#------------------------------------------------------------------------------
#$Date: 2016-03-25 11:19:48 +0100 (vie 25 de mar de 2016) $
#$Revision: 179810 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/06/7010653.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7010653
loop_
_publ_author_name
'Aucott, Stephen M.'
'Slawin, Alexandra M. Z.'
'Woollins, J. Derek'
_publ_section_title
;
 Synthesis of chelate complexes and the dichalcogen derivatives of the
 unsymmetrical diphosphine ligand Ph2PNHC6H4PPh2. Molecular structure
 of [PtCl2(Ph2PNHC6H4PPh2)]·0.75dmso·0.75CHCl3
;
_journal_issue                   15
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              2279
_journal_paper_doi               10.1039/b101772l
_journal_year                    2001
_chemical_formula_analytical     'C32.25 H30.25 Cl4.25 N O0.75 P2 Pt S0.75'
_chemical_formula_moiety
'C30 H25 Cl3 N  P2 Pt.[C H Cl3]0.75.[C2 H6 O S]0.75'
_chemical_formula_structural     'C32.25 H30.25 Cl4.25 N O0.75 P2 Pt S0.75'
_chemical_formula_sum            'C32.25 H30.25 Cl4.25 N O0.75 P2 Pt S0.75'
_chemical_formula_weight         875.56
_chemical_name_systematic
; 
? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL
_cell_angle_alpha                90.00
_cell_angle_beta                 98.8060(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   12.2267(2)
_cell_length_b                   21.7198(3)
_cell_length_c                   14.1548(2)
_cell_measurement_reflns_used    71
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      168
_cell_measurement_theta_min      12
_cell_volume                     3714.66(10)
_computing_cell_refinement       SMART/SAINT
_computing_data_collection       SMART
_computing_data_reduction        SAINT
_computing_molecular_graphics    SHELXTL
_computing_publication_material  SHELXTL
_computing_structure_refinement  'SHELXL-93 (Sheldrick, 1993)'
_computing_structure_solution    'SHELXS-86 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measurement_device       SMART
_diffrn_measurement_method       CCD
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0217
_diffrn_reflns_av_sigmaI/netI    0.0244
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -9
_diffrn_reflns_number            16141
_diffrn_reflns_theta_max         23.22
_diffrn_reflns_theta_min         1.73
_diffrn_standards_decay_%        -
_diffrn_standards_interval_count -
_diffrn_standards_interval_time  -
_diffrn_standards_number         -
_exptl_absorpt_coefficient_mu    4.236
_exptl_absorpt_correction_T_max  1.000000
_exptl_absorpt_correction_T_min  0.649616
_exptl_absorpt_correction_type   sadabs
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.566
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    -
_exptl_crystal_description       prism
_exptl_crystal_F_000             1716
_exptl_crystal_size_max          .2
_exptl_crystal_size_mid          .3
_exptl_crystal_size_min          .4
_refine_diff_density_max         2.771
_refine_diff_density_min         -1.435
_refine_diff_density_rms         0.100
_refine_ls_extinction_coef       0.00094(14)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_all   1.040
_refine_ls_goodness_of_fit_obs   1.081
_refine_ls_hydrogen_treatment    riding
_refine_ls_matrix_type           full
_refine_ls_number_parameters     382
_refine_ls_number_reflns         5260
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.236
_refine_ls_restrained_S_obs      1.081
_refine_ls_R_factor_all          0.0396
_refine_ls_R_factor_obs          0.0330
_refine_ls_shift/esd_max         -0.390
_refine_ls_shift/esd_mean        0.010
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0622P)²+4.1325P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         0.1088
_refine_ls_wR_factor_obs         0.0893
_reflns_number_observed          4656
_reflns_number_total             5310
_reflns_observed_criterion       >2sigma(I)
_cod_data_source_file            b101772l.txt
_cod_data_source_block           3
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value '-' was changed to '?' - the
value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 

The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'calc
w=1/[\s^2^(Fo^2^)+(0.0622P)^2^+4.1325P] where P=(Fo^2^+2Fc^2^)/3' was
changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to
'w=1/[\s^2^(Fo^2^)+(0.0622P)^2^+4.1325P] where P=(Fo^2^+2Fc^2^)/3'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_sg_symbol_H-M      P2(1)/n
_cod_database_code               7010653
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_thermal_displace_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_group
Pt1 Pt 0.17755(2) 0.132722(9) 0.643896(14) 0.03719(12) Uani 1 d . .
Cl1 Cl 0.03978(13) 0.18880(7) 0.70762(12) 0.0592(4) Uani 1 d . .
Cl2 Cl 0.1210(2) 0.17996(9) 0.49439(13) 0.0752(5) Uani 1 d . .
P1 P 0.20963(11) 0.08314(6) 0.78192(9) 0.0365(3) Uani 1 d . .
N1 N 0.3019(4) 0.0251(2) 0.7840(3) 0.0403(10) Uani 1 d D .
H1N H 0.2821(46) -0.0063(19) 0.8280(32) 0.051(16) Uiso 1 d D .
C1 C 0.4102(4) 0.0363(2) 0.7659(4) 0.0402(12) Uani 1 d . .
C2 C 0.4282(4) 0.0608(2) 0.6777(4) 0.0388(12) Uani 1 d . .
C3 C 0.5372(5) 0.0681(3) 0.6603(4) 0.0479(14) Uani 1 d . .
H3A H 0.5501(5) 0.0836(3) 0.6017(4) 0.058 Uiso 1 calc R .
C4 C 0.6266(5) 0.0524(3) 0.7292(5) 0.056(2) Uani 1 d . .
H4A H 0.6985(5) 0.0573(3) 0.7167(5) 0.067 Uiso 1 calc R .
C5 C 0.6081(5) 0.0297(3) 0.8154(5) 0.058(2) Uani 1 d . .
H5A H 0.6680(5) 0.0193(3) 0.8614(5) 0.070 Uiso 1 calc R .
C6 C 0.5019(5) 0.0219(3) 0.8350(4) 0.0488(14) Uani 1 d . .
H6A H 0.4908(5) 0.0071(3) 0.8945(4) 0.059 Uiso 1 calc R .
C7 C 0.2576(5) 0.1298(3) 0.8857(4) 0.0457(14) Uani 1 d . .
C8 C 0.2834(6) 0.1914(3) 0.8748(5) 0.064(2) Uani 1 d . .
H8A H 0.2653(6) 0.2102(3) 0.8154(5) 0.076 Uiso 1 calc R .
C9 C 0.3364(7) 0.2253(4) 0.9526(6) 0.087(2) Uani 1 d . .
H9A H 0.3568(7) 0.2661(4) 0.9456(6) 0.104 Uiso 1 calc R .
C10 C 0.3579(8) 0.1956(5) 1.0418(7) 0.104(3) Uani 1 d . .
H10A H 0.3899(8) 0.2177(5) 1.0952(7) 0.125 Uiso 1 calc R .
C11 C 0.3329(9) 0.1353(4) 1.0515(6) 0.100(3) Uani 1 d . .
H11A H 0.3491(9) 0.1165(4) 1.1110(6) 0.120 Uiso 1 calc R .
C12 C 0.2839(7) 0.1018(4) 0.9744(5) 0.074(2) Uani 1 d . .
H12A H 0.2682(7) 0.0603(4) 0.9815(5) 0.089 Uiso 1 calc R .
C13 C 0.0894(4) 0.0404(3) 0.8050(4) 0.0455(13) Uani 1 d . .
C14 C 0.0216(6) 0.0598(4) 0.8682(6) 0.072(2) Uani 1 d . .
H14A H 0.0369(6) 0.0963(4) 0.9022(6) 0.087 Uiso 1 calc R .
C15 C -0.0707(6) 0.0242(5) 0.8811(7) 0.092(3) Uani 1 d . .
H15A H -0.1151(6) 0.0366(5) 0.9254(7) 0.111 Uiso 1 calc R .
C16 C -0.0958(6) -0.0271(5) 0.8308(8) 0.096(3) Uani 1 d . .
H16A H -0.1582(6) -0.0494(5) 0.8399(8) 0.116 Uiso 1 calc R .
C17 C -0.0300(7) -0.0482(4) 0.7643(7) 0.086(2) Uani 1 d . .
H17A H -0.0482(7) -0.0839(4) 0.7291(7) 0.103 Uiso 1 calc R .
C18 C 0.0636(5) -0.0138(3) 0.7528(5) 0.063(2) Uani 1 d . .
H18A H 0.1093(5) -0.0270(3) 0.7100(5) 0.076 Uiso 1 calc R .
P2 P 0.30932(11) 0.07886(6) 0.58798(9) 0.0364(3) Uani 1 d . .
C19 C 0.2577(4) 0.0052(2) 0.5405(4) 0.0403(12) Uani 1 d . .
C20 C 0.3168(5) -0.0490(3) 0.5612(5) 0.0537(15) Uani 1 d . .
H20A H 0.3847(5) -0.0480(3) 0.6012(5) 0.064 Uiso 1 calc R .
C21 C 0.2753(6) -0.1046(3) 0.5228(5) 0.063(2) Uani 1 d . .
H21A H 0.3165(6) -0.1405(3) 0.5357(5) 0.076 Uiso 1 calc R .
C22 C 0.1735(6) -0.1070(3) 0.4657(5) 0.062(2) Uani 1 d . .
H22A H 0.1445(6) -0.1443(3) 0.4413(5) 0.075 Uiso 1 calc R .
C23 C 0.1151(6) -0.0526(3) 0.4454(5) 0.071(2) Uani 1 d . .
H23A H 0.0467(6) -0.0535(3) 0.4061(5) 0.085 Uiso 1 calc R .
C24 C 0.1557(5) 0.0016(3) 0.4816(5) 0.061(2) Uani 1 d . .
H24A H 0.1147(5) 0.0373(3) 0.4670(5) 0.073 Uiso 1 calc R .
C25 C 0.3676(5) 0.1176(3) 0.4932(4) 0.0437(13) Uani 1 d . .
C26 C 0.3701(5) 0.0907(3) 0.4057(4) 0.058(2) Uani 1 d . .
H26A H 0.3416(5) 0.0513(3) 0.3942(4) 0.070 Uiso 1 calc R .
C27 C 0.4139(7) 0.1210(4) 0.3351(5) 0.081(2) Uani 1 d . .
H27A H 0.4154(7) 0.1018(4) 0.2766(5) 0.097 Uiso 1 calc R .
C28 C 0.4553(7) 0.1790(4) 0.3501(6) 0.084(2) Uani 1 d . .
H28A H 0.4829(7) 0.1998(4) 0.3013(6) 0.100 Uiso 1 calc R .
C29 C 0.4559(7) 0.2074(3) 0.4392(7) 0.082(2) Uani 1 d . .
H29A H 0.4871(7) 0.2462(3) 0.4513(7) 0.099 Uiso 1 calc R .
C30 C 0.4091(6) 0.1764(3) 0.5092(5) 0.069(2) Uani 1 d . .
H30A H 0.4058(6) 0.1955(3) 0.5675(5) 0.082 Uiso 1 calc R .
C40 C 0.6472(11) 0.2544(6) 0.7698(10) 0.113(5) Uani 0.75 d P .
H40A H 0.6736(11) 0.2804(6) 0.8252(10) 0.136 Uiso 0.75 calc PR .
Cl3 Cl 0.5320(3) 0.2121(2) 0.7913(3) 0.1280(15) Uani 0.75 d P .
Cl4 Cl 0.7540(3) 0.2045(2) 0.7465(3) 0.1218(13) Uani 0.75 d P .
Cl5 Cl 0.6102(5) 0.3011(2) 0.6664(5) 0.164(2) Uani 0.75 d P .
O50 O 0.2943(5) -0.0577(3) 0.9403(4) 0.0631(15) Uiso 0.75 d P .
S50 S 0.3262(3) -0.1236(2) 0.9487(3) 0.1118(11) Uiso 0.75 d P .
C51 C 0.3153(18) -0.1544(12) 0.8321(17) 0.184(9) Uiso 0.75 d P .
H51A H 0.3733(18) -0.1379(12) 0.8009(17) 0.277 Uiso 0.75 calc PR .
H51B H 0.2448(18) -0.1436(12) 0.7963(17) 0.277 Uiso 0.75 calc PR .
H51C H 0.3220(18) -0.1984(12) 0.8356(17) 0.277 Uiso 0.75 calc PR .
C52 C 0.2255(23) -0.1550(13) 0.9759(21) 0.231(11) Uiso 0.75 d P .
H52A H 0.2175(23) -0.1439(13) 1.0401(21) 0.347 Uiso 0.75 calc PR .
H52B H 0.2340(23) -0.1989(13) 0.9719(21) 0.347 Uiso 0.75 calc PR .
H52C H 0.1609(23) -0.1424(13) 0.9330(21) 0.347 Uiso 0.75 calc PR .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Pt1 P2 91.03(5) . . ?
P1 Pt1 Cl2 172.80(6) . . ?
P2 Pt1 Cl2 92.18(6) . . ?
P1 Pt1 Cl1 87.38(5) . . ?
P2 Pt1 Cl1 178.37(5) . . ?
Cl2 Pt1 Cl1 89.44(6) . . ?
N1 P1 C7 105.8(2) . . ?
N1 P1 C13 100.0(2) . . ?
C7 P1 C13 108.2(3) . . ?
N1 P1 Pt1 114.0(2) . . ?
C7 P1 Pt1 115.9(2) . . ?
C13 P1 Pt1 111.7(2) . . ?
C1 N1 P1 120.8(4) . . ?
C2 C1 N1 120.5(5) . . ?
C2 C1 C6 119.0(5) . . ?
N1 C1 C6 120.4(5) . . ?
C3 C2 C1 118.9(5) . . ?
C3 C2 P2 122.1(4) . . ?
C1 C2 P2 118.9(4) . . ?
C4 C3 C2 121.0(6) . . ?
C5 C4 C3 119.7(6) . . ?
C4 C5 C6 120.9(6) . . ?
C5 C6 C1 120.5(6) . . ?
C12 C7 C8 119.8(6) . . ?
C12 C7 P1 119.4(5) . . ?
C8 C7 P1 120.1(5) . . ?
C7 C8 C9 120.3(7) . . ?
C8 C9 C10 117.8(7) . . ?
C11 C10 C9 121.3(7) . . ?
C10 C11 C12 120.6(8) . . ?
C11 C12 C7 120.1(7) . . ?
C14 C13 C18 119.5(6) . . ?
C14 C13 P1 123.2(5) . . ?
C18 C13 P1 117.3(5) . . ?
C13 C14 C15 119.5(8) . . ?
C16 C15 C14 121.0(8) . . ?
C15 C16 C17 121.5(7) . . ?
C18 C17 C16 117.9(8) . . ?
C17 C18 C13 120.7(7) . . ?
C19 P2 C25 106.8(3) . . ?
C19 P2 C2 105.3(2) . . ?
C25 P2 C2 104.7(3) . . ?
C19 P2 Pt1 111.4(2) . . ?
C25 P2 Pt1 113.8(2) . . ?
C2 P2 Pt1 114.1(2) . . ?
C20 C19 C24 117.9(5) . . ?
C20 C19 P2 122.0(4) . . ?
C24 C19 P2 120.1(4) . . ?
C19 C20 C21 120.5(6) . . ?
C22 C21 C20 120.4(6) . . ?
C21 C22 C23 118.7(6) . . ?
C24 C23 C22 121.1(6) . . ?
C23 C24 C19 121.5(6) . . ?
C26 C25 C30 118.9(6) . . ?
C26 C25 P2 122.2(5) . . ?
C30 C25 P2 118.9(5) . . ?
C27 C26 C25 121.2(7) . . ?
C28 C27 C26 120.5(8) . . ?
C27 C28 C29 119.8(7) . . ?
C30 C29 C28 118.7(7) . . ?
C25 C30 C29 120.8(7) . . ?
Cl3 C40 Cl4 110.4(7) . . ?
Cl3 C40 Cl5 109.4(8) . . ?
Cl4 C40 Cl5 107.3(7) . . ?
O50 S50 C52 104.0(11) . . ?
O50 S50 C51 108.0(9) . . ?
C52 S50 C51 96.9(14) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 P1 2.2126(13) . ?
Pt1 P2 2.2319(13) . ?
Pt1 Cl2 2.358(2) . ?
Pt1 Cl1 2.3664(14) . ?
P1 N1 1.689(4) . ?
P1 C7 1.806(6) . ?
P1 C13 1.810(5) . ?
N1 C1 1.407(7) . ?
C1 C2 1.404(8) . ?
C1 C6 1.406(8) . ?
C2 C3 1.401(8) . ?
C2 P2 1.821(5) . ?
C3 C4 1.391(8) . ?
C4 C5 1.366(9) . ?
C5 C6 1.380(9) . ?
C7 C12 1.388(9) . ?
C7 C8 1.389(8) . ?
C8 C9 1.399(10) . ?
C9 C10 1.407(13) . ?
C10 C11 1.356(12) . ?
C11 C12 1.371(11) . ?
C13 C14 1.375(9) . ?
C13 C18 1.400(9) . ?
C14 C15 1.403(11) . ?
C15 C16 1.333(13) . ?
C16 C17 1.405(13) . ?
C17 C18 1.397(10) . ?
P2 C19 1.810(5) . ?
P2 C25 1.818(6) . ?
C19 C20 1.389(8) . ?
C19 C24 1.392(8) . ?
C20 C21 1.389(9) . ?
C21 C22 1.378(9) . ?
C22 C23 1.389(10) . ?
C23 C24 1.347(9) . ?
C25 C26 1.374(8) . ?
C25 C30 1.380(9) . ?
C26 C27 1.372(10) . ?
C27 C28 1.362(12) . ?
C28 C29 1.404(12) . ?
C29 C30 1.392(10) . ?
C40 Cl3 1.746(11) . ?
C40 Cl4 1.766(14) . ?
C40 Cl5 1.78(2) . ?
O50 S50 1.485(7) . ?
S50 C52 1.51(3) . ?
S50 C51 1.77(2) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
P2 Pt1 P1 N1 -5.8(2) . . . . ?
Cl2 Pt1 P1 N1 110.7(5) . . . . ?
Cl1 Pt1 P1 N1 174.6(2) . . . . ?
P2 Pt1 P1 C7 117.3(2) . . . . ?
Cl2 Pt1 P1 C7 -126.2(5) . . . . ?
Cl1 Pt1 P1 C7 -62.4(2) . . . . ?
P2 Pt1 P1 C13 -118.2(2) . . . . ?
Cl2 Pt1 P1 C13 -1.7(5) . . . . ?
Cl1 Pt1 P1 C13 62.2(2) . . . . ?
C7 P1 N1 C1 -69.8(4) . . . . ?
C13 P1 N1 C1 177.9(4) . . . . ?
Pt1 P1 N1 C1 58.6(4) . . . . ?
P1 N1 C1 C2 -60.7(6) . . . . ?
P1 N1 C1 C6 120.7(5) . . . . ?
N1 C1 C2 C3 -176.4(5) . . . . ?
C6 C1 C2 C3 2.2(8) . . . . ?
N1 C1 C2 P2 0.9(7) . . . . ?
C6 C1 C2 P2 179.5(4) . . . . ?
C1 C2 C3 C4 -1.0(8) . . . . ?
P2 C2 C3 C4 -178.3(4) . . . . ?
C2 C3 C4 C5 -0.1(9) . . . . ?
C3 C4 C5 C6 0.1(10) . . . . ?
C4 C5 C6 C1 1.1(9) . . . . ?
C2 C1 C6 C5 -2.3(8) . . . . ?
N1 C1 C6 C5 176.3(5) . . . . ?
N1 P1 C7 C12 -50.2(6) . . . . ?
C13 P1 C7 C12 56.2(6) . . . . ?
Pt1 P1 C7 C12 -177.4(5) . . . . ?
N1 P1 C7 C8 120.5(5) . . . . ?
C13 P1 C7 C8 -133.1(5) . . . . ?
Pt1 P1 C7 C8 -6.8(6) . . . . ?
C12 C7 C8 C9 0.5(11) . . . . ?
P1 C7 C8 C9 -170.1(6) . . . . ?
C7 C8 C9 C10 -2.7(12) . . . . ?
C8 C9 C10 C11 3.0(15) . . . . ?
C9 C10 C11 C12 -1.2(17) . . . . ?
C10 C11 C12 C7 -1.1(15) . . . . ?
C8 C7 C12 C11 1.4(12) . . . . ?
P1 C7 C12 C11 172.1(7) . . . . ?
N1 P1 C13 C14 135.7(5) . . . . ?
C7 P1 C13 C14 25.3(6) . . . . ?
Pt1 P1 C13 C14 -103.4(5) . . . . ?
N1 P1 C13 C18 -46.5(5) . . . . ?
C7 P1 C13 C18 -156.9(5) . . . . ?
Pt1 P1 C13 C18 74.4(5) . . . . ?
C18 C13 C14 C15 1.6(10) . . . . ?
P1 C13 C14 C15 179.3(6) . . . . ?
C13 C14 C15 C16 -2.2(13) . . . . ?
C14 C15 C16 C17 1.1(15) . . . . ?
C15 C16 C17 C18 0.4(13) . . . . ?
C16 C17 C18 C13 -1.0(11) . . . . ?
C14 C13 C18 C17 0.0(10) . . . . ?
P1 C13 C18 C17 -177.9(5) . . . . ?
C3 C2 P2 C19 102.8(5) . . . . ?
C1 C2 P2 C19 -74.5(5) . . . . ?
C3 C2 P2 C25 -9.7(5) . . . . ?
C1 C2 P2 C25 173.1(4) . . . . ?
C3 C2 P2 Pt1 -134.8(4) . . . . ?
C1 C2 P2 Pt1 48.0(4) . . . . ?
P1 Pt1 P2 C19 83.6(2) . . . . ?
Cl2 Pt1 P2 C19 -90.0(2) . . . . ?
Cl1 Pt1 P2 C19 96.8(19) . . . . ?
P1 Pt1 P2 C25 -155.6(2) . . . . ?
Cl2 Pt1 P2 C25 30.9(2) . . . . ?
Cl1 Pt1 P2 C25 -142.4(19) . . . . ?
P1 Pt1 P2 C2 -35.5(2) . . . . ?
Cl2 Pt1 P2 C2 150.9(2) . . . . ?
Cl1 Pt1 P2 C2 -22.3(19) . . . . ?
C25 P2 C19 C20 100.3(5) . . . . ?
C2 P2 C19 C20 -10.6(6) . . . . ?
Pt1 P2 C19 C20 -134.8(5) . . . . ?
C25 P2 C19 C24 -80.0(5) . . . . ?
C2 P2 C19 C24 169.1(5) . . . . ?
Pt1 P2 C19 C24 44.9(5) . . . . ?
C24 C19 C20 C21 1.0(9) . . . . ?
P2 C19 C20 C21 -179.3(5) . . . . ?
C19 C20 C21 C22 -1.8(10) . . . . ?
C20 C21 C22 C23 1.8(11) . . . . ?
C21 C22 C23 C24 -1.0(12) . . . . ?
C22 C23 C24 C19 0.2(12) . . . . ?
C20 C19 C24 C23 -0.2(10) . . . . ?
P2 C19 C24 C23 -179.9(6) . . . . ?
C19 P2 C25 C26 -1.6(6) . . . . ?
C2 P2 C25 C26 109.7(5) . . . . ?
Pt1 P2 C25 C26 -125.0(5) . . . . ?
C19 P2 C25 C30 177.4(5) . . . . ?
C2 P2 C25 C30 -71.2(5) . . . . ?
Pt1 P2 C25 C30 54.0(6) . . . . ?
C30 C25 C26 C27 0.6(10) . . . . ?
P2 C25 C26 C27 179.6(6) . . . . ?
C25 C26 C27 C28 -0.6(12) . . . . ?
C26 C27 C28 C29 1.8(13) . . . . ?
C27 C28 C29 C30 -3.0(12) . . . . ?
C26 C25 C30 C29 -1.9(11) . . . . ?
P2 C25 C30 C29 179.0(6) . . . . ?
C28 C29 C30 C25 3.1(12) . . . . ?
