#------------------------------------------------------------------------------
#$Date: 2016-03-25 12:13:36 +0100 (vie 25 de mar de 2016) $
#$Revision: 179832 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/28/7012833.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7012833
loop_
_publ_author_name
'Dutta, Dipak K.'
'Woollins, J. Derek'
'Slawin, Alexandra M. Z.'
'Konwar, Dilip'
'Das, Pankaj'
'Sharma, Manab'
'Bhattacharyya, Pravat'
'Aucott, Stephen M.'
_publ_section_title
;
 An alternative strategy to an electron rich phosphine based
 carbonylation catalyst
;
_journal_issue                   13
_journal_name_full               'Dalton Transactions'
_journal_page_first              2674
_journal_page_last               2679
_journal_paper_doi               10.1039/b301674a
_journal_year                    2003
_chemical_formula_moiety         'C41 H34 Cl O5 P2 Rh'
_chemical_formula_sum            'C41 H34 Cl O5 P2 Rh'
_chemical_formula_weight         806.98
_chemical_name_systematic        ?
_space_group_IT_number           1
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  'P 1'
_symmetry_space_group_name_H-M   'P 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                109.932(3)
_cell_angle_beta                 108.346(3)
_cell_angle_gamma                96.835(4)
_cell_formula_units_Z            1
_cell_length_a                   9.2330(18)
_cell_length_b                   9.5526(18)
_cell_length_c                   11.657(2)
_cell_measurement_reflns_used    135
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      168
_cell_measurement_theta_min      12
_cell_volume                     887.4(3)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 0.9
_diffrn_measured_fraction_theta_full 0.976
_diffrn_measured_fraction_theta_max 0.976
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0623
_diffrn_reflns_av_sigmaI/netI    0.0932
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_number            4346
_diffrn_reflns_theta_full        23.19
_diffrn_reflns_theta_max         23.19
_diffrn_reflns_theta_min         2.01
_exptl_absorpt_coefficient_mu    0.692
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.782407
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.510
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             412
_exptl_crystal_size_max          .12
_exptl_crystal_size_mid          .1
_exptl_crystal_size_min          .01
_refine_diff_density_max         0.610
_refine_diff_density_min         -0.410
_refine_diff_density_rms         0.075
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.00
_refine_ls_extinction_coef       -
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.893
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     418
_refine_ls_number_reflns         3516
_refine_ls_number_restraints     6
_refine_ls_restrained_S_all      0.893
_refine_ls_R_factor_all          0.0721
_refine_ls_R_factor_gt           0.0466
_refine_ls_shift/su_max          0.222
_refine_ls_shift/su_mean         0.041
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0536P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0925
_refine_ls_wR_factor_ref         0.1012
_reflns_number_gt                2563
_reflns_number_total             3516
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b301674a.txt
_cod_data_source_block           2
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'MULTISCAN' changed to
'multi-scan' according to
'/home/saulius/struct/CIF-dictionaries/cif_core.dic' dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_cell_volume        887.5(3)
_cod_original_sg_symbol_H-M      P1
_cod_database_code               7012833
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.8023(3) 1.0724(2) 0.9318(3) 0.0366(2) Uani 1 1 d D . .
Cl1 Cl 1.0140(4) 1.3006(3) 1.0229(3) 0.0588(11) Uani 1 1 d D . .
C30 C 0.6514(14) 0.8845(10) 0.8565(17) 0.107(10) Uani 1 1 d D . .
O30 O 0.5321(6) 0.8112(18) 0.8213(16) 0.072(4) Uani 1 1 d D . .
P1 P 0.7755(6) 1.0627(6) 0.7236(6) 0.0348(13) Uani 1 1 d . . .
C1 C 0.935(2) 0.992(2) 0.6828(18) 0.030(5) Uiso 1 1 d . . .
C2 C 0.936(2) 0.937(2) 0.5495(17) 0.039(5) Uani 1 1 d . . .
H2A H 0.8538 0.9460 0.4833 0.046 Uiso 1 1 calc R . .
C3 C 1.045(2) 0.877(2) 0.5189(15) 0.047(6) Uani 1 1 d . . .
H3A H 1.0338 0.8288 0.4315 0.057 Uiso 1 1 calc R . .
C4 C 1.180(2) 0.8879(19) 0.624(2) 0.075(8) Uani 1 1 d . . .
H4A H 1.2634 0.8554 0.6043 0.090 Uiso 1 1 calc R . .
C5 C 1.193(2) 0.9404(16) 0.7442(17) 0.036(4) Uani 1 1 d . . .
H5A H 1.2825 0.9447 0.8116 0.043 Uiso 1 1 calc R . .
C6 C 1.063(2) 0.9922(19) 0.7705(16) 0.038(5) Uani 1 1 d . . .
H6A H 1.0704 1.0291 0.8576 0.045 Uiso 1 1 calc R . .
C7 C 0.608(2) 0.941(2) 0.5763(16) 0.022(4) Uiso 1 1 d . . .
C8 C 0.584(2) 0.786(3) 0.540(2) 0.044(6) Uani 1 1 d . . .
H8A H 0.6509 0.7464 0.5921 0.052 Uiso 1 1 calc R . .
C9 C 0.460(3) 0.688(2) 0.426(2) 0.055(6) Uani 1 1 d . . .
H9A H 0.4374 0.5827 0.4032 0.066 Uiso 1 1 calc R . .
C10 C 0.363(2) 0.752(3) 0.3414(18) 0.071(9) Uani 1 1 d . . .
H10A H 0.2806 0.6851 0.2634 0.085 Uiso 1 1 calc R . .
C11 C 0.389(2) 0.896(2) 0.3721(19) 0.056(6) Uani 1 1 d . . .
H11A H 0.3274 0.9360 0.3175 0.067 Uiso 1 1 calc R . .
C12 C 0.514(3) 0.994(3) 0.491(2) 0.060(7) Uani 1 1 d . . .
H12A H 0.5345 1.0992 0.5139 0.072 Uiso 1 1 calc R . .
C13 C 0.801(2) 1.255(2) 0.717(2) 0.043(6) Uiso 1 1 d . . .
C14 C 0.707(2) 1.356(2) 0.754(2) 0.039(5) Uiso 1 1 d . . .
C15 C 0.737(2) 1.497(3) 0.752(2) 0.072(8) Uani 1 1 d . . .
H15A H 0.6789 1.5655 0.7792 0.086 Uiso 1 1 calc R . .
C16 C 0.852(2) 1.542(2) 0.7109(18) 0.045(5) Uani 1 1 d . . .
H16A H 0.8669 1.6377 0.7054 0.054 Uiso 1 1 calc R . .
C17 C 0.950(2) 1.442(3) 0.677(2) 0.052(6) Uani 1 1 d . . .
H17A H 1.0324 1.4758 0.6543 0.062 Uiso 1 1 calc R . .
C18 C 0.9236(19) 1.299(2) 0.6763(16) 0.029(4) Uani 1 1 d . . .
H18A H 0.9833 1.2313 0.6504 0.035 Uiso 1 1 calc R . .
C19 C 0.571(3) 1.297(3) 0.786(2) 0.045(5) Uiso 1 1 d . . .
O19 O 0.5250(18) 1.1736(18) 0.7746(16) 0.057(4) Uani 1 1 d . . .
O20 O 0.5048(17) 1.417(2) 0.8263(16) 0.068(5) Uani 1 1 d . . .
C21 C 0.382(3) 1.384(3) 0.868(3) 0.076(7) Uani 1 1 d . . .
H21A H 0.3433 1.4736 0.8955 0.113 Uiso 1 1 calc R . .
H21B H 0.4217 1.3551 0.9414 0.113 Uiso 1 1 calc R . .
H21C H 0.2981 1.3008 0.7971 0.113 Uiso 1 1 calc R . .
P2 P 0.8271(6) 1.0831(6) 1.1399(5) 0.0328(13) Uani 1 1 d . . .
C31 C 0.672(2) 1.156(3) 1.1903(19) 0.041(5) Uani 1 1 d . . .
C32 C 0.688(3) 1.219(3) 1.315(2) 0.065(7) Uani 1 1 d . . .
H32A H 0.7825 1.2343 1.3830 0.078 Uiso 1 1 calc R . .
C33 C 0.551(3) 1.264(3) 1.342(2) 0.071(8) Uani 1 1 d . . .
H33A H 0.5541 1.2921 1.4278 0.085 Uiso 1 1 calc R . .
C34 C 0.424(2) 1.265(2) 1.2512(16) 0.050(6) Uani 1 1 d . . .
H34A H 0.3432 1.3025 1.2719 0.060 Uiso 1 1 calc R . .
C35 C 0.418(3) 1.205(3) 1.114(2) 0.082(8) Uani 1 1 d . . .
H35A H 0.3283 1.2029 1.0478 0.099 Uiso 1 1 calc R . .
C36 C 0.530(2) 1.155(3) 1.082(2) 0.056(6) Uani 1 1 d . . .
H36A H 0.5227 1.1193 0.9951 0.067 Uiso 1 1 calc R . .
C37 C 0.999(2) 1.211(3) 1.290(2) 0.053(6) Uani 1 1 d . . .
C38 C 1.037(2) 1.368(2) 1.325(2) 0.048(6) Uani 1 1 d . . .
H38A H 0.9782 1.4063 1.2678 0.058 Uiso 1 1 calc R . .
C39 C 1.158(3) 1.473(3) 1.441(2) 0.062(7) Uani 1 1 d . . .
H39A H 1.1768 1.5784 1.4647 0.074 Uiso 1 1 calc R . .
C40 C 1.247(2) 1.410(2) 1.519(2) 0.046(6) Uani 1 1 d . . .
H40A H 1.3313 1.4744 1.5964 0.055 Uiso 1 1 calc R . .
C41 C 1.216(2) 1.255(3) 1.4850(18) 0.058(7) Uani 1 1 d . . .
H41A H 1.2784 1.2176 1.5416 0.069 Uiso 1 1 calc R . .
C42 C 1.1001(18) 1.155(3) 1.3738(17) 0.037(5) Uani 1 1 d . . .
H42A H 1.0855 1.0500 1.3515 0.044 Uiso 1 1 calc R . .
C43 C 0.8067(19) 0.897(2) 1.1502(17) 0.031(5) Uani 1 1 d . . .
C44 C 0.898(2) 0.792(3) 1.116(2) 0.037(5) Uani 1 1 d . . .
C45 C 0.868(2) 0.6448(19) 1.1158(15) 0.041(5) Uani 1 1 d . . .
H45A H 0.9356 0.5829 1.0977 0.049 Uiso 1 1 calc R . .
C46 C 0.739(3) 0.586(3) 1.143(2) 0.079(8) Uiso 1 1 d . . .
H46A H 0.7116 0.4846 1.1331 0.095 Uiso 1 1 calc R . .
C47 C 0.662(3) 0.685(3) 1.181(2) 0.058(6) Uiso 1 1 d . . .
H47A H 0.5857 0.6592 1.2117 0.070 Uiso 1 1 calc R . .
C48 C 0.691(3) 0.829(3) 1.178(2) 0.060(6) Uani 1 1 d . . .
H48A H 0.6217 0.8878 1.1979 0.072 Uiso 1 1 calc R . .
C49 C 1.029(2) 0.834(2) 1.0797(18) 0.035(5) Uani 1 1 d . . .
O49 O 1.0773(16) 0.9657(19) 1.0931(13) 0.050(4) Uani 1 1 d . . .
O50 O 1.0948(18) 0.7250(16) 1.0372(16) 0.061(4) Uani 1 1 d . . .
C51 C 1.238(3) 0.767(3) 1.012(2) 0.084(8) Uani 1 1 d . . .
H51A H 1.2739 0.6764 0.9795 0.127 Uiso 1 1 calc R . .
H51B H 1.3198 0.8404 1.0929 0.127 Uiso 1 1 calc R . .
H51C H 1.2145 0.8111 0.9479 0.127 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C30 Rh1 P1 91.0(7) . . ?
C30 Rh1 P2 89.0(7) . . ?
P1 Rh1 P2 179.5(3) . . ?
C30 Rh1 Cl1 174.5(6) . . ?
P1 Rh1 Cl1 87.58(19) . . ?
P2 Rh1 Cl1 92.49(18) . . ?
O30 C30 Rh1 155(2) . . ?
C7 P1 C13 105.1(9) . . ?
C7 P1 C1 100.7(8) . . ?
C13 P1 C1 103.8(9) . . ?
C7 P1 Rh1 122.9(6) . . ?
C13 P1 Rh1 113.4(7) . . ?
C1 P1 Rh1 108.7(7) . . ?
C6 C1 C2 113.6(16) . . ?
C6 C1 P1 122.9(14) . . ?
C2 C1 P1 123.4(14) . . ?
C3 C2 C1 123.3(17) . . ?
C2 C3 C4 117.2(15) . . ?
C5 C4 C3 123.3(18) . . ?
C4 C5 C6 116.8(16) . . ?
C1 C6 C5 125.2(15) . . ?
C8 C7 C12 118.2(18) . . ?
C8 C7 P1 117.5(15) . . ?
C12 C7 P1 123.9(15) . . ?
C9 C8 C7 119(2) . . ?
C8 C9 C10 120(2) . . ?
C11 C10 C9 121(2) . . ?
C10 C11 C12 118(2) . . ?
C7 C12 C11 123(2) . . ?
C18 C13 C14 121.5(19) . . ?
C18 C13 P1 116.7(15) . . ?
C14 C13 P1 121.8(15) . . ?
C15 C14 C19 123(2) . . ?
C15 C14 C13 118.5(19) . . ?
C19 C14 C13 119(2) . . ?
C16 C15 C14 122(2) . . ?
C15 C16 C17 120.0(18) . . ?
C18 C17 C16 120.4(19) . . ?
C17 C18 C13 118.0(19) . . ?
O19 C19 O20 125(2) . . ?
O19 C19 C14 127(2) . . ?
O20 C19 C14 108(2) . . ?
C19 O20 C21 114.7(19) . . ?
C31 P2 C37 98.2(10) . . ?
C31 P2 C43 103.4(10) . . ?
C37 P2 C43 104.5(10) . . ?
C31 P2 Rh1 112.3(7) . . ?
C37 P2 Rh1 121.9(7) . . ?
C43 P2 Rh1 114.0(6) . . ?
C32 C31 C36 120.8(19) . . ?
C32 C31 P2 122.8(16) . . ?
C36 C31 P2 116.1(15) . . ?
C31 C32 C33 118(2) . . ?
C34 C33 C32 123.0(18) . . ?
C33 C34 C35 116.6(17) . . ?
C36 C35 C34 123(2) . . ?
C35 C36 C31 118(2) . . ?
C38 C37 C42 116(2) . . ?
C38 C37 P2 120.9(17) . . ?
C42 C37 P2 122.8(19) . . ?
C37 C38 C39 124(2) . . ?
C40 C39 C38 116(2) . . ?
C39 C40 C41 122(2) . . ?
C42 C41 C40 122(2) . . ?
C41 C42 C37 119(2) . . ?
C44 C43 C48 109(2) . . ?
C44 C43 P2 125.0(15) . . ?
C48 C43 P2 125.4(16) . . ?
C43 C44 C45 122.3(18) . . ?
C43 C44 C49 121.0(19) . . ?
C45 C44 C49 116.8(18) . . ?
C44 C45 C46 122.6(18) . . ?
C47 C46 C45 114(2) . . ?
C46 C47 C48 122(2) . . ?
C47 C48 C43 129(2) . . ?
O49 C49 O50 122(2) . . ?
O49 C49 C44 121.7(18) . . ?
O50 C49 C44 116.4(19) . . ?
C49 O50 C51 117.9(18) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 C30 1.8691(11) . ?
Rh1 P1 2.329(5) . ?
Rh1 P2 2.329(5) . ?
Rh1 Cl1 2.4084(11) . ?
C30 O30 1.0989(11) . ?
P1 C7 1.796(18) . ?
P1 C13 1.85(2) . ?
P1 C1 1.82(2) . ?
C1 C6 1.29(3) . ?
C1 C2 1.46(3) . ?
C2 C3 1.30(3) . ?
C3 C4 1.41(3) . ?
C4 C5 1.28(3) . ?
C5 C6 1.43(2) . ?
C7 C8 1.36(3) . ?
C7 C12 1.37(3) . ?
C8 C9 1.38(3) . ?
C9 C10 1.45(3) . ?
C10 C11 1.27(3) . ?
C11 C12 1.41(3) . ?
C13 C18 1.42(3) . ?
C13 C14 1.43(3) . ?
C14 C15 1.36(3) . ?
C14 C19 1.52(3) . ?
C15 C16 1.38(3) . ?
C16 C17 1.44(3) . ?
C17 C18 1.37(3) . ?
C19 O19 1.15(3) . ?
C19 O20 1.37(3) . ?
O20 C21 1.41(3) . ?
P2 C31 1.83(2) . ?
P2 C37 1.85(2) . ?
P2 C43 1.81(2) . ?
C31 C32 1.32(3) . ?
C31 C36 1.50(3) . ?
C32 C33 1.48(3) . ?
C33 C34 1.31(3) . ?
C34 C35 1.48(3) . ?
C35 C36 1.30(3) . ?
C37 C38 1.38(3) . ?
C37 C42 1.42(3) . ?
C38 C39 1.39(3) . ?
C39 C40 1.37(3) . ?
C40 C41 1.36(3) . ?
C41 C42 1.33(2) . ?
C43 C44 1.42(3) . ?
C43 C48 1.37(3) . ?
C44 C45 1.40(3) . ?
C44 C49 1.45(3) . ?
C45 C46 1.43(3) . ?
C46 C47 1.29(3) . ?
C47 C48 1.38(3) . ?
C49 O49 1.23(2) . ?
C49 O50 1.30(2) . ?
O50 C51 1.48(3) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
P1 Rh1 C30 O30 -97(5) . . . . ?
P2 Rh1 C30 O30 83(5) . . . . ?
Cl1 Rh1 C30 O30 -171(4) . . . . ?
C30 Rh1 P1 C7 18.2(10) . . . . ?
P2 Rh1 P1 C7 -69(31) . . . . ?
Cl1 Rh1 P1 C7 -167.1(8) . . . . ?
C30 Rh1 P1 C13 146.3(9) . . . . ?
P2 Rh1 P1 C13 59(31) . . . . ?
Cl1 Rh1 P1 C13 -39.0(7) . . . . ?
C30 Rh1 P1 C1 -98.8(9) . . . . ?
P2 Rh1 P1 C1 174(100) . . . . ?
Cl1 Rh1 P1 C1 75.9(7) . . . . ?
C7 P1 C1 C6 -148.8(17) . . . . ?
C13 P1 C1 C6 102.6(18) . . . . ?
Rh1 P1 C1 C6 -18.4(19) . . . . ?
C7 P1 C1 C2 34.9(17) . . . . ?
C13 P1 C1 C2 -73.7(17) . . . . ?
Rh1 P1 C1 C2 165.3(14) . . . . ?
C6 C1 C2 C3 8(3) . . . . ?
P1 C1 C2 C3 -175.3(15) . . . . ?
C1 C2 C3 C4 -10(3) . . . . ?
C2 C3 C4 C5 7(3) . . . . ?
C3 C4 C5 C6 -1(3) . . . . ?
C2 C1 C6 C5 -2(3) . . . . ?
P1 C1 C6 C5 -178.8(13) . . . . ?
C4 C5 C6 C1 -1(3) . . . . ?
C13 P1 C7 C8 165.4(14) . . . . ?
C1 P1 C7 C8 57.8(15) . . . . ?
Rh1 P1 C7 C8 -63.0(16) . . . . ?
C13 P1 C7 C12 -7.5(19) . . . . ?
C1 P1 C7 C12 -115.1(17) . . . . ?
Rh1 P1 C7 C12 124.1(15) . . . . ?
C12 C7 C8 C9 -5(3) . . . . ?
P1 C7 C8 C9 -178.3(15) . . . . ?
C7 C8 C9 C10 4(3) . . . . ?
C8 C9 C10 C11 -2(3) . . . . ?
C9 C10 C11 C12 0(3) . . . . ?
C8 C7 C12 C11 3(3) . . . . ?
P1 C7 C12 C11 176.2(15) . . . . ?
C10 C11 C12 C7 -1(3) . . . . ?
C7 P1 C13 C18 -101.7(16) . . . . ?
C1 P1 C13 C18 3.6(18) . . . . ?
Rh1 P1 C13 C18 121.4(14) . . . . ?
C7 P1 C13 C14 80.0(18) . . . . ?
C1 P1 C13 C14 -174.7(16) . . . . ?
Rh1 P1 C13 C14 -56.9(18) . . . . ?
C18 C13 C14 C15 -1(3) . . . . ?
P1 C13 C14 C15 177.0(16) . . . . ?
C18 C13 C14 C19 175.7(18) . . . . ?
P1 C13 C14 C19 -6(3) . . . . ?
C19 C14 C15 C16 -174.3(19) . . . . ?
C13 C14 C15 C16 3(3) . . . . ?
C14 C15 C16 C17 -4(3) . . . . ?
C15 C16 C17 C18 4(3) . . . . ?
C16 C17 C18 C13 -3(3) . . . . ?
C14 C13 C18 C17 1(3) . . . . ?
P1 C13 C18 C17 -176.9(15) . . . . ?
C15 C14 C19 O19 170(2) . . . . ?
C13 C14 C19 O19 -7(4) . . . . ?
C15 C14 C19 O20 -7(3) . . . . ?
C13 C14 C19 O20 176.4(17) . . . . ?
O19 C19 O20 C21 7(3) . . . . ?
C14 C19 O20 C21 -176.2(18) . . . . ?
C30 Rh1 P2 C31 -82.0(10) . . . . ?
P1 Rh1 P2 C31 5(31) . . . . ?
Cl1 Rh1 P2 C31 103.3(8) . . . . ?
C30 Rh1 P2 C37 162.1(11) . . . . ?
P1 Rh1 P2 C37 -111(31) . . . . ?
Cl1 Rh1 P2 C37 -12.6(9) . . . . ?
C30 Rh1 P2 C43 35.2(8) . . . . ?
P1 Rh1 P2 C43 122(31) . . . . ?
Cl1 Rh1 P2 C43 -139.5(6) . . . . ?
C37 P2 C31 C32 -28(2) . . . . ?
C43 P2 C31 C32 79(2) . . . . ?
Rh1 P2 C31 C32 -157.4(19) . . . . ?
C37 P2 C31 C36 146.5(18) . . . . ?
C43 P2 C31 C36 -106.4(17) . . . . ?
Rh1 P2 C31 C36 17.0(19) . . . . ?
C36 C31 C32 C33 10(3) . . . . ?
P2 C31 C32 C33 -175.9(17) . . . . ?
C31 C32 C33 C34 -10(4) . . . . ?
C32 C33 C34 C35 6(3) . . . . ?
C33 C34 C35 C36 -1(3) . . . . ?
C34 C35 C36 C31 1(4) . . . . ?
C32 C31 C36 C35 -6(4) . . . . ?
P2 C31 C36 C35 179.6(18) . . . . ?
C31 P2 C37 C38 -64.6(18) . . . . ?
C43 P2 C37 C38 -170.9(17) . . . . ?
Rh1 P2 C37 C38 58.1(19) . . . . ?
C31 P2 C37 C42 116.2(18) . . . . ?
C43 P2 C37 C42 10.0(19) . . . . ?
Rh1 P2 C37 C42 -121.0(15) . . . . ?
C42 C37 C38 C39 -5(3) . . . . ?
P2 C37 C38 C39 175.3(18) . . . . ?
C37 C38 C39 C40 4(3) . . . . ?
C38 C39 C40 C41 -2(4) . . . . ?
C39 C40 C41 C42 2(3) . . . . ?
C40 C41 C42 C37 -3(3) . . . . ?
C38 C37 C42 C41 5(3) . . . . ?
P2 C37 C42 C41 -175.8(15) . . . . ?
C31 P2 C43 C44 177.7(14) . . . . ?
C37 P2 C43 C44 -80.0(16) . . . . ?
Rh1 P2 C43 C44 55.5(15) . . . . ?
C31 P2 C43 C48 5.2(19) . . . . ?
C37 P2 C43 C48 107.5(18) . . . . ?
Rh1 P2 C43 C48 -117.0(17) . . . . ?
C48 C43 C44 C45 -1(3) . . . . ?
P2 C43 C44 C45 -174.7(14) . . . . ?
C48 C43 C44 C49 179.2(18) . . . . ?
P2 C43 C44 C49 6(2) . . . . ?
C43 C44 C45 C46 4(3) . . . . ?
C49 C44 C45 C46 -176.6(19) . . . . ?
C44 C45 C46 C47 -7(3) . . . . ?
C45 C46 C47 C48 9(4) . . . . ?
C46 C47 C48 C43 -7(4) . . . . ?
C44 C43 C48 C47 3(3) . . . . ?
P2 C43 C48 C47 176(2) . . . . ?
C43 C44 C49 O49 9(3) . . . . ?
C45 C44 C49 O49 -170.4(18) . . . . ?
C43 C44 C49 O50 -173.2(16) . . . . ?
C45 C44 C49 O50 7(3) . . . . ?
O49 C49 O50 C51 4(3) . . . . ?
C44 C49 O50 C51 -173.9(18) . . . . ?
