#------------------------------------------------------------------------------
#$Date: 2016-02-16 02:10:39 +0100 (mar 16 de feb de 2016) $
#$Revision: 176453 $
#$URL: svn://www.crystallography.net/cod/cif/7/20/19/7201994.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7201994
loop_
_publ_author_name
'Kelly, Niamh R.'
'Goetz, Sandrine'
'Batten, Stuart R.'
'Kruger, Paul E.'
_publ_section_title
;
 Synthesis and structural characterisation of lanthanide coordination
 polymers featuring
 4,4′,6,6′-tetra-carboxy-2,2′-bipyridine and rare
 network topology
;
_journal_issue                   8
_journal_name_full               CrystEngComm
_journal_page_first              1018
_journal_paper_doi               10.1039/b801985a
_journal_volume                  10
_journal_year                    2008
_chemical_formula_moiety         'C14 H10 Eu N2 O12.50'
_chemical_formula_sum            'C14 H10 Eu N2 O12.5'
_chemical_formula_weight         558.20
_chemical_name_common            9
_chemical_name_systematic
;
?
;
_space_group_IT_number           62
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-P 2ac 2n'
_symmetry_space_group_name_H-M   'P n m a'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   21.9566(10)
_cell_length_b                   6.6188(3)
_cell_length_c                   11.3669(5)
_cell_measurement_temperature    153(2)
_cell_volume                     1651.91(13)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXTL version 5.1 (Sheldrick, 1998)'
_computing_structure_solution    'SHELXTL version 5.1 (Sheldrick, 1998)'
_diffrn_ambient_temperature      153(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker SMART APEX CCD'
_diffrn_measurement_method       'Omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0311
_diffrn_reflns_av_sigmaI/netI    0.0181
_diffrn_reflns_limit_h_max       26
_diffrn_reflns_limit_h_min       -25
_diffrn_reflns_limit_k_max       7
_diffrn_reflns_limit_k_min       -7
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            12755
_diffrn_reflns_theta_full        24.99
_diffrn_reflns_theta_max         24.99
_diffrn_reflns_theta_min         1.85
_exptl_absorpt_coefficient_mu    3.877
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.7820
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    2.244
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1084
_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.06
_exptl_crystal_size_min          0.03
_refine_diff_density_max         2.197
_refine_diff_density_min         -1.749
_refine_diff_density_rms         0.260
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.423
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     155
_refine_ls_number_reflns         1596
_refine_ls_number_restraints     136
_refine_ls_restrained_S_all      1.364
_refine_ls_R_factor_all          0.0624
_refine_ls_R_factor_gt           0.0619
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0000P)²+62.2209P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1542
_refine_ls_wR_factor_ref         0.1544
_reflns_number_gt                1570
_reflns_number_total             1596
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b801985a.txt
_cod_data_source_block           3
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Orthorhombic' changed to 'orthorhombic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      Pnma
_cod_original_formula_sum        'C14 H10 Eu N2 O12.50'
_cod_database_code               7201994
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'x+1/2, -y+1/2, -z+1/2'
'-x, y+1/2, -z'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'-x-1/2, y-1/2, z-1/2'
'x, -y-1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.13148(3) -0.7500 0.46646(6) 0.0154(3) Uani 1 2 d S . .
N1 N 0.2448(6) -0.7500 0.4223(11) 0.021(3) Uani 1 2 d SU . .
C1 C 0.2625(7) -0.7500 0.3093(13) 0.020(4) Uani 1 2 d SU . .
C2 C 0.3226(7) -0.7500 0.2749(14) 0.029(4) Uani 1 2 d SU . .
H2A H 0.3336 -0.7500 0.1941 0.035 Uiso 1 2 calc SR . .
C3 C 0.3670(8) -0.7500 0.3631(14) 0.039(5) Uani 1 2 d SU . .
C4 C 0.3487(7) -0.7500 0.4815(15) 0.038(5) Uani 1 2 d SU . .
H4A H 0.3782 -0.7500 0.5427 0.046 Uiso 1 2 calc SR . .
C5 C 0.2870(7) -0.7500 0.5075(14) 0.025(4) Uani 1 2 d SU . .
C6 C 0.2641(7) -0.7500 0.6295(14) 0.023(4) Uani 1 2 d SU . .
C7 C 0.3016(6) -0.7500 0.7267(12) 0.010(3) Uiso 1 2 d SU . .
H7A H 0.3445 -0.7500 0.7168 0.012 Uiso 1 2 calc SR . .
C8 C 0.2769(7) -0.7500 0.8392(13) 0.018(3) Uani 1 2 d SU . .
C9 C 0.2143(7) -0.7500 0.8502(15) 0.025(4) Uani 1 2 d SU . .
H9A H 0.1960 -0.7500 0.9259 0.030 Uiso 1 2 calc SR . .
C10 C 0.1784(7) -0.7500 0.7494(13) 0.018(3) Uani 1 2 d SU . .
N2 N 0.2031(5) -0.7500 0.6403(11) 0.016(3) Uani 1 2 d SU . .
C11 C 0.1093(8) -0.785(5) 0.7506(16) 0.018(7) Uani 0.50 1 d PU . .
O1 O 0.0839(5) -0.7500 0.6510(10) 0.030(3) Uani 1 2 d SU . .
O2 O 0.0829(6) -0.7500 0.8457(12) 0.035(3) Uiso 1 2 d SU . .
C12 C 0.3205(7) -0.7500 0.9430(13) 0.022(4) Uani 1 2 d SU . .
O3 O 0.3377(4) -0.9165(14) 0.9806(7) 0.028(2) Uani 1 1 d U . .
C13 C 0.4330(9) -0.7500 0.3346(17) 0.031(4) Uiso 1 2 d SDU . .
O4 O 0.4675(7) -0.7500 0.4264(13) 0.043(4) Uiso 1 2 d SDU . .
H4 H 0.5049(11) -0.7500 0.410(6) 0.064 Uiso 1 2 d SD . .
O5 O 0.4515(7) -0.7500 0.2322(14) 0.047(4) Uiso 1 2 d SU . .
C14 C 0.2102(7) -0.7500 0.2218(13) 0.017(3) Uani 1 2 d SU . .
O6 O 0.2222(5) -0.7500 0.1155(9) 0.024(3) Uani 1 2 d SU . .
O7 O 0.1567(4) -0.7500 0.2650(9) 0.017(2) Uani 1 2 d SU . .
O1W O 0.0438(4) -0.9614(16) 0.4052(11) 0.050(3) Uani 1 1 d . . .
O2W O 0.0405(6) -0.331(2) 0.2232(11) 0.013(3) Uiso 0.50 1 d P . .
O3W O 0.0792(6) -0.832(2) 1.0856(11) 0.012(3) Uiso 0.50 1 d P . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O3 Eu1 O3 145.0(4) 7_665 2_534 ?
O3 Eu1 O1 93.9(2) 7_665 . ?
O3 Eu1 O1 93.9(2) 2_534 . ?
O3 Eu1 O7 89.9(2) 7_665 . ?
O3 Eu1 O7 89.9(2) 2_534 . ?
O1 Eu1 O7 167.1(4) . . ?
O3 Eu1 O1W 141.7(3) 7_665 . ?
O3 Eu1 O1W 73.1(3) 2_534 . ?
O1 Eu1 O1W 84.5(4) . . ?
O7 Eu1 O1W 84.8(3) . . ?
O3 Eu1 O1W 73.1(3) 7_665 8_545 ?
O3 Eu1 O1W 141.7(3) 2_534 8_545 ?
O1 Eu1 O1W 84.5(4) . 8_545 ?
O7 Eu1 O1W 84.8(3) . 8_545 ?
O1W Eu1 O1W 68.7(4) . 8_545 ?
O3 Eu1 N2 76.3(2) 7_665 . ?
O3 Eu1 N2 76.3(2) 2_534 . ?
O1 Eu1 N2 65.0(4) . . ?
O7 Eu1 N2 127.9(4) . . ?
O1W Eu1 N2 134.7(3) . . ?
O1W Eu1 N2 134.7(3) 8_545 . ?
O3 Eu1 N1 74.1(2) 7_665 . ?
O3 Eu1 N1 74.1(2) 2_534 . ?
O1 Eu1 N1 127.9(4) . . ?
O7 Eu1 N1 65.0(4) . . ?
O1W Eu1 N1 134.9(3) . . ?
O1W Eu1 N1 134.9(3) 8_545 . ?
N2 Eu1 N1 62.9(4) . . ?
C5 N1 C1 119.3(13) . . ?
C5 N1 Eu1 122.4(10) . . ?
C1 N1 Eu1 118.3(9) . . ?
N1 C1 C2 123.4(14) . . ?
N1 C1 C14 114.0(13) . . ?
C2 C1 C14 122.6(14) . . ?
C1 C2 C3 117.7(15) . . ?
C1 C2 H2A 121.1 . . ?
C3 C2 H2A 121.1 . . ?
C2 C3 C4 119.2(16) . . ?
C2 C3 C13 121.6(15) . . ?
C4 C3 C13 119.2(15) . . ?
C5 C4 C3 118.9(15) . . ?
C5 C4 H4A 120.6 . . ?
C3 C4 H4A 120.6 . . ?
N1 C5 C4 121.5(14) . . ?
N1 C5 C6 116.3(13) . . ?
C4 C5 C6 122.2(14) . . ?
N2 C6 C7 121.4(14) . . ?
N2 C6 C5 115.2(14) . . ?
C7 C6 C5 123.4(14) . . ?
C6 C7 C8 120.4(14) . . ?
C6 C7 H7A 119.8 . . ?
C8 C7 H7A 119.8 . . ?
C9 C8 C7 118.2(14) . . ?
C9 C8 C12 123.8(14) . . ?
C7 C8 C12 118.0(13) . . ?
C8 C9 C10 119.3(15) . . ?
C8 C9 H9A 120.3 . . ?
C10 C9 H9A 120.3 . . ?
N2 C10 C9 121.9(15) . . ?
N2 C10 C11 113.9(14) . 8_545 ?
C9 C10 C11 123.5(14) . 8_545 ?
N2 C10 C11 113.9(14) . . ?
C9 C10 C11 123.5(14) . . ?
C6 N2 C10 118.8(13) . . ?
C6 N2 Eu1 123.2(10) . . ?
C10 N2 Eu1 117.9(10) . . ?
C11 C11 O2 79.3(16) 8_545 . ?
C11 C11 O1 79.6(15) 8_545 . ?
O2 C11 O1 121.9(17) . . ?
C11 C11 C10 81.3(13) 8_545 . ?
O2 C11 C10 116.1(17) . . ?
O1 C11 C10 113.2(16) . . ?
C11 O1 Eu1 126.6(10) . . ?
C11 O1 Eu1 126.6(10) 8_545 . ?
O3 C12 O3 125.4(14) 8_545 . ?
O3 C12 C8 117.3(7) 8_545 . ?
O3 C12 C8 117.3(7) . . ?
C12 O3 Eu1 155.8(8) . 2_535 ?
O5 C13 O4 124.8(18) . . ?
O5 C13 C3 121.9(17) . . ?
O4 C13 C3 113.4(16) . . ?
C13 O4 H4 113(5) . . ?
O6 C14 O7 124.9(13) . . ?
O6 C14 C1 118.7(13) . . ?
O7 C14 C1 116.4(12) . . ?
C14 O7 Eu1 126.3(9) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O3 2.314(9) 7_665 ?
Eu1 O3 2.314(9) 2_534 ?
Eu1 O1 2.343(11) . ?
Eu1 O7 2.356(10) . ?
Eu1 O1W 2.480(9) . ?
Eu1 O1W 2.480(9) 8_545 ?
Eu1 N2 2.525(12) . ?
Eu1 N1 2.537(12) . ?
N1 C5 1.34(2) . ?
N1 C1 1.342(19) . ?
C1 C2 1.38(2) . ?
C1 C14 1.519(19) . ?
C2 C3 1.40(2) . ?
C2 H2A 0.9500 . ?
C3 C4 1.40(2) . ?
C3 C13 1.48(3) . ?
C4 C5 1.39(2) . ?
C4 H4A 0.9500 . ?
C5 C6 1.48(2) . ?
C6 N2 1.346(19) . ?
C6 C7 1.38(2) . ?
C7 C8 1.39(2) . ?
C7 H7A 0.9500 . ?
C8 C9 1.38(2) . ?
C8 C12 1.52(2) . ?
C9 C10 1.39(2) . ?
C9 H9A 0.9500 . ?
C10 N2 1.352(19) . ?
C10 C11 1.53(2) 8_545 ?
C10 C11 1.53(2) . ?
C11 C11 0.46(7) 8_545 ?
C11 O2 1.25(2) . ?
C11 O1 1.28(2) . ?
O1 C11 1.28(2) 8_545 ?
O2 C11 1.25(2) 8_545 ?
C12 O3 1.241(11) 8_545 ?
C12 O3 1.241(11) . ?
O3 Eu1 2.314(9) 2_535 ?
C13 O5 1.23(2) . ?
C13 O4 1.29(2) . ?
O4 H4 0.84(2) . ?
C14 O6 1.236(18) . ?
C14 O7 1.273(18) . ?
O2W O2W 1.08(3) 8 ?
O3W O3W 1.09(3) 8_545 ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O4 H4 O3W 0.84(2) 1.72(3) 2.517(19) 157(4) 6_657
O4 H4 O3W 0.84(2) 1.72(3) 2.517(19) 157(4) 3_536
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O3 Eu1 N1 C5 82.5(2) 7_665 . . . ?
O3 Eu1 N1 C5 -82.5(2) 2_534 . . . ?
O1 Eu1 N1 C5 0.000(1) . . . . ?
O7 Eu1 N1 C5 180.000(1) . . . . ?
O1W Eu1 N1 C5 -127.2(4) . . . . ?
O1W Eu1 N1 C5 127.2(4) 8_545 . . . ?
N2 Eu1 N1 C5 0.000(1) . . . . ?
O3 Eu1 N1 C1 -97.5(2) 7_665 . . . ?
O3 Eu1 N1 C1 97.5(2) 2_534 . . . ?
O1 Eu1 N1 C1 180.0 . . . . ?
O7 Eu1 N1 C1 0.0 . . . . ?
O1W Eu1 N1 C1 52.8(4) . . . . ?
O1W Eu1 N1 C1 -52.8(4) 8_545 . . . ?
N2 Eu1 N1 C1 180.000(1) . . . . ?
C5 N1 C1 C2 0.000(2) . . . . ?
Eu1 N1 C1 C2 180.0 . . . . ?
C5 N1 C1 C14 180.000(1) . . . . ?
Eu1 N1 C1 C14 0.000(1) . . . . ?
N1 C1 C2 C3 0.000(2) . . . . ?
C14 C1 C2 C3 180.000(1) . . . . ?
C1 C2 C3 C4 0.000(2) . . . . ?
C1 C2 C3 C13 180.000(1) . . . . ?
C2 C3 C4 C5 0.000(2) . . . . ?
C13 C3 C4 C5 180.000(2) . . . . ?
C1 N1 C5 C4 0.000(2) . . . . ?
Eu1 N1 C5 C4 180.000(2) . . . . ?
C1 N1 C5 C6 180.000(2) . . . . ?
Eu1 N1 C5 C6 0.000(2) . . . . ?
C3 C4 C5 N1 0.000(2) . . . . ?
C3 C4 C5 C6 180.000(2) . . . . ?
N1 C5 C6 N2 0.000(2) . . . . ?
C4 C5 C6 N2 180.000(2) . . . . ?
N1 C5 C6 C7 180.000(2) . . . . ?
C4 C5 C6 C7 0.000(3) . . . . ?
N2 C6 C7 C8 0.000(4) . . . . ?
C5 C6 C7 C8 180.000(3) . . . . ?
C6 C7 C8 C9 0.000(4) . . . . ?
C6 C7 C8 C12 180.000(3) . . . . ?
C7 C8 C9 C10 0.000(4) . . . . ?
C12 C8 C9 C10 180.000(3) . . . . ?
C8 C9 C10 N2 0.000(4) . . . . ?
C8 C9 C10 C11 -169.6(15) . . . 8_545 ?
C8 C9 C10 C11 169.6(15) . . . . ?
C7 C6 N2 C10 0.000(4) . . . . ?
C5 C6 N2 C10 180.000(3) . . . . ?
C7 C6 N2 Eu1 180.000(2) . . . . ?
C5 C6 N2 Eu1 0.000(2) . . . . ?
C9 C10 N2 C6 0.000(4) . . . . ?
C11 C10 N2 C6 170.5(14) 8_545 . . . ?
C11 C10 N2 C6 -170.5(14) . . . . ?
C9 C10 N2 Eu1 180.000(3) . . . . ?
C11 C10 N2 Eu1 -9.5(14) 8_545 . . . ?
C11 C10 N2 Eu1 9.5(14) . . . . ?
O3 Eu1 N2 C6 -79.0(2) 7_665 . . . ?
O3 Eu1 N2 C6 79.0(2) 2_534 . . . ?
O1 Eu1 N2 C6 180.000(2) . . . . ?
O7 Eu1 N2 C6 0.000(2) . . . . ?
O1W Eu1 N2 C6 127.5(4) . . . . ?
O1W Eu1 N2 C6 -127.5(4) 8_545 . . . ?
N1 Eu1 N2 C6 0.000(2) . . . . ?
O3 Eu1 N2 C10 101.0(2) 7_665 . . . ?
O3 Eu1 N2 C10 -101.0(2) 2_534 . . . ?
O1 Eu1 N2 C10 0.000(2) . . . . ?
O7 Eu1 N2 C10 180.000(2) . . . . ?
O1W Eu1 N2 C10 -52.5(4) . . . . ?
O1W Eu1 N2 C10 52.5(4) 8_545 . . . ?
N1 Eu1 N2 C10 180.000(2) . . . . ?
N2 C10 C11 C11 -93.9(6) . . . 8_545 ?
C9 C10 C11 C11 95.8(9) . . . 8_545 ?
N2 C10 C11 O2 -167.4(18) . . . . ?
C9 C10 C11 O2 22(3) . . . . ?
C11 C10 C11 O2 -74(2) 8_545 . . . ?
N2 C10 C11 O1 -19(3) . . . . ?
C9 C10 C11 O1 170.5(13) . . . . ?
C11 C10 C11 O1 75(2) 8_545 . . . ?
O2 C11 O1 C11 70(3) . . . 8_545 ?
C10 C11 O1 C11 -76(2) . . . 8_545 ?
C11 C11 O1 Eu1 97.8(12) 8_545 . . . ?
O2 C11 O1 Eu1 168.2(16) . . . . ?
C10 C11 O1 Eu1 22(3) . . . . ?
O3 Eu1 O1 C11 -85.9(19) 7_665 . . . ?
O3 Eu1 O1 C11 60.0(19) 2_534 . . . ?
O7 Eu1 O1 C11 167.0(19) . . . . ?
O1W Eu1 O1 C11 132.5(19) . . . . ?
O1W Eu1 O1 C11 -158.4(19) 8_545 . . . ?
N2 Eu1 O1 C11 -13.0(19) . . . . ?
N1 Eu1 O1 C11 -13.0(19) . . . . ?
O3 Eu1 O1 C11 -60.0(19) 7_665 . . 8_545 ?
O3 Eu1 O1 C11 85.9(19) 2_534 . . 8_545 ?
O7 Eu1 O1 C11 -167.0(19) . . . 8_545 ?
O1W Eu1 O1 C11 158.4(19) . . . 8_545 ?
O1W Eu1 O1 C11 -132.5(19) 8_545 . . 8_545 ?
N2 Eu1 O1 C11 13.0(19) . . . 8_545 ?
N1 Eu1 O1 C11 13.0(19) . . . 8_545 ?
O1 C11 O2 C11 -71(3) . . . 8_545 ?
C10 C11 O2 C11 75(2) . . . 8_545 ?
C9 C8 C12 O3 -91.2(12) . . . 8_545 ?
C7 C8 C12 O3 88.8(12) . . . 8_545 ?
C9 C8 C12 O3 91.2(12) . . . . ?
C7 C8 C12 O3 -88.8(12) . . . . ?
O3 C12 O3 Eu1 -139.6(12) 8_545 . . 2_535 ?
C8 C12 O3 Eu1 38(3) . . . 2_535 ?
C2 C3 C13 O5 0.000(2) . . . . ?
C4 C3 C13 O5 180.000(2) . . . . ?
C2 C3 C13 O4 180.000(1) . . . . ?
C4 C3 C13 O4 0.000(2) . . . . ?
N1 C1 C14 O6 180.000(1) . . . . ?
C2 C1 C14 O6 0.000(1) . . . . ?
N1 C1 C14 O7 0.000(1) . . . . ?
C2 C1 C14 O7 180.0 . . . . ?
O6 C14 O7 Eu1 180.0 . . . . ?
C1 C14 O7 Eu1 0.0 . . . . ?
O3 Eu1 O7 C14 72.5(2) 7_665 . . . ?
O3 Eu1 O7 C14 -72.5(2) 2_534 . . . ?
O1 Eu1 O7 C14 180.000(1) . . . . ?
O1W Eu1 O7 C14 -145.5(2) . . . . ?
O1W Eu1 O7 C14 145.5(2) 8_545 . . . ?
N2 Eu1 O7 C14 0.0 . . . . ?
N1 Eu1 O7 C14 0.0 . . . . ?
