#------------------------------------------------------------------------------
#$Date: 2016-03-25 12:38:46 +0100 (vie 25 de mar de 2016) $
#$Revision: 179855 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/51/7015106.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7015106
loop_
_publ_author_name
'Tong, Hong-Bo'
'Li, Min'
'Bai, Sheng-Di'
'Yuan, Shi-Fang'
'Chao, Jian-Bin'
'Huang, Shuping'
'Liu, Dian-Sheng'
_publ_section_title
;
 A bulky silyl shift-directed synthesis of a silyl-linked
 amidinate-amidine and its Zr(IV) complex.
;
_journal_issue                   16
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              4236
_journal_page_last               4241
_journal_paper_doi               10.1039/c0dt01177k
_journal_volume                  40
_journal_year                    2011
_chemical_formula_sum            'C58 H60 Li2 N10 Si2'
_chemical_formula_weight         967.22
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                115.39(4)
_cell_angle_beta                 97.71(3)
_cell_angle_gamma                105.45(4)
_cell_formula_units_Z            1
_cell_length_a                   10.660(4)
_cell_length_b                   11.667(6)
_cell_length_c                   12.924(7)
_cell_measurement_reflns_used    2434
_cell_measurement_temperature    213(2)
_cell_measurement_theta_max      26.89
_cell_measurement_theta_min      2.34
_cell_volume                     1341.5(13)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      213(2)
_diffrn_measured_fraction_theta_full 0.965
_diffrn_measured_fraction_theta_max 0.965
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0271
_diffrn_reflns_av_sigmaI/netI    0.0575
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_number            6270
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         1.82
_exptl_absorpt_coefficient_mu    0.114
_exptl_absorpt_correction_T_max  0.9831
_exptl_absorpt_correction_T_min  0.9776
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.197
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             512
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.15
_refine_diff_density_max         0.451
_refine_diff_density_min         -0.265
_refine_diff_density_rms         0.057
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.181
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     328
_refine_ls_number_reflns         4618
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.181
_refine_ls_R_factor_all          0.0823
_refine_ls_R_factor_gt           0.0705
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0703P)²+0.5324P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1624
_refine_ls_wR_factor_ref         0.1697
_reflns_number_gt                3819
_reflns_number_total             4570
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c0dt01177k.txt
_cod_data_source_block           s099b
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1555 2011-01-17 13:19:09Z saulius 
;
_cod_original_cell_volume        1341.5(11)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7015106
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Li Li 0.4070(5) 0.5814(5) 0.4990(4) 0.0386(11) Uani 1 1 d . . .
N1 N 0.2632(2) 0.4708(2) 0.3311(2) 0.0322(5) Uani 1 1 d . . .
N2 N 0.1187(2) 0.3272(2) 0.3761(2) 0.0333(5) Uani 1 1 d . . .
H2A H 0.0355 0.2809 0.3642 0.040 Uiso 1 1 calc R . .
N3 N 0.2959(2) 0.5102(2) 0.5985(2) 0.0342(6) Uani 1 1 d . . .
N4 N 0.3820(2) 0.3170(2) 0.4567(2) 0.0316(5) Uani 1 1 d . . .
N5 N 0.5305(2) 0.2113(2) 0.3987(2) 0.0348(6) Uani 1 1 d . . .
Si Si 0.24012(7) 0.33931(8) 0.49135(7) 0.0310(2) Uani 1 1 d . . .
C1 C 0.3049(3) 0.5091(3) 0.2476(2) 0.0316(6) Uani 1 1 d . . .
C2 C 0.3755(3) 0.6466(3) 0.2876(3) 0.0378(7) Uani 1 1 d . . .
H2 H 0.3897 0.7108 0.3664 0.045 Uiso 1 1 calc R . .
C3 C 0.4241(3) 0.6873(3) 0.2107(3) 0.0462(8) Uani 1 1 d . . .
H3 H 0.4703 0.7792 0.2379 0.055 Uiso 1 1 calc R . .
C4 C 0.4052(3) 0.5942(4) 0.0946(3) 0.0500(8) Uani 1 1 d . . .
H4 H 0.4381 0.6229 0.0433 0.060 Uiso 1 1 calc R . .
C5 C 0.3372(3) 0.4578(4) 0.0541(3) 0.0463(8) Uani 1 1 d . . .
H5 H 0.3242 0.3945 -0.0247 0.056 Uiso 1 1 calc R . .
C6 C 0.2883(3) 0.4147(3) 0.1301(3) 0.0386(7) Uani 1 1 d . . .
H6 H 0.2442 0.3224 0.1027 0.046 Uiso 1 1 calc R . .
C7 C 0.1424(3) 0.3833(3) 0.3041(2) 0.0307(6) Uani 1 1 d . . .
C8 C 0.0241(3) 0.3404(3) 0.2023(2) 0.0327(6) Uani 1 1 d . . .
C9 C 0.0048(3) 0.4334(3) 0.1665(3) 0.0379(7) Uani 1 1 d . . .
H9 H 0.0682 0.5216 0.2040 0.045 Uiso 1 1 calc R . .
C10 C -0.1074(3) 0.3947(3) 0.0762(3) 0.0479(8) Uani 1 1 d . . .
H10 H -0.1193 0.4573 0.0531 0.057 Uiso 1 1 calc R . .
C11 C -0.2024(3) 0.2650(4) 0.0194(3) 0.0510(9) Uani 1 1 d . . .
H11 H -0.2775 0.2393 -0.0424 0.061 Uiso 1 1 calc R . .
C12 C -0.1851(3) 0.1729(3) 0.0553(3) 0.0481(8) Uani 1 1 d . . .
H12 H -0.2498 0.0854 0.0184 0.058 Uiso 1 1 calc R . .
C13 C -0.0729(3) 0.2099(3) 0.1452(3) 0.0380(7) Uani 1 1 d . . .
H13 H -0.0618 0.1468 0.1679 0.046 Uiso 1 1 calc R . .
C14 C 0.1403(3) 0.2257(3) 0.5410(3) 0.0472(8) Uani 1 1 d . . .
H14A H 0.1015 0.1342 0.4757 0.071 Uiso 1 1 calc R . .
H14B H 0.0690 0.2558 0.5668 0.071 Uiso 1 1 calc R . .
H14C H 0.1989 0.2285 0.6060 0.071 Uiso 1 1 calc R . .
C15 C 0.3924(4) 0.5527(4) 0.7119(3) 0.0531(9) Uani 1 1 d . . .
H15A H 0.4396 0.6494 0.7520 0.080 Uiso 1 1 calc R . .
H15B H 0.4567 0.5078 0.6964 0.080 Uiso 1 1 calc R . .
H15C H 0.3442 0.5285 0.7615 0.080 Uiso 1 1 calc R . .
C16 C 0.1935(3) 0.5734(3) 0.6211(3) 0.0470(8) Uani 1 1 d . . .
H16A H 0.1308 0.5293 0.6512 0.071 Uiso 1 1 calc R . .
H16B H 0.1452 0.5642 0.5480 0.071 Uiso 1 1 calc R . .
H16C H 0.2374 0.6682 0.6789 0.071 Uiso 1 1 calc R . .
C17 C 0.4033(3) 0.2022(3) 0.3928(2) 0.0311(6) Uani 1 1 d . . .
C18 C 0.2847(3) 0.0691(3) 0.3258(2) 0.0340(7) Uani 1 1 d . . .
C19 C 0.1779(3) 0.0481(3) 0.2384(3) 0.0437(8) Uani 1 1 d . . .
H19 H 0.1827 0.1136 0.2146 0.052 Uiso 1 1 calc R . .
C20 C 0.0635(3) -0.0694(4) 0.1856(3) 0.0566(9) Uani 1 1 d . . .
H20 H -0.0073 -0.0832 0.1259 0.068 Uiso 1 1 calc R . .
C21 C 0.0543(4) -0.1666(4) 0.2218(4) 0.0644(11) Uani 1 1 d . . .
H21 H -0.0237 -0.2442 0.1884 0.077 Uiso 1 1 calc R . .
C22 C 0.1607(4) -0.1476(4) 0.3070(4) 0.0630(10) Uani 1 1 d . . .
H22 H 0.1553 -0.2130 0.3309 0.076 Uiso 1 1 calc R . .
C23 C 0.2772(3) -0.0308(3) 0.3583(3) 0.0479(8) Uani 1 1 d . . .
H23 H 0.3502 -0.0199 0.4145 0.057 Uiso 1 1 calc R . .
C24 C 0.5709(3) 0.1098(3) 0.3208(3) 0.0352(7) Uani 1 1 d . . .
C25 C 0.5131(3) 0.0366(3) 0.1970(3) 0.0384(7) Uani 1 1 d . . .
H25 H 0.4372 0.0474 0.1634 0.046 Uiso 1 1 calc R . .
C26 C 0.5670(3) -0.0515(3) 0.1234(3) 0.0467(8) Uani 1 1 d . . .
H26 H 0.5270 -0.0991 0.0412 0.056 Uiso 1 1 calc R . .
C27 C 0.6786(4) -0.0694(3) 0.1706(4) 0.0537(9) Uani 1 1 d . . .
H27 H 0.7140 -0.1294 0.1208 0.064 Uiso 1 1 calc R . .
C28 C 0.7376(3) 0.0017(3) 0.2916(4) 0.0537(9) Uani 1 1 d . . .
H28 H 0.8139 -0.0096 0.3238 0.064 Uiso 1 1 calc R . .
C29 C 0.6846(3) 0.0908(3) 0.3668(3) 0.0450(8) Uani 1 1 d . . .
H29 H 0.7257 0.1382 0.4488 0.054 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Li Li -0.0003 0.0001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N5 Li N1 123.1(3) 2_666 . ?
N5 Li N4 66.18(17) 2_666 2_666 ?
N1 Li N4 128.9(3) . 2_666 ?
N5 Li N3 102.6(2) 2_666 . ?
N1 Li N3 100.2(2) . . ?
N4 Li N3 128.3(3) 2_666 . ?
N5 Li C17 32.90(11) 2_666 2_666 ?
N1 Li C17 136.1(3) . 2_666 ?
N4 Li C17 33.35(11) 2_666 2_666 ?
N3 Li C17 118.5(2) . 2_666 ?
N5 Li Li 123.3(3) 2_666 2_666 ?
N1 Li Li 107.1(3) . 2_666 ?
N4 Li Li 62.32(17) 2_666 2_666 ?
N3 Li Li 91.6(2) . 2_666 ?
C17 Li Li 92.5(2) 2_666 2_666 ?
C7 N1 C1 121.1(2) . . ?
C7 N1 Li 125.9(2) . . ?
C1 N1 Li 112.8(2) . . ?
C7 N2 Si 127.16(19) . . ?
C7 N2 H2A 116.4 . . ?
Si N2 H2A 116.4 . . ?
C16 N3 C15 110.1(2) . . ?
C16 N3 Si 117.6(2) . . ?
C15 N3 Si 116.7(2) . . ?
C16 N3 Li 108.3(2) . . ?
C15 N3 Li 107.5(2) . . ?
Si N3 Li 94.78(17) . . ?
C17 N4 Si 129.89(19) . . ?
C17 N4 Li 86.7(2) . 2_666 ?
Si N4 Li 142.62(19) . 2_666 ?
C17 N5 C24 124.9(2) . . ?
C17 N5 Li 89.6(2) . 2_666 ?
C24 N5 Li 141.4(2) . 2_666 ?
N4 Si N3 103.99(12) . . ?
N4 Si N2 114.90(12) . . ?
N3 Si N2 102.90(12) . . ?
N4 Si C14 117.91(14) . . ?
N3 Si C14 112.30(14) . . ?
N2 Si C14 104.03(14) . . ?
C6 C1 C2 118.7(3) . . ?
C6 C1 N1 122.7(3) . . ?
C2 C1 N1 118.3(3) . . ?
C3 C2 C1 120.2(3) . . ?
C3 C2 H2 119.9 . . ?
C1 C2 H2 119.9 . . ?
C4 C3 C2 120.8(3) . . ?
C4 C3 H3 119.6 . . ?
C2 C3 H3 119.6 . . ?
C3 C4 C5 119.7(3) . . ?
C3 C4 H4 120.1 . . ?
C5 C4 H4 120.1 . . ?
C4 C5 C6 120.4(3) . . ?
C4 C5 H5 119.8 . . ?
C6 C5 H5 119.8 . . ?
C5 C6 C1 120.2(3) . . ?
C5 C6 H6 119.9 . . ?
C1 C6 H6 119.9 . . ?
N1 C7 N2 118.0(2) . . ?
N1 C7 C8 126.0(2) . . ?
N2 C7 C8 116.0(2) . . ?
C13 C8 C9 118.5(3) . . ?
C13 C8 C7 120.9(3) . . ?
C9 C8 C7 120.5(2) . . ?
C10 C9 C8 120.1(3) . . ?
C10 C9 H9 119.9 . . ?
C8 C9 H9 119.9 . . ?
C9 C10 C11 121.0(3) . . ?
C9 C10 H10 119.5 . . ?
C11 C10 H10 119.5 . . ?
C10 C11 C12 119.2(3) . . ?
C10 C11 H11 120.4 . . ?
C12 C11 H11 120.4 . . ?
C13 C12 C11 120.4(3) . . ?
C13 C12 H12 119.8 . . ?
C11 C12 H12 119.8 . . ?
C12 C13 C8 120.7(3) . . ?
C12 C13 H13 119.7 . . ?
C8 C13 H13 119.7 . . ?
Si C14 H14A 109.5 . . ?
Si C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
Si C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
N3 C15 H15A 109.5 . . ?
N3 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
N3 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
N3 C16 H16A 109.5 . . ?
N3 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
N3 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
N5 C17 N4 117.2(2) . . ?
N5 C17 C18 123.2(2) . . ?
N4 C17 C18 119.4(2) . . ?
N5 C17 Li 57.47(18) . 2_666 ?
N4 C17 Li 59.94(18) . 2_666 ?
C18 C17 Li 179.3(2) . 2_666 ?
C19 C18 C23 118.9(3) . . ?
C19 C18 C17 121.3(3) . . ?
C23 C18 C17 119.6(3) . . ?
C18 C19 C20 120.7(3) . . ?
C18 C19 H19 119.7 . . ?
C20 C19 H19 119.7 . . ?
C19 C20 C21 120.1(3) . . ?
C19 C20 H20 119.9 . . ?
C21 C20 H20 119.9 . . ?
C22 C21 C20 119.5(3) . . ?
C22 C21 H21 120.2 . . ?
C20 C21 H21 120.2 . . ?
C21 C22 C23 120.4(4) . . ?
C21 C22 H22 119.8 . . ?
C23 C22 H22 119.8 . . ?
C18 C23 C22 120.2(3) . . ?
C18 C23 H23 119.9 . . ?
C22 C23 H23 119.9 . . ?
C29 C24 C25 117.4(3) . . ?
C29 C24 N5 118.5(3) . . ?
C25 C24 N5 123.7(3) . . ?
C26 C25 C24 121.0(3) . . ?
C26 C25 H25 119.5 . . ?
C24 C25 H25 119.5 . . ?
C27 C26 C25 120.6(3) . . ?
C27 C26 H26 119.7 . . ?
C25 C26 H26 119.7 . . ?
C28 C27 C26 119.4(3) . . ?
C28 C27 H27 120.3 . . ?
C26 C27 H27 120.3 . . ?
C27 C28 C29 120.6(3) . . ?
C27 C28 H28 119.7 . . ?
C29 C28 H28 119.7 . . ?
C24 C29 C28 120.8(3) . . ?
C24 C29 H29 119.6 . . ?
C28 C29 H29 119.6 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Li N5 2.051(5) 2_666 ?
Li N1 2.092(5) . ?
Li N4 2.109(5) 2_666 ?
Li N3 2.131(5) . ?
Li C17 2.432(6) 2_666 ?
Li Li 3.094(10) 2_666 ?
N1 C7 1.302(3) . ?
N1 C1 1.413(4) . ?
N2 C7 1.362(4) . ?
N2 Si 1.765(3) . ?
N2 H2A 0.8600 . ?
N3 C16 1.466(4) . ?
N3 C15 1.468(4) . ?
N3 Si 1.740(3) . ?
N4 C17 1.339(3) . ?
N4 Si 1.687(2) . ?
N4 Li 2.109(5) 2_666 ?
N5 C17 1.321(3) . ?
N5 C24 1.403(4) . ?
N5 Li 2.051(5) 2_666 ?
Si C14 1.860(3) . ?
C1 C6 1.393(4) . ?
C1 C2 1.395(4) . ?
C2 C3 1.377(4) . ?
C2 H2 0.9300 . ?
C3 C4 1.370(5) . ?
C3 H3 0.9300 . ?
C4 C5 1.380(5) . ?
C4 H4 0.9300 . ?
C5 C6 1.382(4) . ?
C5 H5 0.9300 . ?
C6 H6 0.9300 . ?
C7 C8 1.492(4) . ?
C8 C13 1.388(4) . ?
C8 C9 1.398(4) . ?
C9 C10 1.373(4) . ?
C9 H9 0.9300 . ?
C10 C11 1.373(5) . ?
C10 H10 0.9300 . ?
C11 C12 1.383(5) . ?
C11 H11 0.9300 . ?
C12 C13 1.374(4) . ?
C12 H12 0.9300 . ?
C13 H13 0.9300 . ?
C14 H14A 0.9600 . ?
C14 H14B 0.9600 . ?
C14 H14C 0.9600 . ?
C15 H15A 0.9600 . ?
C15 H15B 0.9600 . ?
C15 H15C 0.9600 . ?
C16 H16A 0.9600 . ?
C16 H16B 0.9600 . ?
C16 H16C 0.9600 . ?
C17 C18 1.505(4) . ?
C17 Li 2.432(6) 2_666 ?
C18 C19 1.379(4) . ?
C18 C23 1.386(4) . ?
C19 C20 1.384(5) . ?
C19 H19 0.9300 . ?
C20 C21 1.387(6) . ?
C20 H20 0.9300 . ?
C21 C22 1.367(6) . ?
C21 H21 0.9300 . ?
C22 C23 1.393(5) . ?
C22 H22 0.9300 . ?
C23 H23 0.9300 . ?
C24 C29 1.390(4) . ?
C24 C25 1.398(4) . ?
C25 C26 1.384(4) . ?
C25 H25 0.9300 . ?
C26 C27 1.371(5) . ?
C26 H26 0.9300 . ?
C27 C28 1.369(5) . ?
C27 H27 0.9300 . ?
C28 C29 1.393(5) . ?
C28 H28 0.9300 . ?
C29 H29 0.9300 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N5 Li N1 C7 -113.5(3) 2_666 . . . ?
N4 Li N1 C7 161.8(3) 2_666 . . . ?
N3 Li N1 C7 -1.0(3) . . . . ?
C17 Li N1 C7 -153.4(3) 2_666 . . . ?
Li Li N1 C7 93.9(3) 2_666 . . . ?
N5 Li N1 C1 61.1(3) 2_666 . . . ?
N4 Li N1 C1 -23.6(4) 2_666 . . . ?
N3 Li N1 C1 173.6(2) . . . . ?
C17 Li N1 C1 21.2(4) 2_666 . . . ?
Li Li N1 C1 -91.5(3) 2_666 . . . ?
N5 Li N3 C16 53.2(3) 2_666 . . . ?
N1 Li N3 C16 -74.3(3) . . . . ?
N4 Li N3 C16 122.7(3) 2_666 . . . ?
C17 Li N3 C16 84.2(3) 2_666 . . . ?
Li Li N3 C16 177.9(2) 2_666 . . . ?
N5 Li N3 C15 -65.7(3) 2_666 . . . ?
N1 Li N3 C15 166.8(2) . . . . ?
N4 Li N3 C15 3.8(4) 2_666 . . . ?
C17 Li N3 C15 -34.7(3) 2_666 . . . ?
Li Li N3 C15 59.0(3) 2_666 . . . ?
N5 Li N3 Si 174.36(18) 2_666 . . . ?
N1 Li N3 Si 46.8(2) . . . . ?
N4 Li N3 Si -116.2(3) 2_666 . . . ?
C17 Li N3 Si -154.7(2) 2_666 . . . ?
Li Li N3 Si -60.9(2) 2_666 . . . ?
C17 N4 Si N3 169.0(2) . . . . ?
Li N4 Si N3 2.9(3) 2_666 . . . ?
C17 N4 Si N2 -79.3(3) . . . . ?
Li N4 Si N2 114.6(3) 2_666 . . . ?
C17 N4 Si C14 43.9(3) . . . . ?
Li N4 Si C14 -122.2(3) 2_666 . . . ?
C16 N3 Si N4 161.7(2) . . . . ?
C15 N3 Si N4 -64.2(2) . . . . ?
Li N3 Si N4 48.15(18) . . . . ?
C16 N3 Si N2 41.5(2) . . . . ?
C15 N3 Si N2 175.7(2) . . . . ?
Li N3 Si N2 -72.00(17) . . . . ?
C16 N3 Si C14 -69.8(3) . . . . ?
C15 N3 Si C14 64.4(2) . . . . ?
Li N3 Si C14 176.74(18) . . . . ?
C7 N2 Si N4 -44.1(3) . . . . ?
C7 N2 Si N3 68.2(2) . . . . ?
C7 N2 Si C14 -174.5(2) . . . . ?
C7 N1 C1 C6 -48.7(4) . . . . ?
Li N1 C1 C6 136.5(3) . . . . ?
C7 N1 C1 C2 136.7(3) . . . . ?
Li N1 C1 C2 -38.2(3) . . . . ?
C6 C1 C2 C3 1.8(4) . . . . ?
N1 C1 C2 C3 176.6(3) . . . . ?
C1 C2 C3 C4 -0.6(5) . . . . ?
C2 C3 C4 C5 -0.3(5) . . . . ?
C3 C4 C5 C6 -0.1(5) . . . . ?
C4 C5 C6 C1 1.3(4) . . . . ?
C2 C1 C6 C5 -2.1(4) . . . . ?
N1 C1 C6 C5 -176.7(3) . . . . ?
C1 N1 C7 N2 165.2(2) . . . . ?
Li N1 C7 N2 -20.6(4) . . . . ?
C1 N1 C7 C8 -16.7(4) . . . . ?
Li N1 C7 C8 157.4(3) . . . . ?
Si N2 C7 N1 -10.4(4) . . . . ?
Si N2 C7 C8 171.36(18) . . . . ?
N1 C7 C8 C13 148.4(3) . . . . ?
N2 C7 C8 C13 -33.5(4) . . . . ?
N1 C7 C8 C9 -35.0(4) . . . . ?
N2 C7 C8 C9 143.1(3) . . . . ?
C13 C8 C9 C10 -0.5(4) . . . . ?
C7 C8 C9 C10 -177.2(3) . . . . ?
C8 C9 C10 C11 0.0(5) . . . . ?
C9 C10 C11 C12 0.9(5) . . . . ?
C10 C11 C12 C13 -1.2(5) . . . . ?
C11 C12 C13 C8 0.7(5) . . . . ?
C9 C8 C13 C12 0.1(4) . . . . ?
C7 C8 C13 C12 176.8(3) . . . . ?
C24 N5 C17 N4 -166.3(3) . . . . ?
Li N5 C17 N4 -4.8(3) 2_666 . . . ?
C24 N5 C17 C18 18.1(4) . . . . ?
Li N5 C17 C18 179.7(3) 2_666 . . . ?
C24 N5 C17 Li -161.5(3) . . . 2_666 ?
Si N4 C17 N5 -167.0(2) . . . . ?
Li N4 C17 N5 4.7(3) 2_666 . . . ?
Si N4 C17 C18 8.8(4) . . . . ?
Li N4 C17 C18 -179.6(3) 2_666 . . . ?
Si N4 C17 Li -171.6(3) . . . 2_666 ?
N5 C17 C18 C19 -124.7(3) . . . . ?
N4 C17 C18 C19 59.9(4) . . . . ?
Li C17 C18 C19 32(19) 2_666 . . . ?
N5 C17 C18 C23 60.3(4) . . . . ?
N4 C17 C18 C23 -115.1(3) . . . . ?
Li C17 C18 C23 -143(19) 2_666 . . . ?
C23 C18 C19 C20 1.4(4) . . . . ?
C17 C18 C19 C20 -173.6(3) . . . . ?
C18 C19 C20 C21 1.1(5) . . . . ?
C19 C20 C21 C22 -2.1(5) . . . . ?
C20 C21 C22 C23 0.7(6) . . . . ?
C19 C18 C23 C22 -2.9(5) . . . . ?
C17 C18 C23 C22 172.2(3) . . . . ?
C21 C22 C23 C18 1.9(5) . . . . ?
C17 N5 C24 C29 -143.8(3) . . . . ?
Li N5 C24 C29 66.7(5) 2_666 . . . ?
C17 N5 C24 C25 43.8(4) . . . . ?
Li N5 C24 C25 -105.7(4) 2_666 . . . ?
C29 C24 C25 C26 0.3(4) . . . . ?
N5 C24 C25 C26 172.8(3) . . . . ?
C24 C25 C26 C27 0.1(4) . . . . ?
C25 C26 C27 C28 -0.5(5) . . . . ?
C26 C27 C28 C29 0.5(5) . . . . ?
C25 C24 C29 C28 -0.3(4) . . . . ?
N5 C24 C29 C28 -173.1(3) . . . . ?
C27 C28 C29 C24 -0.1(5) . . . . ?
