#------------------------------------------------------------------------------
#$Date: 2016-03-26 16:12:40 +0100 (Sat 26 de Mar de 2016) $
#$Revision: 180381 $
#$URL: svn://www.crystallography.net/cod/cif/7/20/50/7205089.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7205089
loop_
_publ_author_name
'Henry, Natacha'
'Costenoble, Sylvain'
'Lagrenée, Michel'
'Loiseau, Thierry'
'Abraham, Francis'
_publ_section_title
;
 Lanthanide-based 0D and 2D molecular assemblies with the
 pyridazine-3,6-dicarboxylate linker
;
_journal_issue                   1
_journal_name_full               CrystEngComm
_journal_page_first              251
_journal_paper_doi               10.1039/c0ce00013b
_journal_volume                  13
_journal_year                    2011
_chemical_formula_moiety
;
'2(Eu 3+). 3(C6 N2 O4 H2 2-). 4(H2 O); 3(H2 O)'
;
_chemical_formula_sum            'C18 H20 Eu2 N6 O19'
_chemical_formula_weight         928.32
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 102.695(5)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   10.4063(10)
_cell_length_b                   13.1997(13)
_cell_length_c                   20.244(2)
_cell_measurement_reflns_used    5602
_cell_measurement_temperature    302(2)
_cell_measurement_theta_max      23.567
_cell_measurement_theta_min      2.501
_cell_volume                     2712.7(5)
_computing_cell_refinement       'Bruker X8/SAINT'
_computing_data_collection       'Bruker X8'
_computing_data_reduction        'Bruker X8/SAINT'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      302(2)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0480
_diffrn_reflns_av_sigmaI/netI    0.0240
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            53377
_diffrn_reflns_theta_full        25.13
_diffrn_reflns_theta_max         25.13
_diffrn_reflns_theta_min         1.86
_exptl_absorpt_coefficient_mu    4.682
_exptl_absorpt_correction_T_max  0.9547
_exptl_absorpt_correction_T_min  0.7058
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'empirical (SADABS)'
_exptl_crystal_colour            'light brown'
_exptl_crystal_density_diffrn    2.273
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       platelet
_exptl_crystal_F_000             1792
_exptl_crystal_size_max          0.08
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.01
_refine_diff_density_max         0.651
_refine_diff_density_min         -0.493
_refine_diff_density_rms         0.108
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.977
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     406
_refine_ls_number_reflns         4822
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.977
_refine_ls_R_factor_all          0.0295
_refine_ls_R_factor_gt           0.0224
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0228P)²+13.0510P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0546
_refine_ls_wR_factor_ref         0.0582
_reflns_number_gt                4230
_reflns_number_total             4822
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            C0CE00013B.TXT
_cod_data_source_block           770966
_cod_original_cell_volume        2712.8(5)
_cod_database_code               7205089
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.44814(2) 0.351010(16) 0.241549(11) 0.01719(7) Uani 1 1 d . . .
Eu2 Eu 0.31183(2) 0.225661(17) 0.415004(11) 0.02017(7) Uani 1 1 d . . .
O1B O 0.6762(3) 0.3602(3) 0.24508(17) 0.0319(8) Uani 1 1 d . . .
O2B O 0.8815(3) 0.3014(3) 0.27867(18) 0.0461(10) Uani 1 1 d . . .
O3B O 0.4748(3) 0.1676(3) 0.50856(16) 0.0329(8) Uani 1 1 d . . .
N1B N 0.6049(4) 0.2797(3) 0.35198(19) 0.0228(8) Uani 1 1 d . . .
N2B N 0.5640(4) 0.2403(3) 0.40470(18) 0.0224(8) Uani 1 1 d . . .
C2B C 0.7309(4) 0.2694(4) 0.3485(2) 0.0253(10) Uani 1 1 d . . .
C3B C 0.8218(5) 0.2178(4) 0.3971(3) 0.0377(13) Uani 1 1 d . . .
H3B H 0.9090 0.2112 0.3934 0.045 Uiso 1 1 calc R . .
C4B C 0.7801(5) 0.1772(4) 0.4501(3) 0.0363(13) Uani 1 1 d . . .
H4B H 0.8375 0.1418 0.4840 0.044 Uiso 1 1 calc R . .
C1B C 0.7656(5) 0.3150(4) 0.2852(3) 0.0296(11) Uani 1 1 d . . .
C5B C 0.6490(5) 0.1904(4) 0.4521(2) 0.0253(10) Uani 1 1 d . . .
O1H O 0.3999(3) 0.3861(3) 0.12382(16) 0.0332(8) Uani 1 1 d . . .
O1C O 0.5067(4) 0.5286(2) 0.24427(17) 0.0336(8) Uani 1 1 d . . .
O1A O 0.2459(3) 0.4368(3) 0.22230(18) 0.0406(9) Uani 1 1 d . . .
C2A C 0.0500(5) 0.5263(4) 0.2002(3) 0.0317(11) Uani 1 1 d . . .
C1A C 0.1600(5) 0.4719(4) 0.1762(3) 0.0345(12) Uani 1 1 d . . .
O2A O 0.1580(4) 0.4703(4) 0.1150(2) 0.0614(13) Uani 1 1 d . . .
O3H O 0.1088(3) 0.3292(3) 0.37725(19) 0.0393(9) Uani 1 1 d . . .
O3C O 0.2954(4) 0.3325(3) 0.50546(17) 0.0355(8) Uani 1 1 d . . .
O2H O 0.1756(4) 0.1294(3) 0.47442(18) 0.0429(9) Uani 1 1 d . . .
O2C O 0.4815(4) 0.6860(2) 0.27889(18) 0.0361(8) Uani 1 1 d . . .
O4C O 0.2775(5) 0.4834(3) 0.5521(2) 0.0625(13) Uani 1 1 d . . .
C6C C 0.3022(5) 0.4276(4) 0.5078(3) 0.0351(12) Uani 1 1 d . . .
C5C C 0.3453(5) 0.4788(4) 0.4489(3) 0.0316(11) Uani 1 1 d . . .
C2C C 0.4289(5) 0.5552(3) 0.3445(2) 0.0261(10) Uani 1 1 d . . .
C1C C 0.4775(5) 0.5930(3) 0.2837(2) 0.0262(11) Uani 1 1 d . . .
N2C N 0.3774(4) 0.4165(3) 0.40313(18) 0.0234(8) Uani 1 1 d . . .
N1C N 0.4196(4) 0.4554(3) 0.35063(19) 0.0225(8) Uani 1 1 d . . .
N1A N -0.0399(4) 0.5737(3) 0.1531(2) 0.0337(10) Uani 1 1 d . . .
N2A N -0.1311(4) 0.6295(3) 0.1731(2) 0.0273(9) Uani 1 1 d . . .
C5A C -0.1342(5) 0.6370(4) 0.2382(2) 0.0280(11) Uani 1 1 d . . .
O4H O 0.3943(3) 0.0628(2) 0.37979(18) 0.0343(8) Uani 1 1 d . . .
C3C C 0.3924(6) 0.6227(4) 0.3901(3) 0.0440(15) Uani 1 1 d . . .
H3C H 0.3972 0.6924 0.3842 0.053 Uiso 1 1 calc R . .
C4C C 0.3496(6) 0.5828(4) 0.4436(3) 0.0448(15) Uani 1 1 d . . .
H4C H 0.3240 0.6245 0.4754 0.054 Uiso 1 1 calc R . .
C3A C 0.0465(5) 0.5287(4) 0.2687(3) 0.0419(14) Uani 1 1 d . . .
H3A H 0.1073 0.4921 0.3003 0.050 Uiso 1 1 calc R . .
C4A C -0.0483(5) 0.5860(4) 0.2884(3) 0.0381(13) Uani 1 1 d . . .
H4A H -0.0541 0.5901 0.3335 0.046 Uiso 1 1 calc R . .
C6A C -0.2385(5) 0.7075(4) 0.2520(2) 0.0260(10) Uani 1 1 d . . .
O3A O -0.2490(3) 0.7246(3) 0.31004(17) 0.0364(9) Uani 1 1 d . . .
O4B O 0.6698(4) 0.1023(3) 0.55497(19) 0.0458(10) Uani 1 1 d . . .
C6B C 0.5945(5) 0.1485(4) 0.5102(2) 0.0273(11) Uani 1 1 d . . .
O4A O -0.3133(3) 0.7491(2) 0.20019(15) 0.0239(7) Uani 1 1 d . . .
O7H O 0.0644(5) 0.2575(4) 0.5599(2) 0.0754(15) Uani 1 1 d . . .
O6H O 0.9744(6) 0.4105(6) 0.4610(4) 0.120(3) Uani 1 1 d . . .
O8H O 0.8956(5) 0.3060(5) 0.1410(3) 0.0860(17) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1A Eu1 O1B 147.04(13) . . ?
O1A Eu1 O2C 135.80(13) . 2_645 ?
O1B Eu1 O2C 72.84(12) . 2_645 ?
O1A Eu1 O1H 75.80(12) . . ?
O1B Eu1 O1H 90.56(11) . . ?
O2C Eu1 O1H 90.53(12) 2_645 . ?
O1A Eu1 O1C 75.43(13) . . ?
O1B Eu1 O1C 72.72(12) . . ?
O2C Eu1 O1C 144.18(12) 2_645 . ?
O1H Eu1 O1C 80.23(12) . . ?
O1A Eu1 O4A 75.83(12) . 2_545 ?
O1B Eu1 O4A 134.25(11) . 2_545 ?
O2C Eu1 O4A 78.96(12) 2_645 2_545 ?
O1H Eu1 O4A 125.39(11) . 2_545 ?
O1C Eu1 O4A 134.04(11) . 2_545 ?
O1A Eu1 N1B 132.77(12) . . ?
O1B Eu1 N1B 64.01(11) . . ?
O2C Eu1 N1B 70.22(12) 2_645 . ?
O1H Eu1 N1B 151.34(11) . . ?
O1C Eu1 N1B 102.75(12) . . ?
O4A Eu1 N1B 72.92(11) 2_545 . ?
O1A Eu1 N1C 68.30(12) . . ?
O1B Eu1 N1C 103.98(12) . . ?
O2C Eu1 N1C 135.59(12) 2_645 . ?
O1H Eu1 N1C 133.80(12) . . ?
O1C Eu1 N1C 63.59(11) . . ?
O4A Eu1 N1C 72.76(11) 2_545 . ?
N1B Eu1 N1C 69.12(11) . . ?
O1A Eu1 O3A 69.39(13) . 2_545 ?
O1B Eu1 O3A 136.71(12) . 2_545 ?
O2C Eu1 O3A 66.52(12) 2_645 2_545 ?
O1H Eu1 O3A 75.86(11) . 2_545 ?
O1C Eu1 O3A 141.21(12) . 2_545 ?
O4A Eu1 O3A 50.66(10) 2_545 2_545 ?
N1B Eu1 O3A 112.90(11) . 2_545 ?
N1C Eu1 O3A 115.15(11) . 2_545 ?
O1A Eu1 C6A 70.61(14) . 2_545 ?
O1B Eu1 C6A 142.14(13) . 2_545 ?
O2C Eu1 C6A 70.88(13) 2_645 2_545 ?
O1H Eu1 C6A 100.19(13) . 2_545 ?
O1C Eu1 C6A 144.69(13) . 2_545 ?
O4A Eu1 C6A 25.82(12) 2_545 2_545 ?
N1B Eu1 C6A 93.44(12) . 2_545 ?
N1C Eu1 C6A 94.46(12) . 2_545 ?
O3A Eu1 C6A 24.85(11) 2_545 2_545 ?
O1A Eu1 C1B 159.02(13) . . ?
O1B Eu1 C1B 17.83(12) . . ?
O2C Eu1 C1B 65.09(13) 2_645 . ?
O1H Eu1 C1B 106.19(12) . . ?
O1C Eu1 C1B 84.26(13) . . ?
O4A Eu1 C1B 116.52(11) 2_545 . ?
N1B Eu1 C1B 46.88(12) . . ?
N1C Eu1 C1B 98.10(12) . . ?
O3A Eu1 C1B 131.58(12) 2_545 . ?
C6A Eu1 C1B 128.09(13) 2_545 . ?
O1A Eu1 Eu2 83.05(9) . . ?
O1B Eu1 Eu2 119.63(8) . . ?
O2C Eu1 Eu2 87.68(9) 2_645 . ?
O1H Eu1 Eu2 147.51(8) . . ?
O1C Eu1 Eu2 118.10(8) . . ?
O4A Eu1 Eu2 23.06(7) 2_545 . ?
N1B Eu1 Eu2 55.63(8) . . ?
N1C Eu1 Eu2 54.53(8) . . ?
O3A Eu1 Eu2 73.72(7) 2_545 . ?
C6A Eu1 Eu2 48.87(9) 2_545 . ?
C1B Eu1 Eu2 102.38(9) . . ?
O3C Eu2 O4A 135.30(11) . 2_545 ?
O3C Eu2 O3B 74.53(12) . . ?
O4A Eu2 O3B 132.31(11) 2_545 . ?
O3C Eu2 O2H 77.07(13) . . ?
O4A Eu2 O2H 134.02(12) 2_545 . ?
O3B Eu2 O2H 80.06(12) . . ?
O3C Eu2 O4H 146.65(12) . . ?
O4A Eu2 O4H 75.58(11) 2_545 . ?
O3B Eu2 O4H 73.60(12) . . ?
O2H Eu2 O4H 87.99(13) . . ?
O3C Eu2 O3H 72.99(13) . . ?
O4A Eu2 O3H 79.27(12) 2_545 . ?
O3B Eu2 O3H 146.16(12) . . ?
O2H Eu2 O3H 83.69(13) . . ?
O4H Eu2 O3H 135.39(12) . . ?
O3C Eu2 N2A 131.19(12) . 2_545 ?
O4A Eu2 N2A 63.19(11) 2_545 2_545 ?
O3B Eu2 N2A 131.85(13) . 2_545 ?
O2H Eu2 N2A 70.83(12) . 2_545 ?
O4H Eu2 N2A 68.01(12) . 2_545 ?
O3H Eu2 N2A 67.86(12) . 2_545 ?
O3C Eu2 N2C 63.98(11) . . ?
O4A Eu2 N2C 74.10(11) 2_545 . ?
O3B Eu2 N2C 103.14(12) . . ?
O2H Eu2 N2C 137.86(12) . . ?
O4H Eu2 N2C 133.67(11) . . ?
O3H Eu2 N2C 70.54(12) . . ?
N2A Eu2 N2C 124.26(12) 2_545 . ?
O3C Eu2 N2B 104.91(12) . . ?
O4A Eu2 N2B 72.21(11) 2_545 . ?
O3B Eu2 N2B 63.02(11) . . ?
O2H Eu2 N2B 140.18(12) . . ?
O4H Eu2 N2B 68.50(11) . . ?
O3H Eu2 N2B 135.59(12) . . ?
N2A Eu2 N2B 123.35(12) 2_545 . ?
N2C Eu2 N2B 69.33(11) . . ?
O3C Eu2 Eu1 119.29(8) . . ?
O4A Eu2 Eu1 23.81(7) 2_545 . ?
O3B Eu2 Eu1 117.39(8) . . ?
O2H Eu2 Eu1 157.80(9) . . ?
O4H Eu2 Eu1 84.47(8) . . ?
O3H Eu2 Eu1 87.09(9) . . ?
N2A Eu2 Eu1 86.99(8) 2_545 . ?
N2C Eu2 Eu1 55.31(8) . . ?
N2B Eu2 Eu1 54.38(8) . . ?
C1B O1B Eu1 126.6(3) . . ?
C6B O3B Eu2 127.7(3) . . ?
C2B N1B N2B 119.4(4) . . ?
C2B N1B Eu1 115.0(3) . . ?
N2B N1B Eu1 124.7(3) . . ?
C5B N2B N1B 119.4(4) . . ?
C5B N2B Eu2 114.5(3) . . ?
N1B N2B Eu2 125.3(3) . . ?
N1B C2B C3B 122.5(4) . . ?
N1B C2B C1B 114.8(4) . . ?
C3B C2B C1B 122.6(4) . . ?
C4B C3B C2B 118.0(5) . . ?
C4B C3B H3B 121.0 . . ?
C2B C3B H3B 121.0 . . ?
C3B C4B C5B 117.6(5) . . ?
C3B C4B H4B 121.2 . . ?
C5B C4B H4B 121.2 . . ?
O1B C1B O2B 126.7(5) . . ?
O1B C1B C2B 117.1(4) . . ?
O2B C1B C2B 116.2(4) . . ?
O1B C1B Eu1 35.5(2) . . ?
O2B C1B Eu1 158.8(4) . . ?
C2B C1B Eu1 82.7(3) . . ?
N2B C5B C4B 123.0(4) . . ?
N2B C5B C6B 116.0(4) . . ?
C4B C5B C6B 121.0(4) . . ?
C1C O1C Eu1 125.4(3) . . ?
C1A O1A Eu1 141.5(3) . . ?
N1A C2A C3A 122.1(4) . . ?
N1A C2A C1A 116.8(4) . . ?
C3A C2A C1A 121.0(4) . . ?
O2A C1A O1A 127.1(5) . . ?
O2A C1A C2A 118.8(5) . . ?
O1A C1A C2A 114.0(4) . . ?
C6C O3C Eu2 128.0(3) . . ?
C1C O2C Eu1 161.6(3) . 2_655 ?
O4C C6C O3C 127.2(5) . . ?
O4C C6C C5C 116.8(5) . . ?
O3C C6C C5C 115.9(4) . . ?
N2C C5C C4C 122.8(5) . . ?
N2C C5C C6C 115.6(4) . . ?
C4C C5C C6C 121.6(5) . . ?
N1C C2C C3C 122.4(5) . . ?
N1C C2C C1C 116.6(4) . . ?
C3C C2C C1C 121.0(4) . . ?
O2C C1C O1C 127.6(5) . . ?
O2C C1C C2C 114.6(4) . . ?
O1C C1C C2C 117.8(4) . . ?
C5C N2C N1C 119.4(4) . . ?
C5C N2C Eu2 114.6(3) . . ?
N1C N2C Eu2 125.2(3) . . ?
C2C N1C N2C 119.9(4) . . ?
C2C N1C Eu1 114.2(3) . . ?
N2C N1C Eu1 125.0(3) . . ?
N2A N1A C2A 118.3(4) . . ?
C5A N2A N1A 121.1(4) . . ?
C5A N2A Eu2 118.0(3) . 2 ?
N1A N2A Eu2 120.9(3) . 2 ?
N2A C5A C4A 122.9(4) . . ?
N2A C5A C6A 114.0(4) . . ?
C4A C5A C6A 123.1(4) . . ?
C4C C3C C2C 117.6(5) . . ?
C4C C3C H3C 121.2 . . ?
C2C C3C H3C 121.2 . . ?
C3C C4C C5C 117.9(5) . . ?
C3C C4C H4C 121.1 . . ?
C5C C4C H4C 121.1 . . ?
C4A C3A C2A 118.7(5) . . ?
C4A C3A H3A 120.6 . . ?
C2A C3A H3A 120.6 . . ?
C3A C4A C5A 116.6(5) . . ?
C3A C4A H4A 121.7 . . ?
C5A C4A H4A 121.7 . . ?
O3A C6A O4A 122.6(4) . . ?
O3A C6A C5A 120.9(4) . . ?
O4A C6A C5A 116.5(4) . . ?
O3A C6A Eu1 67.1(3) . 2 ?
O4A C6A Eu1 55.5(2) . 2 ?
C5A C6A Eu1 171.9(3) . 2 ?
C6A O3A Eu1 88.0(3) . 2 ?
O4B C6B O3B 125.8(5) . . ?
O4B C6B C5B 118.0(4) . . ?
O3B C6B C5B 116.2(4) . . ?
C6A O4A Eu2 128.1(3) . 2 ?
C6A O4A Eu1 98.7(3) . 2 ?
Eu2 O4A Eu1 133.13(13) 2 2 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O1A 2.346(3) . ?
Eu1 O1B 2.362(3) . ?
Eu1 O2C 2.363(3) 2_645 ?
Eu1 O1H 2.371(3) . ?
Eu1 O1C 2.419(3) . ?
Eu1 O4A 2.428(3) 2_545 ?
Eu1 N1B 2.635(4) . ?
Eu1 N1C 2.674(4) . ?
Eu1 O3A 2.687(3) 2_545 ?
Eu1 C6A 2.914(5) 2_545 ?
Eu1 C1B 3.261(5) . ?
Eu1 Eu2 4.3897(4) . ?
Eu2 O3C 2.347(3) . ?
Eu2 O4A 2.356(3) 2_545 ?
Eu2 O3B 2.374(3) . ?
Eu2 O2H 2.413(3) . ?
Eu2 O4H 2.477(3) . ?
Eu2 O3H 2.491(3) . ?
Eu2 N2A 2.618(4) 2_545 ?
Eu2 N2C 2.635(4) . ?
Eu2 N2B 2.684(4) . ?
O1B C1B 1.244(6) . ?
O2B C1B 1.255(6) . ?
O3B C6B 1.265(6) . ?
N1B C2B 1.335(6) . ?
N1B N2B 1.339(5) . ?
N2B C5B 1.329(6) . ?
C2B C3B 1.386(7) . ?
C2B C1B 1.528(6) . ?
C3B C4B 1.354(7) . ?
C3B H3B 0.9300 . ?
C4B C5B 1.385(7) . ?
C4B H4B 0.9300 . ?
C5B C6B 1.516(6) . ?
O1C C1C 1.249(6) . ?
O1A C1A 1.233(6) . ?
C2A N1A 1.337(6) . ?
C2A C3A 1.394(7) . ?
C2A C1A 1.519(7) . ?
C1A O2A 1.234(6) . ?
O3C C6C 1.258(6) . ?
O2C C1C 1.232(6) . ?
O2C Eu1 2.363(3) 2_655 ?
O4C C6C 1.231(6) . ?
C6C C5C 1.521(7) . ?
C5C N2C 1.335(6) . ?
C5C C4C 1.379(8) . ?
C2C N1C 1.328(6) . ?
C2C C3C 1.394(7) . ?
C2C C1C 1.515(6) . ?
N2C N1C 1.338(5) . ?
N1A N2A 1.333(5) . ?
N2A C5A 1.328(6) . ?
N2A Eu2 2.618(4) 2 ?
C5A C4A 1.374(7) . ?
C5A C6A 1.502(6) . ?
C3C C4C 1.364(8) . ?
C3C H3C 0.9300 . ?
C4C H4C 0.9300 . ?
C3A C4A 1.370(7) . ?
C3A H3A 0.9300 . ?
C4A H4A 0.9300 . ?
C6A O3A 1.225(6) . ?
C6A O4A 1.284(6) . ?
C6A Eu1 2.914(5) 2 ?
O3A Eu1 2.687(3) 2 ?
O4B C6B 1.223(6) . ?
O4A Eu2 2.356(3) 2 ?
O4A Eu1 2.428(3) 2 ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O1A Eu1 Eu2 O3C -68.47(14) . . . . ?
O1B Eu1 Eu2 O3C 86.10(15) . . . . ?
O2C Eu1 Eu2 O3C 154.83(14) 2_645 . . . ?
O1H Eu1 Eu2 O3C -117.83(19) . . . . ?
O1C Eu1 Eu2 O3C 0.90(15) . . . . ?
O4A Eu1 Eu2 O3C -138.4(2) 2_545 . . . ?
N1B Eu1 Eu2 O3C 87.33(14) . . . . ?
N1C Eu1 Eu2 O3C -0.22(14) . . . . ?
O3A Eu1 Eu2 O3C -138.97(13) 2_545 . . . ?
C6A Eu1 Eu2 O3C -138.73(16) 2_545 . . . ?
C1B Eu1 Eu2 O3C 90.96(14) . . . . ?
O1A Eu1 Eu2 O4A 69.9(2) . . . 2_545 ?
O1B Eu1 Eu2 O4A -135.5(2) . . . 2_545 ?
O2C Eu1 Eu2 O4A -66.8(2) 2_645 . . 2_545 ?
O1H Eu1 Eu2 O4A 20.5(2) . . . 2_545 ?
O1C Eu1 Eu2 O4A 139.3(2) . . . 2_545 ?
N1B Eu1 Eu2 O4A -134.3(2) . . . 2_545 ?
N1C Eu1 Eu2 O4A 138.1(2) . . . 2_545 ?
O3A Eu1 Eu2 O4A -0.6(2) 2_545 . . 2_545 ?
C6A Eu1 Eu2 O4A -0.4(2) 2_545 . . 2_545 ?
C1B Eu1 Eu2 O4A -130.7(2) . . . 2_545 ?
O1A Eu1 Eu2 O3B -155.38(14) . . . . ?
O1B Eu1 Eu2 O3B -0.81(14) . . . . ?
O2C Eu1 Eu2 O3B 67.92(13) 2_645 . . . ?
O1H Eu1 Eu2 O3B 155.26(19) . . . . ?
O1C Eu1 Eu2 O3B -86.01(14) . . . . ?
O4A Eu1 Eu2 O3B 134.7(2) 2_545 . . . ?
N1B Eu1 Eu2 O3B 0.42(14) . . . . ?
N1C Eu1 Eu2 O3B -87.13(14) . . . . ?
O3A Eu1 Eu2 O3B 134.12(13) 2_545 . . . ?
C6A Eu1 Eu2 O3B 134.35(16) 2_545 . . . ?
C1B Eu1 Eu2 O3B 4.05(14) . . . . ?
O1A Eu1 Eu2 O2H 65.6(3) . . . . ?
O1B Eu1 Eu2 O2H -139.8(3) . . . . ?
O2C Eu1 Eu2 O2H -71.1(3) 2_645 . . . ?
O1H Eu1 Eu2 O2H 16.3(3) . . . . ?
O1C Eu1 Eu2 O2H 135.0(3) . . . . ?
O4A Eu1 Eu2 O2H -4.3(3) 2_545 . . . ?
N1B Eu1 Eu2 O2H -138.6(3) . . . . ?
N1C Eu1 Eu2 O2H 133.9(3) . . . . ?
O3A Eu1 Eu2 O2H -4.9(3) 2_545 . . . ?
C6A Eu1 Eu2 O2H -4.7(3) 2_545 . . . ?
C1B Eu1 Eu2 O2H -135.0(3) . . . . ?
O1A Eu1 Eu2 O4H 136.31(13) . . . . ?
O1B Eu1 Eu2 O4H -69.11(13) . . . . ?
O2C Eu1 Eu2 O4H -0.38(12) 2_645 . . . ?
O1H Eu1 Eu2 O4H 86.96(18) . . . . ?
O1C Eu1 Eu2 O4H -154.32(13) . . . . ?
O4A Eu1 Eu2 O4H 66.4(2) 2_545 . . . ?
N1B Eu1 Eu2 O4H -67.89(13) . . . . ?
N1C Eu1 Eu2 O4H -155.44(13) . . . . ?
O3A Eu1 Eu2 O4H 65.82(12) 2_545 . . . ?
C6A Eu1 Eu2 O4H 66.05(15) 2_545 . . . ?
C1B Eu1 Eu2 O4H -64.25(13) . . . . ?
O1A Eu1 Eu2 O3H 0.17(13) . . . . ?
O1B Eu1 Eu2 O3H 154.74(13) . . . . ?
O2C Eu1 Eu2 O3H -136.53(13) 2_645 . . . ?
O1H Eu1 Eu2 O3H -49.19(18) . . . . ?
O1C Eu1 Eu2 O3H 69.53(13) . . . . ?
O4A Eu1 Eu2 O3H -69.7(2) 2_545 . . . ?
N1B Eu1 Eu2 O3H 155.97(13) . . . . ?
N1C Eu1 Eu2 O3H 68.41(13) . . . . ?
O3A Eu1 Eu2 O3H -70.33(12) 2_545 . . . ?
C6A Eu1 Eu2 O3H -70.10(15) 2_545 . . . ?
C1B Eu1 Eu2 O3H 159.60(13) . . . . ?
O1A Eu1 Eu2 N2A 68.13(13) . . . 2_545 ?
O1B Eu1 Eu2 N2A -137.30(13) . . . 2_545 ?
O2C Eu1 Eu2 N2A -68.56(13) 2_645 . . 2_545 ?
O1H Eu1 Eu2 N2A 18.78(18) . . . 2_545 ?
O1C Eu1 Eu2 N2A 137.50(13) . . . 2_545 ?
O4A Eu1 Eu2 N2A -1.8(2) 2_545 . . 2_545 ?
N1B Eu1 Eu2 N2A -136.07(13) . . . 2_545 ?
N1C Eu1 Eu2 N2A 136.38(13) . . . 2_545 ?
O3A Eu1 Eu2 N2A -2.37(12) 2_545 . . 2_545 ?
C6A Eu1 Eu2 N2A -2.13(15) 2_545 . . 2_545 ?
C1B Eu1 Eu2 N2A -132.43(13) . . . 2_545 ?
O1A Eu1 Eu2 N2C -68.09(14) . . . . ?
O1B Eu1 Eu2 N2C 86.48(14) . . . . ?
O2C Eu1 Eu2 N2C 155.22(14) 2_645 . . . ?
O1H Eu1 Eu2 N2C -117.44(19) . . . . ?
O1C Eu1 Eu2 N2C 1.28(14) . . . . ?
O4A Eu1 Eu2 N2C -138.0(2) 2_545 . . . ?
N1B Eu1 Eu2 N2C 87.71(14) . . . . ?
N1C Eu1 Eu2 N2C 0.16(14) . . . . ?
O3A Eu1 Eu2 N2C -138.59(13) 2_545 . . . ?
C6A Eu1 Eu2 N2C -138.35(16) 2_545 . . . ?
C1B Eu1 Eu2 N2C 91.35(14) . . . . ?
O1A Eu1 Eu2 N2B -156.24(14) . . . . ?
O1B Eu1 Eu2 N2B -1.67(14) . . . . ?
O2C Eu1 Eu2 N2B 67.07(13) 2_645 . . . ?
O1H Eu1 Eu2 N2B 154.41(19) . . . . ?
O1C Eu1 Eu2 N2B -86.87(14) . . . . ?
O4A Eu1 Eu2 N2B 133.9(2) 2_545 . . . ?
N1B Eu1 Eu2 N2B -0.44(14) . . . . ?
N1C Eu1 Eu2 N2B -87.99(14) . . . . ?
O3A Eu1 Eu2 N2B 133.26(13) 2_545 . . . ?
C6A Eu1 Eu2 N2B 133.50(16) 2_545 . . . ?
C1B Eu1 Eu2 N2B 3.20(13) . . . . ?
O1A Eu1 O1B C1B 144.1(4) . . . . ?
O2C Eu1 O1B C1B -61.3(4) 2_645 . . . ?
O1H Eu1 O1B C1B -151.7(4) . . . . ?
O1C Eu1 O1B C1B 128.7(4) . . . . ?
O4A Eu1 O1B C1B -6.8(5) 2_545 . . . ?
N1B Eu1 O1B C1B 14.6(4) . . . . ?
N1C Eu1 O1B C1B 72.6(4) . . . . ?
O3A Eu1 O1B C1B -82.0(4) 2_545 . . . ?
C6A Eu1 O1B C1B -44.2(5) 2_545 . . . ?
Eu2 Eu1 O1B C1B 15.7(4) . . . . ?
O3C Eu2 O3B C6B -131.3(4) . . . . ?
O4A Eu2 O3B C6B 6.9(5) 2_545 . . . ?
O2H Eu2 O3B C6B 149.5(4) . . . . ?
O4H Eu2 O3B C6B 58.7(4) . . . . ?
O3H Eu2 O3B C6B -148.0(4) . . . . ?
N2A Eu2 O3B C6B 96.7(4) 2_545 . . . ?
N2C Eu2 O3B C6B -73.4(4) . . . . ?
N2B Eu2 O3B C6B -15.1(4) . . . . ?
Eu1 Eu2 O3B C6B -15.9(4) . . . . ?
O1A Eu1 N1B C2B -156.2(3) . . . . ?
O1B Eu1 N1B C2B -11.0(3) . . . . ?
O2C Eu1 N1B C2B 69.0(3) 2_645 . . . ?
O1H Eu1 N1B C2B 18.6(5) . . . . ?
O1C Eu1 N1B C2B -74.3(3) . . . . ?
O4A Eu1 N1B C2B 153.1(3) 2_545 . . . ?
N1C Eu1 N1B C2B -129.3(3) . . . . ?
O3A Eu1 N1B C2B 121.3(3) 2_545 . . . ?
C6A Eu1 N1B C2B 137.3(3) 2_545 . . . ?
C1B Eu1 N1B C2B -5.0(3) . . . . ?
Eu2 Eu1 N1B C2B 170.2(4) . . . . ?
O1A Eu1 N1B N2B 34.5(4) . . . . ?
O1B Eu1 N1B N2B 179.7(4) . . . . ?
O2C Eu1 N1B N2B -100.3(3) 2_645 . . . ?
O1H Eu1 N1B N2B -150.7(3) . . . . ?
O1C Eu1 N1B N2B 116.4(3) . . . . ?
O4A Eu1 N1B N2B -16.2(3) 2_545 . . . ?
N1C Eu1 N1B N2B 61.4(3) . . . . ?
O3A Eu1 N1B N2B -48.0(3) 2_545 . . . ?
C6A Eu1 N1B N2B -32.0(3) 2_545 . . . ?
C1B Eu1 N1B N2B -174.3(4) . . . . ?
Eu2 Eu1 N1B N2B 0.9(3) . . . . ?
C2B N1B N2B C5B -0.9(6) . . . . ?
Eu1 N1B N2B C5B 168.0(3) . . . . ?
C2B N1B N2B Eu2 -170.3(3) . . . . ?
Eu1 N1B N2B Eu2 -1.4(5) . . . . ?
O3C Eu2 N2B C5B 75.4(3) . . . . ?
O4A Eu2 N2B C5B -151.2(3) 2_545 . . . ?
O3B Eu2 N2B C5B 11.8(3) . . . . ?
O2H Eu2 N2B C5B -12.2(4) . . . . ?
O4H Eu2 N2B C5B -70.1(3) . . . . ?
O3H Eu2 N2B C5B 156.1(3) . . . . ?
N2A Eu2 N2B C5B -112.3(3) 2_545 . . . ?
N2C Eu2 N2B C5B 129.5(3) . . . . ?
Eu1 Eu2 N2B C5B -169.0(3) . . . . ?
O3C Eu2 N2B N1B -114.7(3) . . . . ?
O4A Eu2 N2B N1B 18.7(3) 2_545 . . . ?
O3B Eu2 N2B N1B -178.3(4) . . . . ?
O2H Eu2 N2B N1B 157.7(3) . . . . ?
O4H Eu2 N2B N1B 99.8(3) . . . . ?
O3H Eu2 N2B N1B -34.0(4) . . . . ?
N2A Eu2 N2B N1B 57.6(4) 2_545 . . . ?
N2C Eu2 N2B N1B -60.6(3) . . . . ?
Eu1 Eu2 N2B N1B 0.9(3) . . . . ?
N2B N1B C2B C3B 0.9(7) . . . . ?
Eu1 N1B C2B C3B -169.0(4) . . . . ?
N2B N1B C2B C1B 178.4(4) . . . . ?
Eu1 N1B C2B C1B 8.5(5) . . . . ?
N1B C2B C3B C4B -0.4(8) . . . . ?
C1B C2B C3B C4B -177.7(5) . . . . ?
C2B C3B C4B C5B -0.1(8) . . . . ?
Eu1 O1B C1B O2B 163.1(4) . . . . ?
Eu1 O1B C1B C2B -15.7(6) . . . . ?
N1B C2B C1B O1B 2.9(7) . . . . ?
C3B C2B C1B O1B -179.6(5) . . . . ?
N1B C2B C1B O2B -176.1(5) . . . . ?
C3B C2B C1B O2B 1.4(7) . . . . ?
N1B C2B C1B Eu1 -6.3(4) . . . . ?
C3B C2B C1B Eu1 171.2(5) . . . . ?
O1A Eu1 C1B O1B -63.0(6) . . . . ?
O2C Eu1 C1B O1B 112.4(4) 2_645 . . . ?
O1H Eu1 C1B O1B 29.5(4) . . . . ?
O1C Eu1 C1B O1B -48.5(4) . . . . ?
O4A Eu1 C1B O1B 174.5(4) 2_545 . . . ?
N1B Eu1 C1B O1B -162.0(5) . . . . ?
N1C Eu1 C1B O1B -110.8(4) . . . . ?
O3A Eu1 C1B O1B 114.8(4) 2_545 . . . ?
C6A Eu1 C1B O1B 147.0(4) 2_545 . . . ?
Eu2 Eu1 C1B O1B -166.1(4) . . . . ?
O1A Eu1 C1B O2B -103.0(11) . . . . ?
O1B Eu1 C1B O2B -40.0(9) . . . . ?
O2C Eu1 C1B O2B 72.4(11) 2_645 . . . ?
O1H Eu1 C1B O2B -10.5(11) . . . . ?
O1C Eu1 C1B O2B -88.6(11) . . . . ?
O4A Eu1 C1B O2B 134.5(10) 2_545 . . . ?
N1B Eu1 C1B O2B 158.0(11) . . . . ?
N1C Eu1 C1B O2B -150.8(10) . . . . ?
O3A Eu1 C1B O2B 74.8(11) 2_545 . . . ?
C6A Eu1 C1B O2B 107.0(10) 2_545 . . . ?
Eu2 Eu1 C1B O2B 153.9(10) . . . . ?
O1A Eu1 C1B C2B 102.9(4) . . . . ?
O1B Eu1 C1B C2B 165.9(6) . . . . ?
O2C Eu1 C1B C2B -81.7(3) 2_645 . . . ?
O1H Eu1 C1B C2B -164.5(3) . . . . ?
O1C Eu1 C1B C2B 117.4(3) . . . . ?
O4A Eu1 C1B C2B -19.5(3) 2_545 . . . ?
N1B Eu1 C1B C2B 4.0(2) . . . . ?
N1C Eu1 C1B C2B 55.2(3) . . . . ?
O3A Eu1 C1B C2B -79.3(3) 2_545 . . . ?
C6A Eu1 C1B C2B -47.0(3) 2_545 . . . ?
Eu2 Eu1 C1B C2B -0.2(3) . . . . ?
N1B N2B C5B C4B 0.3(7) . . . . ?
Eu2 N2B C5B C4B 170.9(4) . . . . ?
N1B N2B C5B C6B 179.8(4) . . . . ?
Eu2 N2B C5B C6B -9.7(5) . . . . ?
C3B C4B C5B N2B 0.2(8) . . . . ?
C3B C4B C5B C6B -179.3(5) . . . . ?
O1A Eu1 O1C C1C 58.5(4) . . . . ?
O1B Eu1 O1C C1C -130.1(4) . . . . ?
O2C Eu1 O1C C1C -146.6(4) 2_645 . . . ?
O1H Eu1 O1C C1C 136.2(4) . . . . ?
O4A Eu1 O1C C1C 5.6(5) 2_545 . . . ?
N1B Eu1 O1C C1C -72.8(4) . . . . ?
N1C Eu1 O1C C1C -14.2(4) . . . . ?
O3A Eu1 O1C C1C 83.8(4) 2_545 . . . ?
C6A Eu1 O1C C1C 42.4(5) 2_545 . . . ?
C1B Eu1 O1C C1C -116.2(4) . . . . ?
Eu2 Eu1 O1C C1C -15.2(4) . . . . ?
O1B Eu1 O1A C1A 73.5(7) . . . . ?
O2C Eu1 O1A C1A -70.4(6) 2_645 . . . ?
O1H Eu1 O1A C1A 5.3(6) . . . . ?
O1C Eu1 O1A C1A 88.7(6) . . . . ?
O4A Eu1 O1A C1A -127.5(6) 2_545 . . . ?
N1B Eu1 O1A C1A -177.3(5) . . . . ?
N1C Eu1 O1A C1A 155.7(6) . . . . ?
O3A Eu1 O1A C1A -74.6(6) 2_545 . . . ?
C6A Eu1 O1A C1A -101.1(6) 2_545 . . . ?
C1B Eu1 O1A C1A 103.6(6) . . . . ?
Eu2 Eu1 O1A C1A -149.8(6) . . . . ?
Eu1 O1A C1A O2A 0.3(11) . . . . ?
Eu1 O1A C1A C2A -176.9(4) . . . . ?
N1A C2A C1A O2A -3.2(8) . . . . ?
C3A C2A C1A O2A 178.8(6) . . . . ?
N1A C2A C1A O1A 174.3(5) . . . . ?
C3A C2A C1A O1A -3.8(8) . . . . ?
O4A Eu2 O3C C6C -10.8(5) 2_545 . . . ?
O3B Eu2 O3C C6C 124.7(5) . . . . ?
O2H Eu2 O3C C6C -152.2(5) . . . . ?
O4H Eu2 O3C C6C 142.3(4) . . . . ?
O3H Eu2 O3C C6C -64.9(4) . . . . ?
N2A Eu2 O3C C6C -102.6(4) 2_545 . . . ?
N2C Eu2 O3C C6C 11.3(4) . . . . ?
N2B Eu2 O3C C6C 68.8(5) . . . . ?
Eu1 Eu2 O3C C6C 11.6(5) . . . . ?
Eu2 O3C C6C O4C 170.3(5) . . . . ?
Eu2 O3C C6C C5C -9.5(7) . . . . ?
O4C C6C C5C N2C 177.0(5) . . . . ?
O3C C6C C5C N2C -3.2(7) . . . . ?
O4C C6C C5C C4C -3.5(8) . . . . ?
O3C C6C C5C C4C 176.3(5) . . . . ?
Eu1 O2C C1C O1C -40.1(14) 2_655 . . . ?
Eu1 O2C C1C C2C 141.0(9) 2_655 . . . ?
Eu1 O1C C1C O2C -164.4(4) . . . . ?
Eu1 O1C C1C C2C 14.4(6) . . . . ?
N1C C2C C1C O2C 178.2(4) . . . . ?
C3C C2C C1C O2C 0.1(7) . . . . ?
N1C C2C C1C O1C -0.8(7) . . . . ?
C3C C2C C1C O1C -178.9(5) . . . . ?
C4C C5C N2C N1C 2.2(8) . . . . ?
C6C C5C N2C N1C -178.3(4) . . . . ?
C4C C5C N2C Eu2 -167.9(4) . . . . ?
C6C C5C N2C Eu2 11.6(5) . . . . ?
O3C Eu2 N2C C5C -11.3(3) . . . . ?
O4A Eu2 N2C C5C 152.7(4) 2_545 . . . ?
O3B Eu2 N2C C5C -76.5(3) . . . . ?
O2H Eu2 N2C C5C 13.1(4) . . . . ?
O4H Eu2 N2C C5C -156.3(3) . . . . ?
O3H Eu2 N2C C5C 68.7(3) . . . . ?
N2A Eu2 N2C C5C 112.3(3) 2_545 . . . ?
N2B Eu2 N2C C5C -130.7(4) . . . . ?
Eu1 Eu2 N2C C5C 169.1(4) . . . . ?
O3C Eu2 N2C N1C 179.3(4) . . . . ?
O4A Eu2 N2C N1C -16.6(3) 2_545 . . . ?
O3B Eu2 N2C N1C 114.1(3) . . . . ?
O2H Eu2 N2C N1C -156.3(3) . . . . ?
O4H Eu2 N2C N1C 34.3(4) . . . . ?
O3H Eu2 N2C N1C -100.6(3) . . . . ?
N2A Eu2 N2C N1C -57.0(4) 2_545 . . . ?
N2B Eu2 N2C N1C 60.0(3) . . . . ?
Eu1 Eu2 N2C N1C -0.3(3) . . . . ?
C3C C2C N1C N2C -1.9(7) . . . . ?
C1C C2C N1C N2C 180.0(4) . . . . ?
C3C C2C N1C Eu1 167.5(4) . . . . ?
C1C C2C N1C Eu1 -10.6(5) . . . . ?
C5C N2C N1C C2C -0.1(6) . . . . ?
Eu2 N2C N1C C2C 168.8(3) . . . . ?
C5C N2C N1C Eu1 -168.4(3) . . . . ?
Eu2 N2C N1C Eu1 0.5(5) . . . . ?
O1A Eu1 N1C C2C -72.0(3) . . . . ?
O1B Eu1 N1C C2C 74.2(3) . . . . ?
O2C Eu1 N1C C2C 153.8(3) 2_645 . . . ?
O1H Eu1 N1C C2C -30.4(4) . . . . ?
O1C Eu1 N1C C2C 12.0(3) . . . . ?
O4A Eu1 N1C C2C -153.3(3) 2_545 . . . ?
N1B Eu1 N1C C2C 128.9(3) . . . . ?
O3A Eu1 N1C C2C -124.8(3) 2_545 . . . ?
C6A Eu1 N1C C2C -139.1(3) 2_545 . . . ?
C1B Eu1 N1C C2C 91.4(3) . . . . ?
Eu2 Eu1 N1C C2C -169.1(4) . . . . ?
O1A Eu1 N1C N2C 96.8(3) . . . . ?
O1B Eu1 N1C N2C -116.9(3) . . . . ?
O2C Eu1 N1C N2C -37.3(4) 2_645 . . . ?
O1H Eu1 N1C N2C 138.4(3) . . . . ?
O1C Eu1 N1C N2C -179.2(4) . . . . ?
O4A Eu1 N1C N2C 15.6(3) 2_545 . . . ?
N1B Eu1 N1C N2C -62.3(3) . . . . ?
O3A Eu1 N1C N2C 44.1(4) 2_545 . . . ?
C6A Eu1 N1C N2C 29.7(3) 2_545 . . . ?
C1B Eu1 N1C N2C -99.8(3) . . . . ?
Eu2 Eu1 N1C N2C -0.3(3) . . . . ?
C3A C2A N1A N2A 3.8(8) . . . . ?
C1A C2A N1A N2A -174.2(4) . . . . ?
C2A N1A N2A C5A -0.8(7) . . . . ?
C2A N1A N2A Eu2 180.0(4) . . . 2 ?
N1A N2A C5A C4A -2.4(8) . . . . ?
Eu2 N2A C5A C4A 176.8(4) 2 . . . ?
N1A N2A C5A C6A 176.7(4) . . . . ?
Eu2 N2A C5A C6A -4.1(5) 2 . . . ?
N1C C2C C3C C4C 1.9(9) . . . . ?
C1C C2C C3C C4C 180.0(5) . . . . ?
C2C C3C C4C C5C 0.0(9) . . . . ?
N2C C5C C4C C3C -2.1(9) . . . . ?
C6C C5C C4C C3C 178.5(5) . . . . ?
N1A C2A C3A C4A -3.5(9) . . . . ?
C1A C2A C3A C4A 174.4(5) . . . . ?
C2A C3A C4A C5A 0.3(9) . . . . ?
N2A C5A C4A C3A 2.6(8) . . . . ?
C6A C5A C4A C3A -176.4(5) . . . . ?
N2A C5A C6A O3A -177.2(5) . . . . ?
C4A C5A C6A O3A 1.9(8) . . . . ?
N2A C5A C6A O4A 1.9(6) . . . . ?
C4A C5A C6A O4A -179.0(5) . . . . ?
N2A C5A C6A Eu1 -5(3) . . . 2 ?
C4A C5A C6A Eu1 174(2) . . . 2 ?
O4A C6A O3A Eu1 -0.2(5) . . . 2 ?
C5A C6A O3A Eu1 178.8(4) . . . 2 ?
Eu2 O3B C6B O4B -166.3(4) . . . . ?
Eu2 O3B C6B C5B 16.0(6) . . . . ?
N2B C5B C6B O4B -179.8(4) . . . . ?
C4B C5B C6B O4B -0.4(7) . . . . ?
N2B C5B C6B O3B -1.9(6) . . . . ?
C4B C5B C6B O3B 177.6(5) . . . . ?
O3A C6A O4A Eu2 -179.2(3) . . . 2 ?
C5A C6A O4A Eu2 1.8(6) . . . 2 ?
Eu1 C6A O4A Eu2 -179.4(4) 2 . . 2 ?
O3A C6A O4A Eu1 0.2(5) . . . 2 ?
C5A C6A O4A Eu1 -178.8(4) . . . 2 ?
