#------------------------------------------------------------------------------
#$Date: 2016-03-26 15:41:24 +0100 (Sat 26 de Mar de 2016) $
#$Revision: 180350 $
#$URL: svn://www.crystallography.net/cod/cif/7/20/19/7201995.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7201995
loop_
_publ_author_name
'Kelly, Niamh R.'
'Goetz, Sandrine'
'Batten, Stuart R.'
'Kruger, Paul E.'
_publ_section_title
;
 Synthesis and structural characterisation of lanthanide coordination
 polymers featuring
 4,4′,6,6′-tetra-carboxy-2,2′-bipyridine and rare
 network topology
;
_journal_issue                   8
_journal_name_full               CrystEngComm
_journal_page_first              1018
_journal_paper_doi               10.1039/b801985a
_journal_volume                  10
_journal_year                    2008
_chemical_formula_moiety         'C14 H6 Eu N2 O9, C2 H8 N'
_chemical_formula_sum            'C16 H14 Eu N3 O9'
_chemical_formula_weight         544.26
_chemical_name_common            11
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 97.5780(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   8.2797(4)
_cell_length_b                   16.7532(9)
_cell_length_c                   12.7089(6)
_cell_measurement_temperature    153(2)
_cell_volume                     1747.47(15)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXTL version 5.1 (Sheldrick, 1998)'
_computing_structure_solution    'SHELXTL version 5.1 (Sheldrick, 1998)'
_diffrn_ambient_temperature      153(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker SMART APEX CCD'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0311
_diffrn_reflns_av_sigmaI/netI    0.0200
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            13473
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.02
_exptl_absorpt_coefficient_mu    3.650
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.7486
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    2.069
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1064
_exptl_crystal_size_max          0.16
_exptl_crystal_size_mid          0.152
_exptl_crystal_size_min          0.06
_refine_diff_density_max         0.632
_refine_diff_density_min         -0.375
_refine_diff_density_rms         0.079
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.103
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     278
_refine_ls_number_reflns         3064
_refine_ls_number_restraints     3
_refine_ls_restrained_S_all      1.104
_refine_ls_R_factor_all          0.0172
_refine_ls_R_factor_gt           0.0164
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0151P)²+2.0737P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0400
_refine_ls_wR_factor_ref         0.0404
_reflns_number_gt                2955
_reflns_number_total             3064
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b801985a.txt
_cod_data_source_block           5
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               7201995
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.413742(13) 0.728233(6) 0.410989(8) 0.01070(5) Uani 1 1 d . . .
N1 N 0.4365(2) 0.61344(11) 0.27894(15) 0.0126(4) Uani 1 1 d . . .
C1 C 0.5052(3) 0.63325(14) 0.19297(18) 0.0134(5) Uani 1 1 d . . .
C2 C 0.5719(3) 0.57731(14) 0.13180(18) 0.0135(5) Uani 1 1 d . . .
H2 H 0.6224 0.5934 0.0723 0.016 Uiso 1 1 calc R . .
C3 C 0.5640(3) 0.49719(14) 0.15828(18) 0.0130(5) Uani 1 1 d . . .
C4 C 0.4840(3) 0.47539(13) 0.24390(17) 0.0122(5) Uani 1 1 d . . .
H4 H 0.4713 0.4208 0.2612 0.015 Uiso 1 1 calc R . .
C5 C 0.4234(3) 0.53547(14) 0.30329(18) 0.0117(5) Uani 1 1 d . . .
C6 C 0.3420(3) 0.52134(14) 0.40040(18) 0.0120(5) Uani 1 1 d . . .
C7 C 0.3097(3) 0.44593(14) 0.43826(18) 0.0134(5) Uani 1 1 d . . .
H7 H 0.3411 0.3992 0.4038 0.016 Uiso 1 1 calc R . .
C8 C 0.2299(3) 0.44049(14) 0.52833(18) 0.0133(5) Uani 1 1 d . . .
C9 C 0.1794(3) 0.51001(14) 0.57301(18) 0.0132(5) Uani 1 1 d . . .
H9 H 0.1173 0.5078 0.6307 0.016 Uiso 1 1 calc R . .
C10 C 0.2205(3) 0.58249(14) 0.53263(18) 0.0128(5) Uani 1 1 d . . .
N2 N 0.3042(2) 0.58875(12) 0.44972(15) 0.0125(4) Uani 1 1 d . . .
C11 C 0.1704(3) 0.66108(14) 0.57848(18) 0.0130(5) Uani 1 1 d . . .
C12 C 0.2020(3) 0.36085(15) 0.58006(18) 0.0145(5) Uani 1 1 d . . .
O1 O 0.2195(2) 0.72378(9) 0.53564(13) 0.0142(4) Uani 1 1 d . . .
O2 O 0.0852(2) 0.65840(10) 0.65112(14) 0.0201(4) Uani 1 1 d . . .
O4 O 0.3129(2) 0.30942(10) 0.57846(13) 0.0161(4) Uani 1 1 d . . .
C13 C 0.6493(3) 0.43663(14) 0.09630(18) 0.0137(5) Uani 1 1 d . . .
O5 O 0.5978(2) 0.36600(11) 0.09413(12) 0.0173(4) Uani 1 1 d . . .
O6 O 0.7628(2) 0.46231(11) 0.05073(16) 0.0259(4) Uani 1 1 d . . .
C14 C 0.5122(3) 0.72205(14) 0.17005(19) 0.0132(5) Uani 1 1 d . . .
O7 O 0.5532(2) 0.74221(11) 0.08233(12) 0.0147(3) Uani 1 1 d . . .
O8 O 0.4768(2) 0.76886(9) 0.24036(13) 0.0160(4) Uani 1 1 d . . .
O1W O 0.1484(2) 0.74124(12) 0.31295(15) 0.0207(4) Uani 1 1 d D . .
H2W1 H 0.068(3) 0.7171(18) 0.326(3) 0.035(10) Uiso 1 1 d D . .
H1W1 H 0.120(4) 0.7683(16) 0.2600(19) 0.027(9) Uiso 1 1 d D . .
N3 N 0.9912(3) 0.35465(17) 0.0129(3) 0.0420(8) Uani 1 1 d . . .
H1N3 H 0.908(4) 0.389(2) 0.024(2) 0.032(8) Uiso 1 1 d . . .
H2N3 H 0.952(4) 0.308(2) 0.027(3) 0.046(10) Uiso 1 1 d . . .
C15 C 1.0306(5) 0.3629(2) -0.0965(3) 0.0607(12) Uani 1 1 d . . .
H15C H 0.9330 0.3521 -0.1470 0.091 Uiso 1 1 calc R . .
H15B H 1.1164 0.3248 -0.1080 0.091 Uiso 1 1 calc R . .
H15A H 1.0686 0.4174 -0.1073 0.091 Uiso 1 1 calc R . .
C16 C 1.1295(4) 0.3708(2) 0.0958(3) 0.0515(10) Uani 1 1 d . . .
H16C H 1.0938 0.3651 0.1660 0.077 Uiso 1 1 calc R . .
H16B H 1.1692 0.4252 0.0876 0.077 Uiso 1 1 calc R . .
H16A H 1.2174 0.3327 0.0891 0.077 Uiso 1 1 calc R . .
O3 O 0.0759(2) 0.35387(11) 0.62158(16) 0.0248(4) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O5 Eu1 O4 107.92(6) 2_655 3_666 ?
O5 Eu1 O7 80.28(6) 2_655 4_576 ?
O4 Eu1 O7 69.76(6) 3_666 4_576 ?
O5 Eu1 O1W 82.08(6) 2_655 . ?
O4 Eu1 O1W 150.70(6) 3_666 . ?
O7 Eu1 O1W 139.52(6) 4_576 . ?
O5 Eu1 O8 72.77(5) 2_655 . ?
O4 Eu1 O8 78.66(6) 3_666 . ?
O7 Eu1 O8 129.21(6) 4_576 . ?
O1W Eu1 O8 78.31(6) . . ?
O5 Eu1 O1 91.19(5) 2_655 . ?
O4 Eu1 O1 132.94(6) 3_666 . ?
O7 Eu1 O1 71.89(6) 4_576 . ?
O1W Eu1 O1 72.37(6) . . ?
O8 Eu1 O1 148.28(6) . . ?
O5 Eu1 N1 137.21(6) 2_655 . ?
O4 Eu1 N1 71.47(6) 3_666 . ?
O7 Eu1 N1 133.12(6) 4_576 . ?
O1W Eu1 N1 82.51(6) . . ?
O8 Eu1 N1 65.09(6) . . ?
O1 Eu1 N1 121.28(6) . . ?
O5 Eu1 N2 153.72(6) 2_655 . ?
O4 Eu1 N2 96.14(6) 3_666 . ?
O7 Eu1 N2 98.89(6) 4_576 . ?
O1W Eu1 N2 81.93(6) . . ?
O8 Eu1 N2 123.70(6) . . ?
O1 Eu1 N2 64.08(6) . . ?
N1 Eu1 N2 60.35(6) . . ?
C1 N1 C5 118.9(2) . . ?
C1 N1 Eu1 114.98(15) . . ?
C5 N1 Eu1 123.92(15) . . ?
N1 C1 C2 122.5(2) . . ?
N1 C1 C14 115.5(2) . . ?
C2 C1 C14 122.0(2) . . ?
C1 C2 C3 119.1(2) . . ?
C2 C3 C4 119.0(2) . . ?
C2 C3 C13 118.8(2) . . ?
C4 C3 C13 122.1(2) . . ?
C5 C4 C3 118.4(2) . . ?
N1 C5 C4 122.0(2) . . ?
N1 C5 C6 113.5(2) . . ?
C4 C5 C6 124.4(2) . . ?
N2 C6 C7 122.2(2) . . ?
N2 C6 C5 114.0(2) . . ?
C7 C6 C5 123.7(2) . . ?
C6 C7 C8 118.4(2) . . ?
C9 C8 C7 118.8(2) . . ?
C9 C8 C12 119.3(2) . . ?
C7 C8 C12 121.8(2) . . ?
C10 C9 C8 119.0(2) . . ?
N2 C10 C9 122.7(2) . . ?
N2 C10 C11 115.4(2) . . ?
C9 C10 C11 121.8(2) . . ?
C10 N2 C6 118.4(2) . . ?
C10 N2 Eu1 116.92(15) . . ?
C6 N2 Eu1 124.14(15) . . ?
O2 C11 O1 126.6(2) . . ?
O2 C11 C10 117.9(2) . . ?
O1 C11 C10 115.56(19) . . ?
O3 C12 O4 126.9(2) . . ?
O3 C12 C8 117.0(2) . . ?
O4 C12 C8 116.1(2) . . ?
C11 O1 Eu1 125.92(14) . . ?
C12 O4 Eu1 152.30(16) . 3_666 ?
O6 C13 O5 126.2(2) . . ?
O6 C13 C3 116.3(2) . . ?
O5 C13 C3 117.5(2) . . ?
C13 O5 Eu1 162.53(16) . 2_645 ?
O8 C14 O7 125.6(2) . . ?
O8 C14 C1 117.3(2) . . ?
O7 C14 C1 117.1(2) . . ?
C14 O7 Eu1 135.58(15) . 4_575 ?
C14 O8 Eu1 124.57(14) . . ?
C16 N3 C15 114.1(3) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O5 2.3106(18) 2_655 ?
Eu1 O4 2.3364(16) 3_666 ?
Eu1 O7 2.3784(16) 4_576 ?
Eu1 O1W 2.3887(18) . ?
Eu1 O8 2.3953(16) . ?
Eu1 O1 2.4026(16) . ?
Eu1 N1 2.5756(19) . ?
Eu1 N2 2.578(2) . ?
N1 C1 1.339(3) . ?
N1 C5 1.350(3) . ?
C1 C2 1.378(3) . ?
C1 C14 1.519(3) . ?
C2 C3 1.387(3) . ?
C3 C4 1.395(3) . ?
C3 C13 1.515(3) . ?
C4 C5 1.391(3) . ?
C5 C6 1.501(3) . ?
C6 N2 1.348(3) . ?
C6 C7 1.390(3) . ?
C7 C8 1.398(3) . ?
C8 C9 1.384(3) . ?
C8 C12 1.519(3) . ?
C9 C10 1.378(3) . ?
C10 N2 1.339(3) . ?
C10 C11 1.520(3) . ?
C11 O2 1.234(3) . ?
C11 O1 1.274(3) . ?
C12 O3 1.235(3) . ?
C12 O4 1.261(3) . ?
O4 Eu1 2.3364(16) 3_666 ?
C13 O6 1.244(3) . ?
C13 O5 1.257(3) . ?
O5 Eu1 2.3106(18) 2_645 ?
C14 O8 1.252(3) . ?
C14 O7 1.254(3) . ?
O7 Eu1 2.3784(16) 4_575 ?
N3 C16 1.476(5) . ?
N3 C15 1.476(5) . ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O1W H2W1 O3 0.819(18) 1.863(19) 2.662(2) 165(3) 3_566
O1W H1W1 O2 0.819(18) 1.844(18) 2.655(2) 170(3) 4_575
N3 H1N3 O6 0.92(3) 1.78(3) 2.702(3) 174(3) .
N3 H2N3 O1 0.87(4) 2.08(4) 2.819(3) 141(3) 2_645
N3 H2N3 O1W 0.87(4) 2.56(4) 3.243(4) 136(3) 2_645
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O5 Eu1 N1 C1 24.6(2) 2_655 . . . ?
O4 Eu1 N1 C1 -72.04(16) 3_666 . . . ?
O7 Eu1 N1 C1 -107.57(16) 4_576 . . . ?
O1W Eu1 N1 C1 94.31(16) . . . . ?
O8 Eu1 N1 C1 13.77(15) . . . . ?
O1 Eu1 N1 C1 158.38(15) . . . . ?
N2 Eu1 N1 C1 179.26(18) . . . . ?
O5 Eu1 N1 C5 -172.67(15) 2_655 . . . ?
O4 Eu1 N1 C5 90.69(18) 3_666 . . . ?
O7 Eu1 N1 C5 55.2(2) 4_576 . . . ?
O1W Eu1 N1 C5 -102.95(18) . . . . ?
O8 Eu1 N1 C5 176.50(19) . . . . ?
O1 Eu1 N1 C5 -38.89(19) . . . . ?
N2 Eu1 N1 C5 -18.01(16) . . . . ?
C5 N1 C1 C2 -3.9(3) . . . . ?
Eu1 N1 C1 C2 159.76(18) . . . . ?
C5 N1 C1 C14 178.8(2) . . . . ?
Eu1 N1 C1 C14 -17.5(2) . . . . ?
N1 C1 C2 C3 1.7(4) . . . . ?
C14 C1 C2 C3 178.8(2) . . . . ?
C1 C2 C3 C4 2.2(3) . . . . ?
C1 C2 C3 C13 -175.1(2) . . . . ?
C2 C3 C4 C5 -3.7(3) . . . . ?
C13 C3 C4 C5 173.5(2) . . . . ?
C1 N1 C5 C4 2.2(3) . . . . ?
Eu1 N1 C5 C4 -159.89(17) . . . . ?
C1 N1 C5 C6 -179.1(2) . . . . ?
Eu1 N1 C5 C6 18.8(3) . . . . ?
C3 C4 C5 N1 1.6(3) . . . . ?
C3 C4 C5 C6 -176.9(2) . . . . ?
N1 C5 C6 N2 -3.4(3) . . . . ?
C4 C5 C6 N2 175.2(2) . . . . ?
N1 C5 C6 C7 177.5(2) . . . . ?
C4 C5 C6 C7 -3.9(4) . . . . ?
N2 C6 C7 C8 2.4(3) . . . . ?
C5 C6 C7 C8 -178.6(2) . . . . ?
C6 C7 C8 C9 3.1(3) . . . . ?
C6 C7 C8 C12 -175.0(2) . . . . ?
C7 C8 C9 C10 -5.1(3) . . . . ?
C12 C8 C9 C10 173.1(2) . . . . ?
C8 C9 C10 N2 1.8(4) . . . . ?
C8 C9 C10 C11 -179.5(2) . . . . ?
C9 C10 N2 C6 3.6(3) . . . . ?
C11 C10 N2 C6 -175.2(2) . . . . ?
C9 C10 N2 Eu1 -168.66(17) . . . . ?
C11 C10 N2 Eu1 12.5(2) . . . . ?
C7 C6 N2 C10 -5.7(3) . . . . ?
C5 C6 N2 C10 175.2(2) . . . . ?
C7 C6 N2 Eu1 165.95(17) . . . . ?
C5 C6 N2 Eu1 -13.1(3) . . . . ?
O5 Eu1 N2 C10 -33.4(2) 2_655 . . . ?
O4 Eu1 N2 C10 123.01(16) 3_666 . . . ?
O7 Eu1 N2 C10 52.61(16) 4_576 . . . ?
O1W Eu1 N2 C10 -86.46(16) . . . . ?
O8 Eu1 N2 C10 -156.54(15) . . . . ?
O1 Eu1 N2 C10 -12.19(15) . . . . ?
N1 Eu1 N2 C10 -172.39(18) . . . . ?
O5 Eu1 N2 C6 154.78(16) 2_655 . . . ?
O4 Eu1 N2 C6 -48.78(18) 3_666 . . . ?
O7 Eu1 N2 C6 -119.19(17) 4_576 . . . ?
O1W Eu1 N2 C6 101.75(18) . . . . ?
O8 Eu1 N2 C6 31.7(2) . . . . ?
O1 Eu1 N2 C6 176.02(19) . . . . ?
N1 Eu1 N2 C6 15.81(16) . . . . ?
N2 C10 C11 O2 176.0(2) . . . . ?
C9 C10 C11 O2 -2.8(3) . . . . ?
N2 C10 C11 O1 -2.8(3) . . . . ?
C9 C10 C11 O1 178.3(2) . . . . ?
C9 C8 C12 O3 35.1(3) . . . . ?
C7 C8 C12 O3 -146.8(2) . . . . ?
C9 C8 C12 O4 -143.1(2) . . . . ?
C7 C8 C12 O4 35.1(3) . . . . ?
O2 C11 O1 Eu1 171.28(17) . . . . ?
C10 C11 O1 Eu1 -10.0(3) . . . . ?
O5 Eu1 O1 C11 -177.34(18) 2_655 . . . ?
O4 Eu1 O1 C11 -61.3(2) 3_666 . . . ?
O7 Eu1 O1 C11 -97.96(18) 4_576 . . . ?
O1W Eu1 O1 C11 101.36(19) . . . . ?
O8 Eu1 O1 C11 124.66(18) . . . . ?
N1 Eu1 O1 C11 32.0(2) . . . . ?
N2 Eu1 O1 C11 11.89(17) . . . . ?
O3 C12 O4 Eu1 -140.0(3) . . . 3_666 ?
C8 C12 O4 Eu1 37.9(4) . . . 3_666 ?
C2 C3 C13 O6 23.0(3) . . . . ?
C4 C3 C13 O6 -154.2(2) . . . . ?
C2 C3 C13 O5 -155.9(2) . . . . ?
C4 C3 C13 O5 26.9(3) . . . . ?
O6 C13 O5 Eu1 34.6(7) . . . 2_645 ?
C3 C13 O5 Eu1 -146.6(4) . . . 2_645 ?
N1 C1 C14 O8 10.5(3) . . . . ?
C2 C1 C14 O8 -166.8(2) . . . . ?
N1 C1 C14 O7 -169.7(2) . . . . ?
C2 C1 C14 O7 13.0(3) . . . . ?
O8 C14 O7 Eu1 -87.6(3) . . . 4_575 ?
C1 C14 O7 Eu1 92.6(3) . . . 4_575 ?
O7 C14 O8 Eu1 -176.33(17) . . . . ?
C1 C14 O8 Eu1 3.5(3) . . . . ?
O5 Eu1 O8 C14 178.7(2) 2_655 . . . ?
O4 Eu1 O8 C14 65.71(19) 3_666 . . . ?
O7 Eu1 O8 C14 117.46(19) 4_576 . . . ?
O1W Eu1 O8 C14 -96.06(19) . . . . ?
O1 Eu1 O8 C14 -118.71(19) . . . . ?
N1 Eu1 O8 C14 -8.97(18) . . . . ?
N2 Eu1 O8 C14 -24.1(2) . . . . ?
