#------------------------------------------------------------------------------
#$Date: 2016-10-08 00:18:24 +0200 (Sat 08 de Oct de 2016) $
#$Revision: 187121 $
#$URL: svn://www.crystallography.net/cod/cif/7/04/03/7040337.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7040337
loop_
_publ_author_name
'Dau, Thuy Minh'
'Asamoah, Benjamin Darko'
'Belyaev, Andrey'
'Chakkaradhari, Gomathy'
'Hirva, Pipsa'
'Jänis, Janne'
'Grachova, Elena V.'
'Tunik, Sergey P.'
'Koshevoy, Igor O.'
_publ_section_title
;
 Adjustable coordination of a hybrid phosphine-phosphine oxide ligand in
 luminescent Cu, Ag and Au complexes.
;
_journal_issue                   36
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              14160
_journal_page_last               14173
_journal_paper_doi               10.1039/c6dt02435a
_journal_volume                  45
_journal_year                    2016
_chemical_formula_moiety
'C84 H66 Ag2 O2 P6, 2(C F3 O3 S), 2(C4 H10 O)'
_chemical_formula_sum            'C94 H86 Ag2 F6 O10 P6 S2'
_chemical_formula_weight         1955.31
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2016-06-13 deposited with the CCDC.
2016-08-05 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 101.235(2)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   14.1014(7)
_cell_length_b                   13.3900(7)
_cell_length_c                   23.1422(13)
_cell_measurement_reflns_used    9921
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      29.28
_cell_measurement_theta_min      2.35
_cell_volume                     4285.9(4)
_computing_cell_refinement       'SAINT (Bruker AXS, 2009)'
_computing_data_collection       'APEX2 (Bruker AXS, 2010)'
_computing_data_reduction        'SAINT (Bruker AXS, 2009)'
_computing_molecular_graphics    'Diamond v.3.2g (Brandenburg, 2011)'
_computing_publication_material  'SHELXL-2014 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2014 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXS-2014 (Sheldrick, 2014)'
_diffrn_ambient_temperature      120(2)
_diffrn_detector_area_resol_mean 16
_diffrn_measured_fraction_theta_full 0.968
_diffrn_measured_fraction_theta_max 0.966
_diffrn_measurement_device       '62mm x 62mm CCD camera on κ-goniostat'
_diffrn_measurement_device_type  'Bruker KAPPA APEX II DUO CCD'
_diffrn_measurement_method       'φ scans and ω scans with κ offset'
_diffrn_radiation_monochromator  'curved graphite crystal'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0523
_diffrn_reflns_av_unetI/netI     0.0710
_diffrn_reflns_Laue_measured_fraction_full 0.968
_diffrn_reflns_Laue_measured_fraction_max 0.966
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       31
_diffrn_reflns_limit_l_min       -31
_diffrn_reflns_number            40813
_diffrn_reflns_point_group_measured_fraction_full 0.968
_diffrn_reflns_point_group_measured_fraction_max 0.966
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         29.308
_diffrn_reflns_theta_min         1.568
_exptl_absorpt_coefficient_mu    0.691
_exptl_absorpt_correction_T_max  0.982
_exptl_absorpt_correction_T_min  0.929
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'SADABS (Sheldrick, 2008)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.515
_exptl_crystal_description       plate
_exptl_crystal_F_000             2000
_exptl_crystal_size_max          0.099
_exptl_crystal_size_mid          0.065
_exptl_crystal_size_min          0.019
_refine_diff_density_max         1.273
_refine_diff_density_min         -1.064
_refine_diff_density_rms         0.103
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.014
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     541
_refine_ls_number_reflns         11331
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.014
_refine_ls_R_factor_all          0.0880
_refine_ls_R_factor_gt           0.0505
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0598P)²+0.2365P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1057
_refine_ls_wR_factor_ref         0.1180
_reflns_Friedel_coverage         0.000
_reflns_number_gt                7612
_reflns_number_total             11331
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c6dt02435a2.cif
_cod_data_source_block           2
_cod_depositor_comments
'Adding full bibliography for 7040337--7040350.cif.'
_cod_database_code               7040337
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.929
_shelx_estimated_absorpt_t_max   0.982
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
C1 C 1.1212(2) 1.1998(2) 0.98104(13) 0.0237(7) Uani 1 1 d . .
C2 C 1.1790(2) 1.1386(2) 1.02262(13) 0.0249(7) Uani 1 1 d . .
H2 H 1.1713 1.0681 1.0206 0.030 Uiso 1 1 calc R U
C3 C 1.2477(3) 1.1811(3) 1.06676(14) 0.0334(8) Uani 1 1 d . .
H3 H 1.2877 1.1397 1.0947 0.040 Uiso 1 1 calc R U
C4 C 1.2582(3) 1.2828(3) 1.07015(16) 0.0419(10) Uani 1 1 d . .
H4 H 1.3048 1.3114 1.1009 0.050 Uiso 1 1 calc R U
C5 C 1.2017(3) 1.3443(3) 1.02934(17) 0.0422(10) Uani 1 1 d . .
H5 H 1.2096 1.4147 1.0321 0.051 Uiso 1 1 calc R U
C6 C 1.1339(3) 1.3032(3) 0.98456(15) 0.0309(8) Uani 1 1 d . .
H6 H 1.0959 1.3454 0.9561 0.037 Uiso 1 1 calc R U
C7 C 1.1008(2) 1.1078(2) 0.86718(13) 0.0195(6) Uani 1 1 d . .
C8 C 1.1799(2) 1.1673(3) 0.86118(15) 0.0273(7) Uani 1 1 d . .
H8 H 1.1915 1.2274 0.8832 0.033 Uiso 1 1 calc R U
C9 C 1.2415(3) 1.1410(3) 0.82406(16) 0.0333(8) Uani 1 1 d . .
H9 H 1.2940 1.1833 0.8202 0.040 Uiso 1 1 calc R U
C10 C 1.2265(2) 1.0530(3) 0.79257(15) 0.0315(8) Uani 1 1 d . .
H10 H 1.2700 1.0330 0.7682 0.038 Uiso 1 1 calc R U
C11 C 1.1475(2) 0.9942(3) 0.79672(14) 0.0255(7) Uani 1 1 d . .
H11 H 1.1371 0.9344 0.7743 0.031 Uiso 1 1 calc R U
C12 C 1.0823(2) 1.0195(2) 0.83282(13) 0.0196(6) Uani 1 1 d . .
C13 C 0.9873(2) 0.8418(2) 0.77948(13) 0.0216(7) Uani 1 1 d . .
C14 C 1.0392(2) 0.7562(2) 0.79819(15) 0.0279(8) Uani 1 1 d . .
H14 H 1.0682 0.7486 0.8386 0.033 Uiso 1 1 calc R U
C15 C 1.0494(3) 0.6811(3) 0.75838(15) 0.0301(8) Uani 1 1 d . .
H15 H 1.0863 0.6232 0.7716 0.036 Uiso 1 1 calc R U
C16 C 1.0064(2) 0.6903(3) 0.69991(15) 0.0285(8) Uani 1 1 d . .
H16 H 1.0137 0.6391 0.6727 0.034 Uiso 1 1 calc R U
C17 C 0.9528(3) 0.7741(3) 0.68124(15) 0.0351(9) Uani 1 1 d . .
H17 H 0.9219 0.7801 0.6411 0.042 Uiso 1 1 calc R U
C18 C 0.9435(3) 0.8496(3) 0.72022(15) 0.0291(8) Uani 1 1 d . .
H18 H 0.9068 0.9074 0.7066 0.035 Uiso 1 1 calc R U
C19 C 0.8770(2) 1.0156(2) 0.79822(12) 0.0180(6) Uani 1 1 d . .
C20 C 0.8896(2) 1.0924(2) 0.75993(13) 0.0226(7) Uani 1 1 d . .
H20 H 0.9521 1.1057 0.7522 0.027 Uiso 1 1 calc R U
C21 C 0.8115(2) 1.1497(2) 0.73303(14) 0.0263(7) Uani 1 1 d . .
H21 H 0.8207 1.2026 0.7073 0.032 Uiso 1 1 calc R U
C22 C 0.7202(2) 1.1301(2) 0.74355(14) 0.0259(7) Uani 1 1 d . .
H22 H 0.6668 1.1699 0.7254 0.031 Uiso 1 1 calc R U
C23 C 0.7063(2) 1.0521(2) 0.78065(14) 0.0244(7) Uani 1 1 d . .
H23 H 0.6432 1.0375 0.7871 0.029 Uiso 1 1 calc R U
C24 C 0.7849(2) 0.9956(2) 0.80840(13) 0.0220(7) Uani 1 1 d . .
H24 H 0.7756 0.9432 0.8344 0.026 Uiso 1 1 calc R U
C25 C 1.2286(2) 0.8517(2) 1.00821(13) 0.0196(6) Uani 1 1 d . .
C26 C 1.2777(2) 0.8769(2) 1.06463(13) 0.0227(7) Uani 1 1 d . .
H26 H 1.2582 0.8495 1.0984 0.027 Uiso 1 1 calc R U
C27 C 1.3553(2) 0.9425(2) 1.07093(15) 0.0278(7) Uani 1 1 d . .
H27 H 1.3886 0.9602 1.1093 0.033 Uiso 1 1 calc R U
C28 C 1.3845(2) 0.9819(3) 1.02268(15) 0.0291(8) Uani 1 1 d . .
H28 H 1.4378 1.0266 1.0278 0.035 Uiso 1 1 calc R U
C29 C 1.3367(2) 0.9569(2) 0.96633(15) 0.0293(8) Uani 1 1 d . .
H29 H 1.3576 0.9836 0.9329 0.035 Uiso 1 1 calc R U
C30 C 1.2586(2) 0.8931(2) 0.95932(14) 0.0250(7) Uani 1 1 d . .
H30 H 1.2248 0.8771 0.9208 0.030 Uiso 1 1 calc R U
C31 C 1.1153(2) 0.7227(2) 1.06880(13) 0.0198(6) Uani 1 1 d . .
C32 C 1.0498(2) 0.7568(2) 1.10363(13) 0.0190(6) Uani 1 1 d . .
C33 C 1.0502(2) 0.7122(2) 1.15831(13) 0.0225(7) Uani 1 1 d . .
H33 H 1.0054 0.7339 1.1815 0.027 Uiso 1 1 calc R U
C34 C 1.1151(2) 0.6366(2) 1.17905(14) 0.0259(7) Uani 1 1 d . .
H34 H 1.1155 0.6075 1.2165 0.031 Uiso 1 1 calc R U
C35 C 1.1792(2) 0.6037(2) 1.14523(15) 0.0256(7) Uani 1 1 d . .
H35 H 1.2236 0.5519 1.1595 0.031 Uiso 1 1 calc R U
C36 C 1.1791(2) 0.6462(2) 1.09012(14) 0.0248(7) Uani 1 1 d . .
H36 H 1.2231 0.6225 1.0670 0.030 Uiso 1 1 calc R U
C37 C 1.1472(3) 0.6666(2) 0.95434(14) 0.0262(7) Uani 1 1 d . .
C38 C 1.0688(3) 0.6055(3) 0.93037(18) 0.0423(10) Uani 1 1 d . .
H38 H 1.0068 0.6183 0.9391 0.051 Uiso 1 1 calc R U
C39 C 1.0813(4) 0.5272(3) 0.89434(19) 0.0574(14) Uani 1 1 d . .
H39 H 1.0279 0.4853 0.8790 0.069 Uiso 1 1 calc R U
C40 C 1.1676(5) 0.5088(3) 0.88032(19) 0.0627(15) Uani 1 1 d . .
H40 H 1.1746 0.4552 0.8546 0.075 Uiso 1 1 calc R U
C41 C 1.2450(4) 0.5670(3) 0.9029(2) 0.0668(15) Uani 1 1 d . .
H41 H 1.3060 0.5536 0.8930 0.080 Uiso 1 1 calc R U
C42 C 1.2356(3) 0.6469(3) 0.94085(19) 0.0465(11) Uani 1 1 d . .
H42 H 1.2900 0.6868 0.9569 0.056 Uiso 1 1 calc R U
C43 C 0.4040(3) 0.7750(3) 0.83139(18) 0.0387(9) Uani 1 1 d . .
C44 C 0.0719(5) 0.7293(4) 0.5375(3) 0.0871(19) Uani 1 1 d . .
H44A H 0.1327 0.6919 0.5427 0.131 Uiso 1 1 calc R U
H44B H 0.0247 0.6917 0.5548 0.131 Uiso 1 1 calc R U
H44C H 0.0467 0.7393 0.4953 0.131 Uiso 1 1 calc R U
C45 C 0.0892(7) 0.8265(6) 0.5666(5) 0.169(5) Uani 1 1 d . .
H45A H 0.1137 0.8186 0.6095 0.203 Uiso 1 1 calc R U
H45B H 0.1358 0.8666 0.5495 0.203 Uiso 1 1 calc R U
C46 C 0.0072(5) 0.9618(7) 0.5798(4) 0.139(4) Uani 1 1 d . .
H46A H 0.0453 1.0031 0.5571 0.167 Uiso 1 1 calc R U
H46B H 0.0456 0.9545 0.6202 0.167 Uiso 1 1 calc R U
C47 C -0.0815(5) 1.0141(5) 0.5830(3) 0.111(2) Uani 1 1 d . .
H47A H -0.0660 1.0793 0.6016 0.166 Uiso 1 1 calc R U
H47B H -0.1194 1.0235 0.5431 0.166 Uiso 1 1 calc R U
H47C H -0.1190 0.9748 0.6063 0.166 Uiso 1 1 calc R U
O1 O 0.98273(16) 1.05761(16) 0.94466(9) 0.0233(5) Uani 1 1 d . .
O2 O 0.4211(2) 0.8934(2) 0.74751(11) 0.0504(8) Uani 1 1 d . .
O3 O 0.56576(17) 0.8486(2) 0.81762(11) 0.0392(6) Uani 1 1 d . .
O4 O 0.44736(18) 0.95971(17) 0.84626(12) 0.0379(6) Uani 1 1 d . .
O5 O -0.0058(4) 0.8717(4) 0.5550(2) 0.120(2) Uani 1 1 d . .
F1 F 0.4340(2) 0.75596(19) 0.88830(11) 0.0636(7) Uani 1 1 d . .
F2 F 0.30873(17) 0.79126(18) 0.82292(12) 0.0584(7) Uani 1 1 d . .
F3 F 0.4177(2) 0.69268(17) 0.80163(13) 0.0692(8) Uani 1 1 d . .
P2 P 1.03329(6) 1.14339(6) 0.92287(3) 0.01881(17) Uani 1 1 d . .
P1 P 0.97768(6) 0.93790(6) 0.83391(3) 0.01873(17) Uani 1 1 d . .
P3 P 1.11998(6) 0.77512(6) 0.99570(3) 0.01928(17) Uani 1 1 d . .
S1 S 0.46706(6) 0.88120(6) 0.80798(4) 0.02707(19) Uani 1 1 d . .
Ag1 Ag 0.99503(2) 0.87559(2) 0.93494(2) 0.02083(7) Uani 1 1 d . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C6 C1 C2 119.3(3) . .
C6 C1 P2 121.3(2) . .
C2 C1 P2 119.4(2) . .
C3 C2 C1 119.8(3) . .
C3 C2 H2 120.1 . .
C1 C2 H2 120.1 . .
C4 C3 C2 120.2(3) . .
C4 C3 H3 119.9 . .
C2 C3 H3 119.9 . .
C3 C4 C5 120.8(3) . .
C3 C4 H4 119.6 . .
C5 C4 H4 119.6 . .
C6 C5 C4 119.9(4) . .
C6 C5 H5 120.1 . .
C4 C5 H5 120.1 . .
C5 C6 C1 120.1(3) . .
C5 C6 H6 120.0 . .
C1 C6 H6 120.0 . .
C8 C7 C12 118.7(3) . .
C8 C7 P2 117.4(2) . .
C12 C7 P2 123.7(2) . .
C9 C8 C7 121.8(3) . .
C9 C8 H8 119.1 . .
C7 C8 H8 119.1 . .
C10 C9 C8 119.7(3) . .
C10 C9 H9 120.1 . .
C8 C9 H9 120.1 . .
C9 C10 C11 119.5(3) . .
C9 C10 H10 120.2 . .
C11 C10 H10 120.2 . .
C10 C11 C12 122.3(3) . .
C10 C11 H11 118.8 . .
C12 C11 H11 118.8 . .
C11 C12 C7 117.8(3) . .
C11 C12 P1 119.1(2) . .
C7 C12 P1 123.1(2) . .
C14 C13 C18 118.4(3) . .
C14 C13 P1 118.3(2) . .
C18 C13 P1 123.3(2) . .
C13 C14 C15 120.6(3) . .
C13 C14 H14 119.7 . .
C15 C14 H14 119.7 . .
C16 C15 C14 120.3(3) . .
C16 C15 H15 119.9 . .
C14 C15 H15 119.9 . .
C17 C16 C15 119.5(3) . .
C17 C16 H16 120.3 . .
C15 C16 H16 120.3 . .
C16 C17 C18 120.6(3) . .
C16 C17 H17 119.7 . .
C18 C17 H17 119.7 . .
C17 C18 C13 120.6(3) . .
C17 C18 H18 119.7 . .
C13 C18 H18 119.7 . .
C24 C19 C20 119.3(3) . .
C24 C19 P1 118.9(2) . .
C20 C19 P1 121.7(2) . .
C21 C20 C19 120.4(3) . .
C21 C20 H20 119.8 . .
C19 C20 H20 119.8 . .
C22 C21 C20 120.1(3) . .
C22 C21 H21 119.9 . .
C20 C21 H21 119.9 . .
C21 C22 C23 120.0(3) . .
C21 C22 H22 120.0 . .
C23 C22 H22 120.0 . .
C22 C23 C24 119.9(3) . .
C22 C23 H23 120.1 . .
C24 C23 H23 120.1 . .
C19 C24 C23 120.2(3) . .
C19 C24 H24 119.9 . .
C23 C24 H24 119.9 . .
C26 C25 C30 119.3(3) . .
C26 C25 P3 122.3(2) . .
C30 C25 P3 118.2(2) . .
C27 C26 C25 119.2(3) . .
C27 C26 H26 120.4 . .
C25 C26 H26 120.4 . .
C28 C27 C26 121.0(3) . .
C28 C27 H27 119.5 . .
C26 C27 H27 119.5 . .
C27 C28 C29 120.3(3) . .
C27 C28 H28 119.8 . .
C29 C28 H28 119.8 . .
C30 C29 C28 119.4(3) . .
C30 C29 H29 120.3 . .
C28 C29 H29 120.3 . .
C29 C30 C25 120.8(3) . .
C29 C30 H30 119.6 . .
C25 C30 H30 119.6 . .
C36 C31 C32 119.0(3) . .
C36 C31 P3 118.0(2) . .
C32 C31 P3 123.0(2) . .
C33 C32 C31 119.4(3) . .
C33 C32 P2 120.7(2) . 3_777
C31 C32 P2 119.9(2) . 3_777
C34 C33 C32 120.7(3) . .
C34 C33 H33 119.7 . .
C32 C33 H33 119.7 . .
C35 C34 C33 119.9(3) . .
C35 C34 H34 120.0 . .
C33 C34 H34 120.0 . .
C34 C35 C36 120.3(3) . .
C34 C35 H35 119.8 . .
C36 C35 H35 119.8 . .
C31 C36 C35 120.7(3) . .
C31 C36 H36 119.7 . .
C35 C36 H36 119.7 . .
C42 C37 C38 118.8(3) . .
C42 C37 P3 124.6(3) . .
C38 C37 P3 116.3(3) . .
C39 C38 C37 120.1(4) . .
C39 C38 H38 119.9 . .
C37 C38 H38 119.9 . .
C40 C39 C38 121.1(4) . .
C40 C39 H39 119.4 . .
C38 C39 H39 119.4 . .
C39 C40 C41 120.0(4) . .
C39 C40 H40 120.0 . .
C41 C40 H40 120.0 . .
C40 C41 C42 120.7(5) . .
C40 C41 H41 119.7 . .
C42 C41 H41 119.7 . .
C37 C42 C41 119.3(4) . .
C37 C42 H42 120.3 . .
C41 C42 H42 120.3 . .
F1 C43 F3 107.7(3) . .
F1 C43 F2 107.1(3) . .
F3 C43 F2 107.5(3) . .
F1 C43 S1 111.5(3) . .
F3 C43 S1 111.4(3) . .
F2 C43 S1 111.4(3) . .
C45 C44 H44A 109.5 . .
C45 C44 H44B 109.5 . .
H44A C44 H44B 109.5 . .
C45 C44 H44C 109.5 . .
H44A C44 H44C 109.5 . .
H44B C44 H44C 109.5 . .
O5 C45 C44 102.8(8) . .
O5 C45 H45A 111.2 . .
C44 C45 H45A 111.2 . .
O5 C45 H45B 111.2 . .
C44 C45 H45B 111.2 . .
H45A C45 H45B 109.1 . .
O5 C46 C47 114.3(8) . .
O5 C46 H46A 108.7 . .
C47 C46 H46A 108.7 . .
O5 C46 H46B 108.7 . .
C47 C46 H46B 108.7 . .
H46A C46 H46B 107.6 . .
C46 C47 H47A 109.5 . .
C46 C47 H47B 109.5 . .
H47A C47 H47B 109.5 . .
C46 C47 H47C 109.5 . .
H47A C47 H47C 109.5 . .
H47B C47 H47C 109.5 . .
P2 O1 Ag1 133.36(13) . .
C46 O5 C45 104.7(7) . .
O1 P2 C32 111.35(14) . 3_777
O1 P2 C1 111.93(14) . .
C32 P2 C1 104.44(14) 3_777 .
O1 P2 C7 112.98(14) . .
C32 P2 C7 110.50(14) 3_777 .
C1 P2 C7 105.15(15) . .
C19 P1 C13 104.24(14) . .
C19 P1 C12 102.13(14) . .
C13 P1 C12 103.96(14) . .
C19 P1 Ag1 123.45(10) . .
C13 P1 Ag1 114.33(10) . .
C12 P1 Ag1 106.51(9) . .
C25 P3 C37 106.04(15) . .
C25 P3 C31 104.35(14) . .
C37 P3 C31 103.15(14) . .
C25 P3 Ag1 105.82(10) . .
C37 P3 Ag1 109.89(11) . .
C31 P3 Ag1 126.08(10) . .
O2 S1 O3 115.30(16) . .
O2 S1 O4 114.44(17) . .
O3 S1 O4 115.18(16) . .
O2 S1 C43 103.09(18) . .
O3 S1 C43 103.43(17) . .
O4 S1 C43 102.97(17) . .
P3 Ag1 P1 131.77(3) . .
P3 Ag1 O1 123.46(5) . .
P1 Ag1 O1 75.74(5) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 C6 1.397(5) .
C1 C2 1.399(4) .
C1 P2 1.808(3) .
C2 C3 1.386(5) .
C2 H2 0.9500 .
C3 C4 1.370(5) .
C3 H3 0.9500 .
C4 C5 1.382(5) .
C4 H4 0.9500 .
C5 C6 1.380(5) .
C5 H5 0.9500 .
C6 H6 0.9500 .
C7 C8 1.400(4) .
C7 C12 1.420(4) .
C7 P2 1.809(3) .
C8 C9 1.381(5) .
C8 H8 0.9500 .
C9 C10 1.379(5) .
C9 H9 0.9500 .
C10 C11 1.383(5) .
C10 H10 0.9500 .
C11 C12 1.399(4) .
C11 H11 0.9500 .
C12 P1 1.840(3) .
C13 C14 1.384(4) .
C13 C18 1.394(4) .
C13 P1 1.824(3) .
C14 C15 1.390(5) .
C14 H14 0.9500 .
C15 C16 1.376(5) .
C15 H15 0.9500 .
C16 C17 1.376(5) .
C16 H16 0.9500 .
C17 C18 1.377(5) .
C17 H17 0.9500 .
C18 H18 0.9500 .
C19 C24 1.391(4) .
C19 C20 1.391(4) .
C19 P1 1.823(3) .
C20 C21 1.387(4) .
C20 H20 0.9500 .
C21 C22 1.382(5) .
C21 H21 0.9500 .
C22 C23 1.389(5) .
C22 H22 0.9500 .
C23 C24 1.392(4) .
C23 H23 0.9500 .
C24 H24 0.9500 .
C25 C26 1.395(4) .
C25 C30 1.397(4) .
C25 P3 1.819(3) .
C26 C27 1.388(5) .
C26 H26 0.9500 .
C27 C28 1.369(5) .
C27 H27 0.9500 .
C28 C29 1.387(5) .
C28 H28 0.9500 .
C29 C30 1.378(5) .
C29 H29 0.9500 .
C30 H30 0.9500 .
C31 C36 1.389(4) .
C31 C32 1.414(4) .
C31 P3 1.844(3) .
C32 C33 1.398(4) .
C32 P2 1.805(3) 3_777
C33 C34 1.387(4) .
C33 H33 0.9500 .
C34 C35 1.378(5) .
C34 H34 0.9500 .
C35 C36 1.396(5) .
C35 H35 0.9500 .
C36 H36 0.9500 .
C37 C42 1.368(5) .
C37 C38 1.400(5) .
C37 P3 1.822(3) .
C38 C39 1.372(6) .
C38 H38 0.9500 .
C39 C40 1.342(7) .
C39 H39 0.9500 .
C40 C41 1.360(7) .
C40 H40 0.9500 .
C41 C42 1.406(6) .
C41 H41 0.9500 .
C42 H42 0.9500 .
C43 F1 1.327(4) .
C43 F3 1.333(4) .
C43 F2 1.337(4) .
C43 S1 1.815(4) .
C44 C45 1.464(11) .
C44 H44A 0.9800 .
C44 H44B 0.9800 .
C44 H44C 0.9800 .
C45 O5 1.446(9) .
C45 H45A 0.9900 .
C45 H45B 0.9900 .
C46 O5 1.334(11) .
C46 C47 1.447(9) .
C46 H46A 0.9900 .
C46 H46B 0.9900 .
C47 H47A 0.9800 .
C47 H47B 0.9800 .
C47 H47C 0.9800 .
O1 P2 1.491(2) .
O1 Ag1 2.457(2) .
O2 S1 1.432(3) .
O3 S1 1.434(3) .
O4 S1 1.436(3) .
P2 C32 1.805(3) 3_777
P1 Ag1 2.4494(8) .
P3 Ag1 2.4343(8) .
