#------------------------------------------------------------------------------
#$Date: 2016-03-25 11:21:42 +0100 (vie 25 de mar de 2016) $
#$Revision: 179812 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/08/7010823.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7010823
loop_
_publ_author_name
'Slawin, Alexandra M. Z.'
'Wainwright, Matthew'
'Woollins, J. Derek'
_publ_section_title
;
 The preparation and coordination chemistry of phosphorus(iii)
 derivatives of dialkyl ureas and thioureas
;
_journal_issue                   19
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              2724
_journal_paper_doi               10.1039/b104122n
_journal_year                    2001
_chemical_formula_analytical     'C30 H31 Au2 Cl5 N2 O P2'
_chemical_formula_moiety         'C29 H30 Au2 Cl2 N2 O P2.C H Cl3 '
_chemical_formula_structural     'C30 H31 Au2 Cl5 N2 O P2'
_chemical_formula_sum            'C30 H31 Au2 Cl5 N2 O P2'
_chemical_formula_weight         1068.69
_chemical_name_systematic
; 
? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL
_cell_angle_alpha                90.00
_cell_angle_beta                 98.36
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   14.5596(5)
_cell_length_b                   15.4267(5)
_cell_length_c                   16.1541(5)
_cell_measurement_reflns_used    37
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      337
_cell_measurement_theta_min      23
_cell_volume                     3589.8(2)
_computing_cell_refinement       SMART/SAINT
_computing_data_collection       SMART
_computing_data_reduction        SAINT
_computing_molecular_graphics    SHELXTL
_computing_publication_material  SHELXTL
_computing_structure_refinement  'SHELXL-93 (Sheldrick, 1993)'
_computing_structure_solution    'SHELXS-86 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measurement_device       SMART
_diffrn_measurement_method       CCD
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0428
_diffrn_reflns_av_sigmaI/netI    0.0647
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            21674
_diffrn_reflns_theta_max         28.69
_diffrn_reflns_theta_min         1.41
_exptl_absorpt_coefficient_mu    8.652
_exptl_absorpt_correction_T_max  1.000000
_exptl_absorpt_correction_T_min  0.549824
_exptl_absorpt_correction_type   sadabs
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.977
_exptl_crystal_description       needle
_exptl_crystal_F_000             2024
_exptl_crystal_size_max          .1
_exptl_crystal_size_mid          .1
_exptl_crystal_size_min          .3
_refine_diff_density_max         1.245
_refine_diff_density_min         -1.011
_refine_diff_density_rms         0.132
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_all   0.849
_refine_ls_goodness_of_fit_obs   0.905
_refine_ls_hydrogen_treatment    riding
_refine_ls_matrix_type           full
_refine_ls_number_parameters     379
_refine_ls_number_reflns         8341
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.008
_refine_ls_restrained_S_obs      0.905
_refine_ls_R_factor_all          0.0747
_refine_ls_R_factor_obs          0.0354
_refine_ls_shift/esd_max         -0.122
_refine_ls_shift/esd_mean        0.007
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_scheme
;
calc w=1/[\s^2^(Fo^2^)+(0.0508P)^2^+0.0000P] where 
P=(Fo^2^+2Fc^2^)/3
;
_refine_ls_wR_factor_all         0.1052
_refine_ls_wR_factor_obs         0.0752
_reflns_number_observed          5380
_reflns_number_total             8391
_reflns_observed_criterion       >2sigma(I)
_cod_data_source_file            b104122n.txt
_cod_data_source_block           15
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               7010823
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_thermal_displace_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_group
Au1 Au 0.73636(2) 0.90347(2) 0.101736(15) 0.04376(8) Uani 1 d . .
Cl1 Cl 0.79076(13) 0.89256(11) -0.02563(10) 0.0556(4) Uani 1 d . .
P1 P 0.67722(12) 0.93446(11) 0.21869(10) 0.0426(4) Uani 1 d . .
Au2 Au 0.85655(2) 0.76540(2) 0.617084(15) 0.04293(8) Uani 1 d . .
Cl2 Cl 0.95411(14) 0.67433(15) 0.70129(13) 0.0775(6) Uani 1 d . .
C1 C 0.7233(6) 1.0384(4) 0.2593(4) 0.059(2) Uani 1 d . .
C2 C 0.8196(7) 1.0456(6) 0.2777(5) 0.079(3) Uani 1 d . .
H2A H 0.8581(7) 0.9994(6) 0.2692(5) 0.095 Uiso 1 calc R .
C3 C 0.8568(9) 1.1262(9) 0.3097(6) 0.114(4) Uani 1 d . .
H3A H 0.9208(9) 1.1330(9) 0.3216(6) 0.137 Uiso 1 calc R .
C4 C 0.8012(17) 1.1926(9) 0.3231(8) 0.156(8) Uani 1 d . .
H4A H 0.8273(17) 1.2436(9) 0.3464(8) 0.187 Uiso 1 calc R .
C5 C 0.7050(14) 1.1862(7) 0.3027(9) 0.146(7) Uani 1 d . .
H5A H 0.6670(14) 1.2333(7) 0.3099(9) 0.175 Uiso 1 calc R .
C6 C 0.6665(8) 1.1072(5) 0.2711(6) 0.095(3) Uani 1 d . .
H6A H 0.6025(8) 1.1015(5) 0.2582(6) 0.114 Uiso 1 calc R .
C7 C 0.5523(5) 0.9449(4) 0.2006(4) 0.051(2) Uani 1 d . .
C8 C 0.5117(6) 0.9753(8) 0.1234(5) 0.115(4) Uani 1 d . .
H8A H 0.5485(6) 0.9881(8) 0.0825(5) 0.137 Uiso 1 calc R .
C9 C 0.4177(8) 0.9865(11) 0.1070(7) 0.162(7) Uani 1 d . .
H9A H 0.3917(8) 1.0114(11) 0.0566(7) 0.194 Uiso 1 calc R .
C10 C 0.3616(6) 0.9620(7) 0.1628(6) 0.101(3) Uani 1 d . .
H10A H 0.2975(6) 0.9668(7) 0.1490(6) 0.122 Uiso 1 calc R .
C11 C 0.3987(6) 0.9306(6) 0.2390(6) 0.077(2) Uani 1 d . .
H11A H 0.3604(6) 0.9148(6) 0.2778(6) 0.092 Uiso 1 calc R .
C12 C 0.4962(5) 0.9221(5) 0.2584(5) 0.063(2) Uani 1 d . .
H12A H 0.5224(5) 0.9010(5) 0.3105(5) 0.076 Uiso 1 calc R .
N1 N 0.7100(3) 0.8641(3) 0.2993(3) 0.0382(11) Uani 1 d . .
C26 C 0.7138(5) 0.7700(4) 0.2838(4) 0.052(2) Uani 1 d . .
H26A H 0.7462(5) 0.7425(4) 0.3336(4) 0.062 Uiso 1 calc R .
H26B H 0.7503(5) 0.7604(4) 0.2389(4) 0.062 Uiso 1 calc R .
C28 C 0.6228(7) 0.7268(5) 0.2613(6) 0.083(3) Uani 1 d . .
H28A H 0.6323(7) 0.6661(5) 0.2523(6) 0.125 Uiso 1 calc R .
H28B H 0.5906(7) 0.7522(5) 0.2111(6) 0.125 Uiso 1 calc R .
H28C H 0.5866(7) 0.7339(5) 0.3060(6) 0.125 Uiso 1 calc R .
C13 C 0.7141(4) 0.8967(4) 0.3816(4) 0.0352(13) Uani 1 d . .
O13 O 0.6604(3) 0.9518(3) 0.3987(2) 0.0427(10) Uani 1 d . .
N2 N 0.7827(3) 0.8622(3) 0.4412(3) 0.0360(11) Uani 1 d . .
C27 C 0.8745(4) 0.8336(4) 0.4204(4) 0.046(2) Uani 1 d . .
H27A H 0.8714(4) 0.8299(4) 0.3601(4) 0.056 Uiso 1 calc R .
H27B H 0.8889(4) 0.7764(4) 0.4435(4) 0.056 Uiso 1 calc R .
C29 C 0.9502(5) 0.8957(6) 0.4546(6) 0.081(3) Uani 1 d . .
H29A H 1.0083(5) 0.8760(6) 0.4401(6) 0.122 Uiso 1 calc R .
H29B H 0.9543(5) 0.8985(6) 0.5144(6) 0.122 Uiso 1 calc R .
H29C H 0.9364(5) 0.9522(6) 0.4312(6) 0.122 Uiso 1 calc R .
P2 P 0.76606(10) 0.86457(10) 0.54358(9) 0.0351(3) Uani 1 d . .
C14 C 0.7908(4) 0.9724(4) 0.5879(4) 0.0419(15) Uani 1 d . .
C15 C 0.7764(5) 1.0478(5) 0.5423(5) 0.065(2) Uani 1 d . .
H15A H 0.7511(5) 1.0456(5) 0.4861(5) 0.078 Uiso 1 calc R .
C16 C 0.7997(5) 1.1278(5) 0.5804(6) 0.075(2) Uani 1 d . .
H16A H 0.7930(5) 1.1786(5) 0.5491(6) 0.090 Uiso 1 calc R .
C17 C 0.8328(5) 1.1307(6) 0.6651(6) 0.076(3) Uani 1 d . .
H17A H 0.8445(5) 1.1841(6) 0.6913(6) 0.092 Uiso 1 calc R .
C18 C 0.8484(6) 1.0575(6) 0.7101(6) 0.080(3) Uani 1 d . .
H18A H 0.8744(6) 1.0604(6) 0.7661(6) 0.096 Uiso 1 calc R .
C19 C 0.8257(5) 0.9772(5) 0.6730(5) 0.062(2) Uani 1 d . .
H19A H 0.8339(5) 0.9269(5) 0.7050(5) 0.074 Uiso 1 calc R .
C20 C 0.6414(4) 0.8460(4) 0.5390(4) 0.0361(13) Uani 1 d . .
C21 C 0.6047(5) 0.7694(4) 0.5043(4) 0.053(2) Uani 1 d . .
H21A H 0.6434(5) 0.7287(4) 0.4846(4) 0.064 Uiso 1 calc R .
C22 C 0.5109(5) 0.7530(5) 0.4986(6) 0.074(2) Uani 1 d . .
H22A H 0.4860(5) 0.7014(5) 0.4754(6) 0.089 Uiso 1 calc R .
C23 C 0.4554(6) 0.8136(6) 0.5276(6) 0.084(3) Uani 1 d . .
H23A H 0.3918(6) 0.8035(6) 0.5225(6) 0.101 Uiso 1 calc R .
C24 C 0.4906(5) 0.8889(5) 0.5639(6) 0.072(2) Uani 1 d . .
H24A H 0.4518(5) 0.9285(5) 0.5849(6) 0.086 Uiso 1 calc R .
C25 C 0.5840(5) 0.9053(4) 0.5690(5) 0.053(2) Uani 1 d . .
H25A H 0.6084(5) 0.9567(4) 0.5929(5) 0.064 Uiso 1 calc R .
C30 C 1.1021(18) 0.6008(13) 0.4558(16) 0.351(20) Uani 1 d . .
H30A H 1.1031(18) 0.5374(13) 0.4527(16) 0.421 Uiso 1 calc R .
Cl3 Cl 1.2107(4) 0.6322(3) 0.4468(4) 0.211(2) Uani 1 d . .
Cl4 Cl 1.0619(4) 0.6216(4) 0.5362(3) 0.218(2) Uani 1 d . .
Cl5 Cl 1.0178(3) 0.6358(4) 0.3639(3) 0.204(2) Uani 1 d . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Au1 Cl1 171.29(6) . . ?
P1 Au1 Au2 112.97(4) . 4_575 ?
Cl1 Au1 Au2 75.53(4) . 4_575 ?
N1 P1 C7 110.1(3) . . ?
N1 P1 C1 103.7(3) . . ?
C7 P1 C1 106.8(4) . . ?
N1 P1 Au1 114.1(2) . . ?
C7 P1 Au1 112.6(2) . . ?
C1 P1 Au1 108.9(2) . . ?
P2 Au2 Cl2 174.48(7) . . ?
P2 Au2 Au1 104.32(4) . 4_576 ?
Cl2 Au2 Au1 80.11(6) . 4_576 ?
C6 C1 C2 121.0(8) . . ?
C6 C1 P1 122.1(8) . . ?
C2 C1 P1 116.9(6) . . ?
C1 C2 C3 117.7(10) . . ?
C4 C3 C2 121.2(13) . . ?
C5 C4 C3 121.1(14) . . ?
C4 C5 C6 118.7(14) . . ?
C1 C6 C5 120.2(12) . . ?
C8 C7 C12 118.9(7) . . ?
C8 C7 P1 117.7(6) . . ?
C12 C7 P1 123.4(5) . . ?
C7 C8 C9 120.1(9) . . ?
C10 C9 C8 121.3(9) . . ?
C9 C10 C11 120.2(8) . . ?
C10 C11 C12 119.2(8) . . ?
C7 C12 C11 120.1(7) . . ?
C13 N1 C26 120.8(5) . . ?
C13 N1 P1 117.3(4) . . ?
C26 N1 P1 120.6(4) . . ?
N1 C26 C28 115.5(6) . . ?
O13 C13 N2 122.2(5) . . ?
O13 C13 N1 121.5(5) . . ?
N2 C13 N1 116.3(5) . . ?
C13 N2 C27 122.3(5) . . ?
C13 N2 P2 118.3(4) . . ?
C27 N2 P2 118.9(4) . . ?
N2 C27 C29 111.2(5) . . ?
N2 P2 C14 110.6(3) . . ?
N2 P2 C20 103.7(3) . . ?
C14 P2 C20 107.3(3) . . ?
N2 P2 Au2 110.1(2) . . ?
C14 P2 Au2 110.3(2) . . ?
C20 P2 Au2 114.7(2) . . ?
C15 C14 C19 119.1(6) . . ?
C15 C14 P2 123.7(5) . . ?
C19 C14 P2 117.2(5) . . ?
C14 C15 C16 120.2(7) . . ?
C17 C16 C15 119.4(8) . . ?
C16 C17 C18 120.9(7) . . ?
C17 C18 C19 120.3(8) . . ?
C14 C19 C18 119.9(8) . . ?
C25 C20 C21 119.5(6) . . ?
C25 C20 P2 122.3(5) . . ?
C21 C20 P2 118.3(5) . . ?
C20 C21 C22 120.4(7) . . ?
C23 C22 C21 118.8(8) . . ?
C24 C23 C22 121.7(7) . . ?
C23 C24 C25 119.2(7) . . ?
C24 C25 C20 120.3(7) . . ?
Cl4 C30 Cl3 119.5(22) . . ?
Cl4 C30 Cl5 109.0(10) . . ?
Cl3 C30 Cl5 111.5(7) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 P1 2.239(2) . ?
Au1 Cl1 2.316(2) . ?
Au1 Au2 3.1279(4) 4_575 ?
P1 N1 1.709(5) . ?
P1 C7 1.807(7) . ?
P1 C1 1.823(7) . ?
Au2 P2 2.243(2) . ?
Au2 Cl2 2.298(2) . ?
Au2 Au1 3.1280(4) 4_576 ?
C1 C6 1.376(11) . ?
C1 C2 1.394(11) . ?
C2 C3 1.423(13) . ?
C3 C4 1.34(2) . ?
C4 C5 1.40(2) . ?
C5 C6 1.40(2) . ?
C7 C8 1.381(10) . ?
C7 C12 1.374(10) . ?
C8 C9 1.368(12) . ?
C9 C10 1.355(14) . ?
C10 C11 1.359(12) . ?
C11 C12 1.415(11) . ?
N1 C13 1.415(7) . ?
N1 C26 1.475(7) . ?
C26 C28 1.480(10) . ?
C13 O13 1.213(6) . ?
C13 N2 1.389(7) . ?
N2 C27 1.492(7) . ?
N2 P2 1.706(5) . ?
C27 C29 1.504(9) . ?
P2 C14 1.827(6) . ?
P2 C20 1.828(6) . ?
C14 C15 1.376(9) . ?
C14 C19 1.397(9) . ?
C15 C16 1.397(10) . ?
C16 C17 1.384(12) . ?
C17 C18 1.345(12) . ?
C18 C19 1.394(10) . ?
C20 C25 1.374(8) . ?
C20 C21 1.383(8) . ?
C21 C22 1.378(9) . ?
C22 C23 1.364(11) . ?
C23 C24 1.366(11) . ?
C24 C25 1.373(10) . ?
C30 Cl4 1.53(2) . ?
C30 Cl3 1.68(2) . ?
C30 Cl5 1.86(3) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Cl1 Au1 P1 N1 -164.9(4) . . . . ?
Au2 Au1 P1 N1 2.3(2) 4_575 . . . ?
Cl1 Au1 P1 C7 68.8(5) . . . . ?
Au2 Au1 P1 C7 -124.0(3) 4_575 . . . ?
Cl1 Au1 P1 C1 -49.5(5) . . . . ?
Au2 Au1 P1 C1 117.7(3) 4_575 . . . ?
N1 P1 C1 C6 -116.3(6) . . . . ?
C7 P1 C1 C6 0.0(7) . . . . ?
Au1 P1 C1 C6 121.8(6) . . . . ?
N1 P1 C1 C2 64.0(6) . . . . ?
C7 P1 C1 C2 -179.7(5) . . . . ?
Au1 P1 C1 C2 -57.9(6) . . . . ?
C6 C1 C2 C3 0.6(11) . . . . ?
P1 C1 C2 C3 -179.8(6) . . . . ?
C1 C2 C3 C4 1.1(14) . . . . ?
C2 C3 C4 C5 -2.8(19) . . . . ?
C3 C4 C5 C6 2.8(21) . . . . ?
C2 C1 C6 C5 -0.5(13) . . . . ?
P1 C1 C6 C5 179.9(8) . . . . ?
C4 C5 C6 C1 -1.2(17) . . . . ?
N1 P1 C7 C8 -159.4(7) . . . . ?
C1 P1 C7 C8 88.6(8) . . . . ?
Au1 P1 C7 C8 -30.9(8) . . . . ?
N1 P1 C7 C12 18.7(7) . . . . ?
C1 P1 C7 C12 -93.3(7) . . . . ?
Au1 P1 C7 C12 147.2(6) . . . . ?
C12 C7 C8 C9 3.4(17) . . . . ?
P1 C7 C8 C9 -178.4(11) . . . . ?
C7 C8 C9 C10 -5.3(23) . . . . ?
C8 C9 C10 C11 4.1(22) . . . . ?
C9 C10 C11 C12 -1.3(17) . . . . ?
C8 C7 C12 C11 -0.6(13) . . . . ?
P1 C7 C12 C11 -178.7(6) . . . . ?
C10 C11 C12 C7 -0.5(13) . . . . ?
C7 P1 N1 C13 -80.9(5) . . . . ?
C1 P1 N1 C13 33.1(5) . . . . ?
Au1 P1 N1 C13 151.5(4) . . . . ?
C7 P1 N1 C26 86.3(5) . . . . ?
C1 P1 N1 C26 -159.7(5) . . . . ?
Au1 P1 N1 C26 -41.3(5) . . . . ?
C13 N1 C26 C28 96.3(7) . . . . ?
P1 N1 C26 C28 -70.5(7) . . . . ?
C26 N1 C13 O13 -133.2(6) . . . . ?
P1 N1 C13 O13 34.0(7) . . . . ?
C26 N1 C13 N2 46.6(8) . . . . ?
P1 N1 C13 N2 -146.2(4) . . . . ?
O13 C13 N2 C27 -147.3(6) . . . . ?
N1 C13 N2 C27 32.9(8) . . . . ?
O13 C13 N2 P2 24.8(7) . . . . ?
N1 C13 N2 P2 -155.1(4) . . . . ?
C13 N2 C27 C29 107.1(7) . . . . ?
P2 N2 C27 C29 -64.9(7) . . . . ?
C13 N2 P2 C14 -78.5(5) . . . . ?
C27 N2 P2 C14 93.8(5) . . . . ?
C13 N2 P2 C20 36.2(5) . . . . ?
C27 N2 P2 C20 -151.5(4) . . . . ?
C13 N2 P2 Au2 159.4(4) . . . . ?
C27 N2 P2 Au2 -28.3(5) . . . . ?
Cl2 Au2 P2 N2 128.6(7) . . . . ?
Au1 Au2 P2 N2 -88.5(2) 4_576 . . . ?
Cl2 Au2 P2 C14 6.3(8) . . . . ?
Au1 Au2 P2 C14 149.2(2) 4_576 . . . ?
Cl2 Au2 P2 C20 -114.9(7) . . . . ?
Au1 Au2 P2 C20 28.0(2) 4_576 . . . ?
N2 P2 C14 C15 31.7(7) . . . . ?
C20 P2 C14 C15 -80.8(6) . . . . ?
Au2 P2 C14 C15 153.6(5) . . . . ?
N2 P2 C14 C19 -148.7(5) . . . . ?
C20 P2 C14 C19 98.8(5) . . . . ?
Au2 P2 C14 C19 -26.8(6) . . . . ?
C19 C14 C15 C16 2.3(11) . . . . ?
P2 C14 C15 C16 -178.1(6) . . . . ?
C14 C15 C16 C17 -3.3(12) . . . . ?
C15 C16 C17 C18 4.2(12) . . . . ?
C16 C17 C18 C19 -4.1(13) . . . . ?
C15 C14 C19 C18 -2.1(11) . . . . ?
P2 C14 C19 C18 178.3(6) . . . . ?
C17 C18 C19 C14 3.0(12) . . . . ?
N2 P2 C20 C25 -119.9(5) . . . . ?
C14 P2 C20 C25 -2.8(6) . . . . ?
Au2 P2 C20 C25 120.0(5) . . . . ?
N2 P2 C20 C21 60.4(5) . . . . ?
C14 P2 C20 C21 177.4(5) . . . . ?
Au2 P2 C20 C21 -59.7(5) . . . . ?
C25 C20 C21 C22 1.0(10) . . . . ?
P2 C20 C21 C22 -179.3(6) . . . . ?
C20 C21 C22 C23 0.1(13) . . . . ?
C21 C22 C23 C24 -1.7(15) . . . . ?
C22 C23 C24 C25 2.1(14) . . . . ?
C23 C24 C25 C20 -0.9(12) . . . . ?
C21 C20 C25 C24 -0.6(10) . . . . ?
P2 C20 C25 C24 179.7(6) . . . . ?
