#------------------------------------------------------------------------------
#$Date: 2016-03-25 13:04:44 +0100 (vie 25 de mar de 2016) $
#$Revision: 179878 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/74/7017437.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7017437
loop_
_publ_author_name
'Taouss, Christina'
'Jones, Peter G.'
_publ_section_title
;
 Halogenation of (phosphine chalcogenide)gold(i) halides; some unexpected
 products.
;
_journal_issue                   44
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              11687
_journal_page_last               11689
_journal_paper_doi               10.1039/c1dt11476j
_journal_volume                  40
_journal_year                    2011
_chemical_formula_sum            'C74 H58 Au2 Cl20 P4 Se2'
_chemical_formula_weight         2331.94
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                95.70(3)
_cell_angle_beta                 97.32(3)
_cell_angle_gamma                95.08(3)
_cell_formula_units_Z            1
_cell_length_a                   9.974(2)
_cell_length_b                   13.760(3)
_cell_length_c                   15.679(3)
_cell_measurement_reflns_used    3323
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      29.2925
_cell_measurement_theta_min      2.0968
_cell_volume                     2112.5(8)
_computing_cell_refinement
;
CrysAlisPro, Agilent Technologies,
Version 1.171.34.49 (release 20-01-2011 CrysAlis171 .NET)
(compiled Jan 20 2011,15:58:25)
;
_computing_data_collection
;
CrysAlisPro, Agilent Technologies,
Version 1.171.34.49 (release 20-01-2011 CrysAlis171 .NET)
(compiled Jan 20 2011,15:58:25)
;
_computing_data_reduction
;
CrysAlisPro, Agilent Technologies,
Version 1.171.34.49 (release 20-01-2011 CrysAlis171 .NET)
(compiled Jan 20 2011,15:58:25)
;
_computing_molecular_graphics    'Bruker XP'
_computing_publication_material  SHELXL-97
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 16.1419
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Xcalibur, Eos'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1858
_diffrn_reflns_av_sigmaI/netI    0.1100
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            68021
_diffrn_reflns_theta_full        25.03
_diffrn_reflns_theta_max         25.03
_diffrn_reflns_theta_min         2.10
_exptl_absorpt_coefficient_mu    5.080
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.74308
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro, Agilent Technologies,
Version 1.171.34.49 (release 20-01-2011 CrysAlis171 .NET)
(compiled Jan 20 2011,15:58:25)
;
_exptl_crystal_colour            'dichroic red-yellow'
_exptl_crystal_density_diffrn    1.833
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             1128
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.02
_exptl_crystal_size_min          0.01
_refine_diff_density_max         3.550
_refine_diff_density_min         -1.722
_refine_diff_density_rms         0.243
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.042
_refine_ls_hydrogen_treatment    riding
_refine_ls_matrix_type           full
_refine_ls_number_parameters     460
_refine_ls_number_reflns         7450
_refine_ls_number_restraints     222
_refine_ls_restrained_S_all      1.031
_refine_ls_R_factor_all          0.1069
_refine_ls_R_factor_gt           0.0687
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0759P)²+5.2575P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1491
_refine_ls_wR_factor_ref         0.1695
_reflns_number_gt                5234
_reflns_number_total             7450
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c1dt11476j.txt
_cod_data_source_block           nevada
_cod_original_cell_volume        2112.5(7)
_cod_database_code               7017437
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Au Au 0.54818(5) 0.59388(3) 0.59537(3) 0.01940(16) Uani 1 1 d .
Se Se 0.36533(11) 0.55052(8) 0.47461(7) 0.0199(3) Uani 1 1 d .
P1 P 0.7233(3) 0.6113(2) 0.71031(19) 0.0162(6) Uani 1 1 d .
P2 P 0.4640(3) 0.7304(2) 0.66338(19) 0.0151(6) Uani 1 1 d .
C1 C 0.7954(12) 0.7338(8) 0.7490(8) 0.026(3) Uani 1 1 d U
C2 C 0.9244(12) 0.7418(8) 0.7912(7) 0.022(3) Uani 1 1 d U
H2 H 0.9626 0.6831 0.8037 0.027 Uiso 1 1 calc R
C3 C 1.0052(12) 0.8323(8) 0.8176(7) 0.024(3) Uani 1 1 d U
H3 H 1.0936 0.8345 0.8490 0.028 Uiso 1 1 calc R
C4 C 0.9527(12) 0.9155(8) 0.7966(8) 0.027(3) Uani 1 1 d U
H4 H 1.0072 0.9765 0.8108 0.032 Uiso 1 1 calc R
C5 C 0.8214(12) 0.9136(9) 0.7550(8) 0.025(3) Uani 1 1 d U
C6 C 0.7723(12) 1.0044(8) 0.7357(8) 0.026(3) Uani 1 1 d U
H6 H 0.8317 1.0634 0.7496 0.031 Uiso 1 1 calc R
C7 C 0.6437(12) 1.0088(8) 0.6983(8) 0.027(3) Uani 1 1 d U
H7 H 0.6131 1.0701 0.6864 0.033 Uiso 1 1 calc R
C8 C 0.5562(12) 0.9226(8) 0.6772(7) 0.023(3) Uani 1 1 d U
H8 H 0.4657 0.9267 0.6513 0.028 Uiso 1 1 calc R
C9 C 0.5960(12) 0.8310(8) 0.6924(8) 0.023(3) Uani 1 1 d U
C10 C 0.7336(11) 0.8247(8) 0.7311(7) 0.018(3) Uani 1 1 d U
C11 C 0.8627(11) 0.5488(8) 0.6808(7) 0.021(3) Uani 1 1 d U
C12 C 0.9494(12) 0.5914(9) 0.6273(8) 0.027(3) Uani 1 1 d U
H12 H 0.9364 0.6552 0.6116 0.032 Uiso 1 1 calc R
C13 C 1.0525(13) 0.5431(9) 0.5973(8) 0.031(3) Uani 1 1 d U
H13 H 1.1089 0.5732 0.5608 0.037 Uiso 1 1 calc R
C14 C 1.0733(11) 0.4509(9) 0.6205(8) 0.026(3) Uani 1 1 d U
H14 H 1.1438 0.4172 0.5996 0.031 Uiso 1 1 calc R
C15 C 0.9921(12) 0.4076(9) 0.6738(8) 0.029(3) Uani 1 1 d U
H15 H 1.0092 0.3451 0.6911 0.034 Uiso 1 1 calc R
C16 C 0.8865(12) 0.4539(8) 0.7024(8) 0.024(3) Uani 1 1 d U
H16 H 0.8290 0.4216 0.7370 0.029 Uiso 1 1 calc R
C21 C 0.6631(12) 0.5486(8) 0.7972(8) 0.023(3) Uani 1 1 d U
C22 C 0.7170(12) 0.5771(9) 0.8830(8) 0.028(3) Uani 1 1 d U
H22 H 0.7838 0.6318 0.8983 0.034 Uiso 1 1 calc R
C23 C 0.6706(13) 0.5234(9) 0.9464(8) 0.031(3) Uani 1 1 d U
H23 H 0.7061 0.5426 1.0054 0.037 Uiso 1 1 calc R
C24 C 0.5769(12) 0.4454(8) 0.9261(7) 0.023(3) Uani 1 1 d U
H24 H 0.5479 0.4096 0.9704 0.027 Uiso 1 1 calc R
C25 C 0.5238(11) 0.4177(8) 0.8421(7) 0.017(2) Uani 1 1 d U
H25 H 0.4572 0.3627 0.8280 0.021 Uiso 1 1 calc R
C26 C 0.5667(11) 0.4697(8) 0.7756(8) 0.022(3) Uani 1 1 d U
H26 H 0.5294 0.4504 0.7169 0.027 Uiso 1 1 calc R
C31 C 0.3975(11) 0.7038(8) 0.7629(7) 0.020(3) Uani 1 1 d U
C32 C 0.3162(12) 0.6146(9) 0.7606(8) 0.028(3) Uani 1 1 d U
H32 H 0.3073 0.5672 0.7113 0.033 Uiso 1 1 calc R
C33 C 0.2502(13) 0.5958(10) 0.8288(8) 0.037(3) Uani 1 1 d U
H33 H 0.1939 0.5361 0.8271 0.044 Uiso 1 1 calc R
C34 C 0.2658(12) 0.6639(10) 0.8997(8) 0.032(3) Uani 1 1 d U
H34 H 0.2188 0.6510 0.9470 0.039 Uiso 1 1 calc R
C35 C 0.3492(13) 0.7522(9) 0.9045(8) 0.030(3) Uani 1 1 d U
H35 H 0.3608 0.7981 0.9550 0.036 Uiso 1 1 calc R
C36 C 0.4143(12) 0.7712(9) 0.8342(7) 0.027(3) Uani 1 1 d U
H36 H 0.4705 0.8309 0.8356 0.033 Uiso 1 1 calc R
C41 C 0.3249(11) 0.7754(7) 0.5969(7) 0.016(2) Uani 1 1 d U
C42 C 0.2104(11) 0.8026(8) 0.6325(8) 0.023(3) Uani 1 1 d U
H42 H 0.2054 0.7980 0.6920 0.028 Uiso 1 1 calc R
C43 C 0.1054(12) 0.8358(9) 0.5821(8) 0.030(3) Uani 1 1 d U
H43 H 0.0288 0.8556 0.6071 0.035 Uiso 1 1 calc R
C44 C 0.1110(12) 0.8405(9) 0.4947(8) 0.030(3) Uani 1 1 d U
H44 H 0.0378 0.8621 0.4590 0.036 Uiso 1 1 calc R
C45 C 0.2237(12) 0.8136(8) 0.4607(8) 0.027(3) Uani 1 1 d U
H45 H 0.2281 0.8171 0.4009 0.033 Uiso 1 1 calc R
C46 C 0.3301(12) 0.7818(8) 0.5105(7) 0.022(3) Uani 1 1 d U
H46 H 0.4075 0.7640 0.4854 0.026 Uiso 1 1 calc R
C97 C 0.3045(13) 0.1720(9) 0.5911(8) 0.029(3) Uani 1 1 d U
H97 H 0.2276 0.1586 0.6249 0.035 Uiso 1 1 calc R
C98 C 0.3060(13) 0.1099(9) 0.9024(9) 0.034(3) Uani 1 1 d U
H98 H 0.2345 0.1101 0.8515 0.041 Uiso 1 1 calc R
C99 C -0.0647(12) 0.2646(8) 0.8859(8) 0.029(3) Uani 1 1 d U
H99 H -0.0097 0.2462 0.8389 0.034 Uiso 1 1 calc R
Cl1 Cl 0.0859(3) 0.1548(2) 0.7306(2) 0.0304(7) Uani 1 1 d .
Cl2 Cl 0.2564(3) 0.2499(2) 0.5124(2) 0.0371(8) Uani 1 1 d .
Cl3 Cl 0.3447(4) 0.0607(2) 0.5402(2) 0.0465(10) Uani 1 1 d .
Cl4 Cl 0.4483(3) 0.2313(2) 0.6622(2) 0.0377(8) Uani 1 1 d .
Cl5 Cl 0.3325(4) 0.2279(3) 0.9598(3) 0.0542(11) Uani 1 1 d .
Cl6 Cl 0.2488(4) 0.0230(3) 0.9697(3) 0.0521(10) Uani 1 1 d .
Cl7 Cl 0.4544(4) 0.0783(3) 0.8650(3) 0.0647(12) Uani 1 1 d .
Cl8 Cl -0.0413(4) 0.1821(3) 0.9643(3) 0.0535(11) Uani 1 1 d .
Cl9 Cl -0.0065(4) 0.3848(3) 0.9310(2) 0.0465(9) Uani 1 1 d .
Cl10 Cl -0.2342(3) 0.2556(2) 0.8407(2) 0.0431(9) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Se Se -0.0929 2.2259 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_3
P1 Au P2 87.64(10) .
P1 Au Se 171.86(7) .
P2 Au Se 98.91(8) .
P1 Au Se 92.29(8) 2_666
P2 Au Se 179.21(8) 2_666
Se Au Se 81.08(5) 2_666
Au Se Au 98.92(5) 2_666
C11 P1 C1 104.9(5) .
C11 P1 C21 105.4(5) .
C1 P1 C21 111.1(5) .
C11 P1 Au 110.3(4) .
C1 P1 Au 116.6(4) .
C21 P1 Au 108.0(4) .
C9 P2 C41 107.3(5) .
C9 P2 C31 107.1(5) .
C41 P2 C31 105.5(5) .
C9 P2 Au 110.8(4) .
C41 P2 Au 113.5(4) .
C31 P2 Au 112.2(4) .
C2 C1 C10 118.5(10) .
C2 C1 P1 115.1(9) .
C10 C1 P1 126.0(9) .
C1 C2 C3 123.9(11) .
C4 C3 C2 118.0(11) .
C3 C4 C5 121.5(11) .
C4 C5 C6 118.4(11) .
C4 C5 C10 122.6(11) .
C6 C5 C10 119.0(11) .
C7 C6 C5 121.7(11) .
C6 C7 C8 119.5(11) .
C9 C8 C7 122.6(11) .
C8 C9 C10 118.7(10) .
C8 C9 P2 114.8(9) .
C10 C9 P2 126.4(8) .
C5 C10 C9 118.3(10) .
C5 C10 C1 115.3(10) .
C9 C10 C1 126.4(10) .
C12 C11 C16 116.8(10) .
C12 C11 P1 119.4(9) .
C16 C11 P1 123.7(9) .
C13 C12 C11 121.8(11) .
C14 C13 C12 119.7(12) .
C15 C14 C13 120.1(11) .
C14 C15 C16 120.8(12) .
C15 C16 C11 120.8(11) .
C26 C21 C22 120.6(11) .
C26 C21 P1 118.2(9) .
C22 C21 P1 121.1(9) .
C21 C22 C23 118.4(12) .
C24 C23 C22 121.7(12) .
C23 C24 C25 119.9(11) .
C24 C25 C26 120.6(10) .
C21 C26 C25 118.8(11) .
C36 C31 C32 120.5(11) .
C36 C31 P2 121.8(9) .
C32 C31 P2 117.4(9) .
C33 C32 C31 120.2(12) .
C32 C33 C34 119.2(13) .
C33 C34 C35 121.8(12) .
C36 C35 C34 118.5(12) .
C31 C36 C35 119.7(12) .
C46 C41 C42 119.0(10) .
C46 C41 P2 120.4(8) .
C42 C41 P2 120.6(8) .
C43 C42 C41 120.5(11) .
C42 C43 C44 119.9(12) .
C45 C44 C43 118.9(11) .
C46 C45 C44 121.7(12) .
C45 C46 C41 119.9(11) .
Cl3 C97 Cl2 109.6(7) .
Cl3 C97 Cl4 110.1(7) .
Cl2 C97 Cl4 108.9(6) .
Cl7 C98 Cl5 110.4(7) .
Cl7 C98 Cl6 110.4(7) .
Cl5 C98 Cl6 109.9(7) .
Cl10 C99 Cl9 111.2(7) .
Cl10 C99 Cl8 110.5(7) .
Cl9 C99 Cl8 110.6(7) .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Au P1 2.323(3) .
Au P2 2.341(3) .
Au Se 2.4432(15) .
Au Se 2.4511(13) 2_666
Se Au 2.4510(13) 2_666
P1 C11 1.784(11) .
P1 C1 1.789(12) .
P1 C21 1.820(12) .
P2 C9 1.805(11) .
P2 C41 1.818(10) .
P2 C31 1.828(12) .
C1 C2 1.360(16) .
C1 C10 1.478(15) .
C2 C3 1.416(15) .
C3 C4 1.353(15) .
C4 C5 1.383(16) .
C5 C6 1.428(16) .
C5 C10 1.428(15) .
C6 C7 1.350(16) .
C7 C8 1.394(16) .
C8 C9 1.388(15) .
C9 C10 1.441(15) .
C11 C12 1.409(16) .
C11 C16 1.413(15) .
C12 C13 1.380(16) .
C13 C14 1.380(17) .
C14 C15 1.377(17) .
C15 C16 1.378(16) .
C21 C26 1.370(16) .
C21 C22 1.388(16) .
C22 C23 1.395(16) .
C23 C24 1.344(16) .
C24 C25 1.359(15) .
C25 C26 1.410(15) .
C31 C36 1.363(15) .
C31 C32 1.405(16) .
C32 C33 1.359(16) .
C33 C34 1.363(17) .
C34 C35 1.400(17) .
C35 C36 1.385(16) .
C41 C46 1.372(15) .
C41 C42 1.397(15) .
C42 C43 1.369(16) .
C43 C44 1.386(17) .
C44 C45 1.369(17) .
C45 C46 1.366(16) .
C97 Cl3 1.758(13) .
C97 Cl2 1.762(12) .
C97 Cl4 1.780(12) .
C98 Cl7 1.734(13) .
C98 Cl5 1.758(12) .
C98 Cl6 1.776(14) .
C99 Cl10 1.737(12) .
C99 Cl9 1.750(12) .
C99 Cl8 1.762(12) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
P1 Au Se Au -35.9(6) . 2_666
P2 Au Se Au -179.20(8) . 2_666
Se Au Se Au 0.0 2_666 2_666
P2 Au P1 C11 -160.7(4) . .
Se Au P1 C11 55.5(7) . .
Se Au P1 C11 20.1(4) 2_666 .
P2 Au P1 C1 -41.2(4) . .
Se Au P1 C1 175.0(6) . .
Se Au P1 C1 139.6(4) 2_666 .
P2 Au P1 C21 84.6(4) . .
Se Au P1 C21 -59.3(7) . .
Se Au P1 C21 -94.6(4) 2_666 .
P1 Au P2 C9 50.6(4) . .
Se Au P2 C9 -134.3(4) . .
Se Au P2 C9 136(6) 2_666 .
P1 Au P2 C41 171.4(4) . .
Se Au P2 C41 -13.5(4) . .
Se Au P2 C41 -103(6) 2_666 .
P1 Au P2 C31 -69.1(4) . .
Se Au P2 C31 106.1(4) . .
Se Au P2 C31 16(6) 2_666 .
C11 P1 C1 C2 -34.1(11) . .
C21 P1 C1 C2 79.3(10) . .
Au P1 C1 C2 -156.5(8) . .
C11 P1 C1 C10 139.1(10) . .
C21 P1 C1 C10 -107.5(11) . .
Au P1 C1 C10 16.7(12) . .
C10 C1 C2 C3 -1.5(18) . .
P1 C1 C2 C3 172.2(9) . .
C1 C2 C3 C4 -2.6(18) . .
C2 C3 C4 C5 3.6(18) . .
C3 C4 C5 C6 179.3(12) . .
C3 C4 C5 C10 -0.4(19) . .
C4 C5 C6 C7 -177.4(12) . .
C10 C5 C6 C7 2.4(18) . .
C5 C6 C7 C8 -0.4(19) . .
C6 C7 C8 C9 -0.6(19) . .
C7 C8 C9 C10 -0.4(18) . .
C7 C8 C9 P2 177.9(9) . .
C41 P2 C9 C8 13.9(11) . .
C31 P2 C9 C8 -98.9(10) . .
Au P2 C9 C8 138.4(8) . .
C41 P2 C9 C10 -168.0(10) . .
C31 P2 C9 C10 79.2(11) . .
Au P2 C9 C10 -43.5(11) . .
C4 C5 C10 C9 176.5(11) . .
C6 C5 C10 C9 -3.3(17) . .
C4 C5 C10 C1 -3.6(17) . .
C6 C5 C10 C1 176.6(11) . .
C8 C9 C10 C5 2.3(17) . .
P2 C9 C10 C5 -175.7(9) . .
C8 C9 C10 C1 -177.5(11) . .
P2 C9 C10 C1 4.4(18) . .
C2 C1 C10 C5 4.5(16) . .
P1 C1 C10 C5 -168.5(9) . .
C2 C1 C10 C9 -175.7(11) . .
P1 C1 C10 C9 11.4(18) . .
C1 P1 C11 C12 -49.8(11) . .
C21 P1 C11 C12 -167.2(9) . .
Au P1 C11 C12 76.5(10) . .
C1 P1 C11 C16 135.3(10) . .
C21 P1 C11 C16 18.0(11) . .
Au P1 C11 C16 -98.4(10) . .
C16 C11 C12 C13 0.1(17) . .
P1 C11 C12 C13 -175.1(9) . .
C11 C12 C13 C14 -0.7(19) . .
C12 C13 C14 C15 -0.4(18) . .
C13 C14 C15 C16 2.2(18) . .
C14 C15 C16 C11 -2.9(18) . .
C12 C11 C16 C15 1.7(17) . .
P1 C11 C16 C15 176.7(9) . .
C11 P1 C21 C26 -88.7(10) . .
C1 P1 C21 C26 158.2(9) . .
Au P1 C21 C26 29.2(10) . .
C11 P1 C21 C22 88.7(10) . .
C1 P1 C21 C22 -24.4(11) . .
Au P1 C21 C22 -153.4(9) . .
C26 C21 C22 C23 0.0(17) . .
P1 C21 C22 C23 -177.3(9) . .
C21 C22 C23 C24 0.6(18) . .
C22 C23 C24 C25 -0.8(18) . .
C23 C24 C25 C26 0.4(17) . .
C22 C21 C26 C25 -0.3(17) . .
P1 C21 C26 C25 177.1(8) . .
C24 C25 C26 C21 0.1(16) . .
C9 P2 C31 C36 20.6(11) . .
C41 P2 C31 C36 -93.5(10) . .
Au P2 C31 C36 142.4(9) . .
C9 P2 C31 C32 -165.7(9) . .
C41 P2 C31 C32 80.3(10) . .
Au P2 C31 C32 -43.9(10) . .
C36 C31 C32 C33 1.9(18) . .
P2 C31 C32 C33 -171.9(9) . .
C31 C32 C33 C34 -1.1(19) . .
C32 C33 C34 C35 -0.7(19) . .
C33 C34 C35 C36 1.6(19) . .
C32 C31 C36 C35 -1.0(17) . .
P2 C31 C36 C35 172.6(9) . .
C34 C35 C36 C31 -0.8(17) . .
C9 P2 C41 C46 80.6(10) . .
C31 P2 C41 C46 -165.5(9) . .
Au P2 C41 C46 -42.2(10) . .
C9 P2 C41 C42 -100.5(10) . .
C31 P2 C41 C42 13.5(10) . .
Au P2 C41 C42 136.8(8) . .
C46 C41 C42 C43 -0.5(17) . .
P2 C41 C42 C43 -179.5(9) . .
C41 C42 C43 C44 1.5(18) . .
C42 C43 C44 C45 -1.4(18) . .
C43 C44 C45 C46 0.4(18) . .
C44 C45 C46 C41 0.5(18) . .
C42 C41 C46 C45 -0.5(17) . .
P2 C41 C46 C45 178.5(9) . .
