#------------------------------------------------------------------------------
#$Date: 2016-03-25 11:15:32 +0100 (vie 25 de mar de 2016) $
#$Revision: 179806 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/02/7010292.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7010292
loop_
_publ_author_name
'Bowmaker, Graham A.'
'Hanna, John V.'
'Rickard, Clifton E. F.'
'Lipton, Andrew S.'
_publ_section_title
;
 Crystal structures and vibrational and solid-state (CPMAS) NMR
 spectroscopy of some bis(triphenylphosphine)silver(I) sulfate,
 selenate and phosphate systems
;
_journal_issue                   1
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              20
_journal_paper_doi               10.1039/b007796h
_journal_year                    2001
_chemical_formula_sum            'C36 H33 Ag O5 P2 Se'
_chemical_formula_weight         794.39
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                104.3870(10)
_cell_angle_beta                 91.6760(10)
_cell_angle_gamma                117.4040(10)
_cell_formula_units_Z            4
_cell_length_a                   12.5358(2)
_cell_length_b                   13.2580(2)
_cell_length_c                   24.5566(2)
_cell_measurement_reflns_used    7524
_cell_measurement_temperature    200(2)
_cell_measurement_theta_max      27
_cell_measurement_theta_min      2
_cell_volume                     3460.39(9)
_computing_cell_refinement       'Siemens SMART'
_computing_data_collection       'Siemens SMART (Siemens, 1995)'
_computing_data_reduction        'Siemens SAINT  (Siemens, 1995)'
_computing_molecular_graphics    'Siemens SHELXTL (Siemens, 1994)'
_computing_publication_material  SHELXL-97
_computing_structure_refinement  'SHELXL-97 Sheldrick, (1997)'
_computing_structure_solution    'SHELXS Sheldrick, (1990)'
_diffrn_ambient_temperature      200(2)
_diffrn_measured_fraction_theta_full 0.972
_diffrn_measured_fraction_theta_max 0.972
_diffrn_measurement_device_type  'Siemens SMART'
_diffrn_measurement_method       'Area detector ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0272
_diffrn_reflns_av_sigmaI/netI    0.0400
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       31
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            32862
_diffrn_reflns_theta_full        26.73
_diffrn_reflns_theta_max         26.73
_diffrn_reflns_theta_min         0.87
_diffrn_standards_decay_%        0
_exptl_absorpt_coefficient_mu    1.767
_exptl_absorpt_correction_T_max  0.8028
_exptl_absorpt_correction_T_min  0.5240
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Blessing, 1995'
_exptl_crystal_colour            Colourless
_exptl_crystal_density_diffrn    1.525
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Prism
_exptl_crystal_F_000             1600
_exptl_crystal_size_max          0.42
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.13
_refine_diff_density_max         2.196
_refine_diff_density_min         -1.853
_refine_diff_density_rms         0.097
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.169
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     824
_refine_ls_number_reflns         14255
_refine_ls_number_restraints     6
_refine_ls_restrained_S_all      1.169
_refine_ls_R_factor_all          0.0710
_refine_ls_R_factor_gt           0.0568
_refine_ls_shift/su_max          1.010
_refine_ls_shift/su_mean         0.011
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0139P)²+15.3110P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1167
_refine_ls_wR_factor_ref         0.1232
_reflns_number_gt                11986
_reflns_number_total             14255
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b007796h.txt
_cod_data_source_block           gab9969
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'Multi-scan' changed
to 'multi-scan' according to
'/home/saulius/struct/CIF-dictionaries/cif_core.dic' dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'calc
w=1/[\s^2^(Fo^2^)+(0.0139P)^2^+15.3110P] where P=(Fo^2^+2Fc^2^)/3'
was changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to
'w=1/[\s^2^(Fo^2^)+(0.0139P)^2^+15.3110P] where P=(Fo^2^+2Fc^2^)/3'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_cell_volume        3460.39(8)
_cod_database_code               7010292
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.26357(4) 0.74018(3) 0.133636(17) 0.03299(10) Uani 1 d . . .
Se1 Se 0.05687(6) 0.53759(6) 0.20527(3) 0.05655(19) Uani 1 d . . .
P1 P 0.37589(12) 0.64261(11) 0.08810(6) 0.0310(3) Uani 1 d . . .
P2 P 0.21906(12) 0.88698(12) 0.11098(6) 0.0304(3) Uani 1 d . . .
O1 O 0.0869(4) 0.5732(5) 0.14820(19) 0.0745(17) Uani 1 d . . .
O2 O -0.0764(5) 0.4295(5) 0.1997(2) 0.0861(19) Uani 1 d . . .
O3 O 0.1601(5) 0.5150(5) 0.2332(3) 0.100(2) Uani 1 d . . .
O4 O 0.0653(5) 0.6576(5) 0.2535(2) 0.0823(17) Uani 1 d . . .
H4 H 0.179(8) 0.759(8) 0.266(4) 0.099 Uiso 1 d . . .
C1 C 0.3037(5) 0.5691(4) 0.0137(2) 0.0326(11) Uani 1 d . . .
C2 C 0.1764(5) 0.4996(5) 0.0018(3) 0.0438(13) Uani 1 d . . .
H2B H 0.1314 0.4914 0.0324 0.053 Uiso 1 calc R . .
C3 C 0.1156(6) 0.4431(5) -0.0535(3) 0.0506(15) Uani 1 d . . .
H3B H 0.0292 0.3967 -0.0609 0.061 Uiso 1 calc R . .
C4 C 0.1809(6) 0.4540(5) -0.0984(3) 0.0480(14) Uani 1 d . . .
H4B H 0.1393 0.4144 -0.1366 0.058 Uiso 1 calc R . .
C5 C 0.3059(5) 0.5224(5) -0.0875(2) 0.0428(13) Uani 1 d . . .
H5A H 0.3502 0.5307 -0.1183 0.051 Uiso 1 calc R . .
C6 C 0.3673(5) 0.5790(5) -0.0320(2) 0.0364(12) Uani 1 d . . .
H6A H 0.4536 0.6250 -0.0249 0.044 Uiso 1 calc R . .
C7 C 0.5333(4) 0.7471(4) 0.0858(2) 0.0311(10) Uani 1 d . . .
C8 C 0.6243(5) 0.7150(5) 0.0819(3) 0.0433(13) Uani 1 d . . .
H8A H 0.6060 0.6366 0.0811 0.052 Uiso 1 calc R . .
C9 C 0.7422(5) 0.7969(6) 0.0790(3) 0.0542(17) Uani 1 d . . .
H9A H 0.8034 0.7735 0.0755 0.065 Uiso 1 calc R . .
C10 C 0.7710(5) 0.9104(6) 0.0811(3) 0.0521(16) Uani 1 d . . .
H10A H 0.8521 0.9662 0.0799 0.063 Uiso 1 calc R . .
C11 C 0.6812(6) 0.9438(6) 0.0849(3) 0.0620(19) Uani 1 d . . .
H11A H 0.7000 1.0219 0.0849 0.074 Uiso 1 calc R . .
C12 C 0.5632(5) 0.8628(5) 0.0887(3) 0.0487(15) Uani 1 d . . .
H12A H 0.5029 0.8872 0.0932 0.058 Uiso 1 calc R . .
C13 C 0.3856(5) 0.5257(5) 0.1113(2) 0.0332(11) Uani 1 d . . .
C14 C 0.3391(5) 0.4100(5) 0.0763(3) 0.0403(12) Uani 1 d . . .
H14A H 0.3011 0.3890 0.0382 0.048 Uiso 1 calc R . .
C15 C 0.3478(5) 0.3245(5) 0.0967(3) 0.0457(14) Uani 1 d . . .
H15A H 0.3166 0.2457 0.0723 0.055 Uiso 1 calc R . .
C16 C 0.4013(6) 0.3536(6) 0.1519(3) 0.0503(15) Uani 1 d . . .
H16A H 0.4051 0.2946 0.1661 0.060 Uiso 1 calc R . .
C17 C 0.4495(7) 0.4691(6) 0.1868(3) 0.0564(17) Uani 1 d . . .
H17A H 0.4885 0.4898 0.2247 0.068 Uiso 1 calc R . .
C18 C 0.4415(6) 0.5547(5) 0.1671(3) 0.0503(15) Uani 1 d . . .
H18A H 0.4741 0.6336 0.1916 0.060 Uiso 1 calc R . .
C19 C 0.1395(5) 0.8419(5) 0.0386(2) 0.0339(11) Uani 1 d . . .
C20 C 0.0517(5) 0.8722(5) 0.0245(3) 0.0427(13) Uani 1 d . . .
H20A H 0.0333 0.9219 0.0531 0.051 Uiso 1 calc R . .
C21 C -0.0086(6) 0.8302(6) -0.0309(3) 0.0529(16) Uani 1 d . . .
H21A H -0.0676 0.8521 -0.0401 0.063 Uiso 1 calc R . .
C22 C 0.0161(6) 0.7562(6) -0.0734(3) 0.0509(15) Uani 1 d . . .
H22A H -0.0262 0.7269 -0.1114 0.061 Uiso 1 calc R . .
C23 C 0.1023(6) 0.7261(6) -0.0598(3) 0.0509(15) Uani 1 d . . .
H23A H 0.1204 0.6767 -0.0888 0.061 Uiso 1 calc R . .
C24 C 0.1634(5) 0.7664(5) -0.0046(2) 0.0412(13) Uani 1 d . . .
H24A H 0.2216 0.7432 0.0042 0.049 Uiso 1 calc R . .
C25 C 0.1349(5) 0.9424(5) 0.1564(2) 0.0364(12) Uani 1 d . . .
C26 C 0.1368(5) 1.0505(5) 0.1593(3) 0.0445(14) Uani 1 d . . .
H26A H 0.1856 1.0988 0.1374 0.053 Uiso 1 calc R . .
C27 C 0.0678(6) 1.0873(7) 0.1940(3) 0.0610(19) Uani 1 d . . .
H27A H 0.0689 1.1600 0.1954 0.073 Uiso 1 calc R . .
C28 C -0.0015(7) 1.0190(8) 0.2261(4) 0.077(2) Uani 1 d . . .
H28A H -0.0488 1.0443 0.2495 0.093 Uiso 1 calc R . .
C29 C -0.0036(7) 0.9132(8) 0.2248(4) 0.076(2) Uani 1 d . . .
H29A H -0.0508 0.8675 0.2480 0.091 Uiso 1 calc R . .
C30 C 0.0634(5) 0.8732(6) 0.1897(3) 0.0513(15) Uani 1 d . . .
H30A H 0.0605 0.7997 0.1883 0.062 Uiso 1 calc R . .
C31 C 0.3639(4) 1.0175(4) 0.1157(2) 0.0326(11) Uani 1 d . . .
C32 C 0.4415(5) 1.0745(5) 0.1687(3) 0.0431(13) Uani 1 d . . .
H32A H 0.4143 1.0474 0.2007 0.052 Uiso 1 calc R . .
C33 C 0.5573(6) 1.1699(6) 0.1752(3) 0.0578(17) Uani 1 d . . .
H33A H 0.6079 1.2091 0.2115 0.069 Uiso 1 calc R . .
C34 C 0.5988(6) 1.2074(6) 0.1288(4) 0.0583(18) Uani 1 d . . .
H34A H 0.6788 1.2712 0.1329 0.070 Uiso 1 calc R . .
C35 C 0.5241(6) 1.1524(6) 0.0764(3) 0.0558(17) Uani 1 d . . .
H35A H 0.5531 1.1790 0.0446 0.067 Uiso 1 calc R . .
C36 C 0.4059(5) 1.0578(5) 0.0693(3) 0.0413(13) Uani 1 d . . .
H36A H 0.3548 1.0214 0.0331 0.050 Uiso 1 calc R . .
Ag2 Ag 0.66651(4) 1.09403(4) 0.368668(18) 0.03664(10) Uani 1 d . . .
Se2 Se 0.41015(6) 0.82432(5) 0.27488(2) 0.04668(16) Uani 1 d . . .
P3 P 0.80145(12) 1.03626(13) 0.40888(7) 0.0376(3) Uani 1 d . . .
P4 P 0.63961(12) 1.26792(11) 0.40202(6) 0.0311(3) Uani 1 d . . .
O5 O 0.4684(3) 0.9220(4) 0.33660(16) 0.0500(11) Uani 1 d . . .
O6 O 0.2871(4) 0.8167(4) 0.2470(2) 0.0644(13) Uani 1 d . . .
O7 O 0.3696(5) 0.6923(4) 0.28684(19) 0.0575(12) Uani 1 d . . .
H7B H 0.294(7) 0.642(7) 0.270(3) 0.069 Uiso 1 d . . .
O8 O 0.5043(5) 0.8426(4) 0.2296(2) 0.0764(16) Uani 1 d . . .
O9 O 0.6908(7) 1.0760(5) 0.2691(2) 0.103(2) Uani 1 d D . .
H9B H 0.727(7) 1.061(7) 0.237(3) 0.124 Uiso 1 d D . .
H9C H 0.615(4) 1.006(5) 0.259(4) 0.124 Uiso 1 d D . .
C37 C 0.9614(5) 1.1367(5) 0.4090(2) 0.0380(12) Uani 1 d . . .
C38 C 0.9924(5) 1.2451(5) 0.4001(3) 0.0466(14) Uani 1 d . . .
H38A H 0.9303 1.2639 0.3920 0.056 Uiso 1 calc R . .
C39 C 1.1143(6) 1.3272(5) 0.4030(3) 0.0546(17) Uani 1 d . . .
H39A H 1.1351 1.4016 0.3969 0.066 Uiso 1 calc R . .
C40 C 1.2043(6) 1.2999(6) 0.4147(3) 0.0581(18) Uani 1 d . . .
H40A H 1.2873 1.3559 0.4170 0.070 Uiso 1 calc R . .
C41 C 1.1750(5) 1.1921(6) 0.4232(3) 0.0570(17) Uani 1 d . . .
H41A H 1.2374 1.1736 0.4314 0.068 Uiso 1 calc R . .
C42 C 1.0543(5) 1.1109(6) 0.4198(3) 0.0509(15) Uani 1 d . . .
H42A H 1.0341 1.0359 0.4250 0.061 Uiso 1 calc R . .
C43 C 0.7895(5) 1.0464(5) 0.4838(2) 0.0359(12) Uani 1 d . . .
C44 C 0.6717(5) 0.9914(5) 0.4973(3) 0.0465(14) Uani 1 d . . .
H44A H 0.6028 0.9464 0.4678 0.056 Uiso 1 calc R . .
C45 C 0.6561(6) 1.0029(6) 0.5539(3) 0.0520(16) Uani 1 d . . .
H45A H 0.5765 0.9654 0.5629 0.062 Uiso 1 calc R . .
C46 C 0.7548(6) 1.0680(5) 0.5968(3) 0.0489(15) Uani 1 d . . .
H46A H 0.7433 1.0755 0.6354 0.059 Uiso 1 calc R . .
C47 C 0.8711(6) 1.1229(6) 0.5843(3) 0.0470(14) Uani 1 d . . .
H47A H 0.9393 1.1679 0.6143 0.056 Uiso 1 calc R . .
C48 C 0.8880(5) 1.1121(5) 0.5280(3) 0.0425(13) Uani 1 d . . .
H48A H 0.9681 1.1502 0.5196 0.051 Uiso 1 calc R . .
C49 C 0.7809(5) 0.8874(5) 0.3772(3) 0.0406(13) Uani 1 d . . .
C50 C 0.8023(5) 0.8219(5) 0.4084(3) 0.0485(15) Uani 1 d . . .
H50A H 0.8242 0.8527 0.4487 0.058 Uiso 1 calc R . .
C51 C 0.7918(6) 0.7119(6) 0.3808(4) 0.0581(18) Uani 1 d . . .
H51A H 0.8079 0.6686 0.4023 0.070 Uiso 1 calc R . .
C52 C 0.7584(6) 0.6656(6) 0.3229(4) 0.065(2) Uani 1 d . . .
H52A H 0.7520 0.5906 0.3044 0.078 Uiso 1 calc R . .
C53 C 0.7335(7) 0.7277(6) 0.2908(3) 0.0631(19) Uani 1 d . . .
H53A H 0.7094 0.6950 0.2506 0.076 Uiso 1 calc R . .
C54 C 0.7445(6) 0.8377(6) 0.3181(3) 0.0526(15) Uani 1 d . . .
H54A H 0.7271 0.8801 0.2964 0.063 Uiso 1 calc R . .
C55 C 0.5277(5) 1.2778(5) 0.3580(2) 0.0327(11) Uani 1 d . . .
C56 C 0.5410(6) 1.3860(5) 0.3537(2) 0.0413(13) Uani 1 d . . .
H56A H 0.6122 1.4581 0.3732 0.050 Uiso 1 calc R . .
C57 C 0.4512(6) 1.3888(6) 0.3213(3) 0.0521(16) Uani 1 d . . .
H57A H 0.4608 1.4627 0.3186 0.063 Uiso 1 calc R . .
C58 C 0.3479(6) 1.2850(6) 0.2929(2) 0.0534(16) Uani 1 d . . .
H58A H 0.2864 1.2875 0.2706 0.064 Uiso 1 calc R . .
C59 C 0.3329(6) 1.1775(6) 0.2966(2) 0.0486(15) Uani 1 d . . .
H59A H 0.2611 1.1060 0.2770 0.058 Uiso 1 calc R . .
C60 C 0.4224(5) 1.1734(5) 0.3290(2) 0.0398(12) Uani 1 d . . .
H60A H 0.4120 1.0991 0.3313 0.048 Uiso 1 calc R . .
C61 C 0.6054(4) 1.2983(4) 0.4742(2) 0.0323(11) Uani 1 d . . .
C62 C 0.6533(5) 1.2668(5) 0.5147(2) 0.0404(12) Uani 1 d . . .
H62A H 0.7057 1.2339 0.5048 0.048 Uiso 1 calc R . .
C63 C 0.6258(6) 1.2827(5) 0.5693(2) 0.0468(14) Uani 1 d . . .
H63A H 0.6588 1.2601 0.5965 0.056 Uiso 1 calc R . .
C64 C 0.5508(6) 1.3310(5) 0.5842(3) 0.0484(15) Uani 1 d . . .
H64A H 0.5326 1.3426 0.6218 0.058 Uiso 1 calc R . .
C65 C 0.5016(6) 1.3629(6) 0.5446(3) 0.0506(15) Uani 1 d . . .
H65A H 0.4495 1.3960 0.5550 0.061 Uiso 1 calc R . .
C66 C 0.5284(5) 1.3465(5) 0.4894(2) 0.0404(13) Uani 1 d . . .
H66A H 0.4943 1.3682 0.4622 0.048 Uiso 1 calc R . .
C67 C 0.7842(5) 1.3970(5) 0.4030(2) 0.0346(11) Uani 1 d . . .
C68 C 0.8270(6) 1.4004(6) 0.3515(3) 0.0532(16) Uani 1 d . . .
H68A H 0.7778 1.3409 0.3172 0.064 Uiso 1 calc R . .
C69 C 0.9411(7) 1.4899(6) 0.3499(3) 0.0630(19) Uani 1 d . . .
H69A H 0.9696 1.4920 0.3146 0.076 Uiso 1 calc R . .
C70 C 1.0129(6) 1.5756(6) 0.3993(3) 0.0573(18) Uani 1 d . . .
H70A H 1.0919 1.6359 0.3983 0.069 Uiso 1 calc R . .
C71 C 0.9707(6) 1.5741(6) 0.4496(3) 0.0536(16) Uani 1 d . . .
H71A H 1.0204 1.6346 0.4835 0.064 Uiso 1 calc R . .
C72 C 0.8558(5) 1.4854(5) 0.4524(2) 0.0427(13) Uani 1 d . . .
H72A H 0.8272 1.4857 0.4878 0.051 Uiso 1 calc R . .
O10 O 0.8702(9) 1.2132(8) 0.2207(4) 0.146(3) Uiso 1 d D . .
H10B H 0.932(8) 1.257(9) 0.253(3) 0.175 Uiso 1 d D . .
H10C H 0.860(11) 1.274(7) 0.213(5) 0.175 Uiso 1 d D . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Se Se -0.0929 2.2259 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Ag1 P2 113.66(15) . . y
O1 Ag1 P1 100.99(15) . . y
P2 Ag1 P1 131.13(5) . . y
O1 Se1 O2 114.5(2) . . ?
O1 Se1 O3 112.4(3) . . ?
O2 Se1 O3 111.0(3) . . ?
O1 Se1 O4 106.5(3) . . ?
O2 Se1 O4 107.1(3) . . ?
O3 Se1 O4 104.6(3) . . ?
C1 P1 C7 104.8(2) . . ?
C1 P1 C13 103.5(2) . . ?
C7 P1 C13 104.9(2) . . ?
C1 P1 Ag1 107.16(17) . . ?
C7 P1 Ag1 113.23(17) . . ?
C13 P1 Ag1 121.70(17) . . ?
C25 P2 C31 104.9(2) . . ?
C25 P2 C19 105.0(2) . . ?
C31 P2 C19 105.4(2) . . ?
C25 P2 Ag1 118.39(19) . . ?
C31 P2 Ag1 107.38(16) . . ?
C19 P2 Ag1 114.66(18) . . ?
Se1 O1 Ag1 129.0(2) . . ?
C6 C1 C2 118.3(5) . . ?
C6 C1 P1 123.9(4) . . ?
C2 C1 P1 117.9(4) . . ?
C3 C2 C1 121.0(6) . . ?
C2 C3 C4 119.8(6) . . ?
C5 C4 C3 119.9(6) . . ?
C4 C5 C6 120.4(5) . . ?
C5 C6 C1 120.6(5) . . ?
C12 C7 C8 118.7(5) . . ?
C12 C7 P1 118.9(4) . . ?
C8 C7 P1 122.4(4) . . ?
C7 C8 C9 120.4(5) . . ?
C10 C9 C8 120.8(6) . . ?
C9 C10 C11 119.6(6) . . ?
C10 C11 C12 120.0(6) . . ?
C7 C12 C11 120.5(5) . . ?
C14 C13 C18 118.8(5) . . ?
C14 C13 P1 123.1(4) . . ?
C18 C13 P1 118.2(4) . . ?
C13 C14 C15 120.4(6) . . ?
C16 C15 C14 120.3(6) . . ?
C15 C16 C17 119.6(6) . . ?
C18 C17 C16 120.6(6) . . ?
C17 C18 C13 120.2(6) . . ?
C20 C19 C24 118.5(5) . . ?
C20 C19 P2 123.8(4) . . ?
C24 C19 P2 117.6(4) . . ?
C21 C20 C19 120.4(6) . . ?
C20 C21 C22 120.8(6) . . ?
C23 C22 C21 119.1(6) . . ?
C22 C23 C24 121.2(6) . . ?
C23 C24 C19 120.1(6) . . ?
C30 C25 C26 118.8(5) . . ?
C30 C25 P2 118.2(4) . . ?
C26 C25 P2 123.0(4) . . ?
C27 C26 C25 120.5(6) . . ?
C28 C27 C26 120.1(7) . . ?
C27 C28 C29 120.7(7) . . ?
C28 C29 C30 120.4(7) . . ?
C29 C30 C25 119.5(7) . . ?
C36 C31 C32 118.6(5) . . ?
C36 C31 P2 124.0(4) . . ?
C32 C31 P2 117.2(4) . . ?
C33 C32 C31 121.0(6) . . ?
C34 C33 C32 119.9(6) . . ?
C33 C34 C35 120.0(6) . . ?
C34 C35 C36 121.0(6) . . ?
C31 C36 C35 119.6(6) . . ?
O5 Ag2 P4 108.19(11) . . y
O5 Ag2 P3 108.07(12) . . y
P4 Ag2 P3 131.20(5) . . y
O5 Ag2 O9 88.45(18) . . y
P4 Ag2 O9 105.66(19) . . y
P3 Ag2 O9 106.9(2) . . y
O5 Se2 O6 112.6(2) . . ?
O5 Se2 O8 113.8(2) . . ?
O6 Se2 O8 109.3(3) . . ?
O5 Se2 O7 105.3(2) . . ?
O6 Se2 O7 106.9(2) . . ?
O8 Se2 O7 108.5(3) . . ?
C49 P3 C37 105.0(2) . . ?
C49 P3 C43 104.6(3) . . ?
C37 P3 C43 105.0(3) . . ?
C49 P3 Ag2 118.84(19) . . ?
C37 P3 Ag2 111.99(19) . . ?
C43 P3 Ag2 110.25(17) . . ?
C55 P4 C61 105.1(2) . . ?
C55 P4 C67 104.5(2) . . ?
C61 P4 C67 105.5(2) . . ?
C55 P4 Ag2 117.16(17) . . ?
C61 P4 Ag2 116.44(17) . . ?
C67 P4 Ag2 106.94(17) . . ?
Se2 O5 Ag2 129.8(2) . . ?
C38 C37 C42 118.4(5) . . ?
C38 C37 P3 118.7(4) . . ?
C42 C37 P3 122.8(4) . . ?
C37 C38 C39 120.6(6) . . ?
C40 C39 C38 119.7(6) . . ?
C41 C40 C39 120.5(6) . . ?
C40 C41 C42 119.5(6) . . ?
C41 C42 C37 121.4(6) . . ?
C48 C43 C44 118.5(5) . . ?
C48 C43 P3 124.0(4) . . ?
C44 C43 P3 117.3(4) . . ?
C45 C44 C43 120.0(6) . . ?
C46 C45 C44 120.4(6) . . ?
C45 C46 C47 120.4(6) . . ?
C46 C47 C48 119.8(6) . . ?
C43 C48 C47 120.8(5) . . ?
C50 C49 C54 118.4(6) . . ?
C50 C49 P3 123.7(5) . . ?
C54 C49 P3 117.9(5) . . ?
C51 C50 C49 120.3(7) . . ?
C52 C51 C50 120.5(7) . . ?
C51 C52 C53 120.4(7) . . ?
C54 C53 C52 119.3(7) . . ?
C53 C54 C49 121.0(7) . . ?
C60 C55 C56 118.7(5) . . ?
C60 C55 P4 118.5(4) . . ?
C56 C55 P4 122.8(4) . . ?
C57 C56 C55 120.4(6) . . ?
C58 C57 C56 120.2(6) . . ?
C57 C58 C59 120.4(6) . . ?
C58 C59 C60 120.0(6) . . ?
C59 C60 C55 120.4(6) . . ?
C62 C61 C66 118.8(5) . . ?
C62 C61 P4 118.5(4) . . ?
C66 C61 P4 122.6(4) . . ?
C63 C62 C61 121.0(5) . . ?
C64 C63 C62 120.0(6) . . ?
C63 C64 C65 120.2(6) . . ?
C64 C65 C66 120.1(6) . . ?
C65 C66 C61 119.9(5) . . ?
C72 C67 C68 119.3(5) . . ?
C72 C67 P4 123.3(4) . . ?
C68 C67 P4 117.2(4) . . ?
C69 C68 C67 120.3(6) . . ?
C70 C69 C68 120.2(6) . . ?
C71 C70 C69 119.8(6) . . ?
C70 C71 C72 121.3(6) . . ?
C67 C72 C71 119.1(6) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 O1 2.421(4) . y
Ag1 P2 2.4349(13) . y
Ag1 P1 2.4405(13) . y
Se1 O1 1.589(4) . y
Se1 O2 1.596(4) . y
Se1 O3 1.626(6) . y
Se1 O4 1.687(6) . y
P1 C1 1.821(6) . y
P1 C7 1.829(5) . y
P1 C13 1.831(5) . y
P2 C25 1.810(5) . y
P2 C31 1.816(5) . y
P2 C19 1.825(5) . y
C1 C6 1.392(7) . ?
C1 C2 1.403(7) . ?
C2 C3 1.376(8) . ?
C3 C4 1.390(9) . ?
C4 C5 1.377(8) . ?
C5 C6 1.383(8) . ?
C7 C12 1.384(7) . ?
C7 C8 1.388(7) . ?
C8 C9 1.392(8) . ?
C9 C10 1.363(9) . ?
C10 C11 1.384(9) . ?
C11 C12 1.395(8) . ?
C13 C14 1.387(7) . ?
C13 C18 1.396(8) . ?
C14 C15 1.393(8) . ?
C15 C16 1.373(9) . ?
C16 C17 1.382(9) . ?
C17 C18 1.380(8) . ?
C19 C20 1.394(7) . ?
C19 C24 1.409(8) . ?
C20 C21 1.381(8) . ?
C21 C22 1.392(9) . ?
C22 C23 1.371(9) . ?
C23 C24 1.383(8) . ?
C25 C30 1.403(8) . ?
C25 C26 1.406(8) . ?
C26 C27 1.393(8) . ?
C27 C28 1.365(11) . ?
C28 C29 1.383(12) . ?
C29 C30 1.400(10) . ?
C31 C36 1.393(7) . ?
C31 C32 1.404(8) . ?
C32 C33 1.389(8) . ?
C33 C34 1.375(10) . ?
C34 C35 1.378(10) . ?
C35 C36 1.402(8) . ?
Ag2 O5 2.402(4) . y
Ag2 P4 2.4275(14) . y
Ag2 P3 2.4278(15) . y
Ag2 O9 2.439(5) . y
Se2 O5 1.611(4) . y
Se2 O6 1.618(5) . y
Se2 O8 1.624(5) . y
Se2 O7 1.689(4) . y
P3 C49 1.823(6) . y
P3 C37 1.825(5) . y
P3 C43 1.827(6) . y
P4 C55 1.817(5) . y
P4 C61 1.826(5) . y
P4 C67 1.826(5) . y
C37 C38 1.382(8) . ?
C37 C42 1.392(8) . ?
C38 C39 1.396(8) . ?
C39 C40 1.377(9) . ?
C40 C41 1.375(9) . ?
C41 C42 1.380(8) . ?
C43 C48 1.387(8) . ?
C43 C44 1.408(7) . ?
C44 C45 1.389(9) . ?
C45 C46 1.369(9) . ?
C46 C47 1.382(8) . ?
C47 C48 1.388(8) . ?
C49 C50 1.395(8) . ?
C49 C54 1.399(9) . ?
C50 C51 1.389(9) . ?
C51 C52 1.367(11) . ?
C52 C53 1.393(11) . ?
C53 C54 1.386(9) . ?
C55 C60 1.392(7) . ?
C55 C56 1.399(7) . ?
C56 C57 1.379(8) . ?
C57 C58 1.373(9) . ?
C58 C59 1.377(9) . ?
C59 C60 1.385(8) . ?
C61 C62 1.389(7) . ?
C61 C66 1.397(7) . ?
C62 C63 1.384(8) . ?
C63 C64 1.374(9) . ?
C64 C65 1.384(9) . ?
C65 C66 1.395(8) . ?
C67 C72 1.384(8) . ?
C67 C68 1.392(8) . ?
C68 C69 1.385(9) . ?
C69 C70 1.371(10) . ?
C70 C71 1.360(9) . ?
C71 C72 1.397(8) . ?
