#------------------------------------------------------------------------------
#$Date: 2016-03-25 15:36:21 +0100 (vie 25 de mar de 2016) $
#$Revision: 179979 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/73/7027383.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided the Crystal Eye server at
# http://wwmm.ch.cam.ac.uk/crystaleye/, created by Nick Day at the
# Peter Murray-Rust laboratory.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_7027383
loop_
_publ_author_name
'Adams, Harry'
'Elsegood, Mark R. J.'
'Fenton, David E.'
'Heath, Sarah L.'
'Ryan, Sara J.'
_publ_section_title
;
 Dinuclear silver(I) complexes of bibracchial tetraimine Schiff base
 macrocycles derived from pyrrole-2,5-dicarbaldehyde
;
_journal_issue                   12
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              2031
_journal_paper_doi               10.1039/a901992h
_journal_year                    1999
_chemical_formula_sum            'C38 H49 Ag2 Cl2 N11 O8'
_chemical_formula_weight         1074.52
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL
_cell_angle_alpha                90.352(2)
_cell_angle_beta                 97.606(2)
_cell_angle_gamma                102.199(2)
_cell_formula_units_Z            2
_cell_length_a                   10.0484(2)
_cell_length_b                   12.2896(3)
_cell_length_c                   18.0780(4)
_cell_measurement_reflns_used    9933
_cell_measurement_temperature    160(2)
_cell_measurement_theta_max      28.35
_cell_measurement_theta_min      2.01
_cell_volume                     2161.52(9)
_computing_cell_refinement       'local programs'
_computing_data_collection       'Siemens SMART'
_computing_data_reduction        'Siemens SAINT'
_computing_molecular_graphics    'Siemens SHELXTL'
_computing_publication_material  'SHELXTL and local programs'
_computing_structure_refinement  'Siemens SHELXTL'
_computing_structure_solution    'Siemens SHELXTL'
_diffrn_ambient_temperature      160(2)
_diffrn_measurement_device       'Siemens SMART CCD diffractometer'
_diffrn_measurement_method       'ω rotation with narrow frames'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0238
_diffrn_reflns_av_sigmaI/netI    0.0489
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            15636
_diffrn_reflns_theta_max         28.40
_diffrn_reflns_theta_min         1.14
_diffrn_standards_decay_%        0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.094
_exptl_absorpt_correction_T_max  0.862
_exptl_absorpt_correction_T_min  0.741
_exptl_absorpt_correction_type   empirical
_exptl_crystal_colour            Yellow
_exptl_crystal_density_diffrn    1.651
_exptl_crystal_description       Plate
_exptl_crystal_F_000             1092
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.06
_refine_diff_density_max         0.561
_refine_diff_density_min         -0.469
_refine_diff_density_rms         0.083
_refine_ls_extinction_coef       0.0014(2)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_all   1.022
_refine_ls_goodness_of_fit_obs   1.056
_refine_ls_matrix_type           full
_refine_ls_number_parameters     595
_refine_ls_number_reflns         9399
_refine_ls_number_restraints     55
_refine_ls_restrained_S_all      1.135
_refine_ls_restrained_S_obs      1.055
_refine_ls_R_factor_all          0.0536
_refine_ls_R_factor_obs          0.0346
_refine_ls_shift/esd_max         -0.001
_refine_ls_shift/esd_mean        0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0313P)²+0.3980P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         0.0858
_refine_ls_wR_factor_obs         0.0698
_reflns_number_observed          7343
_reflns_number_total             9400
_reflns_observed_criterion       >2sigma(I)
_cod_data_source_file            901992hsup1.cif
_cod_data_source_block           2
_cod_depositor_comments
;
The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'calc
w=1/[\s^2^(Fo^2^)+(0.0313P)^2^+0.3980P] where P=(Fo^2^+2Fc^2^)/3' was
changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to
'w=1/[\s^2^(Fo^2^)+(0.0313P)^2^+0.3980P] where P=(Fo^2^+2Fc^2^)/3'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_cell_volume        2161.52(8)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7027383
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_thermal_displace_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_group
Ag1 Ag 0.17949(2) 0.85493(2) 0.421947(13) 0.02597(9) Uani 0.9412(8) d PU 1
Ag1A Ag 0.2715(4) 0.8519(3) 0.4739(2) 0.0346(14) Uani 0.0588(8) d PU 2
N6 N 0.1229(2) 0.8881(2) 0.29488(12) 0.0226(5) Uani 1 d . .
H6A H 0.1302(2) 0.8806(2) 0.34354(12) 0.027 Uiso 0.0588(8) calc PR 2
N8 N 0.5100(2) 0.8492(2) 0.51629(13) 0.0243(5) Uani 1 d . .
H8 H 0.4201(2) 0.8357(2) 0.50464(13) 0.029 Uiso 0.9412(8) calc PR 1
Ag2 Ag 0.03829(2) 0.49958(2) 0.193595(13) 0.02763(9) Uani 0.9722(9) d PU 1
Ag2A Ag -0.0365(11) 0.5162(10) 0.1410(6) 0.054(4) Uani 0.0278(9) d PU 2
N1 N 0.2573(2) 0.5695(2) 0.24791(12) 0.0228(5) Uani 1 d . .
H1A H 0.1726(2) 0.5360(2) 0.23036(12) 0.027 Uiso 0.0278(9) calc PR 2
N2 N 0.1390(2) 0.6259(2) 0.10947(12) 0.0216(5) Uani 1 d . .
N3 N -0.1247(2) 0.5939(2) 0.02440(13) 0.0270(5) Uani 1 d . .
H3 H -0.1128(2) 0.5691(2) 0.06984(13) 0.032 Uiso 0.9722(9) calc PR 1
N4 N -0.1556(2) 0.3801(2) 0.19512(12) 0.0234(5) Uani 1 d . .
N5 N -0.2452(2) 0.6000(2) 0.15882(12) 0.0219(5) Uani 1 d . .
N7 N 0.3848(2) 0.9031(2) 0.37449(12) 0.0208(5) Uani 1 d . .
N9 N 0.1102(2) 0.8199(2) 0.53227(13) 0.0246(5) Uani 1 d . .
N10 N 0.2920(2) 0.6593(2) 0.51645(12) 0.0199(5) Uani 1 d . .
C1 C 0.3289(3) 0.6403(2) 0.2093(2) 0.0239(6) Uani 1 d . .
H1 H 0.4213(3) 0.6737(2) 0.2286(2) 0.029 Uiso 1 calc R .
C2 C 0.2705(3) 0.6705(2) 0.1361(2) 0.0235(6) Uani 1 d . .
C3 C 0.3347(3) 0.7434(2) 0.0854(2) 0.0327(7) Uani 1 d . .
H3C H 0.4268(3) 0.7851(2) 0.0921(2) 0.039 Uiso 1 calc R .
C4 C 0.2374(3) 0.7422(3) 0.0241(2) 0.0337(7) Uani 1 d . .
H4A H 0.2492(3) 0.7818(3) -0.0204(2) 0.040 Uiso 1 calc R .
C5 C 0.1163(3) 0.6703(2) 0.0405(2) 0.0261(6) Uani 1 d . .
C6 C -0.0153(3) 0.6478(2) -0.0015(2) 0.0274(6) Uani 1 d . .
H6B H -0.0248(3) 0.6731(2) -0.0511(2) 0.033 Uiso 1 calc R .
C7 C -0.2651(3) 0.5706(2) -0.0145(2) 0.0293(7) Uani 1 d . .
H7A H -0.3023(3) 0.4891(2) -0.0180(2) 0.035 Uiso 1 calc R .
H7B H -0.2655(3) 0.5983(2) -0.0658(2) 0.035 Uiso 1 calc R .
C8 C -0.3548(3) 0.6271(2) 0.02764(15) 0.0268(6) Uani 1 d . .
H8B H -0.4464(3) 0.6184(2) -0.00251(15) 0.032 Uiso 1 calc R .
H8C H -0.3134(3) 0.7077(2) 0.03345(15) 0.032 Uiso 1 calc R .
C9 C -0.3732(3) 0.5809(2) 0.10463(15) 0.0250(6) Uani 1 d . .
H9A H -0.4414(3) 0.6153(2) 0.12561(15) 0.030 Uiso 1 calc R .
H9B H -0.4116(3) 0.4997(2) 0.09878(15) 0.030 Uiso 1 calc R .
C10 C -0.2036(3) 0.7191(2) 0.1844(2) 0.0241(6) Uani 1 d . .
H10A H -0.2676(3) 0.7353(2) 0.2180(2) 0.029 Uiso 1 calc R .
H10B H -0.2104(3) 0.7666(2) 0.1406(2) 0.029 Uiso 1 calc R .
C11 C -0.0584(3) 0.7477(2) 0.2250(2) 0.0247(6) Uani 1 d . .
H11A H 0.0050(3) 0.7280(2) 0.1922(2) 0.030 Uiso 1 calc R .
H11B H -0.0528(3) 0.7025(2) 0.2700(2) 0.030 Uiso 1 calc R .
C12 C -0.0122(3) 0.8708(2) 0.2484(2) 0.0259(6) Uani 1 d . .
H12A H -0.0055(3) 0.9166(2) 0.2036(2) 0.031 Uiso 1 calc R .
H12B H -0.0799(3) 0.8935(2) 0.2770(2) 0.031 Uiso 1 calc R .
C13 C 0.2290(3) 0.9143(2) 0.2616(2) 0.0236(6) Uani 1 d . .
H13A H 0.2174(3) 0.9287(2) 0.2099(2) 0.028 Uiso 1 calc R .
C14 C 0.3661(3) 0.9228(2) 0.30054(15) 0.0221(6) Uani 1 d . .
C15 C 0.4930(3) 0.9486(2) 0.2719(2) 0.0278(7) Uani 1 d . .
H15A H 0.5064(3) 0.9646(2) 0.2217(2) 0.033 Uiso 1 calc R .
C16 C 0.5930(3) 0.9457(2) 0.3311(2) 0.0282(7) Uani 1 d . .
H16A H 0.6894(3) 0.9604(2) 0.3302(2) 0.034 Uiso 1 calc R .
C17 C 0.5244(3) 0.9166(2) 0.3936(2) 0.0231(6) Uani 1 d . .
C18 C 0.5822(3) 0.8935(2) 0.4660(2) 0.0241(6) Uani 1 d . .
H18A H 0.6794(3) 0.9115(2) 0.4781(2) 0.029 Uiso 1 calc R .
C19 C 0.5634(3) 0.8191(2) 0.59092(15) 0.0255(6) Uani 1 d . .
H19A H 0.5272(3) 0.8588(2) 0.62899(15) 0.031 Uiso 1 calc R .
H19B H 0.6649(3) 0.8425(2) 0.59871(15) 0.031 Uiso 1 calc R .
C20 C 0.5216(3) 0.6934(2) 0.6004(2) 0.0239(6) Uani 1 d . .
H20A H 0.5610(3) 0.6549(2) 0.5631(2) 0.029 Uiso 1 calc R .
H20B H 0.5622(3) 0.6756(2) 0.6506(2) 0.029 Uiso 1 calc R .
C21 C 0.3673(3) 0.6479(2) 0.59149(15) 0.0243(6) Uani 1 d . .
H21A H 0.3505(3) 0.5679(2) 0.60311(15) 0.029 Uiso 1 calc R .
H21B H 0.3284(3) 0.6866(2) 0.62885(15) 0.029 Uiso 1 calc R .
C22 C 0.1438(3) 0.6300(2) 0.5202(2) 0.0243(6) Uani 1 d . .
H22A H 0.1224(3) 0.5588(2) 0.5460(2) 0.029 Uiso 1 calc R .
H22B H 0.0940(3) 0.6182(2) 0.4687(2) 0.029 Uiso 1 calc R .
C23 C 0.0923(3) 0.7171(2) 0.5602(2) 0.0235(6) Uani 1 d . .
C24 C 0.0231(3) 0.6909(3) 0.6211(2) 0.0360(8) Uani 1 d . .
H24A H 0.0134(3) 0.6182(3) 0.6402(2) 0.043 Uiso 1 calc R .
C25 C -0.0316(4) 0.7690(3) 0.6543(2) 0.0450(9) Uani 1 d . .
H25A H -0.0826(4) 0.7508(3) 0.6949(2) 0.054 Uiso 1 calc R .
C26 C -0.0100(3) 0.8750(3) 0.6268(2) 0.0388(8) Uani 1 d . .
H26C H -0.0440(3) 0.9318(3) 0.6491(2) 0.047 Uiso 1 calc R .
C27 C 0.0610(3) 0.8976(3) 0.5669(2) 0.0315(7) Uani 1 d . .
H27A H 0.0761(3) 0.9711(3) 0.5490(2) 0.038 Uiso 1 calc R .
C28 C -0.2693(3) 0.5295(2) 0.22307(15) 0.0244(6) Uani 1 d . .
H28A H -0.3571(3) 0.5370(2) 0.23962(15) 0.029 Uiso 1 calc R .
H28B H -0.1949(3) 0.5566(2) 0.26476(15) 0.029 Uiso 1 calc R .
C29 C -0.2750(3) 0.4086(2) 0.20665(15) 0.0227(6) Uani 1 d . .
C30 C -0.3952(3) 0.3286(2) 0.2057(2) 0.0289(7) Uani 1 d . .
H30A H -0.4783(3) 0.3503(2) 0.2123(2) 0.035 Uiso 1 calc R .
C31 C -0.3943(3) 0.2172(2) 0.1951(2) 0.0367(8) Uani 1 d . .
H31A H -0.4758(3) 0.1616(2) 0.1953(2) 0.044 Uiso 1 calc R .
C32 C -0.2727(3) 0.1884(3) 0.1842(2) 0.0342(7) Uani 1 d . .
H32A H -0.2686(3) 0.1126(3) 0.1771(2) 0.041 Uiso 1 calc R .
C33 C -0.1582(3) 0.2714(2) 0.1839(2) 0.0282(7) Uani 1 d . .
H33A H -0.0754(3) 0.2510(2) 0.1752(2) 0.034 Uiso 1 calc R .
C34 C 0.3206(3) 0.5456(2) 0.32230(14) 0.0251(6) Uani 1 d . .
H34A H 0.4219(3) 0.5691(2) 0.32625(14) 0.030 Uiso 1 calc R .
H34B H 0.2970(3) 0.4646(2) 0.33033(14) 0.030 Uiso 1 calc R .
C35 C 0.2687(3) 0.6079(2) 0.38068(15) 0.0268(7) Uani 1 d . .
H35A H 0.1672(3) 0.5855(2) 0.37512(15) 0.032 Uiso 1 calc R .
H35B H 0.2934(3) 0.6888(2) 0.37222(15) 0.032 Uiso 1 calc R .
C36 C 0.3277(3) 0.5860(2) 0.46012(14) 0.0230(6) Uani 1 d . .
H36A H 0.2919(3) 0.5073(2) 0.47116(14) 0.028 Uiso 1 calc R .
H36B H 0.4289(3) 0.5981(2) 0.46372(14) 0.028 Uiso 1 calc R .
Cl1 Cl 0.20975(7) 1.20170(6) 0.17303(4) 0.0272(2) Uani 1 d . .
Cl2 Cl -0.21306(7) 0.71100(6) 0.41314(4) 0.0275(2) Uani 1 d . .
O1 O 0.2920(2) 1.1759(2) 0.23794(13) 0.0476(6) Uani 1 d . .
O2 O 0.1901(2) 1.3140(2) 0.18139(13) 0.0415(6) Uani 1 d . .
O3 O 0.0782(2) 1.1261(2) 0.16491(14) 0.0475(6) Uani 1 d . .
O4 O 0.2761(3) 1.1935(2) 0.10838(13) 0.0524(7) Uani 1 d . .
O5 O -0.1496(2) 0.8248(2) 0.40274(13) 0.0404(6) Uani 1 d . .
O6 O -0.1213(2) 0.6402(2) 0.39856(12) 0.0401(6) Uani 1 d . .
O7 O -0.2396(3) 0.7001(2) 0.48857(13) 0.0548(7) Uani 1 d . .
O8 O -0.3382(2) 0.6799(2) 0.36327(14) 0.0542(7) Uani 1 d . .
N1S N 0.7104(27) 0.9421(27) 0.0838(19) 0.094(5) Uani 0.50 d PU 1
C1S C 0.6426(11) 0.9514(7) 0.0331(5) 0.067(2) Uani 0.50 d PU 1
C2S C 0.5565(11) 0.9598(9) -0.0360(6) 0.092(3) Uani 0.50 d PU 1
N1SA N 0.7608(24) 0.9611(22) 0.0676(17) 0.086(4) Uani 0.50 d PU 2
C1SA C 0.8618(10) 0.9798(10) 0.0346(7) 0.100(4) Uani 0.50 d PDU 2
C2SA C 1.0000 1.0000 0.0000 0.156(4) Uani 1 d SDU 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_3
N9 Ag1 N7 137.55(8) .
N9 Ag1 N6 148.24(8) .
N7 Ag1 N6 73.85(8) .
N9 Ag1A N7 157.0(2) .
N9 Ag1A N8 128.4(2) .
N7 Ag1A N8 74.5(2) .
N9 Ag1A N10 81.4(2) .
N7 Ag1A N10 112.4(2) .
N8 Ag1A N10 69.92(13) .
C13 N6 C12 117.2(2) .
C13 N6 Ag1 112.3(2) .
C12 N6 Ag1 130.1(2) .
C18 N8 C19 126.2(2) .
C18 N8 Ag1A 107.9(2) .
C19 N8 Ag1A 125.1(2) .
N4 Ag2 N1 148.61(8) .
N4 Ag2 N2 137.03(8) .
N1 Ag2 N2 74.00(8) .
N2 Ag2A N4 159.0(6) .
N2 Ag2A N3 76.0(4) .
N4 Ag2A N3 123.4(5) .
N2 Ag2A N5 117.3(5) .
N4 Ag2A N5 80.3(4) .
N3 Ag2A N5 69.3(3) .
C1 N1 C34 118.1(2) .
C1 N1 Ag2 114.8(2) .
C34 N1 Ag2 127.0(2) .
C2 N2 C5 105.5(2) .
C2 N2 Ag2A 140.4(4) .
C5 N2 Ag2A 114.0(3) .
C2 N2 Ag2 110.5(2) .
C5 N2 Ag2 143.9(2) .
C6 N3 C7 126.5(2) .
C6 N3 Ag2A 104.7(3) .
C7 N3 Ag2A 128.1(3) .
C33 N4 C29 117.6(2) .
C33 N4 Ag2A 125.7(4) .
C29 N4 Ag2A 108.0(3) .
C33 N4 Ag2 118.4(2) .
C29 N4 Ag2 124.0(2) .
C28 N5 C9 108.9(2) .
C28 N5 C10 109.8(2) .
C9 N5 C10 110.5(2) .
C28 N5 Ag2A 89.8(3) .
C9 N5 Ag2A 123.3(3) .
C10 N5 Ag2A 112.1(3) .
C14 N7 C17 105.4(2) .
C14 N7 Ag1A 143.3(2) .
C17 N7 Ag1A 111.3(2) .
C14 N7 Ag1 112.0(2) .
C17 N7 Ag1 142.6(2) .
C27 N9 C23 117.8(3) .
C27 N9 Ag1A 125.2(2) .
C23 N9 Ag1A 111.9(2) .
C27 N9 Ag1 119.1(2) .
C23 N9 Ag1 122.0(2) .
C22 N10 C36 109.9(2) .
C22 N10 C21 108.9(2) .
C36 N10 C21 110.9(2) .
C22 N10 Ag1A 90.3(2) .
C36 N10 Ag1A 115.5(2) .
C21 N10 Ag1A 119.0(2) .
N1 C1 C2 120.8(3) .
N2 C2 C3 111.6(2) .
N2 C2 C1 119.9(3) .
C3 C2 C1 128.6(3) .
C4 C3 C2 106.3(3) .
C3 C4 C5 106.2(3) .
N2 C5 C6 121.0(3) .
N2 C5 C4 110.4(3) .
C6 C5 C4 128.5(3) .
N3 C6 C5 123.1(3) .
N3 C7 C8 109.8(2) .
C7 C8 C9 113.7(2) .
N5 C9 C8 114.6(2) .
N5 C10 C11 112.1(2) .
C10 C11 C12 112.5(2) .
N6 C12 C11 108.6(2) .
N6 C13 C14 121.8(3) .
N7 C14 C15 111.2(3) .
N7 C14 C13 120.0(3) .
C15 C14 C13 128.8(3) .
C16 C15 C14 106.2(3) .
C15 C16 C17 106.5(3) .
N7 C17 C16 110.7(2) .
N7 C17 C18 121.4(3) .
C16 C17 C18 127.7(3) .
N8 C18 C17 123.6(3) .
N8 C19 C20 110.8(2) .
C21 C20 C19 114.3(2) .
N10 C21 C20 115.4(2) .
N10 C22 C23 113.5(2) .
N9 C23 C24 121.4(3) .
N9 C23 C22 117.5(2) .
C24 C23 C22 121.0(3) .
C25 C24 C23 120.7(3) .
C24 C25 C26 117.7(3) .
C27 C26 C25 119.6(3) .
N9 C27 C26 122.8(3) .
N5 C28 C29 113.5(2) .
N4 C29 C30 121.1(3) .
N4 C29 C28 117.1(2) .
C30 C29 C28 121.8(3) .
C31 C30 C29 120.0(3) .
C32 C31 C30 118.7(3) .
C33 C32 C31 118.5(3) .
N4 C33 C32 124.0(3) .
N1 C34 C35 109.2(2) .
C34 C35 C36 112.6(2) .
N10 C36 C35 112.2(2) .
O1 Cl1 O4 110.19(15) .
O1 Cl1 O3 109.13(15) .
O4 Cl1 O3 110.2(2) .
O1 Cl1 O2 109.17(14) .
O4 Cl1 O2 109.18(14) .
O3 Cl1 O2 108.92(14) .
O7 Cl2 O8 110.2(2) .
O7 Cl2 O5 108.58(15) .
O8 Cl2 O5 109.78(15) .
O7 Cl2 O6 109.31(14) .
O8 Cl2 O6 109.47(13) .
O5 Cl2 O6 109.44(14) .
N1S C1S C2S 176.9(19) .
N1SA C1SA C2SA 173.9(17) .
C1SA C2SA C1SA 180.000(2) 2_775
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N9 2.213(2) .
Ag1 N7 2.303(2) .
Ag1 N6 2.352(2) .
Ag1A N9 2.021(5) .
Ag1A N7 2.274(5) .
Ag1A N8 2.425(5) .
Ag1A N10 2.534(4) .
N6 C13 1.276(3) .
N6 C12 1.473(3) .
N8 C18 1.290(3) .
N8 C19 1.464(3) .
Ag2 N4 2.181(2) .
Ag2 N1 2.273(2) .
Ag2 N2 2.349(2) .
Ag2A N2 2.126(11) .
Ag2A N4 2.162(11) .
Ag2A N3 2.455(11) .
Ag2A N5 2.579(12) .
N1 C1 1.280(3) .
N1 C34 1.468(3) .
N2 C2 1.342(3) .
N2 C5 1.375(3) .
N3 C6 1.304(4) .
N3 C7 1.459(4) .
N4 C33 1.344(4) .
N4 C29 1.360(4) .
N5 C28 1.469(3) .
N5 C9 1.485(3) .
N5 C10 1.487(3) .
N7 C14 1.356(3) .
N7 C17 1.374(3) .
N9 C27 1.350(4) .
N9 C23 1.350(3) .
N10 C22 1.467(3) .
N10 C36 1.483(3) .
N10 C21 1.486(3) .
C1 C2 1.458(4) .
C2 C3 1.409(4) .
C3 C4 1.375(4) .
C4 C5 1.412(4) .
C5 C6 1.406(4) .
C7 C8 1.521(4) .
C8 C9 1.525(4) .
C10 C11 1.513(4) .
C11 C12 1.526(4) .
C13 C14 1.445(4) .
C14 C15 1.414(4) .
C15 C16 1.375(4) .
C16 C17 1.409(4) .
C17 C18 1.414(4) .
C19 C20 1.530(4) .
C20 C21 1.519(4) .
C22 C23 1.503(4) .
C23 C24 1.383(4) .
C24 C25 1.374(4) .
C25 C26 1.382(5) .
C26 C27 1.372(4) .
C28 C29 1.501(4) .
C29 C30 1.385(4) .
C30 C31 1.384(4) .
C31 C32 1.379(4) .
C32 C33 1.368(4) .
C34 C35 1.509(4) .
C35 C36 1.527(4) .
Cl1 O1 1.421(2) .
Cl1 O4 1.433(2) .
Cl1 O3 1.436(2) .
Cl1 O2 1.444(2) .
Cl2 O7 1.425(2) .
Cl2 O8 1.426(2) .
Cl2 O5 1.433(2) .
Cl2 O6 1.441(2) .
N1S C1S 1.09(4) .
C1S C2S 1.439(13) .
N1SA C1SA 1.23(2) .
C1SA C2SA 1.571(9) .
C2SA C1SA 1.571(9) 2_775
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_4
N9 Ag1 N6 C13 173.5(2) .
N7 Ag1 N6 C13 0.9(2) .
N9 Ag1 N6 C12 -14.3(3) .
N7 Ag1 N6 C12 173.1(2) .
N9 Ag1A N8 C18 -168.7(2) .
N7 Ag1A N8 C18 9.4(2) .
N10 Ag1A N8 C18 130.9(2) .
N9 Ag1A N8 C19 2.3(4) .
N7 Ag1A N8 C19 -179.5(2) .
N10 Ag1A N8 C19 -58.1(2) .
N4 Ag2 N1 C1 172.2(2) .
N2 Ag2 N1 C1 -0.3(2) .
N4 Ag2 N1 C34 -10.8(3) .
N2 Ag2 N1 C34 176.7(2) .
N4 Ag2A N2 C2 -30.2(21) .
N3 Ag2A N2 C2 171.5(4) .
N5 Ag2A N2 C2 114.1(5) .
N4 Ag2A N2 C5 151.7(16) .
N3 Ag2A N2 C5 -6.7(4) .
N5 Ag2A N2 C5 -64.0(6) .
N4 Ag2A N2 Ag2 -23.0(12) .
N3 Ag2A N2 Ag2 178.6(8) .
N5 Ag2A N2 Ag2 121.3(9) .
N4 Ag2 N2 C2 -173.1(2) .
N1 Ag2 N2 C2 1.2(2) .
N4 Ag2 N2 C5 3.5(4) .
N1 Ag2 N2 C5 177.8(3) .
N4 Ag2 N2 Ag2A 11.8(7) .
N1 Ag2 N2 Ag2A -174.0(7) .
N2 Ag2A N3 C6 9.4(4) .
N4 Ag2A N3 C6 -161.5(5) .
N5 Ag2A N3 C6 136.3(2) .
N2 Ag2A N3 C7 -179.9(2) .
N4 Ag2A N3 C7 9.2(8) .
N5 Ag2A N3 C7 -53.1(4) .
N2 Ag2A N4 C33 -63.2(18) .
N3 Ag2A N4 C33 91.5(6) .
N5 Ag2A N4 C33 148.6(3) .
N2 Ag2A N4 C29 150.4(16) .
N3 Ag2A N4 C29 -54.9(6) .
N5 Ag2A N4 C29 2.2(3) .
N2 Ag2A N4 Ag2 23.8(13) .
N3 Ag2A N4 Ag2 178.4(11) .
N5 Ag2A N4 Ag2 -124.5(7) .
N1 Ag2 N4 C33 -67.6(3) .
N2 Ag2 N4 C33 101.8(2) .
N1 Ag2 N4 C29 112.5(2) .
N2 Ag2 N4 C29 -78.1(2) .
N1 Ag2 N4 Ag2A 179.6(6) .
N2 Ag2 N4 Ag2A -11.1(6) .
N2 Ag2A N5 C28 -141.5(5) .
N4 Ag2A N5 C28 26.3(3) .
N3 Ag2A N5 C28 157.7(2) .
N2 Ag2A N5 C9 105.8(5) .
N4 Ag2A N5 C9 -86.4(4) .
N3 Ag2A N5 C9 45.0(4) .
N2 Ag2A N5 C10 -30.1(6) .
N4 Ag2A N5 C10 137.6(3) .
N3 Ag2A N5 C10 -91.0(3) .
N9 Ag1A N7 C14 -13.4(8) .
N8 Ag1A N7 C14 170.4(3) .
N10 Ag1A N7 C14 110.4(3) .
N9 Ag1A N7 C17 169.7(5) .
N8 Ag1A N7 C17 -6.5(2) .
N10 Ag1A N7 C17 -66.6(2) .
N9 Ag1A N7 Ag1 -11.4(4) .
N8 Ag1A N7 Ag1 172.4(2) .
N10 Ag1A N7 Ag1 112.3(3) .
N9 Ag1 N7 C14 -175.3(2) .
N6 Ag1 N7 C14 -1.0(2) .
N9 Ag1 N7 C17 7.6(3) .
N6 Ag1 N7 C17 -178.1(3) .
N9 Ag1 N7 Ag1A 6.0(2) .
N6 Ag1 N7 Ag1A -179.8(2) .
N7 Ag1A N9 C27 -79.7(6) .
N8 Ag1A N9 C27 95.6(3) .
N10 Ag1A N9 C27 151.4(2) .
N7 Ag1A N9 C23 126.6(5) .
N8 Ag1A N9 C23 -58.1(3) .
N10 Ag1A N9 C23 -2.4(2) .
N7 Ag1A N9 Ag1 11.2(4) .
N8 Ag1A N9 Ag1 -173.5(4) .
N10 Ag1A N9 Ag1 -117.8(2) .
N7 Ag1 N9 C27 104.3(2) .
N6 Ag1 N9 C27 -65.1(3) .
N7 Ag1 N9 C23 -87.7(2) .
N6 Ag1 N9 C23 102.8(2) .
N7 Ag1 N9 Ag1A -6.3(2) .
N6 Ag1 N9 Ag1A -175.8(2) .
N9 Ag1A N10 C22 27.4(2) .
N7 Ag1A N10 C22 -133.4(2) .
N8 Ag1A N10 C22 163.8(2) .
N9 Ag1A N10 C36 139.7(2) .
N7 Ag1A N10 C36 -21.1(3) .
N8 Ag1A N10 C36 -83.9(2) .
N9 Ag1A N10 C21 -84.5(2) .
N7 Ag1A N10 C21 114.6(2) .
N8 Ag1A N10 C21 51.8(2) .
C34 N1 C1 C2 -177.9(2) .
Ag2 N1 C1 C2 -0.5(3) .
C5 N2 C2 C3 -0.2(3) .
Ag2A N2 C2 C3 -178.4(6) .
Ag2 N2 C2 C3 177.7(2) .
C5 N2 C2 C1 -179.8(2) .
Ag2A N2 C2 C1 1.9(7) .
Ag2 N2 C2 C1 -1.9(3) .
N1 C1 C2 N2 1.8(4) .
N1 C1 C2 C3 -177.8(3) .
N2 C2 C3 C4 -0.7(3) .
C1 C2 C3 C4 178.9(3) .
C2 C3 C4 C5 1.2(3) .
C2 N2 C5 C6 -175.2(3) .
Ag2A N2 C5 C6 3.6(5) .
Ag2 N2 C5 C6 8.1(5) .
C2 N2 C5 C4 1.0(3) .
Ag2A N2 C5 C4 179.8(4) .
Ag2 N2 C5 C4 -175.7(2) .
C3 C4 C5 N2 -1.4(3) .
C3 C4 C5 C6 174.4(3) .
C7 N3 C6 C5 177.7(3) .
Ag2A N3 C6 C5 -11.4(4) .
N2 C5 C6 N3 6.9(4) .
C4 C5 C6 N3 -168.6(3) .
C6 N3 C7 C8 -117.4(3) .
Ag2A N3 C7 C8 73.8(5) .
N3 C7 C8 C9 -65.5(3) .
C28 N5 C9 C8 -166.4(2) .
C10 N5 C9 C8 72.9(3) .
Ag2A N5 C9 C8 -63.6(4) .
C7 C8 C9 N5 65.1(3) .
C28 N5 C10 C11 73.1(3) .
C9 N5 C10 C11 -166.7(2) .
Ag2A N5 C10 C11 -25.1(4) .
N5 C10 C11 C12 177.4(2) .
C13 N6 C12 C11 91.9(3) .
Ag1 N6 C12 C11 -80.0(3) .
C10 C11 C12 N6 173.4(2) .
C12 N6 C13 C14 -174.0(2) .
Ag1 N6 C13 C14 -0.7(3) .
C17 N7 C14 C15 0.2(3) .
Ag1A N7 C14 C15 -176.9(3) .
Ag1 N7 C14 C15 -178.0(2) .
C17 N7 C14 C13 179.3(2) .
Ag1A N7 C14 C13 2.2(5) .
Ag1 N7 C14 C13 1.1(3) .
N6 C13 C14 N7 -0.3(4) .
N6 C13 C14 C15 178.7(3) .
N7 C14 C15 C16 -0.7(3) .
C13 C14 C15 C16 -179.7(3) .
C14 C15 C16 C17 0.9(3) .
C14 N7 C17 C16 0.4(3) .
Ag1A N7 C17 C16 178.6(2) .
Ag1 N7 C17 C16 177.7(2) .
C14 N7 C17 C18 -174.6(2) .
Ag1A N7 C17 C18 3.5(3) .
Ag1 N7 C17 C18 2.6(4) .
C15 C16 C17 N7 -0.9(3) .
C15 C16 C17 C18 173.8(3) .
C19 N8 C18 C17 177.4(2) .
Ag1A N8 C18 C17 -11.7(3) .
N7 C17 C18 N8 6.5(4) .
C16 C17 C18 N8 -167.6(3) .
C18 N8 C19 C20 -117.1(3) .
Ag1A N8 C19 C20 73.5(3) .
N8 C19 C20 C21 -60.5(3) .
C22 N10 C21 C20 -170.3(2) .
C36 N10 C21 C20 68.7(3) .
Ag1A N10 C21 C20 -68.9(3) .
C19 C20 C21 N10 63.3(3) .
C36 N10 C22 C23 -165.0(2) .
C21 N10 C22 C23 73.4(3) .
Ag1A N10 C22 C23 -47.6(2) .
C27 N9 C23 C24 1.5(4) .
Ag1A N9 C23 C24 157.4(3) .
Ag1 N9 C23 C24 -166.6(2) .
C27 N9 C23 C22 178.3(2) .
Ag1A N9 C23 C22 -25.8(3) .
Ag1 N9 C23 C22 10.2(3) .
N10 C22 C23 N9 59.6(3) .
N10 C22 C23 C24 -123.5(3) .
N9 C23 C24 C25 1.1(5) .
C22 C23 C24 C25 -175.6(3) .
C23 C24 C25 C26 -2.7(5) .
C24 C25 C26 C27 1.8(5) .
C23 N9 C27 C26 -2.5(4) .
Ag1A N9 C27 C26 -154.8(3) .
Ag1 N9 C27 C26 166.0(2) .
C25 C26 C27 N9 0.8(5) .
C9 N5 C28 C29 74.1(3) .
C10 N5 C28 C29 -164.7(2) .
Ag2A N5 C28 C29 -51.3(3) .
C33 N4 C29 C30 -1.0(4) .
Ag2A N4 C29 C30 148.5(4) .
Ag2 N4 C29 C30 178.9(2) .
C33 N4 C29 C28 176.9(2) .
Ag2A N4 C29 C28 -33.6(4) .
Ag2 N4 C29 C28 -3.2(3) .
N5 C28 C29 N4 69.2(3) .
N5 C28 C29 C30 -112.9(3) .
N4 C29 C30 C31 2.0(4) .
C28 C29 C30 C31 -175.8(3) .
C29 C30 C31 C32 -1.2(5) .
C30 C31 C32 C33 -0.4(5) .
C29 N4 C33 C32 -0.8(4) .
Ag2A N4 C33 C32 -144.3(4) .
Ag2 N4 C33 C32 179.3(2) .
C31 C32 C33 N4 1.5(5) .
C1 N1 C34 C35 101.4(3) .
Ag2 N1 C34 C35 -75.6(3) .
N1 C34 C35 C36 179.0(2) .
C22 N10 C36 C35 67.8(3) .
C21 N10 C36 C35 -171.7(2) .
Ag1A N10 C36 C35 -32.5(3) .
C34 C35 C36 N10 171.9(2) .
N1SA C1SA C2SA C1SA -153.4(1000) 2_775
