#------------------------------------------------------------------------------
#$Date: 2016-02-16 02:10:39 +0100 (Tue 16 de Feb de 2016) $
#$Revision: 176453 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/68/7026873.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7026873
loop_
_publ_author_name
'Akgun, Zeynep'
'Engelbrecht, Hendrik'
'Fan, Kuo-Hsien'
'Barnes, Charles Leslie'
'Cutler, Cathy Sue'
'Jurisson, Silvia Sabine'
'Lever, Susan Zemyan'
_publ_section_title
;
 The complexation of rhodium(III) with acyclic diaminedithioether (DADTE)
 ligands.
;
_journal_issue                   42
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              10169
_journal_page_last               10178
_journal_paper_doi               10.1039/c0dt00813c
_journal_volume                  39
_journal_year                    2010
_chemical_formula_sum            'C28 H45 Cl2 F6 N2 O2.5 P Rh S2'
_chemical_formula_weight         835.78
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 94.3150(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   17.8256(11)
_cell_length_b                   10.4632(6)
_cell_length_c                   18.7671(11)
_cell_measurement_reflns_used    5708
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      27.1
_cell_measurement_theta_min      2.4
_cell_volume                     3490.4(4)
_computing_cell_refinement       'SAINT (Bruker, 1998)'
_computing_data_collection       'SMART (Bruker, 1998)'
_computing_data_reduction        'SAINT (Bruker, 1998)'
_computing_molecular_graphics    'ORTEP-III (Burnett & Johnson, 1996)'
_computing_publication_material  'CIFTAB (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Bruker SMART CCD area detector'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0271
_diffrn_reflns_av_sigmaI/netI    0.0305
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_h_min       -22
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            24240
_diffrn_reflns_theta_full        27.14
_diffrn_reflns_theta_max         27.14
_diffrn_reflns_theta_min         2.18
_diffrn_standards_decay_%        0.0
_exptl_absorpt_coefficient_mu    0.871
_exptl_absorpt_correction_T_max  0.96
_exptl_absorpt_correction_T_min  0.67
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
Data were corrected for decay and absorption using the program SADABS
based on the method of R.H. Blessing (Acta Cryst. A51, 33-38, 1995).
;
_exptl_crystal_colour            brown
_exptl_crystal_density_diffrn    1.579
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             1708
_exptl_crystal_size_max          0.50
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.05
_refine_diff_density_max         0.985
_refine_diff_density_min         -0.639
_refine_diff_density_rms         0.077
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.032
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     420
_refine_ls_number_reflns         7684
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.032
_refine_ls_R_factor_all          0.0450
_refine_ls_R_factor_gt           0.0322
_refine_ls_shift/su_max          0.006
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0435P)²+3.2087P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0807
_refine_ls_wR_factor_ref         0.0887
_reflns_number_gt                6278
_reflns_number_total             7684
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c0dt00813c.txt
_cod_data_source_block           232-N2S2-2P-Rh
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'MONOCLINIC' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      P2~1~/c
_cod_original_formula_sum        'C27 H42 N2 O2 S2 Cl2 Rh . P F6 . 0.5(C2H6O)'
_cod_database_code               7026873
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Rh1 Rh 0.721597(10) 0.198658(19) 0.333267(10) 0.02246(7) Uani 1 1 d .
Cl1 Cl 0.78349(3) 0.06489(6) 0.25627(3) 0.02910(14) Uani 1 1 d .
S1 S 0.73997(3) 0.03909(6) 0.41909(3) 0.02675(14) Uani 1 1 d .
P1 P 0.60893(4) -0.18053(8) 0.67078(4) 0.03710(18) Uani 1 1 d .
F1 F 0.62800(14) -0.1081(3) 0.74320(13) 0.0937(9) Uani 1 1 d .
O1 O 1.02132(11) 0.2341(2) 0.65056(11) 0.0397(5) Uani 1 1 d .
N1 N 0.62058(12) 0.1022(2) 0.30416(11) 0.0267(5) Uani 1 1 d .
C1 C 0.64780(15) -0.0467(3) 0.40751(15) 0.0317(6) Uani 1 1 d .
Cl2 Cl 0.65313(4) 0.33154(7) 0.40450(4) 0.03347(15) Uani 1 1 d .
S2 S 0.82999(3) 0.31423(6) 0.37088(3) 0.02568(14) Uani 1 1 d .
F2 F 0.66483(18) -0.2900(3) 0.69216(17) 0.1114(13) Uani 1 1 d .
O2 O 1.18787(10) 0.4149(2) 0.47452(11) 0.0432(5) Uani 1 1 d .
N2 N 0.70725(13) 0.3359(2) 0.25180(12) 0.0269(5) Uani 1 1 d .
C2 C 0.62428(15) -0.0326(3) 0.32816(14) 0.0308(6) Uani 1 1 d .
H2A H 0.6606 -0.0792 0.3003 0.037 Uiso 1 1 calc R
H2B H 0.5743 -0.0726 0.3180 0.037 Uiso 1 1 calc R
F3 F 0.59115(17) -0.2435(4) 0.59523(16) 0.1136(12) Uani 1 1 d .
C3 C 0.59117(15) 0.1067(3) 0.22748(14) 0.0321(6) Uani 1 1 d .
H3A H 0.5397 0.0705 0.2231 0.039 Uiso 1 1 calc R
H3B H 0.6233 0.0524 0.1991 0.039 Uiso 1 1 calc R
F4 F 0.55354(15) -0.0665(3) 0.64950(16) 0.1007(10) Uani 1 1 d .
C4 C 0.58898(16) 0.2399(3) 0.19671(15) 0.0350(6) Uani 1 1 d .
H4A H 0.5643 0.2973 0.2298 0.042 Uiso 1 1 calc R
H4B H 0.5577 0.2390 0.1508 0.042 Uiso 1 1 calc R
F5 F 0.67567(12) -0.1067(2) 0.63569(13) 0.0659(6) Uani 1 1 d .
C5 C 0.66569(16) 0.2944(3) 0.18384(14) 0.0331(6) Uani 1 1 d .
H5A H 0.6955 0.2287 0.1606 0.040 Uiso 1 1 calc R
H5B H 0.6594 0.3683 0.1510 0.040 Uiso 1 1 calc R
F6 F 0.54252(16) -0.2518(3) 0.70358(18) 0.1028(11) Uani 1 1 d .
C6 C 0.78102(15) 0.3922(3) 0.23601(14) 0.0323(6) Uani 1 1 d .
H6A H 0.7723 0.4623 0.2009 0.039 Uiso 1 1 calc R
H6B H 0.8116 0.3260 0.2141 0.039 Uiso 1 1 calc R
C7 C 0.82440(15) 0.4439(3) 0.30244(14) 0.0290(6) Uani 1 1 d .
C8 C 0.66308(19) -0.1869(3) 0.4252(2) 0.0470(8) Uani 1 1 d .
H8A H 0.6829 -0.1947 0.4751 0.071 Uiso 1 1 calc R
H8B H 0.7000 -0.2207 0.3939 0.071 Uiso 1 1 calc R
H8C H 0.6162 -0.2356 0.4179 0.071 Uiso 1 1 calc R
C9 C 0.58873(16) 0.0088(3) 0.45392(16) 0.0410(7) Uani 1 1 d .
H9A H 0.5854 0.1014 0.4467 0.062 Uiso 1 1 calc R
H9B H 0.6033 -0.0092 0.5043 0.062 Uiso 1 1 calc R
H9C H 0.5397 -0.0303 0.4405 0.062 Uiso 1 1 calc R
C10 C 0.90217(17) 0.4875(3) 0.28306(17) 0.0392(7) Uani 1 1 d .
H10A H 0.9274 0.4169 0.2603 0.059 Uiso 1 1 calc R
H10B H 0.9322 0.5137 0.3265 0.059 Uiso 1 1 calc R
H10C H 0.8967 0.5599 0.2500 0.059 Uiso 1 1 calc R
C11 C 0.78398(17) 0.5549(3) 0.33652(16) 0.0379(7) Uani 1 1 d .
H11A H 0.7744 0.6231 0.3012 0.057 Uiso 1 1 calc R
H11B H 0.8156 0.5879 0.3774 0.057 Uiso 1 1 calc R
H11C H 0.7361 0.5247 0.3528 0.057 Uiso 1 1 calc R
C12 C 0.74023(15) 0.0967(3) 0.51107(14) 0.0346(6) Uani 1 1 d .
H12A H 0.7071 0.1725 0.5123 0.042 Uiso 1 1 calc R
H12B H 0.7194 0.0295 0.5410 0.042 Uiso 1 1 calc R
C13 C 0.81783(15) 0.1321(3) 0.54212(13) 0.0299(6) Uani 1 1 d .
C14 C 0.83169(16) 0.2550(3) 0.56851(14) 0.0325(6) Uani 1 1 d .
H14 H 0.7939 0.3186 0.5614 0.039 Uiso 1 1 calc R
C15 C 0.89966(16) 0.2858(3) 0.60492(14) 0.0308(6) Uani 1 1 d .
H15 H 0.9079 0.3695 0.6235 0.037 Uiso 1 1 calc R
C16 C 0.95569(16) 0.1939(3) 0.61417(14) 0.0312(6) Uani 1 1 d .
C17 C 0.94364(17) 0.0720(3) 0.58701(16) 0.0371(7) Uani 1 1 d .
H17 H 0.9823 0.0096 0.5924 0.045 Uiso 1 1 calc R
C18 C 0.87471(16) 0.0415(3) 0.55183(15) 0.0355(6) Uani 1 1 d .
H18 H 0.8663 -0.0427 0.5341 0.043 Uiso 1 1 calc R
C19 C 1.08206(18) 0.1445(3) 0.6577(2) 0.0517(9) Uani 1 1 d .
H19A H 1.0668 0.0698 0.6847 0.078 Uiso 1 1 calc R
H19B H 1.1259 0.1848 0.6832 0.078 Uiso 1 1 calc R
H19C H 1.0951 0.1174 0.6102 0.078 Uiso 1 1 calc R
C20 C 0.91151(15) 0.2182(3) 0.35106(17) 0.0353(6) Uani 1 1 d .
H20A H 0.9054 0.1308 0.3699 0.042 Uiso 1 1 calc R
H20B H 0.9131 0.2117 0.2986 0.042 Uiso 1 1 calc R
C21 C 0.98541(15) 0.2726(3) 0.38250(15) 0.0301(6) Uani 1 1 d .
C22 C 1.04759(16) 0.2766(3) 0.34267(16) 0.0355(6) Uani 1 1 d .
H22 H 1.0429 0.2477 0.2945 0.043 Uiso 1 1 calc R
C23 C 1.11695(15) 0.3218(3) 0.37134(15) 0.0331(6) Uani 1 1 d .
H23 H 1.1591 0.3226 0.3432 0.040 Uiso 1 1 calc R
C24 C 1.12388(15) 0.3654(3) 0.44071(15) 0.0325(6) Uani 1 1 d .
C25 C 1.06132(17) 0.3623(4) 0.48118(16) 0.0554(10) Uani 1 1 d .
H25 H 1.0656 0.3919 0.5292 0.066 Uiso 1 1 calc R
C26 C 0.99367(17) 0.3168(4) 0.45207(16) 0.0482(9) Uani 1 1 d .
H26 H 0.9516 0.3156 0.4803 0.058 Uiso 1 1 calc R
C27 C 1.25420(15) 0.4159(3) 0.43660(17) 0.0409(7) Uani 1 1 d .
H27A H 1.2662 0.3284 0.4227 0.061 Uiso 1 1 calc R
H27B H 1.2961 0.4509 0.4673 0.061 Uiso 1 1 calc R
H27C H 1.2458 0.4690 0.3937 0.061 Uiso 1 1 calc R
C1S C 0.4911(4) -0.4630(5) 0.4683(4) 0.098(2) Uani 1 1 d .
H2N H 0.6845(18) 0.395(3) 0.2707(18) 0.043(10) Uiso 1 1 d .
H1N H 0.5898(16) 0.141(3) 0.3270(16) 0.026(8) Uiso 1 1 d .
O1S O 0.4854(9) -0.3562(17) 0.4695(6) 0.204(6) Uani 0.50 1 d P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_3
N2 Rh1 N1 94.83(9) .
N2 Rh1 S1 176.93(7) .
N1 Rh1 S1 84.75(6) .
N2 Rh1 Cl2 88.24(7) .
N1 Rh1 Cl2 87.72(7) .
S1 Rh1 Cl2 94.78(2) .
N2 Rh1 S2 85.35(6) .
N1 Rh1 S2 176.27(7) .
S1 Rh1 S2 95.27(2) .
Cl2 Rh1 S2 88.56(2) .
N2 Rh1 Cl1 89.81(7) .
N1 Rh1 Cl1 89.24(7) .
S1 Rh1 Cl1 87.14(2) .
Cl2 Rh1 Cl1 176.24(2) .
S2 Rh1 Cl1 94.48(2) .
C12 S1 C1 102.00(13) .
C12 S1 Rh1 114.03(10) .
C1 S1 Rh1 100.80(9) .
F2 P1 F6 92.09(17) .
F2 P1 F1 92.25(19) .
F6 P1 F1 90.60(17) .
F2 P1 F3 90.3(2) .
F6 P1 F3 92.74(17) .
F1 P1 F3 175.7(2) .
F2 P1 F4 178.6(2) .
F6 P1 F4 89.00(17) .
F1 P1 F4 86.85(17) .
F3 P1 F4 90.51(19) .
F2 P1 F5 88.83(14) .
F6 P1 F5 178.72(17) .
F1 P1 F5 90.24(15) .
F3 P1 F5 86.38(15) .
F4 P1 F5 90.08(14) .
C16 O1 C19 117.1(2) .
C2 N1 C3 109.1(2) .
C2 N1 Rh1 111.16(16) .
C3 N1 Rh1 117.83(16) .
C2 C1 C8 109.7(3) .
C2 C1 C9 111.7(2) .
C8 C1 C9 111.1(3) .
C2 C1 S1 103.99(18) .
C8 C1 S1 107.2(2) .
C9 C1 S1 112.8(2) .
C20 S2 C7 105.17(13) .
C20 S2 Rh1 107.78(10) .
C7 S2 Rh1 99.67(8) .
C24 O2 C27 117.8(2) .
C5 N2 C6 109.5(2) .
C5 N2 Rh1 116.69(17) .
C6 N2 Rh1 110.74(17) .
N1 C2 C1 113.1(2) .
N1 C3 C4 113.3(2) .
C3 C4 C5 114.2(2) .
N2 C5 C4 111.7(2) .
N2 C6 C7 112.4(2) .
C6 C7 C10 109.0(2) .
C6 C7 C11 112.8(2) .
C10 C7 C11 109.7(2) .
C6 C7 S2 107.69(18) .
C10 C7 S2 112.23(19) .
C11 C7 S2 105.45(19) .
C13 C12 S1 112.54(18) .
C18 C13 C14 118.3(3) .
C18 C13 C12 121.5(3) .
C14 C13 C12 119.8(3) .
C15 C14 C13 121.1(3) .
C14 C15 C16 119.7(3) .
O1 C16 C17 124.6(3) .
O1 C16 C15 115.3(2) .
C17 C16 C15 120.1(3) .
C16 C17 C18 119.6(3) .
C17 C18 C13 121.1(3) .
C21 C20 S2 113.3(2) .
C26 C21 C22 117.9(3) .
C26 C21 C20 121.4(2) .
C22 C21 C20 120.6(3) .
C21 C22 C23 121.7(3) .
C24 C23 C22 119.5(2) .
O2 C24 C23 125.3(2) .
O2 C24 C25 115.5(3) .
C23 C24 C25 119.2(3) .
C26 C25 C24 120.4(3) .
C25 C26 C21 121.4(3) .
O1S C1S C1S 122.2(11) 3_646
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Rh1 N2 2.099(2) .
Rh1 N1 2.101(2) .
Rh1 S1 2.3259(7) .
Rh1 Cl2 2.3358(7) .
Rh1 S2 2.3427(7) .
Rh1 Cl1 2.3461(6) .
S1 C12 1.828(3) .
S1 C1 1.871(3) .
P1 F2 1.551(2) .
P1 F6 1.564(2) .
P1 F1 1.571(2) .
P1 F3 1.574(3) .
P1 F4 1.580(2) .
P1 F5 1.601(2) .
O1 C16 1.376(3) .
O1 C19 1.431(4) .
N1 C2 1.480(3) .
N1 C3 1.495(3) .
C1 C2 1.524(4) .
C1 C8 1.524(4) .
C1 C9 1.530(4) .
S2 C20 1.828(3) .
S2 C7 1.866(3) .
O2 C24 1.365(3) .
O2 C27 1.425(3) .
N2 C5 1.491(3) .
N2 C6 1.491(3) .
C3 C4 1.508(4) .
C4 C5 1.517(4) .
C6 C7 1.517(4) .
C7 C10 1.529(4) .
C7 C11 1.532(4) .
C12 C13 1.506(4) .
C13 C18 1.390(4) .
C13 C14 1.393(4) .
C14 C15 1.384(4) .
C15 C16 1.388(4) .
C16 C17 1.384(4) .
C17 C18 1.388(4) .
C20 C21 1.513(4) .
C21 C26 1.382(4) .
C21 C22 1.383(4) .
C22 C23 1.394(4) .
C23 C24 1.376(4) .
C24 C25 1.396(4) .
C25 C26 1.371(4) .
C1S O1S 1.123(17) .
C1S C1S 1.436(12) 3_646
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
N2 Rh1 S1 C12 162.9(12)
N1 Rh1 S1 C12 -114.88(12)
Cl2 Rh1 S1 C12 -27.62(10)
S2 Rh1 S1 C12 61.38(10)
Cl1 Rh1 S1 C12 155.62(10)
N2 Rh1 S1 C1 -88.7(12)
N1 Rh1 S1 C1 -6.41(11)
Cl2 Rh1 S1 C1 80.85(9)
S2 Rh1 S1 C1 169.85(9)
Cl1 Rh1 S1 C1 -95.91(9)
N2 Rh1 N1 C2 155.13(17)
S1 Rh1 N1 C2 -21.81(16)
Cl2 Rh1 N1 C2 -116.82(17)
S2 Rh1 N1 C2 -112.3(10)
Cl1 Rh1 N1 C2 65.39(17)
N2 Rh1 N1 C3 28.2(2)
S1 Rh1 N1 C3 -148.8(2)
Cl2 Rh1 N1 C3 116.20(19)
S2 Rh1 N1 C3 120.8(9)
Cl1 Rh1 N1 C3 -61.59(19)
C12 S1 C1 C2 149.95(19)
Rh1 S1 C1 C2 32.28(19)
C12 S1 C1 C8 -93.9(2)
Rh1 S1 C1 C8 148.5(2)
C12 S1 C1 C9 28.8(2)
Rh1 S1 C1 C9 -88.9(2)
N2 Rh1 S2 C20 -108.92(13)
N1 Rh1 S2 C20 158.2(10)
S1 Rh1 S2 C20 68.06(11)
Cl2 Rh1 S2 C20 162.73(11)
Cl1 Rh1 S2 C20 -19.47(11)
N2 Rh1 S2 C7 0.56(11)
N1 Rh1 S2 C7 -92.4(10)
S1 Rh1 S2 C7 177.53(9)
Cl2 Rh1 S2 C7 -87.80(9)
Cl1 Rh1 S2 C7 90.00(9)
N1 Rh1 N2 C5 -31.2(2)
S1 Rh1 N2 C5 50.8(13)
Cl2 Rh1 N2 C5 -118.76(19)
S2 Rh1 N2 C5 152.54(19)
Cl1 Rh1 N2 C5 58.03(19)
N1 Rh1 N2 C6 -157.37(18)
S1 Rh1 N2 C6 -75.4(12)
Cl2 Rh1 N2 C6 115.07(17)
S2 Rh1 N2 C6 26.37(17)
Cl1 Rh1 N2 C6 -68.14(17)
C3 N1 C2 C1 -175.4(2)
Rh1 N1 C2 C1 53.0(3)
C8 C1 C2 N1 -170.5(2)
C9 C1 C2 N1 65.8(3)
S1 C1 C2 N1 -56.1(3)
C2 N1 C3 C4 -177.0(2)
Rh1 N1 C3 C4 -49.1(3)
N1 C3 C4 C5 72.5(3)
C6 N2 C5 C4 -178.2(2)
Rh1 N2 C5 C4 55.0(3)
C3 C4 C5 N2 -75.9(3)
C5 N2 C6 C7 176.6(2)
Rh1 N2 C6 C7 -53.4(3)
N2 C6 C7 C10 174.4(2)
N2 C6 C7 C11 -63.5(3)
N2 C6 C7 S2 52.4(3)
C20 S2 C7 C6 85.1(2)
Rh1 S2 C7 C6 -26.45(19)
C20 S2 C7 C10 -34.9(2)
Rh1 S2 C7 C10 -146.47(19)
C20 S2 C7 C11 -154.28(19)
Rh1 S2 C7 C11 94.18(17)
C1 S1 C12 C13 161.4(2)
Rh1 S1 C12 C13 -90.9(2)
S1 C12 C13 C18 -63.5(3)
S1 C12 C13 C14 123.1(2)
C18 C13 C14 C15 -1.4(4)
C12 C13 C14 C15 172.2(2)
C13 C14 C15 C16 1.3(4)
C19 O1 C16 C17 2.9(4)
C19 O1 C16 C15 -176.6(3)
C14 C15 C16 O1 179.5(2)
C14 C15 C16 C17 0.1(4)
O1 C16 C17 C18 179.3(3)
C15 C16 C17 C18 -1.4(4)
C16 C17 C18 C13 1.3(5)
C14 C13 C18 C17 0.1(4)
C12 C13 C18 C17 -173.4(3)
C7 S2 C20 C21 82.9(2)
Rh1 S2 C20 C21 -171.42(18)
S2 C20 C21 C26 45.1(4)
S2 C20 C21 C22 -136.5(3)
C26 C21 C22 C23 0.8(5)
C20 C21 C22 C23 -177.6(3)
C21 C22 C23 C24 -0.9(5)
C27 O2 C24 C23 -3.5(4)
C27 O2 C24 C25 177.6(3)
C22 C23 C24 O2 -178.3(3)
C22 C23 C24 C25 0.6(5)
O2 C24 C25 C26 178.7(3)
C23 C24 C25 C26 -0.2(6)
C24 C25 C26 C21 0.2(6)
C22 C21 C26 C25 -0.5(5)
C20 C21 C26 C25 177.9(3)
