#------------------------------------------------------------------------------
#$Date: 2016-02-16 02:10:39 +0100 (mar 16 de feb de 2016) $
#$Revision: 176453 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/22/7012201.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7012201
loop_
_publ_author_name
'Muhammad S. Khan'
'Mohammed K. Al-Suti'
'Muna R. A. Al-Mandhary'
'Birte Ahrens'
'Jens K. Bjernemose'
'Mary F. Mahon'
'Louise Male'
'Paul R. Raithby'
'Richard H. Friend'
'Anna Köhler'
'Joanne S. Wilson'
_publ_section_title
;
 Synthesis and characterisation of new acetylide-functionalised
 aromatic and hetero-aromatic ligands and their dinuclear platinum
 complexes
;
_journal_issue                   1
_journal_name_full               'Dalton Trans.'
_journal_page_first              65
_journal_page_last               73
_journal_paper_doi               10.1039/b208494e
_journal_year                    2003
_chemical_formula_moiety         'C49 H75 N1 P4 Pt2'
_chemical_formula_sum            'C49.5 H76 Cl N P4 Pt2'
_chemical_formula_weight         1234.62
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                112.3960(10)
_cell_angle_beta                 95.2000(10)
_cell_angle_gamma                94.2820(10)
_cell_formula_units_Z            2
_cell_length_a                   9.17940(10)
_cell_length_b                   16.7290(2)
_cell_length_c                   18.8959(2)
_cell_measurement_reflns_used    58387
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      30.03
_cell_measurement_theta_min      2.91
_cell_volume                     2652.93(6)
_computing_cell_refinement       'HKL Scalepack (Otwinski & Minor, 1997)'
_computing_data_collection       'Collect (Nonius BV, 1997-2000)'
_computing_data_reduction
'HKL Denzo & Scalepack (Otwinski & Minor 1997)'
_computing_molecular_graphics    'Ortep-3 for Windows (Farrugia, 1997)'
_computing_publication_material  'WinGX publication routines (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'DirDif-99 (Beurskens, 1999)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Nonius Kappa CCD'
_diffrn_measurement_method       '346 1.7 degree images'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0480
_diffrn_reflns_av_sigmaI/netI    0.0371
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            54771
_diffrn_reflns_theta_full        30.05
_diffrn_reflns_theta_max         30.05
_diffrn_reflns_theta_min         3.53
_exptl_absorpt_coefficient_mu    5.470
_exptl_absorpt_correction_T_max  0.622
_exptl_absorpt_correction_T_min  0.140
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'Gaussian integration (Coppens, 1970)'
_exptl_crystal_colour            'pale yellow'
_exptl_crystal_density_diffrn    1.546
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1226
_exptl_crystal_size_max          0.48
_exptl_crystal_size_mid          0.14
_exptl_crystal_size_min          0.10
_refine_diff_density_max         1.946
_refine_diff_density_min         -2.259
_refine_diff_density_rms         0.140
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.077
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     534
_refine_ls_number_reflns         15461
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.077
_refine_ls_R_factor_all          0.0514
_refine_ls_R_factor_gt           0.0387
_refine_ls_shift/su_max          0.034
_refine_ls_shift/su_mean         0.002
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0365P)²+8.8287P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0937
_refine_ls_wR_factor_ref         0.1009
_reflns_number_gt                12734
_reflns_number_total             15461
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b208494e.txt
_cod_data_source_block           h01prr55
_cod_original_cell_volume        2652.93(5)
_cod_original_formula_sum        'C49.50 H76 Cl N P4 Pt2'
_cod_database_code               7012201
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.444325(17) 0.323168(12) 0.829083(9) 0.03144(5) Uani 1 1 d . . .
Pt2 Pt 1.189068(18) 0.204924(11) 0.307445(9) 0.03212(5) Uani 1 1 d . . .
P11 P 0.26474(13) 0.38506(9) 0.78300(7) 0.0376(3) Uani 1 1 d . . .
P12 P 0.62278(12) 0.25215(8) 0.86404(7) 0.0323(2) Uani 1 1 d . . .
P21 P 0.97381(13) 0.13309(9) 0.23034(7) 0.0375(3) Uani 1 1 d . A .
P22 P 1.40970(17) 0.26720(11) 0.38367(8) 0.0531(4) Uani 1 1 d . A .
C1 C 0.7263(5) 0.3031(4) 0.6322(3) 0.0476(14) Uani 1 1 d . . .
C2 C 0.7508(6) 0.2206(5) 0.5855(3) 0.0513(14) Uani 1 1 d . . .
H2 H 0.7069 0.1720 0.5934 0.062 Uiso 1 1 calc R . .
C3 C 0.8408(6) 0.2068(5) 0.5254(3) 0.0508(14) Uani 1 1 d . . .
H3 H 0.8542 0.1489 0.4936 0.061 Uiso 1 1 calc R . .
C4 C 0.9092(5) 0.2754(4) 0.5122(3) 0.0424(12) Uani 1 1 d . A .
C5 C 0.8867(5) 0.3613(4) 0.5607(3) 0.0459(13) Uani 1 1 d . . .
N6 N 0.9594(6) 0.4362(5) 0.5511(4) 0.0651(15) Uani 0.69 1 d P A 1
C6 C 0.9594(6) 0.4362(5) 0.5511(4) 0.0651(15) Uani 0.31 1 d P A 2
H6 H 1.0267 0.4269 0.5142 0.078 Uiso 0.31 1 calc PR A 2
C7 C 0.9338(8) 0.5202(6) 0.5939(5) 0.077(2) Uani 1 1 d . . .
H7 H 0.9793 0.5674 0.5844 0.092 Uiso 1 1 calc R A 1
C8 C 0.8382(9) 0.5363(6) 0.6527(5) 0.074(2) Uani 1 1 d . A .
H8 H 0.8216 0.5942 0.6827 0.089 Uiso 1 1 calc R B 1
C9 C 0.7699(8) 0.4667(5) 0.6656(4) 0.0722(18) Uani 0.69 1 d P A 1
H9 H 0.7069 0.4778 0.7047 0.087 Uiso 0.69 1 calc PR A 1
N9 N 0.7699(8) 0.4667(5) 0.6656(4) 0.0722(18) Uani 0.31 1 d P A 2
C10 C 0.7940(5) 0.3752(4) 0.6192(3) 0.0488(14) Uani 1 1 d . A .
C11 C 0.6359(6) 0.3167(4) 0.6929(3) 0.0507(14) Uani 1 1 d . . .
C12 C 0.5624(5) 0.3228(4) 0.7446(3) 0.0444(12) Uani 1 1 d . . .
C41 C 0.9984(6) 0.2585(4) 0.4504(3) 0.0441(12) Uani 1 1 d . . .
C42 C 1.0712(6) 0.2400(4) 0.3975(3) 0.0416(11) Uani 1 1 d . A .
C101 C 0.3254(5) 0.3183(4) 0.9151(3) 0.0380(11) Uani 1 1 d . . .
C102 C 0.2268(5) 0.2452(4) 0.9046(4) 0.0484(13) Uani 1 1 d . . .
H102 H 0.2142 0.1969 0.8563 0.058 Uiso 1 1 calc R . .
C103 C 0.1471(6) 0.2409(6) 0.9624(5) 0.070(2) Uani 1 1 d . . .
H103 H 0.0836 0.1896 0.9533 0.084 Uiso 1 1 calc R . .
C104 C 0.1586(7) 0.3087(6) 1.0315(5) 0.073(2) Uani 1 1 d . . .
H104 H 0.1015 0.3061 1.0702 0.088 Uiso 1 1 calc R . .
C105 C 0.2542(7) 0.3810(5) 1.0444(4) 0.0630(18) Uani 1 1 d . . .
H105 H 0.2651 0.4285 1.0931 0.076 Uiso 1 1 calc R . .
C106 C 0.3363(6) 0.3861(4) 0.9872(3) 0.0473(13) Uani 1 1 d . . .
H106 H 0.4012 0.4374 0.9978 0.057 Uiso 1 1 calc R . .
C111 C 0.1382(7) 0.4373(5) 0.8491(4) 0.0607(17) Uani 1 1 d . . .
H11A H 0.0901 0.3934 0.8656 0.073 Uiso 1 1 calc R . .
H11B H 0.1960 0.4829 0.8956 0.073 Uiso 1 1 calc R . .
C112 C 0.0176(8) 0.4790(6) 0.8191(4) 0.075(2) Uani 1 1 d . . .
H11C H -0.0412 0.5074 0.8604 0.112 Uiso 1 1 calc R . .
H11D H -0.0461 0.4340 0.7756 0.112 Uiso 1 1 calc R . .
H11E H 0.0629 0.5223 0.8020 0.112 Uiso 1 1 calc R . .
C113 C 0.3315(8) 0.4684(6) 0.7495(6) 0.088(3) Uani 1 1 d . . .
H11F H 0.3975 0.4437 0.7099 0.105 Uiso 1 1 calc R . .
H11G H 0.2469 0.4863 0.7251 0.105 Uiso 1 1 calc R . .
C114 C 0.4163(14) 0.5494(8) 0.8169(11) 0.182(8) Uani 1 1 d . . .
H11H H 0.4497 0.5930 0.7971 0.274 Uiso 1 1 calc R . .
H11I H 0.5017 0.5321 0.8402 0.274 Uiso 1 1 calc R . .
H11J H 0.3509 0.5742 0.8559 0.274 Uiso 1 1 calc R . .
C115 C 0.1521(10) 0.3066(6) 0.6982(5) 0.097(3) Uani 1 1 d . . .
H11K H 0.0706 0.3357 0.6845 0.116 Uiso 1 1 calc R . .
H11L H 0.2127 0.2906 0.6552 0.116 Uiso 1 1 calc R . .
C116 C 0.0926(12) 0.2321(7) 0.7022(7) 0.128(5) Uani 1 1 d . . .
H11M H 0.0362 0.1949 0.6523 0.192 Uiso 1 1 calc R . .
H11N H 0.0272 0.2462 0.7424 0.192 Uiso 1 1 calc R . .
H11O H 0.1715 0.2015 0.7148 0.192 Uiso 1 1 calc R . .
C121 C 0.6045(5) 0.2258(4) 0.9483(3) 0.0455(12) Uani 1 1 d . . .
H12A H 0.5909 0.2799 0.9920 0.055 Uiso 1 1 calc R . .
H12B H 0.5137 0.1849 0.9371 0.055 Uiso 1 1 calc R . .
C122 C 0.7318(6) 0.1861(5) 0.9743(4) 0.0554(16) Uani 1 1 d . . .
H12C H 0.7135 0.1783 1.0216 0.083 Uiso 1 1 calc R . .
H12D H 0.8234 0.2249 0.9841 0.083 Uiso 1 1 calc R . .
H12E H 0.7406 0.1295 0.9337 0.083 Uiso 1 1 calc R . .
C123 C 0.6299(7) 0.1474(4) 0.7867(4) 0.0605(16) Uani 1 1 d . . .
H12F H 0.6648 0.1569 0.7421 0.073 Uiso 1 1 calc R . .
H12G H 0.7020 0.1156 0.8044 0.073 Uiso 1 1 calc R . .
C124 C 0.4793(9) 0.0912(5) 0.7605(6) 0.094(3) Uani 1 1 d . . .
H12H H 0.4892 0.0352 0.7194 0.140 Uiso 1 1 calc R . .
H12I H 0.4084 0.1214 0.7410 0.140 Uiso 1 1 calc R . .
H12J H 0.4445 0.0813 0.8043 0.140 Uiso 1 1 calc R . .
C125 C 0.8083(5) 0.3083(4) 0.8819(3) 0.0406(11) Uani 1 1 d . . .
H12K H 0.8803 0.2692 0.8875 0.049 Uiso 1 1 calc R . .
H12L H 0.8276 0.3224 0.8370 0.049 Uiso 1 1 calc R . .
C126 C 0.8302(7) 0.3922(4) 0.9545(4) 0.0585(15) Uani 1 1 d . . .
H12M H 0.9308 0.4207 0.9617 0.088 Uiso 1 1 calc R . .
H12N H 0.8143 0.3783 0.9994 0.088 Uiso 1 1 calc R . .
H12O H 0.7597 0.4313 0.9490 0.088 Uiso 1 1 calc R . .
C201 C 1.3048(4) 0.1657(3) 0.2138(2) 0.0299(8) Uani 1 1 d . A .
C202 C 1.3245(5) 0.2149(3) 0.1686(3) 0.0379(10) Uani 1 1 d . . .
H202 H 1.2868 0.2695 0.1832 0.045 Uiso 1 1 calc R . .
C203 C 1.3969(5) 0.1866(4) 0.1033(3) 0.0416(11) Uani 1 1 d . . .
H203 H 1.4075 0.2215 0.0741 0.050 Uiso 1 1 calc R . .
C204 C 1.4536(5) 0.1074(4) 0.0811(3) 0.0408(11) Uani 1 1 d . . .
H204 H 1.5026 0.0875 0.0365 0.049 Uiso 1 1 calc R . .
C205 C 1.4380(5) 0.0578(3) 0.1245(3) 0.0400(11) Uani 1 1 d . . .
H205 H 1.4777 0.0038 0.1100 0.048 Uiso 1 1 calc R . .
C206 C 1.3647(5) 0.0864(3) 0.1893(3) 0.0355(9) Uani 1 1 d . . .
H206 H 1.3547 0.0508 0.2179 0.043 Uiso 1 1 calc R . .
C211 C 0.9858(6) 0.0728(5) 0.1278(3) 0.0562(16) Uani 1 1 d . . .
H21A H 1.0218 0.1148 0.1061 0.067 Uiso 1 1 calc R . .
H21B H 1.0607 0.0321 0.1235 0.067 Uiso 1 1 calc R . .
C212 C 0.8431(6) 0.0207(5) 0.0781(3) 0.0611(17) Uani 1 1 d . . .
H21C H 0.8604 -0.0058 0.0240 0.092 Uiso 1 1 calc R . .
H21D H 0.7666 0.0596 0.0828 0.092 Uiso 1 1 calc R . .
H21E H 0.8109 -0.0251 0.0956 0.092 Uiso 1 1 calc R . .
C213 C 0.8915(8) 0.0527(5) 0.2619(4) 0.074(2) Uani 1 1 d . . .
H21F H 0.8692 0.0825 0.3154 0.089 Uiso 1 1 calc R . .
H21G H 0.7971 0.0249 0.2287 0.089 Uiso 1 1 calc R . .
C214 C 0.9877(15) -0.0162(7) 0.2595(8) 0.140(5) Uani 1 1 d . . .
H21H H 0.9379 -0.0572 0.2778 0.211 Uiso 1 1 calc R . .
H21I H 1.0809 0.0108 0.2928 0.211 Uiso 1 1 calc R . .
H21J H 1.0074 -0.0474 0.2064 0.211 Uiso 1 1 calc R . .
C215 C 0.8303(6) 0.2030(5) 0.2324(4) 0.0621(17) Uani 1 1 d . . .
H21K H 0.7395 0.1664 0.2008 0.075 Uiso 1 1 calc R . .
H21L H 0.8085 0.2310 0.2862 0.075 Uiso 1 1 calc R . .
C216 C 0.8687(10) 0.2723(6) 0.2033(6) 0.101(3) Uani 1 1 d . . .
H21M H 0.7873 0.3078 0.2070 0.151 Uiso 1 1 calc R . .
H21N H 0.8863 0.2452 0.1493 0.151 Uiso 1 1 calc R . .
H21O H 0.9580 0.3094 0.2345 0.151 Uiso 1 1 calc R . .
C221 C 1.5178(8) 0.3431(6) 0.3537(4) 0.078(2) Uani 1 1 d . . .
H22A H 1.5325 0.3122 0.2991 0.094 Uiso 1 1 calc R . .
H22B H 1.4596 0.3914 0.3565 0.094 Uiso 1 1 calc R . .
C222 C 1.6713(8) 0.3826(6) 0.4022(5) 0.089(3) Uani 1 1 d . . .
H22C H 1.7205 0.4220 0.3821 0.134 Uiso 1 1 calc R . .
H22D H 1.7316 0.3356 0.3987 0.134 Uiso 1 1 calc R . .
H22E H 1.6585 0.4149 0.4563 0.134 Uiso 1 1 calc R . .
C223 C 1.4113(10) 0.3211(7) 0.4867(4) 0.103(4) Uani 1 1 d . . .
H22F H 1.3544 0.2814 0.5047 0.123 Uiso 1 1 calc R . .
H22G H 1.5143 0.3303 0.5115 0.123 Uiso 1 1 calc R . .
C224 C 1.3549(12) 0.4005(7) 0.5123(6) 0.107(3) Uani 1 1 d . . .
H22H H 1.3609 0.4239 0.5687 0.160 Uiso 1 1 calc R . .
H22I H 1.2518 0.3923 0.4897 0.160 Uiso 1 1 calc R . .
H22J H 1.4122 0.4413 0.4966 0.160 Uiso 1 1 calc R . .
C225 C 1.5399(8) 0.1865(7) 0.3770(5) 0.088(3) Uani 1 1 d . . .
H22K H 1.5584 0.1579 0.3227 0.105 Uiso 1 1 calc R . .
H22L H 1.6348 0.2167 0.4085 0.105 Uiso 1 1 calc R . .
C226 C 1.4819(12) 0.1188(8) 0.4044(6) 0.106(3) Uani 1 1 d . . .
H22M H 1.5520 0.0759 0.3981 0.159 Uiso 1 1 calc R . .
H22N H 1.3869 0.0895 0.3740 0.159 Uiso 1 1 calc R . .
H22O H 1.4688 0.1466 0.4590 0.159 Uiso 1 1 calc R . .
C60 C 0.8123(19) -0.0999(14) 0.4928(10) 0.076(5) Uani 0.42 1 d P . .
H61 H 0.9048 -0.1096 0.4692 0.091 Uiso 0.42 1 calc PR . .
H62 H 0.7975 -0.1405 0.5190 0.091 Uiso 0.42 1 calc PR . .
Cl61 Cl 0.6679(7) -0.1161(7) 0.4244(3) 0.135(3) Uani 0.42 1 d P . .
Cl62 Cl 0.8209(15) 0.0109(4) 0.5604(5) 0.191(5) Uani 0.42 1 d P . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C12 Pt1 C101 177.6(2) . . ?
C12 Pt1 P12 86.54(14) . . ?
C101 Pt1 P12 91.52(13) . . ?
C12 Pt1 P11 90.17(14) . . ?
C101 Pt1 P11 91.66(13) . . ?
P12 Pt1 P11 174.83(5) . . ?
C42 Pt2 C201 178.23(18) . . ?
C42 Pt2 P21 87.41(14) . . ?
C201 Pt2 P21 91.03(12) . . ?
C42 Pt2 P22 93.73(15) . . ?
C201 Pt2 P22 87.76(12) . . ?
P21 Pt2 P22 175.85(6) . . ?
C115 P11 C111 105.8(4) . . ?
C115 P11 C113 102.6(5) . . ?
C111 P11 C113 103.9(4) . . ?
C115 P11 Pt1 111.8(3) . . ?
C111 P11 Pt1 116.18(19) . . ?
C113 P11 Pt1 115.1(2) . . ?
C123 P12 C125 104.7(3) . . ?
C123 P12 C121 104.0(3) . . ?
C125 P12 C121 104.8(2) . . ?
C123 P12 Pt1 110.3(2) . . ?
C125 P12 Pt1 114.07(17) . . ?
C121 P12 Pt1 117.78(17) . . ?
C213 P21 C215 103.9(4) . . ?
C213 P21 C211 104.5(4) . . ?
C215 P21 C211 105.0(3) . . ?
C213 P21 Pt2 111.3(2) . . ?
C215 P21 Pt2 114.0(2) . . ?
C211 P21 Pt2 116.89(18) . . ?
C223 P22 C221 106.3(4) . . ?
C223 P22 C225 102.0(5) . . ?
C221 P22 C225 100.6(4) . . ?
C223 P22 Pt2 119.0(3) . . ?
C221 P22 Pt2 114.5(2) . . ?
C225 P22 Pt2 112.2(3) . . ?
C2 C1 C10 118.3(5) . . ?
C2 C1 C11 121.0(6) . . ?
C10 C1 C11 120.7(6) . . ?
C1 C2 C3 121.2(6) . . ?
C4 C3 C2 121.8(6) . . ?
C3 C4 C5 117.8(5) . . ?
C3 C4 C41 119.9(5) . . ?
C5 C4 C41 122.2(5) . . ?
C10 C5 C4 120.5(5) . . ?
C10 C5 N6 119.1(6) . . ?
C4 C5 N6 120.4(5) . . ?
C7 N6 C5 122.2(6) . . ?
N6 C7 C8 119.9(7) . . ?
C9 C8 C7 119.8(8) . . ?
C8 C9 C10 121.2(6) . . ?
C5 C10 C1 120.3(6) . . ?
C5 C10 C9 117.7(6) . . ?
C1 C10 C9 122.0(5) . . ?
C12 C11 C1 175.3(7) . . ?
C11 C12 Pt1 175.4(5) . . ?
C42 C41 C4 176.8(6) . . ?
C41 C42 Pt2 178.0(5) . . ?
C106 C101 C102 115.1(5) . . ?
C106 C101 Pt1 123.2(4) . . ?
C102 C101 Pt1 121.8(4) . . ?
C103 C102 C101 122.2(7) . . ?
C104 C103 C102 121.1(7) . . ?
C103 C104 C105 118.6(5) . . ?
C104 C105 C106 121.1(7) . . ?
C101 C106 C105 121.9(6) . . ?
C112 C111 P11 116.7(4) . . ?
C114 C113 P11 111.5(7) . . ?
C116 C115 P11 117.7(8) . . ?
C122 C121 P12 116.4(4) . . ?
C124 C123 P12 112.5(5) . . ?
C126 C125 P12 112.0(4) . . ?
C206 C201 C202 115.5(4) . . ?
C206 C201 Pt2 122.0(3) . . ?
C202 C201 Pt2 122.5(3) . . ?
C203 C202 C201 122.6(5) . . ?
C204 C203 C202 119.8(5) . . ?
C205 C204 C203 119.3(4) . . ?
C204 C205 C206 120.4(5) . . ?
C205 C206 C201 122.4(4) . . ?
C212 C211 P21 116.2(4) . . ?
C214 C213 P21 113.3(7) . . ?
C216 C215 P21 114.2(5) . . ?
C222 C221 P22 115.4(6) . . ?
C224 C223 P22 116.1(9) . . ?
C226 C225 P22 111.8(7) . . ?
Cl61 C60 Cl62 106.5(11) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
P11 Pt1 2.2868(12) . ?
P12 Pt1 2.2856(12) . ?
P21 Pt2 2.2936(12) . ?
P22 Pt2 2.2966(14) . ?
C1 C2 1.373(9) . ?
C1 C10 1.429(9) . ?
C1 C11 1.435(7) . ?
C2 C3 1.422(7) . ?
C3 C4 1.383(8) . ?
C4 C5 1.422(8) . ?
C4 C41 1.438(6) . ?
C5 C10 1.417(6) . ?
C5 N6 1.455(8) . ?
N6 C7 1.379(10) . ?
C7 C8 1.435(11) . ?
C8 C9 1.395(10) . ?
C9 C10 1.491(10) . ?
C11 C12 1.214(7) . ?
C12 Pt1 2.007(5) . ?
C41 C42 1.209(7) . ?
C42 Pt2 2.019(5) . ?
C101 C106 1.390(8) . ?
C101 C102 1.405(8) . ?
C101 Pt1 2.061(4) . ?
C102 C103 1.390(8) . ?
C103 C104 1.352(12) . ?
C104 C105 1.368(11) . ?
C105 C106 1.397(7) . ?
C111 C112 1.529(8) . ?
C111 P11 1.805(6) . ?
C113 C114 1.553(17) . ?
C113 P11 1.826(7) . ?
C115 C116 1.354(13) . ?
C115 P11 1.804(7) . ?
C121 C122 1.519(7) . ?
C121 P12 1.825(5) . ?
C123 C124 1.538(10) . ?
C123 P12 1.815(6) . ?
C125 C126 1.527(8) . ?
C125 P12 1.820(5) . ?
C201 C206 1.401(7) . ?
C201 C202 1.408(6) . ?
C201 Pt2 2.061(4) . ?
C202 C203 1.392(6) . ?
C203 C204 1.386(8) . ?
C204 C205 1.380(7) . ?
C205 C206 1.389(6) . ?
C211 C212 1.530(7) . ?
C211 P21 1.830(5) . ?
C213 C214 1.494(14) . ?
C213 P21 1.810(7) . ?
C215 C216 1.494(11) . ?
C215 P21 1.819(6) . ?
C221 C222 1.558(10) . ?
C221 P22 1.837(8) . ?
C223 C224 1.388(14) . ?
C223 P22 1.805(7) . ?
C225 C226 1.498(13) . ?
C225 P22 1.845(9) . ?
C60 Cl61 1.693(16) . ?
C60 Cl62 1.80(2) . ?
