#------------------------------------------------------------------------------
#$Date: 2016-03-25 23:22:36 +0100 (vie 25 de mar de 2016) $
#$Revision: 180075 $
#$URL: svn://www.crystallography.net/cod/cif/7/05/21/7052174.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7052174
loop_
_publ_author_name
'Seneclauze, Julie Batcha'
'Retailleau, Pascal'
'Ziessel, Raymond'
_publ_section_title
;
 Design and preparation of neutral substituted fluorene- and
 carbazole-based platinum(ii)--acetylide complexes
;
_journal_issue                   8
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              1412
_journal_paper_doi               10.1039/b702374j
_journal_volume                  31
_journal_year                    2007
_chemical_formula_moiety         'C31 H21 N3 Pt'
_chemical_formula_sum            'C31 H21 N3 Pt'
_chemical_formula_weight         630.60
_chemical_name_systematic
;
?
;
_space_group_IT_number           19
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  'P 2ac 2ab'
_symmetry_space_group_name_H-M   'P 21 21 21'
_atom_sites_solution_hydrogens   difmap
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   7.301(5)
_cell_length_b                   12.688(5)
_cell_length_c                   25.728(5)
_cell_measurement_reflns_used    2340
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.485
_cell_measurement_theta_min      0.407
_cell_volume                     2383.3(19)
_computing_cell_refinement
'DENZO (Otwinowski & Minor, 1997) COLLECT (Hooft, 1998)'
_computing_data_collection
'DENZO (Otwinowski & Minor, 1997) COLLECT (Hooft, 1998)'
_computing_data_reduction        'HKL package (Otwinowski & Minor, 1997)'
_computing_molecular_graphics    'PLATON (Spek, 1980-2004)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SIR97 (Altomare, A et al, 1999)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full .986
_diffrn_measured_fraction_theta_max .986
_diffrn_measurement_device_type  'Nonius kappa-CCD diffractometer'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.0407
_diffrn_reflns_av_sigmaI/netI    0.0342
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            14854
_diffrn_reflns_theta_full        25.43
_diffrn_reflns_theta_max         25.43
_diffrn_reflns_theta_min         1.58
_exptl_absorpt_coefficient_mu    5.913
_exptl_absorpt_correction_T_max  0.495
_exptl_absorpt_correction_T_min  0.185
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Scalepack (Otwinowski & Minor, 1997)'
_exptl_crystal_colour            ' brown'
_exptl_crystal_density_diffrn    1.757
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1224
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.12
_refine_diff_density_max         .698
_refine_diff_density_min         -1.307
_refine_diff_density_rms         .362
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.007(13)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.159
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     316
_refine_ls_number_reflns         4276
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.159
_refine_ls_R_factor_all          0.0425
_refine_ls_R_factor_gt           0.0307
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0490P)²+0.8601P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0762
_refine_ls_wR_factor_ref         0.0901
_reflns_number_gt                3759
_reflns_number_total             4276
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b702374J.txt
_cod_data_source_block           jbs032
_cod_database_code               7052174
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'x+1/2, -y+1/2, -z'
'-x, y+1/2, -z+1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 1.26254(4) 0.633037(18) 0.286316(10) 0.04622(11) Uani 1 1 d . . .
N1 N 1.5194(9) 0.5684(6) 0.3077(3) 0.0554(17) Uani 1 1 d . . .
N2 N 1.3198(8) 0.5421(5) 0.2253(2) 0.0484(16) Uani 1 1 d . . .
N4 N 0.9330(11) 1.0253(6) 0.5495(3) 0.066(2) Uani 1 1 d . . .
C1 C 1.0406(11) 0.6640(6) 0.2442(3) 0.051(2) Uani 1 1 d . . .
C2 C 1.0380(10) 0.6056(6) 0.1963(3) 0.053(2) Uani 1 1 d . . .
C3 C 0.8895(11) 0.6152(7) 0.1614(3) 0.064(2) Uani 1 1 d . . .
H12 H 0.8910 0.5799 0.1297 0.077 Uiso 1 1 calc R . .
C4 C 0.7441(14) 0.6767(7) 0.1748(4) 0.074(2) Uani 1 1 d . . .
H13 H 0.6429 0.6795 0.1529 0.088 Uiso 1 1 calc R . .
C5 C 0.7435(13) 0.7333(7) 0.2186(4) 0.077(3) Uani 1 1 d . . .
H14 H 0.6431 0.7757 0.2262 0.093 Uiso 1 1 calc R . .
C6 C 0.8897(12) 0.7300(7) 0.2531(4) 0.066(2) Uani 1 1 d . . .
H15 H 0.8875 0.7723 0.2826 0.080 Uiso 1 1 calc R . .
C7 C 1.5883(10) 0.4990(7) 0.2728(4) 0.056(2) Uani 1 1 d . . .
C8 C 1.7507(11) 0.4485(7) 0.2802(4) 0.070(2) Uani 1 1 d . . .
H2 H 1.7924 0.4006 0.2555 0.084 Uiso 1 1 calc R . .
C9 C 1.8535(14) 0.4680(9) 0.3240(5) 0.090(3) Uani 1 1 d . . .
H3 H 1.9628 0.4326 0.3301 0.108 Uiso 1 1 calc R . .
C10 C 1.7869(13) 0.5432(8) 0.3586(4) 0.079(3) Uani 1 1 d . . .
H4 H 1.8564 0.5619 0.3875 0.095 Uiso 1 1 calc R . .
C11 C 1.6196(12) 0.5901(8) 0.3506(3) 0.066(2) Uani 1 1 d . . .
H5 H 1.5745 0.6375 0.3750 0.079 Uiso 1 1 calc R . .
C12 C 1.1952(10) 0.5399(5) 0.1864(3) 0.0500(19) Uani 1 1 d . . .
C13 C 1.2290(13) 0.4730(6) 0.1445(3) 0.063(2) Uani 1 1 d . . .
H9 H 1.1466 0.4702 0.1170 0.075 Uiso 1 1 calc R . .
C14 C 1.3831(12) 0.4115(7) 0.1437(4) 0.068(2) Uani 1 1 d . . .
H8 H 1.4041 0.3660 0.1159 0.081 Uiso 1 1 calc R . .
C15 C 1.5080(11) 0.4172(7) 0.1843(4) 0.064(2) Uani 1 1 d . . .
H7 H 1.6140 0.3766 0.1837 0.077 Uiso 1 1 calc R . .
C16 C 1.4730(10) 0.4837(6) 0.2256(3) 0.053(2) Uani 1 1 d . . .
C17 C 1.0933(11) 0.8269(6) 0.4302(3) 0.0491(19) Uani 1 1 d . . .
C18 C 1.1944(10) 0.9132(6) 0.4474(3) 0.0480(18) Uani 1 1 d . . .
H21 H 1.3062 0.9288 0.4318 0.058 Uiso 1 1 calc R . .
C19 C 1.1306(10) 0.9753(6) 0.4869(3) 0.0468(18) Uani 1 1 d . . .
C20 C 0.9656(11) 0.9507(6) 0.5116(3) 0.0504(19) Uani 1 1 d . . .
C21 C 0.8642(11) 0.8646(7) 0.4968(3) 0.060(2) Uani 1 1 d . . .
H18 H 0.7553 0.8480 0.5136 0.072 Uiso 1 1 calc R . .
C22 C 0.9280(12) 0.8027(7) 0.4560(4) 0.062(2) Uani 1 1 d . . .
H17 H 0.8604 0.7443 0.4456 0.074 Uiso 1 1 calc R . .
C23 C 1.2028(12) 1.0697(6) 0.5125(3) 0.056(2) Uani 1 1 d . . .
C24 C 1.3565(14) 1.1302(7) 0.5060(4) 0.076(3) Uani 1 1 d . . .
H28 H 1.4424 1.1138 0.4805 0.091 Uiso 1 1 calc R . .
C25 C 1.3806(19) 1.2158(9) 0.5379(6) 0.100(4) Uani 1 1 d . . .
H27 H 1.4834 1.2583 0.5336 0.120 Uiso 1 1 calc R . .
C26 C 1.256(2) 1.2401(8) 0.5761(5) 0.108(4) Uani 1 1 d . . .
H26 H 1.2784 1.2966 0.5983 0.130 Uiso 1 1 calc R . .
C27 C 1.1027(17) 1.1835(9) 0.5819(4) 0.089(3) Uani 1 1 d . . .
H25 H 1.0171 1.2021 0.6070 0.107 Uiso 1 1 calc R . .
C28 C 1.0723(14) 1.0967(7) 0.5500(3) 0.063(2) Uani 1 1 d . . .
C29 C 0.7627(15) 1.0315(8) 0.5806(4) 0.086(3) Uani 1 1 d . . .
H29A H 0.6870 0.9715 0.5730 0.129 Uiso 1 1 calc R . .
H29B H 0.6979 1.0949 0.5719 0.129 Uiso 1 1 calc R . .
H29C H 0.7930 1.0319 0.6169 0.129 Uiso 1 1 calc R . .
C1" C 1.1919(11) 0.7168(6) 0.3477(3) 0.054(2) Uani 1 1 d . . .
C2" C 1.1480(12) 0.7655(6) 0.3856(3) 0.053(2) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C .0033 .0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H .0000 .0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N .0061 .0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1" Pt1 C1 96.7(3) . . ?
C1" Pt1 N2 176.2(3) . . ?
C1 Pt1 N2 81.7(3) . . ?
C1" Pt1 N1 103.4(3) . . ?
C1 Pt1 N1 159.9(3) . . ?
N2 Pt1 N1 78.1(3) . . ?
C11 N1 C7 118.2(8) . . ?
C11 N1 Pt1 127.7(6) . . ?
C7 N1 Pt1 114.1(6) . . ?
C16 N2 C12 123.5(6) . . ?
C16 N2 Pt1 119.4(5) . . ?
C12 N2 Pt1 117.0(5) . . ?
C28 N4 C20 109.6(7) . . ?
C28 N4 C29 125.9(8) . . ?
C20 N4 C29 124.2(8) . . ?
C6 C1 C2 115.9(8) . . ?
C6 C1 Pt1 132.0(7) . . ?
C2 C1 Pt1 112.1(5) . . ?
C3 C2 C1 120.8(7) . . ?
C3 C2 C12 123.2(8) . . ?
C1 C2 C12 116.0(7) . . ?
C4 C3 C2 119.1(8) . . ?
C4 C3 H12 120.5 . . ?
C2 C3 H12 120.5 . . ?
C5 C4 C3 121.6(9) . . ?
C5 C4 H13 119.2 . . ?
C3 C4 H13 119.2 . . ?
C4 C5 C6 121.3(9) . . ?
C4 C5 H14 119.3 . . ?
C6 C5 H14 119.3 . . ?
C5 C6 C1 121.2(9) . . ?
C5 C6 H15 119.4 . . ?
C1 C6 H15 119.4 . . ?
N1 C7 C8 122.5(8) . . ?
N1 C7 C16 114.5(7) . . ?
C8 C7 C16 123.0(8) . . ?
C7 C8 C9 120.3(9) . . ?
C7 C8 H2 119.9 . . ?
C9 C8 H2 119.9 . . ?
C8 C9 C10 117.2(9) . . ?
C8 C9 H3 121.4 . . ?
C10 C9 H3 121.4 . . ?
C11 C10 C9 120.7(10) . . ?
C11 C10 H4 119.7 . . ?
C9 C10 H4 119.7 . . ?
N1 C11 C10 121.0(10) . . ?
N1 C11 H5 119.5 . . ?
C10 C11 H5 119.5 . . ?
N2 C12 C13 117.8(7) . . ?
N2 C12 C2 113.1(7) . . ?
C13 C12 C2 129.0(8) . . ?
C14 C13 C12 120.3(8) . . ?
C14 C13 H9 119.9 . . ?
C12 C13 H9 119.9 . . ?
C13 C14 C15 119.9(8) . . ?
C13 C14 H8 120.1 . . ?
C15 C14 H8 120.1 . . ?
C16 C15 C14 119.3(8) . . ?
C16 C15 H7 120.4 . . ?
C14 C15 H7 120.4 . . ?
N2 C16 C15 119.2(8) . . ?
N2 C16 C7 113.8(7) . . ?
C15 C16 C7 127.0(8) . . ?
C18 C17 C22 118.3(7) . . ?
C18 C17 C2" 122.0(7) . . ?
C22 C17 C2" 119.6(7) . . ?
C19 C18 C17 120.6(7) . . ?
C19 C18 H21 119.7 . . ?
C17 C18 H21 119.7 . . ?
C18 C19 C20 120.2(7) . . ?
C18 C19 C23 133.0(7) . . ?
C20 C19 C23 106.8(7) . . ?
C21 C20 N4 130.5(8) . . ?
C21 C20 C19 121.0(7) . . ?
N4 C20 C19 108.4(7) . . ?
C20 C21 C22 118.6(7) . . ?
C20 C21 H18 120.7 . . ?
C22 C21 H18 120.7 . . ?
C21 C22 C17 121.3(8) . . ?
C21 C22 H17 119.4 . . ?
C17 C22 H17 119.4 . . ?
C24 C23 C28 120.3(8) . . ?
C24 C23 C19 134.3(8) . . ?
C28 C23 C19 105.4(8) . . ?
C23 C24 C25 118.3(10) . . ?
C23 C24 H28 120.8 . . ?
C25 C24 H28 120.8 . . ?
C24 C25 C26 121.3(12) . . ?
C24 C25 H27 119.3 . . ?
C26 C25 H27 119.3 . . ?
C27 C26 C25 120.9(10) . . ?
C27 C26 H26 119.6 . . ?
C25 C26 H26 119.6 . . ?
C26 C27 C28 119.5(10) . . ?
C26 C27 H25 120.2 . . ?
C28 C27 H25 120.2 . . ?
N4 C28 C27 130.7(9) . . ?
N4 C28 C23 109.7(8) . . ?
C27 C28 C23 119.5(10) . . ?
N4 C29 H29A 109.5 . . ?
N4 C29 H29B 109.5 . . ?
H29A C29 H29B 109.5 . . ?
N4 C29 H29C 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
C2" C1" Pt1 178.5(7) . . ?
C1" C2" C17 178.2(9) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C1" 1.973(9) . ?
Pt1 C1 1.988(9) . ?
Pt1 N2 1.992(6) . ?
Pt1 N1 2.119(7) . ?
N1 C11 1.352(10) . ?
N1 C7 1.355(11) . ?
N2 C16 1.342(10) . ?
N2 C12 1.353(10) . ?
N4 C28 1.363(12) . ?
N4 C20 1.379(11) . ?
N4 C29 1.480(12) . ?
C1 C6 1.403(11) . ?
C1 C2 1.437(12) . ?
C2 C3 1.414(11) . ?
C2 C12 1.442(11) . ?
C3 C4 1.362(12) . ?
C3 H12 0.9300 . ?
C4 C5 1.337(13) . ?
C4 H13 0.9300 . ?
C5 C6 1.388(13) . ?
C5 H14 0.9300 . ?
C6 H15 0.9300 . ?
C7 C8 1.361(12) . ?
C7 C16 1.489(11) . ?
C8 C9 1.376(13) . ?
C8 H2 0.9300 . ?
C9 C10 1.394(14) . ?
C9 H3 0.9300 . ?
C10 C11 1.375(13) . ?
C10 H4 0.9300 . ?
C11 H5 0.9300 . ?
C12 C13 1.395(10) . ?
C13 C14 1.369(12) . ?
C13 H9 0.9300 . ?
C14 C15 1.390(12) . ?
C14 H8 0.9300 . ?
C15 C16 1.380(11) . ?
C15 H7 0.9300 . ?
C17 C18 1.393(11) . ?
C17 C22 1.411(11) . ?
C17 C2" 1.444(11) . ?
C18 C19 1.369(10) . ?
C18 H21 0.9300 . ?
C19 C20 1.397(11) . ?
C19 C23 1.464(11) . ?
C20 C21 1.374(11) . ?
C21 C22 1.389(11) . ?
C21 H18 0.9300 . ?
C22 H17 0.9300 . ?
C23 C24 1.371(12) . ?
C23 C28 1.399(12) . ?
C24 C25 1.373(14) . ?
C24 H28 0.9300 . ?
C25 C26 1.375(18) . ?
C25 H27 0.9300 . ?
C26 C27 1.337(17) . ?
C26 H26 0.9300 . ?
C27 C28 1.391(13) . ?
C27 H25 0.9300 . ?
C29 H29A 0.9600 . ?
C29 H29B 0.9600 . ?
C29 H29C 0.9600 . ?
C1" C2" 1.197(11) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1" Pt1 N1 C11 -7.1(8) . . . . ?
C1 Pt1 N1 C11 174.4(8) . . . . ?
N2 Pt1 N1 C11 176.5(7) . . . . ?
C1" Pt1 N1 C7 174.2(5) . . . . ?
C1 Pt1 N1 C7 -4.3(11) . . . . ?
N2 Pt1 N1 C7 -2.2(5) . . . . ?
C1" Pt1 N2 C16 -112(4) . . . . ?
C1 Pt1 N2 C16 -178.2(6) . . . . ?
N1 Pt1 N2 C16 2.6(5) . . . . ?
C1" Pt1 N2 C12 65(4) . . . . ?
C1 Pt1 N2 C12 -0.9(5) . . . . ?
N1 Pt1 N2 C12 179.8(6) . . . . ?
C1" Pt1 C1 C6 4.4(8) . . . . ?
N2 Pt1 C1 C6 -179.1(8) . . . . ?
N1 Pt1 C1 C6 -177.0(7) . . . . ?
C1" Pt1 C1 C2 -174.8(5) . . . . ?
N2 Pt1 C1 C2 1.7(5) . . . . ?
N1 Pt1 C1 C2 3.8(12) . . . . ?
C6 C1 C2 C3 -0.6(11) . . . . ?
Pt1 C1 C2 C3 178.8(6) . . . . ?
C6 C1 C2 C12 178.4(7) . . . . ?
Pt1 C1 C2 C12 -2.3(8) . . . . ?
C1 C2 C3 C4 -3.1(12) . . . . ?
C12 C2 C3 C4 178.0(8) . . . . ?
C2 C3 C4 C5 4.2(14) . . . . ?
C3 C4 C5 C6 -1.4(15) . . . . ?
C4 C5 C6 C1 -2.5(15) . . . . ?
C2 C1 C6 C5 3.3(12) . . . . ?
Pt1 C1 C6 C5 -175.8(7) . . . . ?
C11 N1 C7 C8 2.0(12) . . . . ?
Pt1 N1 C7 C8 -179.1(6) . . . . ?
C11 N1 C7 C16 -177.3(7) . . . . ?
Pt1 N1 C7 C16 1.6(9) . . . . ?
N1 C7 C8 C9 -1.0(13) . . . . ?
C16 C7 C8 C9 178.3(8) . . . . ?
C7 C8 C9 C10 -2.1(14) . . . . ?
C8 C9 C10 C11 4.2(14) . . . . ?
C7 N1 C11 C10 0.1(12) . . . . ?
Pt1 N1 C11 C10 -178.6(6) . . . . ?
C9 C10 C11 N1 -3.2(13) . . . . ?
C16 N2 C12 C13 -0.1(11) . . . . ?
Pt1 N2 C12 C13 -177.2(5) . . . . ?
C16 N2 C12 C2 177.0(6) . . . . ?
Pt1 N2 C12 C2 -0.1(8) . . . . ?
C3 C2 C12 N2 -179.5(7) . . . . ?
C1 C2 C12 N2 1.5(10) . . . . ?
C3 C2 C12 C13 -2.8(13) . . . . ?
C1 C2 C12 C13 178.3(7) . . . . ?
N2 C12 C13 C14 0.7(11) . . . . ?
C2 C12 C13 C14 -175.9(8) . . . . ?
C12 C13 C14 C15 -1.2(13) . . . . ?
C13 C14 C15 C16 1.2(13) . . . . ?
C12 N2 C16 C15 0.0(11) . . . . ?
Pt1 N2 C16 C15 177.1(6) . . . . ?
C12 N2 C16 C7 -179.5(6) . . . . ?
Pt1 N2 C16 C7 -2.5(8) . . . . ?
C14 C15 C16 N2 -0.6(12) . . . . ?
C14 C15 C16 C7 178.9(8) . . . . ?
N1 C7 C16 N2 0.5(10) . . . . ?
C8 C7 C16 N2 -178.8(7) . . . . ?
N1 C7 C16 C15 -179.1(7) . . . . ?
C8 C7 C16 C15 1.7(13) . . . . ?
C22 C17 C18 C19 -2.6(11) . . . . ?
C2" C17 C18 C19 174.2(7) . . . . ?
C17 C18 C19 C20 2.0(11) . . . . ?
C17 C18 C19 C23 -179.3(7) . . . . ?
C28 N4 C20 C21 -179.8(8) . . . . ?
C29 N4 C20 C21 -5.4(14) . . . . ?
C28 N4 C20 C19 -0.3(9) . . . . ?
C29 N4 C20 C19 174.0(7) . . . . ?
C18 C19 C20 C21 -0.2(11) . . . . ?
C23 C19 C20 C21 -179.3(7) . . . . ?
C18 C19 C20 N4 -179.7(7) . . . . ?
C23 C19 C20 N4 1.2(9) . . . . ?
N4 C20 C21 C22 178.6(8) . . . . ?
C19 C20 C21 C22 -0.8(12) . . . . ?
C20 C21 C22 C17 0.1(13) . . . . ?
C18 C17 C22 C21 1.6(12) . . . . ?
C2" C17 C22 C21 -175.4(8) . . . . ?
C18 C19 C23 C24 1.1(16) . . . . ?
C20 C19 C23 C24 179.9(9) . . . . ?
C18 C19 C23 C28 179.5(8) . . . . ?
C20 C19 C23 C28 -1.7(9) . . . . ?
C28 C23 C24 C25 1.7(13) . . . . ?
C19 C23 C24 C25 179.9(10) . . . . ?
C23 C24 C25 C26 0.9(17) . . . . ?
C24 C25 C26 C27 -3(2) . . . . ?
C25 C26 C27 C28 2.3(18) . . . . ?
C20 N4 C28 C27 -178.0(10) . . . . ?
C29 N4 C28 C27 7.8(16) . . . . ?
C20 N4 C28 C23 -0.8(10) . . . . ?
C29 N4 C28 C23 -175.0(8) . . . . ?
C26 C27 C28 N4 177.2(10) . . . . ?
C26 C27 C28 C23 0.2(15) . . . . ?
C24 C23 C28 N4 -179.8(8) . . . . ?
C19 C23 C28 N4 1.5(9) . . . . ?
C24 C23 C28 C27 -2.3(13) . . . . ?
C19 C23 C28 C27 179.1(8) . . . . ?
C1 Pt1 C1" C2" 105(30) . . . . ?
N2 Pt1 C1" C2" 39(33) . . . . ?
N1 Pt1 C1" C2" -75(30) . . . . ?
Pt1 C1" C2" C17 -148(24) . . . . ?
C18 C17 C2" C1" -75(30) . . . . ?
C22 C17 C2" C1" 102(30) . . . . ?
