#------------------------------------------------------------------------------
#$Date: 2016-03-25 15:05:40 +0100 (vie 25 de mar de 2016) $
#$Revision: 179951 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/46/7024614.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7024614
loop_
_publ_author_name
'Xu, Hai-Bing'
'Wen, Hui-Min'
'Chen, Zhong-Hui'
'Li, Jia'
'Shi, Lin-Xi'
'Chen, Zhong-Ning'
_publ_section_title
;
 Square structures and photophysical properties of Zn(2)Ln(2) complexes
 (Ln = Nd, Eu, Sm, Er, Yb).
;
_journal_issue                   8
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1948
_journal_page_last               1953
_journal_paper_doi               10.1039/b919170d
_journal_volume                  39
_journal_year                    2010
_chemical_formula_sum            'C40 H21 Cl0 Eu F18 N4 O8 Zn'
_chemical_formula_weight         1244.94
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 108.254(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   14.9669(11)
_cell_length_b                   17.0280(10)
_cell_length_c                   18.8652(16)
_cell_measurement_temperature    293(2)
_cell_volume                     4566.0(6)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.964
_diffrn_measured_fraction_theta_max 0.964
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0340
_diffrn_reflns_av_sigmaI/netI    0.0352
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            29109
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         2.27
_exptl_absorpt_coefficient_mu    2.015
_exptl_absorpt_correction_T_max  0.7520
_exptl_absorpt_correction_T_min  0.6887
_exptl_absorpt_correction_type   empirical
_exptl_crystal_density_diffrn    1.811
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2432
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.15
_refine_diff_density_max         0.967
_refine_diff_density_min         -0.764
_refine_diff_density_rms         0.114
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.061
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     643
_refine_ls_number_reflns         8642
_refine_ls_number_restraints     76
_refine_ls_restrained_S_all      1.077
_refine_ls_R_factor_all          0.0703
_refine_ls_R_factor_gt           0.0587
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0798P)²+15.1052P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1508
_refine_ls_wR_factor_ref         0.1611
_reflns_number_gt                7285
_reflns_number_total             8642
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b919170d.txt
_cod_data_source_block           x3
_cod_original_sg_symbol_H-M      p21/c
_cod_database_code               7024614
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu Eu 0.24268(2) 0.037215(18) 0.239934(17) 0.04210(13) Uani 1 1 d . . .
Zn Zn 0.25540(5) -0.01803(5) 0.42929(4) 0.0451(2) Uani 1 1 d . . .
N1 N 0.1287(4) -0.0538(3) 0.4487(3) 0.0472(12) Uani 1 1 d . . .
N2 N 0.3038(4) -0.1373(3) 0.4242(3) 0.0496(13) Uani 1 1 d . . .
N3 N 0.3735(4) -0.0276(3) 0.5225(3) 0.0423(12) Uani 1 1 d . . .
N4 N 0.2714(4) 0.0990(3) 0.4813(3) 0.0485(13) Uani 1 1 d . . .
O1 O 0.2854(3) 0.1705(3) 0.2797(3) 0.0619(13) Uani 1 1 d . . .
O2 O 0.1119(3) 0.1239(3) 0.1891(3) 0.0592(12) Uani 1 1 d . . .
O3 O 0.3959(4) 0.0586(3) 0.2244(3) 0.0632(13) Uani 1 1 d . C .
O4 O 0.3105(3) -0.0877(3) 0.2281(3) 0.0563(12) Uani 1 1 d . C .
O5 O 0.2274(5) 0.0409(3) 0.1098(3) 0.0720(16) Uani 1 1 d . D .
O6 O 0.1228(4) -0.0547(3) 0.1773(3) 0.0666(14) Uani 1 1 d . D .
O7 O 0.6528(3) -0.0196(3) 0.6421(3) 0.0509(11) Uani 1 1 d . . .
O14 O 0.1619(3) 0.0094(3) 0.3283(2) 0.0484(10) Uani 1 1 d . . .
C1 C 0.1156(5) -0.0882(4) 0.5081(4) 0.0588(18) Uani 1 1 d . . .
C2 C 0.0238(6) -0.1070(5) 0.5084(5) 0.067(2) Uani 1 1 d . . .
H2A H 0.0155 -0.1306 0.5503 0.081 Uiso 1 1 d R . .
C3 C -0.0518(6) -0.0914(5) 0.4489(5) 0.068(2) Uani 1 1 d . . .
H3A H -0.1118 -0.1037 0.4502 0.082 Uiso 1 1 d R . .
C4 C -0.1141(5) -0.0382(5) 0.3215(5) 0.064(2) Uani 1 1 d . . .
H4A H -0.1757 -0.0484 0.3201 0.077 Uiso 1 1 d R . .
C5 C -0.0962(5) -0.0057(6) 0.2615(5) 0.072(2) Uani 1 1 d . . .
H5A H -0.1463 0.0058 0.2190 0.086 Uiso 1 1 d R . .
C6 C -0.0039(5) 0.0109(5) 0.2619(4) 0.0574(17) Uani 1 1 d . . .
H6A H 0.0061 0.0332 0.2200 0.069 Uiso 1 1 d R . .
C7 C 0.0719(4) -0.0055(4) 0.3239(4) 0.0470(14) Uani 1 1 d . . .
C8 C 0.0533(5) -0.0382(3) 0.3874(4) 0.0452(14) Uani 1 1 d . . .
C9 C -0.0399(5) -0.0560(4) 0.3845(4) 0.0549(17) Uani 1 1 d . . .
C10 C 0.1986(6) -0.1067(6) 0.5743(5) 0.077(2) Uani 1 1 d . . .
H10A H 0.2551 -0.0898 0.5650 0.116 Uiso 1 1 calc R . .
H10B H 0.2014 -0.1623 0.5831 0.116 Uiso 1 1 calc R . .
H10C H 0.1925 -0.0799 0.6173 0.116 Uiso 1 1 calc R . .
C11 C 0.2604(5) -0.1920(5) 0.3740(5) 0.064(2) Uani 1 1 d . . .
H11A H 0.2078 -0.1777 0.3345 0.077 Uiso 1 1 d R . .
C12 C 0.2911(6) -0.2686(5) 0.3789(5) 0.076(2) Uani 1 1 d . . .
H12A H 0.2591 -0.3054 0.3437 0.091 Uiso 1 1 d R . .
C13 C 0.3695(6) -0.2901(5) 0.4364(5) 0.075(2) Uani 1 1 d . . .
H13A H 0.3910 -0.3417 0.4409 0.090 Uiso 1 1 d R . .
C14 C 0.4157(6) -0.2337(4) 0.4870(4) 0.0603(18) Uani 1 1 d . . .
H14A H 0.4694 -0.2467 0.5260 0.072 Uiso 1 1 d R . .
C15 C 0.3815(4) -0.1573(4) 0.4796(3) 0.0427(13) Uani 1 1 d . . .
C16 C 0.4277(4) -0.0922(4) 0.5300(3) 0.0438(14) Uani 1 1 d . . .
C17 C 0.5191(4) -0.0935(4) 0.5752(3) 0.0457(14) Uani 1 1 d . . .
H17A H 0.5531 -0.1401 0.5821 0.055 Uiso 1 1 d R . .
C19 C 0.5023(5) 0.0402(4) 0.6067(4) 0.0454(15) Uani 1 1 d . . .
H19A H 0.5253 0.0853 0.6341 0.054 Uiso 1 1 d R . .
C20 C 0.4103(5) 0.0373(4) 0.5619(4) 0.0427(14) Uani 1 1 d . . .
C21 C 0.3460(5) 0.1058(4) 0.5445(4) 0.0469(15) Uani 1 1 d . . .
C22 C 0.3606(6) 0.1737(5) 0.5867(5) 0.069(2) Uani 1 1 d . . .
H22A H 0.4111 0.1775 0.6304 0.083 Uiso 1 1 d R . .
C23 C 0.2989(7) 0.2362(5) 0.5631(6) 0.084(3) Uani 1 1 d . . .
H23A H 0.3072 0.2822 0.5910 0.100 Uiso 1 1 d R . .
C24 C 0.2258(6) 0.2297(5) 0.4984(6) 0.075(2) Uani 1 1 d . . .
H24A H 0.1848 0.2715 0.4810 0.090 Uiso 1 1 d R . .
C25 C 0.2137(5) 0.1604(4) 0.4594(5) 0.0600(19) Uani 1 1 d . . .
H25A H 0.1632 0.1559 0.4158 0.072 Uiso 1 1 d R . .
C103 C 0.1496(5) 0.2497(4) 0.2420(5) 0.064(2) Uani 1 1 d . . .
H10D H 0.1258 0.2992 0.2465 0.077 Uiso 1 1 d R . .
C104 C 0.0907(5) 0.1925(4) 0.2004(4) 0.0613(19) Uani 1 1 d . B .
C102 C 0.2435(5) 0.2336(4) 0.2769(4) 0.0543(17) Uani 1 1 d . A .
C18 C 0.5616(4) -0.0247(4) 0.6112(4) 0.0442(14) Uani 1 1 d . . .
C107 C 0.4468(6) 0.0178(6) 0.1987(6) 0.082(3) Uani 1 1 d D . .
C108 C 0.4419(7) -0.0644(6) 0.1881(6) 0.088(3) Uani 1 1 d . C .
H10E H 0.4858 -0.0889 0.1698 0.106 Uiso 1 1 d R . .
C109 C 0.3725(7) -0.1105(5) 0.2043(5) 0.070(2) Uani 1 1 d . . .
C112 C 0.1947(9) -0.0077(6) 0.0575(5) 0.100(4) Uani 1 1 d D . .
C114 C 0.1049(8) -0.0910(7) 0.1197(7) 0.101(4) Uani 1 1 d . . .
C113 C 0.1330(10) -0.0722(7) 0.0565(6) 0.116(4) Uani 1 1 d . D .
H11B H 0.1108 -0.1024 0.0135 0.139 Uiso 1 1 d R . .
C101 C 0.3051(5) 0.3020(4) 0.3159(4) 0.071(2) Uani 1 1 d D . .
C105 C -0.0119(6) 0.2144(4) 0.1627(5) 0.088(3) Uani 1 1 d D . .
C110 C 0.3797(6) -0.1985(5) 0.1960(5) 0.086(3) Uani 1 1 d D C .
C115 C 0.0375(7) -0.1587(6) 0.1101(6) 0.151(7) Uani 1 1 d D D .
F1A F 0.3314(8) 0.3451(6) 0.2664(5) 0.0977(17) Uani 0.587(10) 1 d PD A 1
F2A F 0.2545(6) 0.3515(6) 0.3440(6) 0.0977(17) Uani 0.587(10) 1 d PD A 1
F3A F 0.3815(6) 0.2829(6) 0.3703(6) 0.0977(17) Uani 0.587(10) 1 d PD A 1
F1B F 0.3508(10) 0.2783(8) 0.3861(6) 0.0977(17) Uani 0.413(10) 1 d PD A 2
F2B F 0.3729(10) 0.3130(8) 0.2837(8) 0.0977(17) Uani 0.413(10) 1 d PD A 2
F3B F 0.2698(10) 0.3721(6) 0.3206(9) 0.0977(17) Uani 0.413(10) 1 d PD A 2
F4A F -0.0339(9) 0.2842(5) 0.1831(6) 0.117(2) Uani 0.566(7) 1 d PD B 1
F5A F -0.0221(7) 0.2248(7) 0.0875(5) 0.117(2) Uani 0.566(7) 1 d PD B 1
F6A F -0.0741(6) 0.1612(6) 0.1629(7) 0.117(2) Uani 0.566(7) 1 d PD B 1
F4B F -0.0584(9) 0.1666(7) 0.1076(7) 0.117(2) Uani 0.434(7) 1 d PD B 2
F5B F -0.0554(9) 0.1966(8) 0.2165(7) 0.117(2) Uani 0.434(7) 1 d PD B 2
F6B F -0.0342(11) 0.2872(5) 0.1450(8) 0.117(2) Uani 0.434(7) 1 d PD B 2
C6A C 0.5362(10) 0.0591(9) 0.2011(14) 0.156(10) Uani 0.608(19) 1 d PD C 1
F7A F 0.5878(11) 0.0773(11) 0.2715(13) 0.193(5) Uani 0.608(19) 1 d PD C 1
F8A F 0.5931(13) 0.0223(9) 0.1706(15) 0.193(5) Uani 0.608(19) 1 d PD C 1
F9A F 0.5211(12) 0.1308(10) 0.1674(14) 0.193(5) Uani 0.608(19) 1 d PD C 1
C6B C 0.5206(16) 0.0605(13) 0.176(2) 0.156(10) Uani 0.392(19) 1 d PD C 2
F7B F 0.5953(17) 0.0889(17) 0.229(2) 0.193(5) Uani 0.392(19) 1 d PD C 2
F8B F 0.5514(19) 0.0185(15) 0.130(2) 0.193(5) Uani 0.392(19) 1 d PD C 2
F9B F 0.4763(17) 0.1234(15) 0.138(2) 0.193(5) Uani 0.392(19) 1 d PD C 2
F10A F 0.4352(8) -0.2236(6) 0.2643(5) 0.131(2) Uani 0.680(7) 1 d PD C 1
F11A F 0.4179(8) -0.2220(6) 0.1466(6) 0.131(2) Uani 0.680(7) 1 d PD C 1
F12A F 0.2988(6) -0.2362(6) 0.1860(7) 0.131(2) Uani 0.680(7) 1 d PD C 1
F10B F 0.3256(14) -0.2164(12) 0.1245(7) 0.131(2) Uani 0.320(7) 1 d PD C 2
F11B F 0.3470(16) -0.2454(11) 0.2391(11) 0.131(2) Uani 0.320(7) 1 d PD C 2
F12B F 0.4648(9) -0.2269(12) 0.1993(13) 0.131(2) Uani 0.320(7) 1 d PD C 2
C11A C 0.2326(15) 0.0063(11) -0.0063(8) 0.153(7) Uani 0.486(9) 1 d PD D 1
F13A F 0.3266(14) 0.0083(13) 0.0114(9) 0.189(5) Uani 0.486(9) 1 d PD D 1
F14A F 0.2011(18) 0.0760(12) -0.0368(13) 0.189(5) Uani 0.486(9) 1 d PD D 1
F15A F 0.2044(19) -0.0460(12) -0.0620(10) 0.189(5) Uani 0.486(9) 1 d PD D 1
C11B C 0.2151(13) 0.0059(11) -0.0139(7) 0.153(7) Uani 0.514(9) 1 d PD D 2
F13B F 0.2754(16) -0.0497(13) -0.0183(11) 0.189(5) Uani 0.514(9) 1 d PD D 2
F14B F 0.2540(16) 0.0753(11) -0.0172(13) 0.189(5) Uani 0.514(9) 1 d PD D 2
F15B F 0.1396(12) -0.0004(12) -0.0736(9) 0.189(5) Uani 0.514(9) 1 d PD D 2
F16A F -0.0318(9) -0.1402(9) 0.1377(9) 0.166(4) Uani 0.598(9) 1 d PD D 1
F17A F 0.0879(9) -0.2155(7) 0.1576(8) 0.166(4) Uani 0.598(9) 1 d PD D 1
F18A F 0.0013(10) -0.1944(9) 0.0459(6) 0.166(4) Uani 0.598(9) 1 d PD D 1
F16B F 0.0700(13) -0.2266(8) 0.0941(13) 0.166(4) Uani 0.402(9) 1 d PD D 2
F17B F -0.0262(13) -0.1361(11) 0.0431(8) 0.166(4) Uani 0.402(9) 1 d PD D 2
F18B F -0.0125(16) -0.1695(13) 0.1554(11) 0.166(4) Uani 0.402(9) 1 d PD D 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O7 Eu O14 68.89(15) 3_656 .
O7 Eu O5 144.3(2) 3_656 .
O14 Eu O5 144.32(19) . .
O7 Eu O6 124.65(19) 3_656 .
O14 Eu O6 75.53(18) . .
O5 Eu O6 72.2(2) . .
O7 Eu O4 78.21(17) 3_656 .
O14 Eu O4 102.15(16) . .
O5 Eu O4 80.49(18) . .
O6 Eu O4 69.39(18) . .
O7 Eu O2 133.49(17) 3_656 .
O14 Eu O2 82.72(17) . .
O5 Eu O2 76.69(19) . .
O6 Eu O2 79.25(18) . .
O4 Eu O2 145.60(17) . .
O7 Eu O1 77.76(17) 3_656 .
O14 Eu O1 96.42(18) . .
O5 Eu O1 103.05(19) . .
O6 Eu O1 148.49(18) . .
O4 Eu O1 141.71(17) . .
O2 Eu O1 69.46(16) . .
O7 Eu O3 75.82(17) 3_656 .
O14 Eu O3 144.67(17) . .
O5 Eu O3 70.3(2) . .
O6 Eu O3 128.93(18) . .
O4 Eu O3 71.23(17) . .
O2 Eu O3 122.86(18) . .
O1 Eu O3 74.24(18) . .
O7 Eu Zn 37.58(11) 3_656 .
O14 Eu Zn 31.59(10) . .
O5 Eu Zn 166.32(13) . .
O6 Eu Zn 96.66(15) . .
O4 Eu Zn 88.20(12) . .
O2 Eu Zn 109.68(13) . .
O1 Eu Zn 90.59(14) . .
O3 Eu Zn 113.31(13) . .
O14 Zn N3 165.13(19) . .
O14 Zn N1 80.7(2) . .
N3 Zn N1 113.6(2) . .
O14 Zn N2 108.4(2) . .
N3 Zn N2 75.9(2) . .
N1 Zn N2 93.9(2) . .
O14 Zn N4 99.0(2) . .
N3 Zn N4 75.4(2) . .
N1 Zn N4 99.2(2) . .
N2 Zn N4 151.2(2) . .
O14 Zn O7 75.45(17) . 3_656
N3 Zn O7 90.67(19) . 3_656
N1 Zn O7 155.42(19) . 3_656
N2 Zn O7 88.07(19) . 3_656
N4 Zn O7 90.41(19) . 3_656
O14 Zn Eu 38.03(12) . .
N3 Zn Eu 128.40(15) . .
N1 Zn Eu 117.85(16) . .
N2 Zn Eu 96.57(15) . .
N4 Zn Eu 99.72(15) . .
O7 Zn Eu 37.74(11) 3_656 .
C1 N1 C8 119.9(6) . .
C1 N1 Zn 130.1(5) . .
C8 N1 Zn 110.0(4) . .
C15 N2 C11 118.8(6) . .
C15 N2 Zn 115.1(4) . .
C11 N2 Zn 125.9(5) . .
C16 N3 C20 118.9(6) . .
C16 N3 Zn 118.5(4) . .
C20 N3 Zn 119.7(4) . .
C25 N4 C21 118.5(6) . .
C25 N4 Zn 126.9(5) . .
C21 N4 Zn 114.5(4) . .
C102 O1 Eu 136.3(5) . .
C104 O2 Eu 136.7(5) . .
C107 O3 Eu 133.1(5) . .
C109 O4 Eu 135.5(5) . .
C112 O5 Eu 132.4(6) . .
C114 O6 Eu 134.5(7) . .
C18 O7 Zn 119.3(4) . 3_656
C18 O7 Eu 136.0(4) . 3_656
Zn O7 Eu 104.67(18) 3_656 3_656
C7 O14 Zn 113.3(4) . .
C7 O14 Eu 135.1(4) . .
Zn O14 Eu 110.38(18) . .
N1 C1 C2 120.1(7) . .
N1 C1 C10 119.6(7) . .
C2 C1 C10 120.3(7) . .
C3 C2 C1 121.1(7) . .
C2 C3 C9 120.0(7) . .
C5 C4 C9 119.4(7) . .
C4 C5 C6 121.8(8) . .
C7 C6 C5 120.5(7) . .
O14 C7 C6 123.6(6) . .
O14 C7 C8 118.5(6) . .
C6 C7 C8 117.9(6) . .
N1 C8 C9 122.3(6) . .
N1 C8 C7 117.5(6) . .
C9 C8 C7 120.2(6) . .
C4 C9 C8 120.2(7) . .
C4 C9 C3 123.2(7) . .
C8 C9 C3 116.5(7) . .
N2 C11 C12 122.1(8) . .
C13 C12 C11 119.4(7) . .
C12 C13 C14 118.6(7) . .
C13 C14 C15 119.6(7) . .
N2 C15 C14 121.3(6) . .
N2 C15 C16 115.1(5) . .
C14 C15 C16 123.5(6) . .
N3 C16 C17 122.0(6) . .
N3 C16 C15 113.5(5) . .
C17 C16 C15 124.2(6) . .
C16 C17 C18 120.2(6) . .
C20 C19 C18 120.2(6) . .
N3 C20 C19 121.8(6) . .
N3 C20 C21 113.5(6) . .
C19 C20 C21 124.4(6) . .
N4 C21 C22 121.1(6) . .
N4 C21 C20 115.1(6) . .
C22 C21 C20 123.8(7) . .
C21 C22 C23 119.1(8) . .
C24 C23 C22 119.4(8) . .
C23 C24 C25 118.9(7) . .
N4 C25 C24 122.9(8) . .
C102 C103 C104 120.3(7) . .
O2 C104 C103 127.4(7) . .
O2 C104 C105 115.1(6) . .
C103 C104 C105 117.6(7) . .
O1 C102 C103 128.3(7) . .
O1 C102 C101 114.9(6) . .
C103 C102 C101 116.8(6) . .
O7 C18 C17 121.5(6) . .
O7 C18 C19 121.9(6) . .
C17 C18 C19 116.4(6) . .
O3 C107 C108 127.0(7) . .
O3 C107 C6B 116.1(12) . .
C108 C107 C6B 116.9(12) . .
O3 C107 C6A 112.2(10) . .
C108 C107 C6A 118.3(10) . .
C6B C107 C6A 17(2) . .
C109 C108 C107 121.9(8) . .
O4 C109 C108 127.1(8) . .
O4 C109 C110 116.2(8) . .
C108 C109 C110 116.5(8) . .
O5 C112 C113 127.0(8) . .
O5 C112 C11B 117.8(11) . .
C113 C112 C11B 115.0(11) . .
O5 C112 C11A 111.8(11) . .
C113 C112 C11A 121.1(11) . .
C11B C112 C11A 9.8(12) . .
O6 C114 C113 126.8(10) . .
O6 C114 C115 117.0(11) . .
C113 C114 C115 115.8(9) . .
C114 C113 C112 121.5(9) . .
F3A C101 F3B 116.1(11) . .
F3A C101 F1A 107.8(7) . .
F3B C101 F1A 76.3(7) . .
F3A C101 F2A 107.8(7) . .
F3B C101 F2A 28.6(7) . .
F1A C101 F2A 104.8(6) . .
F3A C101 F1B 27.2(7) . .
F3B C101 F1B 107.2(8) . .
F1A C101 F1B 132.8(9) . .
F2A C101 F1B 88.6(9) . .
F3A C101 F2B 78.0(7) . .
F3B C101 F2B 106.1(7) . .
F1A C101 F2B 35.2(6) . .
F2A C101 F2B 133.2(8) . .
F1B C101 F2B 105.2(7) . .
F3A C101 C102 115.7(7) . .
F3B C101 C102 121.9(8) . .
F1A C101 C102 110.3(7) . .
F2A C101 C102 109.8(7) . .
F1B C101 C102 106.9(8) . .
F2B C101 C102 108.4(8) . .
F6A C105 F6B 122.6(11) . .
F6A C105 F4A 112.4(8) . .
F6B C105 F4A 31.8(8) . .
F6A C105 F4B 51.5(7) . .
F6B C105 F4B 110.6(8) . .
F4A C105 F4B 131.2(9) . .
F6A C105 F5A 104.0(7) . .
F6B C105 F5A 71.3(8) . .
F4A C105 F5A 103.0(7) . .
F4B C105 F5A 54.4(7) . .
F6A C105 F5B 49.5(7) . .
F6B C105 F5B 104.6(8) . .
F4A C105 F5B 76.6(8) . .
F4B C105 F5B 100.7(7) . .
F5A C105 F5B 147.2(9) . .
F6A C105 C104 116.5(7) . .
F6B C105 C104 119.6(10) . .
F4A C105 C104 113.0(8) . .
F4B C105 C104 114.8(8) . .
F5A C105 C104 106.3(7) . .
F5B C105 C104 103.8(8) . .
F11A C110 F12A 109.6(7) . .
F11A C110 F11B 125.4(11) . .
F12A C110 F11B 46.2(9) . .
F11A C110 F12B 45.6(9) . .
F12A C110 F12B 129.8(11) . .
F11B C110 F12B 106.1(9) . .
F11A C110 F10A 107.8(7) . .
F12A C110 F10A 103.9(7) . .
F11B C110 F10A 57.8(10) . .
F12B C110 F10A 63.6(10) . .
F11A C110 F10B 58.9(9) . .
F12A C110 F10B 61.5(9) . .
F11B C110 F10B 104.5(9) . .
F12B C110 F10B 103.0(8) . .
F10A C110 F10B 148.8(10) . .
F11A C110 C109 116.1(8) . .
F12A C110 C109 113.7(8) . .
F11B C110 C109 118.5(11) . .
F12B C110 C109 116.6(11) . .
F10A C110 C109 104.7(7) . .
F10B C110 C109 106.4(11) . .
F18A C115 F18B 112.4(15) . .
F18A C115 F16B 57.3(9) . .
F18B C115 F16B 110.5(10) . .
F18A C115 F16A 108.8(9) . .
F18B C115 F16A 27.0(11) . .
F16B C115 F16A 132.7(13) . .
F18A C115 F17A 105.1(8) . .
F18B C115 F17A 77.5(12) . .
F16B C115 F17A 50.8(9) . .
F16A C115 F17A 104.2(9) . .
F18A C115 F17B 46.8(8) . .
F18B C115 F17B 105.3(9) . .
F16B C115 F17B 103.5(8) . .
F16A C115 F17B 83.9(12) . .
F17A C115 F17B 151.2(10) . .
F18A C115 C114 122.3(11) . .
F18B C115 C114 121.7(13) . .
F16B C115 C114 114.6(11) . .
F16A C115 C114 110.3(10) . .
F17A C115 C114 104.5(10) . .
F17B C115 C114 98.1(12) . .
F8A C6A F7A 106.8(9) . .
F8A C6A F9A 104.9(9) . .
F7A C6A F9A 102.4(9) . .
F8A C6A C107 117.0(13) . .
F7A C6A C107 111.6(15) . .
F9A C6A C107 112.9(13) . .
F8B C6B F7B 108.0(10) . .
F8B C6B F9B 106.7(10) . .
F7B C6B F9B 105.8(10) . .
F8B C6B C107 111.6(19) . .
F7B C6B C107 119(2) . .
F9B C6B C107 104.9(18) . .
F14A C11A F15A 105.7(9) . .
F14A C11A F13A 106.6(10) . .
F15A C11A F13A 105.2(9) . .
F14A C11A C112 108.3(17) . .
F15A C11A C112 114.6(15) . .
F13A C11A C112 115.8(15) . .
F14B C11B F15B 107.6(9) . .
F14B C11B F13B 108.4(10) . .
F15B C11B F13B 107.7(10) . .
F14B C11B C112 113.5(16) . .
F15B C11B C112 113.2(14) . .
F13B C11B C112 106.3(14) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu O7 2.304(5) 3_656
Eu O14 2.393(4) .
Eu O5 2.393(5) .
Eu O6 2.394(5) .
Eu O4 2.397(5) .
Eu O2 2.400(5) .
Eu O1 2.413(5) .
Eu O3 2.428(5) .
Eu Zn 3.6408(9) .
Zn O14 2.034(4) .
Zn N3 2.073(5) .
Zn N1 2.131(5) .
Zn N2 2.168(5) .
Zn N4 2.200(6) .
Zn O7 2.296(5) 3_656
N1 C1 1.331(9) .
N1 C8 1.365(9) .
N2 C15 1.341(8) .
N2 C11 1.344(9) .
N3 C16 1.348(8) .
N3 C20 1.349(8) .
N4 C25 1.337(8) .
N4 C21 1.360(9) .
O1 C102 1.237(8) .
O2 C104 1.245(9) .
O3 C107 1.237(10) .
O4 C109 1.214(10) .
O5 C112 1.263(11) .
O6 C114 1.207(11) .
O7 C18 1.309(8) .
O7 Zn 2.296(5) 3_656
O7 Eu 2.304(5) 3_656
O14 C7 1.348(8) .
C1 C2 1.412(11) .
C1 C10 1.492(11) .
C2 C3 1.347(11) .
C3 C9 1.416(11) .
C4 C5 1.360(12) .
C4 C9 1.384(11) .
C5 C6 1.409(11) .
C6 C7 1.380(9) .
C7 C8 1.425(9) .
C8 C9 1.412(9) .
C11 C12 1.376(12) .
C12 C13 1.374(12) .
C13 C14 1.379(11) .
C14 C15 1.388(9) .
C15 C16 1.483(9) .
C16 C17 1.366(9) .
C17 C18 1.403(9) .
C19 C20 1.371(9) .
C19 C18 1.404(9) .
C20 C21 1.483(9) .
C21 C22 1.381(10) .
C22 C23 1.389(11) .
C23 C24 1.364(12) .
C24 C25 1.373(11) .
C103 C102 1.380(10) .
C103 C104 1.382(10) .
C104 C105 1.523(10) .
C102 C101 1.524(10) .
C107 C108 1.413(13) .
C107 C6B 1.490(10) .
C107 C6A 1.501(9) .
C108 C109 1.410(13) .
C109 C110 1.515(11) .
C112 C113 1.431(16) .
C112 C11B 1.489(9) .
C112 C11A 1.502(10) .
C114 C113 1.420(16) .
C114 C115 1.504(14) .
C101 F3A 1.315(8) .
C101 F3B 1.320(8) .
C101 F1A 1.341(8) .
C101 F2A 1.348(8) .
C101 F1B 1.348(8) .
C101 F2B 1.350(8) .
C105 F6A 1.299(8) .
C105 F6B 1.300(8) .
C105 F4A 1.323(8) .
C105 F4B 1.331(8) .
C105 F5A 1.390(8) .
C105 F5B 1.400(9) .
C110 F11A 1.299(8) .
C110 F12A 1.330(8) .
C110 F11B 1.337(9) .
C110 F12B 1.346(9) .
C110 F10A 1.366(8) .
C110 F10B 1.372(9) .
C115 F18A 1.311(8) .
C115 F18B 1.315(10) .
C115 F16B 1.325(9) .
C115 F16A 1.337(9) .
C115 F17A 1.372(9) .
C115 F17B 1.378(9) .
C6A F8A 1.324(9) .
C6A F7A 1.346(10) .
C6A F9A 1.363(9) .
C6B F8B 1.321(10) .
C6B F7B 1.336(10) .
C6B F9B 1.346(10) .
C11A F14A 1.338(10) .
C11A F15A 1.340(9) .
C11A F13A 1.341(10) .
C11B F14B 1.328(10) .
C11B F15B 1.328(9) .
C11B F13B 1.329(10) .
