#------------------------------------------------------------------------------
#$Date: 2016-03-25 11:21:42 +0100 (vie 25 de mar de 2016) $
#$Revision: 179812 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/08/7010852.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7010852
loop_
_publ_author_name
'Clarke, Matthew L.'
'Slawin, Alexandra M. Z.'
'Wheatley, Matthew V.'
'Woollins, J. Derek'
_publ_section_title
;
 Synthesis and structure of novel rhodium complexes of
 multi-functionalised amine-phosphine ligands
;
_journal_issue                   23
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              3421
_journal_paper_doi               10.1039/b104523g
_journal_year                    2001
_chemical_formula_analytical     'C28 H32 Cl4 N2 P Rh'
_chemical_formula_moiety         'C27 H30 Cl2 N2 P Rh.C H2 Cl2'
_chemical_formula_structural     'C28 H32 Cl4 N2 P Rh'
_chemical_formula_sum            'C28 H32 Cl4 N2 P Rh'
_chemical_formula_weight         672.24
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL
_cell_angle_alpha                97.6060(10)
_cell_angle_beta                 94.2100(10)
_cell_angle_gamma                112.4040(10)
_cell_formula_units_Z            2
_cell_length_a                   8.5863(4)
_cell_length_b                   10.3041(5)
_cell_length_c                   18.7795(9)
_cell_measurement_reflns_used    53
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      168
_cell_measurement_theta_min      12
_cell_volume                     1508.60(13)
_computing_cell_refinement       SMART/SAINT
_computing_data_collection       SMART
_computing_data_reduction        SAINT
_computing_molecular_graphics    SHELXTL
_computing_publication_material  SHELXTL
_computing_structure_refinement  'SHELXL-93 (Sheldrick, 1993)'
_computing_structure_solution    'SHELXS-86 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measurement_device       SMART
_diffrn_measurement_method       CCD
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0329
_diffrn_reflns_av_sigmaI/netI    0.0531
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            9484
_diffrn_reflns_theta_max         23.44
_diffrn_reflns_theta_min         2.17
_diffrn_standards_decay_%        -
_diffrn_standards_interval_count -
_diffrn_standards_interval_time  -
_diffrn_standards_number         -
_exptl_absorpt_coefficient_mu    0.993
_exptl_absorpt_correction_T_max  1.000000
_exptl_absorpt_correction_T_min  0.847297
_exptl_absorpt_correction_type   sadabs
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.480
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    -
_exptl_crystal_description       prism
_exptl_crystal_F_000             684
_exptl_crystal_size_max          .15
_exptl_crystal_size_mid          .1
_exptl_crystal_size_min          .1
_refine_diff_density_max         0.776
_refine_diff_density_min         -0.491
_refine_diff_density_rms         0.082
_refine_ls_extinction_coef       0.0000(8)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_all   0.983
_refine_ls_goodness_of_fit_obs   1.034
_refine_ls_hydrogen_treatment    riding
_refine_ls_matrix_type           full
_refine_ls_number_parameters     330
_refine_ls_number_reflns         4326
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.083
_refine_ls_restrained_S_obs      1.034
_refine_ls_R_factor_all          0.0619
_refine_ls_R_factor_obs          0.0447
_refine_ls_shift/esd_max         -0.438
_refine_ls_shift/esd_mean        0.003
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0722P)²+0.7036P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         0.1288
_refine_ls_wR_factor_obs         0.1102
_reflns_number_observed          3510
_reflns_number_total             4353
_reflns_observed_criterion       >2sigma(I)
_cod_data_source_file            b104523g.txt
_cod_data_source_block           8
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value '-' was changed to '?' - the
value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 

The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'calc
w=1/[\s^2^(Fo^2^)+(0.0722P)^2^+0.7036P] where P=(Fo^2^+2Fc^2^)/3' was
changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to
'w=1/[\s^2^(Fo^2^)+(0.0722P)^2^+0.7036P] where P=(Fo^2^+2Fc^2^)/3'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_cell_volume        1508.60(12)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7010852
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_thermal_displace_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_group
Rh1 Rh 0.29279(5) 0.12456(4) 0.27683(2) 0.0361(2) Uani 1 d . .
Cl1 Cl 0.0566(2) 0.1202(2) 0.33775(8) 0.0568(4) Uani 1 d . .
P1 P 0.2536(2) -0.10273(13) 0.29011(7) 0.0346(3) Uani 1 d . .
C1 C 0.1481(6) -0.1799(5) 0.3643(3) 0.0398(12) Uani 1 d . .
C2 C 0.0606(7) -0.3252(6) 0.3566(3) 0.0541(15) Uani 1 d . .
H2A H 0.0547(7) -0.3843(6) 0.3136(3) 0.065 Uiso 1 calc R .
C3 C -0.0186(9) -0.3829(7) 0.4135(4) 0.070(2) Uani 1 d . .
H3A H -0.0806(9) -0.4808(7) 0.4077(4) 0.084 Uiso 1 calc R .
C4 C -0.0074(9) -0.2995(8) 0.4773(4) 0.072(2) Uani 1 d . .
H4A H -0.0593(9) -0.3404(8) 0.5151(4) 0.087 Uiso 1 calc R .
C5 C 0.0803(9) -0.1547(7) 0.4861(3) 0.062(2) Uani 1 d . .
H5A H 0.0868(9) -0.0971(7) 0.5297(3) 0.075 Uiso 1 calc R .
C6 C 0.1603(8) -0.0938(6) 0.4290(3) 0.0526(14) Uani 1 d . .
H6A H 0.2212(8) 0.0042(6) 0.4348(3) 0.063 Uiso 1 calc R .
C7 C 0.4267(6) -0.1616(5) 0.2902(3) 0.0447(13) Uani 1 d . .
C8 C 0.4755(8) -0.2044(7) 0.2253(4) 0.060(2) Uani 1 d . .
H8A H 0.4168(8) -0.2054(7) 0.1815(4) 0.073 Uiso 1 calc R .
C9 C 0.6112(10) -0.2456(9) 0.2257(6) 0.094(3) Uani 1 d . .
H9A H 0.6441(10) -0.2726(9) 0.1820(6) 0.112 Uiso 1 calc R .
C10 C 0.6961(10) -0.2471(10) 0.2884(8) 0.109(4) Uani 1 d . .
H10A H 0.7850(10) -0.2775(10) 0.2875(8) 0.131 Uiso 1 calc R .
C11 C 0.6529(10) -0.2040(8) 0.3542(6) 0.091(3) Uani 1 d . .
H11A H 0.7143(10) -0.2025(8) 0.3974(6) 0.109 Uiso 1 calc R .
C12 C 0.5168(8) -0.1632(6) 0.3548(4) 0.064(2) Uani 1 d . .
H12A H 0.4850(8) -0.1365(6) 0.3988(4) 0.076 Uiso 1 calc R .
N1 N 0.1264(5) -0.1958(4) 0.2129(2) 0.0412(10) Uani 1 d D .
H1N H 0.0900(65) -0.2985(12) 0.1965(26) 0.051(15) Uiso 1 d D .
C13 C 0.0549(6) -0.1305(6) 0.1696(3) 0.0399(12) Uani 1 d . .
N14 N 0.1064(5) 0.0111(5) 0.1871(2) 0.0427(10) Uani 1 d . .
C15 C 0.0285(9) 0.0767(8) 0.1491(3) 0.065(2) Uani 1 d . .
H15A H 0.0580(9) 0.1738(8) 0.1636(3) 0.078 Uiso 1 calc R .
C16 C -0.0914(9) 0.0071(10) 0.0903(4) 0.080(2) Uani 1 d . .
H16A H -0.1410(9) 0.0557(10) 0.0645(4) 0.095 Uiso 1 calc R .
C17 C -0.1382(8) -0.1398(9) 0.0699(3) 0.067(2) Uani 1 d . .
H17A H -0.2172(8) -0.1897(9) 0.0291(3) 0.081 Uiso 1 calc R .
C18 C -0.0682(7) -0.2089(7) 0.1097(3) 0.057(2) Uani 1 d . .
H18A H -0.1011(7) -0.3070(7) 0.0976(3) 0.068 Uiso 1 calc R .
C21 C 0.4009(8) 0.3602(6) 0.2890(4) 0.063(2) Uani 1 d . .
C22 C 0.4768(8) 0.3129(6) 0.3477(3) 0.059(2) Uani 1 d . .
C23 C 0.5641(7) 0.2356(6) 0.3165(4) 0.061(2) Uani 1 d . .
C24 C 0.5378(8) 0.2234(6) 0.2412(4) 0.069(2) Uani 1 d . .
C25 C 0.4445(9) 0.3075(7) 0.2248(4) 0.072(2) Uani 1 d . .
C26 C 0.2999(11) 0.4485(8) 0.3000(6) 0.119(4) Uani 1 d . .
H26A H 0.2910(11) 0.4676(8) 0.3507(6) 0.179 Uiso 1 calc R .
H26B H 0.1882(11) 0.3982(8) 0.2733(6) 0.179 Uiso 1 calc R .
H26C H 0.3550(11) 0.5369(8) 0.2832(6) 0.179 Uiso 1 calc R .
C27 C 0.4721(13) 0.3543(10) 0.4270(4) 0.118(4) Uani 1 d . .
H27A H 0.4016(13) 0.4072(10) 0.4328(4) 0.177 Uiso 1 calc R .
H27B H 0.5853(13) 0.4122(10) 0.4506(4) 0.177 Uiso 1 calc R .
H27C H 0.4265(13) 0.2700(10) 0.4482(4) 0.177 Uiso 1 calc R .
C28 C 0.6802(10) 0.1860(8) 0.3595(7) 0.139(5) Uani 1 d . .
H28A H 0.7264(10) 0.1348(8) 0.3269(7) 0.208 Uiso 1 calc R .
H28B H 0.6168(10) 0.1247(8) 0.3907(7) 0.208 Uiso 1 calc R .
H28C H 0.7712(10) 0.2671(8) 0.3883(7) 0.208 Uiso 1 calc R .
C29 C 0.6240(13) 0.1585(10) 0.1881(6) 0.156(5) Uani 1 d . .
H29A H 0.5849(13) 0.1627(10) 0.1395(6) 0.233 Uiso 1 calc R .
H29B H 0.5967(13) 0.0610(10) 0.1929(6) 0.233 Uiso 1 calc R .
H29C H 0.7449(13) 0.2109(10) 0.1981(6) 0.233 Uiso 1 calc R .
C30 C 0.4026(15) 0.3374(12) 0.1517(5) 0.152(5) Uani 1 d . .
H30A H 0.4462(15) 0.2895(12) 0.1161(5) 0.228 Uiso 1 calc R .
H30B H 0.4533(15) 0.4382(12) 0.1521(5) 0.228 Uiso 1 calc R .
H30C H 0.2815(15) 0.3037(12) 0.1400(5) 0.228 Uiso 1 calc R .
Cl2 Cl -0.0090(3) -0.5223(2) 0.15961(10) 0.0878(6) Uani 1 d . .
C40 C 0.2291(9) -0.3397(8) 0.0174(4) 0.078(2) Uani 1 d . .
H40A H 0.1572(9) -0.3622(8) 0.0553(4) 0.093 Uiso 1 calc R .
H40B H 0.1561(9) -0.3685(8) -0.0287(4) 0.093 Uiso 1 calc R .
Cl3 Cl 0.3489(3) -0.1556(2) 0.03140(12) 0.0976(7) Uani 1 d . .
Cl4 Cl 0.3593(4) -0.4349(3) 0.01744(14) 0.1155(8) Uani 1 d . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N14 Rh1 C24 110.2(2) . . ?
N14 Rh1 C22 155.8(2) . . ?
C24 Rh1 C22 63.3(2) . . ?
N14 Rh1 C23 146.6(2) . . ?
C24 Rh1 C23 37.5(3) . . ?
C22 Rh1 C23 37.2(2) . . ?
N14 Rh1 C21 116.7(2) . . ?
C24 Rh1 C21 63.2(2) . . ?
C22 Rh1 C21 39.1(2) . . ?
C23 Rh1 C21 63.2(2) . . ?
N14 Rh1 C25 97.3(2) . . ?
C24 Rh1 C25 38.0(3) . . ?
C22 Rh1 C25 62.8(2) . . ?
C23 Rh1 C25 62.2(3) . . ?
C21 Rh1 C25 36.4(3) . . ?
N14 Rh1 P1 80.65(12) . . ?
C24 Rh1 P1 108.3(2) . . ?
C22 Rh1 P1 123.4(2) . . ?
C23 Rh1 P1 100.2(2) . . ?
C21 Rh1 P1 162.1(2) . . ?
C25 Rh1 P1 143.4(2) . . ?
N14 Rh1 Cl1 84.43(12) . . ?
C24 Rh1 Cl1 155.3(2) . . ?
C22 Rh1 Cl1 95.1(2) . . ?
C23 Rh1 Cl1 128.5(2) . . ?
C21 Rh1 Cl1 92.7(2) . . ?
C25 Rh1 Cl1 123.0(2) . . ?
P1 Rh1 Cl1 93.37(5) . . ?
N1 P1 C7 103.6(2) . . ?
N1 P1 C1 106.9(2) . . ?
C7 P1 C1 101.6(2) . . ?
N1 P1 Rh1 100.8(2) . . ?
C7 P1 Rh1 121.6(2) . . ?
C1 P1 Rh1 120.5(2) . . ?
C6 C1 C2 119.7(5) . . ?
C6 C1 P1 120.2(4) . . ?
C2 C1 P1 120.0(4) . . ?
C1 C2 C3 119.5(6) . . ?
C4 C3 C2 121.2(6) . . ?
C5 C4 C3 120.1(6) . . ?
C4 C5 C6 119.6(6) . . ?
C1 C6 C5 119.8(6) . . ?
C8 C7 C12 118.2(5) . . ?
C8 C7 P1 120.4(4) . . ?
C12 C7 P1 121.5(5) . . ?
C7 C8 C9 120.1(7) . . ?
C10 C9 C8 120.9(8) . . ?
C9 C10 C11 120.8(8) . . ?
C10 C11 C12 119.0(8) . . ?
C11 C12 C7 120.9(7) . . ?
C13 N1 P1 120.1(4) . . ?
N14 C13 N1 117.3(4) . . ?
N14 C13 C18 121.3(5) . . ?
N1 C13 C18 121.4(5) . . ?
C13 N14 C15 118.6(5) . . ?
C13 N14 Rh1 120.0(3) . . ?
C15 N14 Rh1 121.3(4) . . ?
N14 C15 C16 122.9(7) . . ?
C15 C16 C17 118.2(6) . . ?
C18 C17 C16 119.8(6) . . ?
C17 C18 C13 119.0(6) . . ?
C25 C21 C22 106.7(6) . . ?
C25 C21 C26 129.1(8) . . ?
C22 C21 C26 124.2(7) . . ?
C25 C21 Rh1 72.6(3) . . ?
C22 C21 Rh1 68.7(3) . . ?
C26 C21 Rh1 124.0(5) . . ?
C23 C22 C21 107.5(6) . . ?
C23 C22 C27 127.4(7) . . ?
C21 C22 C27 124.9(7) . . ?
C23 C22 Rh1 72.1(3) . . ?
C21 C22 Rh1 72.2(3) . . ?
C27 C22 Rh1 125.5(5) . . ?
C22 C23 C24 109.1(6) . . ?
C22 C23 C28 123.9(8) . . ?
C24 C23 C28 126.8(8) . . ?
C22 C23 Rh1 70.7(3) . . ?
C24 C23 Rh1 70.2(4) . . ?
C28 C23 Rh1 129.3(4) . . ?
C23 C24 C25 107.8(6) . . ?
C23 C24 C29 125.3(9) . . ?
C25 C24 C29 125.7(9) . . ?
C23 C24 Rh1 72.3(3) . . ?
C25 C24 Rh1 74.0(4) . . ?
C29 C24 Rh1 128.9(5) . . ?
C21 C25 C24 108.6(6) . . ?
C21 C25 C30 124.9(9) . . ?
C24 C25 C30 126.5(9) . . ?
C21 C25 Rh1 71.0(3) . . ?
C24 C25 Rh1 68.1(3) . . ?
C30 C25 Rh1 127.8(5) . . ?
Cl4 C40 Cl3 111.5(4) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 N14 2.104(4) . ?
Rh1 C24 2.160(6) . ?
Rh1 C22 2.169(5) . ?
Rh1 C23 2.186(6) . ?
Rh1 C21 2.217(6) . ?
Rh1 C25 2.238(6) . ?
Rh1 P1 2.2861(13) . ?
Rh1 Cl1 2.3889(14) . ?
P1 N1 1.679(4) . ?
P1 C7 1.807(5) . ?
P1 C1 1.822(5) . ?
C1 C6 1.378(7) . ?
C1 C2 1.377(8) . ?
C2 C3 1.387(8) . ?
C3 C4 1.353(10) . ?
C4 C5 1.372(10) . ?
C5 C6 1.406(8) . ?
C7 C8 1.389(8) . ?
C7 C12 1.394(8) . ?
C8 C9 1.384(10) . ?
C9 C10 1.343(13) . ?
C10 C11 1.381(13) . ?
C11 C12 1.385(10) . ?
N1 C13 1.369(6) . ?
C13 N14 1.339(7) . ?
C13 C18 1.404(8) . ?
N14 C15 1.347(7) . ?
C15 C16 1.361(9) . ?
C16 C17 1.400(10) . ?
C17 C18 1.352(9) . ?
C21 C25 1.392(10) . ?
C21 C22 1.469(9) . ?
C21 C26 1.484(9) . ?
C22 C23 1.391(9) . ?
C22 C27 1.501(10) . ?
C23 C24 1.397(10) . ?
C23 C28 1.512(9) . ?
C24 C25 1.432(10) . ?
C24 C29 1.516(10) . ?
C25 C30 1.493(10) . ?
C40 Cl4 1.746(8) . ?
C40 Cl3 1.751(8) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N14 Rh1 P1 N1 7.8(2) . . . . ?
C24 Rh1 P1 N1 -100.5(3) . . . . ?
C22 Rh1 P1 N1 -170.1(2) . . . . ?
C23 Rh1 P1 N1 -138.4(3) . . . . ?
C21 Rh1 P1 N1 -158.9(6) . . . . ?
C25 Rh1 P1 N1 -81.8(3) . . . . ?
Cl1 Rh1 P1 N1 91.5(2) . . . . ?
N14 Rh1 P1 C7 121.2(3) . . . . ?
C24 Rh1 P1 C7 12.9(3) . . . . ?
C22 Rh1 P1 C7 -56.6(3) . . . . ?
C23 Rh1 P1 C7 -24.9(3) . . . . ?
C21 Rh1 P1 C7 -45.4(6) . . . . ?
C25 Rh1 P1 C7 31.6(4) . . . . ?
Cl1 Rh1 P1 C7 -155.0(2) . . . . ?
N14 Rh1 P1 C1 -109.4(2) . . . . ?
C24 Rh1 P1 C1 142.3(3) . . . . ?
C22 Rh1 P1 C1 72.8(3) . . . . ?
C23 Rh1 P1 C1 104.5(3) . . . . ?
C21 Rh1 P1 C1 84.0(6) . . . . ?
C25 Rh1 P1 C1 161.0(4) . . . . ?
Cl1 Rh1 P1 C1 -25.6(2) . . . . ?
N1 P1 C1 C6 -144.0(4) . . . . ?
C7 P1 C1 C6 107.7(5) . . . . ?
Rh1 P1 C1 C6 -30.0(5) . . . . ?
N1 P1 C1 C2 38.2(5) . . . . ?
C7 P1 C1 C2 -70.1(5) . . . . ?
Rh1 P1 C1 C2 152.2(4) . . . . ?
C6 C1 C2 C3 1.9(9) . . . . ?
P1 C1 C2 C3 179.7(5) . . . . ?
C1 C2 C3 C4 -2.0(10) . . . . ?
C2 C3 C4 C5 1.5(11) . . . . ?
C3 C4 C5 C6 -0.9(10) . . . . ?
C2 C1 C6 C5 -1.4(8) . . . . ?
P1 C1 C6 C5 -179.2(4) . . . . ?
C4 C5 C6 C1 0.8(9) . . . . ?
N1 P1 C7 C8 30.3(5) . . . . ?
C1 P1 C7 C8 141.1(4) . . . . ?
Rh1 P1 C7 C8 -81.7(5) . . . . ?
N1 P1 C7 C12 -150.8(4) . . . . ?
C1 P1 C7 C12 -40.0(5) . . . . ?
Rh1 P1 C7 C12 97.2(4) . . . . ?
C12 C7 C8 C9 -0.7(9) . . . . ?
P1 C7 C8 C9 178.2(5) . . . . ?
C7 C8 C9 C10 1.0(11) . . . . ?
C8 C9 C10 C11 -1.7(13) . . . . ?
C9 C10 C11 C12 2.0(13) . . . . ?
C10 C11 C12 C7 -1.7(11) . . . . ?
C8 C7 C12 C11 1.1(9) . . . . ?
P1 C7 C12 C11 -177.8(5) . . . . ?
C7 P1 N1 C13 -137.3(4) . . . . ?
C1 P1 N1 C13 115.9(4) . . . . ?
Rh1 P1 N1 C13 -10.9(4) . . . . ?
P1 N1 C13 N14 7.6(6) . . . . ?
P1 N1 C13 C18 -171.9(4) . . . . ?
N1 C13 N14 C15 -174.7(5) . . . . ?
C18 C13 N14 C15 4.8(8) . . . . ?
N1 C13 N14 Rh1 1.0(6) . . . . ?
C18 C13 N14 Rh1 -179.5(4) . . . . ?
C24 Rh1 N14 C13 100.1(4) . . . . ?
C22 Rh1 N14 C13 169.5(5) . . . . ?
C23 Rh1 N14 C13 88.3(5) . . . . ?
C21 Rh1 N14 C13 169.4(4) . . . . ?
C25 Rh1 N14 C13 137.0(4) . . . . ?
P1 Rh1 N14 C13 -6.0(3) . . . . ?
Cl1 Rh1 N14 C13 -100.4(4) . . . . ?
C24 Rh1 N14 C15 -84.3(5) . . . . ?
C22 Rh1 N14 C15 -14.9(7) . . . . ?
C23 Rh1 N14 C15 -96.1(5) . . . . ?
C21 Rh1 N14 C15 -15.1(5) . . . . ?
C25 Rh1 N14 C15 -47.5(5) . . . . ?
P1 Rh1 N14 C15 169.5(4) . . . . ?
Cl1 Rh1 N14 C15 75.2(4) . . . . ?
C13 N14 C15 C16 -5.0(9) . . . . ?
Rh1 N14 C15 C16 179.4(5) . . . . ?
N14 C15 C16 C17 1.6(11) . . . . ?
C15 C16 C17 C18 2.1(10) . . . . ?
C16 C17 C18 C13 -2.2(10) . . . . ?
N14 C13 C18 C17 -1.3(8) . . . . ?
N1 C13 C18 C17 178.2(5) . . . . ?
N14 Rh1 C21 C25 -63.6(5) . . . . ?
C24 Rh1 C21 C25 36.6(4) . . . . ?
C22 Rh1 C21 C25 116.4(5) . . . . ?
C23 Rh1 C21 C25 78.8(5) . . . . ?
C25 Rh1 C21 C25 0.000(2) . . . . ?
P1 Rh1 C21 C25 101.5(7) . . . . ?
Cl1 Rh1 C21 C25 -148.8(4) . . . . ?
N14 Rh1 C21 C22 179.9(3) . . . . ?
C24 Rh1 C21 C22 -79.8(4) . . . . ?
C22 Rh1 C21 C22 0.000(2) . . . . ?
C23 Rh1 C21 C22 -37.6(4) . . . . ?
C25 Rh1 C21 C22 -116.4(5) . . . . ?
P1 Rh1 C21 C22 -14.9(8) . . . . ?
Cl1 Rh1 C21 C22 94.8(3) . . . . ?
N14 Rh1 C21 C26 62.2(8) . . . . ?
C24 Rh1 C21 C26 162.4(9) . . . . ?
C22 Rh1 C21 C26 -117.7(9) . . . . ?
C23 Rh1 C21 C26 -155.4(8) . . . . ?
C25 Rh1 C21 C26 125.8(9) . . . . ?
P1 Rh1 C21 C26 -132.6(7) . . . . ?
Cl1 Rh1 C21 C26 -22.9(7) . . . . ?
C25 C21 C22 C23 0.7(6) . . . . ?
C26 C21 C22 C23 -178.7(6) . . . . ?
Rh1 C21 C22 C23 63.9(4) . . . . ?
C25 C21 C22 C27 175.5(6) . . . . ?
C26 C21 C22 C27 -4.0(10) . . . . ?
Rh1 C21 C22 C27 -121.4(6) . . . . ?
C25 C21 C22 Rh1 -63.1(4) . . . . ?
C26 C21 C22 Rh1 117.4(6) . . . . ?
Rh1 C21 C22 Rh1 0.0 . . . . ?
N14 Rh1 C22 C23 -116.0(6) . . . . ?
C24 Rh1 C22 C23 -36.3(4) . . . . ?
C23 Rh1 C22 C23 0.000(1) . . . . ?
C21 Rh1 C22 C23 -115.8(5) . . . . ?
C25 Rh1 C22 C23 -79.1(4) . . . . ?
P1 Rh1 C22 C23 58.7(4) . . . . ?
Cl1 Rh1 C22 C23 156.2(4) . . . . ?
N14 Rh1 C22 C21 -0.2(7) . . . . ?
C24 Rh1 C22 C21 79.5(4) . . . . ?
C23 Rh1 C22 C21 115.8(5) . . . . ?
C21 Rh1 C22 C21 0.000(2) . . . . ?
C25 Rh1 C22 C21 36.7(4) . . . . ?
P1 Rh1 C22 C21 174.6(3) . . . . ?
Cl1 Rh1 C22 C21 -88.0(3) . . . . ?
N14 Rh1 C22 C27 120.4(8) . . . . ?
C24 Rh1 C22 C27 -159.9(8) . . . . ?
C23 Rh1 C22 C27 -123.6(9) . . . . ?
C21 Rh1 C22 C27 120.5(8) . . . . ?
C25 Rh1 C22 C27 157.2(8) . . . . ?
P1 Rh1 C22 C27 -64.9(8) . . . . ?
Cl1 Rh1 C22 C27 32.6(7) . . . . ?
C21 C22 C23 C24 -4.0(6) . . . . ?
C27 C22 C23 C24 -178.6(6) . . . . ?
Rh1 C22 C23 C24 60.0(4) . . . . ?
C21 C22 C23 C28 171.1(6) . . . . ?
C27 C22 C23 C28 -3.5(10) . . . . ?
Rh1 C22 C23 C28 -125.0(6) . . . . ?
C21 C22 C23 Rh1 -64.0(4) . . . . ?
C27 C22 C23 Rh1 121.4(7) . . . . ?
Rh1 C22 C23 Rh1 0.0 . . . . ?
N14 Rh1 C23 C22 138.0(4) . . . . ?
C24 Rh1 C23 C22 119.6(5) . . . . ?
C22 Rh1 C23 C22 0.000(1) . . . . ?
C21 Rh1 C23 C22 39.5(4) . . . . ?
C25 Rh1 C23 C22 80.7(4) . . . . ?
P1 Rh1 C23 C22 -133.6(4) . . . . ?
Cl1 Rh1 C23 C22 -30.9(5) . . . . ?
N14 Rh1 C23 C24 18.4(6) . . . . ?
C24 Rh1 C23 C24 0.000(1) . . . . ?
C22 Rh1 C23 C24 -119.6(5) . . . . ?
C21 Rh1 C23 C24 -80.1(4) . . . . ?
C25 Rh1 C23 C24 -39.0(4) . . . . ?
P1 Rh1 C23 C24 106.8(4) . . . . ?
Cl1 Rh1 C23 C24 -150.5(3) . . . . ?
N14 Rh1 C23 C28 -103.4(9) . . . . ?
C24 Rh1 C23 C28 -121.8(10) . . . . ?
C22 Rh1 C23 C28 118.5(10) . . . . ?
C21 Rh1 C23 C28 158.1(9) . . . . ?
C25 Rh1 C23 C28 -160.8(9) . . . . ?
P1 Rh1 C23 C28 -15.0(9) . . . . ?
Cl1 Rh1 C23 C28 87.6(8) . . . . ?
C22 C23 C24 C25 5.7(7) . . . . ?
C28 C23 C24 C25 -169.2(6) . . . . ?
Rh1 C23 C24 C25 66.0(4) . . . . ?
C22 C23 C24 C29 174.1(6) . . . . ?
C28 C23 C24 C29 -0.7(10) . . . . ?
Rh1 C23 C24 C29 -125.6(7) . . . . ?
C22 C23 C24 Rh1 -60.3(4) . . . . ?
C28 C23 C24 Rh1 124.9(6) . . . . ?
Rh1 C23 C24 Rh1 0.0 . . . . ?
N14 Rh1 C24 C23 -169.3(3) . . . . ?
C22 Rh1 C24 C23 36.1(4) . . . . ?
C23 Rh1 C24 C23 0.000(1) . . . . ?
C21 Rh1 C24 C23 80.1(4) . . . . ?
C25 Rh1 C24 C23 115.2(5) . . . . ?
P1 Rh1 C24 C23 -82.8(3) . . . . ?
Cl1 Rh1 C24 C23 67.2(7) . . . . ?
N14 Rh1 C24 C25 75.4(4) . . . . ?
C22 Rh1 C24 C25 -79.2(4) . . . . ?
C23 Rh1 C24 C25 -115.2(5) . . . . ?
C21 Rh1 C24 C25 -35.1(4) . . . . ?
C25 Rh1 C24 C25 0.000(1) . . . . ?
P1 Rh1 C24 C25 161.9(4) . . . . ?
Cl1 Rh1 C24 C25 -48.0(8) . . . . ?
N14 Rh1 C24 C29 -47.8(10) . . . . ?
C22 Rh1 C24 C29 157.6(10) . . . . ?
C23 Rh1 C24 C29 121.5(11) . . . . ?
C21 Rh1 C24 C29 -158.4(10) . . . . ?
C25 Rh1 C24 C29 -123.3(11) . . . . ?
P1 Rh1 C24 C29 38.7(10) . . . . ?
Cl1 Rh1 C24 C29 -171.3(7) . . . . ?
C22 C21 C25 C24 2.7(7) . . . . ?
C26 C21 C25 C24 -177.8(6) . . . . ?
Rh1 C21 C25 C24 -57.8(4) . . . . ?
C22 C21 C25 C30 -176.1(7) . . . . ?
C26 C21 C25 C30 3.3(11) . . . . ?
Rh1 C21 C25 C30 123.3(7) . . . . ?
C22 C21 C25 Rh1 60.5(4) . . . . ?
C26 C21 C25 Rh1 -120.0(7) . . . . ?
Rh1 C21 C25 Rh1 0.0 . . . . ?
C23 C24 C25 C21 -5.2(7) . . . . ?
C29 C24 C25 C21 -173.6(6) . . . . ?
Rh1 C24 C25 C21 59.6(4) . . . . ?
C23 C24 C25 C30 173.6(7) . . . . ?
C29 C24 C25 C30 5.2(11) . . . . ?
Rh1 C24 C25 C30 -121.5(7) . . . . ?
C23 C24 C25 Rh1 -64.8(4) . . . . ?
C29 C24 C25 Rh1 126.8(7) . . . . ?
Rh1 C24 C25 Rh1 0.0 . . . . ?
N14 Rh1 C25 C21 126.2(4) . . . . ?
C24 Rh1 C25 C21 -120.1(6) . . . . ?
C22 Rh1 C25 C21 -39.5(4) . . . . ?
C23 Rh1 C25 C21 -81.7(4) . . . . ?
C21 Rh1 C25 C21 0.000(2) . . . . ?
P1 Rh1 C25 C21 -149.7(3) . . . . ?
Cl1 Rh1 C25 C21 38.1(5) . . . . ?
N14 Rh1 C25 C24 -113.7(4) . . . . ?
C24 Rh1 C25 C24 0.000(2) . . . . ?
C22 Rh1 C25 C24 80.7(4) . . . . ?
C23 Rh1 C25 C24 38.5(4) . . . . ?
C21 Rh1 C25 C24 120.1(6) . . . . ?
P1 Rh1 C25 C24 -29.6(6) . . . . ?
Cl1 Rh1 C25 C24 158.3(4) . . . . ?
N14 Rh1 C25 C30 6.3(9) . . . . ?
C24 Rh1 C25 C30 119.9(11) . . . . ?
C22 Rh1 C25 C30 -159.4(10) . . . . ?
C23 Rh1 C25 C30 158.4(10) . . . . ?
C21 Rh1 C25 C30 -119.9(11) . . . . ?
P1 Rh1 C25 C30 90.3(9) . . . . ?
Cl1 Rh1 C25 C30 -81.8(9) . . . . ?
