#------------------------------------------------------------------------------
#$Date: 2016-03-26 16:13:36 +0100 (Sat 26 de Mar de 2016) $
#$Revision: 180382 $
#$URL: svn://www.crystallography.net/cod/cif/7/20/51/7205164.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7205164
loop_
_publ_author_name
'Liu, Qing-Xiang'
'Chen, Ai-Hui'
'Zhao, Xiao-Jun'
'Zang, Yan'
'Wu, Xiu-Mei'
'Wang, Xiu-Guang'
'Guo, Jian-Hua'
_publ_section_title
;
 N-Heterocyclic carbene copper(i), mercury(ii) and silver(i) complexes
 containing durene linker: synthesis and structural studies
;
_journal_issue                   1
_journal_name_full               CrystEngComm
_journal_page_first              293
_journal_paper_doi               10.1039/c0ce00142b
_journal_volume                  13
_journal_year                    2011
_chemical_formula_sum            'C30 H42 Ag2 N6'
_chemical_formula_weight         702.43
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                98.1050(10)
_cell_angle_beta                 95.9220(10)
_cell_angle_gamma                107.0280(10)
_cell_formula_units_Z            2
_cell_length_a                   10.9505(6)
_cell_length_b                   14.8255(7)
_cell_length_c                   19.4605(9)
_cell_measurement_reflns_used    4518
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      23.27
_cell_measurement_theta_min      2.33
_cell_volume                     2955.6(3)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0148
_diffrn_reflns_av_sigmaI/netI    0.0337
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            15297
_diffrn_reflns_theta_full        25.03
_diffrn_reflns_theta_max         25.03
_diffrn_reflns_theta_min         1.07
_exptl_absorpt_coefficient_mu    1.355
_exptl_absorpt_correction_T_max  0.763
_exptl_absorpt_correction_T_min  0.691
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            COLORLESS
_exptl_crystal_density_diffrn    1.559
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       BLOCK
_exptl_crystal_F_000             1398.0
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.26
_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.682
_refine_diff_density_min         -0.658
_refine_diff_density_rms         0.084
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.020
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     690
_refine_ls_number_reflns         10382
_refine_ls_number_restraints     113
_refine_ls_restrained_S_all      1.037
_refine_ls_R_factor_all          0.0823
_refine_ls_R_factor_gt           0.0488
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0911P)²+2.0297P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1413
_refine_ls_wR_factor_ref         0.1698
_reflns_number_gt                6554
_reflns_number_total             10444
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            C0CE00142B.TXT
_cod_data_source_block           2e(2)
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'MULTI-SCAN' changed
to 'multi-scan' according to
'/home/saulius/struct/CIF-dictionaries/cif_core.dic' dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1555 2011-01-17 13:19:09Z saulius 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7205164
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.76019(5) 0.99796(3) 0.09961(3) 0.07945(19) Uani 1 1 d . . .
Ag2 Ag 0.90056(6) 1.01068(4) 0.26863(3) 0.0845(2) Uani 1 1 d . . .
Ag3 Ag -0.06140(6) 0.50148(4) 0.24826(3) 0.0876(2) Uani 1 1 d . . .
Ag4 Ag 0.22736(6) 0.64773(4) 0.32159(4) 0.0981(2) Uani 1 1 d . . .
N1 N 0.4819(7) 1.0081(5) 0.0893(3) 0.0838(16) Uani 1 1 d . . .
N2 N 0.4788(5) 0.8642(4) 0.0913(3) 0.0750(14) Uani 1 1 d . . .
N3 N 1.0924(5) 0.8914(4) 0.2625(3) 0.0691(13) Uani 1 1 d . . .
N4 N 1.1931(5) 1.0415(4) 0.2804(3) 0.0734(14) Uani 1 1 d . . .
N5 N 1.1709(7) 1.0859(8) 0.1098(5) 0.134(3) Uani 1 1 d . . .
N6 N 0.5879(14) 1.0819(14) 0.3377(9) 0.281(10) Uani 1 1 d D . .
N7 N 0.3270(7) 0.6136(5) 0.4669(4) 0.104(2) Uani 1 1 d . A .
N8 N 0.2918(8) 0.7431(5) 0.4790(5) 0.126(3) Uani 1 1 d D . .
N9 N -0.1052(5) 0.4262(4) 0.0894(3) 0.0752(14) Uani 1 1 d . . .
N10 N -0.0496(6) 0.3266(4) 0.1439(3) 0.0771(15) Uani 1 1 d . . .
N11 N 0.2053(10) 0.6255(9) 0.1164(6) 0.158(4) Uani 1 1 d . . .
N12 N -0.2757(11) 0.5604(9) 0.3940(5) 0.163(4) Uani 1 1 d . . .
C1 C 0.5713(10) 1.3078(7) 0.2494(5) 0.131(4) Uani 1 1 d . . .
H1A H 0.4858 1.2972 0.2613 0.197 Uiso 1 1 calc R . .
H1B H 0.6123 1.3753 0.2522 0.197 Uiso 1 1 calc R . .
H1C H 0.6209 1.2839 0.2817 0.197 Uiso 1 1 calc R . .
C2 C 0.5631(13) 1.2565(9) 0.1762(6) 0.161(5) Uani 1 1 d . . .
H2A H 0.4999 1.2732 0.1460 0.193 Uiso 1 1 calc R . .
H2B H 0.6460 1.2817 0.1610 0.193 Uiso 1 1 calc R . .
C3 C 0.5330(15) 1.1634(8) 0.1652(5) 0.174(6) Uani 1 1 d . . .
H3A H 0.4484 1.1381 0.1786 0.209 Uiso 1 1 calc R . .
H3B H 0.5939 1.1467 0.1969 0.209 Uiso 1 1 calc R . .
C4 C 0.5297(10) 1.1113(6) 0.0920(4) 0.108(3) Uani 1 1 d . . .
H4A H 0.4740 1.1298 0.0585 0.130 Uiso 1 1 calc R . .
H4B H 0.6160 1.1288 0.0794 0.130 Uiso 1 1 calc R . .
C5 C 0.3550(8) 0.9549(8) 0.0876(4) 0.099(3) Uani 1 1 d . . .
H5 H 0.2845 0.9777 0.0856 0.119 Uiso 1 1 calc R . .
C6 C 0.3517(8) 0.8653(7) 0.0894(4) 0.100(2) Uani 1 1 d . . .
H6 H 0.2791 0.8135 0.0894 0.120 Uiso 1 1 calc R . .
C7 C 0.5620(7) 0.9524(5) 0.0922(3) 0.0739(17) Uani 1 1 d . . .
C8 C 0.5120(7) 0.7743(5) 0.0858(4) 0.0811(19) Uani 1 1 d . . .
H8A H 0.5162 0.7522 0.0370 0.097 Uiso 1 1 calc R . .
H8B H 0.4437 0.7259 0.1002 0.097 Uiso 1 1 calc R . .
C9 C 0.6384(6) 0.7842(4) 0.1295(3) 0.0628(15) Uani 1 1 d . . .
C10 C 0.6447(6) 0.7895(4) 0.2006(3) 0.0655(15) Uani 1 1 d . . .
C11 C 0.7594(6) 0.7931(4) 0.2420(3) 0.0677(16) Uani 1 1 d . . .
C12 C 0.8676(6) 0.7941(4) 0.2094(3) 0.0646(15) Uani 1 1 d . . .
C13 C 0.8627(6) 0.7914(4) 0.1377(4) 0.0667(16) Uani 1 1 d . . .
C14 C 0.7455(7) 0.7848(4) 0.0966(3) 0.0660(16) Uani 1 1 d . . .
C15 C 0.7414(8) 0.7786(6) 0.0171(4) 0.092(2) Uani 1 1 d . . .
H15A H 0.7997 0.8363 0.0077 0.138 Uiso 1 1 d R . .
H15B H 0.6552 0.7712 -0.0043 0.138 Uiso 1 1 d R . .
H15C H 0.7665 0.7245 -0.0018 0.138 Uiso 1 1 d R . .
C16 C 0.5302(7) 0.7945(6) 0.2372(4) 0.091(2) Uani 1 1 d . . .
H16A H 0.4514 0.7576 0.2068 0.137 Uiso 1 1 d R . .
H16B H 0.5318 0.8601 0.2482 0.137 Uiso 1 1 d R . .
H16C H 0.5351 0.7690 0.2797 0.137 Uiso 1 1 d R . .
C17 C 0.7617(8) 0.7960(6) 0.3213(4) 0.097(2) Uani 1 1 d . . .
H17A H 0.7259 0.7322 0.3300 0.145 Uiso 1 1 calc R . .
H17B H 0.7115 0.8351 0.3386 0.145 Uiso 1 1 calc R . .
H17C H 0.8493 0.8226 0.3448 0.145 Uiso 1 1 calc R . .
C18 C 0.9821(7) 0.7959(6) 0.1043(4) 0.092(2) Uani 1 1 d . . .
H18A H 0.9594 0.7507 0.0609 0.138 Uiso 1 1 d R . .
H18B H 1.0436 0.7803 0.1355 0.138 Uiso 1 1 d R . .
H18C H 1.0195 0.8594 0.0952 0.138 Uiso 1 1 d R . .
C19 C 0.9928(6) 0.7983(5) 0.2541(4) 0.082(2) Uani 1 1 d . . .
H19A H 0.9748 0.7851 0.3000 0.099 Uiso 1 1 calc R . .
H19B H 1.0252 0.7488 0.2323 0.099 Uiso 1 1 calc R . .
C20 C 1.2227(7) 0.9024(5) 0.2681(4) 0.0806(19) Uani 1 1 d . . .
H20 H 1.2606 0.8537 0.2651 0.097 Uiso 1 1 calc R . .
C21 C 1.2834(7) 0.9961(6) 0.2788(4) 0.0808(19) Uani 1 1 d . . .
H21 H 1.3723 1.0252 0.2842 0.097 Uiso 1 1 calc R . .
C22 C 1.0719(6) 0.9785(4) 0.2698(3) 0.0684(16) Uani 1 1 d . . .
C23 C 1.2204(8) 1.1471(5) 0.2895(4) 0.092(2) Uani 1 1 d . . .
H23A H 1.2732 1.1709 0.2548 0.111 Uiso 1 1 calc R . .
H23B H 1.1394 1.1606 0.2802 0.111 Uiso 1 1 calc R . .
C24 C 1.2863(11) 1.1991(7) 0.3590(5) 0.128(3) Uani 1 1 d . . .
H24A H 1.3676 1.1856 0.3669 0.154 Uiso 1 1 calc R . .
H24B H 1.3074 1.2671 0.3576 0.154 Uiso 1 1 calc R . .
C25 C 1.2253(16) 1.1831(9) 0.4178(6) 0.184(6) Uani 1 1 d . . .
H25A H 1.2075 1.1158 0.4209 0.221 Uiso 1 1 calc R . .
H25B H 1.1426 1.1945 0.4097 0.221 Uiso 1 1 calc R . .
C26 C 1.2965(17) 1.2420(10) 0.4884(6) 0.207(7) Uani 1 1 d . . .
H26A H 1.3626 1.2164 0.5050 0.310 Uiso 1 1 calc R . .
H26B H 1.2367 1.2396 0.5214 0.310 Uiso 1 1 calc R . .
H26C H 1.3352 1.3073 0.4833 0.310 Uiso 1 1 calc R . .
C27 C 0.9475(7) 1.0530(5) 0.0992(4) 0.086(2) Uani 1 1 d D . .
C28 C 1.0680(8) 1.0694(5) 0.1046(4) 0.085(2) Uani 1 1 d D . .
C29 C 0.7507(10) 1.0503(6) 0.2771(6) 0.110(3) Uani 1 1 d D . .
C30 C 0.6590(11) 1.0699(7) 0.3051(5) 0.116(4) Uani 1 1 d D . .
C31 C -0.1109(8) 0.3485(6) 0.0394(4) 0.092(2) Uani 1 1 d . . .
H31 H -0.1340 0.3416 -0.0088 0.111 Uiso 1 1 calc R . .
C32 C -0.0771(8) 0.2853(5) 0.0732(4) 0.087(2) Uani 1 1 d . . .
H32 H -0.0727 0.2256 0.0534 0.105 Uiso 1 1 calc R . .
C33 C -0.0684(6) 0.4135(4) 0.1545(4) 0.0717(17) Uani 1 1 d . . .
C34 C -0.0067(9) 0.2769(5) 0.1972(4) 0.099(2) Uani 1 1 d . . .
H34A H 0.0360 0.2337 0.1757 0.119 Uiso 1 1 calc R . .
H34B H -0.0815 0.2386 0.2142 0.119 Uiso 1 1 calc R . .
C35 C 0.0861(8) 0.3467(4) 0.2591(4) 0.0749(18) Uani 1 1 d . . .
C36 C 0.0432(7) 0.3567(5) 0.3241(4) 0.0785(19) Uani 1 1 d . . .
C37 C 0.1285(8) 0.4155(5) 0.3826(4) 0.084(2) Uani 1 1 d . . .
C38 C 0.2544(8) 0.4638(5) 0.3741(4) 0.082(2) Uani 1 1 d . . .
C39 C 0.2966(7) 0.4572(5) 0.3085(4) 0.084(2) Uani 1 1 d . . .
C40 C 0.2100(8) 0.3949(5) 0.2502(4) 0.0786(18) Uani 1 1 d . . .
C41 C 0.2514(9) 0.3834(7) 0.1798(5) 0.119(3) Uani 1 1 d . . .
H41A H 0.2095 0.3190 0.1552 0.178 Uiso 1 1 calc R . .
H41B H 0.3434 0.3964 0.1853 0.178 Uiso 1 1 calc R . .
H41C H 0.2279 0.4275 0.1534 0.178 Uiso 1 1 calc R . .
C42 C -0.0948(9) 0.3082(7) 0.3347(5) 0.125(3) Uani 1 1 d . . .
H42A H -0.0952 0.2621 0.3648 0.187 Uiso 1 1 calc R . .
H42B H -0.1462 0.2763 0.2901 0.187 Uiso 1 1 calc R . .
H42C H -0.1300 0.3555 0.3559 0.187 Uiso 1 1 calc R . .
C43 C 0.0839(11) 0.4271(7) 0.4529(4) 0.125(3) Uani 1 1 d . . .
H43A H 0.1574 0.4481 0.4894 0.188 Uiso 1 1 calc R . .
H43B H 0.0270 0.3668 0.4590 0.188 Uiso 1 1 calc R . .
H43C H 0.0388 0.4739 0.4551 0.188 Uiso 1 1 calc R . .
C44 C 0.4310(8) 0.5154(7) 0.2991(6) 0.126(3) Uani 1 1 d . . .
H44A H 0.4624 0.5715 0.3352 0.189 Uiso 1 1 calc R . .
H44B H 0.4278 0.5342 0.2539 0.189 Uiso 1 1 calc R . .
H44C H 0.4879 0.4772 0.3023 0.189 Uiso 1 1 calc R . .
C45 C 0.3508(9) 0.5215(6) 0.4385(5) 0.113(3) Uani 1 1 d . . .
H45A H 0.3463 0.4827 0.4749 0.135 Uiso 1 1 calc R . .
H45B H 0.4373 0.5361 0.4264 0.135 Uiso 1 1 calc R . .
C46 C 0.3561(11) 0.6509(8) 0.5374(5) 0.131(4) Uani 1 1 d . . .
H46 H 0.3866 0.6237 0.5730 0.158 Uiso 1 1 calc R A .
C47 C 0.3319(11) 0.7337(7) 0.5442(6) 0.136(4) Uani 1 1 d D A .
H47 H 0.3408 0.7765 0.5856 0.163 Uiso 1 1 calc R . .
C48 C 0.2860(9) 0.6699(6) 0.4297(5) 0.101(2) Uani 1 1 d D A .
C49 C 0.2637(14) 0.8318(10) 0.4643(9) 0.185(5) Uiso 0.688(11) 1 d PDU A 1
C50 C 0.1245(14) 0.8235(11) 0.4771(11) 0.189(6) Uiso 0.688(11) 1 d PDU A 1
C51 C 0.093(2) 0.9138(15) 0.4629(10) 0.225(8) Uiso 0.688(11) 1 d PDU A 1
C52 C 0.084(3) 0.9747(17) 0.5319(14) 0.269(11) Uiso 0.688(11) 1 d PDU A 1
C53 C -0.3906(17) 0.5212(12) 0.1275(9) 0.222(6) Uani 1 1 d U . .
H53A H -0.3873 0.4939 0.1693 0.333 Uiso 1 1 calc R . .
H53B H -0.4734 0.5302 0.1172 0.333 Uiso 1 1 calc R . .
H53C H -0.3240 0.5820 0.1345 0.333 Uiso 1 1 calc R . .
C54 C -0.3710(15) 0.4569(11) 0.0690(9) 0.184(4) Uani 1 1 d U . .
H54A H -0.3620 0.3996 0.0847 0.221 Uiso 1 1 calc R . .
H54B H -0.4454 0.4379 0.0324 0.221 Uiso 1 1 calc R . .
C55 C -0.2615(12) 0.5020(9) 0.0427(7) 0.155(3) Uani 1 1 d U . .
H55A H -0.2642 0.5663 0.0402 0.186 Uiso 1 1 calc R . .
H55B H -0.2720 0.4694 -0.0054 0.186 Uiso 1 1 calc R . .
C57 C 0.1901(8) 0.6448(6) 0.2199(5) 0.087(2) Uani 1 1 d U . .
C56 C -0.1289(8) 0.5126(6) 0.0744(5) 0.102(2) Uani 1 1 d U . .
H56A H -0.0705 0.5393 0.0429 0.122 Uiso 1 1 calc R . .
H56B H -0.1075 0.5588 0.1178 0.122 Uiso 1 1 calc R . .
C58 C 0.1966(9) 0.6374(7) 0.1679(7) 0.095(2) Uani 1 1 d U . .
C59 C -0.0858(10) 0.5845(7) 0.3376(5) 0.105(3) Uani 1 1 d U . .
C60 C -0.1700(15) 0.5731(8) 0.3618(7) 0.130(3) Uani 1 1 d U . .
C49' C 0.242(2) 0.8236(12) 0.4655(13) 0.186(7) Uiso 0.312(11) 1 d PDU A 2
C50' C 0.357(4) 0.9111(14) 0.461(2) 0.198(8) Uiso 0.312(11) 1 d PDU A 2
C51' C 0.332(5) 1.0037(13) 0.493(3) 0.226(11) Uiso 0.312(11) 1 d PDU A 2
C52' C 0.202(5) 0.978(3) 0.522(3) 0.238(12) Uiso 0.312(11) 1 d PDU A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C27 Ag1 C7 173.0(3) . . ?
C29 Ag2 C22 173.6(3) . . ?
C33 Ag3 C59 170.9(3) . . ?
C33 Ag3 Ag4 115.96(18) . . ?
C59 Ag3 Ag4 72.8(3) . . ?
C57 Ag4 C48 171.8(3) . . ?
C57 Ag4 Ag3 66.6(2) . . ?
C48 Ag4 Ag3 120.9(2) . . ?
C7 N1 C5 111.4(7) . . ?
C7 N1 C4 122.8(7) . . ?
C5 N1 C4 125.7(7) . . ?
C7 N2 C6 112.0(7) . . ?
C7 N2 C8 125.7(6) . . ?
C6 N2 C8 122.1(7) . . ?
C22 N3 C20 110.7(5) . . ?
C22 N3 C19 125.8(5) . . ?
C20 N3 C19 123.4(6) . . ?
C21 N4 C22 111.6(6) . . ?
C21 N4 C23 125.0(6) . . ?
C22 N4 C23 123.3(6) . . ?
C48 N7 C46 112.6(8) . . ?
C48 N7 C45 126.4(7) . . ?
C46 N7 C45 120.8(8) . . ?
C48 N8 C47 114.2(8) . . ?
C48 N8 C49' 123.7(11) . . ?
C47 N8 C49' 121.6(11) . . ?
C48 N8 C49 124.0(10) . . ?
C47 N8 C49 121.7(9) . . ?
C49' N8 C49 9.1(12) . . ?
C33 N9 C31 111.4(6) . . ?
C33 N9 C56 123.6(6) . . ?
C31 N9 C56 125.0(7) . . ?
C33 N10 C32 111.5(6) . . ?
C33 N10 C34 127.5(6) . . ?
C32 N10 C34 121.0(6) . . ?
C2 C1 H1A 109.5 . . ?
C2 C1 H1B 109.5 . . ?
H1A C1 H1B 109.5 . . ?
C2 C1 H1C 109.5 . . ?
H1A C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
C3 C2 C1 118.3(12) . . ?
C3 C2 H2A 107.7 . . ?
C1 C2 H2A 107.7 . . ?
C3 C2 H2B 107.7 . . ?
C1 C2 H2B 107.7 . . ?
H2A C2 H2B 107.1 . . ?
C2 C3 C4 118.6(11) . . ?
C2 C3 H3A 107.7 . . ?
C4 C3 H3A 107.7 . . ?
C2 C3 H3B 107.7 . . ?
C4 C3 H3B 107.7 . . ?
H3A C3 H3B 107.1 . . ?
N1 C4 C3 109.9(8) . . ?
N1 C4 H4A 109.7 . . ?
C3 C4 H4A 109.7 . . ?
N1 C4 H4B 109.7 . . ?
C3 C4 H4B 109.7 . . ?
H4A C4 H4B 108.2 . . ?
C6 C5 N1 107.6(7) . . ?
C6 C5 H5 126.2 . . ?
N1 C5 H5 126.2 . . ?
C5 C6 N2 106.2(8) . . ?
C5 C6 H6 126.9 . . ?
N2 C6 H6 126.9 . . ?
N2 C7 N1 102.8(6) . . ?
N2 C7 Ag1 130.5(5) . . ?
N1 C7 Ag1 126.8(5) . . ?
N2 C8 C9 113.6(5) . . ?
N2 C8 H8A 108.8 . . ?
C9 C8 H8A 108.9 . . ?
N2 C8 H8B 108.9 . . ?
C9 C8 H8B 108.9 . . ?
H8A C8 H8B 107.7 . . ?
C10 C9 C14 121.3(6) . . ?
C10 C9 C8 119.4(6) . . ?
C14 C9 C8 119.3(6) . . ?
C9 C10 C11 120.4(6) . . ?
C9 C10 C16 121.4(6) . . ?
C11 C10 C16 118.2(6) . . ?
C12 C11 C10 118.7(6) . . ?
C12 C11 C17 122.4(6) . . ?
C10 C11 C17 118.9(6) . . ?
C13 C12 C11 121.1(6) . . ?
C13 C12 C19 119.9(6) . . ?
C11 C12 C19 119.0(6) . . ?
C12 C13 C14 119.4(6) . . ?
C12 C13 C18 120.0(6) . . ?
C14 C13 C18 120.6(6) . . ?
C9 C14 C13 119.1(6) . . ?
C9 C14 C15 122.5(6) . . ?
C13 C14 C15 118.4(6) . . ?
C14 C15 H15A 109.5 . . ?
C14 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C14 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C10 C16 H16A 109.5 . . ?
C10 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C10 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C11 C17 H17A 109.5 . . ?
C11 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C11 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C13 C18 H18A 109.5 . . ?
C13 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C13 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
N3 C19 C12 112.6(5) . . ?
N3 C19 H19A 109.1 . . ?
C12 C19 H19A 109.1 . . ?
N3 C19 H19B 109.1 . . ?
C12 C19 H19B 109.1 . . ?
H19A C19 H19B 107.8 . . ?
C21 C20 N3 106.6(7) . . ?
C21 C20 H20 126.7 . . ?
N3 C20 H20 126.7 . . ?
C20 C21 N4 107.8(6) . . ?
C20 C21 H21 126.1 . . ?
N4 C21 H21 126.1 . . ?
N4 C22 N3 103.3(6) . . ?
N4 C22 Ag2 127.0(5) . . ?
N3 C22 Ag2 129.6(5) . . ?
C24 C23 N4 114.3(7) . . ?
C24 C23 H23A 108.7 . . ?
N4 C23 H23A 108.7 . . ?
C24 C23 H23B 108.7 . . ?
N4 C23 H23B 108.7 . . ?
H23A C23 H23B 107.6 . . ?
C25 C24 C23 119.8(10) . . ?
C25 C24 H24A 107.4 . . ?
C23 C24 H24A 107.4 . . ?
C25 C24 H24B 107.4 . . ?
C23 C24 H24B 107.4 . . ?
H24A C24 H24B 106.9 . . ?
C24 C25 C26 117.4(13) . . ?
C24 C25 H25A 108.0 . . ?
C26 C25 H25A 108.0 . . ?
C24 C25 H25B 108.0 . . ?
C26 C25 H25B 108.0 . . ?
H25A C25 H25B 107.2 . . ?
C25 C26 H26A 109.5 . . ?
C25 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
C25 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
C28 C27 Ag1 165.7(6) . . ?
N5 C28 C27 178.2(10) . . ?
C30 C29 Ag2 158.9(10) . . ?
N6 C30 C29 169.1(18) . . ?
C32 C31 N9 107.3(7) . . ?
C32 C31 H31 126.4 . . ?
N9 C31 H31 126.4 . . ?
C31 C32 N10 106.0(7) . . ?
C31 C32 H32 127.0 . . ?
N10 C32 H32 127.0 . . ?
N9 C33 N10 103.8(6) . . ?
N9 C33 Ag3 127.0(5) . . ?
N10 C33 Ag3 128.9(5) . . ?
N10 C34 C35 112.2(6) . . ?
N10 C34 H34A 109.2 . . ?
C35 C34 H34A 109.2 . . ?
N10 C34 H34B 109.2 . . ?
C35 C34 H34B 109.2 . . ?
H34A C34 H34B 107.9 . . ?
C40 C35 C36 122.0(6) . . ?
C40 C35 C34 119.6(7) . . ?
C36 C35 C34 118.4(7) . . ?
C37 C36 C35 119.5(7) . . ?
C37 C36 C42 117.3(7) . . ?
C35 C36 C42 123.1(7) . . ?
C38 C37 C36 118.8(7) . . ?
C38 C37 C43 121.0(8) . . ?
C36 C37 C43 120.2(8) . . ?
C37 C38 C39 122.0(7) . . ?
C37 C38 C45 119.0(8) . . ?
C39 C38 C45 118.9(8) . . ?
C38 C39 C40 118.4(7) . . ?
C38 C39 C44 121.5(8) . . ?
C40 C39 C44 120.1(8) . . ?
C35 C40 C39 119.2(7) . . ?
C35 C40 C41 120.3(7) . . ?
C39 C40 C41 120.5(8) . . ?
C40 C41 H41A 109.5 . . ?
C40 C41 H41B 109.5 . . ?
H41A C41 H41B 109.5 . . ?
C40 C41 H41C 109.5 . . ?
H41A C41 H41C 109.5 . . ?
H41B C41 H41C 109.5 . . ?
C36 C42 H42A 109.5 . . ?
C36 C42 H42B 109.5 . . ?
H42A C42 H42B 109.5 . . ?
C36 C42 H42C 109.5 . . ?
H42A C42 H42C 109.5 . . ?
H42B C42 H42C 109.5 . . ?
C37 C43 H43A 109.5 . . ?
C37 C43 H43B 109.5 . . ?
H43A C43 H43B 109.5 . . ?
C37 C43 H43C 109.5 . . ?
H43A C43 H43C 109.5 . . ?
H43B C43 H43C 109.5 . . ?
C39 C44 H44A 109.5 . . ?
C39 C44 H44B 109.5 . . ?
H44A C44 H44B 109.5 . . ?
C39 C44 H44C 109.5 . . ?
H44A C44 H44C 109.5 . . ?
H44B C44 H44C 109.5 . . ?
N7 C45 C38 113.0(6) . . ?
N7 C45 H45A 109.0 . . ?
C38 C45 H45A 109.0 . . ?
N7 C45 H45B 109.0 . . ?
C38 C45 H45B 109.0 . . ?
H45A C45 H45B 107.8 . . ?
C47 C46 N7 105.6(10) . . ?
C47 C46 H46 127.2 . . ?
N7 C46 H46 127.2 . . ?
C46 C47 N8 105.6(9) . . ?
C46 C47 H47 127.2 . . ?
N8 C47 H47 127.2 . . ?
N7 C48 N8 101.9(8) . . ?
N7 C48 Ag4 128.6(6) . . ?
N8 C48 Ag4 129.6(7) . . ?
N8 C49 C50 108.3(9) . . ?
C51 C50 C49 109.6(9) . . ?
C50 C51 C52 110.5(10) . . ?
C54 C53 H53A 109.5 . . ?
C54 C53 H53B 109.5 . . ?
H53A C53 H53B 109.5 . . ?
C54 C53 H53C 109.5 . . ?
H53A C53 H53C 109.5 . . ?
H53B C53 H53C 109.5 . . ?
C55 C54 C53 110.1(14) . . ?
C55 C54 H54A 109.6 . . ?
C53 C54 H54A 109.6 . . ?
C55 C54 H54B 109.6 . . ?
C53 C54 H54B 109.6 . . ?
H54A C54 H54B 108.2 . . ?
C54 C55 C56 124.3(12) . . ?
C54 C55 H55A 106.2 . . ?
C56 C55 H55A 106.2 . . ?
C54 C55 H55B 106.2 . . ?
C56 C55 H55B 106.2 . . ?
H55A C55 H55B 106.4 . . ?
C58 C57 Ag4 162.0(10) . . ?
N9 C56 C55 116.1(8) . . ?
N9 C56 H56A 108.3 . . ?
C55 C56 H56A 108.3 . . ?
N9 C56 H56B 108.3 . . ?
C55 C56 H56B 108.3 . . ?
H56A C56 H56B 107.4 . . ?
N11 C58 C57 175.6(16) . . ?
C60 C59 Ag3 126.8(11) . . ?
C59 C60 N12 178.5(17) . . ?
N8 C49' C50' 108.9(10) . . ?
C51' C50' C49' 109.4(9) . . ?
C50' C51' C52' 109.5(10) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 C27 1.975(7) . ?
Ag1 C7 2.058(7) . ?
Ag2 C29 1.913(10) . ?
Ag2 C22 2.066(7) . ?
Ag3 C33 2.068(7) . ?
Ag3 C59 2.072(10) . ?
Ag3 Ag4 3.3041(9) . ?
Ag4 C57 1.970(9) . ?
Ag4 C48 2.086(9) . ?
N1 C7 1.372(8) . ?
N1 C5 1.377(10) . ?
N1 C4 1.456(10) . ?
N2 C7 1.353(8) . ?
N2 C6 1.393(9) . ?
N2 C8 1.473(9) . ?
N3 C22 1.365(8) . ?
N3 C20 1.378(8) . ?
N3 C19 1.462(8) . ?
N4 C21 1.350(9) . ?
N4 C22 1.356(8) . ?
N4 C23 1.486(9) . ?
N5 C28 1.071(9) . ?
N6 C30 1.092(5) . ?
N7 C48 1.321(10) . ?
N7 C46 1.372(11) . ?
N7 C45 1.505(10) . ?
N8 C48 1.324(10) . ?
N8 C47 1.341(12) . ?
N8 C49' 1.491(9) . ?
N8 C49 1.493(8) . ?
N9 C33 1.346(8) . ?
N9 C31 1.380(9) . ?
N9 C56 1.442(9) . ?
N10 C33 1.353(8) . ?
N10 C32 1.389(8) . ?
N10 C34 1.469(9) . ?
N11 C58 1.012(12) . ?
N12 C60 1.351(16) . ?
C1 C2 1.499(13) . ?
C1 H1A 0.9600 . ?
C1 H1B 0.9600 . ?
C1 H1C 0.9600 . ?
C2 C3 1.303(14) . ?
C2 H2A 0.9700 . ?
C2 H2B 0.9700 . ?
C3 C4 1.513(12) . ?
C3 H3A 0.9700 . ?
C3 H3B 0.9700 . ?
C4 H4A 0.9700 . ?
C4 H4B 0.9700 . ?
C5 C6 1.323(12) . ?
C5 H5 0.9300 . ?
C6 H6 0.9300 . ?
C8 C9 1.505(9) . ?
C8 H8A 0.9700 . ?
C8 H8B 0.9700 . ?
C9 C10 1.368(9) . ?
C9 C14 1.392(9) . ?
C10 C11 1.403(9) . ?
C10 C16 1.520(9) . ?
C11 C12 1.397(9) . ?
C11 C17 1.536(9) . ?
C12 C13 1.386(9) . ?
C12 C19 1.526(9) . ?
C13 C14 1.410(9) . ?
C13 C18 1.508(9) . ?
C14 C15 1.531(9) . ?
C15 H15A 0.9600 . ?
C15 H15B 0.9600 . ?
C15 H15C 0.9600 . ?
C16 H16A 0.9600 . ?
C16 H16B 0.9600 . ?
C16 H16C 0.9600 . ?
C17 H17A 0.9600 . ?
C17 H17B 0.9600 . ?
C17 H17C 0.9600 . ?
C18 H18A 0.9600 . ?
C18 H18B 0.9600 . ?
C18 H18C 0.9600 . ?
C19 H19A 0.9700 . ?
C19 H19B 0.9700 . ?
C20 C21 1.328(10) . ?
C20 H20 0.9300 . ?
C21 H21 0.9300 . ?
C23 C24 1.458(11) . ?
C23 H23A 0.9700 . ?
C23 H23B 0.9700 . ?
C24 C25 1.397(15) . ?
C24 H24A 0.9700 . ?
C24 H24B 0.9700 . ?
C25 C26 1.517(16) . ?
C25 H25A 0.9700 . ?
C25 H25B 0.9700 . ?
C26 H26A 0.9600 . ?
C26 H26B 0.9600 . ?
C26 H26C 0.9600 . ?
C27 C28 1.259(5) . ?
C29 C30 1.276(5) . ?
C31 C32 1.332(10) . ?
C31 H31 0.9300 . ?
C32 H32 0.9300 . ?
C34 C35 1.528(10) . ?
C34 H34A 0.9700 . ?
C34 H34B 0.9700 . ?
C35 C40 1.378(10) . ?
C35 C36 1.399(10) . ?
C36 C37 1.397(10) . ?
C36 C42 1.520(11) . ?
C37 C38 1.393(11) . ?
C37 C43 1.504(11) . ?
C38 C39 1.403(10) . ?
C38 C45 1.521(10) . ?
C39 C40 1.417(10) . ?
C39 C44 1.517(11) . ?
C40 C41 1.490(10) . ?
C41 H41A 0.9600 . ?
C41 H41B 0.9600 . ?
C41 H41C 0.9600 . ?
C42 H42A 0.9600 . ?
C42 H42B 0.9600 . ?
C42 H42C 0.9600 . ?
C43 H43A 0.9600 . ?
C43 H43B 0.9600 . ?
C43 H43C 0.9600 . ?
C44 H44A 0.9600 . ?
C44 H44B 0.9600 . ?
C44 H44C 0.9600 . ?
C45 H45A 0.9700 . ?
C45 H45B 0.9700 . ?
C46 C47 1.321(14) . ?
C46 H46 0.9300 . ?
C47 H47 0.9300 . ?
C49 C50 1.543(10) . ?
C50 C51 1.531(10) . ?
C51 C52 1.536(10) . ?
C53 C54 1.453(18) . ?
C53 H53A 0.9600 . ?
C53 H53B 0.9600 . ?
C53 H53C 0.9600 . ?
C54 C55 1.378(16) . ?
C54 H54A 0.9700 . ?
C54 H54B 0.9700 . ?
C55 C56 1.471(13) . ?
C55 H55A 0.9700 . ?
C55 H55B 0.9700 . ?
C57 C58 1.015(11) . ?
C56 H56A 0.9700 . ?
C56 H56B 0.9700 . ?
C59 C60 1.060(15) . ?
C49' C50' 1.545(10) . ?
C50' C51' 1.540(10) . ?
C51' C52' 1.545(10) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C33 Ag3 Ag4 C57 45.3(3) . . . . ?
C59 Ag3 Ag4 C57 -131.9(4) . . . . ?
C33 Ag3 Ag4 C48 -138.3(3) . . . . ?
C59 Ag3 Ag4 C48 44.5(4) . . . . ?
C1 C2 C3 C4 -177.6(10) . . . . ?
C7 N1 C4 C3 -100.6(9) . . . . ?
C5 N1 C4 C3 75.5(10) . . . . ?
C2 C3 C4 N1 -174.4(12) . . . . ?
C7 N1 C5 C6 0.0(9) . . . . ?
C4 N1 C5 C6 -176.5(7) . . . . ?
N1 C5 C6 N2 -0.7(9) . . . . ?
C7 N2 C6 C5 1.3(9) . . . . ?
C8 N2 C6 C5 -173.1(7) . . . . ?
C6 N2 C7 N1 -1.2(7) . . . . ?
C8 N2 C7 N1 172.9(6) . . . . ?
C6 N2 C7 Ag1 176.8(5) . . . . ?
C8 N2 C7 Ag1 -9.1(10) . . . . ?
C5 N1 C7 N2 0.7(7) . . . . ?
C4 N1 C7 N2 177.4(6) . . . . ?
C5 N1 C7 Ag1 -177.4(5) . . . . ?
C4 N1 C7 Ag1 -0.7(9) . . . . ?
C27 Ag1 C7 N2 147(2) . . . . ?
C27 Ag1 C7 N1 -36(3) . . . . ?
C7 N2 C8 C9 41.6(9) . . . . ?
C6 N2 C8 C9 -144.8(7) . . . . ?
N2 C8 C9 C10 75.8(8) . . . . ?
N2 C8 C9 C14 -106.1(7) . . . . ?
C14 C9 C10 C11 -1.8(9) . . . . ?
C8 C9 C10 C11 176.3(5) . . . . ?
C14 C9 C10 C16 176.5(6) . . . . ?
C8 C9 C10 C16 -5.5(9) . . . . ?
C9 C10 C11 C12 1.9(9) . . . . ?
C16 C10 C11 C12 -176.4(6) . . . . ?
C9 C10 C11 C17 -178.2(6) . . . . ?
C16 C10 C11 C17 3.5(9) . . . . ?
C10 C11 C12 C13 -0.1(9) . . . . ?
C17 C11 C12 C13 -180.0(6) . . . . ?
C10 C11 C12 C19 179.9(5) . . . . ?
C17 C11 C12 C19 0.0(9) . . . . ?
C11 C12 C13 C14 -1.8(8) . . . . ?
C19 C12 C13 C14 178.2(5) . . . . ?
C11 C12 C13 C18 178.0(6) . . . . ?
C19 C12 C13 C18 -2.0(8) . . . . ?
C10 C9 C14 C13 -0.2(8) . . . . ?
C8 C9 C14 C13 -178.3(5) . . . . ?
C10 C9 C14 C15 179.8(6) . . . . ?
C8 C9 C14 C15 1.7(9) . . . . ?
C12 C13 C14 C9 2.0(8) . . . . ?
C18 C13 C14 C9 -177.8(5) . . . . ?
C12 C13 C14 C15 -178.0(5) . . . . ?
C18 C13 C14 C15 2.2(8) . . . . ?
C22 N3 C19 C12 36.9(9) . . . . ?
C20 N3 C19 C12 -147.1(6) . . . . ?
C13 C12 C19 N3 71.6(8) . . . . ?
C11 C12 C19 N3 -108.3(7) . . . . ?
C22 N3 C20 C21 -0.2(8) . . . . ?
C19 N3 C20 C21 -176.7(6) . . . . ?
N3 C20 C21 N4 0.6(8) . . . . ?
C22 N4 C21 C20 -0.8(8) . . . . ?
C23 N4 C21 C20 -178.5(6) . . . . ?
C21 N4 C22 N3 0.7(7) . . . . ?
C23 N4 C22 N3 178.4(6) . . . . ?
C21 N4 C22 Ag2 179.1(5) . . . . ?
C23 N4 C22 Ag2 -3.2(9) . . . . ?
C20 N3 C22 N4 -0.3(7) . . . . ?
C19 N3 C22 N4 176.2(6) . . . . ?
C20 N3 C22 Ag2 -178.7(5) . . . . ?
C19 N3 C22 Ag2 -2.2(9) . . . . ?
C29 Ag2 C22 N4 -48(3) . . . . ?
C29 Ag2 C22 N3 130(3) . . . . ?
C21 N4 C23 C24 -68.8(10) . . . . ?
C22 N4 C23 C24 113.9(9) . . . . ?
N4 C23 C24 C25 -63.3(14) . . . . ?
C23 C24 C25 C26 -177.8(11) . . . . ?
C7 Ag1 C27 C28 -164(2) . . . . ?
Ag1 C27 C28 N5 -144(30) . . . . ?
C22 Ag2 C29 C30 -50(5) . . . . ?
Ag2 C29 C30 N6 -3(10) . . . . ?
C33 N9 C31 C32 -0.1(9) . . . . ?
C56 N9 C31 C32 177.0(7) . . . . ?
N9 C31 C32 N10 -0.7(9) . . . . ?
C33 N10 C32 C31 1.2(9) . . . . ?
C34 N10 C32 C31 -179.1(7) . . . . ?
C31 N9 C33 N10 0.8(8) . . . . ?
C56 N9 C33 N10 -176.3(6) . . . . ?
C31 N9 C33 Ag3 -173.7(5) . . . . ?
C56 N9 C33 Ag3 9.2(9) . . . . ?
C32 N10 C33 N9 -1.2(8) . . . . ?
C34 N10 C33 N9 179.1(7) . . . . ?
C32 N10 C33 Ag3 173.1(5) . . . . ?
C34 N10 C33 Ag3 -6.5(11) . . . . ?
C59 Ag3 C33 N9 62(2) . . . . ?
Ag4 Ag3 C33 N9 -100.8(6) . . . . ?
C59 Ag3 C33 N10 -111(2) . . . . ?
Ag4 Ag3 C33 N10 86.1(6) . . . . ?
C33 N10 C34 C35 -32.5(11) . . . . ?
C32 N10 C34 C35 147.8(7) . . . . ?
N10 C34 C35 C40 -71.8(9) . . . . ?
N10 C34 C35 C36 110.6(8) . . . . ?
C40 C35 C36 C37 -1.5(10) . . . . ?
C34 C35 C36 C37 176.1(6) . . . . ?
C40 C35 C36 C42 177.0(7) . . . . ?
C34 C35 C36 C42 -5.5(10) . . . . ?
C35 C36 C37 C38 0.8(10) . . . . ?
C42 C36 C37 C38 -177.7(7) . . . . ?
C35 C36 C37 C43 180.0(7) . . . . ?
C42 C36 C37 C43 1.4(11) . . . . ?
C36 C37 C38 C39 1.9(10) . . . . ?
C43 C37 C38 C39 -177.3(7) . . . . ?
C36 C37 C38 C45 -175.1(6) . . . . ?
C43 C37 C38 C45 5.7(11) . . . . ?
C37 C38 C39 C40 -3.9(10) . . . . ?
C45 C38 C39 C40 173.1(6) . . . . ?
C37 C38 C39 C44 175.8(7) . . . . ?
C45 C38 C39 C44 -7.2(10) . . . . ?
C36 C35 C40 C39 -0.5(10) . . . . ?
C34 C35 C40 C39 -178.1(6) . . . . ?
C36 C35 C40 C41 -179.0(7) . . . . ?
C34 C35 C40 C41 3.4(10) . . . . ?
C38 C39 C40 C35 3.1(10) . . . . ?
C44 C39 C40 C35 -176.5(7) . . . . ?
C38 C39 C40 C41 -178.4(7) . . . . ?
C44 C39 C40 C41 2.0(11) . . . . ?
C48 N7 C45 C38 -36.1(14) . . . . ?
C46 N7 C45 C38 148.5(9) . . . . ?
C37 C38 C45 N7 -73.7(10) . . . . ?
C39 C38 C45 N7 109.2(9) . . . . ?
C48 N7 C46 C47 0.2(13) . . . . ?
C45 N7 C46 C47 176.2(10) . . . . ?
N7 C46 C47 N8 -0.8(13) . . . . ?
C48 N8 C47 C46 1.2(14) . . . . ?
C49' N8 C47 C46 173.7(14) . . . . ?
C49 N8 C47 C46 -175.6(10) . . . . ?
C46 N7 C48 N8 0.5(11) . . . . ?
C45 N7 C48 N8 -175.2(9) . . . . ?
C46 N7 C48 Ag4 -179.3(7) . . . . ?
C45 N7 C48 Ag4 5.0(14) . . . . ?
C47 N8 C48 N7 -1.1(12) . . . . ?
C49' N8 C48 N7 -173.4(13) . . . . ?
C49 N8 C48 N7 175.6(9) . . . . ?
C47 N8 C48 Ag4 178.7(8) . . . . ?
C49' N8 C48 Ag4 6.4(17) . . . . ?
C49 N8 C48 Ag4 -4.5(15) . . . . ?
C57 Ag4 C48 N7 -126(2) . . . . ?
Ag3 Ag4 C48 N7 77.6(9) . . . . ?
C57 Ag4 C48 N8 54(3) . . . . ?
Ag3 Ag4 C48 N8 -102.1(9) . . . . ?
C48 N8 C49 C50 99.5(15) . . . . ?
C47 N8 C49 C50 -84.0(16) . . . . ?
C49' N8 C49 C50 8(7) . . . . ?
N8 C49 C50 C51 179.7(13) . . . . ?
C49 C50 C51 C52 -109(2) . . . . ?
C53 C54 C55 C56 79.8(18) . . . . ?
C48 Ag4 C57 C58 79(4) . . . . ?
Ag3 Ag4 C57 C58 -123(3) . . . . ?
C33 N9 C56 C55 -117.7(10) . . . . ?
C31 N9 C56 C55 65.6(11) . . . . ?
C54 C55 C56 N9 50.9(17) . . . . ?
Ag4 C57 C58 N11 39(20) . . . . ?
C33 Ag3 C59 C60 28(3) . . . . ?
Ag4 Ag3 C59 C60 -167.9(13) . . . . ?
Ag3 C59 C60 N12 172(100) . . . . ?
C48 N8 C49' C50' -101(2) . . . . ?
C47 N8 C49' C50' 87(3) . . . . ?
C49 N8 C49' C50' -6(7) . . . . ?
N8 C49' C50' C51' -145(3) . . . . ?
C49' C50' C51' C52' 3(6) . . . . ?
