#------------------------------------------------------------------------------
#$Date: 2016-03-26 16:32:41 +0100 (Sat 26 de Mar de 2016) $
#$Revision: 180399 $
#$URL: svn://www.crystallography.net/cod/cif/7/20/68/7206820.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7206820
loop_
_publ_author_name
'Zhang, Man-Bo'
'Chen, Hao-Min'
'Hu, Rui-Xiang'
'Chen, Zi-Lu'
_publ_section_title
;
 Heterometallic coordination polymers containing unique inorganic chain of
 [Lniii2Cuii3(OH)4]: syntheses, structures and magnetism
;
_journal_issue                   23
_journal_name_full               CrystEngComm
_journal_page_first              7019
_journal_paper_doi               10.1039/c1ce05825h
_journal_volume                  13
_journal_year                    2011
_chemical_formula_sum            'C384 H288 Cu12 Eu8 N32 O88'
_chemical_formula_weight         8736.74
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 120.124(6)
_cell_angle_gamma                90.00
_cell_formula_units_Z            1
_cell_length_a                   15.2175(19)
_cell_length_b                   29.825(3)
_cell_length_c                   21.3743(18)
_cell_measurement_reflns_used    21802
_cell_measurement_temperature    133(2)
_cell_measurement_theta_max      27.4918
_cell_measurement_theta_min      3.0091
_cell_volume                     8390.8(16)
_computing_cell_refinement       'Bruker XSCANS'
_computing_data_collection       'Bruker XSCANS'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      133(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Rotating Anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0478
_diffrn_reflns_av_sigmaI/netI    0.0454
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       38
_diffrn_reflns_limit_k_min       -38
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            75304
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_reflns_theta_min         3.01
_diffrn_standards_decay_%        none
_diffrn_standards_interval_count none
_diffrn_standards_interval_time  none
_diffrn_standards_number         none
_exptl_absorpt_coefficient_mu    2.305
_exptl_absorpt_correction_T_max  0.5964
_exptl_absorpt_correction_T_min  0.5258
_exptl_absorpt_correction_type   empirical
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.729
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             4371
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.32
_exptl_crystal_size_min          0.25
_refine_diff_density_max         1.358
_refine_diff_density_min         -0.762
_refine_diff_density_rms         0.125
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.111
_refine_ls_hydrogen_treatment    none
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1231
_refine_ls_number_reflns         19194
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.111
_refine_ls_R_factor_all          0.0589
_refine_ls_R_factor_gt           0.0484
_refine_ls_shift/su_max          0.008
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0303P)²+15.5025P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0913
_refine_ls_wR_factor_ref         0.0962
_reflns_number_gt                16582
_reflns_number_total             19194
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c1ce05825h.txt
_cod_data_source_block           Eu4
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_cell_volume        8390.8(15)
_cod_original_sg_symbol_H-M      P21/c
_cod_database_code               7206820
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.377293(14) -0.535999(6) 0.939319(10) 0.01054(5) Uani 1 1 d .
Eu2 Eu 0.132741(13) -0.468569(6) 0.560003(10) 0.00999(5) Uani 1 1 d .
Cu1 Cu 0.47132(3) -0.458909(16) 0.86499(2) 0.01203(10) Uani 1 1 d .
Cu2 Cu 0.24666(3) -0.497507(15) 0.75453(2) 0.01228(10) Uani 1 1 d .
Cu3 Cu 0.01838(3) -0.535763(15) 0.63458(2) 0.01141(10) Uani 1 1 d .
O1 O 0.7203(2) -0.52515(10) 0.45903(15) 0.0177(6) Uani 1 1 d .
O2 O 0.86396(19) -0.49410(10) 0.54200(14) 0.0165(6) Uani 1 1 d .
O3 O 0.4835(2) -0.58793(9) 0.92643(15) 0.0191(6) Uani 1 1 d .
O4 O 0.4590(2) -0.59272(10) 0.81433(17) 0.0256(7) Uani 1 1 d .
O5 O 0.5137(2) -0.39631(9) 0.88091(14) 0.0171(6) Uani 1 1 d .
O6 O 0.6306(2) -0.39707(9) 0.99873(15) 0.0208(6) Uani 1 1 d .
O7 O 0.21079(19) -0.56139(9) 0.72894(14) 0.0155(6) Uani 1 1 d .
O8 O 0.2529(2) -0.58050(9) 0.84165(14) 0.0177(6) Uani 1 1 d .
O9 O 0.2868(2) -0.43419(9) 0.77147(14) 0.0155(6) Uani 1 1 d .
O10 O 0.25544(19) -0.42507(9) 0.65858(14) 0.0162(6) Uani 1 1 d .
O11 O -0.0239(2) -0.59883(9) 0.61990(14) 0.0167(6) Uani 1 1 d .
O12 O -0.1466(2) -0.59778(10) 0.50323(15) 0.0194(6) Uani 1 1 d .
O13 O 0.0266(2) -0.41180(9) 0.56612(15) 0.0182(6) Uani 1 1 d .
O14 O 0.0336(2) -0.40415(10) 0.67215(16) 0.0218(6) Uani 1 1 d .
O15 O -0.2252(2) -0.46665(9) 1.04282(14) 0.0172(6) Uani 1 1 d .
O16 O -0.3668(2) -0.49954(10) 0.96130(15) 0.0182(6) Uani 1 1 d .
O17 O 0.54342(19) -0.53609(9) 1.04938(13) 0.0116(5) Uani 1 1 d .
H17B H 0.5716 -0.5573 1.0453 0.044(17) Uiso 1 1 d R
O18 O 0.38490(18) -0.51262(9) 0.83109(13) 0.0110(5) Uani 1 1 d .
H18B H 0.4103 -0.5311 0.8111 0.016 Uiso 1 1 d R
O19 O 0.11528(19) -0.48529(9) 0.66970(13) 0.0125(5) Uani 1 1 d .
H19B H 0.0955 -0.4654 0.6736 0.044(19) Uiso 1 1 d R
O20 O 0.03235(19) -0.53432(10) 0.54930(13) 0.0120(5) Uani 1 1 d .
H20B H 0.0495 -0.5535 0.5476 0.05(2) Uiso 1 1 d R
O21 O 0.2281(2) -0.48285(9) 0.85745(15) 0.0181(6) Uani 1 1 d .
H21C H 0.2349 -0.4584 0.8713 0.027 Uiso 1 1 d R
H21D H 0.1772 -0.4945 0.8609 0.041(16) Uiso 1 1 d R
O22 O 0.2490(2) -0.53081(9) 0.62806(15) 0.0184(6) Uani 1 1 d .
H22B H 0.2691 -0.5427 0.6029 0.049(18) Uiso 1 1 d R
H22C H 0.2527 -0.5495 0.6591 0.073 Uiso 1 1 d R
N1 N 0.5161(2) -0.46126(11) 0.79127(17) 0.0145(7) Uani 1 1 d .
N2 N 0.5184(3) -0.89637(14) 0.9306(2) 0.0392(11) Uani 1 1 d .
N3 N 0.6712(3) -0.09523(12) 0.9196(2) 0.0269(9) Uani 1 1 d .
N4 N 0.1480(4) -0.87210(16) 0.6752(4) 0.0621(16) Uani 1 1 d .
N5 N 0.3218(3) -0.12410(13) 0.7770(2) 0.0348(10) Uani 1 1 d .
N6 N -0.2087(3) -0.89712(12) 0.5973(2) 0.0272(9) Uani 1 1 d .
N7 N -0.0046(4) -0.10321(15) 0.5614(3) 0.0529(14) Uani 1 1 d .
N8 N -0.0209(2) -0.53041(11) 0.71143(18) 0.0152(7) Uani 1 1 d .
C1 C 0.4670(3) -0.48502(15) 0.7304(2) 0.0206(9) Uani 1 1 d .
H1A H 0.4059 -0.4987 0.7194 0.032(14) Uiso 1 1 d R
C2 C 0.5021(3) -0.49008(16) 0.6822(2) 0.0232(9) Uani 1 1 d .
H2A H 0.4641 -0.5064 0.6397 0.047(16) Uiso 1 1 d R
C3 C 0.5936(3) -0.47098(13) 0.6969(2) 0.0155(8) Uani 1 1 d .
C4 C 0.6426(3) -0.44477(15) 0.7593(2) 0.0220(9) Uani 1 1 d .
H4A H 0.7027 -0.4301 0.7708 0.026 Uiso 1 1 d R
C5 C 0.6013(3) -0.44051(14) 0.8034(2) 0.0198(9) Uani 1 1 d .
H5A H 0.6345 -0.4221 0.8440 0.025(12) Uiso 1 1 d R
C6 C 0.6379(3) -0.47879(14) 0.6501(2) 0.0180(8) Uani 1 1 d .
C7 C 0.6005(4) -0.51260(17) 0.5979(3) 0.0329(12) Uani 1 1 d .
H7A H 0.5466 -0.5303 0.5921 0.08(2) Uiso 1 1 d R
C8 C 0.6420(4) -0.52036(17) 0.5541(3) 0.0302(11) Uani 1 1 d .
H8A H 0.6148 -0.5424 0.5184 0.036(15) Uiso 1 1 d R
C9 C 0.7240(3) -0.49500(14) 0.5634(2) 0.0174(8) Uani 1 1 d .
C10 C 0.7619(3) -0.46133(15) 0.6148(2) 0.0223(9) Uani 1 1 d .
H10A H 0.8176 -0.4446 0.6216 0.039(15) Uiso 1 1 d R
C11 C 0.7183(3) -0.45311(16) 0.6567(2) 0.0229(9) Uani 1 1 d .
H11A H 0.7430 -0.4298 0.6903 0.057(18) Uiso 1 1 d R
C12 C 0.7715(3) -0.50509(13) 0.5187(2) 0.0144(8) Uani 1 1 d .
C13 C 0.5503(4) -0.87616(16) 0.8899(3) 0.0322(11) Uani 1 1 d .
H13A H 0.5793 -0.8939 0.8691 0.08(2) Uiso 1 1 d R
C14 C 0.5400(3) -0.83049(15) 0.8753(3) 0.0262(10) Uani 1 1 d .
H14A H 0.5621 -0.8181 0.8456 0.035(14) Uiso 1 1 d R
C15 C 0.4988(3) -0.80299(15) 0.9065(2) 0.0237(9) Uani 1 1 d .
C16 C 0.4650(4) -0.82387(17) 0.9486(3) 0.0376(12) Uani 1 1 d .
H16A H 0.4346 -0.8074 0.9696 0.041(16) Uiso 1 1 d R
C17 C 0.4756(5) -0.87002(18) 0.9579(3) 0.0451(14) Uani 1 1 d .
H17A H 0.4513 -0.8836 0.9855 0.07(2) Uiso 1 1 d R
C18 C 0.4939(3) -0.75357(14) 0.8974(3) 0.0229(9) Uani 1 1 d .
C19 C 0.4775(3) -0.73372(15) 0.8333(3) 0.0268(10) Uani 1 1 d .
H19A H 0.4700 -0.7518 0.7953 0.031(14) Uiso 1 1 d R
C20 C 0.4729(3) -0.68774(15) 0.8248(2) 0.0233(9) Uani 1 1 d .
H20A H 0.4615 -0.6749 0.7815 0.031(14) Uiso 1 1 d R
C21 C 0.4865(3) -0.66005(13) 0.8819(2) 0.0178(8) Uani 1 1 d .
C22 C 0.5029(3) -0.67938(15) 0.9459(3) 0.0246(10) Uani 1 1 d .
H22A H 0.5122 -0.6612 0.9841 0.035(14) Uiso 1 1 d R
C23 C 0.5069(3) -0.72577(15) 0.9535(2) 0.0240(9) Uani 1 1 d .
H23A H 0.5177 -0.7383 0.9968 0.028(13) Uiso 1 1 d R
C24 C 0.4760(3) -0.60934(13) 0.8725(2) 0.0150(8) Uani 1 1 d .
C25 C 0.5846(4) -0.11607(16) 0.8737(3) 0.0373(12) Uani 1 1 d .
H25A H 0.5311 -0.0994 0.8386 0.045 Uiso 1 1 d R
C26 C 0.5705(3) -0.16198(15) 0.8758(3) 0.0304(11) Uani 1 1 d .
H26A H 0.5085 -0.1751 0.8439 0.037 Uiso 1 1 d R
C27 C 0.6499(3) -0.18835(14) 0.9257(2) 0.0191(9) Uani 1 1 d .
C28 C 0.7383(3) -0.16660(15) 0.9737(2) 0.0262(10) Uani 1 1 d .
H28A H 0.7932 -0.1828 1.0090 0.031 Uiso 1 1 d R
C29 C 0.7459(3) -0.12067(15) 0.9688(2) 0.0268(10) Uani 1 1 d .
H29A H 0.8059 -0.1067 1.0023 0.032 Uiso 1 1 d R
C30 C 0.6380(3) -0.23767(14) 0.9280(2) 0.0184(8) Uani 1 1 d .
C31 C 0.6914(4) -0.26176(16) 0.9916(2) 0.0323(11) Uani 1 1 d .
H31A H 0.7392 -0.2472 1.0335 0.039 Uiso 1 1 d R
C32 C 0.6740(4) -0.30691(16) 0.9935(2) 0.0318(11) Uani 1 1 d .
H32A H 0.7113 -0.3224 1.0369 0.038 Uiso 1 1 d R
C33 C 0.6051(3) -0.33017(13) 0.9332(2) 0.0165(8) Uani 1 1 d .
C34 C 0.5552(3) -0.30714(14) 0.8681(2) 0.0226(9) Uani 1 1 d .
H34A H 0.5111 -0.3223 0.8257 0.048(16) Uiso 1 1 d R
C35 C 0.5708(3) -0.26116(14) 0.8661(2) 0.0254(10) Uani 1 1 d .
H35A H 0.5363 -0.2460 0.8222 0.043(15) Uiso 1 1 d R
C36 C 0.5825(3) -0.37855(13) 0.9389(2) 0.0149(8) Uani 1 1 d .
C37 C 0.1375(5) -0.85311(19) 0.7269(4) 0.061(2) Uani 1 1 d .
H37A H 0.1149 -0.8710 0.7517 0.073 Uiso 1 1 d R
C38 C 0.1570(4) -0.80852(18) 0.7466(4) 0.0476(16) Uani 1 1 d .
H38A H 0.1497 -0.7977 0.7847 0.08(2) Uiso 1 1 d R
C39 C 0.1882(3) -0.78019(16) 0.7096(3) 0.0332(12) Uani 1 1 d .
C40 C 0.1987(4) -0.79921(18) 0.6549(3) 0.0446(14) Uani 1 1 d .
H40A H 0.2196 -0.7822 0.6282 0.054 Uiso 1 1 d R
C41 C 0.1764(5) -0.84495(19) 0.6395(4) 0.0565(18) Uani 1 1 d .
H41A H 0.1827 -0.8571 0.6017 0.068 Uiso 1 1 d R
C42 C 0.2036(3) -0.73123(14) 0.7272(3) 0.0245(10) Uani 1 1 d .
C43 C 0.2208(4) -0.71594(16) 0.7932(3) 0.0325(11) Uani 1 1 d .
H43A H 0.2268 -0.7363 0.8281 0.043(15) Uiso 1 1 d R
C44 C 0.2284(4) -0.67058(15) 0.8087(3) 0.0295(11) Uani 1 1 d .
H44A H 0.2398 -0.6609 0.8537 0.042(16) Uiso 1 1 d R
C45 C 0.2190(3) -0.63922(14) 0.7579(2) 0.0159(8) Uani 1 1 d .
C46 C 0.2054(3) -0.65419(14) 0.6917(2) 0.0222(9) Uani 1 1 d .
H46A H 0.2018 -0.6337 0.6575 0.055(18) Uiso 1 1 d R
C47 C 0.1981(3) -0.69963(15) 0.6768(3) 0.0257(10) Uani 1 1 d .
H47A H 0.1890 -0.7092 0.6323 0.056(18) Uiso 1 1 d R
C48 C 0.2285(3) -0.59041(13) 0.7781(2) 0.0136(8) Uani 1 1 d .
C49 C 0.2972(4) -0.14974(16) 0.8170(3) 0.0376(12) Uani 1 1 d .
H49A H 0.2897 -0.1360 0.8532 0.045 Uiso 1 1 d R
C50 C 0.2826(4) -0.19607(16) 0.8080(3) 0.0343(12) Uani 1 1 d .
H50A H 0.2644 -0.2123 0.8370 0.041 Uiso 1 1 d R
C51 C 0.2946(3) -0.21759(14) 0.7555(3) 0.0245(10) Uani 1 1 d .
C52 C 0.3197(3) -0.19067(15) 0.7135(3) 0.0261(10) Uani 1 1 d .
H52A H 0.3284 -0.2032 0.6770 0.022(12) Uiso 1 1 d R
C53 C 0.3327(4) -0.14505(16) 0.7263(3) 0.0327(11) Uani 1 1 d .
H53A H 0.3487 -0.1279 0.6970 0.052(18) Uiso 1 1 d R
C54 C 0.2863(3) -0.26708(14) 0.7457(2) 0.0205(9) Uani 1 1 d .
C55 C 0.3091(3) -0.29546(15) 0.8040(3) 0.0262(10) Uani 1 1 d .
H55A H 0.3283 -0.2831 0.8492 0.060(19) Uiso 1 1 d R
C56 C 0.3065(3) -0.34136(14) 0.7959(2) 0.0220(9) Uani 1 1 d .
H56A H 0.3222 -0.3598 0.8353 0.023(12) Uiso 1 1 d R
C57 C 0.2801(3) -0.36039(13) 0.7292(2) 0.0167(8) Uani 1 1 d .
C58 C 0.2550(3) -0.33244(14) 0.6710(2) 0.0201(9) Uani 1 1 d .
H58A H 0.2368 -0.3445 0.6259 0.016(11) Uiso 1 1 d R
C59 C 0.2581(3) -0.28622(15) 0.6787(2) 0.0234(9) Uani 1 1 d .
H59A H 0.2408 -0.2678 0.6389 0.049(17) Uiso 1 1 d R
C60 C 0.2739(3) -0.40979(13) 0.7191(2) 0.0141(8) Uani 1 1 d .
C61 C -0.1477(4) -0.87226(16) 0.6546(3) 0.0349(12) Uani 1 1 d .
H61A H -0.1151 -0.8859 0.7000 0.042 Uiso 1 1 d R
C62 C -0.1289(4) -0.82700(16) 0.6491(3) 0.0348(12) Uani 1 1 d .
H62A H -0.0851 -0.8112 0.6909 0.042 Uiso 1 1 d R
C63 C -0.1744(3) -0.80516(14) 0.5831(2) 0.0193(9) Uani 1 1 d .
C64 C -0.2380(3) -0.83173(16) 0.5239(2) 0.0292(11) Uani 1 1 d .
H64A H -0.2713 -0.8192 0.4777 0.035 Uiso 1 1 d R
C65 C -0.2536(4) -0.87648(16) 0.5325(3) 0.0301(11) Uani 1 1 d .
H65A H -0.2970 -0.8931 0.4917 0.036 Uiso 1 1 d R
C66 C -0.1557(3) -0.75668(13) 0.5781(2) 0.0171(8) Uani 1 1 d .
C67 C -0.0702(3) -0.73575(14) 0.6332(2) 0.0219(9) Uani 1 1 d .
H67A H -0.0235 -0.7524 0.6729 0.031(14) Uiso 1 1 d R
C68 C -0.0525(3) -0.69023(14) 0.6294(2) 0.0206(9) Uani 1 1 d .
H68A H 0.0047 -0.6769 0.6673 0.035(14) Uiso 1 1 d R
C69 C -0.1190(3) -0.66482(13) 0.5699(2) 0.0153(8) Uani 1 1 d .
C70 C -0.2057(3) -0.68528(14) 0.5157(2) 0.0217(9) Uani 1 1 d .
H70A H -0.2524 -0.6685 0.4761 0.020(12) Uiso 1 1 d R
C71 C -0.2244(3) -0.73050(15) 0.5197(2) 0.0218(9) Uani 1 1 d .
H71A H -0.2837 -0.7432 0.4829 0.030(13) Uiso 1 1 d R
C72 C -0.0957(3) -0.61663(13) 0.5630(2) 0.0136(8) Uani 1 1 d .
C73 C 0.0496(4) -0.12996(19) 0.5431(3) 0.0473(15) Uani 1 1 d .
H73A H 0.0888 -0.1167 0.5259 0.06(2) Uiso 1 1 d R
C74 C 0.0503(4) -0.17639(17) 0.5485(3) 0.0365(12) Uani 1 1 d .
H74A H 0.0880 -0.1933 0.5337 0.019(12) Uiso 1 1 d R
C75 C -0.0062(3) -0.19641(15) 0.5746(3) 0.0301(11) Uani 1 1 d .
C76 C -0.0602(4) -0.16890(17) 0.5940(3) 0.0438(14) Uani 1 1 d .
H76A H -0.0983 -0.1811 0.6129 0.046(17) Uiso 1 1 d R
C77 C -0.0592(4) -0.12320(18) 0.5858(4) 0.0514(17) Uani 1 1 d .
H77A H -0.0986 -0.1055 0.5982 0.07(2) Uiso 1 1 d R
C78 C -0.0066(3) -0.24619(15) 0.5814(3) 0.0245(10) Uani 1 1 d .
C79 C -0.0028(3) -0.27423(15) 0.5310(3) 0.0248(10) Uani 1 1 d .
H79A H -0.0038 -0.2619 0.4906 0.033(14) Uiso 1 1 d R
C80 C 0.0028(3) -0.32035(15) 0.5401(2) 0.0200(9) Uani 1 1 d .
H80A H 0.0049 -0.3386 0.5056 0.028(13) Uiso 1 1 d R
C81 C 0.0041(3) -0.33894(14) 0.5999(2) 0.0166(8) Uani 1 1 d .
C82 C -0.0036(3) -0.31150(15) 0.6491(2) 0.0240(9) Uani 1 1 d .
H82A H -0.0039 -0.3241 0.6889 0.029 Uiso 1 1 d R
C83 C -0.0089(3) -0.26550(15) 0.6399(3) 0.0291(11) Uani 1 1 d .
H83A H -0.0151 -0.2475 0.6731 0.042(16) Uiso 1 1 d R
C84 C 0.0222(3) -0.38879(13) 0.6149(2) 0.0150(8) Uani 1 1 d .
C85 C -0.0677(4) -0.56333(16) 0.7247(3) 0.0300(11) Uani 1 1 d .
H85A H -0.0758 -0.5904 0.7009 0.036 Uiso 1 1 d R
C86 C -0.1064(4) -0.55946(16) 0.7709(3) 0.0307(11) Uani 1 1 d .
H86A H -0.1392 -0.5838 0.7777 0.031(13) Uiso 1 1 d R
C87 C -0.0969(3) -0.51956(15) 0.8065(2) 0.0186(9) Uani 1 1 d .
C88 C -0.0467(3) -0.48517(15) 0.7936(2) 0.0217(9) Uani 1 1 d .
H88A H -0.0362 -0.4580 0.8178 0.019(12) Uiso 1 1 d R
C89 C -0.0108(3) -0.49145(15) 0.7461(2) 0.0218(9) Uani 1 1 d .
H89A H 0.0225 -0.4678 0.7383 0.053(18) Uiso 1 1 d R
C90 C -0.1405(3) -0.51364(14) 0.8537(2) 0.0171(8) Uani 1 1 d .
C91 C -0.0955(3) -0.48413(15) 0.9121(2) 0.0202(9) Uani 1 1 d .
H91A H -0.0369 -0.4686 0.9218 0.021(12) Uiso 1 1 d R
C92 C -0.1378(3) -0.47751(15) 0.9553(2) 0.0214(9) Uani 1 1 d .
H92A H -0.1059 -0.4587 0.9954 0.018(11) Uiso 1 1 d R
C93 C -0.2271(3) -0.49955(13) 0.9402(2) 0.0141(8) Uani 1 1 d .
C94 C -0.2719(3) -0.52923(14) 0.8827(2) 0.0188(9) Uani 1 1 d .
H94A H -0.3310 -0.5443 0.8727 0.026(13) Uiso 1 1 d R
C95 C -0.2286(3) -0.53632(14) 0.8398(2) 0.0205(9) Uani 1 1 d .
H95A H -0.2577 -0.5567 0.8018 0.026(13) Uiso 1 1 d R
C96 C -0.2746(3) -0.48810(14) 0.9843(2) 0.0164(8) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O3 Eu1 O8 79.75(10) . .
O3 Eu1 O17 105.04(9) . 3_647
O8 Eu1 O17 135.76(9) . 3_647
O3 Eu1 O6 75.40(10) . 3_647
O8 Eu1 O6 77.66(9) . 3_647
O17 Eu1 O6 146.55(9) 3_647 3_647
O3 Eu1 O17 70.85(9) . .
O8 Eu1 O17 145.37(9) . .
O17 Eu1 O17 71.40(10) 3_647 .
O6 Eu1 O17 77.57(9) 3_647 .
O3 Eu1 O16 137.21(10) . 3_547
O8 Eu1 O16 128.96(9) . 3_547
O17 Eu1 O16 76.99(9) 3_647 3_547
O6 Eu1 O16 80.82(10) 3_647 3_547
O17 Eu1 O16 69.59(9) . 3_547
O3 Eu1 O18 73.67(9) . .
O8 Eu1 O18 74.25(9) . .
O17 Eu1 O18 65.64(8) 3_647 .
O6 Eu1 O18 141.17(9) 3_647 .
O17 Eu1 O18 112.93(8) . .
O16 Eu1 O18 137.97(9) 3_547 .
O3 Eu1 O15 140.61(10) . 3_547
O8 Eu1 O15 76.47(9) . 3_547
O17 Eu1 O15 113.94(9) 3_647 3_547
O6 Eu1 O15 69.16(9) 3_647 3_547
O17 Eu1 O15 116.00(9) . 3_547
O16 Eu1 O15 52.62(8) 3_547 3_547
O18 Eu1 O15 127.46(8) . 3_547
O3 Eu1 O21 137.97(9) . .
O8 Eu1 O21 73.12(9) . .
O17 Eu1 O21 75.41(9) 3_647 .
O6 Eu1 O21 127.07(9) 3_647 .
O17 Eu1 O21 141.51(9) . .
O16 Eu1 O21 84.54(9) 3_547 .
O18 Eu1 O21 68.47(8) . .
O15 Eu1 O21 61.70(9) 3_547 .
O3 Eu1 C96 146.77(11) . 3_547
O8 Eu1 C96 102.55(10) . 3_547
O17 Eu1 C96 96.18(10) 3_647 3_547
O6 Eu1 C96 72.85(11) 3_647 3_547
O17 Eu1 C96 92.79(10) . 3_547
O16 Eu1 C96 26.45(10) 3_547 3_547
O18 Eu1 C96 139.29(10) . 3_547
O15 Eu1 C96 26.18(10) 3_547 3_547
O21 Eu1 C96 71.81(10) . 3_547
O3 Eu1 Cu1 85.27(7) . .
O8 Eu1 Cu1 107.10(7) . .
O17 Eu1 Cu1 32.87(6) 3_647 .
O6 Eu1 Cu1 159.06(7) 3_647 .
O17 Eu1 Cu1 88.65(6) . .
O16 Eu1 Cu1 109.27(7) 3_547 .
O18 Eu1 Cu1 33.38(6) . .
O15 Eu1 Cu1 131.65(7) 3_547 .
O21 Eu1 Cu1 73.14(6) . .
C96 Eu1 Cu1 124.15(8) 3_547 .
O3 Eu1 Cu2 96.60(7) . .
O8 Eu1 Cu2 57.41(7) . .
O17 Eu1 Cu2 78.43(6) 3_647 .
O6 Eu1 Cu2 135.03(7) 3_647 .
O17 Eu1 Cu2 142.33(6) . .
O16 Eu1 Cu2 124.91(7) 3_547 .
O18 Eu1 Cu2 31.17(6) . .
O15 Eu1 Cu2 96.45(6) 3_547 .
O21 Eu1 Cu2 41.59(6) . .
C96 Eu1 Cu2 112.73(8) 3_547 .
Cu1 Eu1 Cu2 54.336(12) . .
O3 Eu1 H17B 55.0 . .
O8 Eu1 H17B 130.0 . .
O17 Eu1 H17B 81.2 3_647 .
O6 Eu1 H17B 71.8 3_647 .
O17 Eu1 H17B 16.2 . .
O16 Eu1 H17B 84.0 3_547 .
O18 Eu1 H17B 107.5 . .
O15 Eu1 H17B 124.8 3_547 .
O21 Eu1 H17B 155.7 . .
C96 Eu1 H17B 104.9 3_547 .
Cu1 Eu1 H17B 90.6 . .
Cu2 Eu1 H17B 138.6 . .
O10 Eu2 O13 79.43(9) . .
O10 Eu2 O20 134.57(9) . .
O13 Eu2 O20 99.63(10) . .
O10 Eu2 O20 143.77(10) . 3_546
O13 Eu2 O20 68.02(9) . 3_546
O20 Eu2 O20 68.84(10) . 3_546
O10 Eu2 O12 78.62(9) . 3_546
O13 Eu2 O12 72.96(10) . 3_546
O20 Eu2 O12 145.17(9) . 3_546
O20 Eu2 O12 77.03(9) 3_546 3_546
O10 Eu2 O2 132.28(9) . 3_646
O13 Eu2 O2 132.96(9) . 3_646
O20 Eu2 O2 80.98(9) . 3_646
O20 Eu2 O2 68.66(9) 3_546 3_646
O12 Eu2 O2 80.37(9) 3_546 3_646
O10 Eu2 O1 79.31(9) . 3_646
O13 Eu2 O1 139.02(10) . 3_646
O20 Eu2 O1 120.14(9) . 3_646
O20 Eu2 O1 115.41(9) 3_546 3_646
O12 Eu2 O1 68.73(9) 3_546 3_646
O2 Eu2 O1 53.14(9) 3_646 3_646
O10 Eu2 O22 82.91(9) . .
O13 Eu2 O22 143.53(9) . .
O20 Eu2 O22 71.28(9) . .
O20 Eu2 O22 133.07(10) 3_546 .
O12 Eu2 O22 133.87(9) 3_546 .
O2 Eu2 O22 81.69(9) 3_646 .
O1 Eu2 O22 66.47(9) 3_646 .
O10 Eu2 O19 71.85(9) . .
O13 Eu2 O19 72.63(9) . .
O20 Eu2 O19 64.86(8) . .
O20 Eu2 O19 111.02(8) 3_546 .
O12 Eu2 O19 137.88(9) 3_546 .
O2 Eu2 O19 141.67(9) 3_646 .
O1 Eu2 O19 131.28(9) 3_646 .
O22 Eu2 O19 71.61(9) . .
O10 Eu2 C12 105.55(10) . 3_646
O13 Eu2 C12 142.40(10) . 3_646
O20 Eu2 C12 101.96(10) . 3_646
O20 Eu2 C12 91.76(10) 3_546 3_646
O12 Eu2 C12 71.70(10) 3_546 3_646
O2 Eu2 C12 26.76(10) 3_646 3_646
O1 Eu2 C12 26.41(10) 3_646 3_646
O22 Eu2 C12 73.25(10) . 3_646
O19 Eu2 C12 144.82(10) . 3_646
O10 Eu2 Cu3 104.85(6) . .
O13 Eu2 Cu3 82.94(7) . .
O20 Eu2 Cu3 31.84(6) . .
O20 Eu2 Cu3 87.01(6) 3_546 .
O12 Eu2 Cu3 154.70(6) 3_546 .
O2 Eu2 Cu3 112.14(6) 3_646 .
O1 Eu2 Cu3 136.51(7) 3_646 .
O22 Eu2 Cu3 71.10(6) . .
O19 Eu2 Cu3 33.32(6) . .
C12 Eu2 Cu3 129.05(8) 3_646 .
O10 Eu2 Cu3 139.88(7) . 3_546
O13 Eu2 Cu3 88.88(7) . 3_546
O20 Eu2 Cu3 85.02(6) . 3_546
O20 Eu2 Cu3 30.15(6) 3_546 3_546
O12 Eu2 Cu3 61.26(6) 3_546 3_546
O2 Eu2 Cu3 44.11(6) 3_646 3_546
O1 Eu2 Cu3 85.34(6) 3_646 3_546
O22 Eu2 Cu3 124.02(7) . 3_546
O19 Eu2 Cu3 140.42(6) . 3_546
C12 Eu2 Cu3 62.97(8) 3_646 3_546
Cu3 Eu2 Cu3 111.652(12) . 3_546
O10 Eu2 H19B 67.5 . .
O13 Eu2 H19B 58.9 . .
O20 Eu2 H19B 73.3 . .
O20 Eu2 H19B 106.0 3_546 .
O12 Eu2 H19B 124.5 3_546 .
O2 Eu2 H19B 153.7 3_646 .
O1 Eu2 H19B 138.6 3_646 .
O22 Eu2 H19B 84.8 . .
O19 Eu2 H19B 14.2 . .
C12 Eu2 H19B 157.8 3_646 .
Cu3 Eu2 H19B 41.7 . .
Cu3 Eu2 H19B 136.1 3_546 .
O10 Eu2 H20B 134.3 . .
O13 Eu2 H20B 111.3 . .
O20 Eu2 H20B 11.6 . .
O20 Eu2 H20B 74.9 3_546 .
O12 Eu2 H20B 146.9 3_546 .
O2 Eu2 H20B 73.5 3_646 .
O1 Eu2 H20B 108.7 3_646 .
O22 Eu2 H20B 61.9 . .
O19 Eu2 H20B 69.9 . .
C12 Eu2 H20B 92.1 3_646 .
Cu3 Eu2 H20B 38.8 . .
Cu3 Eu2 H20B 85.8 3_546 .
H19B Eu2 H20B 80.3 . .
O5 Cu1 O17 95.34(11) . 3_647
O5 Cu1 O18 161.21(11) . .
O17 Cu1 O18 85.02(10) 3_647 .
O5 Cu1 N1 87.56(12) . .
O17 Cu1 N1 166.97(12) 3_647 .
O18 Cu1 N1 96.32(12) . .
O5 Cu1 O16 102.15(10) . 1_655
O17 Cu1 O16 74.35(10) 3_647 1_655
O18 Cu1 O16 96.04(10) . 1_655
N1 Cu1 O16 92.62(11) . 1_655
O5 Cu1 O9 89.87(10) . .
O17 Cu1 O9 98.84(10) 3_647 .
O18 Cu1 O9 71.56(9) . .
N1 Cu1 O9 93.86(11) . .
O16 Cu1 O9 166.57(9) 1_655 .
O5 Cu1 Cu2 127.14(8) . .
O17 Cu1 Cu2 94.59(7) 3_647 .
O18 Cu1 Cu2 34.44(7) . .
N1 Cu1 Cu2 93.75(9) . .
O16 Cu1 Cu2 130.48(6) 1_655 .
O9 Cu1 Cu2 37.28(6) . .
O5 Cu1 Eu1 136.75(8) . .
O17 Cu1 Eu1 42.07(8) 3_647 .
O18 Cu1 Eu1 43.82(7) . .
N1 Cu1 Eu1 135.54(10) . .
O16 Cu1 Eu1 76.86(6) 1_655 .
O9 Cu1 Eu1 90.31(6) . .
Cu2 Cu1 Eu1 64.719(13) . .
O5 Cu1 Eu1 82.86(8) . 3_647
O17 Cu1 Eu1 39.04(7) 3_647 3_647
O18 Cu1 Eu1 108.13(7) . 3_647
N1 Cu1 Eu1 129.38(9) . 3_647
O16 Cu1 Eu1 42.45(6) 1_655 3_647
O9 Cu1 Eu1 135.46(6) . 3_647
Cu2 Cu1 Eu1 130.775(16) . 3_647
Eu1 Cu1 Eu1 67.357(11) . 3_647
O19 Cu2 O18 172.36(11) . .
O19 Cu2 O9 94.06(11) . .
O18 Cu2 O9 87.88(11) . .
O19 Cu2 O7 84.89(11) . .
O18 Cu2 O7 92.34(11) . .
O9 Cu2 O7 173.47(11) . .
O19 Cu2 O21 106.41(10) . .
O18 Cu2 O21 81.20(10) . .
O9 Cu2 O21 79.86(10) . .
O7 Cu2 O21 106.62(10) . .
O19 Cu2 Cu1 145.97(8) . .
O18 Cu2 Cu1 34.51(7) . .
O9 Cu2 Cu1 53.58(8) . .
O7 Cu2 Cu1 125.93(8) . .
O21 Cu2 Cu1 80.40(7) . .
O19 Cu2 Cu3 32.40(8) . .
O18 Cu2 Cu3 146.52(8) . .
O9 Cu2 Cu3 125.59(8) . .
O7 Cu2 Cu3 54.51(8) . .
O21 Cu2 Cu3 102.26(7) . .
Cu1 Cu2 Cu3 177.134(19) . .
O19 Cu2 Eu1 145.62(8) . .
O18 Cu2 Eu1 40.72(7) . .
O9 Cu2 Eu1 98.92(8) . .
O7 Cu2 Eu1 85.43(8) . .
O21 Cu2 Eu1 46.03(6) . .
Cu1 Cu2 Eu1 60.945(13) . .
Cu3 Cu2 Eu1 121.681(17) . .
O19 Cu2 Eu2 39.54(7) . .
O18 Cu2 Eu2 133.58(7) . .
O9 Cu2 Eu2 84.84(8) . .
O7 Cu2 Eu2 90.30(8) . .
O21 Cu2 Eu2 141.43(7) . .
Cu1 Cu2 Eu2 117.534(16) . .
Cu3 Cu2 Eu2 59.699(12) . .
Eu1 Cu2 Eu2 172.483(15) . .
O19 Cu2 H19B 16.4 . .
O18 Cu2 H19B 168.4 . .
O9 Cu2 H19B 80.7 . .
O7 Cu2 H19B 99.3 . .
O21 Cu2 H19B 94.7 . .
Cu1 Cu2 H19B 134.2 . .
Cu3 Cu2 H19B 45.0 . .
Eu1 Cu2 H19B 139.1 . .
Eu2 Cu2 H19B 47.7 . .
O20 Cu3 O11 93.03(11) . .
O20 Cu3 O19 85.82(11) . .
O11 Cu3 O19 156.21(11) . .
O20 Cu3 N8 168.92(13) . .
O11 Cu3 N8 89.93(12) . .
O19 Cu3 N8 95.73(12) . .
O20 Cu3 O2 75.47(10) . 1_455
O11 Cu3 O2 104.25(10) . 1_455
O19 Cu3 O2 98.47(10) . 1_455
N8 Cu3 O2 93.45(11) . 1_455
O20 Cu3 Cu2 98.78(7) . .
O11 Cu3 Cu2 125.86(8) . .
O19 Cu3 Cu2 31.86(8) . .
N8 Cu3 Cu2 88.08(9) . .
O2 Cu3 Cu2 129.89(7) 1_455 .
O20 Cu3 Eu2 41.28(8) . .
O11 Cu3 Eu2 132.16(8) . .
O19 Cu3 Eu2 44.96(7) . .
N8 Cu3 Eu2 137.76(10) . .
O2 Cu3 Eu2 80.86(6) 1_455 .
Cu2 Cu3 Eu2 65.786(14) . .
O20 Cu3 Eu2 38.94(8) . 3_546
O11 Cu3 Eu2 83.21(8) . 3_546
O19 Cu3 Eu2 109.50(8) . 3_546
N8 Cu3 Eu2 131.20(9) . 3_546
O2 Cu3 Eu2 43.19(6) 1_455 3_546
Cu2 Cu3 Eu2 133.904(16) . 3_546
Eu2 Cu3 Eu2 68.348(11) . 3_546
O20 Cu3 H20B 16.2 . .
O11 Cu3 H20B 80.0 . .
O19 Cu3 H20B 93.9 . .
N8 Cu3 H20B 169.9 . .
O2 Cu3 H20B 88.1 1_455 .
Cu2 Cu3 H20B 98.6 . .
Eu2 Cu3 H20B 52.4 . .
Eu2 Cu3 H20B 47.0 3_546 .
C12 O1 Eu2 93.0(2) . 3_646
C12 O2 Eu2 92.7(2) . 3_646
C12 O2 Cu3 126.3(2) . 1_655
Eu2 O2 Cu3 92.69(9) 3_646 1_655
C24 O3 Eu1 133.0(2) . .
C36 O5 Cu1 127.5(3) . .
C36 O6 Eu1 139.7(3) . 3_647
C48 O7 Cu2 120.5(2) . .
C48 O8 Eu1 138.7(2) . .
C60 O9 Cu2 119.6(2) . .
C60 O9 Cu1 118.0(2) . .
Cu2 O9 Cu1 89.14(10) . .
C60 O10 Eu2 140.9(2) . .
C72 O11 Cu3 127.5(3) . .
C72 O12 Eu2 138.1(2) . 3_546
C84 O13 Eu2 137.7(2) . .
C96 O15 Eu1 91.7(2) . 3_547
C96 O16 Eu1 95.0(2) . 3_547
C96 O16 Cu1 127.2(3) . 1_455
Eu1 O16 Cu1 92.13(9) 3_547 1_455
Cu1 O17 Eu1 105.06(11) 3_647 3_647
Cu1 O17 Eu1 110.60(11) 3_647 .
Eu1 O17 Eu1 108.60(10) 3_647 .
Cu1 O17 H17B 111.3 3_647 .
Eu1 O17 H17B 116.8 3_647 .
Eu1 O17 H17B 104.6 . .
Cu2 O18 Cu1 111.05(13) . .
Cu2 O18 Eu1 108.11(10) . .
Cu1 O18 Eu1 102.81(10) . .
Cu2 O18 H18B 106.4 . .
Cu1 O18 H18B 108.0 . .
Eu1 O18 H18B 120.4 . .
Cu2 O19 Cu3 115.74(14) . .
Cu2 O19 Eu2 111.28(11) . .
Cu3 O19 Eu2 101.72(10) . .
Cu2 O19 H19B 110.8 . .
Cu3 O19 H19B 114.6 . .
Eu2 O19 H19B 101.4 . .
Cu3 O20 Eu2 106.88(11) . .
Cu3 O20 Eu2 110.91(11) . 3_546
Eu2 O20 Eu2 111.16(10) . 3_546
Cu3 O20 H20B 106.0 . .
Eu2 O20 H20B 118.3 . .
Eu2 O20 H20B 103.4 3_546 .
Cu2 O21 Eu1 92.38(9) . .
Cu2 O21 H21C 117.9 . .
Eu1 O21 H21C 114.4 . .
Cu2 O21 H21D 121.1 . .
Eu1 O21 H21D 102.2 . .
H21C O21 H21D 107.0 . .
Eu2 O22 H22B 109.3 . .
Eu2 O22 H22C 134.6 . .
H22B O22 H22C 109.3 . .
C1 N1 C5 116.6(3) . .
C1 N1 Cu1 122.7(3) . .
C5 N1 Cu1 120.6(3) . .
C17 N2 C13 116.0(5) . .
C29 N3 C25 116.8(4) . .
C37 N4 C41 115.5(5) . .
C53 N5 C49 116.3(4) . .
C61 N6 C65 116.8(4) . .
C77 N7 C73 116.5(5) . .
C85 N8 C89 116.5(4) . .
C85 N8 Cu3 121.8(3) . .
C89 N8 Cu3 121.3(3) . .
N1 C1 C2 123.2(4) . .
N1 C1 H1A 118.5 . .
C2 C1 H1A 118.3 . .
C1 C2 C3 120.4(4) . .
C1 C2 H2A 119.9 . .
C3 C2 H2A 119.7 . .
C2 C3 C4 116.1(4) . .
C2 C3 C6 122.0(4) . .
C4 C3 C6 121.9(3) . .
C5 C4 C3 119.9(4) . .
C5 C4 H4A 120.2 . .
C3 C4 H4A 120.0 . .
N1 C5 C4 123.7(4) . .
N1 C5 H5A 118.2 . .
C4 C5 H5A 118.1 . .
C11 C6 C7 117.7(4) . .
C11 C6 C3 121.4(4) . .
C7 C6 C3 120.9(4) . .
C8 C7 C6 121.3(4) . .
C8 C7 H7A 119.0 . .
C6 C7 H7A 119.7 . .
C9 C8 C7 119.6(4) . .
C9 C8 H8A 120.0 . .
C7 C8 H8A 120.4 . .
C10 C9 C8 119.8(4) . .
C10 C9 C12 120.8(4) . .
C8 C9 C12 119.3(4) . .
C11 C10 C9 120.0(4) . .
C11 C10 H10A 120.1 . .
C9 C10 H10A 119.9 . .
C10 C11 C6 121.5(4) . .
C10 C11 H11A 119.6 . .
C6 C11 H11A 118.9 . .
O1 C12 O2 121.0(3) . .
O1 C12 C9 119.5(3) . .
O2 C12 C9 119.5(3) . .
O1 C12 Eu2 60.59(19) . 3_646
O2 C12 Eu2 60.55(19) . 3_646
C9 C12 Eu2 175.1(3) . 3_646
N2 C13 C14 123.7(5) . .
N2 C13 H13A 118.0 . .
C14 C13 H13A 118.4 . .
C13 C14 C15 119.8(5) . .
C13 C14 H14A 120.3 . .
C15 C14 H14A 119.8 . .
C16 C15 C14 116.7(4) . .
C16 C15 C18 121.3(4) . .
C14 C15 C18 122.0(4) . .
C15 C16 C17 118.9(5) . .
C15 C16 H16A 120.7 . .
C17 C16 H16A 120.3 . .
N2 C17 C16 124.8(5) . .
N2 C17 H17A 117.3 . .
C16 C17 H17A 117.9 . .
C23 C18 C19 118.2(4) . .
C23 C18 C15 120.3(4) . .
C19 C18 C15 121.5(4) . .
C20 C19 C18 121.6(4) . .
C20 C19 H19A 118.9 . .
C18 C19 H19A 119.6 . .
C19 C20 C21 119.7(4) . .
C19 C20 H20A 120.6 . .
C21 C20 H20A 119.7 . .
C22 C21 C20 119.3(4) . .
C22 C21 C24 119.9(4) . .
C20 C21 C24 120.7(4) . .
C21 C22 C23 120.4(4) . .
C21 C22 H22A 119.7 . .
C23 C22 H22A 120.0 . .
C18 C23 C22 120.9(4) . .
C18 C23 H23A 119.7 . .
C22 C23 H23A 119.4 . .
O4 C24 O3 125.9(4) . .
O4 C24 C21 119.1(4) . .
O3 C24 C21 115.0(4) . .
N3 C25 C26 123.0(5) . .
N3 C25 H25A 119.1 . .
C26 C25 H25A 118.0 . .
C27 C26 C25 119.7(4) . .
C27 C26 H26A 119.8 . .
C25 C26 H26A 120.5 . .
C28 C27 C26 117.0(4) . .
C28 C27 C30 122.0(4) . .
C26 C27 C30 121.0(4) . .
C27 C28 C29 119.8(4) . .
C27 C28 H28A 120.3 . .
C29 C28 H28A 119.9 . .
N3 C29 C28 123.6(4) . .
N3 C29 H29A 118.1 . .
C28 C29 H29A 118.3 . .
C31 C30 C35 117.5(4) . .
C31 C30 C27 121.7(4) . .
C35 C30 C27 120.7(4) . .
C32 C31 C30 120.7(4) . .
C32 C31 H31A 119.8 . .
C30 C31 H31A 119.5 . .
C33 C32 C31 122.3(4) . .
C33 C32 H32A 118.6 . .
C31 C32 H32A 119.0 . .
C32 C33 C34 117.8(4) . .
C32 C33 C36 120.6(4) . .
C34 C33 C36 121.6(4) . .
C33 C34 C35 120.0(4) . .
C33 C34 H34A 120.1 . .
C35 C34 H34A 119.8 . .
C30 C35 C34 121.4(4) . .
C30 C35 H35A 119.2 . .
C34 C35 H35A 119.4 . .
O6 C36 O5 126.3(4) . .
O6 C36 C33 118.0(4) . .
O5 C36 C33 115.7(3) . .
N4 C37 C38 124.7(7) . .
N4 C37 H37A 117.7 . .
C38 C37 H37A 117.6 . .
C37 C38 C39 119.6(7) . .
C37 C38 H38A 119.7 . .
C39 C38 H38A 120.6 . .
C40 C39 C38 116.7(5) . .
C40 C39 C42 122.9(5) . .
C38 C39 C42 120.3(5) . .
C39 C40 C41 118.7(6) . .
C39 C40 H40A 121.1 . .
C41 C40 H40A 120.2 . .
N4 C41 C40 124.7(6) . .
N4 C41 H41A 117.9 . .
C40 C41 H41A 117.4 . .
C43 C42 C47 118.1(4) . .
C43 C42 C39 120.3(4) . .
C47 C42 C39 121.5(4) . .
C42 C43 C44 121.2(4) . .
C42 C43 H43A 119.8 . .
C44 C43 H43A 119.0 . .
C43 C44 C45 120.7(4) . .
C43 C44 H44A 119.9 . .
C45 C44 H44A 119.4 . .
C44 C45 C46 118.9(4) . .
C44 C45 C48 118.1(4) . .
C46 C45 C48 123.0(4) . .
C47 C46 C45 119.9(4) . .
C47 C46 H46A 119.7 . .
C45 C46 H46A 120.4 . .
C46 C47 C42 121.1(4) . .
C46 C47 H47A 119.0 . .
C42 C47 H47A 119.9 . .
O8 C48 O7 123.8(4) . .
O8 C48 C45 118.3(3) . .
O7 C48 C45 117.9(3) . .
N5 C49 C50 123.7(5) . .
N5 C49 H49A 118.2 . .
C50 C49 H49A 118.1 . .
C51 C50 C49 119.7(5) . .
C51 C50 H50A 120.3 . .
C49 C50 H50A 120.1 . .
C50 C51 C52 116.5(4) . .
C50 C51 C54 122.6(4) . .
C52 C51 C54 120.8(4) . .
C53 C52 C51 120.0(5) . .
C53 C52 H52A 119.4 . .
C51 C52 H52A 120.6 . .
N5 C53 C52 123.9(5) . .
N5 C53 H53A 118.1 . .
C52 C53 H53A 118.0 . .
C59 C54 C55 118.6(4) . .
C59 C54 C51 120.8(4) . .
C55 C54 C51 120.6(4) . .
C56 C55 C54 120.7(4) . .
C56 C55 H55A 119.8 . .
C54 C55 H55A 119.5 . .
C55 C56 C57 120.6(4) . .
C55 C56 H56A 119.6 . .
C57 C56 H56A 119.8 . .
C58 C57 C56 118.8(4) . .
C58 C57 C60 119.9(4) . .
C56 C57 C60 121.2(4) . .
C57 C58 C59 121.0(4) . .
C57 C58 H58A 120.1 . .
C59 C58 H58A 118.9 . .
C58 C59 C54 120.2(4) . .
C58 C59 H59A 120.0 . .
C54 C59 H59A 119.7 . .
O10 C60 O9 123.7(4) . .
O10 C60 C57 118.2(3) . .
O9 C60 C57 118.1(4) . .
N6 C61 C62 122.6(5) . .
N6 C61 H61A 118.5 . .
C62 C61 H61A 118.9 . .
C63 C62 C61 121.4(4) . .
C63 C62 H62A 119.4 . .
C61 C62 H62A 119.1 . .
C62 C63 C64 115.0(4) . .
C62 C63 C66 121.0(4) . .
C64 C63 C66 124.0(4) . .
C65 C64 C63 121.1(4) . .
C65 C64 H64A 119.3 . .
C63 C64 H64A 119.7 . .
N6 C65 C64 123.1(4) . .
N6 C65 H65A 118.5 . .
C64 C65 H65A 118.4 . .
C67 C66 C71 118.0(4) . .
C67 C66 C63 120.5(4) . .
C71 C66 C63 121.5(4) . .
C66 C67 C68 120.9(4) . .
C66 C67 H67A 119.6 . .
C68 C67 H67A 119.4 . .
C69 C68 C67 120.8(4) . .
C69 C68 H68A 119.9 . .
C67 C68 H68A 119.3 . .
C70 C69 C68 118.4(4) . .
C70 C69 C72 120.8(4) . .
C68 C69 C72 120.8(4) . .
C69 C70 C71 121.0(4) . .
C69 C70 H70A 119.6 . .
C71 C70 H70A 119.4 . .
C70 C71 C66 120.8(4) . .
C70 C71 H71A 119.1 . .
C66 C71 H71A 120.1 . .
O12 C72 O11 125.8(4) . .
O12 C72 C69 118.3(3) . .
O11 C72 C69 115.9(3) . .
N7 C73 C74 123.3(6) . .
N7 C73 H73A 118.1 . .
C74 C73 H73A 118.5 . .
C75 C74 C73 119.1(5) . .
C75 C74 H74A 121.4 . .
C73 C74 H74A 119.5 . .
C76 C75 C74 117.2(5) . .
C76 C75 C78 122.5(5) . .
C74 C75 C78 120.3(4) . .
C75 C76 C77 120.6(6) . .
C75 C76 H76A 119.9 . .
C77 C76 H76A 119.5 . .
N7 C77 C76 123.2(6) . .
N7 C77 H77A 118.5 . .
C76 C77 H77A 118.3 . .
C79 C78 C83 118.5(4) . .
C79 C78 C75 121.4(4) . .
C83 C78 C75 120.1(4) . .
C80 C79 C78 120.8(4) . .
C80 C79 H79A 119.6 . .
C78 C79 H79A 119.5 . .
C81 C80 C79 119.9(4) . .
C81 C80 H80A 120.5 . .
C79 C80 H80A 119.6 . .
C82 C81 C80 119.8(4) . .
C82 C81 C84 119.6(4) . .
C80 C81 C84 120.3(4) . .
C83 C82 C81 120.0(4) . .
C83 C82 H82A 120.2 . .
C81 C82 H82A 119.7 . .
C82 C83 C78 120.8(4) . .
C82 C83 H83A 118.9 . .
C78 C83 H83A 120.3 . .
O14 C84 O13 124.8(4) . .
O14 C84 C81 119.6(4) . .
O13 C84 C81 115.6(4) . .
N8 C85 C86 123.9(4) . .
N8 C85 H85A 117.7 . .
C86 C85 H85A 118.4 . .
C87 C86 C85 120.0(4) . .
C87 C86 H86A 120.0 . .
C85 C86 H86A 119.9 . .
C86 C87 C88 116.4(4) . .
C86 C87 C90 121.5(4) . .
C88 C87 C90 122.1(4) . .
C89 C88 C87 120.3(4) . .
C89 C88 H88A 120.3 . .
C87 C88 H88A 119.4 . .
N8 C89 C88 122.9(4) . .
N8 C89 H89A 118.5 . .
C88 C89 H89A 118.6 . .
C91 C90 C95 119.1(4) . .
C91 C90 C87 120.1(4) . .
C95 C90 C87 120.8(4) . .
C92 C91 C90 120.3(4) . .
C92 C91 H91A 119.8 . .
C90 C91 H91A 119.9 . .
C91 C92 C93 120.3(4) . .
C91 C92 H92A 120.0 . .
C93 C92 H92A 119.7 . .
C94 C93 C92 119.8(4) . .
C94 C93 C96 121.9(3) . .
C92 C93 C96 118.2(4) . .
C93 C94 C95 119.8(4) . .
C93 C94 H94A 120.2 . .
C95 C94 H94A 119.9 . .
C94 C95 C90 120.6(4) . .
C94 C95 H95A 120.1 . .
C90 C95 H95A 119.2 . .
O15 C96 O16 120.6(3) . .
O15 C96 C93 120.4(3) . .
O16 C96 C93 118.9(3) . .
O15 C96 Eu1 62.1(2) . 3_547
O16 C96 Eu1 58.55(19) . 3_547
C93 C96 Eu1 176.2(3) . 3_547
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O3 2.352(3) .
Eu1 O8 2.395(3) .
Eu1 O17 2.417(3) 3_647
Eu1 O6 2.432(3) 3_647
Eu1 O17 2.440(3) .
Eu1 O16 2.449(3) 3_547
Eu1 O18 2.474(2) .
Eu1 O15 2.529(3) 3_547
Eu1 O21 2.596(3) .
Eu1 C96 2.860(4) 3_547
Eu1 Cu1 3.4842(5) .
Eu1 Cu2 3.6040(6) .
Eu1 H17B 2.7488 .
Eu2 O10 2.379(3) .
Eu2 O13 2.388(3) .
Eu2 O20 2.425(3) .
Eu2 O20 2.426(3) 3_546
Eu2 O12 2.464(3) 3_546
Eu2 O2 2.471(3) 3_646
Eu2 O1 2.473(3) 3_646
Eu2 O22 2.472(3) .
Eu2 O19 2.538(3) .
Eu2 C12 2.834(4) 3_646
Eu2 Cu3 3.5172(5) .
Eu2 Cu3 3.6059(6) 3_546
Eu2 H19B 2.7579 .
Eu2 H20B 2.7853 .
Cu1 O5 1.949(3) .
Cu1 O17 1.958(3) 3_647
Cu1 O18 1.966(2) .
Cu1 N1 2.007(3) .
Cu1 O16 2.585(3) 1_655
Cu1 O9 2.606(3) .
Cu1 Cu2 3.2382(7) .
Cu1 Eu1 3.6267(6) 3_647
Cu2 O19 1.944(3) .
Cu2 O18 1.962(2) .
Cu2 O9 1.962(3) .
Cu2 O7 1.982(3) .
Cu2 O21 2.394(3) .
Cu2 Cu3 3.3171(7) .
Cu2 H19B 2.2814 .
Cu3 O20 1.939(3) .
Cu3 O11 1.962(3) .
Cu3 O19 1.973(3) .
Cu3 N8 2.016(3) .
Cu3 O2 2.513(3) 1_455
Cu3 Eu2 3.6059(6) 3_546
Cu3 H20B 2.2021 .
O1 C12 1.263(5) .
O1 Eu2 2.473(3) 3_646
O2 C12 1.278(4) .
O2 Eu2 2.471(3) 3_646
O2 Cu3 2.513(3) 1_655
O3 C24 1.273(5) .
O4 C24 1.238(5) .
O5 C36 1.269(5) .
O6 C36 1.240(5) .
O6 Eu1 2.432(3) 3_647
O7 C48 1.282(4) .
O8 C48 1.250(4) .
O9 C60 1.266(4) .
O10 C60 1.262(5) .
O11 C72 1.273(4) .
O12 C72 1.247(5) .
O12 Eu2 2.464(3) 3_546
O13 C84 1.278(5) .
O14 C84 1.235(5) .
O15 C96 1.262(5) .
O15 Eu1 2.529(3) 3_547
O16 C96 1.279(5) .
O16 Eu1 2.449(3) 3_547
O16 Cu1 2.585(3) 1_455
O17 Cu1 1.958(3) 3_647
O17 Eu1 2.417(3) 3_647
O17 H17B 0.7926 .
O18 H18B 0.8945 .
O19 H19B 0.6889 .
O20 Eu2 2.426(3) 3_546
O20 H20B 0.6384 .
O21 H21C 0.7733 .
O21 H21D 0.8849 .
O22 H22B 0.8208 .
O22 H22C 0.8462 .
N1 C1 1.334(5) .
N1 C5 1.339(5) .
N2 C17 1.329(7) .
N2 C13 1.333(7) .
N3 C29 1.331(6) .
N3 C25 1.338(6) .
N4 C37 1.321(9) .
N4 C41 1.325(8) .
N5 C53 1.332(6) .
N5 C49 1.334(6) .
N6 C61 1.330(6) .
N6 C65 1.346(6) .
N7 C77 1.323(8) .
N7 C73 1.339(8) .
N8 C85 1.325(5) .
N8 C89 1.345(5) .
C1 C2 1.385(5) .
C1 H1A 0.9305 .
C2 C3 1.387(5) .
C2 H2A 0.9320 .
C3 C4 1.397(6) .
C3 C6 1.478(5) .
C4 C5 1.377(5) .
C4 H4A 0.9292 .
C5 H5A 0.9317 .
C6 C11 1.389(6) .
C6 C7 1.395(6) .
C7 C8 1.385(6) .
C7 H7A 0.9298 .
C8 C9 1.385(6) .
C8 H8A 0.9312 .
C9 C10 1.383(6) .
C9 C12 1.490(5) .
C10 C11 1.378(6) .
C10 H10A 0.9298 .
C11 H11A 0.9322 .
C12 Eu2 2.834(4) 3_646
C13 C14 1.389(6) .
C13 H13A 0.9322 .
C14 C15 1.389(6) .
C14 H14A 0.9310 .
C15 C16 1.388(7) .
C15 C18 1.484(6) .
C16 C17 1.389(7) .
C16 H16A 0.9306 .
C17 H17A 0.9318 .
C18 C23 1.388(6) .
C18 C19 1.394(6) .
C19 C20 1.381(6) .
C19 H19A 0.9326 .
C20 C21 1.400(6) .
C20 H20A 0.9335 .
C21 C22 1.386(6) .
C21 C24 1.524(5) .
C22 C23 1.391(6) .
C22 H22A 0.9308 .
C23 H23A 0.9328 .
C25 C26 1.390(6) .
C25 H25A 0.9279 .
C26 C27 1.386(6) .
C26 H26A 0.9289 .
C27 C28 1.378(6) .
C27 C30 1.486(5) .
C28 C29 1.383(6) .
C28 H28A 0.9310 .
C29 H29A 0.9296 .
C30 C31 1.383(6) .
C30 C35 1.389(6) .
C31 C32 1.377(6) .
C31 H31A 0.9305 .
C32 C33 1.372(6) .
C32 H32A 0.9322 .
C33 C34 1.388(5) .
C33 C36 1.502(5) .
C34 C35 1.396(6) .
C34 H34A 0.9298 .
C35 H35A 0.9312 .
C37 C38 1.382(7) .
C37 H37A 0.9313 .
C38 C39 1.392(8) .
C38 H38A 0.9328 .
C39 C40 1.380(7) .
C39 C42 1.497(6) .
C40 C41 1.404(7) .
C40 H40A 0.9306 .
C41 H41A 0.9336 .
C42 C43 1.378(7) .
C42 C47 1.401(6) .
C43 C44 1.384(6) .
C43 H43A 0.9311 .
C44 C45 1.384(6) .
C44 H44A 0.9333 .
C45 C46 1.398(6) .
C45 C48 1.505(5) .
C46 C47 1.384(6) .
C46 H46A 0.9325 .
C47 H47A 0.9341 .
C49 C50 1.397(6) .
C49 H49A 0.9313 .
C50 C51 1.381(7) .
C50 H50A 0.9310 .
C51 C52 1.392(6) .
C51 C54 1.487(6) .
C52 C53 1.382(6) .
C52 H52A 0.9319 .
C53 H53A 0.9316 .
C54 C59 1.394(6) .
C54 C55 1.398(6) .
C55 C56 1.378(6) .
C55 H55A 0.9332 .
C56 C57 1.394(6) .
C56 H56A 0.9307 .
C57 C58 1.382(5) .
C57 C60 1.485(5) .
C58 C59 1.386(6) .
C58 H58A 0.9320 .
C59 H59A 0.9327 .
C61 C62 1.397(6) .
C61 H61A 0.9323 .
C62 C63 1.384(6) .
C62 H62A 0.9310 .
C63 C64 1.391(6) .
C63 C66 1.488(5) .
C64 C65 1.384(6) .
C64 H64A 0.9321 .
C65 H65A 0.9302 .
C66 C67 1.390(6) .
C66 C71 1.396(5) .
C67 C68 1.394(6) .
C67 H67A 0.9308 .
C68 C69 1.388(5) .
C68 H68A 0.9296 .
C69 C70 1.385(5) .
C69 C72 1.505(5) .
C70 C71 1.390(6) .
C70 H70A 0.9316 .
C71 H71A 0.9297 .
C73 C74 1.389(7) .
C73 H73A 0.9319 .
C74 C75 1.375(7) .
C74 H74A 0.9302 .
C75 C76 1.365(7) .
C75 C78 1.492(6) .
C76 C77 1.376(7) .
C76 H76A 0.9310 .
C77 H77A 0.9318 .
C78 C79 1.388(6) .
C78 C83 1.393(7) .
C79 C80 1.386(6) .
C79 H79A 0.9321 .
C80 C81 1.384(6) .
C80 H80A 0.9301 .
C81 C82 1.383(6) .
C81 C84 1.517(5) .
C82 C83 1.383(6) .
C82 H82A 0.9322 .
C83 H83A 0.9315 .
C85 C86 1.385(6) .
C85 H85A 0.9297 .
C86 C87 1.380(6) .
C86 H86A 0.9318 .
C87 C88 1.387(6) .
C87 C90 1.472(5) .
C88 C89 1.386(5) .
C88 H88A 0.9305 .
C89 H89A 0.9302 .
C90 C91 1.393(6) .
C90 C95 1.394(5) .
C91 C92 1.380(6) .
C91 H91A 0.9304 .
C92 C93 1.393(5) .
C92 H92A 0.9314 .
C93 C94 1.384(5) .
C93 C96 1.489(5) .
C94 C95 1.388(5) .
C94 H94A 0.9297 .
C95 H95A 0.9302 .
C96 Eu1 2.860(4) 3_547
