#------------------------------------------------------------------------------
#$Date: 2022-05-07 01:39:13 +0200 (Sat 07 de May de 2022) $
#$Revision: 275158 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/21/7012144.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7012144
loop_
_publ_author_name
'Watanabe, Masanobu'
'Sato, Masaru'
'Kai, Masahiro'
_publ_section_title
;
 Synthesis of the first non-carbonyl cisoid fulvalene complexes with an
 Ru--Ru bond bridged by thiolate ligands
;
_journal_issue                   4
_journal_name_full               'Dalton Transactions'
_journal_page_first              651
_journal_paper_doi               10.1039/b207928n
_journal_year                    2003
_chemical_formula_moiety         'C34 H24 Cl4 Ru2 S4 '
_chemical_formula_sum            'C34 H24 Cl4 Ru2 S4'
_chemical_formula_weight         904.75
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_primary     vecmap
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                106.481(4)
_cell_angle_beta                 95.341(6)
_cell_angle_gamma                99.585(4)
_cell_formula_units_Z            2
_cell_length_a                   7.1130(4)
_cell_length_b                   13.2430(10)
_cell_length_c                   19.248(2)
_cell_measurement_temperature    298
_cell_volume                     1695.4(2)
_computing_data_collection       KappaCCD
_computing_data_reduction        'Denzo and Scalepak (Otwinowski & Minor, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'DIRDIF (Buerskens et al., 1992)'
_diffrn_measured_fraction_theta_full 0.750
_diffrn_measured_fraction_theta_max 0.750
_diffrn_measurement_device       KappaCCD
_diffrn_orient_matrix_type       X=UH
_diffrn_orient_matrix_UB_11      0.05419
_diffrn_orient_matrix_UB_12      0.05688
_diffrn_orient_matrix_UB_13      0.04821
_diffrn_orient_matrix_UB_21      -0.13368
_diffrn_orient_matrix_UB_22      0.00842
_diffrn_orient_matrix_UB_23      0.00903
_diffrn_orient_matrix_UB_31      -0.00775
_diffrn_orient_matrix_UB_32      -0.05714
_diffrn_orient_matrix_UB_33      0.02527
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength_id  all
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            8318
_diffrn_reflns_theta_full        30.33
_diffrn_reflns_theta_max         30.33
_exptl_absorpt_coefficient_mu    1.478
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            Red
_exptl_crystal_density_diffrn    1.772
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Needle
_exptl_crystal_size_max          0.34
_exptl_crystal_size_mid          0.06
_exptl_crystal_size_min          0.04
_refine_diff_density_max         0.583
_refine_diff_density_min         -0.903
_refine_diff_density_rms         0.107
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.199
_refine_ls_hydrogen_treatment    refxyz
_refine_ls_matrix_type           full
_refine_ls_number_parameters     397
_refine_ls_number_reflns         7631
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.199
_refine_ls_R_factor_all          0.0615
_refine_ls_R_factor_gt           0.0570
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0177P)²+7.7758P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1158
_refine_ls_wR_factor_ref         0.1181
_reflns_number_gt                7176
_reflns_number_total             7631
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b207928n.txt
_cod_data_source_block           compound_4c
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1555 2011-01-17 13:19:09Z saulius 
;
_cod_original_cell_volume        1695.4(3)
_cod_original_sg_symbol_H-M      'P -1          '
_cod_original_formula_sum        'C34 H24 Cl4 Ru2 S4 '
_cod_database_code               7012144
loop_
_symmetry_equiv_pos_as_xyz
+X,+Y,+Z
-X,-Y,-Z
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ru1 Ru 0.82429(6) 0.33888(3) 0.24899(2) 0.04035(11) Uani 1 1 d . . .
Ru2 Ru 0.74492(6) 0.14243(3) 0.15264(2) 0.03721(11) Uani 1 1 d . . .
Cl1 Cl 0.8411(6) 0.2542(2) 0.61244(14) 0.1416(13) Uani 1 1 d . . .
Cl2 Cl 0.1555(4) 0.0383(3) 0.45175(17) 0.1267(12) Uani 1 1 d . . .
Cl3 Cl 0.1614(4) 0.4173(2) -0.06957(14) 0.1072(9) Uani 1 1 d . . .
Cl4 Cl 0.6046(5) -0.3437(2) 0.29480(15) 0.1085(9) Uani 1 1 d . . .
S1 S 0.6746(3) 0.42791(14) 0.34672(9) 0.0577(4) Uani 1 1 d . . .
S2 S 0.80236(18) 0.17908(10) 0.27999(6) 0.0370(3) Uani 1 1 d . . .
S3 S 0.52614(19) 0.25682(11) 0.17640(7) 0.0403(3) Uani 1 1 d . . .
S4 S 0.4866(2) -0.00386(12) 0.13322(8) 0.0508(4) Uani 1 1 d . . .
C1 C 1.0544(8) 0.3322(5) 0.1800(3) 0.0478(13) Uani 1 1 d . . .
C2 C 0.9543(10) 0.4176(5) 0.1733(4) 0.0593(17) Uani 1 1 d . . .
C3 C 0.9819(10) 0.4939(6) 0.2416(5) 0.0666(19) Uani 1 1 d . . .
C4 C 1.1009(10) 0.4618(5) 0.2929(4) 0.0649(18) Uani 1 1 d . . .
C5 C 1.1442(8) 0.3635(5) 0.2547(4) 0.0526(14) Uani 1 1 d . . .
C6 C 1.0126(8) 0.2259(5) 0.1281(3) 0.0504(14) Uani 1 1 d . . .
C7 C 0.8713(9) 0.1911(6) 0.0630(3) 0.0545(15) Uani 1 1 d . . .
C8 C 0.8224(9) 0.0792(6) 0.0408(3) 0.0568(16) Uani 1 1 d . . .
C9 C 0.9321(9) 0.0408(5) 0.0906(3) 0.0545(15) Uani 1 1 d . . .
C10 C 1.0491(9) 0.1308(5) 0.1437(3) 0.0495(13) Uani 1 1 d . . .
C11 C 0.7373(10) 0.3872(5) 0.4237(3) 0.0541(15) Uani 1 1 d . . .
C12 C 0.5964(13) 0.3745(6) 0.4681(4) 0.073(2) Uani 1 1 d . . .
C13 C 0.6324(16) 0.3359(7) 0.5275(4) 0.088(3) Uani 1 1 d . . .
C14 C 0.8062(17) 0.3106(6) 0.5415(4) 0.088(3) Uani 1 1 d . . .
C15 C 0.9526(14) 0.3270(6) 0.5016(4) 0.081(2) Uani 1 1 d . . .
C16 C 0.9165(11) 0.3656(5) 0.4428(4) 0.0660(18) Uani 1 1 d . . .
C17 C 0.6076(8) 0.1381(4) 0.3238(3) 0.0386(11) Uani 1 1 d . . .
C18 C 0.4241(8) 0.1575(5) 0.3135(3) 0.0508(14) Uani 1 1 d . . .
C19 C 0.2839(9) 0.1256(6) 0.3516(4) 0.0599(17) Uani 1 1 d . . .
C20 C 0.3296(10) 0.0733(6) 0.4006(4) 0.0658(19) Uani 1 1 d . . .
C21 C 0.5073(11) 0.0496(7) 0.4107(4) 0.077(2) Uani 1 1 d . . .
C22 C 0.6492(10) 0.0823(6) 0.3723(3) 0.0570(16) Uani 1 1 d . . .
C23 C 0.4627(7) 0.3090(5) 0.1037(3) 0.0420(12) Uani 1 1 d . . .
C24 C 0.4092(9) 0.2414(5) 0.0325(3) 0.0527(14) Uani 1 1 d . . .
C25 C 0.3203(10) 0.2761(6) -0.0212(4) 0.0621(17) Uani 1 1 d . . .
C26 C 0.2860(10) 0.3773(6) -0.0031(4) 0.0638(18) Uani 1 1 d . . .
C27 C 0.3447(10) 0.4480(6) 0.0663(4) 0.0632(18) Uani 1 1 d . . .
C28 C 0.4342(9) 0.4131(5) 0.1198(3) 0.0524(14) Uani 1 1 d . . .
C29 C 0.5357(10) -0.0947(5) 0.1803(3) 0.0518(14) Uani 1 1 d . . .
C30 C 0.7158(10) -0.0968(5) 0.2134(3) 0.0565(15) Uani 1 1 d . . .
C31 C 0.7384(12) -0.1735(6) 0.2491(4) 0.0665(19) Uani 1 1 d . . .
C32 C 0.5789(14) -0.2478(6) 0.2503(4) 0.076(2) Uani 1 1 d . . .
C33 C 0.4005(14) -0.2473(7) 0.2178(5) 0.089(3) Uani 1 1 d . . .
C34 C 0.3778(12) -0.1721(6) 0.1825(5) 0.075(2) Uani 1 1 d . . .
H2 H 0.8562 0.4105 0.1331 0.071 Uiso 1 1 d R . .
H3 H 0.9405 0.5756 0.2574 0.080 Uiso 1 1 d R . .
H4 H 1.1103 0.4875 0.3453 0.078 Uiso 1 1 d R . .
H5 H 1.1895 0.3147 0.2775 0.063 Uiso 1 1 d R . .
H7 H 0.7956 0.2363 0.0469 0.065 Uiso 1 1 d R . .
H8 H 0.7083 0.0379 0.0077 0.068 Uiso 1 1 d R . .
H9 H 0.9334 -0.0352 0.0868 0.065 Uiso 1 1 d R . .
H10 H 1.1115 0.1305 0.1900 0.059 Uiso 1 1 d R . .
H12 H 0.4731 0.3922 0.4574 0.087 Uiso 1 1 d R . .
H13 H 0.5390 0.3261 0.5592 0.105 Uiso 1 1 d R . .
H15 H 1.0748 0.3113 0.5155 0.097 Uiso 1 1 d R . .
H16 H 1.0165 0.3780 0.4144 0.079 Uiso 1 1 d R . .
H18 H 0.3941 0.1952 0.2794 0.061 Uiso 1 1 d R . .
H19 H 0.1554 0.1384 0.3454 0.072 Uiso 1 1 d R . .
H21 H 0.5359 0.0119 0.4451 0.092 Uiso 1 1 d R . .
H22 H 0.7761 0.0669 0.3783 0.068 Uiso 1 1 d R . .
H24 H 0.4398 0.1709 0.0214 0.063 Uiso 1 1 d R . .
H25 H 0.2791 0.2276 -0.0700 0.075 Uiso 1 1 d R . .
H27 H 0.3150 0.5182 0.0727 0.076 Uiso 1 1 d R . .
H28 H 0.4729 0.4578 0.1696 0.063 Uiso 1 1 d R . .
H30 H 0.8266 -0.0453 0.2118 0.068 Uiso 1 1 d R . .
H31 H 0.8620 -0.1766 0.2729 0.080 Uiso 1 1 d R . .
H33 H 0.2923 -0.2995 0.2194 0.107 Uiso 1 1 d R . .
H34 H 0.2531 -0.1722 0.1592 0.090 Uiso 1 1 d R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_diffrn_radiation_wavelength
0.71073
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Ru1 C2 38.8(2) . . ?
C1 Ru1 C3 62.8(3) . . ?
C2 Ru1 C3 36.5(3) . . ?
C1 Ru1 C5 37.7(2) . . ?
C2 Ru1 C5 62.9(2) . . ?
C3 Ru1 C5 61.9(3) . . ?
C1 Ru1 C4 62.5(3) . . ?
C2 Ru1 C4 62.3(3) . . ?
C3 Ru1 C4 37.6(3) . . ?
C5 Ru1 C4 36.4(2) . . ?
C1 Ru1 S3 109.90(17) . . ?
C2 Ru1 S3 98.11(19) . . ?
C3 Ru1 S3 120.1(2) . . ?
C5 Ru1 S3 146.12(17) . . ?
C4 Ru1 S3 157.57(19) . . ?
C1 Ru1 S2 103.22(16) . . ?
C2 Ru1 S2 140.64(19) . . ?
C3 Ru1 S2 153.62(19) . . ?
C5 Ru1 S2 93.11(17) . . ?
C4 Ru1 S2 116.77(19) . . ?
S3 Ru1 S2 85.13(4) . . ?
C1 Ru1 S1 152.38(17) . . ?
C2 Ru1 S1 123.40(19) . . ?
C3 Ru1 S1 91.7(2) . . ?
C5 Ru1 S1 122.27(18) . . ?
C4 Ru1 S1 91.0(2) . . ?
S3 Ru1 S1 91.54(6) . . ?
S2 Ru1 S1 95.54(5) . . ?
C1 Ru1 Ru2 73.58(16) . . ?
C2 Ru1 Ru2 94.6(2) . . ?
C3 Ru1 Ru2 130.9(2) . . ?
C5 Ru1 Ru2 96.46(17) . . ?
C4 Ru1 Ru2 132.3(2) . . ?
S3 Ru1 Ru2 55.19(4) . . ?
S2 Ru1 Ru2 55.31(3) . . ?
S1 Ru1 Ru2 134.03(5) . . ?
C6 Ru2 C10 37.9(2) . . ?
C6 Ru2 C7 38.1(2) . . ?
C10 Ru2 C7 62.7(2) . . ?
C6 Ru2 C9 62.6(2) . . ?
C10 Ru2 C9 36.9(2) . . ?
C7 Ru2 C9 62.1(2) . . ?
C6 Ru2 C8 62.5(2) . . ?
C10 Ru2 C8 62.1(2) . . ?
C7 Ru2 C8 36.5(2) . . ?
C9 Ru2 C8 37.4(2) . . ?
C6 Ru2 S3 110.40(18) . . ?
C10 Ru2 S3 146.06(17) . . ?
C7 Ru2 S3 100.03(18) . . ?
C9 Ru2 S3 159.42(16) . . ?
C8 Ru2 S3 122.06(18) . . ?
C6 Ru2 S2 103.37(16) . . ?
C10 Ru2 S2 91.47(15) . . ?
C7 Ru2 S2 140.59(17) . . ?
C9 Ru2 S2 115.02(16) . . ?
C8 Ru2 S2 151.81(17) . . ?
S3 Ru2 S2 85.12(5) . . ?
C6 Ru2 S4 154.40(18) . . ?
C10 Ru2 S4 125.51(17) . . ?
C7 Ru2 S4 123.85(18) . . ?
C9 Ru2 S4 93.63(18) . . ?
C8 Ru2 S4 93.10(19) . . ?
S3 Ru2 S4 88.42(5) . . ?
S2 Ru2 S4 95.15(5) . . ?
C6 Ru2 Ru1 74.05(18) . . ?
C10 Ru2 Ru1 95.61(16) . . ?
C7 Ru2 Ru1 95.78(19) . . ?
C9 Ru2 Ru1 132.10(17) . . ?
C8 Ru2 Ru1 131.85(19) . . ?
S3 Ru2 Ru1 55.19(4) . . ?
S2 Ru2 Ru1 55.30(3) . . ?
S4 Ru2 Ru1 131.52(5) . . ?
C11 S1 Ru1 109.0(2) . . ?
C17 S2 Ru1 119.59(18) . . ?
C17 S2 Ru2 117.69(17) . . ?
Ru1 S2 Ru2 69.38(3) . . ?
C23 S3 Ru1 116.11(18) . . ?
C23 S3 Ru2 114.6(2) . . ?
Ru1 S3 Ru2 69.62(4) . . ?
C29 S4 Ru2 113.2(2) . . ?
C5 C1 C6 127.2(5) . . ?
C5 C1 C2 106.3(6) . . ?
C6 C1 C2 123.6(6) . . ?
C5 C1 Ru1 72.4(3) . . ?
C6 C1 Ru1 106.6(3) . . ?
C2 C1 Ru1 70.8(3) . . ?
C3 C2 C1 107.8(6) . . ?
C3 C2 Ru1 72.3(4) . . ?
C1 C2 Ru1 70.4(3) . . ?
C2 C3 C4 109.3(7) . . ?
C2 C3 Ru1 71.2(4) . . ?
C4 C3 Ru1 72.5(3) . . ?
C5 C4 C3 107.3(7) . . ?
C5 C4 Ru1 71.0(3) . . ?
C3 C4 Ru1 69.9(4) . . ?
C4 C5 C1 109.3(6) . . ?
C4 C5 Ru1 72.6(4) . . ?
C1 C5 Ru1 69.9(3) . . ?
C10 C6 C1 125.3(5) . . ?
C10 C6 C7 106.8(6) . . ?
C1 C6 C7 124.7(6) . . ?
C10 C6 Ru2 71.6(3) . . ?
C1 C6 Ru2 105.8(4) . . ?
C7 C6 Ru2 71.7(3) . . ?
C8 C7 C6 108.3(5) . . ?
C8 C7 Ru2 72.3(3) . . ?
C6 C7 Ru2 70.2(3) . . ?
C7 C8 C9 108.6(6) . . ?
C7 C8 Ru2 71.2(3) . . ?
C9 C8 Ru2 71.3(3) . . ?
C10 C9 C8 107.8(6) . . ?
C10 C9 Ru2 70.8(3) . . ?
C8 C9 Ru2 71.3(4) . . ?
C9 C10 C6 108.5(5) . . ?
C9 C10 Ru2 72.4(4) . . ?
C6 C10 Ru2 70.5(3) . . ?
C16 C11 C12 117.9(6) . . ?
C16 C11 S1 124.5(6) . . ?
C12 C11 S1 117.6(5) . . ?
C13 C12 C11 120.6(8) . . ?
C14 C13 C12 119.2(9) . . ?
C13 C14 C15 122.1(8) . . ?
C13 C14 Cl1 118.1(8) . . ?
C15 C14 Cl1 119.8(8) . . ?
C14 C15 C16 118.4(8) . . ?
C15 C16 C11 121.6(8) . . ?
C18 C17 C22 119.0(5) . . ?
C18 C17 S2 125.7(4) . . ?
C22 C17 S2 115.3(4) . . ?
C19 C18 C17 121.7(5) . . ?
C20 C19 C18 118.3(6) . . ?
C21 C20 C19 121.9(6) . . ?
C21 C20 Cl2 119.8(5) . . ?
C19 C20 Cl2 118.3(5) . . ?
C20 C21 C22 119.6(5) . . ?
C17 C22 C21 119.5(6) . . ?
C28 C23 C24 119.0(5) . . ?
C28 C23 S3 119.5(4) . . ?
C24 C23 S3 120.5(4) . . ?
C23 C24 C25 120.6(6) . . ?
C26 C25 C24 119.1(6) . . ?
C25 C26 C27 121.7(6) . . ?
C25 C26 Cl3 118.7(6) . . ?
C27 C26 Cl3 119.6(6) . . ?
C26 C27 C28 119.0(6) . . ?
C23 C28 C27 120.4(6) . . ?
C30 C29 C34 118.4(6) . . ?
C30 C29 S4 125.5(5) . . ?
C34 C29 S4 116.1(5) . . ?
C29 C30 C31 120.6(6) . . ?
C32 C31 C30 119.1(7) . . ?
C33 C32 C31 121.2(7) . . ?
C33 C32 Cl4 119.2(7) . . ?
C31 C32 Cl4 119.6(7) . . ?
C32 C33 C34 119.9(8) . . ?
C33 C34 C29 120.9(8) . . ?
C3 C2 H2 125.2 . . ?
C1 C2 H2 124.4 . . ?
Ru1 C2 H2 108.7 . . ?
C2 C3 H3 129.0 . . ?
C4 C3 H3 121.2 . . ?
Ru1 C3 H3 128.8 . . ?
C5 C4 H4 123.8 . . ?
C3 C4 H4 125.6 . . ?
Ru1 C4 H4 108.0 . . ?
C4 C5 H5 124.3 . . ?
C1 C5 H5 123.6 . . ?
Ru1 C5 H5 108.6 . . ?
C8 C7 H7 124.3 . . ?
C6 C7 H7 124.9 . . ?
Ru2 C7 H7 109.0 . . ?
C7 C8 H8 123.9 . . ?
C9 C8 H8 125.0 . . ?
Ru2 C8 H8 109.2 . . ?
C10 C9 H9 125.4 . . ?
C8 C9 H9 126.7 . . ?
Ru2 C9 H9 126.6 . . ?
C9 C10 H10 125.1 . . ?
C6 C10 H10 123.9 . . ?
Ru2 C10 H10 108.9 . . ?
C13 C12 H12 119.9 . . ?
C11 C12 H12 119.5 . . ?
C14 C13 H13 117.9 . . ?
C12 C13 H13 122.9 . . ?
C14 C15 H15 118.7 . . ?
C16 C15 H15 122.9 . . ?
C15 C16 H16 119.8 . . ?
C11 C16 H16 118.6 . . ?
C19 C18 H18 119.1 . . ?
C17 C18 H18 119.2 . . ?
C20 C19 H19 118.6 . . ?
C18 C19 H19 123.0 . . ?
C20 C21 H21 120.5 . . ?
C22 C21 H21 119.9 . . ?
C17 C22 H22 119.0 . . ?
C21 C22 H22 121.5 . . ?
C23 C24 H24 117.8 . . ?
C25 C24 H24 121.5 . . ?
C26 C25 H25 121.0 . . ?
C24 C25 H25 119.9 . . ?
C26 C27 H27 114.6 . . ?
C28 C27 H27 126.4 . . ?
C23 C28 H28 116.9 . . ?
C27 C28 H28 122.6 . . ?
C29 C30 H30 119.8 . . ?
C31 C30 H30 119.6 . . ?
C32 C31 H31 118.5 . . ?
C30 C31 H31 122.4 . . ?
C32 C33 H33 119.7 . . ?
C34 C33 H33 120.4 . . ?
C33 C34 H34 120.0 . . ?
C29 C34 H34 119.2 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ru1 C1 2.199(6) . ?
Ru1 C2 2.204(6) . ?
Ru1 C3 2.219(6) . ?
Ru1 C5 2.232(6) . ?
Ru1 C4 2.254(6) . ?
Ru1 S3 2.3345(14) . ?
Ru1 S2 2.3415(13) . ?
Ru1 S1 2.3653(17) . ?
Ru1 Ru2 2.6655(7) . ?
Ru2 C6 2.198(5) . ?
Ru2 C10 2.213(6) . ?
Ru2 C7 2.219(5) . ?
Ru2 C9 2.234(6) . ?
Ru2 C8 2.234(6) . ?
Ru2 S3 2.3346(15) . ?
Ru2 S2 2.3418(12) . ?
Ru2 S4 2.3548(15) . ?
Cl1 C14 1.749(8) . ?
Cl2 C20 1.736(6) . ?
Cl3 C26 1.741(6) . ?
Cl4 C32 1.745(7) . ?
S1 C11 1.760(6) . ?
S2 C17 1.775(5) . ?
S3 C23 1.782(5) . ?
S4 C29 1.758(6) . ?
C1 C5 1.432(8) . ?
C1 C6 1.440(9) . ?
C1 C2 1.462(9) . ?
C2 C3 1.386(10) . ?
C3 C4 1.441(10) . ?
C4 C5 1.401(9) . ?
C6 C10 1.432(8) . ?
C6 C7 1.442(8) . ?
C7 C8 1.393(9) . ?
C8 C9 1.433(9) . ?
C9 C10 1.407(9) . ?
C11 C16 1.392(9) . ?
C11 C12 1.395(10) . ?
C12 C13 1.398(10) . ?
C13 C14 1.357(13) . ?
C14 C15 1.376(13) . ?
C15 C16 1.387(10) . ?
C17 C18 1.378(8) . ?
C17 C22 1.384(7) . ?
C18 C19 1.372(8) . ?
C19 C20 1.365(8) . ?
C20 C21 1.362(10) . ?
C21 C22 1.389(9) . ?
C23 C28 1.378(8) . ?
C23 C24 1.385(8) . ?
C24 C25 1.388(8) . ?
C25 C26 1.355(10) . ?
C26 C27 1.375(10) . ?
C27 C28 1.388(8) . ?
C29 C30 1.385(9) . ?
C29 C34 1.402(9) . ?
C30 C31 1.401(9) . ?
C31 C32 1.379(11) . ?
C32 C33 1.364(12) . ?
C33 C34 1.377(10) . ?
C2 H2 0.9647 . ?
C3 H3 1.1335 . ?
C4 H4 0.9607 . ?
C5 H5 0.9584 . ?
C7 H7 0.9630 . ?
C8 H8 0.9604 . ?
C9 H9 0.9903 . ?
C10 H10 0.9596 . ?
C12 H12 0.9638 . ?
C13 H13 0.9611 . ?
C15 H15 0.9585 . ?
C16 H16 0.9568 . ?
C18 H18 0.9604 . ?
C19 H19 0.9597 . ?
C21 H21 0.9609 . ?
C22 H22 0.9621 . ?
C24 H24 0.9629 . ?
C25 H25 0.9604 . ?
C27 H27 0.9641 . ?
C28 H28 0.9594 . ?
C30 H30 0.9621 . ?
C31 H31 0.9656 . ?
C33 H33 0.9541 . ?
C34 H34 0.9555 . ?
loop_
_cod_changelog_entry_id
_cod_changelog_entry_author
_cod_changelog_entry_date
_cod_changelog_entry_text
1 'Vaitkus, Antanas' 2022-05-07T02:35:00+03:00
;
 Replaced the '&#x00A5;' sequences with backslash symbols ('\')
 in multiple data values.
;
