#------------------------------------------------------------------------------
#$Date: 2016-03-25 12:56:31 +0100 (vie 25 de mar de 2016) $
#$Revision: 179871 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/67/7016769.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7016769
loop_
_publ_author_name
'Wang, Li-Feng'
'Kang, Ling-Chen'
'Zhang, Wen-Wei'
'Wang, Fang-Ming'
'Ren, Xiao-Ming'
'Meng, Qing-Jin'
_publ_section_title
;
 New europium coordination polymers with efficient energy transfer from
 conjugated tetracarboxylate ligands to Eu(3+) ion: syntheses,
 structures, luminescence and magnetic properties.
;
_journal_issue                   37
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              9490
_journal_page_last               9497
_journal_paper_doi               10.1039/c1dt10693g
_journal_volume                  40
_journal_year                    2011
_chemical_formula_moiety         'C33 H41 Eu2 N7 O19, C3 H7 N O'
_chemical_formula_sum            'C36 H48 Eu2 N8 O20'
_chemical_formula_weight         1216.76
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 110.731(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   13.989(3)
_cell_length_b                   16.567(3)
_cell_length_c                   21.933(3)
_cell_measurement_reflns_used    2947
_cell_measurement_temperature    291(2)
_cell_measurement_theta_max      26.88
_cell_measurement_theta_min      2.45
_cell_volume                     4754.0(15)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      291(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0868
_diffrn_reflns_av_sigmaI/netI    0.1276
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            25464
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         1.96
_exptl_absorpt_coefficient_mu    2.697
_exptl_absorpt_correction_T_max  0.7045
_exptl_absorpt_correction_T_min  0.6290
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS,2000; Bruker'
_exptl_crystal_density_diffrn    1.700
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2424
_exptl_crystal_size_max          0.19
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.14
_refine_diff_density_max         1.334
_refine_diff_density_min         -1.236
_refine_diff_density_rms         0.161
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.004
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     685
_refine_ls_number_reflns         9310
_refine_ls_number_restraints     58
_refine_ls_restrained_S_all      1.004
_refine_ls_R_factor_all          0.1205
_refine_ls_R_factor_gt           0.0577
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0280P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1250
_refine_ls_wR_factor_ref         0.1425
_reflns_number_gt                5307
_reflns_number_total             9310
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c1dt10693g.txt
_cod_data_source_block           1
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'Multi-Scan'
changed to 'multi-scan' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7016769
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.75588(3) 0.75751(3) 0.833366(19) 0.03175(15) Uani 1 1 d . . .
Eu2 Eu 0.43952(3) 0.76684(3) 1.083278(19) 0.02865(14) Uani 1 1 d . . .
C1 C 0.5006(7) 0.7267(6) 0.7539(4) 0.037(2) Uani 1 1 d . . .
C2 C 0.4220(7) 0.7462(5) 0.7837(4) 0.035(2) Uani 1 1 d . . .
C3 C 0.3223(7) 0.7547(5) 0.7443(5) 0.039(2) Uani 1 1 d . . .
H3 H 0.3050 0.7498 0.6994 0.046 Uiso 1 1 calc R . .
C4 C 0.4470(7) 0.7537(5) 0.8509(4) 0.033(2) Uani 1 1 d . . .
H4 H 0.5144 0.7465 0.8785 0.040 Uiso 1 1 calc R . .
C5 C 0.3731(7) 0.7715(6) 0.8769(4) 0.035(2) Uani 1 1 d . B .
C6 C 0.3978(7) 0.7752(6) 0.9490(4) 0.037(2) Uani 1 1 d . . .
C7 C 0.2716(7) 0.7807(6) 0.8361(4) 0.039(2) Uani 1 1 d . . .
H7 H 0.2219 0.7937 0.8535 0.047 Uiso 1 1 calc R B .
C8 C 0.2452(7) 0.7706(6) 0.7696(5) 0.041(2) Uani 1 1 d . B .
C9 C 0.1407(8) 0.7727(6) 0.7273(5) 0.046(3) Uani 1 1 d . . .
C10 C 0.0542(8) 0.7701(6) 0.6902(5) 0.047(3) Uani 1 1 d . B .
C11 C -0.0520(7) 0.7682(6) 0.6473(5) 0.042(2) Uani 1 1 d . . .
C12 C -0.1292(7) 0.7774(6) 0.6736(4) 0.037(2) Uani 1 1 d . B .
H12 H -0.1118 0.7827 0.7185 0.045 Uiso 1 1 calc R . .
C13 C -0.2304(6) 0.7787(5) 0.6338(4) 0.030(2) Uani 1 1 d . . .
C14 C -0.3102(6) 0.7920(5) 0.6644(4) 0.029(2) Uani 1 1 d . B .
C15 C -0.2564(7) 0.7699(5) 0.5676(4) 0.031(2) Uani 1 1 d . B .
H15 H -0.3246 0.7727 0.5405 0.037 Uiso 1 1 calc R . .
C16 C -0.1809(7) 0.7567(5) 0.5409(4) 0.034(2) Uani 1 1 d . . .
C17 C -0.0796(7) 0.7574(5) 0.5806(4) 0.038(2) Uani 1 1 d . B .
H17 H -0.0292 0.7505 0.5626 0.046 Uiso 1 1 calc R . .
C18 C -0.2059(8) 0.7487(6) 0.4688(5) 0.040(2) Uani 1 1 d . . .
C19 C 0.6035(12) 0.9151(9) 0.7831(7) 0.080(4) Uani 1 1 d . . .
H19 H 0.6152 0.9145 0.7439 0.096 Uiso 1 1 calc R . .
C20 C 0.4970(11) 0.9571(8) 0.8394(7) 0.098(5) Uani 1 1 d . . .
H20A H 0.5485 0.9314 0.8754 0.146 Uiso 1 1 calc R . .
H20B H 0.4334 0.9288 0.8296 0.146 Uiso 1 1 calc R . .
H20C H 0.4887 1.0120 0.8506 0.146 Uiso 1 1 calc R . .
C21 C 0.4633(12) 1.0004(9) 0.7308(7) 0.109(5) Uani 1 1 d . . .
H21A H 0.4920 1.0000 0.6970 0.163 Uiso 1 1 calc R . .
H21B H 0.4582 1.0550 0.7439 0.163 Uiso 1 1 calc R . .
H21C H 0.3965 0.9764 0.7148 0.163 Uiso 1 1 calc R . .
C22 C 0.6399(9) 0.9006(7) 1.1174(6) 0.059(3) Uani 1 1 d U . .
H22 H 0.6739 0.8891 1.1613 0.071 Uiso 1 1 calc R B .
C23 C 0.6461(10) 0.9537(8) 1.0164(6) 0.085(4) Uani 1 1 d U . .
H23A H 0.5926 0.9151 0.9972 0.128 Uiso 1 1 calc R B .
H23B H 0.6995 0.9461 0.9990 0.128 Uiso 1 1 calc R . .
H23C H 0.6190 1.0073 1.0067 0.128 Uiso 1 1 calc R . .
C24 C 0.7886(10) 0.9725(8) 1.1189(6) 0.087(4) Uani 1 1 d U . .
H24A H 0.8041 0.9719 1.1652 0.130 Uiso 1 1 calc R B .
H24B H 0.7930 1.0268 1.1049 0.130 Uiso 1 1 calc R . .
H24C H 0.8366 0.9391 1.1083 0.130 Uiso 1 1 calc R . .
C31 C 0.4522(10) 0.5639(7) 1.0664(6) 0.061(2) Uani 1 1 d U . .
H31 H 0.5211 0.5651 1.0924 0.073 Uiso 1 1 calc R B .
C32 C 0.3072(9) 0.4848(7) 1.0052(6) 0.072(3) Uani 1 1 d U . .
H32A H 0.2737 0.5363 1.0003 0.109 Uiso 1 1 calc R B .
H32B H 0.2732 0.4468 1.0236 0.109 Uiso 1 1 calc R . .
H32C H 0.3050 0.4659 0.9633 0.109 Uiso 1 1 calc R . .
C33 C 0.4673(10) 0.4189(7) 1.0701(6) 0.077(3) Uani 1 1 d U . .
H33A H 0.5365 0.4315 1.0967 0.116 Uiso 1 1 calc R B .
H33B H 0.4671 0.3873 1.0333 0.116 Uiso 1 1 calc R . .
H33C H 0.4357 0.3887 1.0952 0.116 Uiso 1 1 calc R . .
C34 C 0.215(2) 0.4934(14) 0.8023(11) 0.139(8) Uani 1 1 d . . .
H34 H 0.2034 0.4499 0.7738 0.167 Uiso 1 1 calc R . .
C35 C 0.1310(16) 0.5964(12) 0.8391(10) 0.158(8) Uani 1 1 d D . .
H35A H 0.1137 0.5806 0.8761 0.237 Uiso 1 1 calc R . .
H35B H 0.0804 0.6332 0.8125 0.237 Uiso 1 1 calc R . .
H35C H 0.1967 0.6223 0.8539 0.237 Uiso 1 1 calc R . .
C36 C 0.0369(16) 0.5033(12) 0.7647(9) 0.159(9) Uani 1 1 d D . .
H36A H 0.0429 0.4642 0.7339 0.238 Uiso 1 1 calc R . .
H36B H -0.0030 0.5483 0.7417 0.238 Uiso 1 1 calc R . .
H36C H 0.0039 0.4789 0.7917 0.238 Uiso 1 1 calc R . .
N1 N 0.9569(8) 0.8250(8) 0.8534(4) 0.060(3) Uani 1 1 d . . .
N2 N 0.7955(8) 0.5862(7) 0.8146(6) 0.070(3) Uani 1 1 d . . .
N3 N 0.5266(10) 0.9559(7) 0.7847(6) 0.081(3) Uani 1 1 d . . .
N4 N 0.6871(8) 0.9422(6) 1.0865(5) 0.068(3) Uani 1 1 d U B .
N7 N 0.4110(7) 0.4931(6) 1.0474(5) 0.062(2) Uani 1 1 d U B .
N8 N 0.1343(15) 0.5299(11) 0.8036(9) 0.130(6) Uani 1 1 d D . .
O1 O 0.4711(5) 0.7241(4) 0.6935(3) 0.0441(17) Uani 1 1 d . . .
O2 O 0.5886(5) 0.7086(4) 0.7913(3) 0.0429(17) Uani 1 1 d . . .
O3 O 0.4880(5) 0.7596(4) 0.9857(3) 0.0416(17) Uani 1 1 d . B .
O4 O 0.3313(5) 0.7967(4) 0.9714(3) 0.0439(17) Uani 1 1 d . B .
O5 O -0.2803(4) 0.7975(4) 0.7249(3) 0.0328(14) Uani 1 1 d . . .
O6 O -0.4015(4) 0.7970(4) 0.6263(3) 0.0310(14) Uani 1 1 d . . .
O7 O -0.2952(5) 0.7579(4) 0.4300(3) 0.0462(18) Uani 1 1 d . . .
O8 O -0.1359(5) 0.7293(4) 0.4480(3) 0.0513(19) Uani 1 1 d . . .
O9 O 0.8843(7) 0.8698(5) 0.8467(4) 0.069(2) Uani 1 1 d . . .
O10 O 0.9401(5) 0.7531(5) 0.8417(3) 0.055(2) Uani 1 1 d . . .
O11 O 1.0473(7) 0.8529(7) 0.8726(5) 0.115(4) Uani 1 1 d . . .
O12 O 0.7963(7) 0.6120(5) 0.8689(4) 0.078(3) Uani 1 1 d . . .
O13 O 0.7814(6) 0.6376(5) 0.7711(4) 0.063(2) Uani 1 1 d . . .
O14 O 0.8109(10) 0.5156(7) 0.8056(5) 0.126(4) Uani 1 1 d . . .
O15 O 0.6627(7) 0.8770(5) 0.8283(4) 0.071(2) Uani 1 1 d . . .
O16 O 0.5520(6) 0.8757(4) 1.0908(3) 0.0542(19) Uani 1 1 d U B .
O17 O 0.3447(7) 0.8868(5) 1.0921(4) 0.064(2) Uani 1 1 d D B .
O18 O 0.2715(5) 0.7239(5) 1.0831(3) 0.0503(19) Uani 1 1 d . A .
O19 O 0.4075(6) 0.6288(5) 1.0527(4) 0.0607(18) Uani 1 1 d U B .
O20 O 0.2995(10) 0.5077(9) 0.8321(7) 0.139(5) Uani 1 1 d . . .
C28A C 0.1944(14) 0.7075(12) 1.0329(9) 0.037(5) Uani 0.533(17) 1 d P A 1
H28A H 0.1828 0.7351 0.9941 0.044 Uiso 0.533(17) 1 calc PR A 1
C29A C 0.1532(18) 0.5951(13) 1.0923(11) 0.063(7) Uani 0.533(17) 1 d P A 1
H29A H 0.2115 0.6144 1.1277 0.095 Uiso 0.533(17) 1 calc PR A 1
H29B H 0.1674 0.5423 1.0797 0.095 Uiso 0.533(17) 1 calc PR A 1
H29C H 0.0952 0.5925 1.1060 0.095 Uiso 0.533(17) 1 calc PR A 1
C30A C 0.0439(17) 0.6256(14) 0.9779(11) 0.059(7) Uani 0.533(17) 1 d P A 1
H30A H 0.0470 0.6545 0.9407 0.088 Uiso 0.533(17) 1 calc PR A 1
H30B H -0.0193 0.6377 0.9839 0.088 Uiso 0.533(17) 1 calc PR A 1
H30C H 0.0477 0.5687 0.9709 0.088 Uiso 0.533(17) 1 calc PR A 1
N6A N 0.131(12) 0.650(13) 1.037(8) 0.038(15) Uani 0.533(17) 1 d P A 1
C28B C 0.2136(19) 0.6652(15) 1.0812(12) 0.049(7) Uani 0.467(17) 1 d P A 2
H28B H 0.2235 0.6348 1.1186 0.059 Uiso 0.467(17) 1 calc PR A 2
C29B C 0.108(2) 0.7007(18) 0.9713(12) 0.073(9) Uani 0.467(17) 1 d P A 2
H29D H 0.1213 0.7551 0.9871 0.110 Uiso 0.467(17) 1 calc PR A 2
H29E H 0.0371 0.6943 0.9462 0.110 Uiso 0.467(17) 1 calc PR A 2
H29F H 0.1479 0.6892 0.9442 0.110 Uiso 0.467(17) 1 calc PR A 2
C30B C 0.067(2) 0.5795(18) 1.0266(15) 0.080(10) Uani 0.467(17) 1 d P A 2
H30D H 0.0917 0.5537 1.0685 0.120 Uiso 0.467(17) 1 calc PR A 2
H30E H 0.0639 0.5408 0.9933 0.120 Uiso 0.467(17) 1 calc PR A 2
H30F H -0.0001 0.6009 1.0188 0.120 Uiso 0.467(17) 1 calc PR A 2
N6B N 0.137(15) 0.646(15) 1.025(9) 0.05(3) Uani 0.467(17) 1 d P A 2
C25A C 0.2542(14) 0.8941(13) 1.0597(11) 0.070(8) Uani 0.58(2) 1 d PD B 3
H25A H 0.2300 0.8773 1.0164 0.084 Uiso 0.58(2) 1 calc PR B 3
C26A C 0.209(2) 0.9334(15) 1.1554(11) 0.079(8) Uani 0.58(2) 1 d PD B 3
H26A H 0.2756 0.9113 1.1777 0.119 Uiso 0.58(2) 1 calc PR B 3
H26B H 0.1592 0.9037 1.1672 0.119 Uiso 0.58(2) 1 calc PR B 3
H26C H 0.2077 0.9890 1.1674 0.119 Uiso 0.58(2) 1 calc PR B 3
C27A C 0.0832(18) 0.9366(15) 1.0434(12) 0.081(8) Uani 0.58(2) 1 d PD B 3
H27A H 0.0831 0.9604 1.0035 0.121 Uiso 0.58(2) 1 calc PR B 3
H27B H 0.0464 0.9708 1.0628 0.121 Uiso 0.58(2) 1 calc PR B 3
H27C H 0.0509 0.8846 1.0345 0.121 Uiso 0.58(2) 1 calc PR B 3
N5A N 0.186(3) 0.928(9) 1.0871(11) 0.07(2) Uani 0.58(2) 1 d PD B 3
C25B C 0.293(2) 0.9004(17) 1.1250(13) 0.067(10) Uani 0.42(2) 1 d PD B 4
H25B H 0.3216 0.9034 1.1702 0.080 Uiso 0.42(2) 1 calc PR B 4
C26B C 0.151(3) 0.926(2) 1.0237(15) 0.076(11) Uani 0.42(2) 1 d PD B 4
H26D H 0.1714 0.8818 1.0025 0.114 Uiso 0.42(2) 1 calc PR B 4
H26E H 0.1799 0.9752 1.0151 0.114 Uiso 0.42(2) 1 calc PR B 4
H26F H 0.0779 0.9299 1.0074 0.114 Uiso 0.42(2) 1 calc PR B 4
C27B C 0.128(3) 0.934(2) 1.1305(18) 0.074(11) Uani 0.42(2) 1 d PD B 4
H27D H 0.1518 0.9042 1.1708 0.111 Uiso 0.42(2) 1 calc PR B 4
H27E H 0.0573 0.9207 1.1074 0.111 Uiso 0.42(2) 1 calc PR B 4
H27F H 0.1346 0.9904 1.1393 0.111 Uiso 0.42(2) 1 calc PR B 4
N5B N 0.187(4) 0.912(11) 1.0919(14) 0.07(3) Uani 0.42(2) 1 d PD B 4
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O2 Eu1 O5 82.6(2) . 1_655
O2 Eu1 O15 79.2(3) . .
O5 Eu1 O15 78.3(2) 1_655 .
O2 Eu1 O8 127.4(2) . 4_676
O5 Eu1 O8 148.4(2) 1_655 4_676
O15 Eu1 O8 96.0(3) . 4_676
O2 Eu1 O7 75.6(2) . 4_676
O5 Eu1 O7 150.7(2) 1_655 4_676
O15 Eu1 O7 78.7(3) . 4_676
O8 Eu1 O7 52.4(2) 4_676 4_676
O2 Eu1 O13 79.9(2) . .
O5 Eu1 O13 72.1(2) 1_655 .
O15 Eu1 O13 145.6(3) . .
O8 Eu1 O13 118.4(2) 4_676 .
O7 Eu1 O13 121.6(3) 4_676 .
O2 Eu1 O10 151.0(2) . .
O5 Eu1 O10 86.0(2) 1_655 .
O15 Eu1 O10 124.3(3) . .
O8 Eu1 O10 71.5(2) 4_676 .
O7 Eu1 O10 122.2(2) 4_676 .
O13 Eu1 O10 71.2(3) . .
O2 Eu1 O9 150.7(3) . .
O5 Eu1 O9 78.4(2) 1_655 .
O15 Eu1 O9 75.2(3) . .
O8 Eu1 O9 70.1(2) 4_676 .
O7 Eu1 O9 112.7(2) 4_676 .
O13 Eu1 O9 114.4(3) . .
O10 Eu1 O9 49.2(3) . .
O2 Eu1 O12 82.8(3) . .
O5 Eu1 O12 121.7(2) 1_655 .
O15 Eu1 O12 151.0(3) . .
O8 Eu1 O12 77.2(3) 4_676 .
O7 Eu1 O12 74.9(3) 4_676 .
O13 Eu1 O12 49.8(3) . .
O10 Eu1 O12 80.7(3) . .
O9 Eu1 O12 126.3(3) . .
O2 Eu1 C18 101.1(2) . 4_676
O5 Eu1 C18 165.6(2) 1_655 4_676
O15 Eu1 C18 88.6(3) . 4_676
O8 Eu1 C18 26.4(2) 4_676 4_676
O7 Eu1 C18 26.1(2) 4_676 4_676
O13 Eu1 C18 122.2(3) . 4_676
O10 Eu1 C18 96.6(3) . 4_676
O9 Eu1 C18 92.5(3) . 4_676
O12 Eu1 C18 72.8(3) . 4_676
O1 Eu2 O6 78.7(2) 4_576 4_676
O1 Eu2 O16 90.1(2) 4_576 .
O6 Eu2 O16 78.6(2) 4_676 .
O1 Eu2 O19 107.8(3) 4_576 .
O6 Eu2 O19 74.7(2) 4_676 .
O16 Eu2 O19 143.9(2) . .
O1 Eu2 O17 76.8(3) 4_576 .
O6 Eu2 O17 143.5(3) 4_676 .
O16 Eu2 O17 74.9(3) . .
O19 Eu2 O17 138.8(3) . .
O1 Eu2 O4 149.8(2) 4_576 .
O6 Eu2 O4 131.46(19) 4_676 .
O16 Eu2 O4 94.4(2) . .
O19 Eu2 O4 85.6(2) . .
O17 Eu2 O4 75.7(3) . .
O1 Eu2 O18 81.3(2) 4_576 .
O6 Eu2 O18 130.0(2) 4_676 .
O16 Eu2 O18 146.7(2) . .
O19 Eu2 O18 68.7(2) . .
O17 Eu2 O18 71.8(3) . .
O4 Eu2 O18 78.7(2) . .
O1 Eu2 O3 154.7(2) 4_576 .
O6 Eu2 O3 79.30(19) 4_676 .
O16 Eu2 O3 73.5(2) . .
O19 Eu2 O3 77.9(2) . .
O17 Eu2 O3 115.7(3) . .
O4 Eu2 O3 53.1(2) . .
O18 Eu2 O3 122.8(2) . .
O1 Eu2 C25A 88.3(4) 4_576 .
O6 Eu2 C25A 162.2(4) 4_676 .
O16 Eu2 C25A 89.4(4) . .
O19 Eu2 C25A 121.3(4) . .
O17 Eu2 C25A 18.8(4) . .
O4 Eu2 C25A 61.9(4) . .
O18 Eu2 C25A 58.4(4) . .
O3 Eu2 C25A 110.1(4) . .
O1 C1 O2 124.6(9) . .
O1 C1 C2 117.1(8) . .
O2 C1 C2 118.0(8) . .
C3 C2 C4 118.6(9) . .
C3 C2 C1 119.3(8) . .
C4 C2 C1 122.2(8) . .
C2 C3 C8 121.7(9) . .
C2 C3 H3 119.1 . .
C8 C3 H3 119.1 . .
C5 C4 C2 120.8(9) . .
C5 C4 H4 119.6 . .
C2 C4 H4 119.6 . .
C4 C5 C7 120.0(8) . .
C4 C5 C6 121.4(8) . .
C7 C5 C6 118.5(8) . .
O4 C6 O3 121.6(8) . .
O4 C6 C5 120.2(8) . .
O3 C6 C5 118.2(8) . .
C8 C7 C5 119.8(9) . .
C8 C7 H7 120.1 . .
C5 C7 H7 120.1 . .
C7 C8 C3 119.0(9) . .
C7 C8 C9 120.9(9) . .
C3 C8 C9 120.0(9) . .
C10 C9 C8 176.0(12) . .
C9 C10 C11 177.7(12) . .
C17 C11 C12 118.8(9) . .
C17 C11 C10 121.7(9) . .
C12 C11 C10 119.5(9) . .
C13 C12 C11 120.6(8) . .
C13 C12 H12 119.7 . .
C11 C12 H12 119.7 . .
C15 C13 C12 119.8(8) . .
C15 C13 C14 121.7(8) . .
C12 C13 C14 118.5(7) . .
O5 C14 O6 125.5(8) . .
O5 C14 C13 117.6(7) . .
O6 C14 C13 116.9(7) . .
C13 C15 C16 120.3(8) . .
C13 C15 H15 119.8 . .
C16 C15 H15 119.8 . .
C17 C16 C15 119.8(8) . .
C17 C16 C18 118.1(8) . .
C15 C16 C18 121.9(8) . .
C16 C17 C11 120.6(9) . .
C16 C17 H17 119.7 . .
C11 C17 H17 119.7 . .
O7 C18 O8 120.2(9) . .
O7 C18 C16 120.8(8) . .
O8 C18 C16 118.9(9) . .
O7 C18 Eu1 61.1(5) . 4_475
O8 C18 Eu1 59.5(5) . 4_475
C16 C18 Eu1 176.2(7) . 4_475
O15 C19 N3 126.0(15) . .
O15 C19 H19 117.0 . .
N3 C19 H19 117.0 . .
N3 C20 H20A 109.5 . .
N3 C20 H20B 109.5 . .
H20A C20 H20B 109.5 . .
N3 C20 H20C 109.5 . .
H20A C20 H20C 109.5 . .
H20B C20 H20C 109.5 . .
N3 C21 H21A 109.5 . .
N3 C21 H21B 109.5 . .
H21A C21 H21B 109.5 . .
N3 C21 H21C 109.5 . .
H21A C21 H21C 109.5 . .
H21B C21 H21C 109.5 . .
O16 C22 N4 122.4(12) . .
O16 C22 H22 118.8 . .
N4 C22 H22 118.8 . .
N4 C23 H23A 109.5 . .
N4 C23 H23B 109.5 . .
H23A C23 H23B 109.5 . .
N4 C23 H23C 109.5 . .
H23A C23 H23C 109.5 . .
H23B C23 H23C 109.5 . .
N4 C24 H24A 109.5 . .
N4 C24 H24B 109.5 . .
H24A C24 H24B 109.5 . .
N4 C24 H24C 109.5 . .
H24A C24 H24C 109.5 . .
H24B C24 H24C 109.5 . .
O19 C31 N7 125.4(12) . .
O19 C31 H31 117.3 . .
N7 C31 H31 117.3 . .
N7 C32 H32A 109.5 . .
N7 C32 H32B 109.5 . .
H32A C32 H32B 109.5 . .
N7 C32 H32C 109.5 . .
H32A C32 H32C 109.5 . .
H32B C32 H32C 109.5 . .
N7 C33 H33A 109.5 . .
N7 C33 H33B 109.5 . .
H33A C33 H33B 109.5 . .
N7 C33 H33C 109.5 . .
H33A C33 H33C 109.5 . .
H33B C33 H33C 109.5 . .
O20 C34 N8 128(2) . .
O20 C34 H34 115.9 . .
N8 C34 H34 115.9 . .
N8 C35 H35A 109.5 . .
N8 C35 H35B 109.5 . .
H35A C35 H35B 109.5 . .
N8 C35 H35C 109.5 . .
H35A C35 H35C 109.5 . .
H35B C35 H35C 109.5 . .
N8 C36 H36A 109.5 . .
N8 C36 H36B 109.5 . .
H36A C36 H36B 109.5 . .
N8 C36 H36C 109.5 . .
H36A C36 H36C 109.5 . .
H36B C36 H36C 109.5 . .
O9 N1 O10 118.4(10) . .
O9 N1 O11 120.4(13) . .
O10 N1 O11 121.2(12) . .
O14 N2 O13 121.5(13) . .
O14 N2 O12 122.5(13) . .
O13 N2 O12 116.0(11) . .
C19 N3 C20 122.4(14) . .
C19 N3 C21 122.6(14) . .
C20 N3 C21 115.0(13) . .
C22 N4 C24 121.5(11) . .
C22 N4 C23 122.7(11) . .
C24 N4 C23 115.5(10) . .
C31 N7 C32 121.7(11) . .
C31 N7 C33 121.7(11) . .
C32 N7 C33 116.6(10) . .
C34 N8 C35 127(2) . .
C34 N8 C36 121(2) . .
C35 N8 C36 112.5(18) . .
C1 O1 Eu2 170.4(6) . 4_575
C1 O2 Eu1 142.4(6) . .
C6 O3 Eu2 91.4(5) . .
C6 O4 Eu2 93.1(5) . .
C14 O5 Eu1 158.5(6) . 1_455
C14 O6 Eu2 146.7(6) . 4_475
C18 O7 Eu1 92.8(5) . 4_475
C18 O8 Eu1 94.1(6) . 4_475
N1 O9 Eu1 95.3(7) . .
N1 O10 Eu1 95.9(6) . .
N2 O12 Eu1 96.1(7) . .
N2 O13 Eu1 98.0(7) . .
C19 O15 Eu1 132.9(9) . .
C22 O16 Eu2 144.9(8) . .
C25B O17 C25A 67.2(18) . .
C25B O17 Eu2 131.1(15) . .
C25A O17 Eu2 121.2(12) . .
C28B O18 C28A 57.6(14) . .
C28B O18 Eu2 146.1(12) . .
C28A O18 Eu2 125.6(10) . .
C31 O19 Eu2 138.1(8) . .
O18 C28A N6A 119(8) . .
O18 C28A H28A 120.6 . .
N6A C28A H28A 120.6 . .
C28A N6A C29A 123(10) . .
C28A N6A C30A 120(10) . .
C29A N6A C30A 115(10) . .
O18 C28B N6B 120(10) . .
O18 C28B H28B 119.8 . .
N6B C28B H28B 119.8 . .
N6B C29B H29D 109.5 . .
N6B C29B H29E 109.5 . .
H29D C29B H29E 109.5 . .
N6B C29B H29F 109.5 . .
H29D C29B H29F 109.5 . .
H29E C29B H29F 109.5 . .
N6B C30B H30D 109.5 . .
N6B C30B H30E 109.5 . .
H30D C30B H30E 109.5 . .
N6B C30B H30F 109.5 . .
H30D C30B H30F 109.5 . .
H30E C30B H30F 109.5 . .
C28B N6B C29B 120(10) . .
C28B N6B C30B 118(10) . .
C29B N6B C30B 120(10) . .
O17 C25A N5A 121(2) . .
O17 C25A Eu2 40.1(9) . .
N5A C25A Eu2 144(4) . .
O17 C25A H25A 119.6 . .
N5A C25A H25A 119.6 . .
Eu2 C25A H25A 87.2 . .
C25A N5A C26A 122(3) . .
C25A N5A C27A 115(3) . .
C26A N5A C27A 120(2) . .
O17 C25B N5B 117(2) . .
O17 C25B H25B 121.3 . .
N5B C25B H25B 121.3 . .
C25B N5B C26B 118(4) . .
C25B N5B C27B 117(3) . .
C26B N5B C27B 122(4) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O2 2.336(6) .
Eu1 O5 2.345(5) 1_655
Eu1 O15 2.351(8) .
Eu1 O8 2.442(6) 4_676
Eu1 O7 2.477(6) 4_676
Eu1 O13 2.507(8) .
Eu1 O10 2.519(7) .
Eu1 O9 2.530(8) .
Eu1 O12 2.534(8) .
Eu1 C18 2.827(9) 4_676
Eu2 O1 2.303(6) 4_576
Eu2 O6 2.338(6) 4_676
Eu2 O16 2.360(7) .
Eu2 O19 2.381(7) .
Eu2 O17 2.434(8) .
Eu2 O4 2.436(6) .
Eu2 O18 2.455(7) .
Eu2 O3 2.465(6) .
Eu2 C25A 3.237(19) .
C1 O1 1.242(10) .
C1 O2 1.251(10) .
C1 C2 1.499(12) .
C2 C3 1.364(12) .
C2 C4 1.394(11) .
C3 C8 1.402(13) .
C3 H3 0.9300 .
C4 C5 1.377(12) .
C4 H4 0.9300 .
C5 C7 1.393(12) .
C5 C6 1.494(12) .
C6 O4 1.248(10) .
C6 O3 1.261(10) .
C7 C8 1.381(12) .
C7 H7 0.9300 .
C8 C9 1.428(13) .
C9 C10 1.195(14) .
C10 C11 1.450(13) .
C11 C17 1.386(12) .
C11 C12 1.402(13) .
C12 C13 1.377(11) .
C12 H12 0.9300 .
C13 C15 1.373(11) .
C13 C14 1.508(11) .
C14 O5 1.246(9) .
C14 O6 1.258(9) .
C15 C16 1.394(12) .
C15 H15 0.9300 .
C16 C17 1.376(12) .
C16 C18 1.501(13) .
C17 H17 0.9300 .
C18 O7 1.247(11) .
C18 O8 1.259(11) .
C18 Eu1 2.827(9) 4_475
C19 O15 1.219(14) .
C19 N3 1.281(16) .
C19 H19 0.9300 .
C20 N3 1.401(16) .
C20 H20A 0.9600 .
C20 H20B 0.9600 .
C20 H20C 0.9600 .
C21 N3 1.408(16) .
C21 H21A 0.9600 .
C21 H21B 0.9600 .
C21 H21C 0.9600 .
C22 O16 1.231(12) .
C22 N4 1.300(14) .
C22 H22 0.9300 .
C23 N4 1.449(14) .
C23 H23A 0.9600 .
C23 H23B 0.9600 .
C23 H23C 0.9600 .
C24 N4 1.435(14) .
C24 H24A 0.9600 .
C24 H24B 0.9600 .
C24 H24C 0.9600 .
C31 O19 1.227(12) .
C31 N7 1.309(14) .
C31 H31 0.9300 .
C32 N7 1.425(13) .
C32 H32A 0.9600 .
C32 H32B 0.9600 .
C32 H32C 0.9600 .
C33 N7 1.450(14) .
C33 H33A 0.9600 .
C33 H33B 0.9600 .
C33 H33C 0.9600 .
C34 O20 1.16(2) .
C34 N8 1.29(2) .
C34 H34 0.9300 .
C35 N8 1.359(9) .
C35 H35A 0.9600 .
C35 H35B 0.9600 .
C35 H35C 0.9600 .
C36 N8 1.399(9) .
C36 H36A 0.9600 .
C36 H36B 0.9600 .
C36 H36C 0.9600 .
N1 O9 1.223(12) .
N1 O10 1.224(11) .
N1 O11 1.270(12) .
N2 O14 1.218(13) .
N2 O13 1.244(12) .
N2 O12 1.261(12) .
O1 Eu2 2.303(6) 4_575
O5 Eu1 2.345(5) 1_455
O6 Eu2 2.338(6) 4_475
O7 Eu1 2.477(6) 4_475
O8 Eu1 2.442(6) 4_475
O17 C25B 1.214(18) .
O17 C25A 1.218(17) .
O18 C28B 1.26(3) .
O18 C28A 1.268(19) .
C28A N6A 1.32(18) .
C28A H28A 0.9300 .
C29A N6A 1.5(2) .
C29A H29A 0.9600 .
C29A H29B 0.9600 .
C29A H29C 0.9600 .
C30A N6A 1.49(16) .
C30A H30A 0.9600 .
C30A H30B 0.9600 .
C30A H30C 0.9600 .
C28B N6B 1.35(19) .
C28B H28B 0.9300 .
C29B N6B 1.4(3) .
C29B H29D 0.9600 .
C29B H29E 0.9600 .
C29B H29F 0.9600 .
C30B N6B 1.5(2) .
C30B H30D 0.9600 .
C30B H30E 0.9600 .
C30B H30F 0.9600 .
C25A N5A 1.42(2) .
C25A H25A 0.9300 .
C26A N5A 1.418(18) .
C26A H26A 0.9600 .
C26A H26B 0.9600 .
C26A H26C 0.9600 .
C27A N5A 1.421(18) .
C27A H27A 0.9600 .
C27A H27B 0.9600 .
C27A H27C 0.9600 .
C25B N5B 1.416(19) .
C25B H25B 0.9300 .
C26B N5B 1.42(2) .
C26B H26D 0.9600 .
C26B H26E 0.9600 .
C26B H26F 0.9600 .
C27B N5B 1.419(19) .
C27B H27D 0.9600 .
C27B H27E 0.9600 .
C27B H27F 0.9600 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O1 C1 C2 C3 4.3(13) . .
O2 C1 C2 C3 -170.6(9) . .
O1 C1 C2 C4 -177.6(8) . .
O2 C1 C2 C4 7.4(14) . .
C4 C2 C3 C8 0.0(14) . .
C1 C2 C3 C8 178.1(9) . .
C3 C2 C4 C5 -1.8(13) . .
C1 C2 C4 C5 -179.9(9) . .
C2 C4 C5 C7 1.2(14) . .
C2 C4 C5 C6 176.6(8) . .
C4 C5 C6 O4 175.2(9) . .
C7 C5 C6 O4 -9.3(14) . .
C4 C5 C6 O3 -1.7(14) . .
C7 C5 C6 O3 173.7(9) . .
C4 C5 C7 C8 1.1(14) . .
C6 C5 C7 C8 -174.4(9) . .
C5 C7 C8 C3 -2.8(14) . .
C5 C7 C8 C9 174.4(9) . .
C2 C3 C8 C7 2.3(15) . .
C2 C3 C8 C9 -175.0(9) . .
C7 C8 C9 C10 -129(17) . .
C3 C8 C9 C10 48(18) . .
C8 C9 C10 C11 140(24) . .
C9 C10 C11 C17 168(31) . .
C9 C10 C11 C12 -12(31) . .
C17 C11 C12 C13 -2.4(14) . .
C10 C11 C12 C13 177.7(9) . .
C11 C12 C13 C15 0.8(14) . .
C11 C12 C13 C14 -177.7(9) . .
C15 C13 C14 O5 178.3(8) . .
C12 C13 C14 O5 -3.2(13) . .
C15 C13 C14 O6 -2.0(13) . .
C12 C13 C14 O6 176.5(8) . .
C12 C13 C15 C16 2.3(13) . .
C14 C13 C15 C16 -179.2(8) . .
C13 C15 C16 C17 -3.9(14) . .
C13 C15 C16 C18 -178.5(8) . .
C15 C16 C17 C11 2.2(14) . .
C18 C16 C17 C11 177.1(8) . .
C12 C11 C17 C16 0.8(14) . .
C10 C11 C17 C16 -179.2(9) . .
C17 C16 C18 O7 -170.9(9) . .
C15 C16 C18 O7 3.8(14) . .
C17 C16 C18 O8 11.9(13) . .
C15 C16 C18 O8 -173.3(9) . .
C17 C16 C18 Eu1 -53(10) . 4_475
C15 C16 C18 Eu1 122(10) . 4_475
O15 C19 N3 C20 -4(2) . .
O15 C19 N3 C21 178.1(14) . .
O16 C22 N4 C24 178.3(11) . .
O16 C22 N4 C23 -8.6(19) . .
O19 C31 N7 C32 2.7(18) . .
O19 C31 N7 C33 -175.0(11) . .
O20 C34 N8 C35 3(4) . .
O20 C34 N8 C36 -179(2) . .
O2 C1 O1 Eu2 -55(5) . 4_575
C2 C1 O1 Eu2 131(4) . 4_575
O1 C1 O2 Eu1 77.4(14) . .
C2 C1 O2 Eu1 -108.0(10) . .
O5 Eu1 O2 C1 -43.6(10) 1_655 .
O15 Eu1 O2 C1 35.9(10) . .
O8 Eu1 O2 C1 125.2(9) 4_676 .
O7 Eu1 O2 C1 116.9(10) 4_676 .
O13 Eu1 O2 C1 -116.6(10) . .
O10 Eu1 O2 C1 -111.2(10) . .
O9 Eu1 O2 C1 6.2(12) . .
O12 Eu1 O2 C1 -166.9(10) . .
C18 Eu1 O2 C1 122.3(10) 4_676 .
O4 C6 O3 Eu2 9.2(10) . .
C5 C6 O3 Eu2 -173.9(8) . .
O1 Eu2 O3 C6 -165.2(6) 4_576 .
O6 Eu2 O3 C6 165.1(6) 4_676 .
O16 Eu2 O3 C6 -113.8(6) . .
O19 Eu2 O3 C6 88.6(6) . .
O17 Eu2 O3 C6 -50.1(6) . .
O4 Eu2 O3 C6 -5.0(6) . .
O18 Eu2 O3 C6 34.1(6) . .
C25A Eu2 O3 C6 -30.6(7) . .
O3 C6 O4 Eu2 -9.3(10) . .
C5 C6 O4 Eu2 173.9(8) . .
O1 Eu2 O4 C6 168.4(6) 4_576 .
O6 Eu2 O4 C6 -8.0(7) 4_676 .
O16 Eu2 O4 C6 70.6(6) . .
O19 Eu2 O4 C6 -73.1(6) . .
O17 Eu2 O4 C6 143.8(6) . .
O18 Eu2 O4 C6 -142.3(6) . .
O3 Eu2 O4 C6 5.0(6) . .
C25A Eu2 O4 C6 157.6(8) . .
O6 C14 O5 Eu1 81.4(18) . 1_455
C13 C14 O5 Eu1 -99.0(15) . 1_455
O5 C14 O6 Eu2 -75.7(14) . 4_475
C13 C14 O6 Eu2 104.6(10) . 4_475
O8 C18 O7 Eu1 -6.8(10) . 4_475
C16 C18 O7 Eu1 176.1(8) . 4_475
O7 C18 O8 Eu1 6.9(10) . 4_475
C16 C18 O8 Eu1 -176.0(7) . 4_475
O10 N1 O9 Eu1 10.9(10) . .
O11 N1 O9 Eu1 -168.5(9) . .
O2 Eu1 O9 N1 -151.4(6) . .
O5 Eu1 O9 N1 -100.8(6) 1_655 .
O15 Eu1 O9 N1 178.4(7) . .
O8 Eu1 O9 N1 76.2(6) 4_676 .
O7 Eu1 O9 N1 107.6(6) 4_676 .
O13 Eu1 O9 N1 -36.8(7) . .
O10 Eu1 O9 N1 -6.1(6) . .
O12 Eu1 O9 N1 20.1(8) . .
C18 Eu1 O9 N1 90.4(6) 4_676 .
O9 N1 O10 Eu1 -10.9(10) . .
O11 N1 O10 Eu1 168.4(9) . .
O2 Eu1 O10 N1 151.0(6) . .
O5 Eu1 O10 N1 84.3(6) 1_655 .
O15 Eu1 O10 N1 11.4(7) . .
O8 Eu1 O10 N1 -73.2(6) 4_676 .
O7 Eu1 O10 N1 -87.2(6) 4_676 .
O13 Eu1 O10 N1 156.7(6) . .
O9 Eu1 O10 N1 6.1(6) . .
O12 Eu1 O10 N1 -152.7(6) . .
C18 Eu1 O10 N1 -81.5(6) 4_676 .
O14 N2 O12 Eu1 -179.5(11) . .
O13 N2 O12 Eu1 2.9(11) . .
O2 Eu1 O12 N2 81.2(7) . .
O5 Eu1 O12 N2 4.6(8) 1_655 .
O15 Eu1 O12 N2 133.1(7) . .
O8 Eu1 O12 N2 -147.8(7) 4_676 .
O7 Eu1 O12 N2 158.1(7) 4_676 .
O13 Eu1 O12 N2 -1.7(6) . .
O10 Eu1 O12 N2 -74.8(7) . .
O9 Eu1 O12 N2 -94.6(7) . .
C18 Eu1 O12 N2 -174.7(8) 4_676 .
O14 N2 O13 Eu1 179.4(11) . .
O12 N2 O13 Eu1 -2.9(11) . .
O2 Eu1 O13 N2 -87.3(7) . .
O5 Eu1 O13 N2 -172.7(7) 1_655 .
O15 Eu1 O13 N2 -140.8(7) . .
O8 Eu1 O13 N2 39.9(8) 4_676 .
O7 Eu1 O13 N2 -21.3(8) 4_676 .
O10 Eu1 O13 N2 95.4(7) . .
O9 Eu1 O13 N2 119.6(7) . .
O12 Eu1 O13 N2 1.7(7) . .
C18 Eu1 O13 N2 9.6(8) 4_676 .
N3 C19 O15 Eu1 147.5(12) . .
O2 Eu1 O15 C19 -64.3(13) . .
O5 Eu1 O15 C19 20.2(13) 1_655 .
O8 Eu1 O15 C19 168.7(13) 4_676 .
O7 Eu1 O15 C19 -141.6(13) 4_676 .
O13 Eu1 O15 C19 -10.7(16) . .
O10 Eu1 O15 C19 97.0(13) . .
O9 Eu1 O15 C19 101.1(13) . .
O12 Eu1 O15 C19 -116.9(13) . .
C18 Eu1 O15 C19 -165.9(13) 4_676 .
N4 C22 O16 Eu2 141.4(10) . .
O1 Eu2 O16 C22 57.4(13) 4_576 .
O6 Eu2 O16 C22 -21.0(13) 4_676 .
O19 Eu2 O16 C22 -63.9(14) . .
O17 Eu2 O16 C22 133.7(13) . .
O4 Eu2 O16 C22 -152.5(13) . .
O18 Eu2 O16 C22 131.5(12) . .
O3 Eu2 O16 C22 -103.1(13) . .
C25A Eu2 O16 C22 145.7(13) . .
O1 Eu2 O17 C25B -41(2) 4_576 .
O6 Eu2 O17 C25B -90(2) 4_676 .
O16 Eu2 O17 C25B -135(2) . .
O19 Eu2 O17 C25B 61(2) . .
O4 Eu2 O17 C25B 127(2) . .
O18 Eu2 O17 C25B 44(2) . .
O3 Eu2 O17 C25B 162(2) . .
C25A Eu2 O17 C25B 86(2) . .
O1 Eu2 O17 C25A -126.7(15) 4_576 .
O6 Eu2 O17 C25A -175.6(14) 4_676 .
O16 Eu2 O17 C25A 139.5(15) . .
O19 Eu2 O17 C25A -24.7(16) . .
O4 Eu2 O17 C25A 40.9(15) . .
O18 Eu2 O17 C25A -41.7(14) . .
O3 Eu2 O17 C25A 76.6(15) . .
O1 Eu2 O18 C28B -100(2) 4_576 .
O6 Eu2 O18 C28B -33(2) 4_676 .
O16 Eu2 O18 C28B -176(2) . .
O19 Eu2 O18 C28B 13(2) . .
O17 Eu2 O18 C28B -179(2) . .
O4 Eu2 O18 C28B 103(2) . .
O3 Eu2 O18 C28B 72(2) . .
C25A Eu2 O18 C28B 167(2) . .
O1 Eu2 O18 C28A 176.7(12) 4_576 .
O6 Eu2 O18 C28A -116.1(12) 4_676 .
O16 Eu2 O18 C28A 100.1(12) . .
O19 Eu2 O18 C28A -70.2(12) . .
O17 Eu2 O18 C28A 97.9(13) . .
O4 Eu2 O18 C28A 19.4(12) . .
O3 Eu2 O18 C28A -11.5(13) . .
C25A Eu2 O18 C28A 83.3(13) . .
N7 C31 O19 Eu2 170.9(8) . .
O1 Eu2 O19 C31 -59.9(11) 4_576 .
O6 Eu2 O19 C31 12.6(11) 4_676 .
O16 Eu2 O19 C31 56.3(13) . .
O17 Eu2 O19 C31 -150.0(11) . .
O4 Eu2 O19 C31 147.7(11) . .
O18 Eu2 O19 C31 -132.7(12) . .
O3 Eu2 O19 C31 94.6(11) . .
C25A Eu2 O19 C31 -159.1(12) . .
C28B O18 C28A N6A 7(8) . .
Eu2 O18 C28A N6A 146(8) . .
O18 C28A N6A C29A -11(16) . .
O18 C28A N6A C30A -176(8) . .
C28A O18 C28B N6B 5(10) . .
Eu2 O18 C28B N6B -102(10) . .
O18 C28B N6B C29B -12(17) . .
O18 C28B N6B C30B -176(9) . .
C25B O17 C25A N5A 14(7) . .
Eu2 O17 C25A N5A 140(7) . .
C25B O17 C25A Eu2 -125.4(17) . .
O1 Eu2 C25A O17 51.3(14) 4_576 .
O6 Eu2 C25A O17 8(3) 4_676 .
O16 Eu2 C25A O17 -38.8(14) . .
O19 Eu2 C25A O17 161.2(12) . .
O4 Eu2 C25A O17 -134.1(16) . .
O18 Eu2 C25A O17 132.1(16) . .
O3 Eu2 C25A O17 -111.0(14) . .
O1 Eu2 C25A N5A -21(9) 4_576 .
O6 Eu2 C25A N5A -64(9) 4_676 .
O16 Eu2 C25A N5A -112(9) . .
O19 Eu2 C25A N5A 88(9) . .
O17 Eu2 C25A N5A -73(9) . .
O4 Eu2 C25A N5A 153(9) . .
O18 Eu2 C25A N5A 59(9) . .
O3 Eu2 C25A N5A 176(9) . .
O17 C25A N5A C26A -18(15) . .
Eu2 C25A N5A C26A 27(18) . .
O17 C25A N5A C27A 177(6) . .
Eu2 C25A N5A C27A -137(3) . .
C25A O17 C25B N5B -1(9) . .
Eu2 O17 C25B N5B -114(9) . .
O17 C25B N5B C26B -15(17) . .
O17 C25B N5B C27B -176(9) . .
