#------------------------------------------------------------------------------
#$Date: 2017-07-19 05:36:03 +0200 (Wed 19 de Jul de 2017) $
#$Revision: 198797 $
#$URL: svn://www.crystallography.net/cod/cif/7/04/36/7043678.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7043678
loop_
_publ_author_name
'Skoch, Karel'
'Cisarova, Ivana'
'Schulz, Jiri'
'Siemeling, Ulrich'
'Stepnicka, Petr'
_publ_section_title
;
 Synthesis and characterization of
 1'-(diphenylphosphino)-1-isocyanoferrocene, an organometallic ligand
 combining two different soft donor moieties, and its Group 11 metal
 complexes
;
_journal_name_full               'Dalton Trans.'
_journal_paper_doi               10.1039/C7DT02336G
_journal_year                    2017
_chemical_formula_moiety         'C92 H72 Ag2 Fe4 N4 P4, 2(F6 Sb), 3(C3 H6 O)'
_chemical_formula_sum            'C101 H90 Ag2 F12 Fe4 N4 O3 P4 Sb2'
_chemical_formula_weight         2442.29
_chemical_name_systematic
; 
 ? 
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2017-06-26 deposited with the CCDC.
2017-07-17 downloaded from the CCDC.
;
_cell_angle_alpha                90.00
_cell_angle_beta                 127.1702(5)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   29.4021(5)
_cell_length_b                   21.8753(4)
_cell_length_c                   18.7554(3)
_cell_measurement_reflns_used    9944
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      27.49
_cell_measurement_theta_min      2.29
_cell_volume                     9612.4(3)
_computing_cell_refinement       'SAINT V8.34A (Bruker AXS Inc., 2013)'
_computing_data_collection       'Bruker Instrument Service v2015.5.1.2'
_computing_data_reduction        'SAINT V8.34A (Bruker AXS Inc., 2013)'
_computing_molecular_graphics    'PLATON (Spek, 2003)'
_computing_publication_material  'PLATON (Spek, 2003)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0241
_diffrn_reflns_av_sigmaI/netI    0.0271
_diffrn_reflns_limit_h_max       37
_diffrn_reflns_limit_h_min       -38
_diffrn_reflns_limit_k_max       27
_diffrn_reflns_limit_k_min       -28
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            38105
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         2.22
_exptl_absorpt_coefficient_mu    1.680
_exptl_absorpt_correction_T_max  0.787
_exptl_absorpt_correction_T_min  0.539
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'SADABS V2014/5 (Bruker AXS Inc.)'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.688
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             4864
_exptl_crystal_size_max          0.42
_exptl_crystal_size_mid          0.19
_exptl_crystal_size_min          0.15
_refine_diff_density_max         1.786
_refine_diff_density_min         -1.702
_refine_diff_density_rms         0.084
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.067
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     600
_refine_ls_number_reflns         11055
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.067
_refine_ls_R_factor_all          0.0414
_refine_ls_R_factor_gt           0.0307
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0353P)²+17.5340P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0730
_refine_ls_wR_factor_ref         0.0783
_reflns_number_gt                9073
_reflns_number_total             11055
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c7dt02336g2.cif
_cod_data_source_block           ks493
_cod_database_code               7043678
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 1.0000 0.109378(12) 0.7500 0.02012(6) Uani 1 2 d S
Ag2 Ag 1.0000 0.347532(12) 0.7500 0.02094(7) Uani 1 2 d S
Fe1 Fe 0.821371(15) 0.157958(18) 0.67604(3) 0.02408(9) Uani 1 1 d .
Fe2 Fe 1.037746(15) 0.307041(16) 1.01960(2) 0.01916(8) Uani 1 1 d .
P1 P 0.92443(3) 0.04780(3) 0.74351(4) 0.01977(13) Uani 1 1 d .
P2 P 1.00347(3) 0.41341(3) 0.86223(4) 0.01823(13) Uani 1 1 d .
N1 N 0.88260(10) 0.26118(10) 0.65688(15) 0.0254(5) Uani 1 1 d .
N2 N 1.05536(9) 0.20000(10) 0.93335(14) 0.0219(4) Uani 1 1 d .
C1 C 0.83336(11) 0.22618(12) 0.61693(17) 0.0246(5) Uani 1 1 d .
C2 C 0.78700(14) 0.24082(16) 0.6187(2) 0.0410(8) Uani 1 1 d .
H2 H 0.7841 0.2750 0.6469 0.049 Uiso 1 1 calc R
C3 C 0.74623(13) 0.19418(19) 0.5699(2) 0.0525(10) Uani 1 1 d .
H3 H 0.7104 0.1916 0.5596 0.063 Uiso 1 1 calc R
C4 C 0.76696(13) 0.15194(17) 0.5388(2) 0.0444(9) Uani 1 1 d .
H4 H 0.7475 0.1164 0.5042 0.053 Uiso 1 1 calc R
C5 C 0.82154(11) 0.17148(13) 0.56768(17) 0.0260(6) Uani 1 1 d .
H5 H 0.8455 0.1519 0.5564 0.031 Uiso 1 1 calc R
C6 C 0.87801(11) 0.09146(12) 0.75741(17) 0.0229(5) Uani 1 1 d .
C7 C 0.89313(11) 0.14896(13) 0.80334(17) 0.0263(6) Uani 1 1 d .
H7 H 0.9279 0.1704 0.8289 0.032 Uiso 1 1 calc R
C8 C 0.84743(12) 0.16819(15) 0.8040(2) 0.0332(6) Uani 1 1 d .
H8 H 0.8462 0.2047 0.8302 0.040 Uiso 1 1 calc R
C9 C 0.80371(13) 0.12340(15) 0.7585(2) 0.0351(7) Uani 1 1 d .
H9 H 0.7681 0.1249 0.7491 0.042 Uiso 1 1 calc R
C10 C 0.82201(12) 0.07624(14) 0.72966(19) 0.0298(6) Uani 1 1 d .
H10 H 0.8009 0.0407 0.6975 0.036 Uiso 1 1 calc R
C11 C 0.92347(13) 0.28971(13) 0.68908(18) 0.0298(6) Uani 1 1 d .
C12 C 0.95583(11) -0.00811(12) 0.83436(17) 0.0237(5) Uani 1 1 d .
C13 C 0.93128(12) -0.02395(13) 0.87614(18) 0.0288(6) Uani 1 1 d .
H13 H 0.8964 -0.0055 0.8575 0.035 Uiso 1 1 calc R
C14 C 0.95775(13) -0.06672(14) 0.94515(19) 0.0364(7) Uani 1 1 d .
H14 H 0.9410 -0.0773 0.9738 0.044 Uiso 1 1 calc R
C15 C 1.00812(14) -0.09361(14) 0.9719(2) 0.0399(8) Uani 1 1 d .
H15 H 1.0260 -0.1229 1.0189 0.048 Uiso 1 1 calc R
C16 C 1.03302(13) -0.07836(14) 0.9310(2) 0.0397(7) Uani 1 1 d .
H16 H 1.0678 -0.0971 0.9496 0.048 Uiso 1 1 calc R
C17 C 1.00677(12) -0.03558(14) 0.86262(19) 0.0314(6) Uani 1 1 d .
H17 H 1.0239 -0.0249 0.8347 0.038 Uiso 1 1 calc R
C18 C 0.87422(11) 0.00251(12) 0.64343(17) 0.0240(5) Uani 1 1 d .
C19 C 0.84738(12) -0.04958(13) 0.6457(2) 0.0330(6) Uani 1 1 d .
H19 H 0.8557 -0.0629 0.7007 0.040 Uiso 1 1 calc R
C20 C 0.80864(13) -0.08153(16) 0.5675(2) 0.0438(8) Uani 1 1 d .
H20 H 0.7906 -0.1169 0.5692 0.053 Uiso 1 1 calc R
C21 C 0.79599(14) -0.06247(16) 0.4873(2) 0.0483(9) Uani 1 1 d .
H21 H 0.7690 -0.0845 0.4340 0.058 Uiso 1 1 calc R
C22 C 0.82235(14) -0.01149(15) 0.4842(2) 0.0415(8) Uani 1 1 d .
H22 H 0.8136 0.0015 0.4288 0.050 Uiso 1 1 calc R
C23 C 0.86168(12) 0.02082(13) 0.56215(18) 0.0303(6) Uani 1 1 d .
H23 H 0.8801 0.0556 0.5600 0.036 Uiso 1 1 calc R
C51 C 1.07895(11) 0.23932(12) 1.00676(16) 0.0220(5) Uani 1 1 d .
C52 C 1.08119(12) 0.22804(12) 1.08365(18) 0.0270(6) Uani 1 1 d .
H52 H 1.0666 0.1933 1.0943 0.032 Uiso 1 1 calc R
C53 C 1.10939(12) 0.27884(13) 1.14097(17) 0.0282(6) Uani 1 1 d .
H53 H 1.1173 0.2839 1.1978 0.034 Uiso 1 1 calc R
C54 C 1.12406(11) 0.32089(13) 1.10064(17) 0.0270(6) Uani 1 1 d .
H54 H 1.1431 0.3588 1.1254 0.032 Uiso 1 1 calc R
C55 C 1.10524(10) 0.29656(12) 1.01640(17) 0.0220(5) Uani 1 1 d .
H55 H 1.1094 0.3149 0.9748 0.026 Uiso 1 1 calc R
C56 C 0.98803(11) 0.37355(12) 0.92986(17) 0.0208(5) Uani 1 1 d .
C57 C 0.95771(10) 0.31631(12) 0.90299(17) 0.0228(5) Uani 1 1 d .
H57 H 0.9428 0.2952 0.8487 0.027 Uiso 1 1 calc R
C58 C 0.95397(11) 0.29689(13) 0.97149(19) 0.0284(6) Uani 1 1 d .
H58 H 0.9359 0.2607 0.9708 0.034 Uiso 1 1 calc R
C59 C 0.98186(12) 0.34083(13) 1.04114(19) 0.0289(6) Uani 1 1 d .
H59 H 0.9859 0.3390 1.0953 0.035 Uiso 1 1 calc R
C60 C 1.00274(12) 0.38820(12) 1.01595(17) 0.0253(6) Uani 1 1 d .
H60 H 1.0230 0.4235 1.0503 0.030 Uiso 1 1 calc R
C61 C 1.03746(11) 0.16909(12) 0.87226(18) 0.0238(5) Uani 1 1 d .
C62 C 1.07161(10) 0.45268(11) 0.93699(16) 0.0201(5) Uani 1 1 d .
C63 C 1.11212(11) 0.44573(12) 0.92158(18) 0.0242(5) Uani 1 1 d .
H63 H 1.1045 0.4193 0.8753 0.029 Uiso 1 1 calc R
C64 C 1.16373(11) 0.47720(13) 0.97348(19) 0.0298(6) Uani 1 1 d .
H64 H 1.1911 0.4723 0.9624 0.036 Uiso 1 1 calc R
C65 C 1.17506(12) 0.51542(14) 1.04085(19) 0.0330(6) Uani 1 1 d .
H65 H 1.2105 0.5365 1.0769 0.040 Uiso 1 1 calc R
C66 C 1.13520(12) 0.52311(14) 1.0560(2) 0.0341(7) Uani 1 1 d .
H66 H 1.1432 0.5497 1.1024 0.041 Uiso 1 1 calc R
C67 C 1.08343(12) 0.49269(13) 1.00449(18) 0.0282(6) Uani 1 1 d .
H67 H 1.0560 0.4990 1.0150 0.034 Uiso 1 1 calc R
C68 C 0.95111(10) 0.47561(12) 0.81317(16) 0.0207(5) Uani 1 1 d .
C69 C 0.96458(11) 0.53280(12) 0.79815(17) 0.0243(5) Uani 1 1 d .
H69 H 1.0024 0.5412 0.8186 0.029 Uiso 1 1 calc R
C70 C 0.92269(12) 0.57781(13) 0.75319(18) 0.0315(6) Uani 1 1 d .
H70 H 0.9320 0.6168 0.7429 0.038 Uiso 1 1 calc R
C71 C 0.86773(13) 0.56600(14) 0.72356(19) 0.0358(7) Uani 1 1 d .
H71 H 0.8394 0.5969 0.6932 0.043 Uiso 1 1 calc R
C72 C 0.85392(13) 0.50950(15) 0.7379(2) 0.0370(7) Uani 1 1 d .
H72 H 0.8161 0.5016 0.7179 0.044 Uiso 1 1 calc R
C73 C 0.89523(11) 0.46383(13) 0.78177(18) 0.0275(6) Uani 1 1 d .
H73 H 0.8853 0.4246 0.7903 0.033 Uiso 1 1 calc R
Sb1 Sb 0.225604(9) 0.131223(10) 0.213324(14) 0.03722(6) Uani 1 1 d .
F1 F 0.22601(9) 0.21562(9) 0.19782(16) 0.0553(6) Uani 1 1 d .
F2 F 0.16262(9) 0.12250(11) 0.09346(13) 0.0554(6) Uani 1 1 d .
F3 F 0.17708(11) 0.14287(10) 0.24563(16) 0.0615(6) Uani 1 1 d .
F4 F 0.28889(11) 0.13972(11) 0.33255(17) 0.0944(11) Uani 1 1 d .
F5 F 0.27356(10) 0.11941(11) 0.1800(2) 0.0770(8) Uani 1 1 d .
F6 F 0.22587(10) 0.04686(9) 0.22974(14) 0.0593(6) Uani 1 1 d .
O1S O 0.12366(19) 0.78531(18) -0.0168(3) 0.1065(14) Uani 1 1 d .
C1S C 0.1632(3) 0.7492(3) 0.0081(5) 0.0949(18) Uani 1 1 d .
C2S C 0.2278(3) 0.7643(3) 0.0829(4) 0.116(2) Uani 1 1 d .
H2S1 H 0.2475 0.7688 0.0560 0.174 Uiso 1 1 calc R
H2S2 H 0.2453 0.7311 0.1269 0.174 Uiso 1 1 calc R
H2S3 H 0.2307 0.8026 0.1127 0.174 Uiso 1 1 calc R
C3S C 0.1538(2) 0.6865(2) -0.0413(3) 0.0839(15) Uani 1 1 d .
H3S1 H 0.1128 0.6784 -0.0845 0.126 Uiso 1 1 calc R
H3S2 H 0.1719 0.6533 0.0028 0.126 Uiso 1 1 calc R
H3S3 H 0.1709 0.6889 -0.0728 0.126 Uiso 1 1 calc R
O2S O 0.0000 0.2917(2) 0.2500 0.112(2) Uani 1 2 d S
C4S C 0.0000 0.2365(3) 0.2500 0.079(2) Uani 1 2 d S
C5S C 0.0414(3) 0.2008(3) 0.2479(5) 0.122(3) Uani 1 1 d .
H5S1 H 0.0213 0.1773 0.1921 0.183 Uiso 1 1 calc R
H5S2 H 0.0617 0.1727 0.2989 0.183 Uiso 1 1 calc R
H5S3 H 0.0688 0.2285 0.2512 0.183 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Fe Fe 0.3463 0.8444 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C61 Ag1 C61 109.53(14) . 2_756
C61 Ag1 P1 103.35(7) . .
C61 Ag1 P1 112.43(7) 2_756 .
C61 Ag1 P1 112.43(7) . 2_756
C61 Ag1 P1 103.35(7) 2_756 2_756
P1 Ag1 P1 115.87(3) . 2_756
C11 Ag2 C11 110.00(16) . 2_756
C11 Ag2 P2 106.05(7) . .
C11 Ag2 P2 112.61(7) 2_756 .
C11 Ag2 P2 112.61(7) . 2_756
C11 Ag2 P2 106.05(7) 2_756 2_756
P2 Ag2 P2 109.65(3) . 2_756
C1 Fe1 C7 108.47(11) . .
C1 Fe1 C6 127.32(10) . .
C7 Fe1 C6 41.38(11) . .
C1 Fe1 C2 41.04(11) . .
C7 Fe1 C2 122.67(14) . .
C6 Fe1 C2 162.06(13) . .
C1 Fe1 C3 67.75(12) . .
C7 Fe1 C3 158.59(16) . .
C6 Fe1 C3 157.27(15) . .
C2 Fe1 C3 40.50(15) . .
C1 Fe1 C8 119.96(12) . .
C7 Fe1 C8 40.70(11) . .
C6 Fe1 C8 68.99(11) . .
C2 Fe1 C8 103.71(14) . .
C3 Fe1 C8 121.35(15) . .
C1 Fe1 C10 164.99(11) . .
C7 Fe1 C10 69.02(11) . .
C6 Fe1 C10 41.14(10) . .
C2 Fe1 C10 153.05(12) . .
C3 Fe1 C10 120.15(13) . .
C8 Fe1 C10 68.46(13) . .
C1 Fe1 C9 153.79(12) . .
C7 Fe1 C9 68.48(12) . .
C6 Fe1 C9 68.68(11) . .
C2 Fe1 C9 117.09(13) . .
C3 Fe1 C9 105.12(13) . .
C8 Fe1 C9 40.59(12) . .
C10 Fe1 C9 40.38(12) . .
C1 Fe1 C4 67.70(12) . .
C7 Fe1 C4 159.70(14) . .
C6 Fe1 C4 123.91(14) . .
C2 Fe1 C4 68.50(15) . .
C3 Fe1 C4 40.37(16) . .
C8 Fe1 C4 159.01(13) . .
C10 Fe1 C4 109.19(13) . .
C9 Fe1 C4 124.12(13) . .
C1 Fe1 C5 40.83(11) . .
C7 Fe1 C5 123.78(11) . .
C6 Fe1 C5 110.74(11) . .
C2 Fe1 C5 69.32(12) . .
C3 Fe1 C5 68.13(13) . .
C8 Fe1 C5 157.19(12) . .
C10 Fe1 C5 127.35(12) . .
C9 Fe1 C5 162.05(12) . .
C4 Fe1 C5 40.22(12) . .
C51 Fe2 C56 127.68(10) . .
C51 Fe2 C60 164.90(11) . .
C56 Fe2 C60 41.33(10) . .
C51 Fe2 C55 41.16(10) . .
C56 Fe2 C55 106.45(10) . .
C60 Fe2 C55 125.49(11) . .
C51 Fe2 C57 109.43(10) . .
C56 Fe2 C57 41.51(10) . .
C60 Fe2 C57 69.12(11) . .
C55 Fe2 C57 119.65(10) . .
C51 Fe2 C54 68.44(11) . .
C56 Fe2 C54 117.33(11) . .
C60 Fe2 C54 105.75(11) . .
C55 Fe2 C54 40.88(10) . .
C57 Fe2 C54 153.36(11) . .
C51 Fe2 C53 67.88(10) . .
C56 Fe2 C53 151.51(11) . .
C60 Fe2 C53 117.38(11) . .
C55 Fe2 C53 68.45(11) . .
C57 Fe2 C53 165.48(11) . .
C54 Fe2 C53 40.38(11) . .
C51 Fe2 C52 40.98(10) . .
C56 Fe2 C52 166.41(11) . .
C60 Fe2 C52 151.55(11) . .
C55 Fe2 C52 69.45(11) . .
C57 Fe2 C52 128.30(11) . .
C54 Fe2 C52 68.62(11) . .
C53 Fe2 C52 40.35(11) . .
C51 Fe2 C59 153.85(11) . .
C56 Fe2 C59 69.12(10) . .
C60 Fe2 C59 40.77(11) . .
C55 Fe2 C59 163.29(11) . .
C57 Fe2 C59 68.42(11) . .
C54 Fe2 C59 125.59(11) . .
C53 Fe2 C59 107.31(11) . .
C52 Fe2 C59 118.52(11) . .
C51 Fe2 C58 120.91(11) . .
C56 Fe2 C58 69.04(11) . .
C60 Fe2 C58 68.43(12) . .
C55 Fe2 C58 154.74(11) . .
C57 Fe2 C58 40.54(10) . .
C54 Fe2 C58 163.73(11) . .
C53 Fe2 C58 127.46(12) . .
C52 Fe2 C58 108.81(12) . .
C59 Fe2 C58 40.32(11) . .
C6 P1 C18 102.86(12) . .
C6 P1 C12 102.63(12) . .
C18 P1 C12 103.54(12) . .
C6 P1 Ag1 115.33(9) . .
C18 P1 Ag1 118.55(9) . .
C12 P1 Ag1 112.06(9) . .
C56 P2 C62 108.22(12) . .
C56 P2 C68 102.68(12) . .
C62 P2 C68 103.64(12) . .
C56 P2 Ag2 114.36(9) . .
C62 P2 Ag2 112.70(8) . .
C68 P2 Ag2 114.24(8) . .
C11 N1 C1 179.0(3) . .
C61 N2 C51 176.9(3) . .
N1 C1 C2 124.4(3) . .
N1 C1 C5 125.5(2) . .
C2 C1 C5 110.1(3) . .
N1 C1 Fe1 125.68(18) . .
C2 C1 Fe1 70.39(16) . .
C5 C1 Fe1 71.23(15) . .
C3 C2 C1 105.9(3) . .
C3 C2 Fe1 69.81(19) . .
C1 C2 Fe1 68.57(16) . .
C3 C2 H2 127.1 . .
C1 C2 H2 127.1 . .
Fe1 C2 H2 126.1 . .
C2 C3 C4 109.3(3) . .
C2 C3 Fe1 69.69(17) . .
C4 C3 Fe1 70.48(17) . .
C2 C3 H3 125.3 . .
C4 C3 H3 125.3 . .
Fe1 C3 H3 126.1 . .
C3 C4 C5 108.5(3) . .
C3 C4 Fe1 69.14(19) . .
C5 C4 Fe1 69.90(16) . .
C3 C4 H4 125.8 . .
C5 C4 H4 125.8 . .
Fe1 C4 H4 126.8 . .
C4 C5 C1 106.2(3) . .
C4 C5 Fe1 69.88(17) . .
C1 C5 Fe1 67.94(15) . .
C4 C5 H5 126.9 . .
C1 C5 H5 126.9 . .
Fe1 C5 H5 126.8 . .
C10 C6 C7 107.0(2) . .
C10 C6 P1 128.7(2) . .
C7 C6 P1 124.2(2) . .
C10 C6 Fe1 69.77(15) . .
C7 C6 Fe1 68.91(15) . .
P1 C6 Fe1 128.00(14) . .
C8 C7 C6 108.3(2) . .
C8 C7 Fe1 70.29(16) . .
C6 C7 Fe1 69.72(15) . .
C8 C7 H7 125.8 . .
C6 C7 H7 125.8 . .
Fe1 C7 H7 125.7 . .
C7 C8 C9 108.0(3) . .
C7 C8 Fe1 69.02(16) . .
C9 C8 Fe1 70.01(17) . .
C7 C8 H8 126.0 . .
C9 C8 H8 126.0 . .
Fe1 C8 H8 126.6 . .
C10 C9 C8 108.5(3) . .
C10 C9 Fe1 69.62(16) . .
C8 C9 Fe1 69.40(16) . .
C10 C9 H9 125.7 . .
C8 C9 H9 125.7 . .
Fe1 C9 H9 126.8 . .
C9 C10 C6 108.1(3) . .
C9 C10 Fe1 70.00(17) . .
C6 C10 Fe1 69.10(15) . .
C9 C10 H10 125.9 . .
C6 C10 H10 125.9 . .
Fe1 C10 H10 126.5 . .
N1 C11 Ag2 177.9(3) . .
C17 C12 C13 119.0(2) . .
C17 C12 P1 117.8(2) . .
C13 C12 P1 123.3(2) . .
C12 C13 C14 120.1(3) . .
C12 C13 H13 119.9 . .
C14 C13 H13 119.9 . .
C15 C14 C13 120.0(3) . .
C15 C14 H14 120.0 . .
C13 C14 H14 120.0 . .
C14 C15 C16 120.5(3) . .
C14 C15 H15 119.7 . .
C16 C15 H15 119.7 . .
C15 C16 C17 119.4(3) . .
C15 C16 H16 120.3 . .
C17 C16 H16 120.3 . .
C16 C17 C12 121.0(3) . .
C16 C17 H17 119.5 . .
C12 C17 H17 119.5 . .
C23 C18 C19 119.0(3) . .
C23 C18 P1 118.9(2) . .
C19 C18 P1 122.0(2) . .
C20 C19 C18 119.8(3) . .
C20 C19 H19 120.1 . .
C18 C19 H19 120.1 . .
C21 C20 C19 120.6(3) . .
C21 C20 H20 119.7 . .
C19 C20 H20 119.7 . .
C20 C21 C22 120.2(3) . .
C20 C21 H21 119.9 . .
C22 C21 H21 119.9 . .
C21 C22 C23 119.9(3) . .
C21 C22 H22 120.1 . .
C23 C22 H22 120.1 . .
C22 C23 C18 120.5(3) . .
C22 C23 H23 119.8 . .
C18 C23 H23 119.8 . .
N2 C51 C55 125.0(2) . .
N2 C51 C52 125.5(2) . .
C55 C51 C52 109.5(2) . .
N2 C51 Fe2 126.26(17) . .
C55 C51 Fe2 70.03(15) . .
C52 C51 Fe2 70.75(15) . .
C53 C52 C51 106.3(2) . .
C53 C52 Fe2 69.81(15) . .
C51 C52 Fe2 68.27(15) . .
C53 C52 H52 126.9 . .
C51 C52 H52 126.9 . .
Fe2 C52 H52 126.6 . .
C54 C53 C52 109.4(2) . .
C54 C53 Fe2 69.59(15) . .
C52 C53 Fe2 69.85(15) . .
C54 C53 H53 125.3 . .
C52 C53 H53 125.3 . .
Fe2 C53 H53 126.9 . .
C53 C54 C55 108.1(2) . .
C53 C54 Fe2 70.03(16) . .
C55 C54 Fe2 69.16(14) . .
C53 C54 H54 126.0 . .
C55 C54 H54 126.0 . .
Fe2 C54 H54 126.4 . .
C51 C55 C54 106.6(2) . .
C51 C55 Fe2 68.81(14) . .
C54 C55 Fe2 69.96(15) . .
C51 C55 H55 126.7 . .
C54 C55 H55 126.7 . .
Fe2 C55 H55 126.1 . .
C60 C56 C57 106.9(2) . .
C60 C56 P2 130.5(2) . .
C57 C56 P2 122.58(19) . .
C60 C56 Fe2 69.50(15) . .
C57 C56 Fe2 69.52(14) . .
P2 C56 Fe2 124.57(13) . .
C58 C57 C56 108.3(2) . .
C58 C57 Fe2 70.67(15) . .
C56 C57 Fe2 68.97(14) . .
C58 C57 H57 125.9 . .
C56 C57 H57 125.9 . .
Fe2 C57 H57 126.1 . .
C59 C58 C57 108.3(2) . .
C59 C58 Fe2 69.54(15) . .
C57 C58 Fe2 68.79(15) . .
C59 C58 H58 125.9 . .
C57 C58 H58 125.9 . .
Fe2 C58 H58 127.4 . .
C58 C59 C60 108.3(2) . .
C58 C59 Fe2 70.15(15) . .
C60 C59 Fe2 68.87(15) . .
C58 C59 H59 125.9 . .
C60 C59 H59 125.9 . .
Fe2 C59 H59 126.7 . .
C59 C60 C56 108.3(2) . .
C59 C60 Fe2 70.37(16) . .
C56 C60 Fe2 69.18(14) . .
C59 C60 H60 125.8 . .
C56 C60 H60 125.8 . .
Fe2 C60 H60 126.2 . .
N2 C61 Ag1 178.5(2) . .
C63 C62 C67 118.7(2) . .
C63 C62 P2 117.96(19) . .
C67 C62 P2 123.2(2) . .
C64 C63 C62 120.5(2) . .
C64 C63 H63 119.7 . .
C62 C63 H63 119.7 . .
C65 C64 C63 119.9(3) . .
C65 C64 H64 120.0 . .
C63 C64 H64 120.0 . .
C66 C65 C64 120.0(3) . .
C66 C65 H65 120.0 . .
C64 C65 H65 120.0 . .
C65 C66 C67 120.9(3) . .
C65 C66 H66 119.6 . .
C67 C66 H66 119.6 . .
C66 C67 C62 119.9(3) . .
C66 C67 H67 120.0 . .
C62 C67 H67 120.0 . .
C69 C68 C73 119.2(2) . .
C69 C68 P2 120.92(19) . .
C73 C68 P2 119.6(2) . .
C68 C69 C70 120.1(3) . .
C68 C69 H69 119.9 . .
C70 C69 H69 119.9 . .
C71 C70 C69 120.2(3) . .
C71 C70 H70 119.9 . .
C69 C70 H70 119.9 . .
C72 C71 C70 120.1(3) . .
C72 C71 H71 120.0 . .
C70 C71 H71 120.0 . .
C71 C72 C73 120.3(3) . .
C71 C72 H72 119.9 . .
C73 C72 H72 119.9 . .
C72 C73 C68 120.1(3) . .
C72 C73 H73 120.0 . .
C68 C73 H73 120.0 . .
F4 Sb1 F2 179.43(13) . .
F4 Sb1 F1 89.57(11) . .
F2 Sb1 F1 90.49(10) . .
F4 Sb1 F6 89.95(10) . .
F2 Sb1 F6 89.99(10) . .
F1 Sb1 F6 179.49(12) . .
F4 Sb1 F5 90.40(15) . .
F2 Sb1 F5 89.03(12) . .
F1 Sb1 F5 90.43(10) . .
F6 Sb1 F5 89.40(10) . .
F4 Sb1 F3 90.11(14) . .
F2 Sb1 F3 90.47(10) . .
F1 Sb1 F3 89.64(9) . .
F6 Sb1 F3 90.53(10) . .
F5 Sb1 F3 179.49(13) . .
O1S C1S C2S 123.7(6) . .
O1S C1S C3S 122.6(6) . .
C2S C1S C3S 113.3(5) . .
C1S C2S H2S1 109.5 . .
C1S C2S H2S2 109.5 . .
H2S1 C2S H2S2 109.5 . .
C1S C2S H2S3 109.5 . .
H2S1 C2S H2S3 109.5 . .
H2S2 C2S H2S3 109.5 . .
C1S C3S H3S1 109.5 . .
C1S C3S H3S2 109.5 . .
H3S1 C3S H3S2 109.5 . .
C1S C3S H3S3 109.5 . .
H3S1 C3S H3S3 109.5 . .
H3S2 C3S H3S3 109.5 . .
O2S C4S C5S 122.2(3) . 2
O2S C4S C5S 122.2(3) . .
C5S C4S C5S 115.7(7) 2 .
C4S C5S H5S1 109.5 . .
C4S C5S H5S2 109.5 . .
H5S1 C5S H5S2 109.5 . .
C4S C5S H5S3 109.5 . .
H5S1 C5S H5S3 109.5 . .
H5S2 C5S H5S3 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 C61 2.264(3) .
Ag1 C61 2.264(3) 2_756
Ag1 P1 2.5375(7) .
Ag1 P1 2.5375(7) 2_756
Ag2 C11 2.205(3) .
Ag2 C11 2.205(3) 2_756
Ag2 P2 2.5016(6) .
Ag2 P2 2.5016(6) 2_756
Fe1 C1 2.013(3) .
Fe1 C7 2.026(3) .
Fe1 C6 2.037(3) .
Fe1 C2 2.037(3) .
Fe1 C3 2.039(3) .
Fe1 C8 2.042(3) .
Fe1 C10 2.046(3) .
Fe1 C9 2.050(3) .
Fe1 C4 2.056(3) .
Fe1 C5 2.057(3) .
Fe2 C51 2.018(3) .
Fe2 C56 2.028(3) .
Fe2 C60 2.032(3) .
Fe2 C55 2.034(3) .
Fe2 C57 2.035(2) .
Fe2 C54 2.045(3) .
Fe2 C53 2.051(3) .
Fe2 C52 2.051(3) .
Fe2 C59 2.052(3) .
Fe2 C58 2.060(3) .
P1 C6 1.809(3) .
P1 C18 1.826(3) .
P1 C12 1.830(3) .
P2 C56 1.809(3) .
P2 C62 1.823(3) .
P2 C68 1.832(3) .
N1 C11 1.149(4) .
N1 C1 1.390(3) .
N2 C61 1.148(3) .
N2 C51 1.401(3) .
C1 C2 1.420(4) .
C1 C5 1.420(4) .
C2 C3 1.411(5) .
C2 H2 0.9500 .
C3 C4 1.413(6) .
C3 H3 0.9500 .
C4 C5 1.414(4) .
C4 H4 0.9500 .
C5 H5 0.9500 .
C6 C10 1.434(4) .
C6 C7 1.435(4) .
C7 C8 1.415(4) .
C7 H7 0.9500 .
C8 C9 1.420(4) .
C8 H8 0.9500 .
C9 C10 1.414(4) .
C9 H9 0.9500 .
C10 H10 0.9500 .
C12 C17 1.388(4) .
C12 C13 1.392(4) .
C13 C14 1.393(4) .
C13 H13 0.9500 .
C14 C15 1.376(5) .
C14 H14 0.9500 .
C15 C16 1.384(5) .
C15 H15 0.9500 .
C16 C17 1.386(4) .
C16 H16 0.9500 .
C17 H17 0.9500 .
C18 C23 1.393(4) .
C18 C19 1.401(4) .
C19 C20 1.384(4) .
C19 H19 0.9500 .
C20 C21 1.378(5) .
C20 H20 0.9500 .
C21 C22 1.379(5) .
C21 H21 0.9500 .
C22 C23 1.390(4) .
C22 H22 0.9500 .
C23 H23 0.9500 .
C51 C55 1.425(4) .
C51 C52 1.425(4) .
C52 C53 1.415(4) .
C52 H52 0.9500 .
C53 C54 1.414(4) .
C53 H53 0.9500 .
C54 C55 1.425(4) .
C54 H54 0.9500 .
C55 H55 0.9500 .
C56 C60 1.433(3) .
C56 C57 1.440(4) .
C57 C58 1.419(4) .
C57 H57 0.9500 .
C58 C59 1.417(4) .
C58 H58 0.9500 .
C59 C60 1.423(4) .
C59 H59 0.9500 .
C60 H60 0.9500 .
C62 C63 1.393(4) .
C62 C67 1.399(4) .
C63 C64 1.393(4) .
C63 H63 0.9500 .
C64 C65 1.378(4) .
C64 H64 0.9500 .
C65 C66 1.372(4) .
C65 H65 0.9500 .
C66 C67 1.384(4) .
C66 H66 0.9500 .
C67 H67 0.9500 .
C68 C69 1.392(4) .
C68 C73 1.394(4) .
C69 C70 1.394(4) .
C69 H69 0.9500 .
C70 C71 1.379(4) .
C70 H70 0.9500 .
C71 C72 1.378(5) .
C71 H71 0.9500 .
C72 C73 1.394(4) .
C72 H72 0.9500 .
C73 H73 0.9500 .
Sb1 F4 1.863(2) .
Sb1 F2 1.868(2) .
Sb1 F1 1.8701(19) .
Sb1 F6 1.870(2) .
Sb1 F5 1.874(2) .
Sb1 F3 1.874(2) .
O1S C1S 1.241(7) .
C1S C2S 1.569(9) .
C1S C3S 1.583(8) .
C2S H2S1 0.9800 .
C2S H2S2 0.9800 .
C2S H2S3 0.9800 .
C3S H3S1 0.9800 .
C3S H3S2 0.9800 .
C3S H3S3 0.9800 .
O2S C4S 1.208(8) .
C4S C5S 1.468(7) 2
C4S C5S 1.468(7) .
C5S H5S1 0.9800 .
C5S H5S2 0.9800 .
C5S H5S3 0.9800 .
