#------------------------------------------------------------------------------
#$Date: 2016-03-25 21:21:48 +0100 (vie 25 de mar de 2016) $
#$Revision: 180009 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/03/7030375.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7030375
loop_
_publ_author_name
'Cooper, Oliver J.'
'Mills, David P.'
'Lewis, William'
'Blake, Alexander J.'
'Liddle, Stephen T.'
_publ_section_title
;
 Reactivity of the uranium(iv) carbene complex
 [U(BIPM(TMS))(Cl)(μ-Cl)2Li(THF)2] (BIPM(TMS) = {C(PPh2NSiMe3)2}) towards
 carbonyl and heteroallene substrates: metallo-Wittig, adduct formation,
 C-F bond activation, and [2 + 2]-cycloaddition reactions.
;
_journal_issue                   38
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              14275
_journal_page_last               14283
_journal_paper_doi               10.1039/c4dt00909f
_journal_volume                  43
_journal_year                    2014
_chemical_formula_moiety         'C84 H104 Cl4 N4 O2 P4 Si4 U2, 2 C7 H8'
_chemical_formula_sum            'C98 H120 Cl4 N4 O2 P4 Si4 U2'
_chemical_formula_weight         2240.08
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   'geom, Me from difmap'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           'enCIFer editing of SHELXL97 CIF output'
_cell_angle_alpha                104.9723(18)
_cell_angle_beta                 91.5936(17)
_cell_angle_gamma                106.7706(17)
_cell_formula_units_Z            1
_cell_length_a                   12.6232(3)
_cell_length_b                   14.1448(3)
_cell_length_c                   14.8645(3)
_cell_measurement_reflns_used    15978
_cell_measurement_temperature    90(2)
_cell_measurement_theta_max      74.3
_cell_measurement_theta_min      3.39
_cell_volume                     2439.86(10)
_computing_cell_refinement
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.55 (release 05-01-2010 CrysAlis171 .NET)
(compiled Jan  5 2010,16:28:46)
;
_computing_data_collection
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.55 (release 05-01-2010 CrysAlis171 .NET)
(compiled Jan  5 2010,16:28:46)
;
_computing_data_reduction
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.55 (release 05-01-2010 CrysAlis171 .NET)
(compiled Jan  5 2010,16:28:46)
;
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008)'
_computing_publication_material
'enCIFer (Allen et al., 2004); PLATON (Spek, 2009)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXTL (Sheldrick, 2008)'
_diffrn_ambient_temperature      90(2)
_diffrn_detector_area_resol_mean 10.3613
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'SuperNova, Single source at offset), Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_source         'SuperNova (Cu) X-ray Source'
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.5418
_diffrn_reflns_av_R_equivalents  0.0239
_diffrn_reflns_av_sigmaI/netI    0.0230
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            16881
_diffrn_reflns_theta_full        67.50
_diffrn_reflns_theta_max         67.50
_diffrn_reflns_theta_min         3.40
_diffrn_standards_decay_%        0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    11.744
_exptl_absorpt_correction_T_max  0.77
_exptl_absorpt_correction_T_min  0.27
_exptl_absorpt_correction_type   analytical
_exptl_absorpt_process_details
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.55 (release 05-01-2010 CrysAlis171 .NET)
(compiled Jan  5 2010,16:28:46)
Analytical numeric absorption correction using a multifaceted crystal
            model based on expressions derived by R.C. Clark & J.S. Reid.
(Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)
;
_exptl_crystal_colour            Yellow
_exptl_crystal_density_diffrn    1.525
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Plate
_exptl_crystal_F_000             1120
_exptl_crystal_size_max          0.23
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.02
_refine_diff_density_max         1.098
_refine_diff_density_min         -1.512
_refine_diff_density_rms         0.132
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.141
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     542
_refine_ls_number_reflns         8769
_refine_ls_number_restraints     453
_refine_ls_restrained_S_all      1.128
_refine_ls_R_factor_all          0.0278
_refine_ls_R_factor_gt           0.0252
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0256P)²+11.1868P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0605
_refine_ls_wR_factor_ref         0.0702
_reflns_number_gt                8413
_reflns_number_total             8769
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            c4dt00909f1.cif
_cod_data_source_block           3
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 

 Adding full bibliography for 7030374--7030380.cif.
;
_cod_original_cell_volume        2439.86(8)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7030375
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
U1 U 0.578667(11) 0.668749(10) 0.587237(9) 0.01226(5) Uani 1 1 d U
Cl1 Cl 0.59818(8) 0.51481(7) 0.42758(7) 0.01690(19) Uani 1 1 d U
Cl2 Cl 0.44840(9) 0.71881(8) 0.47960(8) 0.0228(2) Uani 1 1 d U
N1 N 0.7416(3) 0.7690(3) 0.5321(2) 0.0142(7) Uani 1 1 d U
N2 N 0.4816(3) 0.7335(3) 0.7159(2) 0.0163(7) Uani 1 1 d U
P1 P 0.77765(8) 0.86071(8) 0.62916(7) 0.0131(2) Uani 1 1 d U
P2 P 0.58590(9) 0.83461(8) 0.76424(7) 0.0152(2) Uani 1 1 d U
Si1 Si 0.78825(10) 0.76453(9) 0.42249(8) 0.0160(2) Uani 1 1 d U
Si2 Si 0.35158(10) 0.69133(9) 0.75371(9) 0.0200(2) Uani 1 1 d U
O1 O 0.6748(3) 0.5822(2) 0.6696(2) 0.0202(6) Uani 1 1 d U
C1 C 0.6893(4) 0.8156(3) 0.7011(3) 0.0157(8) Uani 1 1 d U
C2 C 0.7707(4) 0.9820(3) 0.6126(3) 0.0155(8) Uani 1 1 d U
C3 C 0.6782(4) 0.9797(3) 0.5570(3) 0.0185(9) Uani 1 1 d U
H3A H 0.6230 0.9161 0.5280 0.022 Uiso 1 1 calc R
C4 C 0.6667(4) 1.0709(4) 0.5441(3) 0.0218(9) Uani 1 1 d U
H4A H 0.6036 1.0695 0.5068 0.026 Uiso 1 1 calc R
C5 C 0.7482(4) 1.1638(3) 0.5863(4) 0.0239(9) Uani 1 1 d U
H5A H 0.7409 1.2257 0.5770 0.029 Uiso 1 1 calc R
C6 C 0.8396(4) 1.1668(4) 0.6414(4) 0.0261(10) Uani 1 1 d U
H6A H 0.8950 1.2305 0.6699 0.031 Uiso 1 1 calc R
C7 C 0.8505(4) 1.0754(4) 0.6554(3) 0.0217(9) Uani 1 1 d U
H7A H 0.9127 1.0775 0.6942 0.026 Uiso 1 1 calc R
C8 C 0.9218(4) 0.8881(3) 0.6759(3) 0.0177(8) Uani 1 1 d U
C9 C 1.0007(4) 0.8604(4) 0.6209(3) 0.0222(9) Uani 1 1 d U
H9A H 0.9798 0.8251 0.5563 0.027 Uiso 1 1 calc R
C10 C 1.1106(4) 0.8838(4) 0.6593(4) 0.0298(10) Uani 1 1 d U
H10A H 1.1636 0.8634 0.6210 0.036 Uiso 1 1 calc R
C11 C 1.1420(4) 0.9356(4) 0.7513(4) 0.0338(11) Uani 1 1 d U
H11A H 1.2171 0.9522 0.7768 0.041 Uiso 1 1 calc R
C12 C 1.0657(5) 0.9639(5) 0.8075(4) 0.0376(12) Uani 1 1 d U
H12A H 1.0878 1.0002 0.8717 0.045 Uiso 1 1 calc R
C13 C 0.9547(4) 0.9392(4) 0.7698(4) 0.0314(11) Uani 1 1 d U
H13A H 0.9016 0.9577 0.8091 0.038 Uiso 1 1 calc R
C14 C 0.6160(4) 0.8415(4) 0.8868(3) 0.0206(9) Uani 1 1 d U
C15 C 0.6562(5) 0.7654(4) 0.9037(4) 0.0319(11) Uani 1 1 d U
H15A H 0.6736 0.7183 0.8527 0.038 Uiso 1 1 calc R
C16 C 0.6714(5) 0.7569(5) 0.9937(4) 0.0369(12) Uani 1 1 d U
H16A H 0.6971 0.7033 1.0039 0.044 Uiso 1 1 calc R
C17 C 0.6490(5) 0.8272(4) 1.0681(3) 0.0330(11) Uani 1 1 d U
H17A H 0.6608 0.8230 1.1301 0.040 Uiso 1 1 calc R
C18 C 0.6091(4) 0.9042(4) 1.0526(3) 0.0268(10) Uani 1 1 d U
H18A H 0.5924 0.9516 1.1040 0.032 Uiso 1 1 calc R
C19 C 0.5937(4) 0.9121(4) 0.9628(3) 0.0244(10) Uani 1 1 d U
H19A H 0.5678 0.9657 0.9527 0.029 Uiso 1 1 calc R
C20 C 0.5581(4) 0.9535(3) 0.7638(3) 0.0181(8) Uani 1 1 d U
C21 C 0.4645(4) 0.9522(4) 0.7089(3) 0.0197(9) Uani 1 1 d U
H21A H 0.4108 0.8886 0.6769 0.024 Uiso 1 1 calc R
C22 C 0.4509(4) 1.0435(4) 0.7016(3) 0.0227(9) Uani 1 1 d U
H22A H 0.3868 1.0424 0.6657 0.027 Uiso 1 1 calc R
C23 C 0.5302(4) 1.1376(4) 0.7463(3) 0.0239(9) Uani 1 1 d U
H23A H 0.5205 1.2000 0.7404 0.029 Uiso 1 1 calc R
C24 C 0.6233(4) 1.1391(4) 0.7995(3) 0.0239(9) Uani 1 1 d U
H24A H 0.6776 1.2028 0.8300 0.029 Uiso 1 1 calc R
C25 C 0.6373(4) 1.0479(4) 0.8081(3) 0.0233(9) Uani 1 1 d U
H25A H 0.7013 1.0496 0.8445 0.028 Uiso 1 1 calc R
C26 C 0.8652(4) 0.6671(4) 0.3893(3) 0.0229(9) Uani 1 1 d U
H26A H 0.8166 0.5994 0.3902 0.034 Uiso 1 1 calc R
H26B H 0.9316 0.6871 0.4341 0.034 Uiso 1 1 calc R
H26C H 0.8876 0.6639 0.3262 0.034 Uiso 1 1 calc R
C27 C 0.8800(4) 0.8919(4) 0.4150(3) 0.0240(10) Uani 1 1 d U
H27A H 0.8402 0.9431 0.4314 0.036 Uiso 1 1 calc R
H27B H 0.9002 0.8858 0.3510 0.036 Uiso 1 1 calc R
H27C H 0.9477 0.9136 0.4587 0.036 Uiso 1 1 calc R
C28 C 0.6690(4) 0.7295(4) 0.3308(3) 0.0239(10) Uani 1 1 d U
H28A H 0.6205 0.6600 0.3260 0.036 Uiso 1 1 calc R
H28B H 0.6972 0.7317 0.2704 0.036 Uiso 1 1 calc R
H28C H 0.6265 0.7784 0.3478 0.036 Uiso 1 1 calc R
C29 C 0.3401(5) 0.5806(4) 0.8032(4) 0.0301(11) Uani 1 1 d U
H29A H 0.3417 0.5205 0.7531 0.045 Uiso 1 1 calc R
H29B H 0.2699 0.5644 0.8310 0.045 Uiso 1 1 calc R
H29C H 0.4026 0.5985 0.8514 0.045 Uiso 1 1 calc R
C30 C 0.2413(4) 0.6562(4) 0.6542(4) 0.0299(11) Uani 1 1 d U
H30A H 0.2592 0.6100 0.5994 0.045 Uiso 1 1 calc R
H30B H 0.2376 0.7186 0.6389 0.045 Uiso 1 1 calc R
H30C H 0.1693 0.6215 0.6720 0.045 Uiso 1 1 calc R
C31 C 0.3225(4) 0.7930(4) 0.8513(4) 0.0309(11) Uani 1 1 d U
H31A H 0.3344 0.8564 0.8323 0.046 Uiso 1 1 calc R
H31B H 0.3727 0.8066 0.9077 0.046 Uiso 1 1 calc R
H31C H 0.2452 0.7689 0.8645 0.046 Uiso 1 1 calc R
C32 C 0.7369(4) 0.5551(4) 0.7168(3) 0.0224(9) Uani 1 1 d U
C33 C 0.8554(4) 0.5637(4) 0.6921(4) 0.0267(10) Uani 1 1 d U
C34 C 0.8870(5) 0.4675(5) 0.6929(4) 0.0413(13) Uani 1 1 d U
H34A H 0.8366 0.4078 0.6463 0.062 Uiso 1 1 calc R
H34B H 0.8811 0.4564 0.7552 0.062 Uiso 1 1 calc R
H34C H 0.9637 0.4764 0.6777 0.062 Uiso 1 1 calc R
C35 C 0.9352(4) 0.6611(5) 0.7623(4) 0.0349(12) Uani 1 1 d U
H35A H 0.9069 0.7195 0.7664 0.052 Uiso 1 1 calc R
H35B H 1.0094 0.6760 0.7408 0.052 Uiso 1 1 calc R
H35C H 0.9399 0.6492 0.8242 0.052 Uiso 1 1 calc R
C36 C 0.8646(5) 0.5794(4) 0.5940(4) 0.0301(11) Uani 1 1 d U
H36A H 0.8116 0.5208 0.5483 0.045 Uiso 1 1 calc R
H36B H 0.9404 0.5849 0.5777 0.045 Uiso 1 1 calc R
H36C H 0.8477 0.6427 0.5934 0.045 Uiso 1 1 calc R
C37 C 0.6921(4) 0.5143(4) 0.7950(3) 0.0245(9) Uani 1 1 d U
C38 C 0.5777(4) 0.4709(4) 0.7880(4) 0.0335(11) Uani 1 1 d U
H38A H 0.5322 0.4694 0.7354 0.040 Uiso 1 1 calc R
C39 C 0.5289(5) 0.4294(5) 0.8582(4) 0.0423(13) Uani 1 1 d U
H39A H 0.4506 0.3982 0.8519 0.051 Uiso 1 1 calc R
C40 C 0.5922(5) 0.4331(4) 0.9353(4) 0.0354(12) Uani 1 1 d U
H40A H 0.5585 0.4034 0.9820 0.042 Uiso 1 1 calc R
C41 C 0.7059(5) 0.4803(5) 0.9453(4) 0.0370(12) Uani 1 1 d U
H41A H 0.7496 0.4855 1.0004 0.044 Uiso 1 1 calc R
C42 C 0.7569(5) 0.5201(5) 0.8761(4) 0.0363(12) Uani 1 1 d U
H42A H 0.8353 0.5512 0.8833 0.044 Uiso 1 1 calc R
C43 C 0.9264(7) 1.1337(7) 1.0025(5) 0.0648(18) Uani 1 1 d U
H43A H 0.9403 1.0716 0.9644 0.097 Uiso 1 1 calc R
H43B H 0.8465 1.1194 1.0083 0.097 Uiso 1 1 calc R
H43C H 0.9674 1.1546 1.0650 0.097 Uiso 1 1 calc R
C44 C 0.9646(6) 1.2190(6) 0.9562(5) 0.0531(14) Uani 1 1 d U
C45 C 0.9068(7) 1.2887(8) 0.9627(6) 0.0714(19) Uani 1 1 d U
H45A H 0.8415 1.2820 0.9939 0.086 Uiso 1 1 calc R
C46 C 0.9458(8) 1.3693(8) 0.9229(7) 0.079(2) Uani 1 1 d U
H46A H 0.9090 1.4203 0.9307 0.095 Uiso 1 1 calc R
C47 C 1.0368(6) 1.3774(7) 0.8720(5) 0.0637(17) Uani 1 1 d U
H47A H 1.0600 1.4306 0.8420 0.076 Uiso 1 1 calc R
C48 C 1.0909(6) 1.3074(7) 0.8665(5) 0.0592(16) Uani 1 1 d U
H48A H 1.1552 1.3124 0.8340 0.071 Uiso 1 1 calc R
C49 C 1.0545(6) 1.2291(7) 0.9069(5) 0.0611(17) Uani 1 1 d U
H49A H 1.0935 1.1798 0.9005 0.073 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.2541 0.3302 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
U U -4.3638 13.4090 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 U1 N2 65.59(14) . .
C1 U1 N1 65.37(13) . .
N2 U1 N1 126.11(12) . .
C1 U1 O1 82.37(12) . .
N2 U1 O1 97.04(11) . .
N1 U1 O1 97.34(11) . .
C1 U1 Cl2 110.40(10) . .
N2 U1 Cl2 86.83(9) . .
N1 U1 Cl2 90.22(9) . .
O1 U1 Cl2 167.05(8) . .
C1 U1 Cl1 140.17(10) . 2_666
N2 U1 Cl1 81.20(9) . 2_666
N1 U1 Cl1 152.49(8) . 2_666
O1 U1 Cl1 80.48(8) . 2_666
Cl2 U1 Cl1 87.95(3) . 2_666
C1 U1 Cl1 140.56(11) . .
N2 U1 Cl1 152.62(9) . .
N1 U1 Cl1 80.83(8) . .
O1 U1 Cl1 82.44(7) . .
Cl2 U1 Cl1 88.44(3) . .
Cl1 U1 Cl1 71.69(3) 2_666 .
U1 Cl1 U1 108.31(3) 2_666 .
P1 N1 Si1 129.9(2) . .
P1 N1 U1 94.54(15) . .
Si1 N1 U1 134.04(18) . .
P2 N2 Si2 129.4(2) . .
P2 N2 U1 94.47(16) . .
Si2 N2 U1 136.01(19) . .
N1 P1 C1 103.2(2) . .
N1 P1 C2 111.62(19) . .
C1 P1 C2 114.1(2) . .
N1 P1 C8 112.73(19) . .
C1 P1 C8 111.1(2) . .
C2 P1 C8 104.4(2) . .
N2 P2 C1 103.4(2) . .
N2 P2 C20 112.8(2) . .
C1 P2 C20 112.6(2) . .
N2 P2 C14 109.6(2) . .
C1 P2 C14 112.2(2) . .
C20 P2 C14 106.3(2) . .
N1 Si1 C28 110.7(2) . .
N1 Si1 C27 113.1(2) . .
C28 Si1 C27 104.6(2) . .
N1 Si1 C26 111.14(19) . .
C28 Si1 C26 108.3(2) . .
C27 Si1 C26 108.9(2) . .
N2 Si2 C30 109.3(2) . .
N2 Si2 C29 111.6(2) . .
C30 Si2 C29 110.8(3) . .
N2 Si2 C31 112.7(2) . .
C30 Si2 C31 107.3(2) . .
C29 Si2 C31 105.0(2) . .
C32 O1 U1 168.9(3) . .
P2 C1 P1 144.6(3) . .
P2 C1 U1 95.90(19) . .
P1 C1 U1 96.30(19) . .
C7 C2 C3 119.6(4) . .
C7 C2 P1 122.7(3) . .
C3 C2 P1 117.6(3) . .
C2 C3 C4 120.2(4) . .
C5 C4 C3 119.6(4) . .
C6 C5 C4 120.6(4) . .
C5 C6 C7 119.8(4) . .
C2 C7 C6 120.2(4) . .
C13 C8 C9 118.2(4) . .
C13 C8 P1 119.2(4) . .
C9 C8 P1 122.6(4) . .
C8 C9 C10 120.8(5) . .
C11 C10 C9 120.2(5) . .
C10 C11 C12 120.2(5) . .
C11 C12 C13 119.8(5) . .
C8 C13 C12 120.6(5) . .
C15 C14 C19 118.8(4) . .
C15 C14 P2 116.3(4) . .
C19 C14 P2 124.7(4) . .
C16 C15 C14 121.3(5) . .
C17 C16 C15 119.3(5) . .
C16 C17 C18 120.2(5) . .
C19 C18 C17 120.3(5) . .
C18 C19 C14 120.1(5) . .
C25 C20 C21 119.0(4) . .
C25 C20 P2 119.8(3) . .
C21 C20 P2 120.7(3) . .
C22 C21 C20 119.9(4) . .
C21 C22 C23 120.8(4) . .
C24 C23 C22 119.4(4) . .
C25 C24 C23 120.3(4) . .
C24 C25 C20 120.6(4) . .
O1 C32 C37 118.2(4) . .
O1 C32 C33 119.2(4) . .
C37 C32 C33 122.6(4) . .
C32 C33 C34 112.0(4) . .
C32 C33 C36 109.1(4) . .
C34 C33 C36 108.7(4) . .
C32 C33 C35 107.9(4) . .
C34 C33 C35 111.6(5) . .
C36 C33 C35 107.5(4) . .
C38 C37 C42 118.6(5) . .
C38 C37 C32 116.7(4) . .
C42 C37 C32 124.7(5) . .
C37 C38 C39 120.3(5) . .
C40 C39 C38 120.8(5) . .
C39 C40 C41 119.5(5) . .
C40 C41 C42 121.0(5) . .
C41 C42 C37 119.7(5) . .
C49 C44 C45 118.3(8) . .
C49 C44 C43 122.2(7) . .
C45 C44 C43 119.5(7) . .
C44 C45 C46 118.7(7) . .
C47 C46 C45 121.9(8) . .
C48 C47 C46 117.6(8) . .
C47 C48 C49 120.8(7) . .
C44 C49 C48 122.5(7) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
U1 C1 2.346(4) .
U1 N2 2.423(3) .
U1 N1 2.433(3) .
U1 O1 2.453(3) .
U1 Cl2 2.6223(10) .
U1 Cl1 2.8470(10) 2_666
U1 Cl1 2.8471(9) .
Cl1 U1 2.8470(10) 2_666
N1 P1 1.621(4) .
N1 Si1 1.740(4) .
N2 P2 1.621(4) .
N2 Si2 1.739(4) .
P1 C1 1.675(4) .
P1 C2 1.821(4) .
P1 C8 1.824(4) .
P2 C1 1.672(4) .
P2 C20 1.816(4) .
P2 C14 1.823(5) .
Si1 C28 1.865(5) .
Si1 C27 1.873(5) .
Si1 C26 1.880(5) .
Si2 C30 1.865(5) .
Si2 C29 1.867(5) .
Si2 C31 1.888(5) .
O1 C32 1.239(6) .
C2 C7 1.389(6) .
C2 C3 1.399(6) .
C3 C4 1.399(6) .
C4 C5 1.391(7) .
C5 C6 1.381(7) .
C6 C7 1.404(7) .
C8 C13 1.384(7) .
C8 C9 1.385(6) .
C9 C10 1.398(7) .
C10 C11 1.360(8) .
C11 C12 1.372(8) .
C12 C13 1.404(7) .
C14 C15 1.388(7) .
C14 C19 1.397(6) .
C15 C16 1.386(7) .
C16 C17 1.380(8) .
C17 C18 1.390(7) .
C18 C19 1.381(7) .
C20 C25 1.398(7) .
C20 C21 1.411(6) .
C21 C22 1.382(7) .
C22 C23 1.397(7) .
C23 C24 1.390(7) .
C24 C25 1.389(7) .
C32 C37 1.483(7) .
C32 C33 1.528(7) .
C33 C34 1.528(7) .
C33 C36 1.533(7) .
C33 C35 1.549(7) .
C37 C38 1.386(7) .
C37 C42 1.409(7) .
C38 C39 1.398(8) .
C39 C40 1.360(8) .
C40 C41 1.383(8) .
C41 C42 1.384(8) .
C43 C44 1.507(11) .
C44 C49 1.362(10) .
C44 C45 1.372(11) .
C45 C46 1.391(12) .
C46 C47 1.386(11) .
C47 C48 1.344(11) .
C48 C49 1.366(11) .
