, 1996)'
_computing_data_reduction        SAINT
_computing_molecular_graphics    SHELXTL
_computing_publication_material  'SHELXTL and PLATON (Spek, 1996)'
_computing_structure_refinement  SHELXTL
_computing_structure_solution    'SHELXTL (Sheldrick, 1997)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 8.33
_diffrn_measured_fraction_theta_full 0.927
_diffrn_measured_fraction_theta_max 0.927
_diffrn_measurement_device_type  'SMART CCD'
_diffrn_measurement_method       'ω scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0805
_diffrn_reflns_av_sigmaI/netI    0.1179
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       8
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       40
_diffrn_reflns_limit_l_min       -44
_diffrn_reflns_number            12918
_diffrn_reflns_theta_full        29.56
_diffrn_reflns_theta_max         29.56
_diffrn_reflns_theta_min         1.83
_exptl_absorpt_coefficient_mu    0.905
_exptl_absorpt_correction_T_max  0.8540
_exptl_absorpt_correction_T_min  0.8257
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'Sadabs (Sheldrick, 1996)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.447
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       slab
_exptl_crystal_F_000             2352
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.18
_refine_diff_density_max         0.493
_refine_diff_density_min         -0.500
_refine_diff_density_rms         0.071
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.00
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.947
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     289
_refine_ls_number_reflns         5758
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      0.947
_refine_ls_R_factor_all          0.1005
_refine_ls_R_factor_gt           0.0563
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0571P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1236
_refine_ls_wR_factor_ref         0.1404
_reflns_number_gt                3700
_reflns_number_total             5758
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b007004l.txt
_cod_data_source_block
'[Cu(PPh~3~)(N,N-(2-pyridyl)(4-pyridylmethyl)amine)~1.5~].0.5CHCl~3~.ClO~4~'
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Trigonal' changed to 'trigonal' according
to '/home/saulius/struct/CIF-dictionaries/cif_core.dic' dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      R3
_cod_database_code               7010212
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'x+2/3, y+1/3, z+1/3'
'-y+2/3, x-y+1/3, z+1/3'
'-x+y+2/3, -x+1/3, z+1/3'
'x+1/3, y+2/3, z+2/3'
'-y+1/3, x-y+2/3, z+2/3'
'-x+y+1/3, -x+2/3, z+2/3'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Cu1 Cu 0.0000 0.0000 0.82913(3) 0.0283(3) Uani 1 3 d S . .
Cu2 Cu 0.6667 0.3333 0.72212(3) 0.0294(3) Uani 1 3 d S . .
P1 P 0.0000 0.0000 0.75999(6) 0.0284(5) Uani 1 3 d S . .
P2 P 0.6667 0.3333 0.65403(6) 0.0274(5) Uani 1 3 d S . .
N1 N 0.0136(3) -0.1323(3) 0.85740(12) 0.0313(9) Uani 1 1 d . . .
N2 N 0.1801(3) -0.0830(3) 0.82339(12) 0.0360(9) Uani 1 1 d . . .
H12A H 0.1916 -0.0151 0.8225 0.043 Uiso 1 1 calc R . .
N3 N 0.5356(3) 0.1908(3) 0.74912(12) 0.0337(10) Uani 1 1 d . . .
C1 C -0.1322(4) -0.0247(4) 0.73667(16) 0.0351(12) Uani 1 1 d . . .
C2 C -0.1859(5) 0.0289(5) 0.75351(17) 0.0451(13) Uani 1 1 d . . .
H2B H -0.1528 0.0784 0.7755 0.054 Uiso 1 1 calc R . .
C3 C -0.2871(5) 0.0098(6) 0.7382(2) 0.0600(17) Uani 1 1 d . . .
H3A H -0.3234 0.0448 0.7503 0.072 Uiso 1 1 calc R . .
C4 C -0.3359(5) -0.0605(6) 0.7049(2) 0.0665(19) Uani 1 1 d . . .
H4A H -0.4052 -0.0737 0.6950 0.080 Uiso 1 1 calc R . .
C5 C -0.2827(6) -0.1112(6) 0.6865(2) 0.0642(18) Uani 1 1 d . . .
H5A H -0.3143 -0.1561 0.6633 0.077 Uiso 1 1 calc R . .
C6 C -0.1803(5) -0.0951(5) 0.70265(18) 0.0534(15) Uani 1 1 d . . .
H6A H -0.1448 -0.1311 0.6907 0.064 Uiso 1 1 calc R . .
C7 C -0.0726(4) -0.2054(4) 0.88153(15) 0.0416(12) Uani 1 1 d . . .
H7A H -0.1246 -0.1851 0.8905 0.050 Uiso 1 1 calc R . .
C8 C -0.0872(5) -0.3077(5) 0.89345(18) 0.0496(15) Uani 1 1 d . . .
H8A H -0.1455 -0.3542 0.9112 0.059 Uiso 1 1 calc R . .
C9 C -0.0139(5) -0.3404(5) 0.87870(19) 0.0529(16) Uani 1 1 d . . .
H9A H -0.0252 -0.4117 0.8851 0.063 Uiso 1 1 calc R . .
C10 C 0.0768(5) -0.2677(4) 0.85437(18) 0.0472(14) Uani 1 1 d . . .
H10A H 0.1281 -0.2880 0.8446 0.057 Uiso 1 1 calc R . .
C11 C 0.0883(4) -0.1633(4) 0.84502(15) 0.0316(10) Uani 1 1 d . . .
C12 C 0.2581(4) -0.1077(4) 0.80208(19) 0.0465(14) Uani 1 1 d . . .
H12B H 0.2185 -0.1617 0.7802 0.056 Uiso 1 1 calc R . .
H12C H 0.2870 -0.1417 0.8212 0.056 Uiso 1 1 calc R . .
C13 C 0.3540(4) -0.0040(4) 0.78419(16) 0.0357(12) Uani 1 1 d . . .
C14 C 0.3936(4) -0.0051(4) 0.74520(17) 0.0413(12) Uani 1 1 d . . .
H14A H 0.3602 -0.0710 0.7296 0.050 Uiso 1 1 calc R . .
C15 C 0.4831(4) 0.0921(4) 0.72959(16) 0.0415(13) Uani 1 1 d . . .
H15A H 0.5088 0.0886 0.7034 0.050 Uiso 1 1 calc R . .
C16 C 0.4978(4) 0.1906(4) 0.78786(16) 0.0395(12) Uani 1 1 d . . .
H16A H 0.5333 0.2569 0.8032 0.047 Uiso 1 1 calc R . .
C17 C 0.4090(4) 0.0962(5) 0.80532(17) 0.0461(14) Uani 1 1 d . . .
H17A H 0.3859 0.1004 0.8319 0.055 Uiso 1 1 calc R . .
C18 C 0.5328(4) 0.2314(4) 0.63125(14) 0.0296(10) Uani 1 1 d . . .
C19 C 0.4349(4) 0.2241(5) 0.64673(16) 0.0436(13) Uani 1 1 d . . .
H19A H 0.4402 0.2720 0.6680 0.052 Uiso 1 1 calc R . .
C20 C 0.3312(4) 0.1485(5) 0.63153(17) 0.0505(15) Uani 1 1 d . . .
H20A H 0.2671 0.1471 0.6420 0.061 Uiso 1 1 calc R . .
C21 C 0.3206(5) 0.0756(5) 0.6014(2) 0.0588(17) Uani 1 1 d . . .
H21A H 0.2498 0.0244 0.5910 0.071 Uiso 1 1 calc R . .
C22 C 0.4137(6) 0.0780(6) 0.5866(2) 0.073(2) Uani 1 1 d . . .
H22A H 0.4059 0.0258 0.5666 0.087 Uiso 1 1 calc R . .
C23 C 0.5201(5) 0.1554(6) 0.60020(19) 0.0595(18) Uani 1 1 d . . .
H23A H 0.5833 0.1570 0.5888 0.071 Uiso 1 1 calc R . .
Cl1 Cl 0.6667 0.3333 0.90681(11) 0.0560(6) Uani 1 3 d S . .
O1 O 0.6667 0.3333 0.8757(6) 0.52(3) Uani 1 3 d S . .
O2 O 0.6904(8) 0.2581(7) 0.9216(5) 0.262(8) Uani 1 1 d . . .
Cl2 Cl 0.6667 0.3333 0.45180(9) 0.0580(8) Uani 1 3 d S . .
C24 C 0.6667 0.3333 0.3298(4) 0.094(5) Uani 1 3 d S . .
H24A H 0.6667 0.3333 0.3600 0.113 Uiso 1 3 calc SR . .
O4 O 0.6955(6) 0.2568(5) 0.4427(4) 0.200(5) Uani 1 1 d . . .
Cl3 Cl 0.5300(2) 0.2369(2) 0.31233(8) 0.1088(8) Uani 1 1 d . . .
O3 O 0.6667 0.3333 0.4895(7) 0.313(16) Uani 1 3 d S . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Cu1 N1 102.60(13) 2 3 ?
N1 Cu1 N1 102.60(13) 2 . ?
N1 Cu1 N1 102.60(13) 3 . ?
N1 Cu1 P1 115.69(11) 2 . ?
N1 Cu1 P1 115.69(11) 3 . ?
N1 Cu1 P1 115.69(11) . . ?
N3 Cu2 N3 103.35(14) 2_655 . ?
N3 Cu2 N3 103.35(14) 2_655 3_665 ?
N3 Cu2 N3 103.35(14) . 3_665 ?
N3 Cu2 P2 115.06(12) 2_655 . ?
N3 Cu2 P2 115.06(12) . . ?
N3 Cu2 P2 115.06(12) 3_665 . ?
C1 P1 C1 104.1(2) . 3 ?
C1 P1 C1 104.1(2) . 2 ?
C1 P1 C1 104.1(2) 3 2 ?
C1 P1 Cu1 114.46(17) . . ?
C1 P1 Cu1 114.46(17) 3 . ?
C1 P1 Cu1 114.46(17) 2 . ?
C18 P2 C18 104.50(18) 2_655 . ?
C18 P2 C18 104.50(18) 2_655 3_665 ?
C18 P2 C18 104.50(18) . 3_665 ?
C18 P2 Cu2 114.07(15) 2_655 . ?
C18 P2 Cu2 114.07(15) . . ?
C18 P2 Cu2 114.07(15) 3_665 . ?
C11 N1 C7 117.3(4) . . ?
C11 N1 Cu1 122.9(3) . . ?
C7 N1 Cu1 117.9(3) . . ?
C11 N2 C12 122.9(4) . . ?
C15 N3 C16 115.3(4) . . ?
C15 N3 Cu2 121.8(3) . . ?
C16 N3 Cu2 122.9(4) . . ?
C2 C1 C6 119.2(5) . . ?
C2 C1 P1 118.4(4) . . ?
C6 C1 P1 122.4(4) . . ?
C3 C2 C1 120.6(6) . . ?
C2 C3 C4 120.6(6) . . ?
C5 C4 C3 120.2(6) . . ?
C4 C5 C6 119.8(6) . . ?
C1 C6 C5 119.5(6) . . ?
N1 C7 C8 123.3(5) . . ?
C7 C8 C9 118.6(5) . . ?
C8 C9 C10 120.2(5) . . ?
C9 C10 C11 117.6(5) . . ?
N1 C11 N2 115.7(4) . . ?
N1 C11 C10 122.9(4) . . ?
N2 C11 C10 121.3(4) . . ?
N2 C12 C13 111.5(4) . . ?
C17 C13 C14 116.6(4) . . ?
C17 C13 C12 122.6(5) . . ?
C14 C13 C12 120.8(5) . . ?
C15 C14 C13 119.4(5) . . ?
N3 C15 C14 124.9(5) . . ?
N3 C16 C17 122.6(5) . . ?
C13 C17 C16 121.1(5) . . ?
C19 C18 C23 116.9(5) . . ?
C19 C18 P2 118.3(4) . . ?
C23 C18 P2 124.7(4) . . ?
C20 C19 C18 121.6(5) . . ?
C21 C20 C19 120.5(5) . . ?
C22 C21 C20 119.4(5) . . ?
C21 C22 C23 121.8(6) . . ?
C22 C23 C18 119.7(5) . . ?
O1 Cl1 O2 111.4(7) . . ?
O1 Cl1 O2 111.4(8) . 2_655 ?
O2 Cl1 O2 107.5(8) . 2_655 ?
O1 Cl1 O2 111.4(8) . 3_665 ?
O2 Cl1 O2 107.5(8) . 3_665 ?
O2 Cl1 O2 107.5(8) 2_655 3_665 ?
O3 Cl2 O4 102.9(6) . . ?
O3 Cl2 O4 102.9(6) . 2_655 ?
O4 Cl2 O4 115.2(4) . 2_655 ?
O3 Cl2 O4 102.9(6) . 3_665 ?
O4 Cl2 O4 115.2(4) . 3_665 ?
O4 Cl2 O4 115.2(4) 2_655 3_665 ?
Cl3 C24 Cl3 110.1(4) 2_655 . ?
Cl3 C24 Cl3 110.1(4) 2_655 3_665 ?
Cl3 C24 Cl3 110.1(4) . 3_665 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Cu1 N1 2.117(4) 2 ?
Cu1 N1 2.117(4) 3 ?
Cu1 N1 2.117(4) . ?
Cu1 P1 2.245(2) . ?
Cu2 N3 2.070(4) 2_655 ?
Cu2 N3 2.070(4) . ?
Cu2 N3 2.070(4) 3_665 ?
Cu2 P2 2.210(2) . ?
P1 C1 1.829(5) . ?
P1 C1 1.829(5) 3 ?
P1 C1 1.829(5) 2 ?
P2 C18 1.814(5) 2_655 ?
P2 C18 1.814(5) . ?
P2 C18 1.814(5) 3_665 ?
N1 C11 1.347(6) . ?
N1 C7 1.350(6) . ?
N2 C11 1.377(6) . ?
N2 C12 1.446(6) . ?
N3 C15 1.330(7) . ?
N3 C16 1.359(6) . ?
C1 C2 1.382(7) . ?
C1 C6 1.394(7) . ?
C2 C3 1.368(8) . ?
C3 C4 1.376(10) . ?
C4 C5 1.367(10) . ?
C5 C6 1.406(8) . ?
C7 C8 1.366(7) . ?
C8 C9 1.370(8) . ?
C9 C10 1.384(8) . ?
C10 C11 1.389(7) . ?
C12 C13 1.486(7) . ?
C13 C17 1.371(7) . ?
C13 C14 1.380(7) . ?
C14 C15 1.376(7) . ?
C16 C17 1.376(7) . ?
C18 C19 1.385(7) . ?
C18 C23 1.395(7) . ?
C19 C20 1.363(7) . ?
C20 C21 1.352(8) . ?
C21 C22 1.345(9) . ?
C22 C23 1.376(9) . ?
Cl1 O1 1.009(18) . ?
Cl1 O2 1.315(9) . ?
Cl1 O2 1.315(9) 2_655 ?
Cl1 O2 1.315(9) 3_665 ?
Cl2 O3 1.23(2) . ?
Cl2 O4 1.323(6) . ?
Cl2 O4 1.323(6) 2_655 ?
Cl2 O4 1.323(6) 3_665 ?
C24 Cl3 1.757(5) 2_655 ?
C24 Cl3 1.757(5) . ?
C24 Cl3 1.757(5) 3_665 ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 Cu1 P1 C1 -125.3(2) 2 . . . ?
N1 Cu1 P1 C1 -5.3(2) 3 . . . ?
N1 Cu1 P1 C1 114.7(2) . . . . ?
N1 Cu1 P1 C1 -5.3(2) 2 . . 3 ?
N1 Cu1 P1 C1 114.7(2) 3 . . 3 ?
N1 Cu1 P1 C1 -125.3(2) . . . 3 ?
N1 Cu1 P1 C1 114.7(2) 2 . . 2 ?
N1 Cu1 P1 C1 -125.3(2) 3 . . 2 ?
N1 Cu1 P1 C1 -5.3(2) . . . 2 ?
N3 Cu2 P2 C18 17.3(2) 2_655 . . 2_655 ?
N3 Cu2 P2 C18 -102.7(2) . . . 2_655 ?
N3 Cu2 P2 C18 137.3(2) 3_665 . . 2_655 ?
N3 Cu2 P2 C18 137.3(2) 2_655 . . . ?
N3 Cu2 P2 C18 17.3(2) . . . . ?
N3 Cu2 P2 C18 -102.7(2) 3_665 . . . ?
N3 Cu2 P2 C18 -102.7(2) 2_655 . . 3_665 ?
N3 Cu2 P2 C18 137.3(2) . . . 3_665 ?
N3 Cu2 P2 C18 17.3(2) 3_665 . . 3_665 ?
N1 Cu1 N1 C11 -81.7(4) 2 . . . ?
N1 Cu1 N1 C11 172.1(3) 3 . . . ?
P1 Cu1 N1 C11 45.2(4) . . . . ?
N1 Cu1 N1 C7 114.8(3) 2 . . . ?
N1 Cu1 N1 C7 8.6(4) 3 . . . ?
P1 Cu1 N1 C7 -118.3(3) . . . . ?
N3 Cu2 N3 C15 -101.7(5) 2_655 . . . ?
N3 Cu2 N3 C15 150.9(4) 3_665 . . . ?
P2 Cu2 N3 C15 24.6(4) . . . . ?
N3 Cu2 N3 C16 77.7(4) 2_655 . . . ?
N3 Cu2 N3 C16 -29.8(4) 3_665 . . . ?
P2 Cu2 N3 C16 -156.1(4) . . . . ?
C1 P1 C1 C2 -83.4(6) 3 . . . ?
C1 P1 C1 C2 167.9(4) 2 . . . ?
Cu1 P1 C1 C2 42.3(5) . . . . ?
C1 P1 C1 C6 96.5(4) 3 . . . ?
C1 P1 C1 C6 -12.3(5) 2 . . . ?
Cu1 P1 C1 C6 -137.9(4) . . . . ?
C6 C1 C2 C3 2.7(9) . . . . ?
P1 C1 C2 C3 -177.5(5) . . . . ?
C1 C2 C3 C4 -1.9(10) . . . . ?
C2 C3 C4 C5 -0.9(10) . . . . ?
C3 C4 C5 C6 2.7(10) . . . . ?
C2 C1 C6 C5 -0.8(9) . . . . ?
P1 C1 C6 C5 179.4(4) . . . . ?
C4 C5 C6 C1 -1.9(9) . . . . ?
C11 N1 C7 C8 -0.4(7) . . . . ?
Cu1 N1 C7 C8 164.0(4) . . . . ?
N1 C7 C8 C9 -3.1(9) . . . . ?
C7 C8 C9 C10 4.0(9) . . . . ?
C8 C9 C10 C11 -1.4(9) . . . . ?
C7 N1 C11 N2 -174.7(4) . . . . ?
Cu1 N1 C11 N2 21.7(6) . . . . ?
C7 N1 C11 C10 3.2(7) . . . . ?
Cu1 N1 C11 C10 -160.4(4) . . . . ?
C12 N2 C11 N1 -169.5(5) . . . . ?
C12 N2 C11 C10 12.6(7) . . . . ?
C9 C10 C11 N1 -2.3(8) . . . . ?
C9 C10 C11 N2 175.5(5) . . . . ?
C11 N2 C12 C13 -175.5(5) . . . . ?
N2 C12 C13 C17 43.4(7) . . . . ?
N2 C12 C13 C14 -137.9(5) . . . . ?
C17 C13 C14 C15 -0.8(8) . . . . ?
C12 C13 C14 C15 -179.6(5) . . . . ?
C16 N3 C15 C14 2.4(8) . . . . ?
Cu2 N3 C15 C14 -178.2(4) . . . . ?
C13 C14 C15 N3 -1.0(8) . . . . ?
C15 N3 C16 C17 -2.1(8) . . . . ?
Cu2 N3 C16 C17 178.6(4) . . . . ?
C14 C13 C17 C16 1.1(8) . . . . ?
C12 C13 C17 C16 179.8(5) . . . . ?
N3 C16 C17 C13 0.4(9) . . . . ?
C18 P2 C18 C19 171.4(4) 2_655 . . . ?
C18 P2 C18 C19 -79.1(5) 3_665 . . . ?
Cu2 P2 C18 C19 46.2(4) . . . . ?
C18 P2 C18 C23 -5.6(6) 2_655 . . . ?
C18 P2 C18 C23 104.0(4) 3_665 . . . ?
Cu2 P2 C18 C23 -130.8(5) . . . . ?
C23 C18 C19 C20 -1.9(8) . . . . ?
P2 C18 C19 C20 -179.1(4) . . . . ?
C18 C19 C20 C21 1.9(9) . . . . ?
C19 C20 C21 C22 0.3(9) . . . . ?
C20 C21 C22 C23 -2.4(11) . . . . ?
C21 C22 C23 C18 2.3(12) . . . . ?
C19 C18 C23 C22 -0.1(9) . . . . ?
P2 C18 C23 C22 176.9(5) . . . . ?
